JP2015158008A5 - - Google Patents
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- Publication number
- JP2015158008A5 JP2015158008A5 JP2015007555A JP2015007555A JP2015158008A5 JP 2015158008 A5 JP2015158008 A5 JP 2015158008A5 JP 2015007555 A JP2015007555 A JP 2015007555A JP 2015007555 A JP2015007555 A JP 2015007555A JP 2015158008 A5 JP2015158008 A5 JP 2015158008A5
- Authority
- JP
- Japan
- Prior art keywords
- metal surface
- anodized
- aniline
- anodized metal
- sealing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 229910052751 metal Inorganic materials 0.000 claims 14
- 239000002184 metal Substances 0.000 claims 14
- 238000007789 sealing Methods 0.000 claims 5
- 239000003774 sulfhydryl reagent Substances 0.000 claims 5
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims 4
- 239000000178 monomer Substances 0.000 claims 4
- 238000005260 corrosion Methods 0.000 claims 3
- 229920000767 polyaniline Polymers 0.000 claims 3
- 229910001069 Ti alloy Inorganic materials 0.000 claims 2
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 2
- 239000010936 titanium Substances 0.000 claims 2
- 229910052719 titanium Inorganic materials 0.000 claims 2
- JLAMDELLBBZOOX-UHFFFAOYSA-N 3H-1,3,4-thiadiazole-2-thione Chemical compound SC1=NN=CS1 JLAMDELLBBZOOX-UHFFFAOYSA-N 0.000 claims 1
- 238000002048 anodisation reaction Methods 0.000 claims 1
- 238000007743 anodising Methods 0.000 claims 1
Claims (9)
- 耐食性陽極酸化金属表面を調製するための方法であって、
アニリンモノマーを含む溶液で金属表面を陽極酸化するステップ、および
前記耐食性陽極酸化金属表面を形成するためにチオールインヒビターを含む封孔溶液で前記金属表面を封孔処理するステップ、
を含み、
前記金属表面がチタンまたはチタンアロイを含む、方法。 - 前記アニリンモノマーがアニリンである、請求項1に記載の方法。
- 前記チオールインヒビターが2,5−メルカプト−1,3,4−チアジアゾール(DMcT)である、請求項1または2に記載の方法。
- 前記チオールインヒビターが、0.01M〜0.1Mの濃度の前記封孔溶液中のDMcTである、請求項3に記載の方法。
- 前記封孔溶液が前記封孔処理するステップでは20℃〜100℃の温度を有する、請求項1から4の何れか一項に記載の方法。
- 前記耐食性陽極酸化金属表面を検証するために試験するステップをさらに含む、請求項1から5の何れか一項に記載の方法。
- 陽極酸化の間金属表面上にアニリンモノマーを電気化学的に堆積させて塩基性ポリアニリンを形成し、前記金属表面上にドープポリアニリンを形成するために前記金属表面上の前記塩基性ポリアニリンをチオールインヒビターに暴露するステップによって調製される少なくとも1つの陽極酸化金属表面を含み、前記金属表面がチタンまたはチタンアロイを含む、陽極酸化金属構成要素。
- 前記アニリンモノマーがアニリンである、請求項7に記載の陽極酸化金属構成要素。
- 前記チオールインヒビターがDMcTである、請求項7または8に記載の陽極酸化金属構成要素。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14/188,259 US10557210B2 (en) | 2014-02-24 | 2014-02-24 | Direct electrochemical synthesis of doped conductive polymers on metal alloys |
US14/188,259 | 2014-02-24 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2018214451A Division JP6856608B2 (ja) | 2014-02-24 | 2018-11-15 | 金属アロイ上でのドープ導電性ポリマーの直接的な電気化学的合成 |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2015158008A JP2015158008A (ja) | 2015-09-03 |
JP2015158008A5 true JP2015158008A5 (ja) | 2018-03-08 |
JP6441089B2 JP6441089B2 (ja) | 2018-12-19 |
Family
ID=52469717
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2015007555A Active JP6441089B2 (ja) | 2014-02-24 | 2015-01-19 | 金属アロイ上でのドープ導電性ポリマーの直接的な電気化学的合成 |
JP2018214451A Active JP6856608B2 (ja) | 2014-02-24 | 2018-11-15 | 金属アロイ上でのドープ導電性ポリマーの直接的な電気化学的合成 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2018214451A Active JP6856608B2 (ja) | 2014-02-24 | 2018-11-15 | 金属アロイ上でのドープ導電性ポリマーの直接的な電気化学的合成 |
Country Status (5)
Country | Link |
---|---|
US (1) | US10557210B2 (ja) |
EP (2) | EP3396028B1 (ja) |
JP (2) | JP6441089B2 (ja) |
CN (1) | CN104862756B (ja) |
CA (1) | CA2878540C (ja) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20190112726A1 (en) * | 2016-03-28 | 2019-04-18 | Okuno Chemical Industries Co., Ltd. | Sealing liquid for anodic oxide coating films of aluminum alloy, concentrated liquid and sealing method |
JP6862316B2 (ja) * | 2016-09-08 | 2021-04-21 | Jfeスチール株式会社 | 耐遅れ破壊特性に優れた高強度鋼板およびその製造方法 |
CN109972185A (zh) * | 2019-04-17 | 2019-07-05 | 邓华斌 | 一种铝合金无镍环保封孔剂及其制备方法 |
CN110144611B (zh) * | 2019-06-10 | 2021-10-22 | 河北工业大学 | 一种镁合金表面耐蚀耐磨复合涂层及其制备方法 |
US11952679B2 (en) * | 2019-08-30 | 2024-04-09 | The Regents Of The University Of Michigan | Optimized growth of stable hybrid perovskite materials for electromagnetic and particle radiation detection |
US11987669B2 (en) | 2020-10-08 | 2024-05-21 | The Boeing Company | Polyaniline compositions, articles thereof, and methods thereof |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
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US3647645A (en) * | 1969-11-14 | 1972-03-07 | Rohr Corp | Method for selective anodizing of perforated panels |
US5536452A (en) * | 1993-12-07 | 1996-07-16 | Black; Robert H. | Aqueous shower rinsing composition and a method for keeping showers clean |
US5928795A (en) | 1995-02-03 | 1999-07-27 | Polymer Alloys Llc | Corrosion resistant aluminum article coated with emeraldine base polyaniline |
US5980723A (en) * | 1997-08-27 | 1999-11-09 | Jude Runge-Marchese | Electrochemical deposition of a composite polymer metal oxide |
US6328874B1 (en) | 1998-01-05 | 2001-12-11 | Mcdonnell Douglas Corporation | Anodically formed intrinsically conductive polymer-aluminum oxide composite as a coating on aluminum |
US7578921B2 (en) | 2001-10-02 | 2009-08-25 | Henkel Kgaa | Process for anodically coating aluminum and/or titanium with ceramic oxides |
US7235142B2 (en) * | 2002-01-04 | 2007-06-26 | University Of Dayton | Non-toxic corrosion-protection rinses and seals based on cobalt |
WO2003102034A1 (en) * | 2002-06-04 | 2003-12-11 | Lumimove, Inc. D/B/A Crosslink Polymer Research | Corrosion-responsive coating formulations for protection of metal surfaces |
US6942899B2 (en) * | 2002-07-08 | 2005-09-13 | The Boeing Company | Coating for inhibiting oxidation of a substrate |
US7021993B2 (en) | 2002-07-19 | 2006-04-04 | Cabot Microelectronics Corporation | Method of polishing a substrate with a polishing system containing conducting polymer |
JP4240961B2 (ja) | 2002-09-04 | 2009-03-18 | チッソ株式会社 | 改質された導電性ポリマーフイルム及びその製造方法 |
US7125610B2 (en) * | 2003-03-17 | 2006-10-24 | Kemet Electronics Corporation | Capacitor containing aluminum anode foil anodized in low water content glycerine-phosphate electrolyte without a pre-anodizing hydration step |
US7670511B2 (en) * | 2004-10-01 | 2010-03-02 | Polyone Corporation | Use of cathodic protection compounds on treated metal articles |
KR101237842B1 (ko) | 2004-11-10 | 2013-03-04 | 케메탈 게엠베하 | 수성 조성물 및 그 수성 조성물을 이용하여 금속 표면을코팅하는 방법 |
US8101014B2 (en) | 2004-11-10 | 2012-01-24 | Chemetall Gmbh | Process for coating metallic surfaces with a multicomponent aqueous composition |
JP4603934B2 (ja) | 2005-05-31 | 2010-12-22 | 新日本製鐵株式会社 | 大気環境中において変色を生じにくい発色の純チタン |
US8691028B2 (en) * | 2006-05-10 | 2014-04-08 | The Boeing Company | Article having a hexavalent-chromium-free, corrosion-inhibiting organic conversion coating thereon, and its preparation |
EP2118341A2 (en) | 2007-03-05 | 2009-11-18 | Scott Hayes | Multi-layer and composite corrosion resistant coatings |
EP2371996B1 (en) | 2008-12-26 | 2016-03-09 | Nihon Parkerizing Co., Ltd. | Method of electrolytic ceramic coating for metal, electrolysis solution for electrolytic ceramic coating for metal, and metallic material |
US9771483B2 (en) | 2013-04-19 | 2017-09-26 | The Boeing Company | Systems, compositions, and methods for corrosion inhibition |
-
2014
- 2014-02-24 US US14/188,259 patent/US10557210B2/en active Active
-
2015
- 2015-01-16 CA CA2878540A patent/CA2878540C/en active Active
- 2015-01-19 JP JP2015007555A patent/JP6441089B2/ja active Active
- 2015-02-12 CN CN201510075092.4A patent/CN104862756B/zh active Active
- 2015-02-16 EP EP18166401.2A patent/EP3396028B1/en active Active
- 2015-02-16 EP EP15155273.4A patent/EP2910668B1/en active Active
-
2018
- 2018-11-15 JP JP2018214451A patent/JP6856608B2/ja active Active
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