JP2015137443A - Woven or knitted fabric for clothing including different-color combined filament polyamide crimped yarn - Google Patents
Woven or knitted fabric for clothing including different-color combined filament polyamide crimped yarn Download PDFInfo
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本発明は、衣料用織編物に関するものである。更に詳しくは、本発明は、特に婦人衣料に最適な異色混繊ポリアミド捲縮糸からなる織編物であって、秋冬用途を中心とした婦人衣料素材として求められる、しっかりとしたボリューム感とハリコシ感を有するとともに、軽量性と保温性に優れ、自然な杢調の外観品位特徴を有する衣料用織編物およびその衣料用織編物を用いた婦人衣服に関するものである。 The present invention relates to a woven or knitted fabric for clothing. More specifically, the present invention is a woven or knitted fabric made of different color mixed polyamide crimped yarn that is particularly suitable for women's clothing, and is required to be a material for women's clothing mainly for fall / winter applications. In addition, the present invention relates to a woven or knitted fabric for clothing that is excellent in lightness and heat retention and has a natural tone-like appearance quality characteristic, and ladies' clothing using the woven or knitted fabric for clothing.
近年の衣料用途の原糸や織編物は、より細く、より繊細なポリエステル繊維およびポリアミド繊維を用いた軽量感のある布帛により、ソフト風合いと高いドレープ性を重視した素材が追求され提案されている。特に、秋冬用途を中心とした中厚地織物は、ポリエステル繊維やポリアミド繊維の仮撚加工糸、あるいは海島型繊維や複合割繊糸などを用いた織編物によって展開されている。また、自然な杢調外観を表現するため、ポリエステル繊維とポリアミド繊維の混維糸や、またはこれらとカチオン染料可染ポリエステル繊維との混繊糸が採用されているが、これらの混維糸を用いた織編物は、コートなどのアウター用途で主力である紡毛ウール素材などのボリューム感やハリコシ感には及ばす、なお不十分であった。 In recent years, yarns and knitted fabrics for garments have been proposed by pursuing materials that emphasize soft texture and high drapability, with thinner and more lightweight fabrics using polyester fibers and polyamide fibers. . In particular, medium-thick woven fabrics mainly for autumn / winter applications are developed by woven or knitted fabrics using false twisted yarns of polyester fibers or polyamide fibers, sea-island type fibers or composite split yarns. In addition, in order to express a natural tone appearance, blended yarns of polyester fibers and polyamide fibers or blended yarns of these with cationic dye-dyed polyester fibers are used. The knitted and knitted fabric used was still insufficient to reach the volume and harshness of the woolen wool material, which is the mainstay for outer applications such as coats.
また、衣料用途で展開されているポリエステル繊維やポリアミド繊維糸の総繊度は、通常22デシテックス〜200デシテックスの繊度範囲であり、これらの糸条を混繊し、合撚して用いられるが、紡毛ウール素材のボリューム感や自然な杢調外観を得るには、少なくとも3〜4本以上の糸条を合撚することなどが必要となるため、製造コストが高くなり汎用素材としては使用が困難であった。また、ボリューム感を得るために、仮撚加工糸などを用いた場合は、ボリューム感は得られても風合いは硬粗となり、衣服とした場合に重くなりすぎるなどの課題があり、使用が困難であった。 In addition, the total fineness of polyester fibers and polyamide fiber yarns developed for clothing applications is usually in the range of 22 decitex to 200 decitex, and these yarns are mixed and used by twisting. In order to obtain a voluminous feel and a natural tone appearance of the wool material, it is necessary to twist at least 3 to 4 yarns. Therefore, the production cost becomes high and it is difficult to use as a general-purpose material. there were. In addition, when false twisted yarn is used to obtain a sense of volume, it is difficult to use because there is a problem that even if a sense of volume is obtained, the texture becomes hard and rough, and it becomes too heavy for clothing. Met.
一方で、従来、軽量厚地織物として、中空率が5〜30%、単繊維繊度が5デニール以上で、総繊度が300デニール以上の井型断面ナイロン中空マルチフィラメント糸を用いた軽量厚地織物が提案されている(特許文献1参照。)。この提案では、ナイロン繊維の異形中空断面延伸糸を用い、異形断面による単糸間の空隙と300デニール以上の繊度によって軽量の厚地織物を得ているため、生地厚みと軽量感は得られるが、シャリ感、ドライ感およびハリコシ感が強すぎること、また、膨らみ感のあるボリューム感ならびに紡毛ウールの自然な杢調外観を得ることが難しく、近年の衣料用途素材で追求されているソフト感においても、満足のいくものではなかった。 On the other hand, as a lightweight heavyweight woven fabric, a lightweight heavyweight woven fabric using a well-shaped cross-section nylon hollow multifilament yarn with a hollowness of 5-30%, a single fiber fineness of 5 denier or more, and a total fineness of 300 denier or more has been proposed. (See Patent Document 1). In this proposal, since a lightweight, thick fabric is obtained by using a hollow shaped stretched nylon yarn of a nylon fiber and a gap between single yarns by a modified cross section and a fineness of 300 denier or more, a fabric thickness and a lightweight feeling can be obtained. It is difficult to obtain a crispness, dryness and harshness, and a bulging volume and a natural tone of woolen wool. , Was not satisfactory.
また、スパン調粗杢織物として、ポリアミド捲縮フィラメントとカチオン可染性ポリエステルフィラメントの混繊交絡糸を用いた布帛が提案されている(特許文献2参照。)。しがしながら、この提案では、使用される糸条の総繊度範囲が30〜75デニールとこれまでの衣料用で用いられる繊度範囲であるため、自然な杢調が得られるが、紡毛ウール素材の様なしっかりとしたボリューム感や膨らみ感を得るまでに至っていない。また、ソフトタッチを得るため単繊維繊度を1.5デニール以下としているため、軽量性と保温性においても満足のいくものがではなかった。 In addition, a fabric using a mixed entangled yarn of a polyamide crimped filament and a cationic dyeable polyester filament has been proposed as a spanned coarse woven fabric (see Patent Document 2). However, in this proposal, since the total fineness range of the yarn used is 30 to 75 deniers and the fineness range used for garments so far, natural tone can be obtained. It has not yet reached a solid volume and bulge. Moreover, since the single fiber fineness is 1.5 denier or less in order to obtain a soft touch, the lightness and the heat retention are not satisfactory.
上記のように、従来技術では、衣料用途、特に秋冬用途を中心とした婦人衣料用途で求められるボリューム感とハリコシ感、および紡毛ウールの自然な杢調外観を満足する織編物を得るまでに至っていない。
そこで本発明の目的は、上記の従来技術の背景に鑑み、製造コストを抑え、しっかりとしたボリューム感とハリコシ感を有するとともに、軽量性と保温性に優れ、自然な杢調な外観品位に特徴を有する衣料用織編物を提供することができる異色混繊ポリアミド捲縮糸を用いた織編物、およびそれらの織編物を用いた婦人用衣服を提供することにある。
As described above, the conventional technology has led to the production of woven and knitted fabrics that satisfy the voluminous and harshness required for apparel applications, particularly women's apparel applications, especially for autumn and winter, and the natural tone of woolen wool. Not in.
Therefore, in view of the background of the above-mentioned conventional technology, the object of the present invention is to reduce the manufacturing cost, to have a solid volume feeling and a firm feeling, to be excellent in lightness and heat retention, and to be characterized by a natural tone appearance quality. It is another object of the present invention to provide a woven or knitted fabric using different color mixed polyamide crimped yarns and a garment for women using the woven or knitted fabric.
本発明は、上記の課題を解決するために、次の手段を採用する。 The present invention employs the following means in order to solve the above problems.
本発明の異色混繊ポリアミド捲縮糸を用いた衣料用織編物は、マルチフィラメントからなる互いに異色性を示すポリアミド捲縮糸を含む異色混繊ポリアミド捲縮糸を、少なくとも25質量%含む織編物であって、前記異色混繊ポリアミド捲縮糸が下記要件(1)〜(6)を満たす捲縮糸であることを特徴とする衣料用織編物である。
(1)単繊維繊度が1.5デシテックス以上25デシテックス以下であり、
(2)総繊度が400デシテックス以上1500デシテックス以下であり、
(3)構成フィラメント数が50本以上1000本以下であり、
(4)互いに異色性を示すポリアミド捲縮糸のフィラメント数が10:90〜90:10の範囲で混在し、
(5)単繊維の断面形状が単繊維断面の中心点から放射状に延びて形成された3葉以上の多葉の形状であり、異形度が1.5以上5.5以下であり、
(6)単繊維断面の異形度の変動係数(CV)%が7.0未満1.0以上であること。
The woven or knitted fabric for clothing using the different-color mixed polyamide crimped yarn of the present invention includes at least 25% by mass of the different-color mixed-polyamide crimped yarn including the polyamide crimped yarn having multicolor properties and having different colors. The knitted or knitted fabric for clothing is characterized in that the different color mixed polyamide crimped yarn is a crimped yarn satisfying the following requirements (1) to (6).
(1) The single fiber fineness is 1.5 decitex or more and 25 decitex or less,
(2) The total fineness is not less than 400 dtex and not more than 1500 dtex,
(3) The number of constituent filaments is 50 or more and 1000 or less,
(4) The number of filaments of polyamide crimped yarns exhibiting different colors is mixed in the range of 10:90 to 90:10,
(5) The cross-sectional shape of the single fiber is a multi-leaf shape of three or more leaves formed by extending radially from the center point of the single fiber cross-section, and the deformity is 1.5 or more and 5.5 or less,
(6) The coefficient of variation (CV)% of the degree of irregularity of the single fiber cross section is less than 7.0 and 1.0 or more.
本発明の衣料用織編物の好ましい態様によれば、前記の互いに異色性を示すポリアミド捲縮糸の一方は、カチオン染料可染性ポリアミド捲縮糸である。 According to a preferred aspect of the woven or knitted fabric for clothing of the present invention, one of the polyamide crimped yarns exhibiting different color from each other is a cationic dye dyeable polyamide crimped yarn.
本発明の衣料用織編物の好ましい態様によれば、前記の互いに異色性を示すポリアミド捲縮糸の少なくとも一方のポリアミド捲縮糸を構成する単繊維は、中空率5%以上25%以下の中空糸である。 According to a preferred aspect of the woven or knitted fabric for clothing of the present invention, the single fiber constituting at least one polyamide crimped yarn exhibiting a different color from each other has a hollow ratio of 5% or more and 25% or less. It is a thread.
本発明の衣料用織編物の好ましい態様によれば、前記の異色混繊ポリアミド捲縮糸に実撚りが付与されており、次式(1)で示される撚係数(K)は300以上35,000以下である。
・撚係数K=T×D1/2 ・・・・式(1)
T=糸長1m当たりの撚数
D=糸条の総繊度(デシテックス)
本発明の衣料用織編物の好ましい態様によれば、前記の異色混繊ポリアミド捲縮糸の沸水処理後の伸長率は5%以上30%以下であり、かつ交絡数は5個/m以上50個/m以下である。
According to a preferred aspect of the woven or knitted fabric for clothing of the present invention, a real twist is imparted to the above-mentioned different color mixed polyamide crimped yarn, and the twist coefficient (K) represented by the following formula (1) is 300 to 35, 000 or less.
-Twist factor K = T x D 1/2 ··· Formula (1)
T = number of twists per 1 m of yarn length D = total fineness of yarn (decitex)
According to a preferred aspect of the woven or knitted fabric for clothing of the present invention, the elongation ratio after boiling water treatment of the different color mixed polyamide crimped yarn is 5% or more and 30% or less, and the number of entanglements is 5 / m or more and 50 or more. Pieces / m or less.
本発明の衣料用織編物の好ましい態様によれば、本発明の衣料用織編物の軽量性(cm3/g)は3.0以上6.0以下であり、そして保温性(%)は20以上50以下である。 According to the preferred embodiment of the woven or knitted fabric for clothing of the present invention, the lightweight property (cm 3 / g) of the woven or knitted fabric for clothing of the present invention is 3.0 or more and 6.0 or less, and the heat retention (%) is 20 It is 50 or less.
本発明の衣料用織編物の好ましい態様によれば、前記の衣料用織編物を分解し得られた異色混繊ポリアミド捲縮糸の捲縮率は2.5%以上25%以下である。 According to a preferred aspect of the woven or knitted fabric for clothing of the present invention, the crimp ratio of the different color mixed polyamide crimped yarn obtained by decomposing the woven or knitted fabric for clothing is 2.5% or more and 25% or less.
本発明においては、前記の衣料用織編物を用いて、コート、マント、ジャケット、スカート、ワンピース、パンツおよびドレス等の、特に好ましくは本発明で意図するところの婦人用衣服を製造することができる。 In the present invention, the above-mentioned woven or knitted fabric for clothing can be used to produce a women's garment such as a coat, a cloak, a jacket, a skirt, a dress, pants and a dress, particularly preferably as intended in the present invention. .
本発明によれば、ボリューム感のある衣料用織編物に最適な異色混繊ポリアミド捲縮糸からなる衣料用織編物であって、秋冬用途を中心とした婦人衣料素材に求められるしっかりとしたボリューム感と適度なハリコシ感を有するとともに、軽量性と保温性に優れ、自然な杢調の外観品位特徴を有する衣料用織編物、およびそれらを用いた婦人衣服を得ることができる。 According to the present invention, a woven or knitted fabric for clothing composed of a different color mixed polyamide crimped yarn, which is most suitable for woven fabric and knitted fabric with a sense of volume, and a firm volume required for women's clothing materials mainly for autumn / winter use It is possible to obtain a woven or knitted fabric for clothing having a feeling of feeling and an appropriate elasticity, excellent in lightness and heat retention, and having a natural tone-like appearance quality characteristic, and women's clothing using them.
次に、本発明の異色混繊ポリアミド捲縮糸からなる衣料用織編物について、更に詳細に説明する。 Next, the woven or knitted fabric for clothing made of the different color mixed polyamide crimped yarn of the present invention will be described in more detail.
本発明の異色混繊ポリアミド捲縮糸を用いた衣料用織編物は、マルチフィラメントからなる互いに異色性を示すポリアミド捲縮糸を含む異色混繊ポリアミド捲縮糸を、少なくとも25質量%含む織編物であって、前記異色混繊ポリアミド捲縮糸が下記要件(1)〜(6)を満たす捲縮糸であることを特徴とする衣料用織編物である。
(1)単繊維繊度が1.5デシテックス以上25デシテックス以下であり、
(2)総繊度が400デシテックス以上1500デシテックス以下であり、
(3)構成フィラメント数が50本以上1000本以下であり、
(4)互いに異色性を示すポリアミド捲縮糸のフィラメント数が10:90〜90:10の範囲で混在し、
(5)単繊維の断面形状が単繊維断面の中心点から放射状に延びて形成された3葉以上の多葉の形状であり、異形度が1.5以上5.5以下であり、
(6)単繊維断面の異形度の変動係数(CV)%が7.0未満1.0以上であること。
The woven or knitted fabric for clothing using the different-color mixed polyamide crimped yarn of the present invention includes at least 25% by mass of the different-color mixed-polyamide crimped yarn including the polyamide crimped yarn having multicolor properties and having different colors. The knitted or knitted fabric for clothing is characterized in that the different color mixed polyamide crimped yarn is a crimped yarn satisfying the following requirements (1) to (6).
(1) The single fiber fineness is 1.5 decitex or more and 25 decitex or less,
(2) The total fineness is not less than 400 dtex and not more than 1500 dtex,
(3) The number of constituent filaments is 50 or more and 1000 or less,
(4) The number of filaments of polyamide crimped yarns exhibiting different colors is mixed in the range of 10:90 to 90:10,
(5) The cross-sectional shape of the single fiber is a multi-leaf shape of three or more leaves formed by extending radially from the center point of the single fiber cross-section, and the deformity is 1.5 or more and 5.5 or less,
(6) The coefficient of variation (CV)% of the degree of irregularity of the single fiber cross section is less than 7.0 and 1.0 or more.
本発明における異色混繊ポリアミド捲縮糸とは、互いに異色性を示す捲縮糸を2種以上引き揃えて交絡処理することにより得られる混繊糸であり、かつ捲縮を有する嵩高な糸である。 The different color mixed polyamide crimped yarn in the present invention is a mixed yarn obtained by arranging two or more types of crimped yarns having different colors from each other and tangling them, and is a bulky yarn having crimps. is there.
本発明における異色性を示す捲縮糸とは、顔料または染料によってあらかじめ着色された捲縮糸、もしくは染色性を有する捲縮糸である。すなわち、本発明における異色混繊捲縮糸は、色調が異なるか、もしくは後に染色等の処理を行うことで色調が異なりうる捲縮糸を2種以上引き揃えて交絡処理することにより得られる混繊糸であり、かつ捲縮を有する嵩高な糸である。 In the present invention, the crimped yarn exhibiting a different color is a crimped yarn pre-colored with a pigment or a dye, or a crimped yarn having dyeability. That is, the different color mixed crimped yarn in the present invention is a blend obtained by concentrating two or more types of crimped yarns that are different in color tone or that may be different in color tone by subsequent processing such as dyeing. It is a bulky yarn that is a fine yarn and has crimps.
互いに異色性を示す捲縮糸の組み合わせとしては、顔料もしくは染料によってあらかじめ着色された2種以上の捲縮糸の混繊、または染色性を有する2種以上の捲縮糸の混繊、または顔料もしくは染料によってあらかじめ着色された1種以上の捲縮糸と、染色性を有する1種以上の捲縮糸の混繊、が考えられる。 Examples of combinations of crimped yarns that exhibit different color from each other include a mixture of two or more types of crimped yarns that have been colored in advance with a pigment or a dye, or a mixture of two or more types of crimped yarns that have dyeability. Alternatively, one or more types of crimped yarns pre-colored with a dye and one or more types of crimped yarns having dyeability may be considered.
顔料は有機物、無機物のどちらでも差し支えないが一般的にはカーボンブラック、ベンガラ、フタロシアニン系の顔料が用いられる。 The pigment may be either organic or inorganic, but generally carbon black, bengara, or phthalocyanine pigments are used.
染色性を有する糸としては、例えばポリアミド繊維を例に取るならば通常のポリアミド、酸性染料と結合するアミノ末端基(−NH2)量を増加させたポリアミド、塩基性染料と結合するスルホ末端基(−SO3)を導入したポリアミドが挙げられる。 Examples of the yarn having dyeability include, for example, a polyamide fiber, an ordinary polyamide, a polyamide having an increased amount of amino end groups (—NH 2 ) bonded to an acid dye, and a sulfo end group bonded to a basic dye. Polyamide introduced with (—SO 3 ) may be mentioned.
本発明の異色混繊捲縮糸は、それを構成する捲縮糸があらかじめ顔料または染料で着色させている場合には染色されずとも異色性を示し、それを構成する捲縮糸が潜在的に染色性を有する場合には染色することで最終的に異色性を示すことになる。 The different color mixed crimped yarn of the present invention shows a different color even if it is not dyed when the crimped yarn constituting it is previously colored with a pigment or a dye, and the crimped yarn constituting it is a potential If the dye has dyeability, the dyeing will eventually show a discoloration.
本発明の異色混繊ポリアミド捲縮糸からなる衣料用織編物は、異色混繊ポリアミド捲縮糸を少なくとも25質量%含有していることが重要である。異色混繊ポリアミド捲縮糸の含有量は、好ましくは25質量%以上75質量%未満であり、より好ましくは75質量%以上〜100質量%以下である。本発明の衣料用織編物全体に占める異色混繊ポリアミド捲縮糸の割合が25質量%未満では、本発明の効果であるボリューム感とハリコシ感、ならびに軽量性と保温性の機能性の他、紡毛ウール調の自然な杢調外観の特徴が得られにくくなり、また、本発明の衣料用織編物における衣料用ポリアミド捲縮糸の占める割合は、100質量%までの範囲で選択される。 It is important that the woven or knitted fabric for clothing comprising the different color mixed polyamide crimped yarn of the present invention contains at least 25% by mass of the different color mixed polyamide crimped yarn. The content of the different color mixed polyamide crimped yarn is preferably 25% by mass or more and less than 75% by mass, and more preferably 75% by mass or more and 100% by mass or less. When the proportion of the differently colored mixed polyamide crimped yarn in the entire woven or knitted fabric for clothing of the present invention is less than 25% by mass, in addition to the volume and harshness that are the effects of the present invention, and the functionality of lightness and heat retention, It is difficult to obtain a characteristic of a woolen wool-like natural tone appearance, and the proportion of the polyamide crimped yarn for clothing in the woven or knitted fabric for clothing of the present invention is selected in the range of up to 100% by mass.
本発明で用いられる異色混繊ポリアミド捲縮糸は、単繊維繊度が1.5デシテックス以上25デシテックス以下であり、好ましくは1.5デシテックス以上20デシテックス以下で、更に好ましくは1.5デシテックス以上15デシテックス以下である。 The different color mixed-polyamide crimped yarn used in the present invention has a single fiber fineness of 1.5 dtex to 25 dtex, preferably 1.5 dtex to 20 dtex, and more preferably 1.5 dtex to 15 dtex. Less than decitex.
単繊維繊度が1.5デシテック未満では、風合いはソフトなものが得られるが、単繊維間の空隙が少なくなりボリューム感が得難くなる。また、単繊維繊度が25デシテックスを超えると、生地厚みは得られるが、膨らみのあるしっかりとしたボリューム感、また、衣料用として求められる適度なハリコシ感や風合いが得られないだけではなく、婦人衣料用途においては、女性の肌ならびに中衣や内衣類へ摩擦等の刺激による傷や、外観不良等を引き起こす要因ともなる。 If the single fiber fineness is less than 1.5 decitec, a soft texture can be obtained, but the voids between the single fibers are reduced, making it difficult to obtain a volume feeling. In addition, if the single fiber fineness exceeds 25 dtex, the fabric thickness can be obtained, but not only does it not provide a firm and voluminous sense of volume, but also the appropriate harshness and texture required for clothing. In apparel applications, it can cause damage to the skin of women, inner garments and inner garments due to irritation such as friction, and poor appearance.
本発明で用いられる異色混繊ポリアミド捲縮糸の総繊度は、400デシテックス以上1500デシテックス以下であり、好ましくは400デシテックス以上1200デシテックス以下で、更に好ましくは800デシテックス以上1100デシテックス以下である。 The total fineness of the different color mixed polyamide crimped yarn used in the present invention is 400 dtex or more and 1500 dtex or less, preferably 400 dtex or more and 1200 dtex or less, and more preferably 800 dtex or more and 1100 dtex or less.
総繊度が400デシテックス未満では、織編物にしたときにボリューム感が得難くなり、また、ボリューム感を得るために、少なくとも3本以上を合撚する工程が必要となり、製造コストが上がり、経済的にも好ましくない。また、総繊度が1500デシテックスを超えると、風合いが硬くなるだけではなく、衣料用織編物を製造する撚糸、整経、製織および編成等の工程において、工程通過性の低下および一般的に用いられる衣料用織編物を生産する設備では織編物自体が製造できなくなる場合が生じる。 When the total fineness is less than 400 dtex, it is difficult to obtain a volume feeling when it is made into a woven or knitted fabric, and in order to obtain a volume feeling, a process of twisting at least three yarns is required, which increases the manufacturing cost and is economical. Also, it is not preferable. Further, when the total fineness exceeds 1500 dtex, not only the texture becomes hard, but also in the process of twisting, warping, weaving, knitting and the like for producing a woven or knitted fabric for garments, it is generally used and the process passability is lowered. In a facility for producing a woven or knitted fabric for clothing, the woven or knitted fabric itself may not be manufactured.
本発明で用いられる異色混繊ポリアミド捲縮糸の構成フィラメント本数は、50本以上1000本以下であり、好ましくは60本以上800本以下である。構成フィラメント本数が50本未満になると、本発明の目的の一つである自然な杢調外観が得難くなる。構成フィラメント数が1000本を超えると、衣料素材として求められるしっかりとしたボリューム感、ハリコシ感が得難くなる。 The number of constituent filaments of the different color mixed polyamide crimped yarn used in the present invention is 50 or more and 1000 or less, preferably 60 or more and 800 or less. When the number of constituent filaments is less than 50, it is difficult to obtain a natural gradation appearance, which is one of the objects of the present invention. When the number of constituent filaments exceeds 1000, it becomes difficult to obtain a solid volume feeling and a firm feeling required as clothing materials.
本発明で用いられる異色混繊ポリアミド捲縮糸は、互いに異色性を示すポリアミド捲縮糸のフィラメント数が10:90〜90:10の範囲で混在する。さらに好ましくは30:70〜70:30の範囲である。異色性を示すポリアミド捲縮糸の一方のフィラメント数の範囲が10未満、または90を越える範囲になると、本発明の目的の一つである自然な杢調外観が得難くなる。 The different color mixed polyamide crimped yarns used in the present invention are mixed in a range of 10:90 to 90:10 filaments of polyamide crimped yarns having different colors. More preferably, it is the range of 30: 70-70: 30. When the number of filaments on one side of the polyamide crimped yarn exhibiting the discoloration is less than 10 or more than 90, it is difficult to obtain a natural tone appearance, which is one of the objects of the present invention.
本発明で用いられる異色混繊ポリアミド捲縮糸の単繊維の断面形状は、単繊維断面の中心点から放射状に延びて形成された3葉以上の多葉の形状であり、異形度が1.5以上5.5以下であり、異形度の変動係数(CV)%が7.0未満1.0以上である。 The cross-sectional shape of the single fiber of the different color mixed polyamide crimped yarn used in the present invention is a multi-leaf shape of three or more leaves formed radially extending from the center point of the single fiber cross section, and the degree of deformity is 1. It is 5 or more and 5.5 or less, and the coefficient of variation (CV)% of the irregularity is less than 7.0 and 1.0 or more.
具体的な3葉以上の多葉の形状としては、Y型、十字型およびX断面などが挙げられるが、中でも、風合いとボリューム感のバランスの観点から、Y型断面が好ましく用いられる。 Specific examples of the shape of three or more leaves are a Y shape, a cross shape, and an X cross section. Among them, a Y cross section is preferably used from the viewpoint of balance between texture and volume feeling.
多葉の形状としては、更に好ましくは3葉または4葉の形状であり、異形度は2.0以上4.0以下である。多葉の形状は、特に好ましくは3葉のY型断面形状であり、異形度は2.0以上3.0以下である。多葉形状が3葉未満の形状になると、単繊維間の空隙が発現し難くなり、ボリューム感が得難くなる。また、多葉形状が、単繊維断面の中心点から放射状に延びて形成された多葉の形状でない場合、織編物の外観品位にイラツキが発生し易く、高級感不足となる。 More preferably, the multileaf shape is a three-leaf or four-leaf shape, and the degree of irregularity is 2.0 or more and 4.0 or less. The multileaf shape is particularly preferably a three-leaf Y-shaped cross-sectional shape, and the degree of irregularity is 2.0 or more and 3.0 or less. If the multi-leaf shape is less than 3 leaves, it becomes difficult for voids between the single fibers to appear, and it becomes difficult to obtain a volume feeling. In addition, when the multi-leaf shape is not a multi-leaf shape formed by extending radially from the center point of the single fiber cross section, the appearance quality of the woven or knitted fabric is easily irritated, resulting in a lack of luxury.
また、異形度が1.5未満では、単繊維間の空隙が発現し難くなり、ボリューム感が得難くなる。一方、異形度が5.5を超えると、風合いが硬くシャリ感が強くなり過ぎる他、着用時の肌への刺激ならびに他の衣服類へ摩擦等による外観不良等を引き起こす要因となる。 On the other hand, if the degree of deformity is less than 1.5, voids between single fibers are hardly expressed, and it is difficult to obtain a volume feeling. On the other hand, if the degree of deformity exceeds 5.5, the texture becomes hard and the sharpness becomes too strong, and it may cause irritation to the skin at the time of wearing and poor appearance due to friction to other clothes.
異形度の変動係数(CV)は、1.0%以上7.0%未満であり、好ましくは1.0%以上5.5%以下である。CVが1%未満の異色混繊ポリアミド捲縮糸は、単繊維間の異形度バラツキが殆ど存在しない状態であるが、実質的に製造困難である。また、CVが7.0%を超えると、単繊維間の異形度バラツキが大きいため、異形度が比較的大きい単繊維間に異形度が比較的小さい単繊維が配置されることにより、単繊維間の空隙が発現し難くなり、膨らみのあるしっかりとしたボリューム感、また、秋冬衣料用途として求められる適度なハリコシ感や風合いが得難くなる。 The coefficient of variation (CV) of the degree of irregularity is 1.0% or more and less than 7.0%, preferably 1.0% or more and 5.5% or less. An unusually mixed polyamide crimped yarn having a CV of less than 1% is in a state in which there is almost no irregularity variation between single fibers, but is substantially difficult to produce. Further, if the CV exceeds 7.0%, the variation in the degree of irregularity between the single fibers is large. Therefore, the single fibers having a relatively small degree of irregularity are arranged between the single fibers having a relatively large degree of irregularity. It is difficult to obtain a gap between them, and it is difficult to obtain a firm and voluminous feeling of swelling and an appropriate harshness and texture required for autumn / winter clothing applications.
発明者らの検討によれば、特に、異形度が高い仮撚加工糸では、CVが大きくなることが確認されているが、これは、熱と撚りが同時に強条件で付与される仮撚加工の加工工程において、単繊維にかかる応力による断面変形が単繊維間で異なるためであると考えている。 According to the study by the inventors, it has been confirmed that the false twisted yarn having a high degree of deformity has a high CV, and this is because the false twist is imparted under strong conditions simultaneously with heat and twist. In this processing step, it is considered that the cross-sectional deformation due to the stress applied to the single fiber is different between the single fibers.
また、異形度が1.5未満の仮撚加工糸では、CVが5.5未満の捲縮糸が得られるが、
単繊維間の空隙が発現し難くなり、ボリューム感が得難くなる。
In addition, a false twisted yarn having an irregularity of less than 1.5 can yield a crimped yarn having a CV of less than 5.5.
It becomes difficult to develop voids between single fibers, making it difficult to obtain a volume feeling.
本発明で用いられる異色混繊ポリアミド捲縮糸は、混在する互いに異色性を示すポリアミド捲縮糸の一方が、カチオン染料可染性ポリアミド捲縮糸であることが好ましい。より好ましくは、カチオン染料可染性ポリアミド捲縮糸と、通常の酸性染料可染性を有するポリアミド捲縮糸が混在されていることが好ましい。混在する互いに異色性を示すポリアミド捲縮糸の割合は、10:90〜90:10の範囲で存在する。好ましくは、30:70〜70:30の範囲である。混在する互いに異色性を示すポリアミド捲縮糸の割合が10:90〜90:10の範囲外になると、自然な外観杢調が得られなくなる。 In the different color mixed polyamide crimped yarn used in the present invention, it is preferable that one of the mixed polyamide crimped yarns exhibiting different colors is a cationic dye dyeable polyamide crimped yarn. More preferably, a cationic dyeable dyed polyamide crimped yarn and a normal acid dyeable dyeable polyamide crimped yarn are mixed. The ratio of the mixed polyamide crimped yarns exhibiting different colors is in the range of 10:90 to 90:10. Preferably, it is the range of 30: 70-70: 30. When the ratio of the mixed polyamide crimped yarns having different color characteristics is out of the range of 10:90 to 90:10, a natural appearance gradation cannot be obtained.
本発明で用いられる異色混繊ポリアミド捲縮糸は、互いに異色性を示すポリアミド捲縮糸の少なくとも一方の捲縮糸を構成する単糸繊維が、中空率5%以上25%以下であることが好ましい。中空断面を有する中空糸(中空繊維)を採用することにより、より軽量性のあるボリューム感を得ることができる。より好ましい中空率は、5%〜15%である。中空率が5%未満になると、軽量性が得られにくくなる。また、中空率が25%を超えると、捲縮糸の製造において、製糸性や捲縮付与時の中空断面の潰れ等が発生し易くなる。中空部は、単繊維の繊維長に対し垂直の断面の中に1つでも複数あってもよいが、それらの中空率の合計が5〜25%であることが好ましい。 In the different color mixed polyamide crimped yarn used in the present invention, the single yarn fiber constituting at least one of the polyamide crimped yarns exhibiting different colors may have a hollowness of 5% or more and 25% or less. preferable. By adopting a hollow fiber (hollow fiber) having a hollow cross section, a lighter volume feeling can be obtained. A more preferable hollow ratio is 5% to 15%. When the hollow ratio is less than 5%, it is difficult to obtain light weight. On the other hand, if the hollow ratio exceeds 25%, the production of crimped yarns tends to cause the spinning performance and the collapse of the hollow cross section when crimped. One or a plurality of hollow portions may be present in a cross section perpendicular to the fiber length of the single fiber, but the total of the hollow ratios is preferably 5 to 25%.
本発明で用いられる異色混繊ポリアミド捲縮糸は、実撚りが付与され、次式(1)で示される撚係数(K)が300以上35,000以下であることが好ましい。
・撚係数K=T×D1/2 ・・・・・式(1)
ただし、
・T=糸長1m当たりの撚数、
・D=糸条の総繊度(デシテックス)。
The different color mixed polyamide crimped yarn used in the present invention is preferably provided with a real twist, and the twist coefficient (K) represented by the following formula (1) is preferably 300 or more and 35,000 or less.
-Twist factor K = T x D 1/2 Formula (1)
However,
T = number of twists per meter of yarn length,
D = total fineness of the yarn (decitex).
撚係数(K)は、より好ましくは600以上32,000以下であり、更に好ましくは800以上28,000以下である。撚係数(K)が300未満になると、膨らみ感は得られるが、衣料用織編物を製造する際の工程通過性、特に経糸に用いられる整経工程での毛羽が発生し易くなる場合がある。また、撚係数(K)が35,000を超えると、収束性が高くなり過ぎてボリューム感が得られにくく、シャリ感とドライ感が強すぎる傾向があるほか、杢感がこなれ過ぎ、自然な杢調が得られ難くなる。撚係数(K)が600以上32,000以下の実撚りを付与することにより、衣料用織編物を製造する際の工程通過性が良好となるだけでなく、異色混繊ポリアミド捲縮糸の適度な収束性と解撚トルクにより、本発明の目的とするボリューム感と膨らみ感を最大限に発現させ、優れた軽量性と保温性を得ることができる。 The twist coefficient (K) is more preferably 600 or more and 32,000 or less, and still more preferably 800 or more and 28,000 or less. When the twist coefficient (K) is less than 300, a feeling of swelling can be obtained, but there may be cases where fluff is likely to occur in the warping process used for warp, especially in the process passability when producing a woven or knitted fabric for clothing. . On the other hand, if the twist coefficient (K) exceeds 35,000, the convergence is too high and it is difficult to obtain a sense of volume, and there is a tendency that the sharpness and dryness are too strong. It becomes difficult to obtain gradation. By imparting a real twist with a twisting coefficient (K) of 600 or more and 32,000 or less, not only the process passability when producing a woven or knitted fabric for clothing is improved, but also the moderately mixed mixed polyamide crimped yarn is suitable. With the excellent convergence and untwisting torque, it is possible to maximize the volume and swelling feelings of the present invention, and to obtain excellent lightness and heat retention.
また、実撚りの付与方法については、衣料用途で通常使用されるダウンツイスターやダブルツイスター等を用いることができる。また、工程通過性にビリ等の問題がある場合は、適時、実撚り後に、撚止めセットとしてスチームセット等も実施しても何ら問題はない。 Moreover, about the provision method of a real twist, the down twister, the double twister, etc. which are normally used by the garment use can be used. In addition, when there is a problem such as chatter in process passability, there is no problem even if a steam set or the like is implemented as a twist set after timely twisting.
本発明で用いられる異色混繊ポリアミド捲縮糸は、沸水処理後の伸長率が好ましくは5%以上30%以下であり、さらに好ましくは8%以上30%以下である。沸水処理後の伸長率が5%未満では、ボリューム感や膨らみ感が低下する場合がある。また、沸水処理後の伸長率が30%を超える捲縮糸は、ピンやベルトを用いた仮撚加工機によって捲縮を付与することはできるが、原糸断面が潰れやくなり、光沢ムラやイラツキのような外観不良を起こし易くなる傾向がある。 The different-color mixed-polyamide crimped yarn used in the present invention preferably has an elongation percentage after boiling water treatment of 5% or more and 30% or less, and more preferably 8% or more and 30% or less. When the elongation rate after the boiling water treatment is less than 5%, the volume feeling and the swelling feeling may be lowered. In addition, a crimped yarn having an elongation rate of more than 30% after boiling water treatment can be crimped by a false twisting machine using a pin or a belt, but the cross-section of the raw yarn becomes crushed, gloss unevenness and There is a tendency to cause appearance defects such as irritation.
また、本発明で用いられる異色混繊ポリアミド捲縮糸は、交絡数が5個/m以上50個/m以下であることが好ましい。交絡数は、より好ましくは10個/m以上40個/m以下であり、更に好ましくは10個/m以上20個/m以下である。交絡数が5個/m未満になると、衣料用織編物を製造する撚糸、整経、製織および編成等の工程において、毛羽が発生し易く、工程通過性が著しく低下する場合がある。また、交絡数が50個/mを超えると、衣料用織編物を製造する際の工程通過性は良好であるが、単繊維間の収束性が高く空隙が少なくなり、ボリューム感が得難くなる傾向がある。 In addition, the different color mixed polyamide crimped yarn used in the present invention preferably has an entanglement number of 5 / m or more and 50 / m or less. The number of entanglement is more preferably 10 pieces / m or more and 40 pieces / m or less, and still more preferably 10 pieces / m or more and 20 pieces / m or less. When the number of entanglements is less than 5 / m, fluff is likely to occur in the processes such as twisting, warping, weaving and knitting for producing a woven or knitted fabric for clothing, and the process passability may be significantly reduced. Further, when the number of entanglements exceeds 50 / m, the process passability when producing a woven or knitted fabric for clothing is good, but the convergence between single fibers is high and the gaps are reduced, making it difficult to obtain a sense of volume. Tend.
また、本発明で用いられる異色混繊ポリアミド捲縮糸の製造にあたっては、用いられるポリマー(ポリアミド)としては、ナイロン6、ナイロン66、ナイロン610およびナイロン56等を用いることができ、異色性を示すナイロンとして、塩基性染料と結合するスルホ末端基(−SO3)を導入したポリアミドが挙げられる。特に、ナイロン6またはナイロン66からなるポリアミドが好ましく用いられる。 In the production of the different color mixed polyamide crimped yarn used in the present invention, nylon 6, nylon 66, nylon 610, nylon 56, etc. can be used as the polymer (polyamide) to be used, and exhibit different color. Nylon includes a polyamide having a sulfo end group (—SO 3 ) bonded to a basic dye. In particular, polyamide made of nylon 6 or nylon 66 is preferably used.
また、本発明の効果を損わない範囲であれば、ポリマー(ポリアミド)は共重合成分を含んでいても良い。共重合成分としては、ε-カプラミド、テトラメチレンアジパミド、ヘキサメチレンセバカミド、テトラメチレンイソフタルアミドおよびテトラメチレンテレフタルアミド等が挙げられる。 Further, the polymer (polyamide) may contain a copolymerization component as long as the effects of the present invention are not impaired. Examples of the copolymer component include ε-capramide, tetramethylene adipamide, hexamethylene sebacamide, tetramethylene isophthalamide, and tetramethylene terephthalamide.
また、ポリマー(ポリアミド)には、酸化チタン等の艶消し剤を配合することができる。 Moreover, matting agents, such as a titanium oxide, can be mix | blended with a polymer (polyamide).
本発明で用いられる異色混繊ポリアミド捲縮糸の製造基本工程としては、通常の溶融紡糸、冷却、給油、延伸および捲縮処理からなる捲縮糸製造工程によって得られる互いに異色性を示すポリアミド捲縮糸を、後述する図3に示すような流体交絡処理工程または撚糸処理を得て、異色混繊ポリアミド捲縮糸となる。 The basic process for producing the different color mixed polyamide crimped yarn used in the present invention is a polyamide knot obtained by a crimped yarn production process comprising ordinary melt spinning, cooling, oiling, drawing and crimping processes and showing different colors. The crimped yarn is subjected to a fluid entanglement treatment step or a twisted yarn treatment as shown in FIG.
本発明で用いられる溶融紡糸装置は、エクストルーダー型紡糸機でもプレッシャーメルター型紡糸機でも使用可能であるが、製品の均一性と製糸収率等の点で、エクストルーダー型紡糸機が好ましく用いられる。艶消し剤を添加する場合は、艶消し剤を高濃度で添加したマスターチップを、ポリアミドチップとブレンドしたチップを紡糸機に投入することができ、また、それぞれのチップを紡糸機直上で計量しながら投入することもできる。また、艶消し剤を粉体あるいは液体の状態で、直接紡糸機に投入することもできる。 The melt spinning apparatus used in the present invention can be used in both an extruder-type spinning machine and a pressure melter-type spinning machine, but an extruder-type spinning machine is preferably used in terms of product uniformity and yarn production yield. . When a matting agent is added, a master chip to which a matting agent is added at a high concentration and a chip blended with a polyamide chip can be put into a spinning machine, and each chip is weighed directly above the spinning machine. It can also be thrown in. Further, the matting agent can be directly put into the spinning machine in a powder or liquid state.
かかる異色混繊ポリアミド捲縮糸の特定の総繊度、単繊維繊度および断面形状などを満足させるには、ポリアミドの粘度、紡糸温度、口金孔形状、吐出量および冷却等の紡糸条件を適切に設定して溶融紡糸する。 In order to satisfy the specific total fineness, single fiber fineness, cross-sectional shape, etc. of such different-color mixed polyamide crimped yarn, the spinning conditions such as polyamide viscosity, spinning temperature, die hole shape, discharge rate and cooling are set appropriately. And melt spinning.
溶融紡糸された糸条は、冷風によって冷却固化され、次いで油剤を付与された後、所定の引き取り速度で回転する引き取りローラーに捲回して引き取られる。引き取り速度は、300〜1500m/分が好ましい。引き取られた糸条は、通常、引き続き延伸および捲縮加工を連続して行う。また別の方法として、未延伸糸で一旦巻き取った後、別工程で延伸および捲縮加工を行う方法、あるいは延伸糸を一旦巻き取った後、別工程で捲縮加工を行う方法も可能である。 The melt-spun yarn is cooled and solidified by cold air, and after an oil agent is applied, the yarn is wound around a take-up roller that rotates at a predetermined take-up speed and taken up. The take-up speed is preferably 300 to 1500 m / min. The drawn yarn is usually continuously stretched and crimped continuously. As another method, a method of once winding with an undrawn yarn and then drawing and crimping in another step, or a method of winding the drawn yarn once and then carrying out crimping in another step is also possible. is there.
本発明にかかる異色混繊維ポリアミド捲縮糸が、5%以上30%以下の沸水処理後の伸長率を有するためには、延伸工程で十分に分子鎖の配向を高めてから捲縮加工することが好ましい。延伸倍率は、好ましくは2.0〜4.0倍の範囲であり、伸度が30〜100%となるように延伸することが好ましい。次いで、延伸された糸条は、捲縮付与装置を通して捲縮加工処理される。捲縮は、飽和蒸気、過熱蒸気または加熱空気等の加熱流体加工処理によって行われる。捲縮加工装置は、例えば、特開2004−84080号公報で開示された捲縮加工ノズル装置などを使用することができる。通常は、該捲縮加工ノズルを有するジェットノズル方式で捲縮加工され、ニードル内を通過する糸条に周囲から過熱蒸気や加熱空気等の高圧の高温流体を接触させ、大気中に放出し冷却することにより捲縮が付与される
更に、捲縮を固定する目的で、捲縮ノズルを通過した捲縮糸に冷風を吹きつけたり、内部に吸引するロータリーフィルターの表面に捲縮糸を堆積させて冷却する方法等も採用することができる。
In order for the different-color mixed fiber polyamide crimped yarn according to the present invention to have an elongation rate after boiling water treatment of 5% or more and 30% or less, the molecular chain orientation should be sufficiently increased in the drawing process before crimping. Is preferred. The draw ratio is preferably in the range of 2.0 to 4.0 times, and is preferably drawn so that the elongation is 30 to 100%. Next, the drawn yarn is subjected to a crimping process through a crimping device. Crimping is performed by heated fluid processing such as saturated steam, superheated steam or heated air. As the crimping apparatus, for example, a crimping nozzle apparatus disclosed in Japanese Patent Application Laid-Open No. 2004-84080 can be used. Normally, crimping is performed by a jet nozzle method having the crimping nozzle, and a high-temperature high-temperature fluid such as superheated steam or heated air is brought into contact with the yarn passing through the needle from the surroundings and released into the atmosphere for cooling. In addition, for the purpose of fixing the crimps, cold air is blown on the crimped yarns that have passed through the crimping nozzles, or the crimped yarns are deposited on the surface of the rotary filter that sucks them inside. A cooling method or the like can also be employed.
捲縮加工する際の捲縮ノズルの温度は、190〜250℃が好ましく、より好ましくは210〜240℃である。捲縮ノズルの温度が190℃未満になると、熱処理が不十分なため捲縮を十分に付与することができない。また、捲縮ノズルの温度が250℃を超えると、熱処理が過多となり、ポリマーの融着や劣化が起こり、捲縮糸の物性(強度、伸度および伸長率)が低下することがある。 The temperature of the crimp nozzle when crimping is preferably 190 to 250 ° C, more preferably 210 to 240 ° C. When the temperature of the crimp nozzle is less than 190 ° C., the heat treatment is insufficient, so that the crimp cannot be imparted sufficiently. On the other hand, when the temperature of the crimp nozzle exceeds 250 ° C., the heat treatment becomes excessive, the polymer is fused or deteriorated, and the physical properties (strength, elongation and elongation rate) of the crimp yarn may be lowered.
捲縮加工された互いに異色性を示すポリアミド捲縮糸に適度なストレッチを与えて、捲縮を一部潜在化させた後、集束性を付与するため流体交絡処理工程を得て、異色混繊ポリアミド捲縮糸を得る。 Appropriate stretch is applied to the crimped polyamide crimped yarns exhibiting different colors to make the crimps partially latent, and then a fluid entanglement treatment step is performed to impart converging properties. A polyamide crimped yarn is obtained.
図3に、流体交絡処理による合糸混繊法の一例を示す。混繊される互いに異色性を示すポリアミド捲縮糸がそれぞれ解じょされ、第1ローラーcで引き取られる。次いで第1ローラーcと第2ローラーe間に配置された交絡エアーガイドdによって捲縮糸同士が合糸、混繊され巻き取られて異色混繊ポリアミド捲縮糸が得られる。 FIG. 3 shows an example of a mixed yarn mixing method by fluid entanglement processing. The polyamide crimped yarns having different colors mixed with each other are unwound and taken up by the first roller c. Next, the crimped yarns are combined, mixed and wound by an entangled air guide d disposed between the first roller c and the second roller e to obtain a different color mixed polyamide crimped yarn.
本発明の衣料用織編物は、軽量性(cm3/g)が3.0以上6.0以下であり、かつ保温性(%)が20以上50以下であることが好ましい。軽量性が3.0未満になると、本発明の目的のひとつであるボリューム感が得難くなるほか、従来から衣料用で展開されている22デシテックス〜200デシテックスの繊度範囲のポリエステル繊維やポリアミド繊維の織編物で達成することができる範囲であり、軽量性としては不十分である。また、軽量性が6.0を超えると、ボリューム感の他、秋冬素材に求められる軽量性と保温性がともに優れたものを得ることができるが、織編物が非常に厚くなるため、縫製が難しく実質的に製造困難となる。また、ハリコシ感の不足、生地物性の縫目滑脱抵抗値の不良や、生地のほつれが生じ易い。 The woven or knitted fabric for clothing of the present invention preferably has a lightness (cm 3 / g) of 3.0 or more and 6.0 or less and a heat retention (%) of 20 or more and 50 or less. When the lightness is less than 3.0, it is difficult to obtain a volume feeling, which is one of the objects of the present invention, and polyester fibers and polyamide fibers having a fineness range of 22 decitex to 200 decitex that have been developed for clothing are conventionally used. This is a range that can be achieved with a woven or knitted fabric, and is insufficient in lightness. In addition, when the lightness exceeds 6.0, in addition to the voluminous feel, it is possible to obtain a material that is excellent in both lightness and heat retention required for autumn / winter materials. Difficult and practically difficult to manufacture. In addition, lack of firmness, poor fabric slip resistance resistance and fabric fraying are likely to occur.
また、保温性が20%未満では、秋冬用途に求められ保温性とは言い難く、従来から衣料用途で展開されている22デシテックス〜200デシテックスのポリエステル繊維やポリアミド繊維の織編物で達成できる範囲である。また、保温性が50%を超えると、軽量性が得難くなるほか、非常に厚くする必要があるため実質的に製造が困難となる。 In addition, if the heat retention is less than 20%, it is difficult to say that it is required for autumn / winter applications, and it is within the range that can be achieved with woven and knitted fabrics of 22 decitex to 200 decitex polyester fibers and polyamide fibers that have been developed for garments. is there. On the other hand, if the heat retention exceeds 50%, it is difficult to obtain light weight, and it is necessary to make it very thick, so that it is substantially difficult to manufacture.
本発明の衣料用織編物は、上記に記載した異色混繊ポリアミド捲縮糸を少なくとも25質量%含有していれば、異色混繊ポリアミド捲縮糸以外に他の繊維を含有することができる。他の繊維としては、ポリエステルフィラメントの生糸または仮撚加工糸、ナイロンフィラメントの生糸または仮撚加工糸、スパン糸の合成繊維、アセテートフィラメント糸の半合成繊維、レーヨンフィラメントやスパン糸等の再生繊維、ウールおよび綿や麻等の天然繊維等が挙げられる。他の繊維の含有形態としては、他の繊維単独または、混紡、混繊および合撚されたものとの交編および交織が挙げられる。 The woven or knitted fabric for clothing of the present invention can contain other fibers in addition to the different-color mixed fiber polyamide crimped yarn as long as it contains at least 25% by mass of the different-color mixed fiber polyamide crimped yarn described above. Other fibers include polyester filament raw or false twisted yarn, nylon filament raw or false twisted yarn, spun yarn synthetic fiber, acetate filament yarn semi-synthetic fiber, regenerated fiber such as rayon filament or span yarn, Examples include wool and natural fibers such as cotton and hemp. Examples of the form of the other fibers include other fibers alone, or knitting and weaving with blended fibers, blended fibers, and twisted ones.
織物の形態としては、上記に記載した異色混繊ポリアミド捲縮糸を少なくとも経糸および/または緯糸に用いたものであり、異色混繊ポリアミド捲縮糸を25質量%以上含有していることが必要である。織物組織としては、平織、綾織、サテン、リップル、アムンゼン、平二重および綾二重組織など公知の織物組織であれば、紡毛ウール調の自然な杢調外観の特徴が得られる。 As the form of the woven fabric, the above-described different color mixed polyamide crimped yarn is used for at least warp and / or weft, and it is necessary to contain 25% by mass or more of the different color mixed polyamide crimped yarn. It is. As a woven fabric structure, if it is a known woven fabric structure such as plain weave, twill weave, satin, ripple, amundsen, flat double, and twill double, a natural woolen appearance characteristic of woolen wool can be obtained.
また、編物の形態において、編物組織としては、ハーフ組織やデンビー組織等の経編地、および、ポンチ組織、モックロディ組織、天竺組織やフライス組織等の丸編地の組織等が挙げられる。特に、丸編物は、編組織の空隙と異色混繊ポリアミド捲縮糸の効果により、ボリューム感とハリコシ感、ならびに軽量性が高く、自然な杢調外観の特徴に優れた編物が得られる。 Further, in the form of the knitted fabric, examples of the knitted fabric include warp knitted fabrics such as a half structure and a denby structure, and circular knitted fabric structures such as a punched structure, a mockroded structure, a tentacle structure, and a milling structure. In particular, a circular knitted fabric is knitted with excellent volume and harshness, light weight, and excellent natural tone appearance due to the effects of the voids of the knitting structure and the different colored mixed polyamide crimped yarn.
また、本発明の衣料織編物に用いられる異色混繊ポリアミド捲縮糸は、本発明の特徴であるボリューム感とハリコシ感の阻害、ならびに織編物を製造する際の工程通過性に問題とならない範囲であれば、無撚り状態でも用いることができる。ボリューム感と膨らみ感を最大限に発現させるには、上述したように異色混繊ポリアミド捲縮糸の撚係数(K)が300以上35,000以下の範囲であることが好ましい。 Further, the different color mixed polyamide crimped yarn used in the garment knitted fabric of the present invention is a range in which the volume feeling and the harshness that are the characteristics of the present invention are not inhibited, and the processability during the production of the woven or knitted fabric is not a problem. If it is, it can be used even in a non-twisted state. In order to maximize the volume and swelling feeling, it is preferable that the twist coefficient (K) of the different color mixed polyamide crimped yarn is in the range of 300 to 35,000 as described above.
また、本発明の衣料用織編物は、当該織編物を分解し得られた異色混繊ポリアミド捲縮糸の捲縮率が2.5%以上25%以下であることが好ましい。捲縮率は、更に好ましくは3%以上20%以下である。分解し得られた異色混繊ポリアミド捲縮糸の捲縮率が2.5%未満になると、膨らみのあるボリューム感が得られにくく、捲縮率が25%を超えるとふかつき感が大きくなり、適度なハリコシ感が得られにくくなる。また、衣服にした場合に生地が伸びた状態で回復しなくなり、わらい現象が発生し易くなる。 In the woven or knitted fabric for clothing of the present invention, the crimp ratio of the different color mixed polyamide crimped yarn obtained by decomposing the woven or knitted fabric is preferably 2.5% or more and 25% or less. The crimp rate is more preferably 3% or more and 20% or less. When the crimp ratio of the dissimilar mixed-polyamide crimped yarn obtained by decomposition is less than 2.5%, it is difficult to obtain a swelled volume feeling, and when the crimp ratio exceeds 25%, the feeling of wiping increases. , It will be difficult to obtain a moderate feeling of elasticity. Moreover, when it is used as a garment, the fabric does not recover in the stretched state, and a soft phenomenon is likely to occur.
本発明の衣料用織編物の製造に当たっては、異色混繊ポリアミド捲縮糸を少なくとも25質量%含み製織または編成された生機に、織編物の通常工程である精練、リラックス、乾燥および乾熱セットを行った後、染色、乾燥、および仕上げで一般に適用される公知の方法が適用される。 In the production of the woven or knitted fabric for clothing of the present invention, a scouring, relaxing, drying and dry heat set, which is a normal process of woven or knitted fabric, is applied to a raw machine woven or knitted containing at least 25% by mass of a different color mixed polyamide crimped yarn. After doing, known methods commonly applied in dyeing, drying and finishing are applied.
交編や交織に使用される他の繊維によっては、シルケット、縮絨、酵素減量、およびアルカリ減量等の一般に適用される公知の加工方法を適用することができる。また、より優れたボリューム感やハリコシ感を得るために、ベンジルアルコールを含有する処理液を用いて加熱処理することにより、ポリアミド繊維を収縮させる工程を適用することもできる。さらに必要に応じて、本発明の目的を達成する範囲内で、柔軟、撥水、防汚、抗菌および制電などの仕上げ樹脂加工などを施すことができる。 Depending on other fibers used for knitting and weaving, generally known processing methods such as mercerization, shrinkage, enzyme weight loss, and alkali weight loss can be applied. In addition, in order to obtain a more excellent volume feeling and harsh feeling, a process of shrinking the polyamide fiber by heat treatment using a treatment liquid containing benzyl alcohol can be applied. Furthermore, if necessary, finishing resin processing such as flexibility, water repellency, antifouling, antibacterial and antistatic can be performed within the scope of achieving the object of the present invention.
このようにして得られた本発明の衣料用織編物は、例えば、コート、マント、ジャケット、スカート、ワンピース、パンツおよびドレスから選ばれる上衣類の婦人用途衣服等として好適に用いることができる。特に見た目に特徴を有することから、秋冬用途で重ね着として使用し、最も外側で使用することが好まれるコート、ジャケット等にてより好適に用いることができる。 The woven or knitted fabric for clothing of the present invention thus obtained can be suitably used as, for example, women's clothing for upper clothing selected from coats, cloaks, jackets, skirts, dresses, pants and dresses. Since it has particular visual features, it can be used more suitably in coats, jackets, etc. that are used as layering in autumn / winter applications and are preferred to be used on the outermost side.
次に、本発明の異色混繊ポリアミド捲縮糸からなる衣料用織編物について、実施例によりさらに詳細に説明する。上述の説明中および実施例に示す各特性値は、次の方法により測定したものである。 Next, the woven or knitted fabric for clothing comprising the different color mixed polyamide crimped yarn of the present invention will be described in more detail with reference to examples. Each characteristic value shown in the above description and in the examples is measured by the following method.
(1)総繊度:
JIS L1013(2010) 8.3.1 b)B法に規定される正量繊度を測定して、総繊度とした。
(1) Total fineness:
JIS L1013 (2010) 8.3.1 b) The positive fineness specified in the B method was measured and used as the total fineness.
(2)単繊維繊度:
異色混繊ポリアミド捲縮糸を構成する互いに異色性を示すポリアミド捲縮糸のそれぞれの総繊度を、それぞれのフィラメント数で除して求めた。
(2) Single fiber fineness:
The total fineness of each of the polyamide crimped yarns showing the different color from each other constituting the different color mixed polyamide crimped yarn was obtained by dividing by the number of each filament.
(3)沸水処理後の伸長率:
異色混繊ポリアミド捲縮糸をかせ状にとり、これを温度20℃、湿度65%RHの室内に3時間放置して放縮させた。次いで、沸騰水中に20分間浸漬して沸騰水処理を行った。沸騰水処理したかせ状の糸条を、12時間前記室内で放置乾燥させた。次に、当該糸条を1m程度の長さに切り取り、糸条の総繊度をA(dtex)とすると、17.7A(μN)(1.8A(mg))の初荷重を30秒間加えた後の糸条の長さL1を先ず測定した。
(3) Elongation rate after boiling water treatment:
The different colored mixed polyamide crimped yarn was taken in a skein shape and allowed to stand for 3 hours in a room at a temperature of 20 ° C. and a humidity of 65% RH to be shrunk. Subsequently, it was immersed in boiling water for 20 minutes to perform boiling water treatment. The skeined yarn treated with boiling water was left to dry in the room for 12 hours. Next, the yarn was cut to a length of about 1 m, and assuming that the total fineness of the yarn was A (dtex), an initial load of 17.7 A (μN) (1.8 A (mg)) was applied for 30 seconds. The length L1 of the subsequent yarn was first measured.
次に、883A(μN)(90A(mg))の定荷重を30秒間加えた後の糸条の長さL2を測定した。本発明における沸水処理後の伸長率G(%)は、上記のL1とL2より、次式(2)から求めた。沸水処理後の伸長率は、5サンプルの平均値から求めた。
・G={(L2−L1)/L1}×100(%) ・・・・・式(2)。
Next, the length L2 of the yarn after applying a constant load of 883 A (μN) (90 A (mg)) for 30 seconds was measured. The elongation G (%) after boiling water treatment in the present invention was determined from the following equation (2) from the above L1 and L2. The elongation after the boiling water treatment was determined from the average value of 5 samples.
G = {(L2−L1) / L1} × 100 (%) (2)
(4)交絡数:
異色混繊ポリアミド捲縮糸の交絡数については、目視によって1m当たりの交絡数を測定した。異色混繊ポリアミド捲縮糸の長手方向に5回測定し、その平均値から求めた。または、衣料用織編物から分解して得られた異色混繊ポリアミド捲縮糸は、実撚りが付与されているものは解撚機を用いて実撚りを除去した後、目視して50cm当たりの交絡数を測定した。解撚後の異色混繊ポリアミド捲縮糸の長手方向に5回測定し、1m当たりに換算した数値の平均値より求めた。
(4) Number of confounding:
About the number of entanglement of the different color mixed polyamide crimped yarn, the number of entanglement per 1 m was measured visually. Measurement was performed five times in the longitudinal direction of the different color mixed polyamide crimped yarn, and the average value was obtained. Or, the different colored mixed polyamide crimped yarn obtained by decomposing from the woven or knitted fabric for clothing is applied with a real twist. After removing the real twist using an untwisting machine, it is visually observed per 50 cm. The number of confounding was measured. It measured 5 times in the longitudinal direction of the different color mixed polyamide crimped yarn after untwisting, and calculated | required from the average value of the numerical value converted per 1 m.
(5)異形度:
レーヨンステープルで包んだ異色混繊ポリアミド捲縮糸の糸端を、厚さ0.5mmのステンレス製プレパラートに設けた穴(穴径1.0mm)に通し、安全カミソリでプレパラートの両面に沿って平行にカットしたものを、断面観察用の試料とした。この試料を、KEYENCE社製デジタルマイクロスコープ「VHX−500」を用いて500倍で観察し、単繊維の横断面の外接円の直径Dと、単繊維の横断面の内接円の直径dから、次式(3)により異形度を求めた。異形度は、10サンプルの平均値から求めた。ここで言う外接円とは、単繊維の横断面を内部に含む最小の円のことを意味し、また、ここで言う内接円とは、単繊維の横断面(中空糸の場合は、中空部も単繊維の横断面に含める)の内部に含まれる最大の円のことを意味する。
(5) Deformity:
The ends of the different color mixed polyamide crimped yarns wrapped with rayon staples are passed through a hole (hole diameter: 1.0 mm) in a stainless steel preparation with a thickness of 0.5 mm and parallel along both sides of the preparation with a safety razor. A sample cut into a cross section was used as a sample for cross-sectional observation. This sample was observed at 500 times using a digital microscope “VHX-500” manufactured by KEYENCE, and from the diameter D of the circumscribed circle of the cross section of the single fiber and the diameter d of the inscribed circle of the cross section of the single fiber. The degree of irregularity was determined by the following equation (3). The degree of profile was determined from the average value of 10 samples. The circumscribed circle here means the smallest circle including the cross section of the single fiber inside, and the inscribed circle here means the cross section of the single fiber (in the case of hollow fiber, it is hollow. Part is also included in the cross section of the single fiber).
異色混繊ポリアミド捲縮糸の互いに異色性を示すポリアミド捲縮糸のそれぞれで異形度が異なる場合は、それぞれについて、10サンプルの平均値から異形度を算出した。
・異形度=D/d ・・・・・式(3)。
In the case where the different degrees of irregularity of the differently-colored mixed polyamide crimped yarns showing different colorities from each other, the degree of irregularity was calculated from the average value of 10 samples.
Deformation degree = D / d Equation (3).
(6)中空率:
レーヨンステープルで包んだ異色混繊ポリアミド捲縮糸の糸端を、厚さ0.5mmのステンレス製プレパラートに設けた穴(穴径1.0mm)に通し、安全カミソリでプレパラートの両面に沿って平行にカットしたものを断面観察用の試料とした。この試料をKEYENCE社製デジタルマイクロスコープ「VHX−500」を用いて500倍で観察し、面積計測機能により、中空部を含む繊維の断面積Sと中空部の面積sから次式(4)により中空率を求めた。中空率は、10サンプルの平均値から求めた。
・中空率=(s/S)×100(%) ・・・・・式(4)
(7)撚係数:
異色混繊ポリアミド捲縮糸、または衣料用織編物から分解し得た異色混繊ポリアミド捲縮糸を、解撚機によって算出した1m当たりの撚数Tと、上記(1)の総繊度Dから、次式(1)により撚係数Kを求めた。撚係数は、10サンプルの平均値から求めた。
・撚係数K=T×D1/2 ・・・・・式(1)
T=糸長1m当たりの撚数
D=糸条の総繊度(デシテックス)。
(6) Hollow ratio:
The ends of the different color mixed polyamide crimped yarns wrapped with rayon staples are passed through a hole (hole diameter: 1.0 mm) in a stainless steel preparation with a thickness of 0.5 mm and parallel along both sides of the preparation with a safety razor. A sample cut into two was used as a sample for cross-sectional observation. This sample was observed 500 times using a digital microscope “VHX-500” manufactured by KEYENCE, and the area measurement function was used to calculate the cross-sectional area S of the fiber including the hollow part and the area s of the hollow part according to the following formula (4). The hollow ratio was determined. The hollow ratio was determined from the average value of 10 samples.
・ Hollow rate = (s / S) × 100 (%) Expression (4)
(7) Twist factor:
The different color mixed polyamide crimped yarn or the different color mixed polyamide crimped yarn that can be decomposed from the woven or knitted fabric for clothing is calculated from the number T of twists per meter calculated by the untwisting machine and the total fineness D of (1) above. The twist coefficient K was determined by the following formula (1). The twist coefficient was determined from the average value of 10 samples.
-Twist factor K = T x D 1/2 Formula (1)
T = Number of twists per 1 m of yarn length D = Total fineness of yarn (decitex).
(8)捲縮率:
JIS L1096(2010)に規定される糸の織縮み率B法の方法に準じて測定し、初荷重は0.002cN/デシテックスとし、定荷重は0.11cN/デシテックスとして次式(5)より求めた数値を捲縮率とした。捲縮率を、20cmの3サンプルの平均値から求めた。
・捲縮率(%)=(定荷重時の長さ−初荷重時の長さ)/(初荷重時の長さ)×100 ・・・・式(5)
(9)異形度の変動係数(CV):
サンプル数を全単繊維とすること以外は、上記の(5)項の異形度測定方法に順じて測定を行い、得られた全単繊維の異形度の標準偏差σと平均値μから、次式(6)により変動係数(CV)を求めた。異色混繊ポリアミド捲縮糸の互いに異色性を示すポリアミド捲縮糸の異形度が異なる場合は、それぞれの全単繊維をサンプル数として求めた。
・CV=(σ/μ)×100(%) ・・・・・式(6)
(10)ボリューム感:
ボリューム感は、5人の風合い判定者で次の官能判定を行い、○を合格とした。
○:しっかりとしたボリューム感
△:ボリューム感が不足し不十分
×:ボリューム感なく不良。
(8) Crimp rate:
Measured according to the method of yarn weaving rate B defined in JIS L1096 (2010), the initial load is 0.002 cN / dtex, and the constant load is 0.11 cN / dtex, obtained from the following equation (5). The numerical value obtained was used as the crimp rate. The crimp rate was determined from the average value of 3 samples of 20 cm.
-Crimp rate (%) = (Length at constant load-Length at initial load) / (Length at initial load) x 100 (5)
(9) Variability coefficient of variation (CV):
Except that the number of samples is all monofilaments, measurement is performed in accordance with the method for measuring the degree of deformity in the above item (5), and from the standard deviation σ and average value μ of the degree of deformity of the obtained all single fibers, The coefficient of variation (CV) was determined by the following equation (6). When the deformed degrees of the differently colored mixed polyamide crimped yarns differing from each other in the degree of deformation of the polyamide crimped yarns showing different colors, the total number of single fibers was determined as the number of samples.
CV = (σ / μ) × 100 (%) (6)
(10) Volume feeling:
As for the volume feeling, the following sensory judgments were made by five texture judgment persons, and ○ was accepted.
○: Solid volume feeling Δ: Volume feeling is insufficient and insufficient ×: Defect without volume feeling
(11)ハリコシ感:
ハリコシ感の風合いは、5人の風合い判定者で次の官能判定を行い、○を合格とした。
○:適度なハリコシ感があり良好
△:ハリコシ感が不足し不十分
×:ハリコシ感なく、または有り過ぎて不良。
(11) Harshness:
As for the texture of the harshness, the following sensory determinations were made by five texture determiners, and ○ was accepted.
◯: Appropriate harshness and good △: Harshness is insufficient and insufficient ×: No harshness or too much, poor.
(12)自然な杢調外観品位:
杢調の外観品位は、生地検反機上で次の目視判定を行い、○を合格とした。
○:自然な杢調外観
△:杢感が不十分
×:杢感がなく不良。
(12) Natural tone appearance quality:
As for the appearance quality of tone, the following visual judgment was made on a fabric inspection machine, and ○ was accepted.
○: Natural tone appearance Δ: Inadequate feeling of dullness ×: Inferiority without feeling of dullness
(13)目付:
JIS L1096(2010)に規定される標準状態における単位面積当たりの質量A法の方法を用いて、目付を測定した。
(13) Weight per unit:
The basis weight was measured using the mass A method per unit area in the standard state defined in JIS L1096 (2010).
(14)厚み:
JIS L1096(2010)に規定される厚さA法の方法を用いて、厚みを測定した。
(14) Thickness:
The thickness was measured using the method of the thickness A method defined in JIS L1096 (2010).
(15)軽量性:
JIS L1096(2010)に規定されるかさ高性の方法を用い、測定した数値を軽量性とした。
(15) Lightweight:
Using the bulkiness method defined in JIS L1096 (2010), the measured numerical value was defined as lightweight.
(16)保温性:
JISL1096(2010)に規定される保温率A法によって求めた数値を、保温性(%)とした。
(16) Thermal insulation:
The value obtained by the heat retention rate A method defined in JISL1096 (2010) was defined as heat retention (%).
(17)生産性・工程通過性:
織編物の生機生産性と工程通過性において、糸切れと毛羽立ちなどの発生有無から判定し、○を合格とした
○:原糸分割、撚糸、整経、製織、および編成がともに良好、生産性も良好
△:原糸分割、撚糸、整経、製織、編成の工程で僅かに毛羽や糸切れの問題あり、生産はやや不良
×:原糸分割、撚糸、整経、製織、編成の工程で毛羽や糸切れが発生し、不良または生産性は不良。
(17) Productivity / processability:
Judging from the occurrence of yarn breakage and fluffing in the raw machine productivity and processability of knitted and knitted fabrics, ○ was passed. ○: Good splitting, twisting, warping, weaving, and knitting are all good, productivity △: There is a slight fluff or yarn breakage problem in the process of splitting, twisting, warping, weaving, and knitting, and production is slightly poor ×: In the process of splitting, twisting, warping, weaving, knitting Fluff and thread breakage occur, resulting in poor or poor productivity.
(実施例1)
硫酸相対粘度が2.8で、酸化チタンを0.13質量%含むナイロン6チップを、エクストルーダー型紡糸機を用いて溶融紡糸した。紡糸温度は250℃で、3葉断面(Y型)用の孔を有する口金を用いて、総繊度が450デシテックスで、フィラメント数が180本、単繊維繊度が2.5デシテックス、異形度が2.15となるように製糸した。紡糸速度は1200m/分で、延伸倍率は2.4倍、延伸温度は195℃で熱延伸した。次いで、得られた延伸糸条を連続して、公知のジェットスタッファーノズルを用いて捲縮を付与した。引き続き、得られた糸条を巻き取ることなく、冷却ロールで冷却した後、0.12cN/dtexの張力をかけてストレッチし、捲縮を潜在化して巻き取り、酸性染料可染のポリアミド捲縮糸を得た。
Example 1
A nylon 6 chip having a relative viscosity of sulfuric acid of 2.8 and 0.13% by mass of titanium oxide was melt-spun using an extruder-type spinning machine. The spinning temperature is 250 ° C., using a die having a hole for a three-leaf cross section (Y type), the total fineness is 450 dtex, the number of filaments is 180, the single fiber fineness is 2.5 dtex, and the deformity is 2 .15 was produced. The spinning speed was 1200 m / min, the stretching ratio was 2.4 times, and the stretching temperature was 195 ° C. Next, the obtained drawn yarn was continuously crimped using a known jet stuffer nozzle. Subsequently, after cooling with a cooling roll without winding up the obtained yarn, it was stretched by applying a tension of 0.12 cN / dtex, and the crimp was made latent and wound up, and the acid-dye-dyed polyamide crimp I got a thread.
別に、硫酸相対粘度が2.8で、酸化チタンを0.13質量%含み、スルホン酸ナトリウムを共重合してなるカチオン染料可染のナイロン6チップを、上記と同様に、3葉断面(Y型)用の孔を有する口金を用いて、総繊度が450デシテックスで、フィラメント数が180本、単繊維繊度が2.5デシテックス、異形度が2.15となるように製糸した。次いで、得られた延伸糸条を連続して、公知のジェットスタッファーノズルを用いて、捲縮を付与した。引き続き、得られた糸条を巻き取ることなく、冷却ロールで冷却した後、0.12cN/dtexの張力をかけてストレッチし、捲縮を潜在化して巻き取り、カチオン染料可染のポリアミド捲縮糸を得た。次いで、上記で得られた酸性染料可染のポリアミド捲縮糸とカチオン染料可染のポリアミド捲縮糸を解じょしながら引き揃え、交絡工程を通し、流体交絡処理による合糸混繊を行い、12個/mの交絡を付与して2600m/分で巻き取った。 Separately, a cationic dye-dyed nylon 6 chip having a relative viscosity of sulfuric acid of 2.8, containing 0.13% by mass of titanium oxide, and copolymerized with sodium sulfonate was treated in the same manner as above with a three-leaf cross section (Y Using a die having holes for molds, yarns were produced so that the total fineness was 450 dtex, the number of filaments was 180, the single fiber fineness was 2.5 dtex, and the deformity was 2.15. Next, the obtained drawn yarn was continuously crimped using a known jet stuffer nozzle. Subsequently, after cooling with a cooling roll without winding up the obtained yarn, it was stretched by applying a tension of 0.12 cN / dtex, and the crimp was made latent and wound up. I got a thread. Next, the acid-dye-dyed polyamide crimped yarn and the cationic dye-dyed polyamide crimped yarn obtained as described above are unwound and aligned, and through a entanglement step, a mixed yarn is mixed by fluid entanglement treatment. A piece / m entangled was applied and wound at 2600 m / min.
このようにして、総繊度が900デシテックスで、フィラメント数が360本、単繊維繊度が2.5デシテックス、異形度が2.15、CVが5.35%で、Y型断面の、互いに異色性を示すポリアミド捲縮糸のフィラメント数範囲が50:50で、沸水処理後の伸長率が9.3%、交絡数が12個/mの異色混繊ポリアミド捲縮糸を得た。得られた異色混繊ポリアミド捲縮糸の単繊維の断面を、図1に示す。 In this way, the total fineness is 900 dtex, the number of filaments is 360, the single fiber fineness is 2.5 dtex, the deformity is 2.15, the CV is 5.35%, and the Y-shaped cross sections are different from each other. A polyamide crimped yarn having a different number of filaments in a range of 50:50, a stretch ratio after boiling water treatment of 9.3%, and a tangle of 12 / m was obtained. The cross section of the single fiber of the obtained different color mixed polyamide crimped yarn is shown in FIG.
次いで、リワインダーを用いて異色混繊ポリアミド捲縮糸を約5kg巻き質量に分割した後、ダブルツイスター機を用いて、S撚り方向に100T/mの実撚りを付与し、撚係数Kが3000の異色混繊ポリアミド捲縮糸を得た。 Next, after splitting the different color mixed polyamide crimped yarn into about 5 kg winding mass using a rewinder, a double twister machine was used to give a real twist of 100 T / m in the S twist direction, and the twist coefficient K was 3000 A different color mixed polyamide crimped yarn was obtained.
得られた異色混繊ポリアミド捲縮糸を用い、経糸に撚数100T/mが付与された異色混繊ポリアミド捲縮糸を用い、緯糸に無撚りの異色混繊ポリアミド捲縮糸を用い、経糸密度が31本/2.54cmで、緯糸密度が35本/2.54cmのオックス組織の衣料用ポリアミド捲縮糸を100質量%用いた織物を製織した。織物を製造する工程での通過性は、良好であった。次いで、得られた生機を織物の通常工程である精練、リラックスおよび乾熱セットの各工程を通した後、酸性染料とカチオン染料を用いて液流染色機で染色した後、乾燥乾熱セットにより仕上げ、異色混繊ポリアミド捲縮糸からなる衣料用織物を得た。 Using the different colored mixed polyamide crimped yarn obtained, using the different colored mixed polyamide crimped yarn with a twist of 100 T / m as the warp, and using the non-twisted different colored mixed polyamide crimped yarn as the weft, the warp A woven fabric using 100% by mass of polyamide crimped yarn for clothing having a density of 31 yarns / 2.54 cm and an weft density of 35 yarns / 2.54 cm was woven. The permeability in the process for producing the woven fabric was good. Next, the obtained raw machine is passed through each process of scouring, relaxing and dry heat setting, which are normal processes for fabrics, and then dyed with a liquid dyeing machine using an acid dye and a cationic dye, and then dried with a dry heat set. A woven fabric for clothing made of finished, different color mixed polyamide crimped yarn was obtained.
得られた衣料用織物から、分解して得られた異色混繊ポリアミド捲縮糸の捲縮率は11.6%であり、得られた織物は、軽量性が3.13で、保温性は20.6%と良好であり、しっかりとしたボリューム感と適度なハリコシ感があり、自然な杢調品位の外観を特徴とする婦人衣料用途、特に上衣類に好適な織物であった。 The crimped rate of the different color mixed polyamide crimped yarn obtained by decomposing from the obtained woven fabric for clothing is 11.6%, and the obtained woven fabric has a lightweight property of 3.13 and a heat retention property of It was a good woven fabric suitable for women's apparel use, especially upper clothing, characterized by a good volume feeling and moderate elasticity, and a natural tone-quality appearance.
(実施例2)
実施例1と同様に、互いに異色性を示すナイロン6ポリマーを用い、実施例1と同様に溶融紡糸した。紡糸温度は250℃で、3葉断面(Y型)中空断面用の孔を有する口金を用いて、総繊度が470デシテックスで、フィラメント数が34本、単繊維繊度が13.8デシテックス、異形度が2.65となるように製糸した。紡糸速度は1200m/分で、延伸倍率は2.4倍、延伸温度は195℃で熱延伸した。次いで、得られた延伸糸条を連続して、公知のジェットスタッファーノズルを用いて捲縮を付与した。引き続き、得られた糸条を巻き取ることなく、冷却ロールで冷却した後、0.12cN/dtexの張力をかけてストレッチし、捲縮を潜在化し、酸性染料可染のポリアミド捲縮糸とカチオン染料可染のポリアミド捲縮糸を、それぞれ得た。
(Example 2)
In the same manner as in Example 1, melt spinning was performed in the same manner as in Example 1 using nylon 6 polymers having different colors. The spinning temperature is 250 ° C., using a die having a hole for a three-leaf cross section (Y type) hollow cross section, the total fineness is 470 dtex, the number of filaments is 34, the single fiber fineness is 13.8 dtex, and the degree of profile Was made to be 2.65. The spinning speed was 1200 m / min, the stretching ratio was 2.4 times, and the stretching temperature was 195 ° C. Next, the obtained drawn yarn was continuously crimped using a known jet stuffer nozzle. Subsequently, after cooling with a cooling roll without winding up the obtained yarn, it was stretched by applying a tension of 0.12 cN / dtex, latently crimped, and an acid dye-dyed polyamide crimped yarn and a cation. Each dye-dyeable polyamide crimped yarn was obtained.
次いで、得られた酸性染料可染のポリアミド捲縮糸とカチオン染料可染のポリアミド捲縮糸を解じょしながら引き揃え、交絡を施し、流体交絡処理による合糸混繊を行い、14個/mの交絡を付与して2600m/分の速度で巻き取った。 Next, the obtained acid dye-dyed polyamide crimped yarn and cationic dye-dyed polyamide crimped yarn are unwound and aligned, entangled, and mixed yarn by fluid entanglement treatment, 14 pieces / m Was wound up at a speed of 2600 m / min.
このようにして、総繊度が940デシテックスで、フィラメント数が68本、単繊維繊度が13.8デシテックス、異形度が2.65、CVが4.16%、中空率が12%のY型断面、互いに異色性を示すポリアミド捲縮糸のフィラメント数範囲が50:50、沸水処理後の伸長率が17.0%、交絡数が14個/mの異色混繊ポリアミド捲縮糸を得た。得られた異色混繊ポリアミド捲縮糸の単繊維の断面を、図2に示す。 In this way, a Y-shaped cross section having a total fineness of 940 dtex, 68 filaments, single fiber fineness of 13.8 dtex, deformity of 2.65, CV of 4.16%, and hollowness of 12% Polyamide crimped yarns having a different number of different colors and a polyamide number crimped yarn having a filament number range of 50:50, an elongation rate after boiling water treatment of 17.0%, and an entanglement number of 14 / m were obtained. The cross section of the single fiber of the obtained different color mixed polyamide crimped yarn is shown in FIG.
次いで、実施例1と同様に、分割した後、S撚り方向に200T/mの実撚りを付与し、撚係数Kが6132の異色混繊ポリアミド捲縮糸を得た。得られた異色混繊ポリアミド捲縮糸を経糸と緯糸に用い、経糸密度が24本/2.54cmで、緯糸密度が35本/2.54cmのオックス組織の異色混繊ポリアミド捲縮糸を100質量%用いた織物を製織した。織物を製造する工程での通過性は、良好であった。 Next, in the same manner as in Example 1, after splitting, an actual twist of 200 T / m was applied in the S twist direction to obtain a different color mixed polyamide crimped yarn having a twist coefficient K of 6132. The obtained different color mixed polyamide crimped yarn was used as a warp and weft, and an odd color mixed polyamide polyamide crimped yarn having an ox structure with a warp density of 24 / 2.54 cm and a weft density of 35 / 2.54 cm was used. The woven fabric used in mass% was woven. The permeability in the process for producing the woven fabric was good.
次いで、得られた生機を実施例1と同様の織物の通常工程で加工し、異色混繊ポリアミド捲縮糸からなる衣料用織物を得た。得られた織物から、分解して得られた衣料ポリアミド捲縮糸の捲縮率は6.8%であり、得られた織物は、軽量性は4.71で、保温性は23.7%と良好であり、しっかりとしたボリューム感と適度なハリコシ感があり、自然な杢調の外観品位で、婦人衣料用途、特に上衣類に好適な織物であった。 Subsequently, the obtained raw machine was processed in the normal process of the same fabric as in Example 1 to obtain a woven fabric for clothing made of different color mixed polyamide crimped yarn. The crimp ratio of the garment polyamide crimped yarn obtained by decomposing from the obtained woven fabric is 6.8%, and the obtained woven fabric has a light weight of 4.71 and a heat retention of 23.7%. It was a good woven fabric suitable for women's apparel use, especially for upper apparel, with a solid volume and moderate elasticity, a natural tone and appearance.
(実施例3)
実施例1で得られた総繊度が450デシテックスで、フィラメント数が180本、単繊維繊度が2.5デシテックス、異形度が2.15、CVが5.35%、Y型断面の酸性染料可染のポリアミド捲縮糸と、実施例2で得られた総繊度が470デシテックスで、フィラメント数が34本、単繊維繊度が13.8デシテックス、異形度が2.65、CVが4.16%、中空率が12%のY型断面のカチオン染料可染のポリアミド捲縮糸を用い、実施例1と同様に解じょしながら引き揃え、交絡を施し、流体交絡処理による合糸混繊を行い、12個/mの交絡を付与して2600m/分で巻き取った。
(Example 3)
The total fineness obtained in Example 1 is 450 dtex, the number of filaments is 180, the single fiber fineness is 2.5 dtex, the deformity is 2.15, the CV is 5.35%, and an acid dye having a Y-shaped cross section is acceptable. Dyed polyamide crimped yarn and the total fineness obtained in Example 2 is 470 dtex, the number of filaments is 34, the single fiber fineness is 13.8 dtex, the degree of deformity is 2.65, and the CV is 4.16%. , Using a polyamide crimped yarn dyed with a cationic dye having a Y-shaped cross section with a hollowness of 12%, unwinding and entanglement in the same manner as in Example 1, entangled, and mixed yarn by fluid entanglement treatment, Twelve pieces / m was entangled and wound up at 2600 m / min.
このようにして、総繊度が920デシテックスで、フィラメント数が214本、互いに異色性を示すポリアミド捲縮糸のフィラメント数範囲が84:16、沸水処理後の伸長率が10.6%、交絡数が12個/mの異色混繊ポリアミド捲縮糸を得た。 In this way, the total fineness is 920 dtex, the number of filaments is 214, the range of the number of filaments of the polyamide crimped yarn showing discoloration is 84:16, the elongation after boiling water treatment is 10.6%, the number of entanglements Of 12 / m 2 was obtained.
無撚りの状態の異色混繊ポリアミド捲縮糸と、アクリル繊維60質量%とレーヨン40質量%からなる毛番2/52の混紡糸を用い、12Gのシングル丸編機を用いて、インレイ組織の衣料用ポリアミド捲縮糸50質量%を用いた編物を編成した。編物を製造する工程での通過性は、良好であった。 Using an uncolored mixed-polyamide crimped yarn in an untwisted state and a blended yarn of hair No. 2/52 consisting of 60% by mass of acrylic fiber and 40% by mass of rayon, using a 12G single circular knitting machine, A knitted fabric using 50% by mass of polyamide crimped yarn for clothing was knitted. The permeability in the process of producing the knitted fabric was good.
次いで、得られた生機を編物の通常工程であるリラックスおよび乾熱セットの各工程を通した後、酸性染料とカチオン染料を用いて液流染色機で染色し、乾燥、乾熱セットし、柔軟剤を付与して仕上げ、異色混繊ポリアミド捲縮糸からなる衣料用編物を得た。 Next, the obtained raw machine is passed through each process of relaxation and dry heat setting, which is a normal process of knitting, and then dyed with a liquid dyeing machine using acid dye and cationic dye, dried and set with dry heat, flexible A knitted fabric for clothing consisting of different color mixed polyamide crimped yarn was obtained.
得られた衣料用編物から、分解して得られた異色混繊ポリアミド捲縮糸の捲縮率は14.7%であり、得られた編物は、軽量性は4.94で保温性は30.7%であり、しっかとしたボリューム感と適度なハリコシ感があり、非常に軽量性も高く、自然な杢調の外観品位で、婦人衣料用途、特に上衣類に好適な編物であった。 The crimped ratio of the different color mixed polyamide crimped yarn obtained by decomposing from the obtained knitted fabric is 14.7%. The obtained knitted fabric has a light weight of 4.94 and a heat retention of 30. The knitted fabric had a solid volume feeling and moderate elasticity, was very light and had a natural tone, and was suitable for use in women's clothing, particularly for upper clothing.
(実施例4)
実施例2で得られた異色混繊ポリアミド捲縮糸を用い、撚係数Kが9198になるようにS撚り方向に300T/mの実撚りを付与した。次いで、得られた異色混繊ポリアミド捲縮糸を経糸に用い、緯糸にはアクリル繊維60質量%とレーヨン40質量%からなる毛番2/52の混紡糸と、総繊度が33デシテックスで10フィラメントのナイロン仮撚加工糸を用い、経糸密度が61本/2.54cmで、緯糸密度が80本/2.54cmの接結綾二重組織の異色混繊ポリアミド捲縮糸を60質量%用いた織物を製織した。織物を製造する工程での通過性は、良好であった。次いで、得られた生機を織物の通常工程である精練、リラックスおよび乾熱セットの各工程を通した後、酸性染料、カチオン染料および直接染料を用いて液流染色機で染色した後、乾燥、乾熱セットにより仕上げ、異色混繊ポリアミド捲縮糸を用いた衣料用織物を得た。
Example 4
Using the different color mixed polyamide crimped yarn obtained in Example 2, an actual twist of 300 T / m was applied in the S twist direction so that the twist coefficient K was 9198. Next, the different color mixed-polyamide crimped yarn obtained was used as a warp, and the weft was a blended yarn of hair No. 2/52 consisting of 60% by mass of acrylic fiber and 40% by mass of rayon, and 10 filaments with a total fineness of 33 dtex. Nylon false twisted yarn was used, and 60% by mass of dissimilar mixed-polyamide crimped yarn having a bonded twill double structure with a warp density of 61 / 2.54 cm and a weft density of 80 / 2.54 cm was used. Woven fabric. The permeability in the process for producing the woven fabric was good. Next, the obtained raw machine is subjected to the steps of scouring, relaxing and dry heat setting, which are normal processes of the fabric, dyed with a liquid dyeing machine using an acid dye, a cationic dye and a direct dye, and then dried. Finished by dry heat setting to obtain a woven fabric for clothing using a different color mixed polyamide crimped yarn.
得られた衣料用織物から、分解して得られた異色混繊ポリアミド捲縮糸の捲縮率は7.1%であり、得られた織物は、軽量性は4.03で保温性は28.2%であり、しっかとしたボリューム感と適度なハリコシ感があり、自然な杢調の外観品位で、婦人衣料用途、特に上衣類に好適な織物であった。 The crimped ratio of the different color mixed polyamide crimped yarn obtained by decomposing from the obtained woven fabric for clothing is 7.1%, and the obtained woven fabric has a light weight of 4.03 and a heat retention of 28. It was a woven fabric suitable for women's apparel use, especially upper clothing, with a solid volume and moderate elasticity, natural tone and appearance.
上記の実施例1〜4で得られた織編物の評価結果を、表1に示す。 Table 1 shows the evaluation results of the woven and knitted fabrics obtained in Examples 1 to 4 above.
(比較例1)
実施例1と同様のナイロン6ポリマーを用い、実施例1と同様にしてそれぞれ溶融紡糸した。紡糸温度は250℃で、3葉断面(Y型)用の孔を有する口金を用いて、総繊度が450デシテックスで、フィラメント数が350本、単繊維繊度が1.29デシテックス、異形度が1.45となるようにそれぞれ製糸したこと以外は、実施例1と同様に延伸、捲縮付与および巻き取りを行い、酸性染料可染のポリアミド捲縮糸とカチオン染料可染のポリアミド捲縮糸をそれぞれ得た。次いで、得られた酸性染料可染のポリアミド捲縮糸とカチオン染料可染のポリアミド捲縮糸を解じょしながら引き揃え、交絡を施し、流体交絡処理による合糸混繊を行い、8個/mの交絡を付与して2600m/分の速度で巻き取った。
(Comparative Example 1)
Using the same nylon 6 polymer as in Example 1, each was melt spun in the same manner as in Example 1. The spinning temperature is 250 ° C., using a die having a hole for a three-leaf cross section (Y type), the total fineness is 450 dtex, the number of filaments is 350, the single fiber fineness is 1.29 dtex, and the deformity is 1 Except that the yarns were each made to be .45, stretching, crimping and winding were carried out in the same manner as in Example 1 to obtain polyamide crimped yarns dyeable with acid dyes and polyamide crimped yarns dyed with cationic dyes. I got each. Next, the obtained acid dyeable polyamide crimped yarn and cationic dyeable polyamide crimped yarn are unwound and aligned, entangled, and mixed yarn by fluid entanglement treatment, 8 pieces / m Was wound up at a speed of 2600 m / min.
このようにして、総繊度が900デシテックスで、フィラメント数が700本、単繊維繊度が1.29デシテックス、異形度が1.45、CVが5.11%、Y型断面で、沸水処理後の伸長率が3.2%、交絡数が8個/mのポリアミド捲縮糸を得た。得られたポリアミド捲縮糸を実施例1と同様に、分割、実撚りを付与した後、実施例1と同様の密度と組織の織物を得た。織物を製造する工程での通過性は、良好であった。次いで、得られた織物を実施例1と同様の工程で仕上げた。得られた織物は、ボリューム感とハリコシ感がなく、満足できるものではなかった。 In this way, the total fineness is 900 dtex, the number of filaments is 700, the single fiber fineness is 1.29 dtex, the deformity is 1.45, the CV is 5.11%, the Y-type cross section, after the boiling water treatment A polyamide crimped yarn having an elongation rate of 3.2% and an entanglement number of 8 / m was obtained. After the obtained polyamide crimped yarn was divided and actually twisted in the same manner as in Example 1, a woven fabric having the same density and structure as in Example 1 was obtained. The permeability in the process for producing the woven fabric was good. Next, the obtained woven fabric was finished in the same process as in Example 1. The obtained woven fabric was not satisfactory because it did not have a sense of volume and elasticity.
(比較例2)
実施例1と同様のナイロン6ポリマーを用い、実施例1と同様にしてそれぞれ溶融紡糸した。紡糸温度は250℃で、3葉断面(Y型)の中空断面用の孔を有する口金を用いて、総繊度が780デシテックスで、フィラメント数が48本、単繊維繊度が16.3デシテックス、異形度が2.65となるようにそれぞれ製糸したこと以外は、実施例1と同様に延伸、捲縮付与および巻き取りを行い、酸性染料可染のポリアミド捲縮糸とカチオン染料可染のポリアミド捲縮糸をそれぞれ得た。次いで、得られた酸性染料可染のポリアミド捲縮糸とカチオン染料可染のポリアミド捲縮糸を解じょしながら引き揃え、交絡を施し、流体交絡処理による合糸混繊を行い、14個/mの交絡を付与して2600m/分の速度で巻き取った。
(Comparative Example 2)
Using the same nylon 6 polymer as in Example 1, each was melt spun in the same manner as in Example 1. The spinning temperature is 250 ° C., using a die having a hollow section with a three-leaf cross section (Y type), the total fineness is 780 dtex, the number of filaments is 48, the single fiber fineness is 16.3 dtex, and an irregular shape Except that each yarn was produced so as to have a degree of 2.65, stretching, crimping and winding were carried out in the same manner as in Example 1, and a polyamide crimped yarn dyed with an acid dye and a polyamide yarn dyed with a cationic dye. Each crimp was obtained. Next, the obtained acid dye-dyed polyamide crimped yarn and cationic dye-dyed polyamide crimped yarn are unwound and aligned, entangled, and mixed yarn by fluid entanglement treatment, 14 pieces / m Was wound up at a speed of 2600 m / min.
このようにして、総繊度が1560デシテックスで、フィラメント数が96本、単繊維繊度が16.3デシテックス、異形度が2.65、CVが4.17%、中空率が12%のY型断面、沸水処理後の伸長率が17%、交絡数が14個/mのポリアミド捲縮糸を得た。 Thus, a Y-shaped cross section with a total fineness of 1560 dtex, 96 filaments, single fiber fineness of 16.3 dtex, deformity of 2.65, CV of 4.17% and hollowness of 12% A polyamide crimped yarn having an elongation rate of 17% after boiling water treatment and an entanglement number of 14 / m was obtained.
次いで、リワインダーを用いてポリアミド捲縮糸を約5kg巻き質量に分割した後、ダブルツイスター機を用いて、S撚り方向に30T/mの実撚りを付与し、撚係数Kが1184のポリアミド捲縮糸を得た。得られたポリアミド捲縮糸を用い、経糸密度が25本/2.54cmで、緯糸密度が30本/2.54cmのオックス組織の織物を製織した。織物を製造する工程での通過性は、製造可能な設備に制約が発生し、通過性自体は問題ないものの生産性は不良であった。次いで、得られた織物を実施例1と同様の工程で仕上げた。 Next, after the polyamide crimped yarn is divided into about 5 kg winding mass using a rewinder, a real twist of 30 T / m is applied in the S twist direction using a double twister, and the polyamide crimp is 1184 with a twist coefficient K of 1184 I got a thread. The polyamide crimped yarn thus obtained was used to weave an ox fabric with a warp density of 25 / 2.54 cm and a weft density of 30 / 2.54 cm. The passability in the process of manufacturing the woven fabric is limited in equipment that can be manufactured, and the passability itself is not a problem, but the productivity is poor. Next, the obtained woven fabric was finished in the same process as in Example 1.
得られた織物は、ボリューム感はあるものの、ハリコシ感が有りすぎ、非常に硬い生地となり、婦人衣料用途、特に上衣類には不適な織物であった。 Although the obtained woven fabric had a sense of volume, it had too much elasticity and became a very hard fabric, which was unsuitable for use in women's clothing, particularly for upper clothing.
(比較例3)
比較例1で得られた総繊度が450デシテックスで、フィラメント数が350本、単繊維繊度が1.29デシテックス、異形度が1.45の酸性染料可染のポリアミド捲縮糸と、実施例2で得られた総繊度が470デシテックスで、フィラメント数が34本、単繊維繊度が13.8デシテックス、異形度が2.65のカチオン染料可染のポリアミド捲縮糸を用い、実施例1と同様に解じょしながら引き揃え、交絡を施し、流体交絡処理による合糸混繊を行い、12個/mの交絡を付与して2600m/分の速度で巻き取った。
(Comparative Example 3)
An acid dye-dyed polyamide crimped yarn having a total fineness of 450 dtex, a filament count of 350, a single fiber fineness of 1.29 dtex, and an irregularity of 1.45 obtained in Comparative Example 1, and Example 2 As in Example 1, using a polyamide crimped yarn dyed with a cationic dye having a total fineness of 470 dtex, a filament number of 34, a single fiber fineness of 13.8 dtex, and an irregularity of 2.65 Then, the fibers were aligned, entangled, mixed with the yarn by fluid entanglement treatment, entangled at 12 pieces / m, and wound at a speed of 2600 m / min.
このようにして、総繊度が920デシテックスで、フィラメント数が384本、互いに異色性を示すポリアミド捲縮糸のフィラメント数範囲が91:9、沸水処理後の伸長率が8.8%、交絡数が12個/mの異色混繊ポリアミド捲縮糸を得た。 In this way, the total fineness is 920 dtex, the number of filaments is 384, the range of the number of polyamide crimped yarns showing different colors is 91: 9, the elongation after boiling water treatment is 8.8%, the number of entanglements Of 12 / m 2 was obtained.
次いで、実施例1と同様に得られた異色混繊ポリアミド捲縮糸を用い、経糸に撚数100T/mが付与された異色混繊ポリアミド捲縮糸を用い、緯糸に無撚りの異色混繊ポリアミド捲縮糸を用いて、経糸密度が31本/2.54cmで、緯糸密度が35本/2.54cmのオックス組織の衣料用ポリアミド捲縮糸を100質量%用いた織物を製織した。織物を製造する工程での通過性は、良好であった。次いで、得られた生機を織物の通常工程である精練、リラックスおよび乾熱セットの各工程を通した後、酸性染料とカチオン染料を用いて液流染色機で染色した後、乾燥、乾熱セットにより仕上げ、異色混繊ポリアミド捲縮糸からなる衣料用織物を得た。 Next, using the different color mixed polyamide crimped yarn obtained in the same manner as in Example 1, using the different color mixed polyamide crimped yarn having a twist number of 100 T / m for the warp, and the untwisted different color mixed fiber for the weft. Using a polyamide crimped yarn, a woven fabric using 100% by mass of a polyamide crimped yarn for clothing having a warp density of 31 yarns / 2.54 cm and a weft density of 35 yarns / 2.54 cm was woven. The permeability in the process for producing the woven fabric was good. Next, the obtained raw machine is passed through the scouring, relaxation, and dry heat set processes, which are normal processes for fabrics, and then dyed with a liquid dyeing machine using an acid dye and a cationic dye, followed by drying and dry heat setting. Thus, a woven fabric for clothing made of different color mixed polyamide crimped yarn was obtained.
得られた織物から、分解して得られた異色混繊ポリアミド捲縮糸の捲縮率は9.4%であり、得られた織物は、軽量性は2.53で保温性は19.2%であり、ボリューム感と適度なハリコシ感は不足し、また、杢調品位の外観も満足するものではなかった。 The crimp ratio of the different color mixed polyamide crimped yarn obtained by decomposition from the obtained woven fabric is 9.4%, and the obtained woven fabric has a light weight of 2.53 and a heat retention of 19.2. Therefore, the volume and moderate tension were insufficient, and the appearance of tone quality was not satisfactory.
(比較例4)
本発明の異色混繊ポリアミド捲縮糸を用いることなく、単繊維の断面形状がY型断面(異形度1.48、CV5.39)の総繊度が167デシテックスで36フィラメントのナイロン仮撚加工糸の双糸を、経糸と緯糸に用いて、比較例3と同様の織物を製織した。織物を製造する工程での通過性は、良好であった。次いで、得られた織物を、実施例1と同様の工程で仕上げた。得られた織物は、ボリューム感とハリコシ感がなく、また、軽量性も2.24と低く、織組織も際立たず不十分であり、満足できるものではなかった。
(Comparative Example 4)
Nylon false twisted yarn of 36 filaments with a total fineness of 167 decitex with a Y-shaped cross section (difference degree 1.48, CV 5.39) without using the different color mixed polyamide crimped yarn of the present invention A woven fabric similar to that of Comparative Example 3 was woven using the two yarns as warp and weft. The permeability in the process for producing the woven fabric was good. Next, the obtained woven fabric was finished in the same process as in Example 1. The obtained woven fabric was not satisfactory because it did not have a sense of volume and elasticity, had a low lightness of 2.24, and the woven structure was inconspicuous and insufficient.
上記の比較例1〜4で得られた織編物の評価結果を、表2に示す。 Table 2 shows the evaluation results of the woven and knitted fabrics obtained in Comparative Examples 1 to 4 above.
Claims (8)
(1)単繊維繊度が1.5デシテックス以上25デシテックス以下であり、
(2)総繊度が400デシテックス以上1500デシテックス以下であり、
(3)構成フィラメント数が50本以上1000本以下であり、
(4)互いに異色性を示すポリアミド捲縮糸のフィラメント数が10:90〜90:10の範囲で混在し、
(5)単繊維断面形状が単繊維断面の中心点から放射状に延びて形成された3葉以上の多葉の形状であり、異形度が1.5以上5.5以下であり、
(6)単繊維断面の異形度の変動係数(CV)%が7.0未満1.0以上であること。 A woven or knitted fabric containing at least 25% by mass of a different color mixed polyamide crimped yarn including a polyamide crimped yarn comprising multifilaments and exhibiting different colors, wherein the different color mixed polyamide crimped yarn has the following requirements (1) to A woven or knitted fabric for clothing, which is a crimped yarn satisfying (6).
(1) The single fiber fineness is 1.5 decitex or more and 25 decitex or less,
(2) The total fineness is not less than 400 dtex and not more than 1500 dtex,
(3) The number of constituent filaments is 50 or more and 1000 or less,
(4) The number of filaments of polyamide crimped yarns exhibiting different colors is mixed in the range of 10:90 to 90:10,
(5) The single fiber cross-sectional shape is a multi-leaf shape of 3 or more leaves formed radially extending from the center point of the single fiber cross-section, and the degree of deformity is 1.5 or more and 5.5 or less,
(6) The coefficient of variation (CV)% of the degree of irregularity of the single fiber cross section is less than 7.0 and 1.0 or more.
・撚係数K=T×D1/2 ・・・・式(1)
T=糸長1m当たりの撚数
D=糸条の総繊度(デシテックス) The actual twist is given to the different color mixed polyamide crimped yarn, and the twist coefficient (K) represented by the following formula (1) is 300 or more and 35,000 or less. The woven or knitted fabric for clothing according to crab.
-Twist factor K = T x D 1/2 ··· Formula (1)
T = number of twists per 1 m of yarn length D = total fineness of yarn (decitex)
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Cited By (1)
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WO2017091159A1 (en) * | 2015-11-25 | 2017-06-01 | Thai Toray Synthetics Co., Ltd. | Combined nylon filament yarn |
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WO2017091159A1 (en) * | 2015-11-25 | 2017-06-01 | Thai Toray Synthetics Co., Ltd. | Combined nylon filament yarn |
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