JP2015134755A5 - - Google Patents
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- Publication number
- JP2015134755A5 JP2015134755A5 JP2014256888A JP2014256888A JP2015134755A5 JP 2015134755 A5 JP2015134755 A5 JP 2015134755A5 JP 2014256888 A JP2014256888 A JP 2014256888A JP 2014256888 A JP2014256888 A JP 2014256888A JP 2015134755 A5 JP2015134755 A5 JP 2015134755A5
- Authority
- JP
- Japan
- Prior art keywords
- mol
- coordination compound
- trichlorosilane
- tertiary amine
- amount
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000001875 compounds Chemical class 0.000 description 5
- ZDHXKXAHOVTTAH-UHFFFAOYSA-N Trichlorosilane Chemical compound Cl[SiH](Cl)Cl ZDHXKXAHOVTTAH-UHFFFAOYSA-N 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- 239000005052 trichlorosilane Substances 0.000 description 2
- 238000007363 ring formation reaction Methods 0.000 description 1
- 230000002194 synthesizing Effects 0.000 description 1
Description
環化反応に用いる配位化合物、ハロシラン化合物、第３級アミンの使用量は、適宜決定すればよく、例えば、上記スキームのようにドデカクロロシクロヘキサシランを合成する際は、トリクロロシラン６モルに対し、典型的には、配位化合物を２モル用いる。配位化合物は、１モル以上であればより好ましく、５０モル程度までの範囲で使用することができる。第３級アミンは、トリクロロシラン１モルに対して、０．５〜４モル用いることが好ましく、同モルとすることが特に好ましい。他のハロシラン化合物を用いる場合も同様である。 The amount of coordination compound, halosilane compound, and tertiary amine used in the cyclization reaction may be appropriately determined. For example, when synthesizing dodecachlorocyclohexasilane as in the above scheme, 6 mol of trichlorosilane is added. In contrast, typically, 2 moles of the coordination compound is used. The coordination compound is more preferably 1 mol or more, and can be used in a range of up to about 50 mol. The tertiary amine is preferably used in an amount of 0.5 to 4 mol, particularly preferably the same mol, per 1 mol of trichlorosilane. The same applies when other halosilane compounds are used.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2014256888A JP6349246B2 (en) | 2013-12-20 | 2014-12-19 | Method for producing neutral complex of cyclic silane and method for producing cyclic hydrogenated silane or cyclic organosilane |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013264515 | 2013-12-20 | ||
| JP2013264515 | 2013-12-20 | ||
| JP2014256888A JP6349246B2 (en) | 2013-12-20 | 2014-12-19 | Method for producing neutral complex of cyclic silane and method for producing cyclic hydrogenated silane or cyclic organosilane |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2015134755A JP2015134755A (en) | 2015-07-27 |
| JP2015134755A5 true JP2015134755A5 (en) | 2015-10-08 |
| JP6349246B2 JP6349246B2 (en) | 2018-06-27 |
Family
ID=53766900
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014256888A Active JP6349246B2 (en) | 2013-12-20 | 2014-12-19 | Method for producing neutral complex of cyclic silane and method for producing cyclic hydrogenated silane or cyclic organosilane |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP6349246B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7055674B2 (en) | 2018-03-15 | 2022-04-18 | 株式会社日本触媒 | Method for Producing Polysilane Composition and Heteroatom-Introduced Polysilane Composition |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6588320B2 (en) * | 2015-11-27 | 2019-10-09 | 株式会社日本触媒 | Cyclic halosilane compound and method for producing the same, and method for producing cyclic silane compound |
| JP7022512B2 (en) * | 2017-03-09 | 2022-02-18 | 株式会社日本触媒 | Cyclohexasilane with low halogen element content |
| TWI783027B (en) | 2017-08-28 | 2022-11-11 | 日商日本觸媒股份有限公司 | Hydrosilane composition |
| TWI775922B (en) | 2017-08-31 | 2022-09-01 | 日商日本觸媒股份有限公司 | Hydrosilane composition |
| CN108739690B (en) * | 2018-05-07 | 2020-12-15 | 威海市世一网业有限公司 | Fishing net with excellent aging resistance |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE69808403T2 (en) * | 1997-08-27 | 2003-07-10 | Dow Corning | Compounds containing tetradecachlorocyclohexasilandianone |
| EP2528864B1 (en) * | 2010-01-28 | 2017-03-29 | Ndsu Research Foundation | Method of producing cyclohexasilane compounds |
| JP2013203601A (en) * | 2012-03-28 | 2013-10-07 | Nippon Shokubai Co Ltd | Method for producing cyclohexasilane |
| JP6346555B2 (en) * | 2013-12-20 | 2018-06-20 | 株式会社日本触媒 | Cyclic halosilane neutral complex |
-
2014
- 2014-12-19 JP JP2014256888A patent/JP6349246B2/en active Active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7055674B2 (en) | 2018-03-15 | 2022-04-18 | 株式会社日本触媒 | Method for Producing Polysilane Composition and Heteroatom-Introduced Polysilane Composition |
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