JP2015134710A5 - - Google Patents
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- JP2015134710A5 JP2015134710A5 JP2014256889A JP2014256889A JP2015134710A5 JP 2015134710 A5 JP2015134710 A5 JP 2015134710A5 JP 2014256889 A JP2014256889 A JP 2014256889A JP 2014256889 A JP2014256889 A JP 2014256889A JP 2015134710 A5 JP2015134710 A5 JP 2015134710A5
- Authority
- JP
- Japan
- Prior art keywords
- mol
- coordination compound
- trichlorosilane
- tertiary amine
- amount
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 150000001875 compounds Chemical class 0.000 description 5
- ZDHXKXAHOVTTAH-UHFFFAOYSA-N Trichlorosilane Chemical compound Cl[SiH](Cl)Cl ZDHXKXAHOVTTAH-UHFFFAOYSA-N 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- 239000005052 trichlorosilane Substances 0.000 description 2
- 238000007363 ring formation reaction Methods 0.000 description 1
- 230000002194 synthesizing Effects 0.000 description 1
Description
環化反応に用いる配位化合物、ハロシラン化合物、第３級アミンの使用量は、適宜決定すればよく、例えば、上記スキームのようにドデカクロロシクロヘキサシランを合成する際は、トリクロロシラン６モルに対し、典型的には、配位化合物を２モル用いる。配位化合物は、１モル以上であればより好ましく、５０モル程度までの範囲で使用することができる。また、第３級アミンは、トリクロロシラン１モルに対して、０．５〜４モル用いることが好ましく、同モルとすることが特に好ましい。他のハロシラン化合物を用いる場合も同様である。 The amount of coordination compound, halosilane compound, and tertiary amine used in the cyclization reaction may be appropriately determined. For example, when synthesizing dodecachlorocyclohexasilane as in the above scheme, 6 mol of trichlorosilane is added. In contrast, typically, 2 moles of the coordination compound is used. The coordination compound is more preferably 1 mol or more, and can be used in a range of up to about 50 mol. Further, the tertiary amine is preferably used in an amount of 0.5 to 4 mol, particularly preferably the same mol, per 1 mol of trichlorosilane. The same applies when other halosilane compounds are used.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2014256889A JP6346555B2 (en) | 2013-12-20 | 2014-12-19 | Cyclic halosilane neutral complex |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013264516 | 2013-12-20 | ||
| JP2013264516 | 2013-12-20 | ||
| JP2014256889A JP6346555B2 (en) | 2013-12-20 | 2014-12-19 | Cyclic halosilane neutral complex |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2015134710A JP2015134710A (en) | 2015-07-27 |
| JP2015134710A5 true JP2015134710A5 (en) | 2015-10-08 |
| JP6346555B2 JP6346555B2 (en) | 2018-06-20 |
Family
ID=53766872
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014256889A Active JP6346555B2 (en) | 2013-12-20 | 2014-12-19 | Cyclic halosilane neutral complex |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP6346555B2 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6349246B2 (en) * | 2013-12-20 | 2018-06-27 | 株式会社日本触媒 | Method for producing neutral complex of cyclic silane and method for producing cyclic hydrogenated silane or cyclic organosilane |
| JP6664917B2 (en) * | 2015-09-28 | 2020-03-13 | 株式会社日本触媒 | Cyclic halosilane compound, method for producing, handling method, and method for producing cyclic silane compound |
| JP6588320B2 (en) * | 2015-11-27 | 2019-10-09 | 株式会社日本触媒 | Cyclic halosilane compound and method for producing the same, and method for producing cyclic silane compound |
| JP7055674B2 (en) * | 2018-03-15 | 2022-04-18 | 株式会社日本触媒 | Method for Producing Polysilane Composition and Heteroatom-Introduced Polysilane Composition |
| US20220153595A1 (en) | 2019-03-29 | 2022-05-19 | The Coretec Group Inc. | Method of preparing cyclosilane |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102008042934A1 (en) * | 2008-10-17 | 2010-04-22 | Wacker Chemie Ag | Process for the preparation of neopentasilanes |
| DE102010062984A1 (en) * | 2010-12-14 | 2012-06-14 | Evonik Degussa Gmbh | Process for the preparation of higher halogen and hydridosilanes |
| JP2013203601A (en) * | 2012-03-28 | 2013-10-07 | Nippon Shokubai Co Ltd | Method for producing cyclohexasilane |
| JP5902572B2 (en) * | 2012-07-04 | 2016-04-13 | 株式会社日本触媒 | Method for producing halogenated cyclic silane compound having silicon-halogen bond or salt thereof |
| JP6343145B2 (en) * | 2012-12-25 | 2018-06-13 | 株式会社日本触媒 | Method for producing cyclohexasilane |
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2014
- 2014-12-19 JP JP2014256889A patent/JP6346555B2/en active Active
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