JP2015105246A - Foamy hair cosmetic - Google Patents
Foamy hair cosmetic Download PDFInfo
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- JP2015105246A JP2015105246A JP2013248249A JP2013248249A JP2015105246A JP 2015105246 A JP2015105246 A JP 2015105246A JP 2013248249 A JP2013248249 A JP 2013248249A JP 2013248249 A JP2013248249 A JP 2013248249A JP 2015105246 A JP2015105246 A JP 2015105246A
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- hair cosmetic
- feeling
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- 239000002537 cosmetic Substances 0.000 title claims abstract description 37
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 150000005690 diesters Chemical class 0.000 claims abstract description 12
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 11
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000004094 surface-active agent Substances 0.000 claims abstract description 9
- 229960003237 betaine Drugs 0.000 claims abstract description 6
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims abstract 2
- 239000000203 mixture Substances 0.000 claims description 15
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 claims description 5
- 239000006260 foam Substances 0.000 abstract description 45
- 238000011282 treatment Methods 0.000 abstract description 21
- 239000003676 hair preparation Substances 0.000 abstract description 15
- -1 laurylamino Chemical group 0.000 abstract description 14
- DYVQFOVKDXUCFA-UHFFFAOYSA-N 1-chlorooctadecane N,N-dimethylmethanamine Chemical compound CN(C)C.CCCCCCCCCCCCCCCCCCCl DYVQFOVKDXUCFA-UHFFFAOYSA-N 0.000 abstract 1
- ZXFQDPHJZVBMJZ-UHFFFAOYSA-N OCC[N+]1(CC([O-])=O)CCN=C1 Chemical compound OCC[N+]1(CC([O-])=O)CCN=C1 ZXFQDPHJZVBMJZ-UHFFFAOYSA-N 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 7
- 238000005187 foaming Methods 0.000 description 7
- 229910052710 silicon Inorganic materials 0.000 description 7
- 239000010703 silicon Substances 0.000 description 7
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 230000001953 sensory effect Effects 0.000 description 5
- 239000000839 emulsion Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 238000013329 compounding Methods 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 241000183666 Nepsera aquatica Species 0.000 description 2
- 239000000443 aerosol Substances 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- QYQADNCHXSEGJT-UHFFFAOYSA-N cyclohexane-1,1-dicarboxylate;hydron Chemical compound OC(=O)C1(C(O)=O)CCCCC1 QYQADNCHXSEGJT-UHFFFAOYSA-N 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 239000008213 purified water Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000008685 targeting Effects 0.000 description 2
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical group OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 1
- ASLICXGLMBICCD-UHFFFAOYSA-N 1-ethyl-4,5-dihydroimidazole Chemical compound CCN1CCN=C1 ASLICXGLMBICCD-UHFFFAOYSA-N 0.000 description 1
- SLQVHWZLWVVHBD-UHFFFAOYSA-N 2-(2-oxotridecylamino)ethanesulfonic acid Chemical class CCCCCCCCCCCC(=O)CNCCS(O)(=O)=O SLQVHWZLWVVHBD-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- 239000004475 Arginine Substances 0.000 description 1
- 241000195940 Bryophyta Species 0.000 description 1
- 206010015535 Euphoric mood Diseases 0.000 description 1
- 206010016322 Feeling abnormal Diseases 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 229920013822 aminosilicone Polymers 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 1
- 239000010495 camellia oil Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 description 1
- ZJDCURJWFBQZMS-UHFFFAOYSA-L disodium;2-[carboxylatomethyl(dodecyl)amino]acetate Chemical compound [Na+].[Na+].CCCCCCCCCCCCN(CC([O-])=O)CC([O-])=O ZJDCURJWFBQZMS-UHFFFAOYSA-L 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 235000011929 mousse Nutrition 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000001331 rosmarinus officinalis leaf Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は泡沫状毛髪化粧料に関し、詳細には、泡の弾力性が高く、垂れ落ちのない適度な泡持ち感を有しながら、毛髪化粧料として適度な消泡速度を両立でき、かつ毛髪に対して高いトリートメント感を付与できるノンガスタイプの泡沫状毛髪化粧料に関する。 The present invention relates to foam-like hair cosmetics, and in particular, has high elasticity of foam, has an appropriate feeling of foam retention without dripping, and can achieve both an appropriate defoaming speed as a hair cosmetic and hair. The present invention relates to a non-gas type foamy hair cosmetic that can give a high treatment feeling.
ヘアケア製品として、ミスト型、乳液型、クリーム型、オイル型、エアゾール型等のさまざまな形態のヘアケア製品が市場に存在するなか、比較的新しいタイプの形態として、ノンガスタイプの泡沫状の製品が挙げられる。従来の泡沫状のヘアケア製品としては、エアゾール型のフォームやムースが主流であったが、環境への配慮や消費者の嗜好の変化などにより、ガスを使わないノンエアゾール型の泡沫状の製品が各社から提案されるようになてきたためである。このような製品は、ノンガスタイプ、またはポンプフォーマー型といわれることもある。 There are various types of hair care products such as mist type, emulsion type, cream type, oil type, aerosol type, etc. as hair care products on the market. As a relatively new type of form, non-gas type foam products are listed. It is done. Conventional foam-type hair care products were mainly aerosol-type foams and mousses, but non-aerosol-type foam-type products that do not use gas due to environmental concerns and changes in consumer preferences. This is because each company has come to propose. Such products are sometimes referred to as non-gas types or pump former types.
このようなノンガスタイプのヘアケア製品のなかでも、アウトバス系製品として、スタイリング剤や寝癖直し等のさまざまな製品が提案されている。例えば、特定のポリオキシエチレン・ポリオキシプロピレンデシルエーテルを含有させることにより、優れた起泡性ときめ細かい泡質を有し、使用感に優れる泡状化粧料（例えば、特許文献１参照。）が挙げられる。しかし、このような毛髪化粧料は、起泡性やクリーミーな泡質において優れるものの、泡持ちや泡弾力の観点からは満足できるものではなく、特に毛髪化粧料を使用するときに髪全体に塗布する前に、垂れ落ちてしまう等の問題がある。また、Ｎ−アシルメチルタウリン塩やラウロイルメチルタウリン塩などの陰イオン性界面活性剤とポリエーテル変性シリコーンと特定の割合で組み合わせることにより、起泡性に優れ、泡のきめが細かくクリーミーな寝癖直し用毛髪化粧料（例えば、特許文献２又は３参照。）や、カチオン界面活性剤や両性界面活性剤とポリオキシエチレンのアルキルエーテルを組み合わせた寝癖を直して整髪する頭髪用化粧料組成物（例えば、特許文献４参照。）などもある。しかし、前者に関しては、刺激性が強いと言われる陰イオン性の活性剤を使用しているため、安全性が懸念される。また、両者とも寝癖直しに適するものの、毛髪へのケア感（トリートメント感）付与という観点では不十分である。その他にも、特定のポリプロピレングリコール又はポリオキシプロピレンエーテルとポリエーテル変性シリコーン又はアミノ変性シリコーンを組み合わせることにより、泡量及び泡質に優れ仕上がりの感触に優れたノンエアゾール型泡状毛髪化粧料（例えば、特許文献５参照。）や、ポリアルキレングリコールと油成分と界面活性剤を組合せた泡状整髪剤組成物（例えば、特許文献６参照。）などがある。しかし、後者はエアゾール型フォーム剤により適するものの、ノンガスタイプのフォーム剤としては、剤の安定性と起泡力が満足できず、両者とも感触等に優れているものの、泡持ち感、泡の弾力性などに関して、満足できないものであった。 Among such non-gas-type hair care products, various products such as styling agents and bedclothes have been proposed as out bath products. For example, by containing a specific polyoxyethylene / polyoxypropylene decyl ether, a foam cosmetic (eg, see Patent Document 1) having excellent foamability and fine foam quality and excellent usability. Can be mentioned. However, although such hair cosmetics are excellent in foaming properties and creamy foam quality, they are not satisfactory from the viewpoint of foam retention and foam elasticity, and are especially applied to the entire hair when using the hair cosmetics. There is a problem such as dripping down. In addition, combining an anionic surfactant such as N-acylmethyltaurine salt or lauroylmethyltaurine salt with polyether-modified silicone at a specific ratio provides excellent foaming properties and a finely textured foam. Hair cosmetics (for example, see Patent Document 2 or 3), and hair cosmetic compositions for correcting hair with a combination of a cationic surfactant or amphoteric surfactant and a polyoxyethylene alkyl ether (for example, hair styling) , See Patent Document 4). However, regarding the former, since an anionic active agent that is said to be highly irritating is used, there is a concern about safety. In addition, both are suitable for rehabilitation, but are insufficient from the viewpoint of giving a feeling of care (treatment feeling) to the hair. In addition, by combining a specific polypropylene glycol or polyoxypropylene ether with a polyether-modified silicone or amino-modified silicone, a non-aerosol-type foamy hair cosmetic that is excellent in foam amount and foam quality and excellent in finish feeling (for example, And Patent Document 5), and a foam-like hair styling composition comprising a polyalkylene glycol, an oil component, and a surfactant (for example, see Patent Document 6). However, the latter is more suitable for aerosol foams, but as non-gas type foams, the stability and foaming power of the agents are not satisfactory, both of which are excellent in touch etc. I was not satisfied with the sex.
そのため、泡の弾力性が高く、垂れ落ちのない適度な泡持ち感を有しながら、毛髪化粧料として適度な消泡速度を両立でき、かつ毛髪に対して高いトリートメント感を付与できる泡沫状毛髪化粧料の開発が強く望まれていた。 Therefore, foam-like hair that has high foam elasticity, has a suitable foam-holding feeling without dripping, and can achieve both a suitable defoaming speed as a hair cosmetic and can impart a high treatment feeling to the hair. The development of cosmetics was strongly desired.
本発明は、泡の弾力性が高く、垂れ落ちのない適度な泡持ち感を有しながら、毛髪化粧料として適度な消泡速度を両立でき、かつ毛髪に対して高いトリートメント感を付与できるノンガスタイプの泡沫状毛髪化粧料を提供することを目的とするものである。 The present invention is a non-gas that has a high elasticity of foam, has an appropriate feeling of foam retention without dripping, and is compatible with an appropriate defoaming speed as a hair cosmetic and can impart a high feeling of treatment to hair. The object is to provide a foamy hair cosmetic of the type.
本発明者は、上記目的を達成するために、鋭意研究を重ねた結果、ノンガスタイプの毛髪化粧料において、特定の界面活性剤から選ばれる１種以上及び水溶性のジエステルのうち少なくとも一方と、ポリエーテル変性シリコーンと、エタノールをそれぞれ特定量で組み合わせることにより上記問題が解決されることを見出した。 As a result of intensive studies to achieve the above object, the present inventor, as a result, in non-gas type hair cosmetics, at least one of at least one selected from a specific surfactant and a water-soluble diester, It has been found that the above problem can be solved by combining polyether-modified silicone and ethanol in specific amounts.
すなわち、本発明の毛髪化粧料は、下記成分（Ａ）及び（Ｂ）のうち少なくとも一方と、下記成分（Ｃ）及び（Ｄ）を含有することを特徴とするノンガスタイプの泡沫状毛髪化粧料である。
（Ａ）ラウリルアミノジ酢酸塩、２−アルキル−Ｎ−カルボキシメチル−Ｎ−ヒドロキシエチルイミダゾリニウムベタイン、及び塩化ステアリルトリメチルアンモニウムから選ばれる１種以上の界面活性剤 ０〜１５質量％
（Ｂ）水溶性ジエステル ０〜５質量％
（Ｃ）ポリエーテル変性シリコーン ０．０１〜１５質量％
（Ｄ）エタノール ２〜２０質量％
That is, the hair cosmetic of the present invention contains at least one of the following components (A) and (B) and the following components (C) and (D), and is a non-gas type foamy hair cosmetic characterized by: It is.
(A) One or more surfactants selected from laurylaminodiacetate, 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, and stearyltrimethylammonium chloride 0-15% by mass
(B) Water-soluble diester 0 to 5% by mass
(C) Polyether-modified silicone 0.01-15% by mass
(D) 2-20% by mass of ethanol
本発明によれば、泡の弾力性が高く、垂れ落ちのない適度な泡持ち感を有しながら、毛髪化粧料として適度な消泡速度を両立でき、かつ毛髪に対して高いトリートメント感を付与できるノンガスタイプの泡沫状毛髪化粧料を提供することができる。 According to the present invention, the foam has high elasticity, has an appropriate foam holding feeling without dripping, and at the same time has an appropriate defoaming speed as a hair cosmetic and imparts a high treatment feeling to the hair. A non-gas type foamy hair cosmetic that can be provided can be provided.
以下、本発明の毛髪化粧料について詳細に説明する。 Hereinafter, the hair cosmetic composition of the present invention will be described in detail.
本発明の泡沫状毛髪化粧料に用いられる（Ａ）成分としての界面活性剤は、両性界面活性剤であるラウリルアミノジ酢酸塩、２−アルキル−Ｎ−カルボキシメチル−Ｎ−ヒドロキシエチルイミダゾリニウムベタイン、カチオン性界面活性剤である塩化ステアリルトリメチルアンモニウムである。これら界面活性剤は市販品を用いることができ、例えば、ラウリルアミノジ酢酸塩としては日油社製のニッサンアノンＬＡ（有効分２７％）など、２−アルキル−Ｎ−カルボキシメチル−Ｎ−ヒドロキシエチルイミダゾリニウムベタインとしては日油社製のニッサンアノンＧＬＭ−Ｒ−ＬＶ（有効分３０％）など、塩化ステアリルトリメチルアンモニウムとしては日油社製のカチオンＡＢ−６００（有効分６３％）などが挙げられる。 The surfactant as the component (A) used in the foamy hair cosmetic of the present invention is an amphoteric surfactant, laurylaminodiacetate, 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium. Betaine is stearyltrimethylammonium chloride which is a cationic surfactant. Commercially available products can be used as these surfactants. For example, 2-alkyl-N-carboxymethyl-N-hydroxy such as Nissan Anon LA (effective fraction 27%) manufactured by NOF Corporation as laurylaminodiacetate. Examples of ethyl imidazolinium betaine include NISSAN ANON GLM-R-LV (effective amount 30%) manufactured by NOF Corporation, and examples of stearyltrimethylammonium chloride include cation AB-600 (effective content 63%) manufactured by NOF Corporation. Can be mentioned.
本発明の泡沫状毛髪化粧料においては、上記成分（Ａ）の界面活性剤から適宜選択して１種単独又は２種以上を組み合わせて配合し、その配合量は、泡沫状毛髪化粧料全体に対し、有効分として０〜１５質量％の範囲であるが、好ましくは０．０１質量％以上、より好ましくは０．１〜５質量％である。成分（Ａ）が０質量％の場合は成分（Ｂ）を配合することが必要である。１５質量％を越える配合量では、泡沫状の毛髪化粧料とするには感触等の観点から適さなくなる場合があるだけでなく、ポンプフォーマー容器の使用が難しくなる場合がある。 In the foamy hair cosmetic composition of the present invention, the surfactant of the component (A) is appropriately selected and blended alone or in combination of two or more, and the blending amount is the whole foamy hair cosmetic composition. On the other hand, the effective content is in the range of 0 to 15% by mass, preferably 0.01% by mass or more, and more preferably 0.1 to 5% by mass. When the component (A) is 0% by mass, it is necessary to blend the component (B). If the blending amount exceeds 15% by mass, it may not be suitable for a foamy hair cosmetic from the viewpoint of touch and the like, and it may be difficult to use the pump former container.
本発明の泡沫状毛髪化粧料に用いられる（Ｂ）成分としての水溶性ジエステルは、下記一般式（Ｉ）で示される成分である。このジエステルは、水溶性の性質を示す化合物であり、エトキシジグリコール（詳細にはエチレングリコールモノエチルエーテル）とシクロヘキサンジカルボン酸のジエステルである。このジエステル化合物は既知の製造方法またはそれらの組み合わせにより得られる。例えば、各原料のジカルボン酸またはジカルボン酸無水物とポリオキシエチレンモノアルキルエーテルを、触媒や溶媒または無触媒条件下でのエステル化反応で合成後、未精製または減圧蒸留、水洗、水蒸気脱臭、活性炭処理等の通常の精製方法で精製することにより得られるジエステルが挙げられる。具体的には、１，４−シクロヘキサンジカルボン酸ビス（ジエチレングリコールモノエチルエーテル）エステルである。このようなジエステルは、既に市販されており、購入して利用することができる。例えば、シクロへキサンジカルボン酸ビスエトキシジグリコール［Ｎｅｏｓｏｌｕｅ−Ａｑｕａｌｉｏ、日本精化社製］を挙げることができる。 The water-soluble diester as the component (B) used in the foamed hair cosmetic composition of the present invention is a component represented by the following general formula (I). This diester is a compound exhibiting water-soluble properties, and is a diester of ethoxydiglycol (specifically ethylene glycol monoethyl ether) and cyclohexanedicarboxylic acid. This diester compound is obtained by a known production method or a combination thereof. For example, each raw material dicarboxylic acid or dicarboxylic acid anhydride and polyoxyethylene monoalkyl ether are synthesized by an esterification reaction under a catalyst, solvent or non-catalytic condition, then purified or distilled under reduced pressure, washed with water, steam deodorized, activated carbon The diester obtained by refine | purifying with normal purification methods, such as a process, is mentioned. Specifically, it is 1,4-cyclohexanedicarboxylic acid bis (diethylene glycol monoethyl ether) ester. Such diesters are already commercially available and can be purchased and used. For example, cyclohexanedicarboxylic acid bisethoxydiglycol [Neosol-Aqualio, manufactured by Nippon Seika Co., Ltd.] can be mentioned.
本発明の泡沫状毛髪化粧料において、上記成分（Ｂ）の水溶性ジエステルの配合量は、泡沫状毛髪化粧料全体に対し、有効分として０〜５質量％の範囲である。成分（Ｂ）が０質量％の場合は成分（Ａ）を配合することが必要であるが、その場合の成分（Ａ）の配合量は０．０１質量％以上あれば良い。成分（Ｂ）の配合量が５質量％を越える場合は泡弾力性が低下する場合がある。 In the foamed hair cosmetic of the present invention, the amount of the water-soluble diester of the component (B) is in the range of 0 to 5% by mass as an effective component with respect to the entire foamed hair cosmetic. When the component (B) is 0% by mass, it is necessary to add the component (A). In this case, the amount of the component (A) may be 0.01% by mass or more. When the blending amount of the component (B) exceeds 5% by mass, the foam elasticity may be lowered.
本発明の泡沫状毛髪化粧料に用いられる（Ｃ）成分としてのポリエーテル変性シリコーンは、例えばポリオキシエチレン・メチルポリシロキサン共重合体である。これらポリエーテル変性シリコーンは市販品を用いることができ、例えば、東レ・ダウコーニング社製のシリコンＳＳ−２８０４、シリコンＳＳ−２８０２、シリコンＳＳ−２８０３など、信越化学工業社製のシリコンＫＦ−６０１１などが挙げられる。 The polyether-modified silicone as the component (C) used in the foamed hair cosmetic composition of the present invention is, for example, a polyoxyethylene / methylpolysiloxane copolymer. Commercially available products can be used for these polyether-modified silicones, such as silicon SS-2804, silicon SS-2802, silicon SS-2803 manufactured by Toray Dow Corning, and silicon KF-6011 manufactured by Shin-Etsu Chemical Co., Ltd. Is mentioned.
本発明の泡沫状毛髪化粧料において、（Ｃ）成分としてのポリエーテル変性シリコーンの配合量は、泡沫状毛髪化粧料全体に対し、０．０１〜１５質量％の範囲であるが、好ましくは１〜５質量％である。配合量がこの範囲未満又は超える場合は、毛髪化粧料としての適度な泡弾力、適度な泡持ち感と適度な消泡速度が得られない場合がある。 In the foamed hair cosmetic of the present invention, the amount of the polyether-modified silicone as the component (C) is in the range of 0.01 to 15% by mass with respect to the entire foamed hair cosmetic, but preferably 1 ˜5 mass%. When the blending amount is less than or exceeds this range, a suitable foam elasticity, a suitable foam feeling and a suitable defoaming speed as a hair cosmetic composition may not be obtained.
本発明の泡沫状毛髪化粧料において、（Ｄ）成分としてのエタノールの配合量は、泡沫状毛髪化粧料全体に対し、２〜２０質量％の範囲であるが、好ましくは５〜１５質量％である。配合量がこの範囲未満又は超える場合は、毛髪化粧料としての適度な泡持ち感と適度な消泡速度が得られない場合がある。 In the foamed hair cosmetic of the present invention, the blending amount of ethanol as the component (D) is in the range of 2 to 20% by mass, preferably 5 to 15% by mass with respect to the entire foamed hair cosmetic. is there. When the blending amount is less than or exceeds this range, there may be a case where an appropriate foam feeling and an appropriate defoaming speed as a hair cosmetic composition cannot be obtained.
本発明の泡沫状毛髪化粧料には、上記必須成分の他に、通常用いられる配合剤、例えばその他の界面活性剤、油分、保湿剤、増粘剤、防腐剤、酸化防止剤、キレート剤、ｐＨ調整剤、香料、色素、紫外線吸収・散乱剤、ビタミン類、水等の任意成分を配合することができるが、任意成分はこれらに限定されるものではない。 In addition to the above-mentioned essential components, the foamed hair cosmetic of the present invention includes usually used compounding agents such as other surfactants, oils, moisturizers, thickeners, preservatives, antioxidants, chelating agents, Although arbitrary components, such as a pH adjuster, a fragrance | flavor, a pigment | dye, a ultraviolet absorber, a scattering agent, vitamins, and water, can be mix | blended, arbitrary components are not limited to these.
本発明の泡沫状毛髪化粧料の剤形は特に限定されるものではないが、例えば、透明液状、乳液状、ゲル状等にすることができ、特にヘアトリートメントとして好適なスタイリング
剤等が最適である。また本発明の泡沫状毛髪化粧料は、常法により製造することができる。
The dosage form of the foam hair cosmetic composition of the present invention is not particularly limited. For example, it can be made into a transparent liquid, an emulsion, a gel, etc., and a styling agent suitable as a hair treatment is optimal. is there. Moreover, the foam-like hair cosmetics of this invention can be manufactured by a conventional method.
以下、実施例により本発明を具体的に説明するが、これらの実施例により本発明の技術範囲が限定されるものではない。なお、実施例及び比較例の毛髪化粧料について、泡弾力、適度な泡持ち感（垂れ落ちのなさ）、適度な消泡速度、トリートメント感に関する試験法を下記に示す。 EXAMPLES Hereinafter, although an Example demonstrates this invention concretely, the technical scope of this invention is not limited by these Examples. In addition, about the hair cosmetics of an Example and a comparative example, the test method regarding foam elasticity, moderate foam-holding feeling (no dripping), moderate defoaming speed, and a feeling of treatment is shown below.
（泡弾力性）
実施例及び比較例の毛髪化粧料をポンプフォーマー容器（泡ポンプ）に充填し、テクスチャーアナライザー（Ｓｔｅｖｅｎｓ／Ｍｅｃｈｔｒｉｃ社）を用いて泡弾力を測定した。ポンプフォーマー容器の仕様は、メッシュ内側２００、外側２５５、吐出量０．７ｃｃとし、測定１回毎にｎ＝６点の平均値を求め、さらにこの測定をｎ＝３で平均値を求めた。
(Bubble elasticity)
The hair cosmetics of Examples and Comparative Examples were filled in a pump former container (foam pump), and the foam elasticity was measured using a texture analyzer (Stevens / Metric). The specifications of the pump former container were as follows: mesh inner side 200, outer side 255, discharge amount 0.7 cc. The average value of n = 6 points was obtained for each measurement, and the average value was obtained for this measurement with n = 3. .
判定基準（泡弾力性の程度）
毛髪化粧料の泡をテクスチャーアナライザーを用いた際の泡弾力が、横軸Ｐｏｗｅｒ（ｇ）とした時の数値により、下記基準に従って判定した。
◎：１８０以上
○：１８０未満
△：１６０未満
×：１４０未満
Judgment standard (degree of bubble elasticity)
The foam elasticity when the foam of hair cosmetics was used with a texture analyzer was determined according to the following criteria based on the numerical value when the horizontal axis Power (g) was used.
◎: 180 or more ○: Less than 180 △: Less than 160 ×: Less than 140
適度な泡持ち感（垂れ落ち感のなさ）
５名の専門パネルを対象に、実施例及び比較例の毛髪化粧料を上記ポンプフォーマー型容器から内容液を１プッシュ吐出させて手に取り、泡の状態を約１０秒間観察させた。その時の泡持ち感（垂れ落ちのなさ）について官能試験を行い、下記に示す判定基準により評価を行った。
Moderate bubble feeling (no dripping feeling)
For the five professional panels, the hair cosmetics of the examples and comparative examples were taken out by pushing the content liquid from the pump former type container by one push, and the state of bubbles was observed for about 10 seconds. A sensory test was conducted on the feeling of foaming (no dripping) at that time, and the evaluation was performed according to the following criteria.
判定基準（泡持ち感が良い若しくは適度である（垂れ落ちしない）、または泡持ち感が悪い若しくは適さない（垂れ落ちする））
◎：パネルの４名以上が泡持ち感がよい若しくは適度であると判断
○：パネルの３名が泡持ち感がよい若しくは適度であると判断
△：パネルの２名が泡持ち感がよい若しくは適度であると判断
×：泡持ち感が悪い若しくは適さないと判断したパネルが４名以上
Judgment criteria (feeling of foam is good or moderate (does not sag), or feels bad or unsuitable (sags))
A: Four or more people on the panel judge that the feeling of foaming is good or moderate. ○: Three people on the panel judge that the feeling of foaming is good or moderate. Δ: Two persons on the panel feel good about foaming. Judged to be appropriate ×: 4 or more panels judged to have poor foam feeling or not suitable
（適度な消泡速度）
５名の専門パネルを対象に、実施例及び比較例の毛髪化粧料を上記ポンプフォーマー型容器から内容液を１プッシュ吐出させて手に取り、毛束（長さ１０ｃｍ、重さ１０ｇのバージン毛髪）に塗布した。その時の泡の消泡速度について官能試験を行い、下記に示す判定基準により評価を行った。
(Moderate defoaming speed)
Targeting 5 professional panels, the hair cosmetics of the examples and comparative examples were taken out from the pump former-type container by one push of the content liquid and taken into the hand, and the hair bundle (length 10 cm, weight 10 g virgin) Hair). The sensory test was done about the defoaming speed of the foam at that time, and it evaluated by the criteria shown below.
判定基準（適度な速さで泡が消える、または適度な速さで泡が消えない）
◎：パネルの４名以上が適度な速さで泡が消えると判断
○：パネルの３名が適度な速さで泡が消えると判断
△：パネルの２名が適度な速さで泡が消えると判断
×：適度な速さで泡が消えないと判断したパネルが４名以上
Judgment criteria (foam disappears at moderate speed, or foam does not disappear at moderate speed)
A: Four or more people on the panel judge that the bubbles disappear at a moderate speed. ○: Three people on the panel judge that the bubbles disappear at a moderate speed. Δ: Two people on the panel disappear at a moderate speed. ×: Four or more panel members judged that bubbles did not disappear at a moderate speed
（トリートメント感）
５名の専門パネルを対象に、実施例及び比較例の毛髪化粧料を上記ポンプフォーマー型容
器から内容液を１プッシュ吐出させて手に取り、毛束（長さ１０ｃｍ、重さ１０ｇのバージン毛髪）に塗布し、その時の毛髪へのトリートメント感付与について官能試験を行い、下記に示す判定基準により評価を行った。
(Feeling of treatment)
Targeting 5 professional panels, the hair cosmetics of the examples and comparative examples were taken out from the pump former-type container by one push of the content liquid and taken into the hand, and the hair bundle (length 10 cm, weight 10 g virgin) The hair was then subjected to a sensory test for imparting a feeling of treatment to the hair, and evaluated according to the following criteria.
判定基準（トリートメント感がある、またはトリートメント感がない）
◎：パネルの４名以上がトリートメント感があると判断
○：パネルの３名がトリートメント感があると判断
△：パネルの２名がトリートメント感があると判断
×：トリートメント感がないと判断したパネルが４名以上
Judgment criteria (with or without treatment)
◎: Four or more people on the panel judge that there is a treatment feeling ○: Three people on the panel judge that there is a feeling of treatment △: Two people on the panel judge that there is a feeling of treatment ×: A panel that judges that there is no treatment feeling 4 or more
実施例１〜６及び比較例１〜２（泡沫状ヘアトリートメント）
表１に示す処方の泡沫状ヘアトリートメントを常法により調製し、泡弾力や官能評価で泡持ち感、消泡速度感、トリートメント感について評価を行った。その結果を併せて表１に示す。なお、各成分の配合量は有効分に換算してのものであり、市販品原料そのものの配合量ではない。
Examples 1-6 and Comparative Examples 1-2 (foam-like hair treatment)
Foam-like hair treatments having the formulations shown in Table 1 were prepared by conventional methods, and foam feeling, defoaming speed feeling and treatment feeling were evaluated by foam elasticity and sensory evaluation. The results are also shown in Table 1. In addition, the compounding quantity of each component is a thing converted into an effective part, and is not the compounding quantity of commercially available raw material itself.
表１から明らかなように実施例１〜６の本発明の泡沫状毛髪化粧料は、泡の弾力性が高く、適度な泡持ち感を有しながら、毛髪化粧料として適度な消泡速度を両立でき、垂れ落ちしない、かつ毛髪に対してケア感に優れていた。 As is clear from Table 1, the foamed hair cosmetics of Examples 1 to 6 of the present invention have a high foam elasticity and an appropriate defoaming speed as a hair cosmetic while having an appropriate foam feeling. It was compatible, did not sag, and was excellent in care for hair.
以下、本発明毛髪化粧料のその他の処方例を実施例として挙げる。なお、これらの実施例の毛髪化粧料についても、上記の泡弾力や官能評価で適度な泡持ち感、適度な消泡速度感、トリートメント感について各項目を検討したところ、いずれの実施例においても、優れた特性を有しており良好であった。 Hereinafter, other formulation examples of the hair cosmetic composition of the present invention will be given as examples. In addition, for the hair cosmetics of these examples, each item was examined with respect to the above-mentioned foam elasticity and sensory evaluation for appropriate foam feeling, moderate defoaming speed feeling, and treatment feeling. It had excellent characteristics and was good.
実施例７（泡のヘアトリートメント）
（１）エタノール １０．０
（２）ラウリルアミノジ酢酸Ｎａ １．０
（３）２−アルキル−Ｎ−カルボキシルメチル
−Ｎ−ヒドロキシエチルイミダゾリニウムベタイン ０．５
（４）水溶性ジエステル １．０
（商品名：Ｎｅｏｓｏｌｕｅ−Ａｑｕａｌｉｏ、日本精化社製）
（５）ポリオキシエチレン・メチルポリシロキサン共重合体 ０．１
（商品名：シリコンＳＳ−２８０４、東レ・ダウコーニング社製）
（６）シリコーンエマルション ０．５
（商品名：シリコンＢＹ２２−０８３、東レ・ダウコーニング）
（７）パラメトキシケイ皮酸２−エチルヘキシル ０．０１
（８）アルギニン ０．０１
（９）コメ油 ０．０１
（１０）ツバキ油 ０．０１
（１１）ローズマリー葉エキス ０．１
（１２）香料 ０．０１
（１３）精製水 残 余
Example 7 (foam hair treatment)
(1) Ethanol 10.0
(2) Laurylaminodiacetic acid Na 1.0
(3) 2-alkyl-N-carboxylmethyl-N-hydroxyethylimidazolinium betaine 0.5
(4) Water-soluble diester 1.0
(Product name: Neosolute-Aqualio, manufactured by Nippon Seika Co., Ltd.)
(5) Polyoxyethylene / methylpolysiloxane copolymer 0.1
(Product name: Silicon SS-2804, manufactured by Toray Dow Corning)
(6) Silicone emulsion 0.5
(Product name: Silicon BY22-083, Toray Dow Corning)
(7) 2-Methylhexyl paramethoxycinnamate 0.01
(8) Arginine 0.01
(9) Rice oil 0.01
(10) Camellia oil 0.01
(11) Rosemary leaf extract 0.1
(12) Fragrance 0.01
(13) Residue of purified water
（製法）（１）〜（１３）を均一に混合溶解し、泡のヘアトリートメントを調整した。 (Production method) (1) to (13) were mixed and dissolved uniformly to prepare a hair treatment for foam.
実施例８（泡のスタイリングウォーター）
（１）エタノール ３．０
（２）水溶性ジエステル ０．０１
（商品名：Ｎｅｏｓｏｌｕｅ−Ａｑｕａｌｉｏ、日本精化社製）
（３）ポリオキシエチレン・メチルポリシロキサン共重合体 １．０
（商品名：シリコンＳＳ−２８０２、東レ・ダウコーニング社製）
（４）塩化ステアリルトリメチルアンモニウム １．０
（５）ポリオキシプロピレンジグリセリルエーテル ０．５
（６）アミノシリコーンエラストマーエマルジョン ０．３
（商品名：ＣＥ−７０８０ Ｓｍａｒｔ Ｓｔｙｌｅ、東レ・ダウコーニング社製）（７）パラメトキシケイ皮酸２−エチルヘキシル ０．０１
（８）アルテア根エキス ０．５
（商品名：オーガニックアルテアエキスＢＧ−５０、香栄興業社製）
（９）香料 ０．０１
（１０）精製水 残 余
Example 8 (foam styling water)
(1) Ethanol 3.0
(2) Water-soluble diester 0.01
(Product name: Neosolute-Aqualio, manufactured by Nippon Seika Co., Ltd.)
(3) Polyoxyethylene / methylpolysiloxane copolymer 1.0
(Product name: Silicon SS-2802, manufactured by Toray Dow Corning)
(4) Stearyltrimethylammonium chloride 1.0
(5) Polyoxypropylene diglyceryl ether 0.5
(6) Aminosilicone elastomer emulsion 0.3
(Brand name: CE-7080 Smart Style, manufactured by Toray Dow Corning) (7) 2-Ethylhexyl paramethoxycinnamate 0.01
(8) Altea root extract 0.5
(Product name: Organic Altea Extract BG-50, manufactured by Koei Kogyo Co., Ltd.)
(9) Fragrance 0.01
(10) Purified water residue
（製法）（１）〜（１０）を均一に混合溶解し、容器に充填して泡のスタイリングウォーターを調整した。 (Manufacturing method) (1) to (10) were mixed and dissolved uniformly, and filled in a container to prepare foam styling water.
Claims (2)
（Ａ）ラウリルアミノジ酢酸塩、２−アルキル−Ｎ−カルボキシメチル−Ｎ−ヒドロキシエチルイミダゾリニウムベタイン、及び塩化ステアリルトリメチルアンモニウムから選ばれる１種以上の界面活性剤 ０〜１５質量％
（Ｂ）水溶性ジエステル ０〜５質量％
（Ｃ）ポリエーテル変性シリコーン ０．０１〜１５質量％
（Ｄ）エタノール ２〜２０質量％ A non-gas type foamy hair cosmetic comprising at least one of the following components (A) and (B) and the following components (C) and (D).
(A) One or more surfactants selected from laurylaminodiacetate, 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, and stearyltrimethylammonium chloride 0-15% by mass
(B) Water-soluble diester 0 to 5% by mass
(C) Polyether-modified silicone 0.01-15% by mass
(D) 2-20% by mass of ethanol
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013248249A JP6192165B2 (en) | 2013-11-29 | 2013-11-29 | Foam hair cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013248249A JP6192165B2 (en) | 2013-11-29 | 2013-11-29 | Foam hair cosmetic |
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| JP6192165B2 JP6192165B2 (en) | 2017-09-06 |
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| JP2002104934A (en) * | 2000-07-28 | 2002-04-10 | Kao Corp | Hair cosmetic |
| JP2002256298A (en) * | 2001-03-02 | 2002-09-11 | Kanebo Ltd | Detergent composition |
| JP2003026541A (en) * | 2001-07-10 | 2003-01-29 | Shiseido Co Ltd | Hair cosmetic |
| JP2007217374A (en) * | 2006-02-17 | 2007-08-30 | Kao Corp | Hair cosmetic |
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| JP2012046507A (en) * | 2010-07-30 | 2012-03-08 | Dow Corning Toray Co Ltd | Cosmetic for hair containing co-modified organopolysiloxane |
| JP2012046508A (en) * | 2010-07-30 | 2012-03-08 | Dow Corning Toray Co Ltd | Cosmetic for hair containing sugar alcohol-modified silicone |
| JP2013071924A (en) * | 2011-09-29 | 2013-04-22 | Mikimoto Pharmaceut Co Ltd | Shampoo |
| JP2013151660A (en) * | 2011-12-27 | 2013-08-08 | Dow Corning Toray Co Ltd | Novel liquid organopolysiloxane and use thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2001226233A (en) * | 2000-02-18 | 2001-08-21 | Mandom Corp | Hair cosmetic composition |
| JP2002104934A (en) * | 2000-07-28 | 2002-04-10 | Kao Corp | Hair cosmetic |
| JP2002256298A (en) * | 2001-03-02 | 2002-09-11 | Kanebo Ltd | Detergent composition |
| JP2003026541A (en) * | 2001-07-10 | 2003-01-29 | Shiseido Co Ltd | Hair cosmetic |
| JP2007217374A (en) * | 2006-02-17 | 2007-08-30 | Kao Corp | Hair cosmetic |
| JP2011122011A (en) * | 2009-12-08 | 2011-06-23 | Shiseido Co Ltd | Method for producing foamy detergent and cleaning method |
| JP2012046507A (en) * | 2010-07-30 | 2012-03-08 | Dow Corning Toray Co Ltd | Cosmetic for hair containing co-modified organopolysiloxane |
| JP2012046508A (en) * | 2010-07-30 | 2012-03-08 | Dow Corning Toray Co Ltd | Cosmetic for hair containing sugar alcohol-modified silicone |
| JP2013071924A (en) * | 2011-09-29 | 2013-04-22 | Mikimoto Pharmaceut Co Ltd | Shampoo |
| JP2013151660A (en) * | 2011-12-27 | 2013-08-08 | Dow Corning Toray Co Ltd | Novel liquid organopolysiloxane and use thereof |
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| JP6192165B2 (en) | 2017-09-06 |
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