JP2015054852A - Skin detergent composition - Google Patents
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- JP2015054852A JP2015054852A JP2013190131A JP2013190131A JP2015054852A JP 2015054852 A JP2015054852 A JP 2015054852A JP 2013190131 A JP2013190131 A JP 2013190131A JP 2013190131 A JP2013190131 A JP 2013190131A JP 2015054852 A JP2015054852 A JP 2015054852A
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- 239000003599 detergent Substances 0.000 title abstract description 9
- -1 polyoxyethylene Polymers 0.000 claims abstract description 40
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 21
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 15
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- 229940045920 sodium pyrrolidone carboxylate Drugs 0.000 claims description 9
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- OVRNDRQMDRJTHS-UHFFFAOYSA-N N-acelyl-D-glucosamine Natural products CC(=O)NC1C(O)OC(CO)C(O)C1O OVRNDRQMDRJTHS-UHFFFAOYSA-N 0.000 description 1
- OVRNDRQMDRJTHS-FMDGEEDCSA-N N-acetyl-beta-D-glucosamine Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O OVRNDRQMDRJTHS-FMDGEEDCSA-N 0.000 description 1
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- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
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- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
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- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
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- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 229940010747 sodium hyaluronate Drugs 0.000 description 1
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 description 1
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Abstract
Description
本発明は皮膚洗浄剤組成物に関し、詳しくは、皮膚の洗浄において、アニオン性界面活性剤及び両性界面活性剤を含まないため泡立てる手間なく簡単に使用できる一方で、汚れを効果的に落としながらも肌が本来必要とするうるおい成分を逃さずに洗うことで、角層水分量が上昇し、仕上がりのしっとり感やつっぱり感のなさに優れ、洗浄後に肌の乾燥を生じることなく、しかも保存安定性にも優れた皮膚洗浄剤組成物に関する。 The present invention relates to a skin cleanser composition, and more particularly, in skin cleaning, since it does not contain an anionic surfactant and an amphoteric surfactant, it can be used easily without the need for foaming, while effectively removing dirt. By washing without losing moisture components that are essential to the skin, the moisture content of the stratum corneum is increased, and the finish has a moist and firm feeling without causing dryness of the skin after washing and storage stability. Further, the present invention relates to an excellent skin cleanser composition.
従来、化粧石鹸、ボディソープ、洗顔料などの皮膚洗浄剤にはアニオン性界面活性剤を用いることが一般的である。その理由としては、アニオン性界面活性剤の洗浄力と起泡力が高いことにある。洗浄力が高いことにより、使用時に汚れ落ちが高いと実感し、起泡力が高いことで、使用時に泡立ちが豊かであると実感でき、この２つの要素は皮膚洗浄剤の嗜好性の高さに大きく貢献する。また皮膚洗浄剤にはアニオン性界面活性剤の補助剤として両性界面活性剤を配合することも知られている。洗浄力と起泡力を高く設計することが嗜好性の高さに繋がることから、アニオン性界面活性剤及び両性界面活性剤を併用する方法に関してこれまでに様々な皮膚洗浄剤（例えば、特許文献１〜３を参照。）が提案されている。 Conventionally, anionic surfactants are generally used for skin cleansing agents such as cosmetic soaps, body soaps, and facial cleansers. The reason is that the detergency and foaming power of the anionic surfactant are high. The high detergency makes you feel that dirt has been removed at the time of use, and the high foaming power makes you feel that the foaming is rich at the time of use. Greatly contribute to It is also known that an amphoteric surfactant is added to the skin cleanser as an anionic surfactant adjuvant. Since designing a high detergency and foaming power leads to high palatability, various skin cleansing agents have been developed so far (for example, patent documents) regarding a method of using an anionic surfactant and an amphoteric surfactant together. 1 to 3)) have been proposed.
しかしながら、洗浄力が高いと、肌が本来必要としている脂質や水溶性うるおい成分まで洗い流してしまうことで、洗浄後の肌は水分量が低下し、乾燥するという問題が生じる。また、皮膚刺激を低減する目的で、直接洗浄剤を肌に塗布せず、泡立ててから洗浄することが一般的に行われているが、泡立て行為が面倒であると感じている消費者が多いことも分かっている。多忙な生活に追われる消費者も多いという社会的な背景もあり、より簡単に済ませたいという声も多くなっている。これらのことから一般的な洗浄力が高く、起泡力の高い皮膚洗浄剤は、肌が乾燥するという問題点と、泡立てる行為が面倒であるという問題点を有していた。 However, if the detergency is high, the skin will wash away even the lipids and water-soluble moisture components originally required by the skin, resulting in a problem that the skin after washing has a reduced moisture content and is dried. In addition, for the purpose of reducing skin irritation, it is common practice not to apply a cleansing agent directly to the skin but to lather and then wash, but many consumers feel that lathering is troublesome I know that. There is a social background that there are many consumers who are busy with busy life, and there are many voices that want to make it easier. From these facts, a general skin cleanser having a high detergency and a high foaming power has a problem that the skin dries and a problem that a foaming action is troublesome.
一方、セルロース誘導体やポリオキシエチレンアルキルグルコシドを用いたものとして、乳酸またはその塩、水溶性の皮膜形成性高分子、ポリオキシエチレンメチルグルコシドまたは分子量６００以上のポリエチレングリコールを含有する化粧料（例えば、特許文献４を参照。）が知られている。この化粧料は、乳酸またはその塩本来の保湿性を維持しつつも刺激感が少ないというものである。しかしながら、アニオン性界面活性剤及び両性界面活性剤を含まない皮膚洗浄剤に対し、セルロース誘導体やポリオキシエチレンアルキルグルコシドを用いて、汚れを効果的に落とす一方、肌が本来必要とするうるおい成分を逃さずに洗うというものではなかった。 On the other hand, cosmetics containing cellulose derivative or polyoxyethylene alkyl glucoside, lactic acid or salts thereof, water-soluble film-forming polymer, polyoxyethylene methyl glucoside or polyethylene glycol having a molecular weight of 600 or more (for example, (See Patent Document 4). This cosmetic has less irritation while maintaining the original moisture retention of lactic acid or its salt. However, for skin cleansing agents that do not contain anionic surfactants and amphoteric surfactants, cellulose derivatives and polyoxyethylene alkyl glucosides are used to effectively remove dirt, while moisture components that are essential to the skin are removed. It wasn't about washing without missing.
また、ピロリドンカルボン酸ナトリウムを用いたものとして、脂肪酸石けんと、粘土鉱物であるスメクタイト属のソジウム・モンモリロナイト又はヘクトライトを含有する脂肪酸石けん（例えば、特許文献５を参照。）が知られている。この脂肪酸石けんは、皮膚に対し極めて温和で殆んど無刺激であるが、洗浄力が優れるというものである。しかしながら、アニオン性界面活性剤である脂肪酸石けんに対し、ピロリドンカルボン酸ナトリウムは任意成分として配合されているに過ぎず、汚れを効果的に落とす一方、肌が本来必要とするうるおい成分を逃さずに洗うというものではなかった。 Further, fatty acid soaps containing sodium pyrrolidonecarboxylate and fatty acid soaps containing a clay mineral, smectite genus sodium montmorillonite or hectorite (see, for example, Patent Document 5) are known. This fatty acid soap is extremely mild to the skin and almost non-irritating, but has excellent cleaning power. However, sodium pyrrolidonecarboxylate is only added as an optional component to the fatty acid soap, which is an anionic surfactant, and it effectively removes dirt while not losing moisture components that the skin originally needs. It was not a wash.
本発明は上記背景技術に鑑みなされたものであり、皮膚の洗浄において、アニオン性界面活性剤及び両性界面活性剤を含まないため泡立てる手間なく簡単に使用できる一方で、汚れを効果的に落としながらも肌が本来必要とするうるおい成分を逃さずに洗うことで、角層水分量が上昇し、仕上がりのしっとり感やつっぱり感のなさに優れ、洗浄後に肌の乾燥を生じることなく、しかも保存安定性にも優れた皮膚洗浄剤組成物を得ることを目的とする。 The present invention has been made in view of the above-mentioned background art, and in washing the skin, since it does not contain an anionic surfactant and an amphoteric surfactant, it can be used easily without the need for foaming, while effectively removing dirt. By washing without losing the moisture components that the skin originally needs, the moisture content of the stratum corneum rises, the finish is moist and unsmooth, and the skin does not dry out after washing and is stable in storage. The object is to obtain a skin cleanser composition having excellent properties.
本発明者は上記課題を解決するために鋭意検討を重ねた結果、アニオン性界面活性剤及び両性界面活性剤を含まない皮膚洗浄剤組成物であっても、セルロース誘導体及びポリオキシエチレンメチルグルコシドを配合することにより、効果的に皮膚を洗浄し、なおかつ洗浄後の肌に乾燥を生じることなくうるおいを保持できることを見出し、本発明を完成するに至った。また、ピロリドンカルボン酸ナトリウムを更に配合することにより、連用したときに角層水分量が上昇することも見出した。 As a result of intensive studies to solve the above problems, the present inventor has obtained a cellulose derivative and polyoxyethylene methyl glucoside even in a skin cleanser composition that does not contain an anionic surfactant and an amphoteric surfactant. It has been found that, by blending, the skin can be effectively washed and moisture can be retained without causing dryness in the washed skin, and the present invention has been completed. Further, it has also been found that by further blending sodium pyrrolidonecarboxylate, the stratum corneum moisture content increases when used continuously.
すなわち、本発明はアニオン性界面活性剤及び両性界面活性剤を含まない皮膚洗浄剤組成物であって、下記成分（Ａ）及び（Ｂ）を含有することを特徴とする皮膚洗浄剤組成物である。
（Ａ）セルロース誘導体 ０．０１〜１０質量％
（Ｂ）ポリオキシエチレンアルキルグルコシド ０．００１〜２０質量％
更に、上記皮膚洗浄剤組成物には、成分（Ｃ）ピロリドンカルボン酸ナトリウムを配合することが好ましく、更に成分（Ｄ）非イオン性界面活性剤（但し、成分（Ｂ）を除く。）を１質量％以下含有することが好ましい。
That is, the present invention is a skin cleanser composition that does not contain an anionic surfactant and an amphoteric surfactant, and includes the following components (A) and (B): is there.
(A) Cellulose derivative 0.01 to 10% by mass
(B) Polyoxyethylene alkyl glucoside 0.001-20 mass%
Furthermore, it is preferable to mix | blend component (C) sodium pyrrolidone carboxylate with the said skin cleansing composition, Furthermore, component (D) nonionic surfactant (however, except component (B)) is 1. It is preferable to contain it by mass% or less.
本発明の皮膚洗浄剤組成物によれば、皮膚の洗浄において、アニオン性界面活性剤及び両性界面活性剤を含まないため泡立てる手間なく簡単に使用できる一方で、汚れを効果的に落としながらも肌が本来必要とするうるおい成分を逃さずに洗うことで、角層水分量が上昇し、仕上がりのしっとり感やつっぱり感のなさに優れ、洗浄後に肌の乾燥を生じることなく、しかも保存安定性にも優れる。 According to the skin cleanser composition of the present invention, since it does not contain an anionic surfactant and an amphoteric surfactant, it can be used easily without the need for foaming, while it effectively removes dirt while washing the skin. Washing without missing the moisture components that are essential to the skin, the stratum corneum moisture content is increased, the finish is moist and smooth, and the skin does not dry out after washing, and it also has storage stability. Also excellent.
以下、本発明の構成について説明する。 The configuration of the present invention will be described below.
本発明の皮膚洗浄剤組成物は、泡立てる手間なく簡単に使用できるようにするため、起泡力が高いアニオン性界面活性剤及び両性界面活性剤を含まないものである。ただし、本発明において、成分（Ａ）〜（Ｄ）及び他の任意成分の作用による泡立ち自体を否定するものではない。 The skin cleansing composition of the present invention does not contain an anionic surfactant and an amphoteric surfactant having high foaming power so that they can be used easily without the need for foaming. However, in the present invention, foaming itself due to the action of the components (A) to (D) and other optional components is not denied.
本発明に用いられる成分（Ａ）セルロース誘導体は、通常の皮膚洗浄剤組成物に用いられるものであれば何れでも良いが、好ましいセルロース誘導体の具体例として、メチルセルロース、エチルセルロース、ヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、ヒドロキシプロピルメチルセルロース、カルボキシメチルセルロース、カチオン化セ
ルロース等を挙げることができる。これらのなかで、特に好ましいセルロース誘導体は、メチルセルロース、ヒドロキシエチルセルロース、ヒドロキシプロピルメチルセルロースである。
The component (A) cellulose derivative used in the present invention may be any cellulose derivative as long as it is used in ordinary skin cleansing compositions. Specific examples of preferred cellulose derivatives include methyl cellulose, ethyl cellulose, hydroxyethyl cellulose, and hydroxypropyl cellulose. , Hydroxypropylmethylcellulose, carboxymethylcellulose, cationized cellulose and the like. Among these, particularly preferred cellulose derivatives are methylcellulose, hydroxyethylcellulose, and hydroxypropylmethylcellulose.
本発明の皮膚洗浄剤組成物では、上記セルロース誘導体を、１種単独又は２種以上を組み合わせて用いることができる。セルロース誘導体の配合量は、皮膚洗浄剤組成物全量に対し、０．０１〜１０質量％（以下、単に％と記す。）配合することが必要であり、好ましくは０．１〜３％である。０．０１％未満であると、増粘が不十分なため剤に適度な粘性が出ず使い易さに劣るだけでなく、汚れ落ち感も十分に得られず、また１０％を超えると粘度が高く扱い難く、仕上がりにつっぱり感が生じるからである。 In the skin cleansing composition of the present invention, the above cellulose derivatives can be used singly or in combination of two or more. The blending amount of the cellulose derivative needs to be blended in an amount of 0.01 to 10% by mass (hereinafter simply referred to as%), preferably 0.1 to 3%, based on the total amount of the skin cleanser composition. . If it is less than 0.01%, the agent is not thick enough to give a suitable viscosity and is not easy to use. In addition, a sufficient feeling of soiling cannot be obtained. This is because it is difficult to handle and has a feeling of tension in the finish.
本発明に用いられる成分（Ｂ）ポリオキシエチレンアルキルグルコシドは、通常の皮膚洗浄剤組成物に用いられるものであれば何れでも良いが、汚れ落ち感の観点から、アルキレンオキサイドの平均付加モル数は、好ましくは５〜３０モル、さらに好ましくは１０〜２０モルである。 The component (B) polyoxyethylene alkyl glucoside used in the present invention may be any as long as it is used in a normal skin cleanser composition, but from the viewpoint of the feeling of soiling, the average added mole number of alkylene oxide is , Preferably 5 to 30 mol, more preferably 10 to 20 mol.
上記ポリオキシエチレンアルキルグルコシドの具体例としては、ポリオキシエチレンメチルグルコシド、ポリオキシエチレンプロピレンメチルグルコシド等のポリオキシエチレンメチルグルコシド類、ポリオキシエチレンエチルグルコシド、ポリオキシエチレンプロピレンエチルグルコシド等のポリオキシエチレンエチルグルコシド類、ポリオキシエチレンプロピルグルコシド、ポリオキシエチレンプロピレンプロピルグルコシド等のポリオキシアルキレンプロピルグルコシド類などが挙げられる。これらのなかで、特に好ましいポリオキシエチレンアルキルグルコシドは、保湿性の観点からポリオキシエチレンメチルグルコシドである。 Specific examples of the polyoxyethylene alkyl glucoside include polyoxyethylene methyl glucoside, polyoxyethylene methyl glucoside such as polyoxyethylene propylene methyl glucoside, polyoxyethylene such as polyoxyethylene ethyl glucoside, polyoxyethylene propylene ethyl glucoside Examples thereof include polyoxyalkylene propyl glucosides such as ethyl glucoside, polyoxyethylene propyl glucoside and polyoxyethylene propylene propyl glucoside. Among these, a particularly preferred polyoxyethylene alkyl glucoside is polyoxyethylene methyl glucoside from the viewpoint of moisture retention.
本発明の皮膚洗浄剤組成物では、上記ポリオキシエチレンアルキルグルコシドを、１種単独又は２種以上を組み合わせて用いることができる。ポリオキシエチレンアルキルグルコシドの配合量は、皮膚洗浄剤組成物全量に対し、０．００１％〜２０％配合することが必要であり、好ましくは０．１〜５％である。０．００１％未満では、可溶化力や汚れ落ち感が十分に得られず、また２０％を超えると角質水分量が上昇せず、仕上がりのしっとり感が劣るだけでなくつっぱり感も生じるため肌荒れ改善及び予防効果が得られないからである。 In the skin cleansing composition of the present invention, the polyoxyethylene alkyl glucoside can be used singly or in combination of two or more. The blending amount of the polyoxyethylene alkyl glucoside needs to be 0.001% to 20%, preferably 0.1 to 5%, based on the total amount of the skin cleanser composition. If it is less than 0.001%, sufficient solubilizing power and a feeling of removing stains cannot be obtained, and if it exceeds 20%, the amount of keratin moisture does not increase, and not only the moist feeling of the finish is inferior but also the feeling of tightness is caused, resulting in rough skin. This is because improvement and prevention effects cannot be obtained.
本発明で好ましく用いられる成分（Ｃ）ピロリドンカルボン酸ナトリウムは、通常の皮膚洗浄剤組成物に用いられるものであればよい。本発明におけるピロリドンカルボン酸ナトリウムの配合量は、皮膚洗浄剤組成物全量に対し、好ましくは０．００１〜２０％、さらに好ましくは、１〜５％である。 The component (C) sodium pyrrolidonecarboxylate preferably used in the present invention may be any as long as it is used in ordinary skin cleansing compositions. The amount of sodium pyrrolidonecarboxylate in the present invention is preferably 0.001 to 20%, more preferably 1 to 5%, based on the total amount of the skin cleanser composition.
本発明の皮膚洗浄剤組成物は、使用時の心地よさの演出の目的で油性香料の配合や、油溶性の有効成分を配合することができるが、油性成分を安定に配合するために、成分（Ｄ）非イオン性界面活性剤（但し、成分（Ｂ）を除く。）を配合することができる。非イオン性界面活性剤は通常の皮膚洗浄剤組成物に用いられるものであれば何れでも良いが、油性成分を可溶化させるためには、ＨＬＢ値が７以上のものが好ましく、ＨＬＢ値が１２以上のものが特に好ましい。非イオン性界面活性剤の配合量は、皮膚洗浄剤組成物全量に対し、０．００１〜１％が好ましい。可溶化力を十分に発揮し、保存安定性を良くするには０．００１％以上が好ましく、洗い流した後のべたつき感の観点から１％以下が好ましいからである。 The skin cleanser composition of the present invention can be blended with oily fragrances and oil-soluble active ingredients for the purpose of producing comfort during use, but in order to stably blend oily ingredients, (D) A nonionic surfactant (excluding the component (B)) can be blended. The nonionic surfactant may be any as long as it is used in a normal skin cleansing composition, but in order to solubilize the oil component, those having an HLB value of 7 or more are preferable, and the HLB value is 12 The above is particularly preferable. The blending amount of the nonionic surfactant is preferably 0.001 to 1% with respect to the total amount of the skin cleansing composition. This is because 0.001% or more is preferable for sufficiently exhibiting the solubilizing power and improving the storage stability, and 1% or less is preferable from the viewpoint of stickiness after washing.
本発明の皮膚洗浄剤組成物には、本発明の効果を損なわない限り、上記成分に加えて洗浄剤に一般に配合される任意の成分を含有していてもよい。任意の成分としては、例えば、
プロピレングリコール、グリセリン、ポリエチレングリコール等の保湿成分、脂肪酸エチレングリコール等のパール光沢剤、水溶性高分子化合物（ノニオン性、アニオン性、カチオン性、両性のいずれも含む）、蛋白質誘導体、他の動植物由来の抽出物、防腐剤、ｐＨ調整剤、紫外線吸収剤、酸化防止剤、色素及び香料、油剤、粉体（顔料、色素等）、粘剤、樹脂、溶媒、天然系の植物抽出成分、海藻抽出成分、生薬成分、有効成分、塩類等を適宜配合することができる。
As long as the effects of the present invention are not impaired, the skin cleanser composition of the present invention may contain any component generally blended in the cleanser in addition to the above components. As an optional component, for example,
Moisturizing components such as propylene glycol, glycerin and polyethylene glycol, pearl brighteners such as fatty acid ethylene glycol, water-soluble polymer compounds (including nonionic, anionic, cationic and amphoteric), protein derivatives, other animal and plant origin Extracts, preservatives, pH adjusters, UV absorbers, antioxidants, dyes and fragrances, oils, powders (pigments, dyes, etc.), adhesives, resins, solvents, natural plant extract components, seaweed extraction Ingredients, herbal medicine ingredients, active ingredients, salts and the like can be appropriately blended.
本発明の洗浄剤組成物は、ボディソープ、洗顔料、ハンドソープ等として適用することができる。剤形として具体的には、液状、粘性液状、ジェル状、また透明タイプ、可溶化タイプ、懸濁タイプ等様々な剤型のものに用いることができる。 The cleaning composition of the present invention can be applied as a body soap, a facial cleanser, a hand soap and the like. Specifically, the dosage form can be used in various dosage forms such as liquid, viscous liquid, gel, transparent type, solubilized type, suspension type and the like.
本発明の洗浄剤組成物は、その容器形態を特に限定することなく、一般に用いられるあらゆる容器形態をとることができる。具体的には、ローションボトル式、ポンプ式、チューブ式などが例示される。 The detergent composition of the present invention can take any commonly used container form without any particular limitation on the container form. Specifically, a lotion bottle type, a pump type, a tube type, etc. are illustrated.
以下、本発明の実施例について説明する。なお、本発明は実施例により限定されるものではない。また、配合量は特に指定がない限り、質量％で示す。実施例に先立ち、各実施例で採用した試験法、評価法を説明する。 Examples of the present invention will be described below. The present invention is not limited to the examples. Further, unless otherwise specified, the blending amount is expressed in mass%. Prior to the examples, test methods and evaluation methods employed in each example will be described.
ａ）洗浄後の角層水分量
調製した皮膚洗浄剤を用い、洗浄前後に前腕部の角層水分量を測定した（２５℃湿度５０％の部屋で２０分間馴化）。また、測定値により、次のような基準で評価した。
２・・・優秀 使用後の角層水分量／使用前の角層水分量×１００の値が＋５％以上
１・・・良好 使用後の角層水分量／使用前の角層水分量×１００の値が±５％未満
０・・・普通 使用後の角層水分量／使用前の角層水分量×１００の値が−５％以下
a) The amount of stratum corneum moisture after washing Using the prepared skin cleanser, the amount of stratum corneum moisture in the forearm was measured before and after washing (acclimate for 20 minutes in a room at 25 ° C. and 50% humidity). Moreover, it evaluated on the following references | standards by the measured value.
2 ... Excellent stratum corneum moisture after use / corn stratum moisture before use × 100 + 5% or more 1 ... good stratum corneum moisture after use / corn stratum moisture before use × 100 Value is less than ± 5% 0 ... Normal The stratum corneum moisture after use / the stratum corneum moisture before use × 100 is less than -5%
ｂ）可溶化力試験
試験管に調製した皮膚洗浄剤１０ｇと、皮脂の変わりとしてマカデミアナッツ油０．３ｇを添加し、ボルテックスミキサーで１分間攪拌し、１時間静置後の液体の状態を目視により観察して、下記基準により可溶化性能の評価を行った。
２・・・汚れを落とす機能が十分にある 外観が透明で、分離が認められない
１・・・汚れを落と機能が不足である 外観が濁っている
０・・・汚れを落とすことができない 分離が認められる
b) 10 g of the skin cleansing agent prepared in the test tube and 0.3 g of macadamia nut oil as a change of sebum, stirred for 1 minute with a vortex mixer, and the state of the liquid after standing for 1 hour visually The solubilization performance was evaluated according to the following criteria.
2 ... Has enough function to remove dirt Appearance is transparent and separation is not recognized 1 ... Dirt is removed and function is insufficient Appearance is cloudy 0 ... Cannot remove dirt Separation Is accepted
ｃ）使用感
専門の評価者により、使用試験を実施し、汚れ落ち感、仕上がりのうるおい感、つっぱり感のなさ、を評価した。また、評価の基準を次のように設定した。
３・・・優秀 評価者の９０％以上が良好と回答
２・・・良好 評価者の７０％以上８５％未満が良好と回答
１・・・普通 評価者の５５％以上７０％未満が良好と回答
０・・・不良 評価者の５５％未満が良好と回答
c) A use test was conducted by an evaluator specializing in the feeling of use, and the feeling of soiling, the feeling of moisture in the finish, and the lack of a feeling of tension were evaluated. The evaluation criteria were set as follows.
3 ... Excellent 90% or more of the evaluators answered that it was good 2 ... Good 70% or more of the evaluator answered that it was less than 85% 1 ... Normal 55% or more of the evaluator said that it was good Answer 0: Defect Less than 55% of evaluators answered that it was good
ｄ）保存安定性
試作品を５０℃に１ケ月後の概観の変化を目視にて判定した。
３・・・変化なし
２・・・若干の変化が確認される
１・・・明らかな変化が確認される
d) Storage stability The appearance change of the prototype after 1 month at 50 ° C. was judged visually.
3 ... No change 2 ... Some changes are confirmed 1 ... A clear change is confirmed
表１、２に示す成分で実施例１〜１４及び比較例１〜１０の皮膚洗浄料を常法にて調製し
、上記各試験を実施した。その結果を表１、２に併せて示す。
The skin cleansing materials of Examples 1 to 14 and Comparative Examples 1 to 10 were prepared in the usual manner with the components shown in Tables 1 and 2, and the above tests were performed. The results are also shown in Tables 1 and 2.
表１より明らかなように、本発明の成分を用いた実施例１〜１４の洗浄剤はいずれも優れた性能を示していた。一方、比較例１〜１０の洗浄剤は、洗浄後の角層水分量、使用感（汚れ落ち感、仕上がりのうるおい感、つっぱり感のなさ）及び安定性のいずれかの特性が劣っており、本発明の目的を達成できなかった。 As is clear from Table 1, the cleaning agents of Examples 1 to 14 using the components of the present invention all showed excellent performance. On the other hand, the cleaning agents of Comparative Examples 1 to 10 are inferior in the properties of any of the stratum corneum water content after washing, the feeling of use (feeling of soiling, the moist feeling of the finish, the lack of feeling of grip) and the stability. The object of the present invention could not be achieved.
以下、本発明の皮膚洗浄剤組成物のその他の処方例を実施例１５及び実施例１６として示す。 Hereinafter, other formulation examples of the skin cleansing composition of the present invention are shown as Example 15 and Example 16.
実施例１５（洗顔料）
（％）
・ヒドロキシプロピルメチルセルロース ２．０
・ポリオキシエチレンメチルグルコシド（２０Ｅ．Ｏ．） ５．０
・ピロリドンカルボン酸ナトリウム ３．０
・グリセリン ５．０
・ジプロピレングリコール １．０
・クエン酸 ０．０２５
・クエン酸ナトリウム ０．０４
・アロエエキス １．０
・ヒアルロン酸ナトリウム ０．０１
・パルミチン酸レチノール ０．００５
・フェノキシエタノール ０．２
・香料 適 量
・水 残 部
Example 15 (face wash)
(%)
・ Hydroxypropyl methylcellulose 2.0
Polyoxyethylene methyl glucoside (20E.O.) 5.0
・ Sodium pyrrolidonecarboxylate 3.0
・ Glycerin 5.0
・ Dipropylene glycol 1.0
・ Citric acid 0.025
・ Sodium citrate 0.04
・ Aloe extract 1.0
・ Sodium hyaluronate 0.01
・ Retinol palmitate 0.005
・ Phenoxyethanol 0.2
・ Perfume proper amount ・ Water balance
全成分を７０℃で均一に溶解した後、３０℃まで冷却し洗顔フォームを調製した。角層水分量、使用感、保存安定性を評価したところ、いずれの特性も優れており良好な結果を得た。 All components were uniformly dissolved at 70 ° C., and then cooled to 30 ° C. to prepare a face-washing foam. When the stratum corneum moisture content, feeling of use, and storage stability were evaluated, all of the properties were excellent and good results were obtained.
実施例１６（ボディ用洗浄料）
（％）
・ヒドロキシプロピルメチルセルロース ３．０
・ポリオキシエチレンメチルグルコシド（１０Ｅ．Ｏ．） ５．０
・ピロリドンカルボン酸ナトリウム １．０
・キサンタンガム １．０
・トリ（カプリル・カプリン・ミリスチン・ステアリン酸）グリセリル ２．０
・ジステアリン酸エチレングリコール １．０
・ガンマーアミノ酪酸 １．０
・Ｎ−アセチルグルコサミン １．０
・ポリオキシエチレン硬化ヒマシ油 ０．２
・ローヤルゼリーセキス 適 量
・香料 適 量
・水 残 部
Example 16 (Body cleaning material)
(%)
・ Hydroxypropyl methylcellulose 3.0
Polyoxyethylene methyl glucoside (10E.O.) 5.0
・ Sodium pyrrolidonecarboxylate 1.0
・ Xanthan gum 1.0
・ Tori (capryl, caprin, myristic, stearic acid) glyceryl 2.0
・ Ethylene glycol distearate 1.0
・ Gamma-aminobutyric acid 1.0
・ N-acetylglucosamine 1.0
・ Polyoxyethylene hydrogenated castor oil 0.2
・ Royal jelly squeezed amount / fragrance amount / water balance
全成分を７０℃に加温混合し均一に溶解した後、３０℃まで冷却しボディ用洗浄料を調製した。角層水分量、使用感、保存安定性を評価したところ、いずれの特性も優れており良好な結果を得た。 All components were heated and mixed to 70 ° C. and dissolved uniformly, and then cooled to 30 ° C. to prepare a body cleaning material. When the stratum corneum moisture content, feeling of use, and storage stability were evaluated, all of the properties were excellent and good results were obtained.
Claims (3)
（Ａ）セルロース誘導体 ０．０１〜１０質量％
（Ｂ）ポリオキシエチレンアルキルグルコシド ０．００１〜２０質量％ A skin cleanser composition that does not contain an anionic surfactant and an amphoteric surfactant, the skin cleanser composition comprising the following components (A) and (B):
(A) Cellulose derivative 0.01 to 10% by mass
(B) Polyoxyethylene alkyl glucoside 0.001-20 mass%
（Ｃ）ピロリドンカルボン酸ナトリウム Furthermore, the skin cleanser composition of Claim 1 containing the following component (C).
(C) Sodium pyrrolidonecarboxylate
（Ｄ）非イオン性界面活性剤（但し、成分（Ｂ）を除く。） １質量％以下 Furthermore, the skin cleanser composition of Claim 1 or 2 containing the following component (D).
(D) Nonionic surfactant (however, excluding component (B)) 1% by mass or less
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN114340592A (en) * | 2019-08-26 | 2022-04-12 | 欧莱雅 | Silicone-free low-friction cleaners with high foam properties |
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