JP2014533648A - ゼオライトのイオン交換方法 - Google Patents
ゼオライトのイオン交換方法 Download PDFInfo
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- JP2014533648A JP2014533648A JP2014541780A JP2014541780A JP2014533648A JP 2014533648 A JP2014533648 A JP 2014533648A JP 2014541780 A JP2014541780 A JP 2014541780A JP 2014541780 A JP2014541780 A JP 2014541780A JP 2014533648 A JP2014533648 A JP 2014533648A
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/026—After-treatment
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- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
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- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/085—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
- B01J29/087—X-type faujasite
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- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/085—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
- B01J29/088—Y-type faujasite
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
- B01J29/185—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/50—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952
- B01J29/505—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/60—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
- B01J29/605—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
- B01J29/7053—A-type
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
- B01J29/7065—CHA-type, e.g. Chabazite, LZ-218
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0027—Powdering
- B01J37/0036—Grinding
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/06—Washing
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
- B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/38—Base treatment
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- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Catalysts (AREA)
- Treatment Of Water By Ion Exchange (AREA)
Abstract
Description
前記イオン交換のためには、アルカリ金属又はアルカリ土類金属イオンを含む、天然又は合成の結晶質のゼオライトが好適である。好ましいのは、ナトリウム、カリウム、カルシウム及びマグネシウムイオン、特に好ましいのはナトリウムイオンである。
1質量%未満の量の原子番号58〜71の元素の塩を含んでもよいランタナムの塩水溶液である。
炭酸アンモニウム水溶液中の懸濁したゼオライトは、例えば、ろ過又は遠心分離によって除去され得る。
前記イオン交換後にゼオライトから除去された過剰の炭酸アンモニア溶液は、さらに炭酸ナトリウムを含む。前記ゼオライトが水で洗浄される場合は、この溶液は該水と結合され得る。
前記加熱処理から低沸点で得られた二酸化炭素とアンモニアは、回収のために冷却することによって再結合され得る。それらは、好ましくは水溶液中で再結合される。特に好ましいのは、凝結及び前記液流の冷却による回収であり、前記液流が気体の二酸化炭素及びアンモニアの吸収のために使用されている。
前記方法から放出された前記加熱処理から得られた底部生成物は、炭酸ナトリウム水溶液である。
塊中の純度が99%を超える炭酸アンモニウム(Fisher Chemicals/Fisher Scientific)を、室温で激しく撹拌することによって2kgの蒸留水中に溶解させた。得られた20%の炭酸アンモニウム溶液をその後の実験で使用した。
410gの硝酸アンモニウムを、室温で激しく撹拌することによって2kgの蒸留水に
溶解させた。得られた17%の硝酸アンモニウム溶液をその後の実験で使用した。
Claims (2)
- ナトリウムイオン及び希土類金属イオンを含むゼオライト中のナトリウムイオンをアンモニウムイオンに交換する方法であって、ナトリウムイオン及び希土類イオンを含む前記ゼオライトを水及び炭酸アンモニウムを含む溶液で処理する工程を含むことを特徴とするイオン交換方法。
- 前記ゼオライトの希土類金属イオンの含有量が0.01質量%〜10質量%(REOとして表される)であることを特徴とする請求項1に記載のイオン交換方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201161561294P | 2011-11-18 | 2011-11-18 | |
US61/561,294 | 2011-11-18 | ||
PCT/IB2012/056205 WO2013072808A1 (en) | 2011-11-18 | 2012-11-07 | Process for ion exchange on zeolites |
Publications (1)
Publication Number | Publication Date |
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JP2014533648A true JP2014533648A (ja) | 2014-12-15 |
Family
ID=48427162
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014541780A Pending JP2014533648A (ja) | 2011-11-18 | 2012-11-07 | ゼオライトのイオン交換方法 |
Country Status (8)
Country | Link |
---|---|
US (1) | US9446960B2 (ja) |
EP (1) | EP2780284A4 (ja) |
JP (1) | JP2014533648A (ja) |
KR (1) | KR20140094010A (ja) |
CN (1) | CN103946160B (ja) |
BR (1) | BR112014011305A2 (ja) |
WO (1) | WO2013072808A1 (ja) |
ZA (1) | ZA201404332B (ja) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2903938A1 (en) * | 2013-03-08 | 2014-09-12 | Bp Chemicals Limited | Carbonylation catalyst and process |
CN107708861B (zh) | 2015-06-22 | 2022-01-28 | 艾克瑟路斯股份有限公司 | 改进的催化烷基化、烷基化催化剂和制备烷基化催化剂的方法 |
CN114964976A (zh) * | 2022-08-01 | 2022-08-30 | 北矿检测技术有限公司 | 稀土氧化物标准样品及其制备方法 |
Citations (4)
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US3140252A (en) * | 1961-12-21 | 1964-07-07 | Socony Mobil Oil Co Inc | Hydrocarbon conversion with crystalline acid-metal aluminosilicates |
JPS61278351A (ja) * | 1985-05-31 | 1986-12-09 | ダブリユー・アール・グレイス・アンド・カンパニー−コネチカツト | 接触クラツキング触媒及びその使用法 |
JP2007253038A (ja) * | 2006-03-22 | 2007-10-04 | Petroleum Energy Center | 接触分解触媒及びその製造方法並びに炭化水素油の接触分解方法 |
JP2012061409A (ja) * | 2010-09-15 | 2012-03-29 | Japan Petroleum Energy Center | 接触分解触媒の製造方法 |
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GB0909527D0 (en) * | 2009-06-03 | 2009-07-15 | Univ Manchester | Modified zeolites and their use in the recycling of plastics waste |
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2012
- 2012-11-07 EP EP12849592.6A patent/EP2780284A4/en not_active Withdrawn
- 2012-11-07 JP JP2014541780A patent/JP2014533648A/ja active Pending
- 2012-11-07 WO PCT/IB2012/056205 patent/WO2013072808A1/en active Application Filing
- 2012-11-07 KR KR1020147016481A patent/KR20140094010A/ko not_active Application Discontinuation
- 2012-11-07 CN CN201280056377.8A patent/CN103946160B/zh not_active Expired - Fee Related
- 2012-11-07 BR BR112014011305A patent/BR112014011305A2/pt not_active IP Right Cessation
- 2012-11-16 US US13/679,054 patent/US9446960B2/en not_active Expired - Fee Related
-
2014
- 2014-06-13 ZA ZA2014/04332A patent/ZA201404332B/en unknown
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3140252A (en) * | 1961-12-21 | 1964-07-07 | Socony Mobil Oil Co Inc | Hydrocarbon conversion with crystalline acid-metal aluminosilicates |
JPS61278351A (ja) * | 1985-05-31 | 1986-12-09 | ダブリユー・アール・グレイス・アンド・カンパニー−コネチカツト | 接触クラツキング触媒及びその使用法 |
JP2007253038A (ja) * | 2006-03-22 | 2007-10-04 | Petroleum Energy Center | 接触分解触媒及びその製造方法並びに炭化水素油の接触分解方法 |
JP2012061409A (ja) * | 2010-09-15 | 2012-03-29 | Japan Petroleum Energy Center | 接触分解触媒の製造方法 |
Also Published As
Publication number | Publication date |
---|---|
US9446960B2 (en) | 2016-09-20 |
KR20140094010A (ko) | 2014-07-29 |
CN103946160A (zh) | 2014-07-23 |
WO2013072808A1 (en) | 2013-05-23 |
EP2780284A1 (en) | 2014-09-24 |
ZA201404332B (en) | 2015-08-26 |
BR112014011305A2 (pt) | 2017-05-09 |
EP2780284A4 (en) | 2015-08-26 |
CN103946160B (zh) | 2016-07-13 |
US20130129613A1 (en) | 2013-05-23 |
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