JP2014505774A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2014505774A5 JP2014505774A5 JP2013553835A JP2013553835A JP2014505774A5 JP 2014505774 A5 JP2014505774 A5 JP 2014505774A5 JP 2013553835 A JP2013553835 A JP 2013553835A JP 2013553835 A JP2013553835 A JP 2013553835A JP 2014505774 A5 JP2014505774 A5 JP 2014505774A5
- Authority
- JP
- Japan
- Prior art keywords
- exudates
- phepal
- mpp
- prevented
- impact resistance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 210000000416 Exudates and Transudates Anatomy 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 4
- 239000003063 flame retardant Substances 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 2
- 230000004059 degradation Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 210000001357 hemopoietic progenitor cell Anatomy 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 2
- 229910001593 boehmite Inorganic materials 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- YSRVJVDFHZYRPA-UHFFFAOYSA-N melem Chemical compound NC1=NC(N23)=NC(N)=NC2=NC(N)=NC3=N1 YSRVJVDFHZYRPA-UHFFFAOYSA-N 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
Description
しかし、揮発性が比較的高いホスフィン酸塩の使用の場合の欠点は、射出成形の際に金型付着物が生ずること、湿気が高く暖かい貯蔵条件の際に滲出物が生じること、並びにコンパウンド化の際に放出物が生ずることである。
窒素含有相乗剤またはリン／窒素難燃剤、及び特定の金属化合物（成分Ｃ）を添加することによって、難燃作用を顕著に向上しそしてポリマー分解を防ぐことができる。更に、金型付着物及び滲出物は観察されない。
上記の例から、ＰＨＥＰＡＬ及びＭＰＰもしくはメレム及びホウ酸亜鉛もしくはベーマイトの成分からなる本発明の混合物が、ＰＨＥＰＡＬの単独使用と比べて、向上した防火挙動（２０％の添加でＶ−０が達成される）、良好な加工性（平滑なポリマーストランド）、ポリマー分解無し（高い耐衝撃性及びノッチ付き耐衝撃性）、及び湿気が高く暖かい貯蔵での滲出物無しという効果を示すこことが分かる。ＰＨＥＰＡＬを単独で使用した場合には、３０％の添加量で初めてＵＬ−９４Ｖ−０が達成される（Ｖ−２）。
ＰＡ６．６へ難燃剤としてＰＨＥＰＡＬ及びＭＰＰを配合することは確かにＵＬ９４Ｖ−０を与えるが、滲出物及び粗いポリマーストランド、成形材料の灰色の着色、滲出物及び高いメルトインデックスを招く（Ｂ−１）。ホウ酸亜鉛を加えることによって、灰色の着色を防ぎ、そして滲出物を明らかに減少することができる。
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102011011928.0 | 2011-02-22 | ||
| DE102011011928A DE102011011928A1 (de) | 2011-02-22 | 2011-02-22 | Flammschutzmittel-Stabilisator-Kombination für thermoplastische Polymere |
| PCT/EP2012/000652 WO2012113520A1 (de) | 2011-02-22 | 2012-02-14 | Flammschutzmittel-stabilisator-kombination für thermoplastische polymere |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2014505774A JP2014505774A (ja) | 2014-03-06 |
| JP2014505774A5 true JP2014505774A5 (ja) | 2016-11-10 |
| JP6077465B2 JP6077465B2 (ja) | 2017-02-08 |
Family
ID=45774126
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013553835A Expired - Fee Related JP6077465B2 (ja) | 2011-02-22 | 2012-02-14 | 熱可塑性ポリマー用の難燃剤−安定化剤の組み合わせ |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20140128516A1 (ja) |
| EP (1) | EP2678388B1 (ja) |
| JP (1) | JP6077465B2 (ja) |
| DE (1) | DE102011011928A1 (ja) |
| ES (1) | ES2773374T3 (ja) |
| WO (1) | WO2012113520A1 (ja) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014060004A1 (de) | 2012-10-16 | 2014-04-24 | Wolfgang Wehner | Verfahren zur herstellung von metall-2-hydroxydiphenyl-2' -(thio)phosphinaten und metall-diphenylen-(thio)phosphonaten, diese enthaltende zusammensetzungen sowie deren verwendung als flammschutzmittel |
| US20150028247A1 (en) | 2013-07-23 | 2015-01-29 | Sabic Innovative Plastics Ip B.V. | Rigid foam and associated article and method |
| US9765204B2 (en) | 2013-07-24 | 2017-09-19 | Lanxess Solutions Us Inc. | Halogen free high temperature polyamide compositions comprising phosphorus containing flame retardants |
| US9175160B2 (en) | 2013-08-28 | 2015-11-03 | Sabic Global Technologies B.V. | Blend of poly(phenylene ether) particles and polyoxymethylene, article thereof, and method of preparation |
| US9447227B2 (en) | 2013-10-03 | 2016-09-20 | Sabic Global Technologies B.V. | Flexible polyurethane foam and associated method and article |
| CN107828207B (zh) * | 2016-09-15 | 2020-12-25 | 科莱恩塑料和涂料有限公司 | 用于热塑性聚合物的阻燃剂-稳定剂组合 |
| CN106633082B (zh) * | 2016-12-31 | 2019-08-20 | 华南理工大学 | 一种基于环三磷腈的大分子氮、磷膨胀阻燃剂及其制备方法 |
| JP7021668B2 (ja) * | 2017-06-01 | 2022-02-17 | 日油株式会社 | トリアジンペルオキシド誘導体、該化合物を含有する重合性組成物 |
| WO2021048154A1 (en) | 2019-09-11 | 2021-03-18 | Clariant International Ltd | Metal complexes, manufacturing method thereof, flame-retardant polymer composition comprising the same and their use |
| KR102346106B1 (ko) * | 2019-10-10 | 2022-01-03 | 주식회사 경동원 | 고난연성 유기 변성 실리케이트를 이용한 유무기 복합 합성수지 및 이의 제조방법 |
| CN111849117A (zh) * | 2020-07-17 | 2020-10-30 | 浙江王氏科技有限公司 | 一种阻燃塑料及其加工工艺 |
| CN114032507B (zh) * | 2021-11-22 | 2022-06-24 | 佛山市彩龙镀膜包装材料有限公司 | 一种双面真空镀铝膜工艺 |
| CN114716812B (zh) * | 2022-02-17 | 2023-11-07 | 上海金发科技发展有限公司 | 一种mca阻燃聚酰胺复合材料及其制备方法和应用 |
| CN114874616B (zh) * | 2022-06-10 | 2024-02-02 | 金旸（厦门）新材料科技有限公司 | 一种抗黄变低模垢无卤阻燃聚酰胺复合材料及其制备方法 |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ZA738245B (en) | 1972-10-25 | 1974-09-25 | Hoechst Ag | Flame resistant thermoplastic polyesters |
| DE2447727A1 (de) | 1974-10-07 | 1976-04-08 | Hoechst Ag | Schwerentflammbare polyamidformmassen |
| DE4430932A1 (de) | 1994-08-31 | 1996-03-07 | Hoechst Ag | Flammgeschützte Polyesterformmasse |
| BE1008947A3 (nl) | 1994-12-01 | 1996-10-01 | Dsm Nv | Werkwijze voor de bereiding van condensatieproducten van melamine. |
| MX199755B (es) | 1995-06-28 | 2000-11-24 | Gen Electric | CONTROLADOR DEl NIVEL DE AGUA ADAPTABLE PARAMAQUINA LAVADORA. |
| DE19608006A1 (de) | 1996-03-04 | 1997-09-11 | Hoechst Ag | Salze von phosphonigen Säuren und deren Verwendung als Flammschutzmittel in Kunststoffen |
| DE19614424A1 (de) | 1996-04-12 | 1997-10-16 | Hoechst Ag | Synergistische Flammschutzmittel-Kombination für Polymere |
| TW425391B (en) | 1997-03-04 | 2001-03-11 | Nissan Chemical Ind Ltd | Melamine-melam-melem salt of a polyphosphoric acid and process for its production |
| DE19734437A1 (de) | 1997-08-08 | 1999-02-11 | Clariant Gmbh | Synergistische Flammschutzmittel-Kombination für Polymere |
| DE19737727A1 (de) | 1997-08-29 | 1999-07-08 | Clariant Gmbh | Synergistische Flammschutzmittel-Kombination für Kunststoffe |
| DE19820398A1 (de) * | 1998-05-07 | 1999-11-11 | Basf Ag | Flammgeschützte Polyesterformmassen |
| DE19920276A1 (de) | 1999-05-04 | 2000-11-09 | Basf Ag | Thermoplastische Formmassen |
| DE19933901A1 (de) | 1999-07-22 | 2001-02-01 | Clariant Gmbh | Flammschutzmittel-Kombination |
| JP2001335699A (ja) * | 2000-05-30 | 2001-12-04 | Daicel Chem Ind Ltd | 難燃性樹脂組成物 |
| DE102004023085A1 (de) * | 2004-05-11 | 2005-12-15 | Clariant Gmbh | Dialkylphosphinsäure-Salze, ein Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE102004026799B4 (de) * | 2004-06-02 | 2006-05-18 | Clariant Gmbh | Pressgranulierte Flammschutzmittelzusammensetzung, Verfahren zu deren Herstellung und deren Verwendung |
| KR101259913B1 (ko) | 2004-06-22 | 2013-05-02 | 슈프레스타 엘엘씨 | 열가소성 중합체를 위한 인-함유 난연제 |
| US20060045770A1 (en) | 2004-08-24 | 2006-03-02 | Fei-Tyh Chuang | Piston rod for oil-less air compressor |
| EP1995280B1 (en) * | 2006-03-17 | 2016-08-24 | Mitsubishi Engineering-Plastics Corporation | Flame retardant polyamide resin composition and molding |
| US7829614B2 (en) * | 2008-12-30 | 2010-11-09 | Sabic Innovative Plastics Ip B.V. | Reinforced polyester compositions, methods of manufacture, and articles thereof |
| JP2010248351A (ja) * | 2009-04-14 | 2010-11-04 | Mitsubishi Engineering Plastics Corp | 難燃性熱可塑性ポリエステル樹脂組成物 |
| JP2010270269A (ja) * | 2009-05-25 | 2010-12-02 | Mitsubishi Engineering Plastics Corp | 難燃性ポリアミド系樹脂組成物 |
| DE102010026973A1 (de) * | 2010-07-13 | 2012-01-19 | Clariant International Ltd. | Flammschutzmittel-Stabilisator-Kombination für thermoplastische Polymere |
-
2011
- 2011-02-22 DE DE102011011928A patent/DE102011011928A1/de not_active Withdrawn
-
2012
- 2012-02-14 ES ES12706456T patent/ES2773374T3/es active Active
- 2012-02-14 US US14/000,774 patent/US20140128516A1/en not_active Abandoned
- 2012-02-14 EP EP12706456.6A patent/EP2678388B1/de active Active
- 2012-02-14 WO PCT/EP2012/000652 patent/WO2012113520A1/de active Application Filing
- 2012-02-14 JP JP2013553835A patent/JP6077465B2/ja not_active Expired - Fee Related
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2014505774A5 (ja) | ||
| ATE457331T1 (de) | Flammwidrige polymerzusammensetzungen | |
| CY1123306T1 (el) | Συνθεση ρητινης χυτευσης συμπεριλαμβανοντας χλωριωμενη ρητινη βασει χλωριουχου βινυλιου και χυτευμενο ειδος εξ αυτης | |
| ATE552302T1 (de) | Flammwidrige polyolefinzusammensetzung | |
| JP6077465B2 (ja) | 熱可塑性ポリマー用の難燃剤−安定化剤の組み合わせ | |
| BR112015001170A2 (pt) | composições compreendendo polímeros catiônicos hidrofobicamente modificados | |
| MX363645B (es) | Composiciones para moldear copolimeros de acrilonitrilo estabilizadas contra intemperización. | |
| JP2015528839A5 (ja) | ||
| EA026860B9 (ru) | Способ получения композиции, содержащей гетерофазный пропиленовый сополимер и тальк | |
| WO2013068437A3 (en) | P-n-compounds as flame retardants | |
| BR112013033560A2 (pt) | composição adesiva, fita adesiva e estrutura de adesão | |
| PL2178960T3 (pl) | Dodatek opóźniający palenie niezawierający fluorowców | |
| MY156004A (en) | Heat aging-resistant polyamides with flame retardancy | |
| CY1124716T1 (el) | Συνθεση ρητινης χυτευσης συμπεριλαμβανοντας χλωριωμενη ρητινη βασει χλωριουχου βινυλιου και χυτευμενο ειδος εξ αυτης | |
| TWI455981B (zh) | 防焰ｐｍｍａ模製材料 | |
| DE602008005156D1 (ja) | ||
| MY169167A (en) | Concentrated polymeric compositions of vinyl aromatic polymers and/or vinyl aromatic copolymers | |
| CN104177736A (zh) | 一种阻燃聚氯乙烯电缆料及其加工工艺 | |
| MX340757B (es) | Composición a base de copolímero de bloque estirénico con propiedades pirorretardantes mejoradas. | |
| JP2019515985A5 (ja) | ||
| BR112014026341A2 (pt) | composições de pc/abs com boa estabilidade térmica e química | |
| WO2012065098A3 (en) | Amino terminated phosphonamide oligomers and flame retardant compositions therefrom | |
| JP6094019B2 (ja) | ポリカーボネート樹脂組成物 | |
| NZ590534A (en) | Fire retardant polypropylene | |
| MY198951A (en) | "expandable compositions containing aromatic vinyl polymers having self-extinguishing properties and improved processability" |