JP2014205917A - Ferritic stainless steel sheet excellent in moldability - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a ferritic stainless steel sheet excellent in moldability and satisfying deep drawability and ridging resistance.SOLUTION: There is provided a ferritic stainless steel sheet containing, by mass%, C:0.010 to 0.070%, Si:1.00% or less, Mn:1.00% or less, P:0.040% or less, S:0.010% or less, Al:0.150% or less, Cr:14.00 to 20.00%, Ni:1.00% or less, N:0.010 to 0.060%, further V:0.005 to 0.100% and B:0.0001 to 0.0050% with V/B≥10 satisfied and the balance Fe with inevitable impurities.

Description

  The present invention relates to a ferritic stainless steel sheet suitable for use in building kitchen appliances, household products, electrical appliances, automobile parts, and the like, and particularly, molding that satisfies deep drawability and ridging resistance. The present invention relates to a ferritic stainless steel sheet having excellent workability. In addition, the steel plate in this invention shall include a steel strip, a steel plate, and foil material.

  Ferritic stainless steel is widely used as a material having excellent corrosion resistance in various industrial fields including household goods and automobile parts. This ferritic stainless steel is less expensive than austenitic stainless steel containing a large amount of Ni. However, it is generally inferior in workability. For example, when a molding process is performed, surface defects called ridging are likely to occur, and it is not suitable for applications in which a strong process such as deep drawing is performed. In addition, ferritic stainless steel has a large in-plane anisotropy (Δr) of the plastic strain ratio (r value), and there is also a problem that non-uniform deformation is likely to occur during deep drawing. For this reason, in order to further expand the application of ferritic stainless steel sheets, the r value, which is an index of deep drawability, is improved, the in-plane anisotropy (Δr) of the plastic strain ratio is reduced, and the ridging resistance is also improved. Is required.

In response to such a request, for example, in Patent Document 1, C: 0.03 to 0.08%, Si: 0.4% or less, Mn: 0.5% or less, P: 0.03% or less , S: 0.008 or less, Ni: 0.3% or less, Cr: 15-20%, Al: N × 2 to 0.2% or less, N: 0.01% or less, the balance Fe and unavoidable A ferritic stainless steel having excellent processability composed of impurities is disclosed. In Patent Document 2, Cr: 11.0 to 20.0%, Si: 1.5% or less, Mn: 1.5% or less, C% + N%: 0.02 to 0.06%, Zr: 0 .2 to 0.6%, including Zr in the range of Zr% = 10 (C% + N%) ± 0.15%, the balance being substantially heat-resistant ferritic alloy substantially consisting of Fe Stainless steel is disclosed. In Patent Document 3, mass% is C: 0.02 to 0.06%, Si: 1.0% or less, Mn: 1.0% or less, P: 0.05% or less, S: 0 0.01% or less, Al: 0.005% or less, Ti: 0.005% or less, Cr: 11-30% or less, Ni: 0.7% or less, and N in relation to the C content , 0.06 ≦ (C + N) ≦ 0.12 and 1 ≦ N / C are satisfied, and further, V is 1.5 × 10 ⁻³ ≦ (V × N) in relation to the N content. There is disclosed a ferritic stainless steel sheet excellent in formability, which is contained so as to satisfy ≦ 1.5 × 10 ⁻² and consists of the balance Fe and inevitable impurities. Further, in Patent Document 4, C: 0.02% or less, Si: 1.0% or less, Mn: 2.0% or less, Cr: 11 to 35%, Ni: 0.5% by weight%, A ferritic stainless steel having N: 0.03% or less, V: 0.5-5.0%, the balance, iron and accompanying impurities and having excellent corrosion resistance is disclosed.

JP 52-24913 A Japanese Patent Laid-Open No. 54-112319 Japanese Patent No. 3584881 JP 59-193250 A

However, since the technique described in Patent Literature 1 is premised on low N, there is a problem in that an increase in cost in the steelmaking process cannot be avoided.
Moreover, in the technique described in Patent Document 2, since a large amount of Zr is added, the amount of inclusions in the steel increases, and there is a problem that surface defects due to this increase cannot be avoided.
The technique described in Patent Document 3 aims at improving elongation and r value and improving ridging resistance as an index of moldability. However, no consideration is given to the reduction of the in-plane anisotropy (Δr), and there remains a problem in the moldability.
In the technique described in Patent Document 4, it is said that the addition of V significantly improves the corrosion resistance, particularly the stress corrosion cracking resistance. However, no consideration has been given to moldability, leaving a problem with moldability.
As described above, in the above-described conventional techniques, when strict deep drawing is performed, ridging is generated to increase the polishing load or to solve the problem that non-uniform deformation is likely to occur. Was not reached.

  In view of such circumstances, an object of the present invention is to provide a ferritic stainless steel sheet excellent in formability that satisfies deep drawability and ridging resistance.

As a result of various studies to achieve the above-described problems, the present inventors set V / B to 10 or more, and the contents of V and B are optimal ranges, such as carbides and nitrides in steel. By controlling the precipitate, the crystal grain size can be refined to improve deep drawability, ridging can be suppressed, and a ferritic stainless steel sheet excellent in forming processability can be obtained. As a result of the above, it was found that even when the finish annealing temperature fluctuates in actual operation, it is possible to suppress the sensitization of the steel sheet surface, and the present invention has been completed. The gist of the present invention is as follows.
(1) By mass%, C: 0.010 to 0.070%, Si: 1.00% or less, Mn: 1.00% or less, P: 0.040% or less, S: 0.010% or less, Al: 0.150% or less, Cr: 14.00 to 20.00%, Ni: 1.00% or less, N: 0.010 to 0.060%, and V: 0.005 to 0.000. A ferritic stainless steel sheet containing 100%, B: 0.0001 to 0.0050%, satisfying V / B ≧ 10, with the balance being Fe and inevitable impurities.
(2) The ferritic stainless steel sheet according to (1), wherein Si: 0.05 to 0.28% and Mn: 0.05 to 0.92%.
(3) The ferritic stainless steel sheet according to (1) or (2), wherein V / B ≧ 20 is satisfied.
In the present invention, the ferritic stainless steel sheet excellent in moldability means a ferritic stainless steel sheet satisfying an elongation (El) of 30% or more, an r value of 1.3 or more, and Δr0.3 or less.

  ADVANTAGE OF THE INVENTION According to this invention, the ferritic stainless steel plate excellent in the moldability which satisfies deep drawability and ridging resistance can be obtained.

FIG. 1 is a graph showing the relationship between mechanical properties and V / B of a cold-rolled annealed plate, (a) is a graph showing the relationship between elongation (El) and V / B, and (b) is an r value and V / B. The graph which shows the relationship between / B, (c) is the graph which shows the relationship between (DELTA) r and V / B, (d) is the graph which shows the relationship between ridging height and V / B. FIG. 2 is a graph showing the relationship between the contents of V and B for ensuring the sensitization characteristics of the cold-rolled annealed sheet.

  Hereinafter, embodiments for carrying out the present invention will be described in detail. In addition, unless otherwise indicated,% showing the quantity of a component means the mass%.

  First, the reasons for limiting the components of the ferritic stainless steel sheet according to the present invention will be described.

C: 0.010-0.070%
C forms a solid solution in the steel and contributes to stabilization of the austenite phase during hot rolling, and is combined with Cr and precipitated as Cr carbide or Cr carbonitride in the crystal grains and the grain boundaries. However, if C is less than 0.010%, the effect of refining crystal grains due to fine precipitation of carbonitrides and carbides such as V (C, N), VC, and V ₄ C ₃ cannot be obtained. In addition, the austenite phase fraction during hot rolling is reduced, so that ridging is noticeably generated in the cold-rolled steel sheet, which is a product sheet, and the formability is deteriorated. On the other hand, if C exceeds 0.070%, the amount of Cr carbide or Cr carbonitride increases too much, the steel plate becomes hard and the formability decreases, and the Cr removal layer (Cr depletion layer), coarse precipitates, and inclusions increase. Therefore, C is made 0.010% to 0.070%. More preferably, it is 0.020 to 0.040%.

Si: 1.00% or less Si is an element useful as a deoxidizer for steel. In order to obtain this effect, 0.05% or more is preferable. However, if it exceeds 1.00%, the ductility is lowered and the moldability is lowered. Therefore, Si is made 1.00% or less. More preferably, it is 0.05 to 0.50% or less. If Si is 0.28% or less, the pickling property becomes good. If pickling property is required, the content is made 0.05% to 0.28%.

Mn: 1.00% or less Mn combines with S present in the steel to form MnS and lowers the corrosion resistance. Therefore, Mn is made 1.00% or less. More preferably, it is 0.80% or less. On the other hand, 0.05% or more is preferable because refining costs increase to reduce Mn more than necessary. In addition, it is more preferably 0.05 to 0.60% from the viewpoint of particularly high corrosion resistance required and refining costs. If Mn is 0.92% or less, the pickling property becomes good. If pickling property is necessary, the content is made 0.05% to 0.92%.

P: 0.040% or less Since P is an element harmful to corrosion resistance, it is preferably reduced as much as possible. Moreover, when it exceeds 0.040%, workability will fall by solid solution strengthening. Therefore, P is set to 0.040% or less. More preferably, it is 0.030% or less.

S: 0.010% or less S forms sulfides in steel. When Mn is contained, it combines with Mn to form MnS. MnS expands by hot rolling or the like and exists as precipitates (inclusions) at ferrite grain boundaries and the like. Such sulfide-based precipitates (inclusions) lower the elongation, and particularly have a great influence on the occurrence of cracks during bending. Therefore, it is desirable to reduce S as much as possible, and it is acceptable up to 0.010%. In addition, Preferably it is 0.005% or less.

Cr: 14.00 to 20.00%
Cr is an element that contributes to improving the corrosion resistance while solid-strengthening steel, and is an essential element for a stainless steel plate. However, if Cr is less than 14.00%, the corrosion resistance as stainless steel is insufficient. On the other hand, when Cr exceeds 20.00%, in addition to the toughness being lowered, the steel is too hardened and the elongation is also significantly lowered. Therefore, Cr is 14.00 to 20.00%. Furthermore, from a viewpoint of corrosion resistance and manufacturability, it is preferably 16.00 to 18.00%.

Al: 0.150% or less Al is an element useful as a deoxidizer for steel. In order to acquire this effect, 0.001% or more is preferable. However, excessive addition causes a surface flaw due to an increase in Al-based inclusions, so the content is made 0.150% or less. More preferably, it is 0.100% or less. More preferably, it is 0.010% or less.

Ni: 1.00% or less Ni has an effect of reducing crevice corrosion. In order to obtain this effect, 0.05% or more is preferable. However, in addition to being an expensive element, even if the content exceeds 1.00%, those effects are saturated, and on the contrary, the hot workability is lowered. Therefore, Ni is made 1.00% or less. More preferably, it is 0.05 to 0.40%.

N: 0.010 to 0.060%
N, like C, contributes to the stabilization of the austenite phase during hot rolling by solid solution in steel, and combines with Cr to form Cr nitrides or Cr carbonitrides in crystal grains or crystals. Precipitates at grain boundaries and the like. Furthermore, it combines with V, which is important in the present invention, to form nitrides and carbonitrides, and refines the crystal grains of the final product to contribute to the improvement of the r value. If N is less than 0.010%, the austenite phase fraction during hot rolling decreases, and therefore, ridging occurs significantly in the cold-rolled steel sheet, which is the final product, and the formability deteriorates. On the other hand, if the content exceeds 0.060%, the amount of Cr nitride or the amount of Cr carbonitride increases excessively, the steel plate becomes hard and elongation decreases. Therefore, N is made 0.010 to 0.060%. More preferably, it is 0.020 to 0.050%.

V: 0.005 to 0.100%, B: 0.0001 to 0.0050%, and V / B ≧ 10 or more V and B are extremely important elements in the present invention. V is combined with N to form nitrides and carbonitrides such as VN and V (C, N), and has an effect of suppressing coarsening of crystal grains of the hot-rolled annealing plate. B also has an effect of assisting the suppression of grain growth by concentrating on ferrite grain boundaries and delaying grain boundary migration. Due to the combined effect of V and B, the crystal grains of the hot-rolled annealing plate are refined. As a result, the area of grain boundaries that are preferential nucleation sites of the recrystallized grains after cold rolling annealing increases, and the recrystallized grains in the {111} orientation increase. Therefore, it is considered that the r value is improved. Further, since the ratio between the V amount and the B amount is considered to affect the ferrite crystal grain size and the ferrite grain interfacial area, the present inventors have made V and B in order to maximize the r value improvement effect. The content optimization was examined.

  As component composition, C: 0.04%, Si: 0.40%, Mn: 0.80%, P: 0.030%, S: 0.004%, Al: 0.002%, Cr: 16. 20%, Ni: 0.10%, N: 0.060% contained, the steel added by changing the amount of V and B, and the steel slab was heated to 1170 ° C, the finishing temperature was Hot rolling at 830 ° C. was performed to obtain a hot rolled sheet. These hot-rolled sheets were subjected to hot-rolled sheet annealing at 860 ° C. × 8 hours, then pickled, and then cold-rolled with a total rolling reduction of 86% to obtain cold-rolled sheets. Then, these cold-rolled plates were subjected to finish annealing at 820 ° C. × 30 sec in the air, and then pickled to obtain cold-rolled annealed plates having a thickness of 0.7 mm. About the obtained cold-rolled annealing board, elongation, r value, Δr, and ridging height were determined. FIG. 1 shows the relationship between V / B and the mechanical properties (elongation, r value, Δr, ridging height) of the cold-rolled annealed sheet. From FIG. 1, when the V amount is 0.005% or more, the B amount is 0.0001% or more, and V / B ≧ 10, all of El, r value, Δr, and ridging height are satisfied. all right.

  In the present invention, V is 0.005 to 0.1%, B is 0.0001 to 0.0050%, and V / B ≧ 10. If V and B are added excessively exceeding 0.1% and 0.0050%, respectively, not only the effect of refinement of crystal grains and suppression of growth and improvement of forming processability during annealing will be saturated, but conversely The material is cured and the ductility is lowered, and the molding processability is deteriorated. From the viewpoint of ensuring high ductility, more preferably, V is 0.005 to 0.03% or less and B is 0.0001 to 0.0020%. In addition, when the V / B ratio is less than 10, since B is combined with N and precipitates as a nitride, the effect of suppressing the grain growth by reducing the concentration of B at the grain boundary is reduced. Is considered to be insufficient.

  In actual operation, the finish annealing temperature is not necessarily constant, and fluctuations in heating time and ultimate temperature cannot be avoided. In ferritic stainless steel sheets that do not contain stabilizing elements such as Ti and Nb that fix C and N, when annealed at high temperatures, sensitization occurs during cooling, and grain boundaries are eroded during subsequent pickling. The surface quality may deteriorate. For this reason, it is extremely important to prevent sensitization from occurring in a wide temperature range in order to obtain stable quality in actual operation.

  Therefore, the present inventors investigated the relationship between sensitization characteristics and V / B. As component composition, C: 0.04%, Si: 0.40%, Mn: 0.80%, P: 0.030%, S: 0.004%, Al: 0.002%, Cr: 16. 20%, Ni: 0.10%, N: 0.060% contained, the steel added by changing the amount of V and B, and the steel slab was heated to 1170 ° C, the finishing temperature was Hot rolling at 830 ° C. was performed to obtain a hot rolled sheet. These hot-rolled sheets were subjected to hot-rolled sheet annealing at 860 ° C. × 8 hours, then pickled, and then cold-rolled with a total rolling reduction of 86% to obtain cold-rolled sheets. Then, these cold-rolled plates were subjected to finish annealing at 900 ° C. for 30 seconds in the air, and then pickled to obtain cold-rolled annealed pickled plates having a thickness of 0.7 mm. The surface of the obtained cold-rolled annealed pickling plate is observed using a scanning electron microscope to observe the grain boundaries in the 500 μm × 500 μm region, investigate the presence or absence of intergranular corrosion, and evaluate the surface quality. did. The obtained results are shown in FIG. When no erosion occurred, it was marked as ◯, and when erosion occurred, it was marked as x.

  From FIG. 2, it is understood that by adding V and B so that the addition amount satisfies V / B ≧ 20, grain boundary sensitization can be suppressed even by annealing at 900 ° C. This is because Cr carbonitriding at the grain boundaries that occurs during cooling after finish annealing even when the finish annealing temperature is as high as 900 ° C by fixing C and N in steel. This is thought to be due to the suppression of the precipitation of materials. On the other hand, when V / B is less than 20, the precipitation amount of the carbonitride of V decreases because the precipitation amount of the carbonitride of V is decreased by binding B to N and precipitates as a nitride. It is thought that sensitization progressed. From the viewpoint of ensuring high ductility, more preferably, V is 0.005 to 0.03% or less and B is 0.0001 to 0.0020%.

  The balance other than the chemical components described above is Fe and inevitable impurities. Inevitable impurities include, for example, Nb: 0.05% or less, Ti: 0.05% or less, Co: 0.5% or less, W: 0.01% or less, Zr: 0.01% or less, Ta : 0.01% or less, Mg: 0.0050% or less, Ca: 0.0020% or less are acceptable.

  Below, the manufacturing method of the ferritic stainless steel of this invention is demonstrated. The molten steel having the above composition is melted in a generally known converter or electric furnace and further refined by vacuum degassing (RH), VOD (Vacuum Oxygen Decarburization), AOD (Argon Oxygen Decarburization), etc., and preferably continuously. It is cast by the casting method and used as a rolled material (slab, etc.). Next, the rolled material is heated and hot-rolled to obtain a hot-rolled sheet. The hot rolling slab heating temperature is preferably in the temperature range of 1050 ° C. to 1250 ° C., and the hot rolling finishing temperature is preferably 800 to 900 ° C. from the viewpoint of manufacturability. The hot-rolled sheet can be subjected to hot-rolled sheet annealing as necessary for the purpose of improving workability in a subsequent process. When hot-rolled sheet annealing is performed, box annealing (batch annealing) at 700 ° C. to 900 ° C. for 2 hours or more, or continuous annealing in a temperature range of 900 to 1100 ° C. may be performed for a short time. Is preferred. In addition, a hot-rolled sheet can be descaled and used as a product as it is, or can be used as a material for cold rolling. The hot-rolled sheet of the material for cold rolling is subjected to cold rolling at a cold rolling reduction ratio of 30% or more to obtain a cold-rolled sheet. The cold rolling reduction ratio is preferably 50 to 95%. Moreover, in order to provide further workability of the cold-rolled sheet, finish annealing at 600 ° C. or higher, preferably 700 to 900 ° C. can be performed. Moreover, you may perform cold rolling-annealing twice or more. Further, when glossiness is required, a skin pass or the like may be applied. For the finish processing of the cold-rolled sheet, 2D, 2B, BA, and various types of polishing specified by the Japan industrial Standard (JIS) G4305 are possible.

Molten steel having the composition shown in Table 1 was melted by secondary refining using a converter and VOD, and was made into a slab by a continuous casting method. After these slabs were heated to 1170 ° C., hot rolling was performed at a finishing temperature of 830 ° C. to obtain hot rolled sheets. These hot-rolled sheets were subjected to hot-rolled sheet annealing at 860 ° C. × 8 hours, then pickled, and then cold-rolled with a total rolling reduction of 86% to obtain cold-rolled sheets. Next, Steel No. 1-18 and steel no. Coke oven gas was combusted on 24-32 cold-rolled plates at an air ratio of 1.3, and finish annealing was performed at 820 ° C. for 30 seconds in this combustion atmosphere. Then, it pickled and it was set as the cold rolled annealing pickling board with a board thickness of 0.7 mm. In the pickling, after electrolysis of 5 A / dm ² × 10 seconds in a temperature of 80 ° C. and 20 mass% Na ₂ SO ₄ three times, in 5 mass% nitric acid at a temperature of 60 ° C., 10 A / dm ² X5 seconds of electrolysis were performed twice. In each sample, the oxide film was completely removed by pickling.

  About the obtained cold-rolled annealing pickling board, elongation, r value, and (DELTA) r were calculated | required and the moldability was evaluated. Moreover, the ridging height was calculated | required and ridging resistance was evaluated.

Steel No. For cold rolled sheets 19-23 and 33-36, coke oven gas was burned at an air ratio of 1.3, and after finish annealing at 900 ° C. × 30 sec in this combustion atmosphere, the same conditions as described above were applied. It pickled and it was set as the cold rolled annealing pickling board of thickness 0.7mm. In each sample, the oxide film was completely removed by pickling. The obtained cold-rolled annealed pickling plate was evaluated for moldability and ridging resistance. The measuring method of elongation, r value, Δr, and ridging height is as follows.
(1) JIS No. 13 B test specimens were collected from each direction [rolling direction (L direction), rolling perpendicular direction (C direction), and 45 ° direction (D direction)] from the cold-rolled annealed pickled sheet. Tensile tests were carried out using these tensile test pieces, and the elongation in each direction was measured. The average value of elongation was calculated from the following formula using the elongation value in each direction. El passed 30% or more.
E1 = (ElL + 2 × ElD + ElC) / 4
Here, ElL, ElD, and ElC represent elongations in the L direction, the D direction, and the C direction, respectively.
(2) JIS13B test specimens were collected from each direction [rolling direction (L direction), rolling perpendicular direction (C direction) and rolling direction 45 ° direction (D direction)] of r-value cold-rolled annealed pickled sheets. . Based on the ratio of width strain and thickness strain when 15% uniaxial tensile pre-strain was applied to these specimens, the r value in each direction (Lankford Value) ) And the r value and Δr were determined by the following equation. An r value of 1.3 or more and Δr of 0.3 or less were accepted.
r = (rL + 2 × rD + rC) / 4
Δr = (rL−2 × rD + rC) / 2
Here, rL, rD, and rC represent r values in the L direction, the D direction, and the C direction, respectively.
(3) A JIS No. 5 tensile specimen was taken from the rolling direction of the ridging height cold-rolled annealed pickled plate. One side of these specimens is finished and polished with # 600, and after applying 20% prestrain of uniaxial stretching to these specimens, the surface of the central part of the specimen is measured using a roughness meter. The swell height was measured. This height of the waviness is unevenness due to ridging. From the height of the undulation, ridging resistance was evaluated in four stages: A: 5 μm or less, B: 5 μm to 10 μm or less, C: 10 μm to 20 μm or less, D: 20 μm or more. The lower the swell height, the better the aesthetic after molding. A evaluation with a swell height of 5.0 μm or less was regarded as acceptable.

  The obtained results are shown in Table 2.

  Each of the inventive examples has an A evaluation with an elongation of 30% or more, an r value of 1.3 or more, an Δr of 0.3 or less, and a waviness height of 5.0 μm or less, and good moldability and ridging resistance. It has sex. In contrast, the comparative example did not satisfy any of elongation, r value, Δr, and ridging height.

Invention Example No. 1 of Example 1 having good moldability and ridging resistance. 5-11 and no. About 19-36, although the pickling power was weaker than the pickling method of Example 1, the pickling property in the highly productive nitric acid and hydrochloric acid electrolytic method was evaluated. . Steel No. 1 produced in Example 1 was used. 5-11 and the plate thickness 0.7mm cold-rolled sheet of 19-36, a weakly reducing atmosphere _{(H 2: 5vol%, N} 2: 95vol%, the dew point (dew point) -40 degrees) at the 820 ° C. × 30 sec Annealing was performed to obtain a cold-rolled annealed plate. The cold-rolled annealed plate was electrolyzed in a solution composed of 50 ° C., 10% by mass nitric acid and 1.0% by mass hydrochloric acid, and the pickling property was evaluated by visually observing the presence or absence of the oxide film residue.
10A / dm ² × 2 seconds oxide film by electrolysis performed twice what was completely removed ◎ (excellent), could not be completely removed oxide coating by electrolysis performed 10A / dm ² × 2 seconds twice and although, 10A / dm ² × 4 seconds electrolytic twice performed and the ○ (good) which oxide film is completely removed, and also completely oxidized film went 10A / ^dm 2 x4 seconds electrolytic twice Those that could not be removed were evaluated as x (defect). ◎ (Excellent) and ○ (Good) are acceptable.

  The results are shown in Table 3.

  Steel No. having Si of 0.28% or less and Mn of 0.92% or less. 5-10, 19-26 and 30-34 are particularly excellent in pickling properties in addition to good moldability and ridging resistance. It can be produced not only by a general pickling method but also by a highly productive nitric acid hydrochloric acid electrolysis method.

  Steel No. 1 of Example 1 About 19-23 and 33-36, the sensitization evaluation which considered the case where the range of finish annealing temperature was fluctuate | varied by actual operation was performed.

In the sensitization evaluation method, a cold-rolled sheet having a thickness of 0.7 mm produced in Example 1 was annealed at 900 ° C. × 30 sec, and washed with nitric acid after Na ₂ SO ₄ electrolysis under the same conditions as in Example 1. . Using a scanning electron microscope, the surface of the cold-rolled annealed pickling plate was observed for grain boundaries in a 500 μm × 500 μm region to investigate the presence or absence of grain boundary erosion, and the surface quality was evaluated. It was evaluated that there was no sensitization when no erosion occurred at the grain boundaries, and there was sensitization when erosion occurred. The results are shown in Table 4.

  From the results of Table 4, steel No. with V / B of 20 or more. In Nos. 21 to 23 and 33 to 36, in addition to good moldability and ridging resistance, no occurrence of grain boundary erosion was observed, and the sensitization resistance was also good.

  According to the present invention, a ferritic stainless steel sheet satisfying deep drawability and ridging resistance and excellent in formability can be produced by optimizing the component composition, particularly V and B contents. The effect of. Furthermore, by adjusting the V and B contents to the optimum ranges, the sensitization resistance is improved, and it is possible to stably produce ferritic stainless steel sheets with excellent surface quality in addition to forming processability. Become.

Claims (3)

  C: 0.010 to 0.070%, Si: 1.00% or less, Mn: 1.00% or less, P: 0.040% or less, S: 0.010% or less, Al: 0 150% or less, Cr: 14.00 to 20.00%, Ni: 1.00% or less, N: 0.010 to 0.060%, V: 0.005 to 0.100%, B: A ferritic stainless steel sheet containing 0.0001 to 0.0050% and satisfying V / B ≧ 10, the balance being Fe and inevitable impurities.   The ferritic stainless steel sheet according to claim 1, wherein Si: 0.05 to 0.28% and Mn: 0.05 to 0.92%.   The ferritic stainless steel sheet according to claim 1 or 2, wherein V / B≥20 is satisfied.

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