JP2013544734A - 極塑性変形操作を包含する、水素貯蔵用材料の製造方法 - Google Patents
極塑性変形操作を包含する、水素貯蔵用材料の製造方法 Download PDFInfo
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- 239000001257 hydrogen Substances 0.000 title claims abstract description 63
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 63
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims description 58
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 239000011232 storage material Substances 0.000 title description 2
- 206010020718 hyperplasia Diseases 0.000 title 1
- 230000002390 hyperplastic effect Effects 0.000 title 1
- 150000004678 hydrides Chemical class 0.000 claims abstract description 51
- 239000007769 metal material Substances 0.000 claims abstract description 50
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 42
- 239000000956 alloy Substances 0.000 claims abstract description 42
- 238000000034 method Methods 0.000 claims abstract description 36
- 239000000463 material Substances 0.000 claims abstract description 28
- 229910052751 metal Inorganic materials 0.000 claims abstract description 28
- 239000002184 metal Substances 0.000 claims abstract description 28
- 150000001875 compounds Chemical class 0.000 claims abstract description 20
- 239000006185 dispersion Substances 0.000 claims abstract description 15
- 238000005242 forging Methods 0.000 claims abstract description 12
- 238000005097 cold rolling Methods 0.000 claims abstract description 9
- 229910052987 metal hydride Inorganic materials 0.000 claims abstract description 8
- 150000004681 metal hydrides Chemical class 0.000 claims abstract description 8
- 238000005452 bending Methods 0.000 claims abstract description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 56
- 239000011777 magnesium Substances 0.000 claims description 49
- 229910052749 magnesium Inorganic materials 0.000 claims description 47
- 238000005984 hydrogenation reaction Methods 0.000 claims description 28
- 238000000227 grinding Methods 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 17
- 239000012298 atmosphere Substances 0.000 claims description 16
- 238000003860 storage Methods 0.000 claims description 10
- 238000001125 extrusion Methods 0.000 claims description 6
- 230000003213 activating effect Effects 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- 229910000861 Mg alloy Inorganic materials 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 150000002739 metals Chemical class 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 229910001068 laves phase Inorganic materials 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract description 2
- 238000010521 absorption reaction Methods 0.000 description 16
- 238000001994 activation Methods 0.000 description 15
- 238000003795 desorption Methods 0.000 description 12
- 230000004913 activation Effects 0.000 description 11
- 230000015572 biosynthetic process Effects 0.000 description 10
- 229910012375 magnesium hydride Inorganic materials 0.000 description 8
- 238000005096 rolling process Methods 0.000 description 7
- 238000003786 synthesis reaction Methods 0.000 description 7
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- 229910052726 zirconium Inorganic materials 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000013078 crystal Substances 0.000 description 5
- 238000006356 dehydrogenation reaction Methods 0.000 description 5
- 150000002431 hydrogen Chemical class 0.000 description 5
- 229910052776 Thorium Inorganic materials 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 239000012300 argon atmosphere Substances 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 229910052804 chromium Inorganic materials 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910002804 graphite Inorganic materials 0.000 description 4
- 239000010439 graphite Substances 0.000 description 4
- 229910052748 manganese Inorganic materials 0.000 description 4
- 229910052758 niobium Inorganic materials 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 229910052720 vanadium Inorganic materials 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- 229910052688 Gadolinium Inorganic materials 0.000 description 3
- 229910052772 Samarium Inorganic materials 0.000 description 3
- 229910052790 beryllium Inorganic materials 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 229910052746 lanthanum Inorganic materials 0.000 description 3
- 229910052744 lithium Inorganic materials 0.000 description 3
- 229910052750 molybdenum Inorganic materials 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 229910052763 palladium Inorganic materials 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 229910052727 yttrium Inorganic materials 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 229910052692 Dysprosium Inorganic materials 0.000 description 2
- 229910052691 Erbium Inorganic materials 0.000 description 2
- 229910052779 Neodymium Inorganic materials 0.000 description 2
- 229910052777 Praseodymium Inorganic materials 0.000 description 2
- 229910052770 Uranium Inorganic materials 0.000 description 2
- 229910052769 Ytterbium Inorganic materials 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910052735 hafnium Inorganic materials 0.000 description 2
- 238000005551 mechanical alloying Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 238000004347 surface barrier Methods 0.000 description 2
- 241001121515 Celes Species 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 229910052693 Europium Inorganic materials 0.000 description 1
- 229910052689 Holmium Inorganic materials 0.000 description 1
- 229910052771 Terbium Inorganic materials 0.000 description 1
- 229910052775 Thulium Inorganic materials 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- 150000002680 magnesium Chemical class 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000010137 moulding (plastic) Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- -1 titanium hydrides Chemical class 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0031—Intermetallic compounds; Metal alloys; Treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0026—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof of one single metal or a rare earth metal; Treatment thereof
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C11/00—Use of gas-solvents or gas-sorbents in vessels
- F17C11/005—Use of gas-solvents or gas-sorbents in vessels for hydrogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/4998—Combined manufacture including applying or shaping of fluent material
- Y10T29/49982—Coating
- Y10T29/49986—Subsequent to metal working
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Powder Metallurgy (AREA)
Abstract
Description
本開示は、水素貯蔵に適当な材料、すなわち直接、または少なくとも一回の活性化工程の後、水素の貯蔵、輸送及び/又は製造の目的で、水素を吸収することができる材料の製造方法に関する。有利には、水素を貯蔵できる材料は、可逆的に水素を貯蔵し得る材料、すなわち水素を特定の条件下で脱着することができる材料である。
水素は、様々な工業的化学的用途、例えばアンモニアの製造、精製、プラスチックの成形、等、に使用される。水素は、その急速な、または遅い燃焼の際に水だけを製造し、温室効果ガスを放出しないため、燃料(サーマルモーター、燃料電池)としても有利に使用できる。
本発明の目的は、水素を好ましくは可逆的に貯蔵するのに適当な材料の、工業化が容易な、該材料における反応速度及び水素吸収率が有利に増加した、製造方法を提供することである。
図1に示すように、驚くべきことに、マグネシウムを含む金属材料を主要な極塑性変形操作(extreme plastic deformation operation)(図1におけるケースn°1)にかけ、次いで水素化物を該金属材料に加え、分散を行うことにより、水素を可逆的に貯蔵するのに特に適当なマグネシウム含有材料の製造が可能であることを発見した。分散は、有利には、不活性雰囲気中で行うとよい。「不活性雰囲気」は、分散すべき材料と反応し得るガスを一切含まない雰囲気、特に水素を含まない雰囲気を指定するのに使用する。不活性雰囲気は、アルゴン雰囲気が有利である。
1)Li、Be、B、Na、Mg、Si、K、Ca、Sc、Ti、V、Cr、Mn、Ni、Cu、Zn、Ga、Rb、Sr、Y、Zr、Nb、Pd、Cs、Ba、La、Hf、Ta、Ce、Pr、Nd、Sm、Gd、Tb、Dy、Ho、Er、Tm、Yb、Lu、Ac、Th及びUの中から選択された元素である。
2)AB5タイプ合金、ここで
−Aは、La、Ca、Y、Ce、Mm、Pr、Nd、Sm、Eu、Gd、Yb及びThの中から選択された少なくとも一種の元素であり、
−Bは、Ni、Al、Co、Cr、Cu、Fe、Mn、Si、Ti、V、Zn、Zr、Nb、Mo及びPdの中から選択された少なくとも一種の元素である。
3)タイプAB2のラーベス相構造を有する合金で、
−Aが、Ca、Ce、Dy、Er、Gd、Ho、Hf、La、Li、Pr、Sc、Sm、Th、Ti、U、Y及びZrの中から選択された少なくとも一種の元素であり、
−Bが、Ni、Fe、Mn、Co、Al、Rh、Ru、Pd、Cr、Zr、Be、Ti、Mo、V、Nb、Cu及びZnの中から選択された少なくとも一種の元素である。
4)ABタイプ合金で、
−Aが、Ti、Er、Hf、Li、Th、U及びZrの中から選択された少なくとも一種の元素であり、
−Bが、Fe、Al、Be、Co、Cr、Mn、Mo、Nb及びVの中から選択された少なくとも一種の元素である。
5)体心立方構造の合金、例えば米国特許第5968291号に記載されている。
Claims (13)
- 水素貯蔵に適当な材料の製造方法であって、
−金属及び前記金属を含む合金の中から選択された金属材料に対して、または
−金属及び前記金属を含む合金の中から選択された金属材料を含み、前記金属の水素化物または前記合金の水素化物が添加されている化合物に対して行なわれる、冷間圧延、急速鍛造及び押出し曲げの中から選択された極塑性変形操作を含んでなり、
前記極塑性変形操作が前記金属材料に対して行われる場合、前記金属材料に、前記金属の水素化物または前記合金の水素化物を添加する操作、及び分散操作を続いて行う、方法。 - 前記極塑性変形操作が前記金属材料に対して行われる場合、前記金属材料に、前記金属の水素化物または前記合金の水素化物を添加する操作、及び分散操作を不活性雰囲気中で行う、請求項1に記載の方法。
- 前記金属材料が、マグネシウム、マグネシウムを含む合金、アルミニウムを含む合金、体心立方構造の合金、ラーベス相構造の合金、AB5タイプ合金、及びABタイプ合金の中から選択される、請求項1または2に記載の方法。
- 前記極塑性変形操作にかけられる前記金属材料または前記化合物が固体片の形態にある、請求項1〜3のいずれか一項に記載の方法。
- 前記金属材料に、前記水素化物を添加する操作が、前記分散操作の際に行われる、請求項1〜4のいずれか一項に記載の方法。
- 前記金属材料に、前記水素化物を添加する操作が、前記分散操作の前に行われる、請求項1〜4のいずれか一項に記載の方法。
- 前記分散操作に続いて、前記混合物の水素化の第一操作を行い、前記混合物を活性化する、請求項1〜6のいずれか一項に記載の方法。
- 金属材料及び水素化物を含む前記化合物に対して行われる前記極塑性変形に続いて、前記化合物の水素化の第一操作を行い、前記化合物を活性化する、請求項1〜4のいずれか一項に記載の方法。
- 前記分散操作が、前記極塑性変形と、前記化合物の水素化の前記第一操作との間に行われる、請求項8に記載の方法。
- 前記極塑性変形と、前記化合物の水素化の前記第一操作との間に行われる前記分散操作が、不活性雰囲気中で行われる、請求項9に記載の方法。
- 前記分散操作が、1時間以内の機械的粉砕により行われる、請求項1〜10のいずれか一項に記載の方法。
- 前記金属材料に添加される前記水素化物が、前記添加の前に行われる、前記金属材料を活性化するための前記金属材料の水素化操作により得られる、請求項1〜11のいずれか一項に記載の方法。
- 前記金属材料に添加される水素化物の比率が、前記金属材料の総重量に対して0.5〜10重量%、好ましくは1〜10重量%である、請求項1〜12のいずれか一項に記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1002928 | 2010-07-12 | ||
FR1002928A FR2962430B1 (fr) | 2010-07-12 | 2010-07-12 | Procede de preparation d'un materiau de stockage de l'hydrogene comprenant une operation de deformation plastique severe |
PCT/FR2011/000409 WO2012007657A1 (fr) | 2010-07-12 | 2011-07-11 | Procédé de préparation d'un matériau de stockage de l'hydrogène comprenant une opération de déformation plastique sévère. |
Publications (2)
Publication Number | Publication Date |
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JP2013544734A true JP2013544734A (ja) | 2013-12-19 |
JP5855649B2 JP5855649B2 (ja) | 2016-02-09 |
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JP2013519123A Active JP5855649B2 (ja) | 2010-07-12 | 2011-07-11 | 極塑性変形操作を包含する、水素貯蔵用材料の製造方法 |
Country Status (8)
Country | Link |
---|---|
US (1) | US20130111736A1 (ja) |
EP (1) | EP2593401B1 (ja) |
JP (1) | JP5855649B2 (ja) |
AU (1) | AU2011278213B2 (ja) |
BR (1) | BR112013000704A2 (ja) |
CA (1) | CA2804615C (ja) |
FR (1) | FR2962430B1 (ja) |
WO (1) | WO2012007657A1 (ja) |
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EP3638824A4 (en) * | 2017-06-21 | 2021-07-28 | Atomic Energy of Canada Limited/ Énergie Atomique du Canada Limitée | ADDING HYDROGEN GASES TO MECHANICALLY ASSISTED METAL ALLOYS |
CN111101007B (zh) * | 2020-01-13 | 2022-02-25 | 周口师范学院 | 一种高性能镍基合金复合带材的制备方法 |
CN111533086B (zh) * | 2020-05-11 | 2023-12-01 | 中国科学院长春应用化学研究所 | 一种利用含氢化合物快速活化储氢合金的短流程制备方法 |
CN112321835B (zh) * | 2020-10-30 | 2021-06-08 | 宁波众兴新材料科技有限公司 | 一种含硼聚金属碳硅烷及其制备方法 |
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- 2011-07-11 WO PCT/FR2011/000409 patent/WO2012007657A1/fr active Application Filing
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Publication number | Publication date |
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WO2012007657A1 (fr) | 2012-01-19 |
FR2962430A1 (fr) | 2012-01-13 |
FR2962430B1 (fr) | 2013-07-19 |
CA2804615C (en) | 2019-04-02 |
US20130111736A1 (en) | 2013-05-09 |
EP2593401B1 (fr) | 2018-12-05 |
CA2804615A1 (en) | 2012-01-19 |
BR112013000704A2 (pt) | 2016-05-17 |
AU2011278213B2 (en) | 2015-12-03 |
EP2593401A1 (fr) | 2013-05-22 |
JP5855649B2 (ja) | 2016-02-09 |
AU2011278213A1 (en) | 2013-01-31 |
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