JP2013539812A5 - - Google Patents
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- Publication number
- JP2013539812A5 JP2013539812A5 JP2013533331A JP2013533331A JP2013539812A5 JP 2013539812 A5 JP2013539812 A5 JP 2013539812A5 JP 2013533331 A JP2013533331 A JP 2013533331A JP 2013533331 A JP2013533331 A JP 2013533331A JP 2013539812 A5 JP2013539812 A5 JP 2013539812A5
- Authority
- JP
- Japan
- Prior art keywords
- group
- peroxide
- copolymer
- propylene polymer
- melt strength
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 claims description 17
- 229920001155 polypropylene Polymers 0.000 claims description 9
- 150000002978 peroxides Chemical class 0.000 claims description 5
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 4
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 4
- 239000003381 stabilizer Substances 0.000 claims description 4
- 239000000314 lubricant Substances 0.000 claims description 3
- 239000000155 melt Substances 0.000 claims description 3
- 239000000178 monomer Substances 0.000 claims description 3
- 239000000758 substrate Substances 0.000 claims description 3
- YHGJJXWSBKQECN-UHFFFAOYSA-N 2,4-ditert-butylphenol;phosphoric acid Chemical compound OP(O)(O)=O.CC(C)(C)C1=CC=C(O)C(C(C)(C)C)=C1.CC(C)(C)C1=CC=C(O)C(C(C)(C)C)=C1.CC(C)(C)C1=CC=C(O)C(C(C)(C)C)=C1 YHGJJXWSBKQECN-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 2
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 claims description 2
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 2
- BEIOEBMXPVYLRY-UHFFFAOYSA-N [4-[4-bis(2,4-ditert-butylphenoxy)phosphanylphenyl]phenyl]-bis(2,4-ditert-butylphenoxy)phosphane Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(C=1C=CC(=CC=1)C=1C=CC(=CC=1)P(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C BEIOEBMXPVYLRY-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- 239000003963 antioxidant agent Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims 4
- 239000004711 α-olefin Substances 0.000 claims 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims 2
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 claims 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims 2
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 claims 2
- RYPKRALMXUUNKS-UHFFFAOYSA-N 2-Hexene Natural products CCCC=CC RYPKRALMXUUNKS-UHFFFAOYSA-N 0.000 claims 2
- 239000004743 Polypropylene Substances 0.000 claims 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 claims 2
- -1 polypropylene Polymers 0.000 claims 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 2
- BYMLDFIJRMZVOC-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoic acid;methane Chemical compound C.CC(C)(C)C1=CC(CCC(O)=O)=CC(C(C)(C)C)=C1O BYMLDFIJRMZVOC-UHFFFAOYSA-N 0.000 claims 1
- 239000004342 Benzoyl peroxide Substances 0.000 claims 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 claims 1
- MEYBPUZOYCHPIG-UHFFFAOYSA-N benzoic acid;2-tert-butylperoxy-2-methylpropane Chemical compound OC(=O)C1=CC=CC=C1.CC(C)(C)OOC(C)(C)C MEYBPUZOYCHPIG-UHFFFAOYSA-N 0.000 claims 1
- 235000019400 benzoyl peroxide Nutrition 0.000 claims 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical group [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims 1
- 239000008116 calcium stearate Substances 0.000 claims 1
- 235000013539 calcium stearate Nutrition 0.000 claims 1
- 239000012933 diacyl peroxide Substances 0.000 claims 1
- 150000002432 hydroperoxides Chemical class 0.000 claims 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims 1
- QMMOXUPEWRXHJS-UHFFFAOYSA-N pent-2-ene Chemical compound CCC=CC QMMOXUPEWRXHJS-UHFFFAOYSA-N 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- XMIIGOLPHOKFCH-UHFFFAOYSA-N 3-phenylpropionic acid Chemical compound OC(=O)CCC1=CC=CC=C1 XMIIGOLPHOKFCH-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- JXOHGGNKMLTUBP-HSUXUTPPSA-N shikimic acid Chemical compound O[C@@H]1CC(C(O)=O)=C[C@@H](O)[C@H]1O JXOHGGNKMLTUBP-HSUXUTPPSA-N 0.000 description 1
- JXOHGGNKMLTUBP-JKUQZMGJSA-N shikimic acid Natural products O[C@@H]1CC(C(O)=O)=C[C@H](O)[C@@H]1O JXOHGGNKMLTUBP-JKUQZMGJSA-N 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IN2860/MUM/2010 | 2010-10-14 | ||
| IN2860MU2010 | 2010-10-14 | ||
| PCT/IN2011/000707 WO2012049690A1 (en) | 2010-10-14 | 2011-10-11 | A process for preparing high melt strength propylene polymers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2013539812A JP2013539812A (ja) | 2013-10-28 |
| JP2013539812A5 true JP2013539812A5 (https=) | 2015-03-05 |
Family
ID=45937959
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013533331A Pending JP2013539812A (ja) | 2010-10-14 | 2011-10-11 | 高溶融強度プロピレン系重合体の調製プロセス |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US9074062B2 (https=) |
| EP (1) | EP2627686A4 (https=) |
| JP (1) | JP2013539812A (https=) |
| KR (1) | KR101559638B1 (https=) |
| BR (1) | BR112013008999A2 (https=) |
| WO (1) | WO2012049690A1 (https=) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013102938A1 (en) * | 2012-01-07 | 2013-07-11 | Council Of Scientific & Industrial Research | Modified polypropylene compositions for reduced necking in extrusion film casting or extrusion coating processes |
| MY163472A (en) * | 2012-07-24 | 2017-09-15 | Petroliam Nasional Berhad (Petronas) | Polymer compositions |
| BR112015009509B1 (pt) | 2012-10-31 | 2021-09-21 | Exxonmobil Chemical Patents Inc | Artigos moldado compreendendo resinas de polipropileno de ampla distribuição de peso molecular e resina espumável |
| EP2914637B1 (en) | 2012-10-31 | 2017-12-13 | ExxonMobil Chemical Patents Inc. | Broad molecular weight distribution polypropylene resins |
| JP6568798B2 (ja) * | 2013-09-27 | 2019-08-28 | 積水化成品工業株式会社 | 改質ポリプロピレン系樹脂、樹脂発泡体及び発泡樹脂製容器、及び、改質ポリプロピレン系樹脂の製造方法 |
| IN2014MU00160A (https=) * | 2014-01-17 | 2015-08-28 | Reliance Ind Ltd | |
| US20170073487A1 (en) | 2014-03-10 | 2017-03-16 | Hickory Springs Manufacturing Company | High temperature non-crosslinked polyethylene-based foam and method of making the same |
| CN114230931A (zh) * | 2014-06-25 | 2022-03-25 | 埃克森美孚化学专利公司 | 高熔体强度聚丙烯以及用于保持熔体强度的挤出方法 |
| US20160030728A1 (en) | 2014-07-31 | 2016-02-04 | Tekni-Plex, Inc. | Extrudable tubing and solvent bonded fitting for delivery of medicinal fluids |
| KR101949068B1 (ko) | 2015-02-04 | 2019-02-15 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 균형화된 변형 경화, 용융 강도, 및 전단 박화를 갖는 폴리프로필렌 |
| CN107466305B (zh) * | 2015-04-10 | 2021-03-30 | 埃克森美孚化学专利公司 | 聚丙烯与有机过氧化物的挤出 |
| WO2016175942A1 (en) | 2015-04-28 | 2016-11-03 | Exxonmobil Chemical Patents Inc. | Propylene-based impact copolymers |
| BR112018008830B1 (pt) | 2015-11-30 | 2022-01-18 | Exxonmobil Chemical Patents Inc | Polipropileno para filmes, seu processo de preparação e os filmes do mesmo |
| JP6852482B2 (ja) * | 2017-03-16 | 2021-03-31 | Ｍｃｐｐイノベーション合同会社 | 非発泡成形用熱可塑性エラストマー組成物及びその成形体 |
| US11117995B2 (en) | 2018-08-23 | 2021-09-14 | Formosa Plastics Corporation, U.S.A. | Process for preparing high melt strength polypropylene |
| JP7436470B2 (ja) | 2018-10-12 | 2024-02-21 | ヌーリオン ケミカルズ インターナショナル ベスローテン フェノーツハップ | 固体有機過酸化物組成物 |
| US11021603B2 (en) * | 2019-01-03 | 2021-06-01 | Nan Ya Plastics Corporation | White polyester film with properties of lightweight and low-shrinkage |
| US11286317B2 (en) | 2019-04-12 | 2022-03-29 | Indian Oil Corporation Limited | Morphology modified heterophase propylene copolymers and their products thereof |
| JP7706137B2 (ja) | 2019-05-27 | 2025-07-11 | 上野製薬株式会社 | 液晶ポリマー組成物 |
| EP4127060B1 (en) * | 2020-03-26 | 2024-05-01 | Fina Technology, Inc. | High melt strength polypropylene and process of preparation thereof |
| WO2022081164A1 (en) * | 2020-10-15 | 2022-04-21 | Milliken & Company | Polymer compositions and methods for making the same |
| EP4573133A1 (en) * | 2022-08-19 | 2025-06-25 | Borealis AG | Process for preparing a long chain branched polypropylene composition |
| CN116041855B (zh) * | 2023-01-03 | 2024-07-05 | 青岛海泰科新材料科技有限公司 | 一种高熔体强度微发泡聚丙烯复合材料及其制备方法 |
| WO2025021757A1 (en) | 2023-07-26 | 2025-01-30 | Sabic Global Technologies B.V. | Process for preparing high melt strength propylene polymer |
| CN117659569B (zh) * | 2023-12-20 | 2026-04-14 | 山东凯旋模塑有限公司 | 一种高强度玻璃纤维改性聚丙烯材料建筑模板及其制备方法 |
| CN119552313B (zh) * | 2025-02-05 | 2025-04-25 | 成都科成精化科技有限公司 | 聚烯烃组合物及其制备方法 |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US383431A (en) | 1888-05-29 | David t | ||
| US3318976A (en) | 1965-12-03 | 1967-05-09 | Shell Oil Co | Production of modified polyolefin |
| JPS5124555B2 (https=) | 1974-03-05 | 1976-07-24 | ||
| US4451589A (en) | 1981-06-15 | 1984-05-29 | Kimberly-Clark Corporation | Method of improving processability of polymers and resulting polymer compositions |
| JPS60188412A (ja) * | 1984-03-09 | 1985-09-25 | Chisso Corp | ポリオレフイン樹脂組成物の製造方法 |
| IN166935B (https=) | 1985-01-31 | 1990-08-11 | Himont Inc | |
| DE3688258T3 (de) | 1985-01-31 | 2001-02-22 | Montell North America Inc., Wilmington | Polypropylen mit freier Langkettenverzweigung, Verfahren zur Herstellung und Verwendung davon. |
| JPS61190540A (ja) * | 1985-02-20 | 1986-08-25 | Idemitsu Petrochem Co Ltd | ポリプロピレン樹脂組成物の改質方法 |
| US5047485A (en) | 1989-02-21 | 1991-09-10 | Himont Incorporated | Process for making a propylene polymer with free-end long chain branching and use thereof |
| US5200439A (en) | 1990-04-13 | 1993-04-06 | Mitsui Toatsu Chemicals, Inc. | Method for increasing intrinsic viscosity of syndiotactic polypropylene |
| US5439949A (en) | 1991-08-21 | 1995-08-08 | Rexene Corporation | Propylene compositions with improved resistance to thermoforming sag |
| US5416169A (en) | 1992-11-26 | 1995-05-16 | Chisso Corporation | Polypropylene having a high melt-tensile strength, a process for producing the same and a molded product from the same |
| US5414027A (en) | 1993-07-15 | 1995-05-09 | Himont Incorporated | High melt strength, propylene polymer, process for making it, and use thereof |
| US5447985A (en) | 1993-10-28 | 1995-09-05 | Akzo Nobel N.V. | Modification of (CO)polymers with unsaturated peroxyacids |
| JP3355816B2 (ja) * | 1994-09-19 | 2002-12-09 | チッソ株式会社 | 改質ポリプロピレンの製造法および成形品 |
| US5820981A (en) | 1996-04-02 | 1998-10-13 | Montell North America Inc. | Radiation visbroken polypropylene and fibers made therefrom |
| TW341579B (en) | 1996-06-24 | 1998-10-01 | Akzo Nobel Nv | Process for enhancing the melt strength of polypropylene (co)polymers |
| UA60351C2 (uk) * | 1997-11-21 | 2003-10-15 | Акцо Нобель Н.В. | Спосіб модифікації поліпропілену |
| US6225411B1 (en) | 1999-04-19 | 2001-05-01 | Montell Technology Company Bv | Soft propylene polymer blend with high melt strength |
| US6664317B2 (en) | 2000-02-18 | 2003-12-16 | Ciba Specialty Chemicals Corporation | Stabilized gamma irradiated polyolefins |
| US6548600B2 (en) * | 2000-09-22 | 2003-04-15 | Dupont Dow Elastomers L.L.C. | Thermoplastic elastomer compositions rheology-modified using peroxides and free radical coagents |
| US6444722B1 (en) | 2000-11-02 | 2002-09-03 | Basell Poliolefine Italia S.P.A. | Making polyolefin graft copolymers with low molecular weight side chains using a polymeric peroxide as an initiator |
| EP1380613A1 (en) | 2002-07-09 | 2004-01-14 | ATOFINA Research | Long chain branching polypropylene |
| CN101148490B (zh) * | 2006-09-22 | 2010-11-24 | 中国石油化工股份有限公司 | 一种高熔体强度聚丙烯的制备方法 |
| EP2167570A1 (en) | 2007-06-29 | 2010-03-31 | Basell Poliolefine Italia S.R.L. | An irradiated polyolefin composition comprising a non - phenolic stabilizer |
| CN100535047C (zh) | 2007-07-20 | 2009-09-02 | 唐山市福恩特防腐电气控制设备有限公司 | 一种高熔体强度聚丙烯材料及其制备方法 |
| WO2010007671A1 (ja) | 2008-07-16 | 2010-01-21 | 株式会社日立製作所 | プラズマディスプレイパネルの製造方法 |
| CN102105527A (zh) * | 2008-07-23 | 2011-06-22 | 沙特基础工业公司 | 制备改性聚丙烯组合物的方法 |
| US20100087602A1 (en) * | 2008-10-08 | 2010-04-08 | Fina Technology, Inc. | Long chain branched polypropylene for cast film applications |
| US7935740B2 (en) | 2008-12-30 | 2011-05-03 | Basell Poliolefine Italia S.R.L. | Process for producing high melt strength polypropylene |
-
2011
- 2011-10-11 EP EP11832231.2A patent/EP2627686A4/en not_active Withdrawn
- 2011-10-11 KR KR1020137011356A patent/KR101559638B1/ko not_active Expired - Fee Related
- 2011-10-11 US US13/879,296 patent/US9074062B2/en not_active Expired - Fee Related
- 2011-10-11 JP JP2013533331A patent/JP2013539812A/ja active Pending
- 2011-10-11 WO PCT/IN2011/000707 patent/WO2012049690A1/en not_active Ceased
- 2011-10-11 BR BR112013008999A patent/BR112013008999A2/pt not_active IP Right Cessation
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