JP2013530915A - 高温用のガラス基板 - Google Patents
高温用のガラス基板 Download PDFInfo
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- 239000011521 glass Substances 0.000 title claims abstract description 490
- 239000000758 substrate Substances 0.000 title claims abstract description 169
- 238000000137 annealing Methods 0.000 claims abstract description 76
- 239000005357 flat glass Substances 0.000 claims abstract description 39
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims description 45
- 238000000576 coating method Methods 0.000 claims description 44
- 238000012545 processing Methods 0.000 claims description 43
- 238000002844 melting Methods 0.000 claims description 38
- 230000008018 melting Effects 0.000 claims description 38
- 238000005496 tempering Methods 0.000 claims description 32
- 238000000151 deposition Methods 0.000 claims description 30
- 239000011248 coating agent Substances 0.000 claims description 28
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 27
- 239000005361 soda-lime glass Substances 0.000 claims description 26
- 239000006060 molten glass Substances 0.000 claims description 20
- 229910052726 zirconium Inorganic materials 0.000 claims description 13
- 238000007496 glass forming Methods 0.000 claims description 12
- 238000002834 transmittance Methods 0.000 claims description 9
- 239000005329 float glass Substances 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 5
- 238000011068 loading method Methods 0.000 claims description 5
- 229910052684 Cerium Inorganic materials 0.000 claims description 4
- 230000001747 exhibiting effect Effects 0.000 claims 1
- 239000000203 mixture Substances 0.000 abstract description 34
- 238000004519 manufacturing process Methods 0.000 abstract description 19
- 238000005728 strengthening Methods 0.000 abstract description 9
- HUAUNKAZQWMVFY-UHFFFAOYSA-M sodium;oxocalcium;hydroxide Chemical compound [OH-].[Na+].[Ca]=O HUAUNKAZQWMVFY-UHFFFAOYSA-M 0.000 abstract description 5
- 230000009286 beneficial effect Effects 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 51
- 239000011734 sodium Substances 0.000 description 31
- 229910052742 iron Inorganic materials 0.000 description 25
- 238000010438 heat treatment Methods 0.000 description 24
- 239000010408 film Substances 0.000 description 21
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 20
- 230000008021 deposition Effects 0.000 description 20
- 239000005347 annealed glass Substances 0.000 description 19
- 239000010410 layer Substances 0.000 description 18
- 238000006243 chemical reaction Methods 0.000 description 17
- 238000007739 conversion coating Methods 0.000 description 16
- 239000005341 toughened glass Substances 0.000 description 15
- 229910052708 sodium Inorganic materials 0.000 description 12
- 238000000926 separation method Methods 0.000 description 11
- 230000006835 compression Effects 0.000 description 10
- 238000007906 compression Methods 0.000 description 10
- 239000000463 material Substances 0.000 description 10
- 230000008569 process Effects 0.000 description 10
- 125000006850 spacer group Chemical group 0.000 description 8
- 230000005540 biological transmission Effects 0.000 description 7
- 239000000446 fuel Substances 0.000 description 7
- 238000005816 glass manufacturing process Methods 0.000 description 6
- 230000003287 optical effect Effects 0.000 description 6
- 238000010583 slow cooling Methods 0.000 description 6
- 230000008901 benefit Effects 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000010791 quenching Methods 0.000 description 3
- 229910052711 selenium Inorganic materials 0.000 description 3
- 239000011669 selenium Substances 0.000 description 3
- 238000004544 sputter deposition Methods 0.000 description 3
- 238000007740 vapor deposition Methods 0.000 description 3
- WUPHOULIZUERAE-UHFFFAOYSA-N 3-(oxolan-2-yl)propanoic acid Chemical compound OC(=O)CCC1CCCO1 WUPHOULIZUERAE-UHFFFAOYSA-N 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229910052980 cadmium sulfide Inorganic materials 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 238000005352 clarification Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- HVMJUDPAXRRVQO-UHFFFAOYSA-N copper indium Chemical compound [Cu].[In] HVMJUDPAXRRVQO-UHFFFAOYSA-N 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- ZZEMEJKDTZOXOI-UHFFFAOYSA-N digallium;selenium(2-) Chemical compound [Ga+3].[Ga+3].[Se-2].[Se-2].[Se-2] ZZEMEJKDTZOXOI-UHFFFAOYSA-N 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000005346 heat strengthened glass Substances 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- -1 small molecule compounds Chemical class 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 230000003313 weakening effect Effects 0.000 description 2
- MARUHZGHZWCEQU-UHFFFAOYSA-N 5-phenyl-2h-tetrazole Chemical compound C1=CC=CC=C1C1=NNN=N1 MARUHZGHZWCEQU-UHFFFAOYSA-N 0.000 description 1
- JBRZTFJDHDCESZ-UHFFFAOYSA-N AsGa Chemical compound [As]#[Ga] JBRZTFJDHDCESZ-UHFFFAOYSA-N 0.000 description 1
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical compound C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 229910001218 Gallium arsenide Inorganic materials 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- KTSFMFGEAAANTF-UHFFFAOYSA-N [Cu].[Se].[Se].[In] Chemical compound [Cu].[Se].[Se].[In] KTSFMFGEAAANTF-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 238000001994 activation Methods 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000005354 aluminosilicate glass Substances 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000005388 borosilicate glass Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- DVRDHUBQLOKMHZ-UHFFFAOYSA-N chalcopyrite Chemical compound [S-2].[S-2].[Fe+2].[Cu+2] DVRDHUBQLOKMHZ-UHFFFAOYSA-N 0.000 description 1
- 229910052951 chalcopyrite Inorganic materials 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- JAONJTDQXUSBGG-UHFFFAOYSA-N dialuminum;dizinc;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Al+3].[Zn+2].[Zn+2] JAONJTDQXUSBGG-UHFFFAOYSA-N 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 229910003472 fullerene Inorganic materials 0.000 description 1
- 238000005338 heat storage Methods 0.000 description 1
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical compound [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000001755 magnetron sputter deposition Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 238000005240 physical vapour deposition Methods 0.000 description 1
- 229920000553 poly(phenylenevinylene) Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 239000003566 sealing material Substances 0.000 description 1
- 125000003748 selenium group Chemical group *[Se]* 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000007751 thermal spraying Methods 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
- C03C3/085—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal
- C03C3/087—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal containing calcium oxide, e.g. common sheet or container glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B18/00—Shaping glass in contact with the surface of a liquid
- C03B18/02—Forming sheets
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
- C03C27/06—Joining glass to glass by processes other than fusing
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/0092—Compositions for glass with special properties for glass with improved high visible transmittance, e.g. extra-clear glass
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/02—Details
- H01L31/0216—Coatings
- H01L31/02161—Coatings for devices characterised by at least one potential jump barrier or surface barrier
- H01L31/02167—Coatings for devices characterised by at least one potential jump barrier or surface barrier for solar cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
- H01L31/0488—Double glass encapsulation, e.g. photovoltaic cells arranged between front and rear glass sheets
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/90—Other aspects of coatings
- C03C2217/94—Transparent conductive oxide layers [TCO] being part of a multilayer coating
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24S—SOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
- F24S80/00—Details, accessories or component parts of solar heat collectors not provided for in groups F24S10/00-F24S70/00
- F24S80/50—Elements for transmitting incoming solar rays and preventing outgoing heat radiation; Transparent coverings
- F24S80/52—Elements for transmitting incoming solar rays and preventing outgoing heat radiation; Transparent coverings characterised by the material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49826—Assembling or joining
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- Geochemistry & Mineralogy (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Computer Hardware Design (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
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- General Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Ceramic Engineering (AREA)
- Glass Compositions (AREA)
- Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)
- Surface Treatment Of Glass (AREA)
Abstract
【選択図】図1
Description
Claims (38)
- 67〜75重量%のSiO2と、
13重量%超のCaO+MgOと、
10〜14.5重量%のNa2Oとを含み、
約554℃よりも高い徐冷点を示すソーダ石灰シリカ系ガラス。 - 前記CaO+MgOは、
8.2〜10.5重量%のCaOと、
3.5〜6.0重量%のMgOとを含む、請求項1に記載のソーダ石灰シリカ系ガラス。 - 約600℃未満の徐冷点を示す、請求項1に記載のソーダ石灰シリカ系ガラス。
- 約554〜約585℃の徐冷点を示す、請求項3に記載のソーダ石灰シリカ系ガラス。
- 88%を超える太陽光透過率を示す、請求項1に記載のソーダ石灰シリカ系ガラス。
- 前記CaO+MgOは約13.5〜約15.8重量%である、請求項1に記載のソーダ石灰シリカ系ガラス。
- Zr、Li、Sr、Ba、Sb、B、P、GeおよびCeのうちの1種類以上を実質的に含まない、請求項1に記載のソーダ石灰シリカ系ガラス。
- 前記SiO2は70〜75重量%であり、前記CaOは9〜10.65重量%であり、前記MgOは4.4〜5.85重量%であり、前記Na2Oは10.9〜13.6重量%である、請求項1に記載のソーダ石灰シリカ系ガラス。
- 前記ガラスは、第1の主要面と第2の主要面を有する平坦なシートであり、前記平坦なシートの前記第1の主要面および前記第2の主要面の少なくとも一方の上に堆積された透明な導電性酸化物コーティングをさらに備える、請求項1に記載のソーダ石灰シリカ系ガラス。
- 140ポンド/平方インチ(psi)を超える表面圧縮応力を示す、請求項9に記載のソーダ石灰シリカ系ガラス。
- 約260〜約380psiの表面圧縮応力を示す、請求項10に記載のソーダ石灰シリカ系ガラス。
- 10,000psiを超える表面圧縮応力を示す、請求項9に記載のソーダ石灰シリカ系ガラス。
- 67〜75重量%のSiO2と、
13重量%超のCaO+MgOと、
10〜14.5重量%のNa2Oとを含む平坦なソーダ石灰シリカ系ガラス基板を備え、
前記平坦なガラス基板が約554℃よりも高い徐冷点を示す、ガラス系ソーラー・パネル。 - 前記CaO+MgOは、
8.2〜10.5重量%のCaOと、
3.5〜6.0重量%のMgOとを含む、請求項13に記載のガラス系ソーラー・パネル。 - 前記平坦なガラス基板は約600℃未満の徐冷点を示す、請求項13に記載のガラス系ソーラー・パネル。
- 前記平坦なガラス基板は88%を超える太陽光透過率を示す、請求項13に記載のガラス系ソーラー・パネル。
- 前記CaO+MgOは約13.5〜約15.8重量%である、請求項13に記載のガラス系ソーラー・パネル。
- 前記平坦なガラス基板は、Zr、Li、Sr、Ba、Sb、B、P、GeおよびCeのうちの1種類以上を実質的に含まない、請求項13に記載のガラス系ソーラー・パネル。
- 前記SiO2は70〜75重量%であり、前記CaOは9〜10.65重量%であり、前記MgOは4.4〜5.85重量%であり、前記Na2Oは10.9〜13.6重量%である、請求項13に記載のガラス系ソーラー・パネル。
- 前記平坦なガラス基板は、第1の主要面と第2の主要面を有する平坦なシートであり、前記平坦なシートの前記第1の主要面および前記第2の主要面の少なくとも一方の上に堆積された透明な導電性酸化物コーティングをさらに備える、請求項13に記載のガラス系ソーラー・パネル。
- 前記平坦なガラス基板は、140ポンド/平方インチ(psi)を超える表面圧縮応力を示す、請求項20に記載のガラス系ソーラー・パネル。
- 前記平坦なガラス基板が、10,000psiを超える表面圧縮応力を示す、請求項20に記載のガラス系ソーラー・パネル。
- 前記平坦なガラス基板は、第1の平坦なガラス基板を備え、さらに第2の平坦なガラス基板を備え、
前記第1の平坦なガラス基板は、前記第2の平坦なガラス基板に気密に取り付けられ、前記第1の平坦なガラス基板の上に堆積された前記透明な導電性酸化物コーティングを閉じ込める、請求項20に記載のガラス系ソーラー・パネル。 - 前記第1の平坦なガラス基板は、前記第2の平坦なガラス基板から約0.09インチ未満の距離だけ離れている、請求項23に記載のガラス系ソーラー・パネル。
- ガラス形成成分を炉の中で溶融させるステップと、
溶融した前記ガラス形成成分を堆積させて、ソーダ石灰シリカ系ガラスの平坦なシートを形成するステップを含み、
前記平坦なシートは、以下の成分:
67〜75重量%のSiO2と、
13重量%超のCaO+MgOと、
10〜14.5重量%のNa2Oとを含み、
前記平坦なシートは約554℃よりも高い徐冷点を示す、方法。 - 前記ガラス形成成分を溶融させる前記ステップが、前記ガラス形成成分をフロート・ガラス・ラインの装填口に加える操作を含み、
前記溶融したガラス形成成分を堆積させる前記ステップが、前記フロート・ガラス・ラインのフロート浴の上にガラス・リボンを堆積させる工程を含み、
前記ガラス・リボンが前記炉を出て前記フロート浴に入るときに、前記ガラス・リボンは約1,050〜約1,150℃の温度を有する、請求項25に記載の方法。 - 前記CaO+MgOは、
8.2〜10.5重量%のCaOと、
3.5〜6.0重量%のMgOとを含む、請求項25に記載の方法。 - 前記平坦なシートは約600℃未満の徐冷点を示す、請求項25に記載の方法。
- 前記平坦なシートは88%を超える太陽光透過率を示す、請求項25に記載の方法。
- 前記CaO+MgOは約13.5〜約15.8重量%である、請求項25に記載の方法。
- 前記平坦なシートは、Zr、Li、Sr、Ba、Sb、B、P、GeおよびCeのうちの1種類以上を実質的に含まない、請求項25に記載の方法。
- 前記SiO2は70〜75重量%であり、前記CaOは9〜10.65重量%であり、前記MgOは4.4〜5.85重量%であり、前記Na2Oは10.9〜13.6重量%である、請求項25に記載の方法。
- 前記溶融したガラス形成成分を堆積させる前記ステップは、前記ソーダ石灰シリカ系ガラスの前記平坦なシートが焼なましおよび焼き戻しの少なくとも一方が行われるように、前記溶融したガラス形成成分を冷却する工程を含む、請求項25に記載の方法。
- 前記溶融したガラス形成成分を冷却した後、被覆プロセスにおいて約1〜約3分間にわたって約700〜約800℃の温度に前記平坦なシートを曝すステップをさらに含む、請求項33に記載の方法。
- 被覆プロセスにおいて約700〜約800℃の温度に前記平坦なシートを曝す前記ステップは、前記平坦なシートの上に透明な導電性酸化物を堆積させる工程を含む、請求項34に記載の方法。
- 前記平坦なシートを高温処理ステップに曝すステップをさらに含み、
前記平坦なシートは、その高温処理ステップに曝される前にその平坦なシートが示す値の90%を超える値の中心部張力および/または表面圧縮応力を示す、請求項25に記載の方法。 - 前記高温処理ステップが、前記平坦なシートを少なくとも約1分間にわたって500〜約900℃の温度に曝す工程を含む、請求項36に記載の方法。
- 前記高温処理ステップが被覆操作を含む、請求項37に記載の方法。
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