JP2013257359A - Antidazzle hard coat film - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide an antidazzle hard coat film, which has high transmittance, a low haze value, excellent transparency and high image sharpness, suppresses glare of an image, reduces whiteness (white blur) of a coating film, suppresses decrease in contrast and improves visibility of a display, compared to a conventional antidazzle film, without imparting an excessive antidazzle property than a required degree to the film, and which is also excellent in an antifouling property and scratch resistance.SOLUTION: An antidazzle hard coat film includes an antidazzle hard coat layer containing fine particles, a resin and a fluorine-containing polymerizable compound, formed on a transparent film. The antidazzle hard coat film has a maximum cross-sectional height of 1.0 to 3.0 μm and an average inclination angle of 1 degree or less on the film surface, and shows a transmissive sharpness of 70% or more in each measurement using four types of optical combs (with widths of 2 mm, 1 mm, 0.5 mm and 0.125 mm).

Description

  The present invention relates to an antiglare hard coat film suitable for preventing a reduction in visibility used on the surface of various displays represented by liquid crystal displays, plasma displays, and organic EL displays.

  In order to prevent reflection of outside scenes on the display surface of notebook PCs, LCD monitors, etc., usually a mixture of organic or inorganic fine particles and a binder resin or curable resin is applied to the substrate to form irregularities on the surface. As a result, antiglare properties are exhibited. In order to improve the antiglare property, it is necessary to increase the uneven shape or increase the frequency of the unevenness. However, if the irregularities are large or the frequency increases, the haze value (degree) of the anti-glare layer increases and anti-glare properties can be obtained, but the screen is blurred due to the reflection of external light, or the haze value increases. As a result, there has been a problem that the image definition is lowered and the visibility of the display image is deteriorated. Furthermore, when the haze value of the surface, which is a general evaluation of conventional anti-glare hard coat films, is lowered, the degree of white blurring due to the reflection of external light can be suppressed, but so-called scintillation (glare, As a technique to eliminate this, a method of increasing the haze value inside the antiglare layer was used, but due to the internal haze caused by the difference in refractive index between the fine particles and the resin The transmittance was lowered, the display brightness of the display device was lowered, and at the same time, the coating film became whitish due to the internal haze, so that the contrast was greatly lowered.

  For example, in Japanese Patent Application Laid-Open No. 11-326608 (Patent Document 1), the average particle diameter is 0.5 to 5.0 μm, and the difference in refractive index from the transparent resin is 0.02 to 0.20. An antiglare film containing translucent fine particles is disclosed. By setting the difference in refractive index between the translucent resin constituting the antiglare layer and the translucent fine particles contained therein to 0.02 to 0.20, an image can be obtained without reducing diffusion and antiglare properties. In this case, the image definition can be maintained high even if the haze value is increased to reduce glare. However, the haze of the film specifically obtained is as high as 10% or more and has an antiglare property, while the coating film becomes whitish and the transmittance and contrast are remarkably reduced.

  Japanese Patent Application Laid-Open No. 2008-286878 (Patent Document 2) discloses that, in an antiglare film, the difference in refractive index between a cured binder and a light-transmitting fine particle is as small as 0 to 0.05. Therefore, the light transmittance in the antiglare hard coat layer can be improved, and the arithmetic average roughness (Ra) measured in accordance with JIS B 0601-1994 on the surface of the antiglare hard coat layer. Is suppressed to a small range of 0.01 to 0.30 μm and the average interval of unevenness (Sm) of 10 to 300 μm, while diffusing light on the surface (outer surface) of the antiglare hard coat layer, Light transmittance can be maintained, and the anti-glare film is said to be able to exhibit a good balance between suppression of glare and improvement of transmission clarity. However, the arithmetic average roughness (Ra) is 0.01 to 0.30 μm and the average interval of unevenness (Sm) is not so small as 10 to 300 μm, and most of the antiglare films currently on the market are Applicable to the range. In addition, the film obtained specifically has an arithmetic average roughness (Ra) of 0.1 μm or more, an image sharpness value measured through an optical comb having a width of 2 mm is less than 70%, and 60 ° reflection. When the measured image sharpness value is 60% or less, the antiglare property is not sufficient, but glare prevention on the high-definition panel is insufficient, and the whiteness of the coating film is not taken into consideration. The problem remains that the contrast is significantly reduced.

JP 11-326608 A JP 2008-286878 A

  In the conventional technology, considering the antiglare property, the haze value is increased from the viewpoint of preventing glare, and the image clarity cannot be sufficiently increased, so the low transmittance and the whitishness of the coating are eliminated. If the image is not formed and the image is displayed, the screen becomes whitish, and there is a problem that the image quality is deteriorated particularly in the black display.

  Therefore, the object of the present invention is to provide a high transmittance, a low haze value, excellent transparency, and image clarity, without imparting an antiglare property more than necessary, compared to such a conventional antiglare film. High, suppresses glare in the image, reduces the whitishness of the paint film, suppresses contrast deterioration, improves the visibility of the display, and is for surface protection with excellent antifouling and scratch resistance. It is providing an anti-glare hard coat film.

The present invention provides the following [1] to [3].
[1] An antiglare hard coat film in which an antiglare hard coat layer containing fine particles, a resin and a fluorine-containing polymerizable compound is provided on a transparent film, wherein the antiglare hard coat film is within the evaluation region on the surface of the antiglare hard coat film The maximum cross-sectional height expressed by the difference between the maximum height value in the evaluation region and the minimum height value in the evaluation region when the average value of the heights is zero (zero) is 1.0 to 3.0 μm. In addition, the average inclination angle of the unevenness on the surface of the antiglare hard coat film is 1 degree or less, and the optical clarity is measured using a transmission sharpness measuring device based on JIS K 7105-1981 of the antiglare hard coat film. An anti-glare hard coat film characterized by having a transmission sharpness value measured through a comb (width 2 mm, 1 mm, 0.5 mm, 0.125 mm) of 70% or more.
[2] The antiglare hard coat film according to [1], wherein the fluorine-containing polymerizable compound has a fluorine fluoroaliphatic group and a hydrophilic group.
[3] The content of the fluorine-containing polymerizable compound is 0.1 to 1.0 part by weight (solid content) with respect to 100 parts by weight of the resin in the hard coat layer. [2] The antiglare hard coat film according to [2].

  According to the present invention, the transmittance is high, the haze value is low, the transparency is excellent, the image clarity is high, and the image is not glaring, as compared with the conventional antiglare film. , Anti-glare hard coat for surface protection with excellent antifouling and scratch resistance as well as improving the visibility of the display by reducing the whitishness of the paint film A film can be provided. That is, according to the antiglare hard coat film of the present invention, the antiglare property is excellent in antifouling property and scratch resistance, and the antiglare property has a practically no problem level without reducing the whiteness of the coating film and reducing the contrast. High transmittance, high image definition, and image glare can be suppressed, and the visibility of the display can be improved.

  Hereinafter, embodiments of the present invention will be described in detail.

  The antiglare hard coat film of the present invention is an antiglare hard coat film in which an antiglare hard coat layer containing fine particles, a resin and a fluorine-containing polymerizable compound is provided on a transparent film, the antiglare hard coat The maximum cross-sectional height represented by the difference between the maximum height in the evaluation area and the minimum height in the evaluation area when the average value of the height in the evaluation area on the surface of the film is zero. It is 1.0-3.0 micrometers, and the average inclination | tilt angle of the unevenness | corrugation on this anti-glare hard coat film surface is 1 degree or less, It is characterized by the above-mentioned.

Here, “maximum cross-sectional height” is as defined above, but as defined in JIS B0601, it is a value calculated from the cross-sectional curve (measurement curve) of the film surface that is the object of measurement. is there. The surface of the antiglare hard coat film provided with the antiglare hard coat layer containing the fine particles and the resin as in the present invention has not only fine irregular shapes but also undulations. A measurement curve (usually called a cross-section curve) measured with a surface roughness measuring machine is between a waviness curve and a roughness curve.
There is a relationship of cross-sectional curve = waviness curve + roughness curve. Therefore, the “maximum cross-sectional height” in the present invention evaluates a cross-sectional curve including a “surface waviness component”. In the 2001 version of JIS, the maximum cross-sectional height is represented by the symbol “Pt”.

In addition, the above “average inclination angle” refers to the slope of a line segment that divides a cross-sectional curve (measurement curve) of the film surface to be measured at a constant interval ΔX and connects the start points of the cross-sectional curves in each section. (Inclination angle: The inclination angle is obtained by calculating the absolute value of tan ⁻¹ (determined by ΔYi / ΔX) and averaging the values (θa) (see FIG. 1), that is, the average inclination angle (θa ) Is a value defined by the following formula.

According to such an anti-glare hard coat film of the present invention, the reason why the haze value is low, the transmittance is high, and the transparency is excellent is presumed as follows according to the study of the present inventors.

  The haze value of the antiglare hard coat film is attributed to the surface haze generated when light is refracted and scattered due to the irregularities on the surface of the antiglare hard coat layer and the presence of fine particles in the antiglare hard coat layer. There is an internal haze generated by light being refracted and scattered, and the maximum height in the evaluation area when the average height in the evaluation area on the surface of the antiglare hard coat film is zero. And the maximum cross-sectional height represented by the difference between the height in the evaluation region is 1.0 to 3.0 μm, and the average inclination angle of the irregularities on the surface of the antiglare hard coat film is 1 degree or less. The surface properties such as the undulation of the specific region or the gentle (gradual) surface unevenness can be obtained, and the refraction and scattering of the light caused by the surface unevenness can be suppressed, so that the surface haze is hardly expressed and the light Reduces light loss due to refraction and scattering With the decrease in transmittance can be suppressed since the by scattered light in the antiglare hard coat layer surface is considered that excellent transparency since the antiglare hard coat film is suppressed phenomenon turbid whitish.

  In addition, when the above-mentioned maximum cross-sectional height of the surface of the antiglare hard coat film exceeds 3.0 μm, the refraction and scattering of light due to the unevenness of the surface becomes strong, so that surface haze is easily developed, and the refraction and scattering of light. There is a concern about the decrease in transmittance due to the loss of light due to light, and it is easy to obtain antiglare properties due to scattered light on the surface of the antiglare hard coat layer, but it is difficult to suppress the phenomenon that the antiglare hard coat film becomes whitish and cloudy. For this reason, transparency and transmission clarity are liable to decrease.

  Further, the lower limit of the maximum cross-sectional height is not particularly limited, but when the maximum cross-sectional height is less than 1.0 μm, the unevenness of the film surface becomes too small, and thus the scattered light on the surface of the antiglare hard coat layer. It becomes difficult to obtain the antiglare property due to.

  Further, when the average inclination angle is larger than 1 degree (more than 1 degree), refraction and scattering of light due to surface unevenness is enhanced, so that surface haze is easily developed, and light loss due to refraction and scattering of light. As a result, there is concern about a decrease in transmittance, and it is easy to obtain antiglare properties due to scattered light on the surface of the antiglare hard coat layer, but it is difficult to suppress the phenomenon that the antiglare hard coat film becomes whitish and turbid. In addition, there is a problem that transmission clarity tends to decrease.

  Therefore, in the present invention, the maximum cross-sectional height of the surface of the antiglare hard coat film is preferably 1.0 μm or more and 3.0 μm or less, and more preferably the maximum cross-sectional height is 1.2 μm or more and 2 or less. .5 μm or less.

  The average inclination angle of the surface of the antiglare hard coat film is preferably 1 degree or less, more preferably the average inclination angle is 0.9 degree, and further preferably the average inclination angle is 0.7 degree. Less than or equal to degrees. Although there is no restriction | limiting in particular about the lower limit of the said average inclination angle, From a glare-proof viewpoint, it is preferable that it is 0.1 degree or more.

In the present invention, the “evaluation region” is a measurement region.
Moreover, in the anti-glare hard coat film of the present invention, it is measured through four optical combs (width 2 mm, 1 mm, 0.5 mm, 0.125 mm) using a transmission sharpness measuring device based on JIS K 7105-1981. The total value of the transmission definition is 280% or more, and the transmission definition value measured through each optical comb is 70% or more, so that the image definition is high and the whiteness of the coating film (white) It is possible to reduce blur and suppress a decrease in contrast and improve the visibility of the display.

  The transparent film that can be used in the present invention is not particularly limited. For example, a polyethylene terephthalate film (PET; refractive index 1.665), a polycarbonate film (PC; refractive index 1.582), a triacetyl cellulose film (TAC) ; Refractive index 1.485), norbornene film (NB; refractive index 1.525) can be used, and the film thickness is not particularly limited, but about 25 μm to 250 μm is generally used. Since the refractive index of a general ionizing radiation curable resin is about 1.52, a TAC film or NB film close to the refractive index of the resin is preferable in order to increase the visibility. A PET film is preferred.

  The resin used in the present invention can be used without particular limitation as long as it is a resin that forms a film. In particular, it imparts hard properties (pencil hardness, scratch resistance) to the surface of the antiglare hard coat layer, and also provides antiglare hard. An ionizing radiation curable resin is preferred in that a large amount of heat is not required when forming the coat layer.

  The ionizing radiation curable resin is not particularly limited as long as it is a transparent resin that is cured by irradiation with an electron beam or ultraviolet rays. For example, a urethane acrylate resin, a polyester acrylate resin, and an epoxy acrylate resin It can select suitably from resin etc. Preferred examples of the ionizing radiation curable resin include those composed of an ultraviolet curable polyfunctional acrylate having two or more (meth) acryloyl groups in the molecule. Specific examples of the UV curable polyfunctional acrylate having two or more (meth) acryloyl groups in the molecule include neopentyl glycol di (meth) acrylate, 1,6-hexanediol di (meth) acrylate, and trimethylol. Polyol polyacrylates such as propane tri (meth) acrylate, ditrimethylolpropane tetra (meth) acrylate, pentaerythritol tetra (meth) acrylate, pentaerythritol tri (meth) acrylate, dipentaerythritol hexa (meth) acrylate, bisphenol A diglycidyl Epoxys such as diacrylate of ether, diacrylate of neopentyl glycol diglycidyl ether, di (meth) acrylate of 1,6-hexanediol diglycidyl ether ( A) Polyester (meth) acrylate, polyhydric alcohol, polyisocyanate and hydroxyl group-containing (meta) which can be obtained by esterifying acrylate, polyhydric alcohol and polyhydric carboxylic acid and / or anhydride and acrylic acid ) Urethane (meth) acrylate obtained by reacting acrylate, polysiloxane poly (meth) acrylate, and the like.

  The ultraviolet curable polyfunctional acrylate may be used alone or in combination of two or more, and the content thereof is preferably 50 to 95% by weight with respect to the resin solid content of the antiglare hard coat layer coating material. is there. In addition to the polyfunctional (meth) acrylate, preferably 10% by weight or less of 2-hydroxy (meth) acrylate, 2-hydroxypropyl (meth) based on the resin solid content of the antiglare hard coat layer coating. ) Monofunctional acrylates such as acrylate and glycidyl (meth) acrylate can also be added.

In addition, a polymerizable oligomer used for the purpose of adjusting the hardness can be added to the antiglare hard coat layer. Examples of such oligomers include terminal (meth) acrylate polymethyl (meth) acrylate, terminal styryl poly (meth) acrylate, terminal (meth) acrylate polystyrene, terminal (meth) acrylate polyethylene glycol, terminal (meth) acrylate acrylonitrile-styrene copolymer. Macromonomers such as polymers and terminal (meth) acrylate styrene-methyl methacrylate copolymers can be mentioned, and the content thereof is preferably 5 to 50 weights based on the resin solid content in the antiglare hard coat coating material. %.
The material for forming the fine particles used in the present invention is not particularly limited. For example, silica (refractive index 1.420 to 1.460), vinyl chloride resin (refractive index 1.530), acrylic resin (refractive index 1.. 490), (meth) acrylic resin (refractive index 1.520 to 1.530), polystyrene resin (refractive index 1.590), melamine resin (refractive index 1.650), polyethylene resin, polycarbonate resin, acrylic-styrene copolymer. Resin (refractive index 1.490-1.590) etc. can be mentioned, A microparticle may be used independently or it is also possible to use 2 or more types together. Further, the refractive index of the fine particles is not limited, but in order to further obtain the effects of the present invention, the fine particles have a refractive index difference of 0.001 with respect to the refractive index of the resin used for the antiglare hard coat layer. It is preferable to use fine particles having a refractive index of ˜0.200, and it is more preferable to use fine particles having a refractive index difference of 0.001 to 0.100.

  In the present invention, the coating thickness of the antiglare hard coat layer is preferably 0.5 to 1.5 times the average particle size of the fine particles constituting the antiglare hard coat layer, more preferably 0. .8 to 1.2 times. The average particle size of the fine particles is preferably 1.0 to 4.0 μm, and the average particle size of the fine particles is more preferably 3.0 to 4.0 μm in order to impart high pencil hardness.

When the coating film thickness is less than 0.5 times the average particle size of the fine particles constituting the antiglare hard coat layer, the fine particles are not fixed in the coating film, and the hardness of the coating film surface is remarkably deteriorated.
On the other hand, when the coating thickness exceeds 1.5 times the average particle size of the fine particles constituting the antiglare hard coat layer, no antiglare property can be obtained. The average particle diameter of the fine particles can be measured by, for example, a laser diffraction scattering method.

  Further, when the average particle size of the fine particles is 4 μm or more, the antiglare is more than necessary when the coating thickness of the antiglare hard coat layer is set to 0.5 to 1.5 times the average particle size of the fine particles. And the scattering of external light on the surface of the coating film becomes large, and the surface becomes whitish due to the scattering of light, and the visibility of the display is remarkably lowered. On the other hand, when the average particle size of the fine particles is smaller than 1.0 μm, the coating film thickness must be reduced, so that the hard property is lacking.

  In the present invention, the fine particles are preferably blended in the antiglare hard coat layer in an amount of 0.05 to 3 parts by weight, more preferably 0.075 to 1 part by weight based on 100 parts by weight of the resin. Preferably, 0.1 to 0.5 part by weight is blended.

When the amount of fine particles is less than 0.05 parts by weight with respect to 100 parts by weight of the resin, the coating thickness of the antiglare hard coat layer is 0.5 to 1.5 times the average particle size of the fine particles. When set, no antiglare property is obtained. Moreover, when the compounding quantity of microparticles exceeds 3 weight part with respect to 100 weight part of said resin, a haze value will become high and the transmittance | permeability and contrast will fall.
In the present invention, the fluorine-containing polymerizable compound is a polymerizable fluorine-based surfactant or fluorine-based surface modifier having an unsaturated group, and these polymerized fluorine-based surfactant or fluorine-based surface modifier. Preferably has a fluoroaliphatic group and a hydrophilic group, and more preferably has a perfluoroalkylene ether chain from the viewpoint of antifouling properties.

  Leveling agents, antifouling agents (excluding fluorine-containing polymerizable resins), antifoaming agents, lubricants, ultraviolet absorbers, light stabilizers, polymerization inhibitors, wetting and dispersing agents, and rheology control as long as the effects of the present invention are not changed. An agent, an antioxidant, an antistatic agent, a conductive agent and the like may be contained as necessary.

  Therefore, as described above, the antiglare hard coat film of the present invention is an antiglare hard coat film in which an antiglare hard coat layer containing fine particles, a resin and a fluorine-containing polymerizable compound is provided on a transparent film, Expressed by the difference between the maximum height in the evaluation area and the minimum height in the evaluation area when the average height in the evaluation area on the surface of the antiglare hard coat film is zero. The maximum cross-sectional height is 1.0 to 3.0 μm, the average inclination angle of the irregularities on the surface of the antiglare hard coat film is 1 degree or less, and a transmission sharpness measuring device based on JIS K 7105-1981 is used. The total value of transmitted sharpness measured through four optical combs (width 2 mm, 1 mm, 0.5 mm, 0.125 mm) is 280% or more, and the transmitted sharpness values measured through each optical comb are each 7 In this case, the fine particles have an average particle size of 1.0 to 4.0 μm, and the coating thickness of the antiglare hard coat layer is 0. 0 of the average particle size of the fine particles. It is preferable that the compounding amount of the fine particles is 0.05 to 3 parts by weight with respect to 100 parts by weight of the resin. The haze value of the antiglare hard coat film is preferably 0.1 to 5.0%, more preferably the haze value is 0.1 to 3.5%, and still more preferably the haze value is 0. 0.1-2.0%. Furthermore, it is preferable that the compounding quantity of the said fluorine-containing polymeric compound is 0.1-10 weight part (solid content conversion) with respect to 100 weight part of said resin.

  The antiglare hard coat layer can be formed by applying and drying a paint obtained by dissolving and dispersing the resin and fine particles in a solvent on a transparent film. The solvent can be appropriately selected depending on the solubility of the resin, and may be any solvent that can uniformly dissolve or disperse at least solids (resin, fine particles, catalyst, curing agent, and other additives). Examples of such solvents include ketones (acetone, methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone, etc.), ethers (dioxane, tetrahydrofuran, etc.), aliphatic hydrocarbons (hexane, etc.), alicyclic hydrocarbons ( Cyclohexane, etc.), aromatic hydrocarbons (toluene, xylene, etc.), halogenated carbons (dichloromethane, dichloroethane, etc.), esters (methyl acetate, ethyl acetate, butyl acetate, etc.), alcohols (methanol, ethanol, isopropanol, Butanol, cyclohexanol, etc.), cellosolves (methyl cellosolve, ethyl cellosolve, etc.), cellosolve acetates, sulfoxides, amides and the like. Further, the solvents may be used alone or in combination.

  The coating method of the anti-glare hard coat layer is not particularly limited, but the coating thickness can be adjusted by gravure coating, micro gravure coating, bar coating, slide die coating, slot die coating, dip coating, etc. Coating is possible with an easy method. The film thickness of the coated antiglare hard coat layer can be measured by observing a cross-sectional photograph of the antiglare film with a microscope or the like and actually measuring from the coating film interface to the surface.

  In the antiglare hard coat film of the present invention, the 60 ° specular gloss is preferably 70% or more and 95% or less, and the 20 ° specular gloss is preferably 30% or more and 90% or less. The transmittance (transmission Y value) is preferably 92.00 or more.

  In the antiglare hard coat film of the present invention, a functional layer such as an antireflection layer or an antistatic layer can be provided on the transparent film in addition to the antiglare hard coat layer containing fine particles and a resin. is there. However, by providing such a functional layer, surface undulations may be canceled and the desired anti-glare property may not be obtained, so a functional layer is provided on the anti-glare hard coat layer containing fine particles. In this case, the thickness of the functional layer is desirably 0.5 μm or less.

  It is also possible to provide a functional layer under the antiglare hard coat layer. Examples of the functional layer include a refractive index control layer for improving the antireflection function, an easy adhesion layer for obtaining adhesion between the base material and the antiglare hard coat layer, and an antistatic layer.

  Further, in the antiglare hard coat film of the present invention, in addition to the antiglare hard coat layer containing fine particles and a resin, a functional layer such as an antireflection layer or an antistatic layer is contained on the transparent film. When provided on the antiglare hard coat layer, when the coating thickness of the antiglare hard coat layer is set below the average particle size of the fine particles constituting the antiglare hard coat layer, it functions as an antiglare hard coat layer. The total coating thickness of the layers needs to be 0.5 to 1.5 times the average particle size of the fine particles constituting the antiglare hard coat layer.

  In addition, when the antiglare hard coat film of the present invention is provided with a functional layer such as an antireflection layer or an antistatic layer on the antiglare hard coat layer containing the fine particles and the resin on the transparent film, The maximum height in the evaluation area and the minimum height in the evaluation area when the average height in the evaluation area of the surface of the antiglare hard coat film, that is, the surface of the functional layer is zero. It is necessary that the maximum cross-sectional height represented by the difference between the thickness of the functional layer is 1.0 to 3.0 μm and the average inclination angle of the irregularities on the surface of the functional layer is 1 degree or less.

  The following examples illustrate the invention, but are not intended to limit the invention. The average particle size of the fine particles was measured with a laser diffraction particle size analyzer SALD2200 (manufactured by Shimadzu Corporation). The thickness of the coating film was measured by observing the cross section with a scanning electron microscope manufactured by Keyence Corporation. Unless otherwise specified, “parts” and “%” described below represent “parts by weight” and “% by weight”, respectively.

[Example 1]
<Preparation of paint>
0.17 g of acrylic-styrene copolymer particles (manufactured by Sekisui Plastics Co., Ltd., average particle size 4.0 μm, refractive index: 1.525) was added to 45.00 g of butyl acetate and sufficiently stirred. 50.83 g of acrylic ultraviolet curable resin (manufactured by Nippon Synthetic Chemical Industry Co., Ltd., refractive index: 1.52) and Irgacure 184 (photopolymerization initiator, manufactured by Ciba Specialty Chemical Co., Ltd.) 75 g and 0.50 g of a fluorine-containing polymerizable compound (manufactured by DIC Corporation) were added and sufficiently stirred to prepare a coating material.
<Preparation of antiglare film>
The above-mentioned paint was applied to Fuji TAC (triacetylcellulose film, manufactured by Fuji Film Co., Ltd.) with Meyer bar # 4 (manufactured by RDS), dried at 80 ° C. for 1 minute, and then irradiated with 350 mJ / cm ² ultraviolet light (light source) : UV lamp manufactured by Fusion Japan) and cured. The thickness of the obtained coating film was 3.6 μm.

[Example 2]
<Preparation of paint>
0.17 g of acrylic-styrene copolymer particles (manufactured by Sekisui Plastics Co., Ltd., average particle size 4.0 μm, refractive index: 1.525) was added to 45.00 g of butyl acetate and sufficiently stirred. 51.33 g of an acrylic ultraviolet curable resin (manufactured by Nippon Synthetic Chemical Industry Co., Ltd., refractive index: 1.52) and Irgacure 184 (photopolymerization initiator, manufactured by Ciba Specialty Chemicals Co., Ltd.) 75 g and 0.75 g of a fluorine-containing polymerizable compound (manufactured by DIC Corporation) were added and sufficiently stirred to prepare a coating material.
<Preparation of antiglare film>
An antiglare film was produced in the same manner as in Example 1. The thickness of the obtained coating film was 3.6 μm.

[Example 3]
<Preparation of paint>
0.17 g of acrylic-styrene copolymer particles (manufactured by Sekisui Plastics Co., Ltd., average particle size 4.0 μm, refractive index: 1.525) was added to 45.00 g of butyl acetate and sufficiently stirred. 50.33 g of an acrylic UV curable resin (manufactured by Nippon Synthetic Chemical Industry Co., Ltd., refractive index: 1.52) and Irgacure 184 (photopolymerization initiator, manufactured by Ciba Specialty Chemical Co., Ltd.) 75 g and 1.75 g of a fluorine-containing polymerizable compound (manufactured by DIC Corporation) were added and sufficiently stirred to prepare a coating material.
<Preparation of antiglare film>
An antiglare film was produced in the same manner as in Example 1. The thickness of the obtained coating film was 3.6 μm.

[Comparative Example 1]
<Preparation of paint>
0.17 g of acrylic-styrene copolymer particles (manufactured by Sekisui Plastics Co., Ltd., average particle size 4.0 μm, refractive index: 1.525) was added to 45.00 g of butyl acetate and sufficiently stirred. In this liquid, 52.08 g of an acrylic UV curable resin (manufactured by Nippon Synthetic Chemical Industry Co., Ltd., refractive index: 1.52) and Irgacure 184 (photopolymerization initiator, manufactured by Ciba Specialty Chemicals Co., Ltd.) 75 g was added and stirred well to prepare a paint.
<Preparation of antiglare film>
An antiglare film was produced in the same manner as in Example 1. The thickness of the obtained coating film was 3.6 μm.

  The antiglare hard coat films of Examples and Comparative Examples produced as described above were evaluated for the following items, and the results are summarized in the table below.

(1) Maximum cross-sectional height It was measured using a three-dimensional surface roughness meter “VertScan2.0” manufactured by Ryoka System Co., Ltd. The maximum height value (P) in the evaluation region and the minimum height value (V) in the evaluation region when the average value (Ave) of the height in the evaluation region of the region cross-sectional curve parameter obtained by measurement is zero. ) To determine the maximum cross-sectional height (Pt). The measurement conditions are set as follows.
<Optical conditions>
Camera: SONY HR-50 1/3 type Objective: 10 x (10 times)
Tube: 1 x Body
Relay: No Relay
Filter: 530 white
-Light quantity adjustment: Automatically performed so that the value of Lamp falls within the range of 50-95.
<Measurement conditions>
Mode: Wave
Size: 640 × 480
Range (μm): Start (5), Stop (−10)

(2) Average inclination angle The average inclination angle of the concavo-convex portions on the film surface was measured using a three-dimensional surface roughness meter “VertScan2.0” manufactured by Ryoka System Co., Ltd.

(3) Haze value The haze value was measured using a haze meter “HM150” manufactured by Murakami Color Research Laboratory.

(4) Luminous transmittance (transmission Y value)
Murakami Color Research Laboratory “integrated sphere high-speed spectral transmission measurement system DOT-3” was used, and the measurement was carried out according to JISZ8722.

  Here, the luminous transmittance is obtained from Y = K∫S (λ) y (λ) T (λ) dλ. S (λ): spectral distribution of wavelength 400 to 700 nm, y (λ): color matching function, T (λ): spectral solid angle transmittance, Y: luminous transmittance.

(5) Transmission clarity Measurement was carried out using a Suga Test Instruments Co., Ltd. image clarity measuring device “ICM-1DP”. The measurement was performed using an optical comb having widths of 2 mm, 1 mm, 0.5 mm, and 0.125 mm, and the measured values at each width and the sum thereof were calculated.

(6) Glossiness (20 degrees, 60 degrees)
Using a gloss meter (GM-3D) manufactured by Murakami Color Research Laboratory, apply a black vinyl tape (Nitto Vinyl Tape, PROSELF No. 21 (wide)) to the opposite side of the coating and measure the glossiness at 20 or 60 degrees. did.

(7) Pencil hardness It carried out based on JISK5400 using HEIDON14 by Shinto Scientific.

(8) Glitter Each anti-glare film was layered on a liquid crystal display (LCD) having a resolution of 150 ppi that was displayed in green on the entire surface, and the degree of occurrence of glittering screen was visually evaluated. In addition, a clear type hard coat film which does not generate glare was previously set on the LCD surface. The case where there was no glare and the case where the glare was slight was designated as “◯”, and the case where the glare was large and the visibility deteriorated was designated as “X”.

(9) White bokeh, whitish White bokeh due to reflection of external light is applied with a black vinyl tape (Nitto Vinyl Tape, PROSELF No. 21 (wide)) on the opposite side of the coating as black density using a Macbeth densitometer. It was measured. 2.15 or more is “◯”, 2.10 or more and less than 2.15 is “Δ”, and less than 2.10 is “x”. In addition, the whitishness of the coating film due to transmitted light is that light diffuses in the film due to internal haze when the white fluorescent lamp is viewed through an anti-glare hard coat film with the coated surface facing the observer. The state in which the coating became whitish was visually evaluated. Those with no whiteness and slight whiteness were indicated with “◯”, those with a slight whiteness were indicated with “△”, and those with a white coating film were indicated with “X”.

(10) Anti-glare property The anti-glare property is obtained by reflecting 10 lines drawn at 1 mm width on the coated surface of the anti-glare hard coat film, with the coated surface facing the observer, and through the anti-glare hard coat film. When the line width was viewed, the state in which the line width was blurred and difficult to see due to light scattering was visually evaluated. “◯” indicates that the line width cannot be recognized, and “X” indicates that the line width can be recognized.

(11) Scratch resistance test Using a # 0000 steel wool, it was reciprocated 10 times while applying a load of 1000 gf / cm ² , and the presence or absence of scratches was confirmed.

(12) Antifouling The antifouling property is “◎”, which can be wiped off easily when a line is drawn with a magic on the coated surface of the antiglare hard coat film and the line drawn with the magic is wiped off with a cloth. Was “◯”, those that were difficult to wipe off were “Δ”, and those that could not be wiped were “X”.

  Also, in all of Examples 1 to 3, the average particle diameter of fine particles used in the antiglare hard coat layer, the blending amount thereof, the coating thickness of the antiglare hard coat layer, the haze value of the antiglare hard coat film, and fluorine content The compounding amount of the polymerizable compound is within the desired range of the present invention, and has good image definition, luminous transmittance, glossiness, good scratch resistance and antifouling property, and also has glare, white An anti-glare hard coat film with reduced blur and whitishness was obtained. On the other hand, the average particle diameter of the fine particles used for the antiglare hard coat layer, the blending amount thereof, the coating thickness of the antiglare hard coat layer, and the haze value of the antiglare hard coat film are within the desired ranges of the present invention. However, in Comparative Example 1 containing no fluorine-containing polymerizable compound, no scratch resistance was obtained.

Claims (3)

  An anti-glare hard coat film comprising an anti-glare hard coat layer containing fine particles, a resin and a fluorine-containing polymerizable compound on a transparent film, the height within the evaluation region of the surface of the anti-glare hard coat film And the maximum cross-sectional height represented by the difference between the maximum height value in the evaluation region and the minimum height value in the evaluation region when the average value is zero (zero) is 1.0 to 3.0 μm The optical antiglare hard coat film surface has an average inclination angle of 1 degree or less, and four optical combs (widths) using a transmission sharpness measuring device based on JIS K 7105-1981 of the antiglare hard coat film. An anti-glare hard coat film characterized by having a transmission sharpness value measured through 2 mm, 1 mm, 0.5 mm, and 0.125 mm) of 70% or more. The antiglare hard coat film according to claim 1, wherein the fluorine-containing polymerizable compound has a fluorine fluoroaliphatic group and a hydrophilic group. The antiglare according to claim 1 or 2, wherein the content of the fluorine-containing polymerizable compound is 0.1 to 10 parts by weight (solid content) with respect to 100 parts by weight of the resin in the hard coat layer. Hard coat film.