JP2013210348A - Method for diagnosing deterioration of battery pack and charge/discharge monitoring control system - Google Patents

Method for diagnosing deterioration of battery pack and charge/discharge monitoring control system Download PDF

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JP2013210348A
JP2013210348A JP2012082183A JP2012082183A JP2013210348A JP 2013210348 A JP2013210348 A JP 2013210348A JP 2012082183 A JP2012082183 A JP 2012082183A JP 2012082183 A JP2012082183 A JP 2012082183A JP 2013210348 A JP2013210348 A JP 2013210348A
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JP5783116B2 (en
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Kenji Yamauchi
賢治 山内
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GS Yuasa Corp
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract

PROBLEM TO BE SOLVED: To provide a diagnostic method capable of accurately and quickly detecting deterioration states of constituting single batteries and a battery group in a parallel connection battery pack, and to provide a charge/discharge monitoring control system of the parallel connection battery pack, including the diagnostic method.SOLUTION: In the diagnostic method for diagnosing a deterioration state of a battery pack by using an electric variable measured in each column of single batteries in a battery pack configured by connecting single batteries of N columns in parallel, a discharge current Ior a discharge electric quantity Wto be an electric variable is measured in each column of single batteries connected in parallel, and single batteries in which the discharge current Imeasured in each column of the single batteries or the measured discharge electric quantity Wto an average discharge current Ifound out from the discharge current Ior average electric quantity Wfound out from the discharge electric quantity Wis suited to a predetermined diagnostic condition is diagnosed as a deteriorated state.

Description

本発明は、単電池を並列接続した組電池、複数個の単電池を直列接続した電池群を並列接続した組電池などの並列接続された組電池における寿命を判断する劣化診断方法と、その劣化診断方法を搭載した組電池の充放電監視制御システムに関する。   The present invention relates to a deterioration diagnosis method for determining the life of a battery pack connected in parallel, such as a battery pack connected in parallel with a plurality of battery cells, a battery set connected in parallel to a group of cells connected in series, and the deterioration thereof. The present invention relates to a charge / discharge monitoring control system for an assembled battery equipped with a diagnostic method.

駆動用の電源として電動車両に搭載される鉛蓄電池や非常用電源装置、ロードレベリング装置等に使用される鉛蓄電池は、通常単電池として使用されることは少なく、単電池を複数個組み合わせた組電池の形で供される。
この単電池を複数個組み合せた組電池には、複数個の単電池を直列に接続した組電池、複数個の単電池を並列に接続した組電池、さらに、その両者を組み合わせた、複数個の単電池を直列に接続した電池群を、複数群並列に接続した組電池がある。
Lead storage batteries installed in electric vehicles as power sources for driving, lead storage batteries used in emergency power supply devices, load leveling devices, etc. are rarely used as single cells, and are a combination of multiple single cells. Offered in the form of a battery.
An assembled battery in which a plurality of unit cells are combined includes an assembled battery in which a plurality of unit cells are connected in series, a assembled battery in which a plurality of unit cells are connected in parallel, and a combination of both. There is an assembled battery in which a plurality of battery groups in which single cells are connected in series are connected in parallel.

このような組電池を構成する鉛蓄電池は、充放電を繰り返して使用されるため、その劣化状態を的確に検知、把握し、寿命に達する前に交換できるようにしておくことが、信頼性、稼働効率などの点で重要なものである。   Since the lead storage battery that constitutes such an assembled battery is repeatedly used for charging and discharging, it is necessary to accurately detect and grasp the deterioration state, and to be able to replace it before reaching the end of its life, This is important in terms of operational efficiency.

この組電池の劣化状態検知、把握において、特許文献1に開示されるように、直列接続した鉛蓄電池を放電した時の放電末の端子電圧が予め設定した下限電圧値を下回った時に劣化状態として検知しているものがある。   In the detection and grasping of the deterioration state of the assembled battery, as disclosed in Patent Document 1, when the terminal voltage at the end of discharge when discharging lead-acid batteries connected in series falls below a preset lower limit voltage value, Some are detected.

しかし、並列接続した単電池又は複数個の単電池を直列接続した電池群を並列接続した組電池において、ある一列の単電池若しくは電池群が劣化するとその列の抵抗が大きくなるような劣化形態の場合には、この一列の放電電流が低くなるだけで、放電末にその列の端子電圧が予め設定した下限電圧値を下回らないこともあり、並列接続した単電池又は複数個の単電池を直列接続した電池群においては、列ごとに端子電圧を検出するだけでは劣化診断が困難であるという問題があった。
そこで、並列接続した単電池又は複数個の単電池を直列接続した電池群を並列接続した組電池においても、それを構成する単電池の劣化具合を的確に素早く検知する診断方法が希求されていた。
However, in an assembled battery in which a battery connected in parallel or a battery group in which a plurality of battery cells are connected in series is connected in parallel, when a single cell or battery group in a row deteriorates, the resistance of the row increases. In such a case, the discharge current of this row only becomes low, and the terminal voltage of that row may not fall below the preset lower limit voltage value at the end of discharge, and a single cell or a plurality of single cells connected in parallel may be connected in series. In the connected battery group, there is a problem that deterioration diagnosis is difficult only by detecting the terminal voltage for each column.
Therefore, there has been a demand for a diagnostic method for accurately and quickly detecting deterioration of single cells constituting a single battery connected in parallel or a battery pack in which a plurality of single batteries are connected in series. .

特許4077136号公報Japanese Patent No. 4077136

このような状況に鑑み、本発明は、並列接続した単電池又は複数個の単電池を直列接続した電池群を並列接続した組電池においても、それを構成する単電池、あるいは電池群の劣化具合を的確に素早く検知する診断方法を提供するとともに、この診断方法を組電池に備える組電池の充放電監視制御システムを提供するものである。   In view of such a situation, the present invention also relates to a unit cell or a battery group in which a unit cell or a group of batteries that are connected in parallel is connected to a unit cell that is connected in parallel. In addition to providing a diagnostic method for accurately and quickly detecting battery packs, a battery pack charge / discharge monitoring and control system including the diagnostic method for an assembled battery is provided.

本発明の第1の発明は、単電池をN列並列に接続して構成された組電池における前記単電池の列毎に測定した電気変量を用いた組電池の劣化状態の診断方法であって、並列接続されている単電池の列毎に電気変量である放電電流I 、又は放電電気量W を測定し、前記放電電流I から求めた平均放電電流IAVE、又は放電電気量W から求めた平均放電電気量WAVEに対して、前記単電池の列毎に測定した放電電流I 、又は測定した放電電気量W が、下記診断条件(1)及び(2)の状態になった単電池を劣化状態であると診断することを特徴とする組電池の劣化診断方法である。 A first aspect of the present invention is a method for diagnosing a deterioration state of an assembled battery using an electric variable measured for each row of the cells in an assembled battery configured by connecting the cells in N rows in parallel. The discharge current I d N or the discharge electricity quantity W d N which is an electric variable is measured for each column of the cells connected in parallel, and the average discharge current I AVE obtained from the discharge current I d N or the discharge With respect to the average discharge electricity quantity W AVE determined from the electricity quantity W d N, the discharge current I d N measured for each column of the unit cells or the measured discharge electricity quantity W d N is expressed by the following diagnosis condition (1) And a method for diagnosing deterioration of an assembled battery, characterized in that the unit cell in the state of (2) is diagnosed as being in a deteriorated state.

[診断条件]
(1)前記平均放電電流IAVEと測定した放電電流I の差(IAVE−I )が、予め設定した電流差dIより大きい場合、又は前記平均放電電気量WAVEと測定した放電電気量W の差(WAVE−W )が、予め設定した電気量差dWよりも大きい場合。
(2)前記平均放電電流IAVEと測定した放電電流I の差(IAVE−I )が、前記測定した放電電流から算出した標準偏差σに係数Aを乗じた数より大きい場合、又は、前記平均放電電気量WAVEと測定した放電電気量W の差(WAVE−W )が、前記測定した放電電気量W から算出した標準偏差σに係数Aを乗じた数より大きい場合。
[Diagnostic conditions]
(1) The average discharge difference between the currents I AVE and measured discharge current I d N (I AVE -I d N) is, if the current difference greater than dI d set in advance, or the average discharge electric quantity W AVE and Measurement When the difference (W AVE −W d N ) in the discharged electricity quantity W d N is larger than the preset electricity quantity difference dW d .
(2) the difference between the average discharge current I AVE and measured discharge current I d N (I AVE -I d N) is, than the number obtained by multiplying the coefficient A I standard deviation sigma I calculated from the discharge current and the measured If it is larger, or the difference (W AVE −W d N ) between the average discharge electricity amount W AVE and the measured discharge electricity amount W d N is the standard deviation σ W calculated from the measured discharge electricity amount W d N When larger than the number multiplied by the coefficient A W.

本発明の第2の発明は、複数個の単電池を直列接続して構成される電池群を、N列並列に接続して構成された組電池における前記電池群の列毎に測定した電気変量を用いた組電池の劣化状態の診断方法であって、並列接続されている電池群の列毎に電気変量である放電電流I 、又は放電電気量W を測定し、前記放電電流I から求めた平均放電電流IAVE、又は放電電気量W から求めた平均放電電気量WAVEに対して、前記電池群の列毎に測定した放電電流I 、又は測定した放電電気量W が、下記診断条件(1)及び(2)の状態になった電池群を劣化状態であるとして診断することを特徴とする組電池の劣化診断方法である。 According to a second aspect of the present invention, an electrical variable measured for each column of the battery group in a battery pack configured by connecting a plurality of unit cells in series to each other and connecting N columns in parallel. A method for diagnosing a deterioration state of a battery pack using a battery, wherein a discharge current I d N or a discharge electricity quantity W d N which is an electric variable is measured for each column of battery groups connected in parallel, and the discharge current the average discharge current I AVE calculated from I d N, or to the average discharge electric quantity W AVE calculated from discharge electricity quantity W d N, the discharge current was measured for each column of the cell group I d N, or to measure A method for diagnosing deterioration of an assembled battery, characterized in that a battery group whose discharge electric quantity W d N is in a state of the following diagnosis conditions (1) and (2) is diagnosed as being in a deteriorated state.

[診断条件]
(1)前記平均放電電流IAVEと測定した放電電流I の差(IAVE−I )が、予め設定した電流差dIより大きい場合、又は前記平均放電電気量WAVEと測定した放電電気量W の差(WAVE−W )が、予め設定した電気量差dWよりも大きい場合。
(2)前記平均放電電流IAVEと測定した放電電流I の差(IAVE−I )が、前記測定した放電電流から算出した標準偏差σに係数Aを乗じた数より大きい場合、又は、前記平均放電電気量WAVEと測定した放電電気量W の差(WAVE−W )が、前記測定された放電電気量W から算出した標準偏差σに係数Aを乗じた数より大きい場合。
[Diagnostic conditions]
(1) The average discharge difference between the currents I AVE and measured discharge current I d N (I AVE -I d N) is, if the current difference greater than dI d set in advance, or the average discharge electric quantity W AVE and Measurement When the difference (W AVE −W d N ) in the discharged electricity quantity W d N is larger than the preset electricity quantity difference dW d .
(2) the difference between the average discharge current I AVE and measured discharge current I d N (I AVE -I d N) is, than the number obtained by multiplying the coefficient A I standard deviation sigma I calculated from the discharge current and the measured If it is larger, or the difference (W AVE −W d N ) between the average discharge electricity amount W AVE and the measured discharge electricity amount W d N is a standard deviation σ W calculated from the measured discharge electricity amount W d N If the number is greater than multiplied by the coefficient a W to.

本発明の第3の発明は、単電池をN列並列に接続して構成された組電池の充放電監視制御システムであって、前記組電池の充電側に充電切替部を、前記組電池の放電側に放電切替部を備え、前記組電池を構成する単電池の劣化状態を、前記単電池の電気変量から求める第1の発明の組電池の劣化診断方法を搭載する監視装置を備え、前記劣化診断方法により診断された単電池の状態に応じて、前記充電切替部を動作させて前記組電池の充電量の制御、或いは前記放電切替部を動作させて前記組電池の放電量の制御を行うことを特徴とする組電池の充放電監視制御システムである。   A third aspect of the present invention is a charge / discharge monitoring control system for an assembled battery configured by connecting cells in N columns in parallel, wherein a charge switching unit is provided on a charge side of the assembled battery, A monitoring device equipped with a method for diagnosing deterioration of an assembled battery according to a first aspect of the present invention, comprising a discharge switching unit on a discharge side, wherein the deterioration state of the unit cell constituting the assembled battery is obtained from an electrical variable of the unit cell; Depending on the state of the unit cell diagnosed by the deterioration diagnosis method, the charge switching unit is operated to control the charge amount of the assembled battery, or the discharge switching unit is operated to control the discharge amount of the assembled battery. It is the charging / discharging monitoring control system of an assembled battery characterized by performing.

本発明の第4の発明は、複数個の単電池を直列接続して構成される電池群を、N列並列に接続して構成された組電池の充放電監視制御システムであって、前記組電池の充電側に充電切替部を、前記組電池の放電側に放電切替部を備え、前記組電池を構成する電池群の劣化状態を、前記電池群の電気変量から求める第2の発明の組電池の劣化診断方法を搭載する監視装置を備え、前記劣化診断方法により診断された電池群の状態に応じて、前記充電切替部を動作させて前記組電池の充電量の制御、或いは前記放電切替部を動作させて前記組電池の放電量の制御をすることを特徴とする組電池の充放電監視制御システムである。   A fourth invention of the present invention is a charge / discharge monitoring and control system for an assembled battery configured by connecting a battery group configured by connecting a plurality of single cells in series to each other in N rows in parallel. A group of the second invention, wherein a charge switching unit is provided on the charging side of the battery, and a discharge switching unit is provided on the discharging side of the assembled battery, and a deterioration state of the battery group constituting the assembled battery is obtained from an electric variable of the battery group. A monitoring device equipped with a battery deterioration diagnosis method is provided, and the charge switching unit is operated according to the state of the battery group diagnosed by the deterioration diagnosis method to control the charge amount of the assembled battery, or the discharge switching A charge / discharge monitoring and control system for an assembled battery, wherein the discharge amount of the assembled battery is controlled by operating a unit.

充放電サイクル用途の組電池は、組電池を構成する単電池あるいは電池群のうち、最も劣化が進行した単電池あるいは電池群が深放電され、そのために更に劣化が進んで充電され難くなるが、本発明によれば、劣化が進行した単電池あるいは電池群が深放電する前に充放電をコントロールすることができ、劣化が進み難くなる。
また、劣化が進行した場合でも、システムを停止せずに劣化した単電池あるいは電池群を交換することが可能となり、稼働効率の低下を防ぐことができる。
The assembled battery for charge / discharge cycle use is deeply discharged from the single cell or battery group that constitutes the assembled battery. According to the present invention, charge / discharge can be controlled before a cell or a group of batteries that have progressed deep discharge, and the deterioration is difficult to proceed.
Further, even when the deterioration progresses, it becomes possible to replace the deteriorated unit cell or battery group without stopping the system, and it is possible to prevent a decrease in operating efficiency.

本発明が対象とする組電池の代表例を示すもので、(a)は単電池からなる組電池(N=4)、(b)は単電池を直列接続(4個)した電池群を4個並列に接続した組電池(N=4)を示す図である。FIG. 2 shows a representative example of an assembled battery targeted by the present invention, where (a) shows an assembled battery (N = 4) made up of unit cells, and (b) shows four battery groups in which unit cells are connected in series (four). It is a figure which shows the assembled battery (N = 4) connected in parallel. 本発明の組電池の劣化診断方法の診断工程図である。It is a diagnostic process figure of the degradation diagnosis method of an assembled battery of the present invention. 本発明の充放電監視制御システムの全体図である。1 is an overall view of a charge / discharge monitoring control system of the present invention. 本発明の充放電監視制御システムのフロー図である。It is a flowchart of the charging / discharging monitoring control system of this invention. 単電池11aを9個直列接続した電池群11bを3列並列に接続した構成の組電池(N=3)を示す図である。It is a figure which shows the assembled battery (N = 3) of the structure which connected the battery group 11b which connected nine cell 11a in series to 3 rows in parallel. 実施例1、比較例1で用いた単電池A〜Dを並列に接続した組電池(N=4)を示す図である。It is a figure which shows the assembled battery (N = 4) which connected the battery cells AD used in Example 1 and Comparative Example 1 in parallel. 実施例1の診断結果を示す図である。It is a figure which shows the diagnostic result of Example 1. 比較例1の診断結果を示す図である。It is a figure which shows the diagnostic result of the comparative example 1. 実施例2における組電池A列の充放電サイクル試験結果である。It is a charging / discharging cycle test result of the assembled battery A row in Example 2. 比較例2における組電池A列の充放電サイクル試験結果である。It is a charging / discharging cycle test result of the assembled battery A row in Comparative Example 2. 比較例3における組電池A列の充放電サイクル試験結果である。It is a charging / discharging cycle test result of the assembled battery A row in Comparative Example 3.

先ず、本発明に係る組電池の劣化診断方法について図を参照して説明する。
図1は、本発明が対象とする組電池の代表例を示すもので、(a)は単電池からなる組電池で、単電池が4個並列に接続される場合(N=4)を示す図である。図1(b)は4個の単電池を直列接続した電池群を4個並列に接続した場合(N=4)を示す図である。なお、Nは並列接続の列数を意味するもので、単電池群の組電池の場合には、単電池の数を表すものではない。
図2は、本発明の組電池の劣化診断方法の診断工程図である。
First, an assembled battery deterioration diagnosis method according to the present invention will be described with reference to the drawings.
FIG. 1 shows a representative example of an assembled battery targeted by the present invention. FIG. 1 (a) shows an assembled battery composed of single cells, where four single cells are connected in parallel (N = 4). FIG. FIG.1 (b) is a figure which shows the case where the battery group which connected four unit cells in series is connected in parallel (N = 4). Note that N means the number of columns connected in parallel, and does not represent the number of single cells in the case of a battery pack of a single cell group.
FIG. 2 is a diagnosis process diagram of the assembled battery deterioration diagnosis method of the present invention.

以下、図1(a)のような単電池をn個並列に接続した組電池を例(N=n)として、組電池の劣化診断方法について説明する。なお、単電池を電池群に置き換えることで、電池群をn個並列に接続した場合も同様に説明できるものである。   Hereinafter, an assembled battery deterioration diagnosis method will be described by taking an assembled battery in which n unit cells as shown in FIG. 1A are connected in parallel as an example (N = n). In addition, the case where n battery groups are connected in parallel by replacing a single battery with a battery group can be explained similarly.

[列毎の電気変量の測定]
本発明では、電気変量として、(1)放電電流I、(2)放電電気量Wを用いる。
1列からn列の単電池の電気変量である放電電流I (N=1〜n)、或いは放電電気量W (N=1〜n)を測定する。なお、放電電流I は、放電を開始し、予め設定した放電時間の経過時に測定したもの、もしくは予め設定した放電電圧に達した時に測定したものである。
[Measurement of electric variables for each column]
In the present invention, (1) discharge current I d and (2) discharge electricity W d are used as electric variables.
A discharge current I d N (N = 1 to n) or a discharge electricity amount W d N (N = 1 to n), which is an electric variable of the cells in the first to n columns, is measured. The discharge current I d N is measured when discharge is started and a preset discharge time elapses or when a preset discharge voltage is reached.

[平均電気変量の算出]
先に測定した電気変量の平均値(平均電気変量)を下記式(1)で求める。
[Calculation of average electric variable]
The average value of the electrical variables measured previously (average electrical variable) is obtained by the following formula (1).

Figure 2013210348
Figure 2013210348

[劣化判定の設定]
組電池を構成する単電池が劣化しているかどうかを見極めるための指標を設定する。本発明では、下記の2種類の指標を用いて劣化診断を行う。
[Deterioration judgment settings]
An index is set to determine whether or not the cells constituting the assembled battery are deteriorated. In the present invention, deterioration diagnosis is performed using the following two types of indicators.

<設定1>
平均電気変量と測定した電気変量との差(電気変量差)を劣化判定の指標に用いる。
本発明では、放電電流差dI、或いは放電電気量差dWを用いる。その値は、適宜設定できるが、通常、単電池の満充電容量が定格容量の50%に減少した時の値を設定する。
<Setting 1>
The difference between the average electric variable and the measured electric variable (electric variable difference) is used as an index for determining deterioration.
In the present invention, the discharge current difference dI d or the discharge electricity quantity difference dW d is used. The value can be set as appropriate, but normally the value when the full charge capacity of the unit cell is reduced to 50% of the rated capacity is set.

<設定2>
測定した電気変量の標準偏差σ、及び組電池の使用条件に沿って設定した係数Aを劣化判定の指標に用いる。
本発明では、放電電流標準偏差σ、放電電流係数A、放電電気量標準偏差σ、放電電気量係数Aを用いる。
標準偏差に関しては、測定した電気変量から算出されるが、係数Aは、組電池を使用する電動車両、非常用電源装置、ロードレベリング装置等の性能、使用条件などの環境因子から適宜選定できるが、通常は3を用い、より劣化状態が電動車両、非常用電源装置、ロードレベリング装置等の稼働に影響する場合においては3未満の1〜2の値を採用する。
<Setting 2>
The measured standard deviation σ of the electric variable and the coefficient A set in accordance with the use condition of the assembled battery are used as indicators for determining deterioration.
In the present invention, the discharge current standard deviation σ d , the discharge current coefficient A d , the discharge electricity standard deviation σ W , and the discharge electricity quantity coefficient A W are used.
The standard deviation is calculated from the measured electrical variables, but the coefficient A can be appropriately selected from environmental factors such as the performance and usage conditions of the electric vehicle using the assembled battery, the emergency power supply device, the load leveling device, etc. Normally, 3 is used, and when the deterioration state affects the operation of the electric vehicle, the emergency power supply device, the load leveling device, etc., a value of 1 to 2 less than 3 is adopted.

[劣化診断]
<劣化診断1>
劣化診断1として、表1の条件式に示す関係より、劣化状態の診断を行う。
この条件式の関係を満たすとき劣化状態にあると診断する。
[Deterioration diagnosis]
<Deterioration diagnosis 1>
As the deterioration diagnosis 1, the deterioration state is diagnosed based on the relationship shown in the conditional expression of Table 1.
When the relationship of this conditional expression is satisfied, it is diagnosed that it is in a deteriorated state.

Figure 2013210348
Figure 2013210348

<劣化診断2>
劣化診断2として、表2の条件式に示す関係より、劣化状態の診断を行う。
この条件式の関係を満たすとき劣化状態にあると診断する。
<Deterioration diagnosis 2>
As the deterioration diagnosis 2, the deterioration state is diagnosed from the relationship shown in the conditional expression of Table 2.
When the relationship of this conditional expression is satisfied, it is diagnosed that it is in a deteriorated state.

Figure 2013210348
Figure 2013210348

劣化診断1と劣化診断2における劣化状態との関係を表3に示す。
表3から測定した電気変量が診断1、2の条件式を両方とも満たす場合は劣化状態、即ち故障となり、判定値1と判定値2の間に電気変量が測定された場合、どちらかの診断条件(条件式)を満たすことになり、やや劣化状態であるとの判定となり、今後劣化が進むと考えられることから警報が出されることになる。
Table 3 shows the relationship between the deterioration diagnosis 1 and the deterioration state in the deterioration diagnosis 2.
If the electrical variable measured from Table 3 satisfies both of the conditional expressions of diagnosis 1 and 2, it becomes a degraded state, that is, a failure, and if the electrical variable is measured between judgment value 1 and judgment value 2, either diagnosis The condition (conditional expression) is satisfied, and it is determined that the state is slightly deteriorated, and an alarm is issued because it is considered that deterioration will proceed in the future.

Figure 2013210348
Figure 2013210348

[充放電監視制御システム]
次に、本発明の組電池の劣化診断方法を備えた充放電監視制御システムに関して説明する。
図3は、充放電監視制御システムの全体図で、本発明の充放電監視制御システム10は、並列接続された単電池或いは電池群11と接続して、充電側に充電切替部12、放電側に放電切替部13を備え、その両切替部は、並列接続された単電池或いは電池群11の電圧、電流、温度を測定して、得られたデータを出力する監視回路14と接続している制御回路15によって充放電監視制御システムとしての制御が成されている。
図3において、破線は信号線、実線は電流線を示すものである。
[Charge / discharge monitoring control system]
Next, a charge / discharge monitoring control system including the assembled battery deterioration diagnosis method of the present invention will be described.
FIG. 3 is an overall view of the charge / discharge monitoring control system. The charge / discharge monitoring control system 10 of the present invention is connected to a single cell or a battery group 11 connected in parallel, and the charge switching unit 12 is connected to the charging side. The discharge switching unit 13 is connected to a monitoring circuit 14 that measures the voltage, current, and temperature of the cells or the battery group 11 connected in parallel and outputs the obtained data. The control circuit 15 controls the charge / discharge monitoring control system.
In FIG. 3, a broken line indicates a signal line, and a solid line indicates a current line.

この制御回路15は、監視回路14から送られた測定データを基に、組電池の劣化状態を診断し、その状態に応じて光、音、その他の出力信号を出力する機能を有する。また、温度制御機能が組込まれていても良く、例えば冷暖房回路16を備え、これを制御してシステム全体の温度を適温に維持する機能を有していても良い。
この制御回路15において行われる組電池の劣化状態の診断は、これまで述べてきた本発明に係る組電池の劣化診断方法によって診断されている。
The control circuit 15 has a function of diagnosing the deterioration state of the assembled battery based on the measurement data sent from the monitoring circuit 14 and outputting light, sound, and other output signals according to the state. Further, a temperature control function may be incorporated, and for example, the air conditioning circuit 16 may be provided and controlled to maintain the temperature of the entire system at an appropriate temperature.
The diagnosis of the deterioration state of the assembled battery performed in the control circuit 15 is made by the assembled battery deterioration diagnosis method according to the present invention described so far.

次に、本発明の充放電監視制御システムの動作を図4の充放電監視制御システムのフロー図に従って説明する。このフロー図は、満充電状態への充電を起点とした例である。
なお、説明に際して、図5のような、シール型鉛蓄電池(単電池11a;定格電圧2.0V/セル、10時間率定格容量10Ah/セル)を9個直列接続した電池群11bを3列並列に接続した構成の組電池を想定して、各種条件、制御における数値を用いている。
Next, the operation of the charge / discharge monitoring control system of the present invention will be described with reference to the flowchart of the charge / discharge monitoring control system of FIG. This flowchart is an example starting from charging to a fully charged state.
In the description, as shown in FIG. 5, three series of battery groups 11b in which nine sealed lead-acid batteries (unit cell 11a; rated voltage 2.0V / cell, 10 hour rate rated capacity 10Ah / cell) are connected in series are arranged. Assuming an assembled battery having a configuration connected to, numerical values in various conditions and control are used.

先ず、本システムを搭載する機器が運転(充放電サイクル)を開始するにあたり、制御回路15から充電切替部12に信号が送られ、表4に示す充電条件による充電が行われる。
次に、表4の充電終了の条件で、制御回路15から放電切替部13に信号が送られ、表4に示す放電条件による放電が行われ、表4の放電終了の条件で、放電が停止される。
First, when a device equipped with the present system starts operation (charge / discharge cycle), a signal is sent from the control circuit 15 to the charge switching unit 12 and charging is performed according to the charging conditions shown in Table 4.
Next, a signal is sent from the control circuit 15 to the discharge switching unit 13 under the charge termination conditions shown in Table 4, discharge is performed according to the discharge conditions shown in Table 4, and discharge stops under the discharge completion conditions shown in Table 4. Is done.

Figure 2013210348
Figure 2013210348

この放電中に、表5に示す放電制御の放電回路遮断の条件に適合する状態に至った電池群がある場合、その電池群に対して放電回路遮断の制御を実施した後、放電を継続する。
放電回路遮断の条件に適合する電池群がない場合には、放電回路遮断の制御をせずに放電を継続し、放電条件が表4の放電終了の条件に達した時点で放電を停止する。
During the discharge, if there is a battery group that has reached a condition that meets the discharge control interruption conditions shown in Table 5, the discharge circuit interruption control is performed on the battery group, and then the discharge is continued. .
If there is no battery group that meets the discharge circuit cutoff condition, the discharge is continued without controlling the discharge circuit cutoff, and the discharge is stopped when the discharge condition reaches the discharge termination condition shown in Table 4.

放電回路遮断の条件に適合する電池群があって、その放電を停止した場合は、表5の充電制御の条件に沿って適合判定を行い、表6に示す充放電サイクル終了条件に適合させて表7に示す均等充電条件に沿って均等充電を行った後、全ての放電回路の復帰を行う。   If there is a battery group that meets the conditions for interrupting the discharge circuit and the discharge is stopped, conformity determination is performed according to the charge control conditions in Table 5, and the charge / discharge cycle end conditions shown in Table 6 are adapted. After the equal charge is performed according to the equal charge conditions shown in Table 7, all the discharge circuits are restored.

Figure 2013210348
Figure 2013210348

Figure 2013210348
Figure 2013210348

表6の充放電サイクル終了条件を適合させた場合、適合するx列(単電池ではx列y番)の電池群の劣化情報を監視回路14に発信する。
その情報を基に、電池群内の劣化単電池をピックアップしてその単電池の交換作業を行う。交換作業の確認後、表5の充電制御の条件に沿って適合判定を行い、表7に示した均等充電条件による均等充電を表6の条件に沿って行い、均等充電の終了後、表4に示した充放電サイクル条件での放電を行う。
また、表6の充放電サイクル終了条件を適合させなかった場合は、表7に示した均等充電条件によって均等充電を行い、均等充電の終了後、表4に示した充放電サイクル条件での放電を行う。
When the charge / discharge cycle termination conditions in Table 6 are adapted, the deterioration information of the battery group in the x column (x column y in the case of a single cell) is transmitted to the monitoring circuit 14.
Based on the information, a deteriorated cell in the battery group is picked up and the cell is replaced. After confirming the replacement work, conformity determination is performed according to the charge control conditions in Table 5, equal charge under the equal charge conditions shown in Table 7 is performed according to the conditions in Table 6, and after completion of the equal charge, Table 4 Discharge is performed under the charge / discharge cycle conditions shown in FIG.
Further, when the charge / discharge cycle end conditions in Table 6 are not adapted, the equal charge is performed under the equal charge conditions shown in Table 7, and after completion of the equal charge, the discharge under the charge / discharge cycle conditions shown in Table 4 is performed. I do.

一方、表7に示した均等充電条件によって均等充電を行って、均等充電が終了しなかった場合には、表4に示した充放電サイクル条件での充電を実施する。   On the other hand, when the equal charge is performed under the equal charge conditions shown in Table 7 and the equal charge is not completed, the charge is performed under the charge / discharge cycle conditions shown in Table 4.

Figure 2013210348
Figure 2013210348

以上の判定は、その判定に使用するデータを監視回路14が収集して制御回路15に送られ、制御回路15において、必要な場合には、本発明の組電池の劣化診断方法として使用される。   In the above determination, data used for the determination is collected by the monitoring circuit 14 and sent to the control circuit 15, and the control circuit 15 is used as a method for diagnosing deterioration of a battery pack according to the present invention when necessary. .

以下、実施例を用いて、本発明を詳細に説明する。
実施例1及び比較例1は、「組電池の劣化診断方法」に関するもので、実施例2以降は「組電池の充放電監視制御方法」に関するものである。
Hereinafter, the present invention will be described in detail with reference to examples.
Example 1 and Comparative Example 1 relate to a “assembled battery deterioration diagnosis method”, and Example 2 and subsequent examples relate to an “assembled battery charge / discharge monitoring control method”.

図6に示すA〜Dの4個の単電池を並列に接続した組電池を用いて、充放電サイクル試験を行った。
用いた単電池は、定格電圧2.0V/セル、10時間率定格容量10Ah/セルのシール型鉛蓄電池で、表8に示す充放電サイクル試験条件を用いて、充放電サイクル試験を行い、各サイクル毎の電気変量の推移を測定した。
A charge / discharge cycle test was performed using an assembled battery in which four cells A to D shown in FIG. 6 were connected in parallel.
The unit cell used was a sealed lead-acid battery with a rated voltage of 2.0 V / cell, a 10 hour rate rated capacity of 10 Ah / cell, and a charge / discharge cycle test was performed using the charge / discharge cycle test conditions shown in Table 8. The transition of the electric variable for each cycle was measured.

Figure 2013210348
Figure 2013210348

電気変量として、放電開始から5分経過時の放電電流及び放電開始から放電終了までの放電電気量を用いて、図2の診断工程に従って劣化診断を行った。
その結果を図7に示す。図7は放電電流を電気変量とした場合の結果を示すものであるが、放電電気量を電気変量とした場合も同様な結果が得られたので、以下、電気変量に放電電流を用いた場合を例に示す。
As an electrical variable, the deterioration diagnosis was performed according to the diagnosis process of FIG. 2 using the discharge current at the time of 5 minutes from the start of discharge and the discharge amount of electricity from the start of discharge to the end of discharge.
The result is shown in FIG. FIG. 7 shows the result when the discharge current is an electric variable. However, since the same result was obtained when the discharge electric quantity was an electric variable, hereinafter, the case where the discharge current was used as the electric variable. Is shown as an example.

(比較例1)
電気変量として、放電末の端子電圧(放電電圧)を用いて、その推移を測定した。
その結果を図8に示す。
(Comparative Example 1)
The transition was measured using the terminal voltage (discharge voltage) at the end of discharge as an electrical variable.
The result is shown in FIG.

実施例1においては、列Aの単電池の劣化状態を確実に捉えることが可能であった。即ち、充放電サイクルが進むと、先ず放電電流(電気変量)が、表3の劣化状態の診断2を満たす値となり、劣化状態に陥ってきていることを把握できる。次に、より充放電サイクルが進むと、放電電流(電気変量)が、表3の劣化状態の診断1をも満たす値になり、劣化状態にあると診断できる。   In Example 1, it was possible to reliably grasp the deterioration state of the cells in row A. That is, as the charge / discharge cycle progresses, first, the discharge current (electrical variable) becomes a value satisfying the diagnosis 2 of the deterioration state shown in Table 3, and it can be understood that the deterioration state has been reached. Next, when the charge / discharge cycle progresses further, the discharge current (electrical variable) becomes a value that also satisfies the diagnosis 1 of the deterioration state in Table 3, and it can be diagnosed that it is in the deterioration state.

一方、比較例1では放電電圧(電気変量)が、列A〜列Dの単電池において、あまり変わらず緩やかな右下がりの曲線を描くために、単電池の劣化状態は把握できなかった。   On the other hand, in Comparative Example 1, the discharge voltage (electrical variable) did not change so much in the single cells in columns A to D, and a gentle downward curve was drawn, so the deterioration state of the single cells could not be grasped.

本発明の並列接続の組電池の充放電監視制御システムを用いた充放電サイクル試験を行った。
組電池に、実施例1で使用したシール型鉛蓄電池を直列に9個接続した電池群を3群並列(A列、B列、C列:N=3)に接続したものを用い、図3の充放電監視制御システム回路に接続して充放電サイクル試験を、表4の充放電サイクル条件により実施した。試験に際しては、本発明を検証する意味で、組電池を構成する全ての単電池の端子電圧を測定した。
なお、組電池のB列、C列には未使用電池のみからなる電池群を用い、A列には未使用電池と使用電池からなる組電池を用いた。
A charge / discharge cycle test was performed using the charge / discharge monitoring control system for the battery packs connected in parallel according to the present invention.
As the assembled battery, a battery group in which nine sealed lead-acid batteries used in Example 1 were connected in series was connected in three groups in parallel (A row, B row, C row: N = 3). The charge / discharge cycle test was conducted according to the charge / discharge cycle conditions shown in Table 4. In the test, terminal voltages of all the unit cells constituting the assembled battery were measured in order to verify the present invention.
In addition, the battery group which consists only of an unused battery was used for the B row | line | column and C row | line | column of an assembled battery, and the assembled battery which consists of an unused battery and a used battery was used for A column.

組電池A列の充放電サイクル試験結果を図9に示す、図9は組電池A列の電池群における端子電圧の推移と、本発明による充放電制御を適合させた場合の電池交換(実線矢印)、及び均等充電(破線矢印)のタイミングを示している。
図9よりわかるように、A列の放電電圧の推移では、総放電電圧、平均放電電圧共に、1〜2個の単電池が劣化状態にあったとしても、その変化はわずかであり劣化状態を検出することは困難であることがわかる。一方、本発明の劣化診断方法を用いた場合では、単電池の劣化に伴い、均等充電、充放電制御が発動して劣化状態にある単電池をリフレッシュすることで充放電サイクル寿命を延ばしていることがわかる。
FIG. 9 shows the results of the charge / discharge cycle test of the assembled battery A row. FIG. 9 shows the change of the terminal voltage in the battery group of the assembled battery A row and the battery replacement when the charge / discharge control according to the present invention is adapted (solid arrow). ) And equal charge (broken arrows).
As can be seen from FIG. 9, in the transition of the discharge voltage in row A, even if one or two single cells are in a deteriorated state, both the total discharge voltage and the average discharge voltage are slight, and the change is slight. It turns out that it is difficult to detect. On the other hand, in the case of using the deterioration diagnosis method of the present invention, as the unit cell deteriorates, the charge / discharge cycle life is extended by activating the uniform charge and charge / discharge control to refresh the unit cell in the deteriorated state. I understand that.

(比較例2)
実施例2と同様の構成の組電池を用い、放電制御並びに充電制御をしない点以外は、実施例2と同様の方法で充放電サイクル試験を行った。
その結果を図10に示す。
(Comparative Example 2)
A charge / discharge cycle test was performed in the same manner as in Example 2 except that the assembled battery having the same configuration as in Example 2 was used and discharge control and charge control were not performed.
The result is shown in FIG.

(比較例3)
実施例2と同様の構成の組電池を用い、均等充電、放電制御並びに充電制御をしない点以外は、実施例2と同様の方法で充放電サイクル試験を行った。
その結果を図11に示す。
(Comparative Example 3)
A charge / discharge cycle test was conducted in the same manner as in Example 2 except that the assembled battery having the same configuration as that of Example 2 was used and uniform charge, discharge control, and charge control were not performed.
The result is shown in FIG.

図9〜11からも明らかなように、本発明の充放電監視制御システムを採用することにより充放電サイクルを大きくすることができ、組電池の長寿命化が図れることがわかる。
表9に実施例2、比較例2、3の充放電サイクル試験結果を纏めて示す。
従来の方法(比較例2、比較例3)に比べて2〜5倍の充放電サイクルが実現可能であることがわかる。
As is apparent from FIGS. 9 to 11, it can be seen that by adopting the charge / discharge monitoring control system of the present invention, the charge / discharge cycle can be increased and the life of the assembled battery can be extended.
Table 9 summarizes the charge / discharge cycle test results of Example 2 and Comparative Examples 2 and 3.
It can be seen that 2 to 5 times as many charge / discharge cycles can be realized as compared with the conventional methods (Comparative Examples 2 and 3).

Figure 2013210348
Figure 2013210348

1a 単電池を並列接続した組電池
1b 単電池を直列接続した電池群を並列接続した組電池
10 充放電監視制御システム
11 組電池を構成する単電池又は電池群
11a 単電池(シール型鉛蓄電池)
11b 電池群
12 充電切替部
13 放電切替部
14 監視回路
15 制御回路
16 冷暖房回路
DESCRIPTION OF SYMBOLS 1a The assembled battery which connected the single battery in parallel 1b The assembled battery which connected the battery group which connected the single battery in series 10 Charge / discharge monitoring control system 11 The single battery or battery group 11a single battery (seal type lead acid battery) which comprises an assembled battery
11b Battery group 12 Charge switching unit 13 Discharge switching unit 14 Monitoring circuit 15 Control circuit 16 Air conditioning circuit

Claims (4)

単電池をN列並列に接続して構成された組電池における前記単電池の列毎に測定した電気変量を用いた組電池の劣化状態の診断方法であって、
並列接続されている単電池の列毎に電気変量である放電電流I 、又は放電電気量W を測定し、前記放電電流I から求めた平均放電電流IAVE、又は放電電気量W から求めた平均放電電気量WAVEに対して、前記単電池の列毎に測定した放電電流I 、又は測定した放電電気量W が、下記診断条件(1)及び(2)の状態になった単電池を劣化状態であると診断することを特徴とする組電池の劣化診断方法。
[診断条件]
(1)前記平均放電電流IAVEと測定した放電電流I の差(IAVE−I )が、予め設定した電流差dIより大きい場合、又は前記平均放電電気量WAVEと測定した放電電気量W の差(WAVE−W )が、予め設定した電気量差dWよりも大きい場合。
(2)前記平均放電電流IAVEと測定した放電電流I の差(IAVE−I )が、前記測定した放電電流から算出した標準偏差σに係数Aを乗じた数より大きい場合、又は、前記平均放電電気量WAVEと測定した放電電気量W の差(WAVE−W )が、前記測定した放電電気量W から算出した標準偏差σに係数Aを乗じた数より大きい場合。
A method for diagnosing a deterioration state of an assembled battery using an electric variable measured for each row of the cells in an assembled battery configured by connecting cells in parallel in N rows,
The discharge current I d N or the discharge electricity quantity W d N , which is an electric variable, is measured for each row of cells connected in parallel, and the average discharge current I AVE obtained from the discharge current I d N or the discharge electricity With respect to the average discharge electricity quantity W AVE obtained from the quantity W d N, the discharge current I d N measured for each column of the unit cells or the measured discharge electricity quantity W d N is expressed by the following diagnosis condition (1) and A method for diagnosing deterioration of an assembled battery, comprising diagnosing a single battery in a state of (2) as being in a deteriorated state.
[Diagnostic conditions]
(1) The average discharge difference between the currents I AVE and measured discharge current I d N (I AVE -I d N) is, if the current difference greater than dI d set in advance, or the average discharge electric quantity W AVE and Measurement When the difference (W AVE −W d N ) in the discharged electricity quantity W d N is larger than the preset electricity quantity difference dW d .
(2) the difference between the average discharge current I AVE and measured discharge current I d N (I AVE -I d N) is, than the number obtained by multiplying the coefficient A I standard deviation sigma I calculated from the discharge current and the measured If it is larger, or the difference (W AVE −W d N ) between the average discharge electricity amount W AVE and the measured discharge electricity amount W d N is the standard deviation σ W calculated from the measured discharge electricity amount W d N When larger than the number multiplied by the coefficient A W.
複数個の単電池を直列接続して構成される電池群を、N列並列に接続して構成された組電池における前記電池群の列毎に測定した電気変量を用いた組電池の劣化状態の診断方法であって、
並列接続されている電池群の列毎に電気変量である放電電流I 、又は放電電気量W を測定し、前記放電電流I から求めた平均放電電流IAVE、又は放電電気量W から求めた平均放電電気量WAVEに対して、前記電池群の列毎に測定した放電電流I 、又は測定した放電電気量W が、下記診断条件(1)及び(2)の状態になった電池群を劣化状態であるとして診断することを特徴とする組電池の劣化診断方法。
[診断条件]
(1)前記平均放電電流IAVEと測定した放電電流I の差(IAVE−I )が、予め設定した電流差dIより大きい場合、又は前記平均放電電気量WAVEと測定した放電電気量W の差(WAVE−W )が、予め設定した電気量差dWよりも大きい場合。
(2)前記平均放電電流IAVEと測定した放電電流I の差(IAVE−I )が、前記測定した放電電流から算出した標準偏差σに係数Aを乗じた数より大きい場合、又は、前記平均放電電気量WAVEと測定した放電電気量W の差(WAVE−W )が、前記測定された放電電気量W から算出した標準偏差σに係数Aを乗じた数より大きい場合。
A battery group configured by connecting a plurality of single cells in series, and an assembled battery using an electrical variable measured for each column of the battery group in an assembled battery configured by connecting N columns in parallel. A diagnostic method,
The discharge current I d N or the discharge electricity quantity W d N as an electric variable is measured for each column of the battery group connected in parallel, and the average discharge current I AVE obtained from the discharge current I d N or the discharge electricity With respect to the average discharge electricity quantity W AVE obtained from the quantity W d N, the discharge current I d N measured for each column of the battery group or the measured discharge electricity quantity W d N is expressed by the following diagnosis condition (1) and A method for diagnosing deterioration of a battery pack, wherein the battery group in the state of (2) is diagnosed as being in a deteriorated state.
[Diagnostic conditions]
(1) The average discharge difference between the currents I AVE and measured discharge current I d N (I AVE -I d N) is, if the current difference greater than dI d set in advance, or the average discharge electric quantity W AVE and Measurement When the difference (W AVE −W d N ) in the discharged electricity quantity W d N is larger than the preset electricity quantity difference dW d .
(2) the difference between the average discharge current I AVE and measured discharge current I d N (I AVE -I d N) is, than the number obtained by multiplying the coefficient A I standard deviation sigma I calculated from the discharge current and the measured If it is larger, or the difference (W AVE −W d N ) between the average discharge electricity amount W AVE and the measured discharge electricity amount W d N is a standard deviation σ W calculated from the measured discharge electricity amount W d N If the number is greater than multiplied by the coefficient a W to.
単電池をN列並列に接続して構成された組電池の充放電監視制御システムであって、
前記組電池の充電側に充電切替部を、前記組電池の放電側に放電切替部を備え、
前記組電池を構成する単電池の劣化状態を、前記単電池の電気変量から求める請求項1記載の並列接続の組電池の劣化診断方法を搭載する監視装置を備え、
前記劣化診断方法により診断された単電池の状態に応じて、前記充電切替部を動作させて前記組電池の充電量の制御、或いは前記放電切替部を動作させて前記組電池の放電量の制御を行うことを特徴とする組電池の充放電監視制御システム。
A charge / discharge monitoring and control system for an assembled battery configured by connecting cells in N rows in parallel,
A charge switching unit on the charging side of the assembled battery, a discharge switching unit on the discharging side of the assembled battery,
A monitoring device equipped with the parallel connection assembled battery deterioration diagnosis method according to claim 1, wherein the deterioration state of the battery constituting the assembled battery is obtained from an electric variable of the single battery.
Depending on the state of the unit cell diagnosed by the deterioration diagnosis method, the charge switching unit is operated to control the charge amount of the assembled battery, or the discharge switching unit is operated to control the discharge amount of the assembled battery. A charge / discharge monitoring and control system for an assembled battery.
複数個の単電池を直列接続して構成される電池群を、N列並列に接続して構成された組電池の充放電監視制御システムであって、
前記組電池の充電側に充電切替部を、前記組電池の放電側に放電切替部を備え、
前記組電池を構成する電池群の劣化状態を、前記電池群の電気変量から求める請求項2記載の並列接続の組電池の劣化診断方法を搭載する監視装置を備え、
前記劣化診断方法により診断された電池群の状態に応じて、前記充電切替部を動作させて前記組電池の充電量の制御、或いは前記放電切替部を動作させて前記組電池の放電量の制御をすることを特徴とする組電池の充放電監視制御システム。
A battery group configured by connecting a plurality of single cells in series, a battery pack charge / discharge monitoring control system configured by connecting N columns in parallel,
A charge switching unit on the charging side of the assembled battery, a discharge switching unit on the discharging side of the assembled battery,
A monitoring device equipped with the parallel connection assembled battery deterioration diagnosis method according to claim 2, wherein a deterioration state of the battery group constituting the assembled battery is obtained from an electric variable of the battery group,
Depending on the state of the battery group diagnosed by the deterioration diagnosis method, the charge switching unit is operated to control the charge amount of the assembled battery, or the discharge switching unit is operated to control the discharge amount of the assembled battery. A charge / discharge monitoring and control system for an assembled battery.
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CN107225104A (en) * 2017-07-27 2017-10-03 东莞威胜储能技术有限公司 A kind of method for separating of battery
CN107377422A (en) * 2017-07-27 2017-11-24 东莞威胜储能技术有限公司 A kind of method for separating of cell
CN115707985A (en) * 2021-08-19 2023-02-21 北京大瞬科技有限公司 Method for calculating electric quantity of battery and battery management system

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