JP2013191585A5 - - Google Patents

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JP2013191585A5
JP2013191585A5 JP2013138324A JP2013138324A JP2013191585A5 JP 2013191585 A5 JP2013191585 A5 JP 2013191585A5 JP 2013138324 A JP2013138324 A JP 2013138324A JP 2013138324 A JP2013138324 A JP 2013138324A JP 2013191585 A5 JP2013191585 A5 JP 2013191585A5
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temperature
fuel cell
solid oxide
gas
atr
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JP2013138324A
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JP5565759B2 (en
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燃料ガスと酸化剤ガスとを電気化学的に反応させることにより発電する固体電解質型燃料電池であって、
燃料電池モジュール内に配置された固体電解質型の燃料電池セルと、
燃料ガスを水素に改質して上記燃料電池セルに供給する改質器であって、燃料ガスと水蒸気を化学反応させることにより燃料ガスを水蒸気改質する改質反応であるSR、及び、所定の温度帯域に応じて燃料ガスと酸化剤ガスを化学反応させることにより燃料ガスを部分酸化改質する改質反応であるPOXと上記SRとを併用させることにより燃料ガスをオートサーマル改質する改質反応であるATRによって燃料ガスを改質する、上記燃料電池モジュール内に配置された上記改質器と、
上記燃料電池モジュール内の温度を検出する、上記燃料電池モジュール内に配置された温度検出手段と、
上記燃料電池モジュールの運転の起動を制御する起動制御手段と、上記燃料電池モジュールの運転の停止を制御する停止制御手段と、を備えた制御手段と、を有し、
上記起動制御手段は、上記温度検出手段により検出された温度が所定の定常温度未満のATR温度帯域内にある場合には、上記改質器を昇温させるために通常起動時のATRを実行し、上記温度検出手段により検出された温度が上記所定の定常温度以上である場合には、上記改質器を昇温させるために通常起動時のSRを実行し、
上記起動制御手段は、更に、上記燃料電池モジュールが高温状態からの停止に伴って上記停止制御手段による停止処理が実行され、上記ATR温度帯域内で運転の再起動が実行された場合には、上記温度検出手段により検出された温度が上記通常起動時のATR温度帯域内の所定温度未満である場合にはATRによる再起動制御を実行し、上記ATR温度帯域内の所定温度以上である場合には、通常起動時のATRをスキップして上記SRによる再起動制御を実行することを特徴とする固体電解質型燃料電池。
A solid oxide fuel cell that generates electricity by electrochemically reacting a fuel gas and an oxidant gas,
A solid oxide fuel cell disposed in the fuel cell module;
A reformer that reforms a fuel gas into hydrogen and supplies the fuel cell to the fuel cell, SR, which is a reforming reaction in which the fuel gas is steam-reformed by chemically reacting the fuel gas and steam, and a predetermined amount POX, which is a reforming reaction in which the fuel gas is partially oxidized and reformed by chemically reacting the fuel gas and the oxidant gas in accordance with the temperature range, and the SR are used in combination to improve the autothermal reforming of the fuel gas. The reformer disposed in the fuel cell module, which reforms the fuel gas by ATR which is a quality reaction;
Temperature detecting means arranged in the fuel cell module for detecting the temperature in the fuel cell module;
Control means comprising: start control means for controlling start of operation of the fuel cell module; and stop control means for controlling stop of operation of the fuel cell module;
When the temperature detected by the temperature detecting means is within an ATR temperature band lower than a predetermined steady temperature, the start control means executes ATR during normal start to raise the temperature of the reformer. When the temperature detected by the temperature detection means is equal to or higher than the predetermined steady temperature, the SR at the normal start-up is executed to raise the temperature of the reformer,
Further, when the fuel cell module is stopped from the high temperature state, a stop process is executed by the stop control unit, and when the restart of operation is executed within the ATR temperature band, When the temperature detected by the temperature detecting means is lower than a predetermined temperature in the ATR temperature band at the normal startup, the ATR restart control is executed, and when the temperature is equal to or higher than the predetermined temperature in the ATR temperature band. Is a solid oxide fuel cell characterized by skipping the ATR during normal startup and executing the restart control by the SR.
上記再起動制御で行われるSRは、上記通常起動時のSRよりも燃料ガスの供給量を多くするように構成されている請求項1に記載の固体電解質型燃料電池。 2. The solid oxide fuel cell according to claim 1, wherein the SR performed by the restart control is configured to increase the amount of fuel gas supplied compared to the SR at the time of normal startup. 上記再起動制御で行われるSRは、上記通常起動時のSRより水の供給量を少なくするように構成されている請求項1又は2に記載の固体電解質型燃料電池。 3. The solid oxide fuel cell according to claim 1, wherein the SR performed by the restart control is configured to reduce the amount of water supplied compared to the SR at the time of normal startup. 上記再起動制御で行われるSRは、上記改質状態温度が予め決定された所定温度以上上昇した時点で通常起動時のSRに変更される請求項1に記載の固体電解質型燃料電池。 2. The solid oxide fuel cell according to claim 1, wherein the SR performed by the restart control is changed to an SR at the time of normal startup when the reformed state temperature rises by a predetermined temperature or more. 上記再起動制御は、予め決定された燃料ガスの供給量及び水の供給量を変更させることなく一定量を維持してSRによる再起動を実行する請求項1に記載の固体電解質型燃料電池。 2. The solid oxide fuel cell according to claim 1, wherein the restart control performs restart by SR while maintaining a constant amount without changing a predetermined fuel gas supply amount and water supply amount. 更に、純水を生成して上記改質器に供給する水供給手段を有し、この水供給手段は、上記改質器に水を導入する水配管と、この水配管を保温する保温手段と、を備えている請求項1乃至の何れか1項に記載の固体電解質型燃料電池。 Furthermore, it has water supply means for generating pure water and supplying it to the reformer, and the water supply means includes a water pipe for introducing water into the reformer, and a heat retaining means for keeping the water pipe warm. The solid oxide fuel cell according to any one of claims 1 to 5 , further comprising: 更に、複数の燃料電池セルを備えたセル集合体の下部を支持すると共に燃料ガスと酸化剤ガスとの燃焼によって生成された排気ガスが排出される排気ガス室を形成するセル集合体支持手段を有し、上記保温手段は、上記水配管を上記排気ガス室内に経由させるように配置することにより、改質器に供給される水の温度低下を抑制するように構成されている請求項記載の固体電解質型燃料電池。 Furthermore, cell assembly support means for supporting the lower part of a cell assembly including a plurality of fuel cells and forming an exhaust gas chamber in which exhaust gas generated by combustion of fuel gas and oxidant gas is discharged. a, the heat insulating means, by arranging the water pipe so as to through the chamber the exhaust gas, according to claim 6, wherein being configured to suppress a temperature drop of the water supplied to the reformer Solid oxide fuel cell. 更に、上記セル集合体を収容するハウジング部材を備え、このハウジング部材を形成する対向する一対の側面には上記排気ガス室に連通する排気ガス通路が配置され、他の側面には、上記水配管の通路が配置されている請求項記載の固体電解質型燃料電池。 Furthermore, a housing member that accommodates the cell assembly is provided. Exhaust gas passages that communicate with the exhaust gas chamber are disposed on a pair of opposed side surfaces that form the housing member, and the water pipe is disposed on the other side surface. The solid oxide fuel cell according to claim 6 , wherein the passage is disposed.
JP2013138324A 2013-07-01 2013-07-01 Solid oxide fuel cell Expired - Fee Related JP5565759B2 (en)

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JP2013191585A JP2013191585A (en) 2013-09-26
JP2013191585A5 true JP2013191585A5 (en) 2013-11-07
JP5565759B2 JP5565759B2 (en) 2014-08-06

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JP6211969B2 (en) * 2014-03-22 2017-10-11 京セラ株式会社 Fuel cell device
JP6939282B2 (en) * 2017-09-05 2021-09-22 日産自動車株式会社 Fuel cell system and start control method

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JP2003095611A (en) * 2001-09-19 2003-04-03 Toyota Motor Corp Method for starting hydrogen producing apparatus
JP4369685B2 (en) * 2003-02-25 2009-11-25 京セラ株式会社 Operation method of fuel cell
JP2004338975A (en) * 2003-05-13 2004-12-02 Mitsubishi Kakoki Kaisha Ltd Starting method of hydrogen production apparatus
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JP2008243597A (en) * 2007-03-27 2008-10-09 Kyocera Corp Fuel cell device
US20110053017A1 (en) * 2007-08-29 2011-03-03 Kyocera Corporation Fuel Cell Apparatus

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