JP2013191282A - Power storage element, electrode body, core material and winding shaft - Google Patents

Power storage element, electrode body, core material and winding shaft Download PDF

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JP2013191282A
JP2013191282A JP2012054510A JP2012054510A JP2013191282A JP 2013191282 A JP2013191282 A JP 2013191282A JP 2012054510 A JP2012054510 A JP 2012054510A JP 2012054510 A JP2012054510 A JP 2012054510A JP 2013191282 A JP2013191282 A JP 2013191282A
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core material
electrode body
electrode
storage element
winding
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JP5948987B2 (en
JP2013191282A5 (en
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Akihiko Miyazaki
明彦 宮▲崎▼
Sumio Mori
森  澄男
Tomonori Kako
智典 加古
Jo Sasaki
丈 佐々木
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GS Yuasa Corp
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
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Abstract

PROBLEM TO BE SOLVED: To provide a power storage element capable of improving uniformity of a stress that an electrode body receives from a container.SOLUTION: A power storage element 10 comprises an electrode body 400 formed by winding a positive electrode, a negative electrode, and a separator around a winding shaft. The electrode body 400 comprises a core material 410 arranged inward on an innermost periphery of the positive electrode, the negative electrode, and the separator that are wound around, and the core material 410 has lower rigidity at its longitudinal ends on its cross section vertical to the winding shaft than at its longitudinal center part.

Description

本発明は、正極と負極とセパレータとが捲回されて形成される電極体を備える蓄電素子、電極体、電極体の最内周に配置される芯材及び巻軸に関する。   The present invention relates to a power storage element including an electrode body formed by winding a positive electrode, a negative electrode, and a separator, an electrode body, a core material disposed on the innermost periphery of the electrode body, and a winding shaft.

世界的な環境問題への取り組みとして、ガソリン自動車から電気自動車への転換が重要になってきている。このため、リチウムイオン二次電池などの蓄電素子を動力源に用いた電気自動車の開発が進められている。   The shift from gasoline cars to electric cars has become important as a global environmental problem. For this reason, development of an electric vehicle using a power storage element such as a lithium ion secondary battery as a power source is being promoted.

ここで、従来の蓄電素子においては、正極と負極とセパレータとを巻軸まわりに捲回して電極体を形成する捲回型の蓄電素子が広く知られている(例えば、特許文献1参照)。このような捲回型の蓄電素子においては、電極体を形成した後に巻軸を抜き取り、当該電極体を容器に挿入することで、製造される。   Here, in a conventional power storage element, a wound type power storage element in which an electrode body is formed by winding a positive electrode, a negative electrode, and a separator around a winding axis is widely known (for example, see Patent Document 1). Such a wound-type power storage element is manufactured by extracting a winding shaft after forming an electrode body and inserting the electrode body into a container.

特開2000−156241号公報JP 2000-156241 A

しかしながら、上記従来の捲回型の蓄電素子では、電極体を容器に挿入した場合に、電極体が容器から受ける応力が電極体の位置によって不均一になるため、蓄電素子の性能が低下するという問題がある。   However, in the conventional wound type electricity storage element, when the electrode body is inserted into the container, the stress that the electrode body receives from the container becomes non-uniform depending on the position of the electrode body, so that the performance of the electricity storage element decreases. There's a problem.

図9は、従来の捲回型の蓄電素子の問題点を説明するための図である。同図の(a)に示すように、巻軸が抜き取られた電極体には、中心部分に巻軸が配置されていた空間が形成される。そして、この電極体を容器に挿入した場合に、電極体が同図の(b)に示すように、電極体の端部の幅Aの方が中央部の幅Bよりも大きくなるように変形する。   FIG. 9 is a diagram for explaining a problem of a conventional wound-type energy storage device. As shown to (a) of the figure, in the electrode body from which the winding shaft was extracted, the space where the winding shaft was arrange | positioned in the center part is formed. When the electrode body is inserted into the container, the electrode body is deformed so that the width A of the end portion of the electrode body is larger than the width B of the center portion as shown in FIG. To do.

このため、電極体を容器に挿入した場合の挿入係数(電極体の外寸/ケース内寸)が電極体の位置によって不均一になる。これにより、電極体が容器から受ける応力が電極体の位置によって不均一になるため、電極体の耐久性(サイクルの耐久特性)が低下し、蓄電素子の性能が低下する。   For this reason, when the electrode body is inserted into the container, the insertion coefficient (the outer dimension of the electrode body / the inner dimension of the case) varies depending on the position of the electrode body. As a result, the stress that the electrode body receives from the container becomes non-uniform depending on the position of the electrode body, so that the durability of the electrode body (cycle durability characteristics) is reduced and the performance of the electricity storage device is reduced.

本発明は、上記問題を解決するためになされたものであり、電極体が容器から受ける応力の均一性を向上させることができる蓄電素子、電極体、電極体の最内周に配置される芯材及び巻軸を提供することを目的とする。   The present invention has been made in order to solve the above-described problem, and is an electricity storage element that can improve the uniformity of stress that the electrode body receives from the container, the electrode body, and the core disposed on the innermost periphery of the electrode body It aims at providing a material and a winding axis.

上記目的を達成するために、本発明の一態様に係る蓄電素子は、正極と負極とセパレータとが捲回軸周りに捲回されて形成される電極体を備える蓄電素子であって、前記電極体は、捲回された前記正極と前記負極と前記セパレータとの最内周内方に配置される芯材を備え、前記芯材は、前記捲回軸に垂直の断面における長手方向の端部の方が中央部よりも剛性が低い。   In order to achieve the above object, a power storage device according to one embodiment of the present invention is a power storage device including an electrode body formed by winding a positive electrode, a negative electrode, and a separator around a winding axis, the electrode The body includes a core material disposed at an innermost inner periphery of the wound positive electrode, the negative electrode, and the separator, and the core material is a longitudinal end portion in a cross section perpendicular to the winding axis. Is less rigid than the center.

これによれば、蓄電素子は、電極体の最内周に、捲回軸に垂直の断面における長手方向の端部の方が中央部よりも剛性が低い芯材を備える。つまり、電極体の最内周には、外側から応力が加わった際に端部の方が中央部よりも変形しやすい芯材が備わっているため、図9の(b)に示した電極体の端部の幅Aが中央部の幅Bの長さに近づくように電極体が変形する。このため、電極体を容器に挿入した場合の挿入係数の均一性を向上させることができ、電極体が容器から受ける応力の均一性を向上させることができる。これにより、電極体の耐久性を向上させることができるため、蓄電素子の性能を向上させることができる。   According to this, the power storage element includes a core material having a lower rigidity at the end portion in the longitudinal direction in the cross section perpendicular to the winding axis than at the central portion on the innermost periphery of the electrode body. That is, since the innermost periphery of the electrode body is provided with a core material whose end portion is more easily deformed than the central portion when stress is applied from the outside, the electrode body shown in FIG. The electrode body is deformed so that the width A of the end of the electrode approaches the length of the width B of the central portion. For this reason, the uniformity of the insertion coefficient when the electrode body is inserted into the container can be improved, and the uniformity of the stress that the electrode body receives from the container can be improved. Thereby, since durability of an electrode body can be improved, the performance of an electrical storage element can be improved.

また、好ましくは、前記捲回軸に垂直の断面における短手方向において、前記芯材の幅に対して前記芯材が占める長さの割合を空間占有率とし、前記芯材は、前記正極と前記負極と前記セパレータとが捲回されていない状態で、前記長手方向の端部の方が中央部よりも空間占有率が小さい。   Preferably, in a short direction in a cross section perpendicular to the winding axis, a ratio of a length occupied by the core material to a width of the core material is a space occupancy, and the core material includes the positive electrode and the positive electrode. In a state where the negative electrode and the separator are not wound, the end portion in the longitudinal direction has a smaller space occupation ratio than the central portion.

これによれば、芯材は、捲回前の状態で、長手方向の端部の方が中央部よりも空間占有率が小さいように形成されている。つまり、電極体の最内周において端部の方が中央部よりも空間占有率が小さいことで、図9の(b)に示した電極体の端部の幅Aが中央部の幅Bの長さに近づくように電極体が変形する。このため、電極体を容器に挿入した場合の挿入係数の均一性を向上させることができ、電極体が容器から受ける応力の均一性を向上させることができる。   According to this, the core material is formed so that the end portion in the longitudinal direction has a smaller space occupancy rate than the central portion in a state before winding. That is, in the innermost circumference of the electrode body, the end portion has a smaller space occupancy rate than the center portion, so that the width A of the end portion of the electrode body shown in FIG. The electrode body is deformed so as to approach the length. For this reason, the uniformity of the insertion coefficient when the electrode body is inserted into the container can be improved, and the uniformity of the stress that the electrode body receives from the container can be improved.

また、好ましくは、前記芯材は、板状の部材から成り、前記板状の部材は、前記長手方向の端部の方が中央部よりも前記短手方向の厚みが薄い。   Preferably, the core member is made of a plate-like member, and the plate-like member has a thickness in the lateral direction that is smaller at an end portion in the longitudinal direction than at a central portion.

これによれば、芯材は板状の部材から成り、当該板状の部材は、長手方向の端部の方が中央部よりも厚みが薄いように形成されている。つまり、電極体の最内周において端部の方が中央部よりも厚みが薄いことで、図9の(b)に示した電極体の端部の幅Aが中央部の幅Bの長さに近づくように電極体が変形する。このため、電極体を容器に挿入した場合の挿入係数の均一性を向上させることができ、電極体が容器から受ける応力の均一性を向上させることができる。   According to this, a core material consists of a plate-shaped member, and the said plate-shaped member is formed so that the thickness of the edge part of a longitudinal direction is thinner than a center part. That is, the end portion of the innermost periphery of the electrode body is thinner than the center portion, so that the width A of the end portion of the electrode body shown in FIG. 9B is the length of the width B of the center portion. The electrode body is deformed so as to approach. For this reason, the uniformity of the insertion coefficient when the electrode body is inserted into the container can be improved, and the uniformity of the stress that the electrode body receives from the container can be improved.

また、好ましくは、前記芯材は、前記長手方向の端部の方が中央部よりも前記短手方向の幅が大きい空間が形成されている。   Preferably, the core material has a space in which the end portion in the longitudinal direction has a width in the short-side direction larger than that in the central portion.

これによれば、芯材は、長手方向の端部の方が中央部よりも幅が大きい空間が形成されている。つまり、電極体の最内周において端部の方が中央部よりも幅が大きい空間が形成されていることで、図9の(b)に示した電極体の端部の幅Aが中央部の幅Bの長さに近づくように電極体が変形する。このため、電極体を容器に挿入した場合の挿入係数の均一性を向上させることができ、電極体が容器から受ける応力の均一性を向上させることができる。   According to this, as for the core material, the space where the width | variety of the edge part of a longitudinal direction is larger than a center part is formed. That is, a space having a larger width at the end portion than at the center portion is formed in the innermost periphery of the electrode body, so that the width A of the end portion of the electrode body shown in FIG. The electrode body is deformed so as to approach the length of the width B. For this reason, the uniformity of the insertion coefficient when the electrode body is inserted into the container can be improved, and the uniformity of the stress that the electrode body receives from the container can be improved.

また、本発明は、このような蓄電素子として実現することができるだけでなく、当該蓄電素子が備える電極体、または当該電極体が備える芯材として実現することもできる。   In addition, the present invention can be realized not only as such a power storage element, but also as an electrode body included in the power storage element or a core material included in the electrode body.

また、上記目的を達成するために、本発明の一態様に係る巻軸は、上記の芯材に挿入され、正極と負極とセパレータとを捲回軸周りに捲回して電極体を形成するための巻軸であって、前記捲回軸に垂直の断面における長手方向の端部の方が中央部よりも、前記捲回軸に垂直の断面における短手方向の幅が大きい。   In order to achieve the above object, a winding shaft according to an aspect of the present invention is inserted into the core material, and a positive electrode, a negative electrode, and a separator are wound around a winding axis to form an electrode body. The end in the longitudinal direction in the cross section perpendicular to the winding axis is wider in the short direction in the cross section perpendicular to the winding axis than the center.

これによれば、巻軸は、捲回軸に垂直の断面における長手方向の端部の方が中央部よりも、捲回軸に垂直の断面における短手方向の幅が大きいように形成されている。つまり、巻軸の端部の方が中央部よりも幅が大きいことで、電極体の最内周において端部の方が中央部よりも幅が大きい空間が形成されることになる。これにより、図9の(b)に示した電極体の端部の幅Aが中央部の幅Bの長さに近づくように変形する電極体を形成することができる。このため、電極体を容器に挿入した場合の挿入係数の均一性を向上させることができ、電極体が容器から受ける応力の均一性を向上させることができる。   According to this, the winding shaft is formed such that the end in the longitudinal direction in the cross section perpendicular to the winding axis is wider in the short direction in the cross section perpendicular to the winding axis than the central portion. Yes. That is, the width of the end portion of the winding shaft is larger than that of the central portion, so that a space having a width larger than that of the central portion at the end portion is formed in the innermost periphery of the electrode body. As a result, an electrode body can be formed that is deformed so that the width A of the end portion of the electrode body shown in FIG. 9B approaches the length of the width B of the center portion. For this reason, the uniformity of the insertion coefficient when the electrode body is inserted into the container can be improved, and the uniformity of the stress that the electrode body receives from the container can be improved.

本発明によると、電極体が容器から受ける応力の均一性を向上させ、蓄電素子の性能を向上させることができる。   According to the present invention, the uniformity of stress that the electrode body receives from the container can be improved, and the performance of the electricity storage device can be improved.

本発明の実施の形態に係る蓄電素子の外観斜視図である。It is an external appearance perspective view of the electrical storage element which concerns on embodiment of this invention. 本発明の実施の形態に係る電極体の構成を示す図である。It is a figure which shows the structure of the electrode body which concerns on embodiment of this invention. 本発明の実施の形態に係る芯材の構成を示す斜視図である。It is a perspective view which shows the structure of the core material which concerns on embodiment of this invention. 本発明の実施の形態に係る巻軸の構成を示す斜視図である。It is a perspective view which shows the structure of the winding shaft which concerns on embodiment of this invention. 本発明の実施の形態に係る電極体の製造方法を説明するための図である。It is a figure for demonstrating the manufacturing method of the electrode body which concerns on embodiment of this invention. 本発明の実施の形態に係る電極体が容器内方に収容された状態を示す図である。It is a figure which shows the state in which the electrode body which concerns on embodiment of this invention was accommodated inside the container. 本発明の実施の形態の変形例1に係る芯材の構成を示す斜視図である。It is a perspective view which shows the structure of the core material which concerns on the modification 1 of embodiment of this invention. 本発明の実施の形態の変形例2に係る芯材の構成を示す斜視図である。It is a perspective view which shows the structure of the core material which concerns on the modification 2 of embodiment of this invention. 従来の捲回型の蓄電素子の問題点を説明するための図である。It is a figure for demonstrating the problem of the conventional winding type electrical storage element.

以下、図面を参照しながら、本発明の実施の形態に係る蓄電素子、電極体、電極体の最内周に配置される芯材及び巻軸について説明する。   Hereinafter, a power storage element, an electrode body, a core material disposed on the innermost circumference of the electrode body, and a winding shaft will be described with reference to the drawings.

なお、以下で説明する実施の形態は、いずれも本発明の好ましい一具体例を示すものである。以下の実施の形態で示される数値、形状、材料、構成要素、構成要素の配置位置及び接続形態などは、一例であり、本発明を限定する主旨ではない。本発明は、特許請求の範囲によって特定される。よって、以下の実施の形態における構成要素のうち、本発明の最上位概念を示す独立請求項に記載されていない構成要素については、本発明の課題を達成するのに必ずしも必要ではないが、より好ましい形態を構成するものとして説明される。   Each of the embodiments described below shows a preferred specific example of the present invention. Numerical values, shapes, materials, constituent elements, arrangement positions and connection forms of constituent elements, and the like shown in the following embodiments are merely examples, and are not intended to limit the present invention. The invention is specified by the claims. Therefore, among the constituent elements in the following embodiments, constituent elements that are not described in the independent claims indicating the highest concept of the present invention are not necessarily required to achieve the object of the present invention. It will be described as constituting a preferred form.

まず、蓄電素子10の構成について、説明する。   First, the configuration of the power storage element 10 will be described.

図1は、本発明の実施の形態に係る蓄電素子10の外観斜視図である。なお、同図は、容器内部を透視した図となっている。   FIG. 1 is an external perspective view of a power storage device 10 according to an embodiment of the present invention. In addition, the figure is a figure which saw through the container inside.

蓄電素子10は、電気を充電し、また、電気を放電することのできる二次電池であり、より具体的には、リチウムイオン二次電池などの非水電解質電池である。   The storage element 10 is a secondary battery that can charge electricity and discharge electricity, and more specifically, is a non-aqueous electrolyte battery such as a lithium ion secondary battery.

同図に示すように、蓄電素子10は、容器100と、正極端子200と、負極端子300とを備え、容器100は、上壁であるふた板110を備えている。また、容器100内方には、電極体400と、正極集電体120と、負極集電体130とが配置されている。   As shown in the figure, the power storage element 10 includes a container 100, a positive electrode terminal 200, and a negative electrode terminal 300, and the container 100 includes a lid plate 110 that is an upper wall. In addition, an electrode body 400, a positive electrode current collector 120, and a negative electrode current collector 130 are disposed inside the container 100.

なお、蓄電素子10の容器100の内部には電解液などの液体が封入されているが、当該液体の図示は省略する。また、蓄電素子10は、非水電解質電池には限定されず、非水電解質電池以外の二次電池であってもよいし、キャパシタであってもよい。   Note that a liquid such as an electrolytic solution is sealed inside the container 100 of the power storage element 10, but the liquid is not shown. Moreover, the electrical storage element 10 is not limited to a non-aqueous electrolyte battery, and may be a secondary battery other than the non-aqueous electrolyte battery or a capacitor.

容器100は、金属からなる矩形筒状で底を備える筐体本体と、当該筐体本体の開口を閉塞する金属製のふた板110とで構成されている。また、容器100は、電極体400等を内部に収容後、ふた板110と筐体本体とが溶接等されることにより、内部を密封することができるものとなっている。   The container 100 includes a casing body having a rectangular cylindrical shape made of metal and having a bottom, and a metal lid plate 110 that closes an opening of the casing body. In addition, the container 100 can be hermetically sealed by welding the lid plate 110 and the housing body after the electrode body 400 and the like are accommodated therein.

電極体400は、正極と負極とセパレータとを備え、電気を蓄えることができる部材である。具体的には、電極体400は、負極と正極との間にセパレータが挟み込まれるように層状に配置されたものを全体が長円形状となるように捲回されて形成されている。電極体400の詳細な構成については、後述する。   The electrode body 400 includes a positive electrode, a negative electrode, and a separator, and is a member that can store electricity. Specifically, the electrode body 400 is formed by winding a layered arrangement so that a separator is sandwiched between a negative electrode and a positive electrode so that the whole becomes an oval shape. The detailed configuration of the electrode body 400 will be described later.

正極端子200は、電極体400の正極に電気的に接続された電極端子であり、負極端子300は、電極体400の負極に電気的に接続された電極端子である。つまり、正極端子200及び負極端子300は、電極体400に蓄えられている電気を蓄電素子10の外部空間に導出し、また、電極体400に電気を蓄えるために蓄電素子10の内部空間に電気を導入するための金属製の電極端子である。また、正極端子200及び負極端子300は、電極体400の上方に配置されたふた板110に取り付けられている。   The positive electrode terminal 200 is an electrode terminal electrically connected to the positive electrode of the electrode body 400, and the negative electrode terminal 300 is an electrode terminal electrically connected to the negative electrode of the electrode body 400. That is, the positive electrode terminal 200 and the negative electrode terminal 300 lead the electricity stored in the electrode body 400 to the external space of the power storage element 10, and in order to store the electricity in the electrode body 400, It is an electrode terminal made of metal for introducing. The positive electrode terminal 200 and the negative electrode terminal 300 are attached to a lid plate 110 disposed above the electrode body 400.

正極集電体120は、電極体400の正極と容器100の側壁との間に配置され、正極端子200と電極体400の正極とに電気的に接続される導電性と剛性とを備えた部材である。なお、正極集電体120は、電極体400の正極と同様、アルミニウムで形成されている。   The positive electrode current collector 120 is disposed between the positive electrode of the electrode body 400 and the side wall of the container 100, and is a member having conductivity and rigidity that is electrically connected to the positive electrode terminal 200 and the positive electrode of the electrode body 400. It is. The positive electrode current collector 120 is made of aluminum, like the positive electrode of the electrode body 400.

負極集電体130は、電極体400の負極と容器100の側壁との間に配置され、負極端子300と電極体400の負極とに電気的に接続される導電性と剛性とを備えた部材である。なお、負極集電体130は、電極体400の負極と同様、銅で形成されている。   The negative electrode current collector 130 is disposed between the negative electrode of the electrode body 400 and the side wall of the container 100, and is a member having conductivity and rigidity that is electrically connected to the negative electrode terminal 300 and the negative electrode of the electrode body 400. It is. The negative electrode current collector 130 is made of copper, like the negative electrode of the electrode body 400.

次に、電極体400の詳細な構成について、説明する。   Next, a detailed configuration of the electrode body 400 will be described.

図2は、本発明の実施の形態に係る電極体400の構成を示す図である。具体的には、同図は、図1に示された電極体400をYZ平面で切断した場合の断面図である。   FIG. 2 is a diagram showing the configuration of the electrode body 400 according to the embodiment of the present invention. Specifically, this figure is a cross-sectional view when the electrode body 400 shown in FIG. 1 is cut along the YZ plane.

同図に示すように、電極体400は、芯材410と、芯材410の周りに配置される電極部420とを備えている。   As shown in the figure, the electrode body 400 includes a core material 410 and an electrode portion 420 disposed around the core material 410.

具体的には、電極部420は、正極と負極とセパレータとを備えており、当該正極と負極とセパレータとが捲回軸周りに捲回されて形成されている。つまり、電極体400は、捲回型の電極体である。ここで、捲回軸とは、正極と負極とセパレータとが捲回される際の中心軸である。   Specifically, the electrode part 420 includes a positive electrode, a negative electrode, and a separator, and the positive electrode, the negative electrode, and the separator are wound around a winding axis. That is, the electrode body 400 is a wound electrode body. Here, the winding axis is a central axis when the positive electrode, the negative electrode, and the separator are wound.

正極は、アルミニウム箔からなる長尺帯状の正極基材の表面に、正極活物質層が形成されたものである。なお、本発明に係る蓄電素子10に用いられる正極は、特に従来用いられてきたものと異なるところはなく、通常用いられているものが使用できる。   The positive electrode is obtained by forming a positive electrode active material layer on the surface of a long belt-like positive electrode base material made of aluminum foil. In addition, the positive electrode used for the electrical storage element 10 according to the present invention is not particularly different from those conventionally used, and those normally used can be used.

例えば、正極活物質としては、LiMPO、LiMSiO、LiMBO(MはFe、Ni、Mn、Co等から選択される1種または2種以上の遷移金属元素)等のポリアニオン化合物、チタン酸リチウム、マンガン酸リチウム等のスピネル化合物、LiMO(MはFe、Ni、Mn、Co等から選択される1種または2種以上の遷移金属元素)等のリチウム遷移金属酸化物等を用いることができる。 For example, as the positive electrode active material, polyanion compounds such as LiMPO 4 , LiMSiO 4 , LiMBO 3 (M is one or more transition metal elements selected from Fe, Ni, Mn, Co, etc.), lithium titanate, etc. , Spinel compounds such as lithium manganate, lithium transition metal oxides such as LiMO 2 (M is one or more transition metal elements selected from Fe, Ni, Mn, Co, etc.), etc. can be used. .

負極は、銅箔からなる長尺帯状の負極基材の表面に、負極活物質層が形成されたものである。なお、本発明に係る蓄電素子10に用いられる負極は、特に従来用いられてきたものと異なるところはなく、通常用いられているものが使用できる。   In the negative electrode, a negative electrode active material layer is formed on the surface of a long strip-shaped negative electrode substrate made of copper foil. In addition, the negative electrode used for the electrical storage element 10 according to the present invention is not particularly different from those conventionally used, and those normally used can be used.

例えば、負極活物質としては、リチウム金属、リチウム合金(リチウム−アルミニウム、リチウム−鉛、リチウム−錫、リチウム−アルミニウム−錫、リチウム−ガリウム、及びウッド合金等のリチウム金属含有合金)の他、リチウムを吸蔵・放出可能な合金、炭素材料(例えば黒鉛、難黒鉛化炭素、易黒鉛化炭素、低温焼成炭素、非晶質カーボン等)、金属酸化物、リチウム金属酸化物(LiTi12等)、ポリリン酸化合物などが挙げられる。 For example, as the negative electrode active material, lithium metal, lithium alloy (lithium metal-containing alloys such as lithium-aluminum, lithium-lead, lithium-tin, lithium-aluminum-tin, lithium-gallium, and wood alloy), lithium Alloys, carbon materials (eg, graphite, non-graphitizable carbon, graphitizable carbon, low-temperature calcined carbon, amorphous carbon, etc.), metal oxides, lithium metal oxides (Li 4 Ti 6 O 12 Etc.) and polyphosphoric acid compounds.

芯材410は、電極部420の最内周内方に配置された絶縁性の部材である。具体的には、芯材410は、捲回された正極と負極とセパレータとの最内周内方に配置された、ポリプロピレンまたはポリエチレンなどの樹脂製の巻芯である。つまり、芯材410の周りに正極と負極とセパレータとが捲回されることで、電極体400が形成される。   The core material 410 is an insulating member arranged on the innermost inner periphery of the electrode portion 420. Specifically, the core material 410 is a core made of resin such as polypropylene or polyethylene, which is disposed on the innermost inner periphery of the wound positive electrode, negative electrode, and separator. That is, the electrode body 400 is formed by winding the positive electrode, the negative electrode, and the separator around the core material 410.

なお、芯材410は、樹脂シートを巻くことにより形成される巻シート輪であってもよいし、成形された部材であってもよい。また、芯材410は、一体に形成された部材であってもよいし、複数の部材から形成されていてもよい。また、芯材410の材料は特に限定されない。例えば、電極体400のうち、最も芯材に近い位置にセパレータを配置する場合や、正極または負極のいずれか一方の電位を芯材410に落とす場合は、導電性の材料を用いても良い。   The core material 410 may be a wound sheet wheel formed by winding a resin sheet, or may be a molded member. Moreover, the core material 410 may be an integrally formed member, or may be formed of a plurality of members. Moreover, the material of the core material 410 is not specifically limited. For example, when a separator is disposed at a position closest to the core material in the electrode body 400, or when the potential of either the positive electrode or the negative electrode is dropped on the core material 410, a conductive material may be used.

ここで、芯材410は、中央位置に中央部411と、中央部411の両端に端部412とを備えている。以下、芯材410の構成について、詳細に説明する。   Here, the core material 410 includes a central portion 411 at a central position and end portions 412 at both ends of the central portion 411. Hereinafter, the configuration of the core material 410 will be described in detail.

図3は、本発明の実施の形態に係る芯材410の構成を示す斜視図である。なお、以下では、電極部420が捲回される際の捲回軸(同図のX軸方向の軸)に垂直の断面(同図のYZ平面で切断した場合の断面)における長手方向(同図のZ軸方向)を、芯材410の長手方向という。また、電極部420が捲回される際の捲回軸(同図のX軸方向の軸)に垂直の断面(同図のYZ平面で切断した場合の断面)における短手方向(同図のY軸方向)を、芯材410の短手方向という。   FIG. 3 is a perspective view showing the configuration of the core material 410 according to the embodiment of the present invention. In the following, the longitudinal direction (same as the section taken along the YZ plane in the figure) perpendicular to the winding axis (axis in the X-axis direction in the figure) when the electrode part 420 is wound is shown. The Z-axis direction in the figure is referred to as the longitudinal direction of the core material 410. Further, a short direction (cross-section when cut along the YZ plane in the figure) perpendicular to the winding axis (axis in the X-axis direction in the figure) when the electrode section 420 is wound (in the figure) (Y-axis direction) is referred to as the short direction of the core material 410.

同図に示すように、芯材410は、X軸方向に延びる中空の平板状部材であり、長手方向(Z軸方向)の中央部分に中央部411を備え、長手方向(Z軸方向)の両端部に端部412を備えている。   As shown in the figure, the core material 410 is a hollow flat plate-like member extending in the X-axis direction, and includes a central portion 411 at the central portion in the longitudinal direction (Z-axis direction), and in the longitudinal direction (Z-axis direction). End portions 412 are provided at both ends.

中央部411は、外周及び内周が平面で形成される部位である。具体的には、中央部411は、Y軸方向に空間を隔てて並ぶ2つの板状の部材からなる。また、端部412は、外周及び内周が曲面で形成される板状の部位である。具体的には、端部412は、YZ平面での断面形状において、円弧形状の外形を有し、内部には楕円形状の空間が形成されている。このように、芯材410は、板状の部材から成り、当該板状の部材を1周巻いたような形状である。   The central part 411 is a part where the outer periphery and the inner periphery are formed as flat surfaces. Specifically, the central portion 411 is composed of two plate-like members arranged with a space in the Y-axis direction. Further, the end portion 412 is a plate-like portion whose outer periphery and inner periphery are formed with curved surfaces. Specifically, the end 412 has an arc-shaped outer shape in a cross-sectional shape on the YZ plane, and an elliptical space is formed inside. Thus, the core material 410 is made of a plate-like member, and has a shape such that the plate-like member is wound once.

そして、芯材410の当該板状の部材は、端部412の方が中央部411よりも、短手方向(Y軸方向)の厚みが薄くなるように形成されている。例えば、中央部411の2つの板状の部材の厚みは0.1〜2mmであり、端部412の厚みは0.05〜0.5mmである。なお、中央部411及び端部412の厚みは、上記数値には限定されない。   The plate-like member of the core material 410 is formed so that the end portion 412 is thinner in the lateral direction (Y-axis direction) than the central portion 411. For example, the thickness of the two plate-like members in the central portion 411 is 0.1 to 2 mm, and the thickness of the end portion 412 is 0.05 to 0.5 mm. In addition, the thickness of the center part 411 and the edge part 412 is not limited to the said numerical value.

また、芯材410には、端部412の方が中央部411よりも短手方向の幅が大きい空間が形成されている。なお、同図では、中央部411は、YZ平面での断面が長方形状の空間を有し、端部412は、YZ平面での断面が楕円形状の空間を有しているが、空間の形状はこれには限定されない。例えば、端部412に形成された空間は、YZ平面での断面が円形状や長方形状などの多角形状であってもよい。   Further, the core material 410 has a space in which the end portion 412 has a width in the short side direction larger than that of the central portion 411. In the same figure, the central portion 411 has a space whose section in the YZ plane is rectangular, and the end portion 412 has a space whose section in the YZ plane is elliptical. Is not limited to this. For example, the space formed in the end 412 may have a polygonal shape such as a circular shape or a rectangular shape in cross section on the YZ plane.

上記の構成により、芯材410は、正極と負極とセパレータとが捲回されていない状態で、端部412の方が中央部411よりも空間占有率が小さくなるように形成されている。ここで、空間占有率とは、短手方向(Y軸方向)において、芯材410の幅に対して芯材410が占める長さの割合を示している。   With the above configuration, the core material 410 is formed so that the end portion 412 has a smaller space occupancy rate than the central portion 411 in a state where the positive electrode, the negative electrode, and the separator are not wound. Here, the space occupancy indicates the ratio of the length occupied by the core material 410 to the width of the core material 410 in the short direction (Y-axis direction).

このように、芯材410は、端部412の方が中央部411よりも剛性が低くなるように形成されている。   Thus, the core material 410 is formed such that the end portion 412 has lower rigidity than the central portion 411.

次に、芯材410の周りに正極と負極とセパレータとを捲回して電極体400を形成する際に、芯材410に挿入される巻軸について、説明する。   Next, the winding shaft inserted into the core material 410 when the positive electrode, the negative electrode, and the separator are wound around the core material 410 to form the electrode body 400 will be described.

図4は、本発明の実施の形態に係る巻軸20の構成を示す斜視図である。なお、以下では、芯材410と同様に、電極部420が捲回される際の捲回軸(同図のX軸方向の軸)に垂直の断面(同図のYZ平面で切断した場合の断面)における長手方向(同図のZ軸方向)を、巻軸20の長手方向という。また、電極部420が捲回される際の捲回軸(同図のX軸方向の軸)に垂直の断面(同図のYZ平面で切断した場合の断面)における短手方向(同図のY軸方向)を、巻軸20の短手方向という。   FIG. 4 is a perspective view showing the configuration of the winding shaft 20 according to the embodiment of the present invention. In the following, similarly to the core material 410, a cross section perpendicular to the winding axis (the axis in the X-axis direction in the figure) when the electrode part 420 is wound (when cut along the YZ plane in the figure) The longitudinal direction (cross-sectional direction) in the cross section) is referred to as the longitudinal direction of the winding shaft 20. Further, a short direction (cross-section when cut along the YZ plane in the figure) perpendicular to the winding axis (axis in the X-axis direction in the figure) when the electrode section 420 is wound (in the figure) (Y-axis direction) is referred to as the short direction of the winding shaft 20.

巻軸20は、芯材410に挿入され、正極と負極とセパレータとを捲回軸(X軸方向の軸)周りに捲回して電極体400を形成するための軸体である。同図に示すように、巻軸20は、X軸方向に延びる板状部材であり、長手方向(Z軸方向)の中央部分に中央部21を備え、長手方向(Z軸方向)の両端部に端部22を備えている。   The winding shaft 20 is inserted into the core material 410 and is a shaft body for forming the electrode body 400 by winding the positive electrode, the negative electrode, and the separator around the winding axis (X-axis direction axis). As shown in the figure, the winding shaft 20 is a plate-like member extending in the X-axis direction, and has a central portion 21 at the central portion in the longitudinal direction (Z-axis direction), and both end portions in the longitudinal direction (Z-axis direction). The end portion 22 is provided.

中央部21は、外周が平面で形成される平板状の部位であり、外面形状が芯材410の中央部411の内面形状に対応している。また、端部22は、外周が曲面で形成される部位であり、外面形状が芯材410の端部412の内面形状に対応している。具体的には、端部412は、YZ平面での断面形状において、楕円形状の外形を有する。なお、中央部21及び端部412の形状は、芯材410の中央部411及び端部412の内面形状に対応していれば、どのような形状であっても構わない。また、巻軸20全体が芯材410の内面形状に対応する必要はなく、一部隙間を有している箇所があっても良い。さらに、X軸方向において、芯材410と巻軸20との長さが異なっていても良い。例えば、巻軸20を巻回装置などに取り付ける場合、芯材410から外側へ突出した部分は、内面形状に対応させるよりも、長方形や円形などの単純な形状にするのが好ましい。   The central portion 21 is a flat plate portion having a flat outer periphery, and the outer surface shape corresponds to the inner surface shape of the central portion 411 of the core material 410. Further, the end 22 is a portion where the outer periphery is formed of a curved surface, and the outer surface shape corresponds to the inner surface shape of the end 412 of the core material 410. Specifically, the end 412 has an elliptical outer shape in the cross-sectional shape on the YZ plane. The shapes of the central portion 21 and the end portion 412 may be any shapes as long as they correspond to the inner surface shapes of the central portion 411 and the end portion 412 of the core material 410. Moreover, the whole winding shaft 20 does not need to correspond to the inner surface shape of the core material 410, and there may be a part having a gap. Furthermore, the length of the core material 410 and the winding shaft 20 may be different in the X-axis direction. For example, when attaching the winding shaft 20 to a winding device or the like, it is preferable that the portion protruding outward from the core material 410 has a simple shape such as a rectangle or a circle rather than corresponding to the shape of the inner surface.

このように、巻軸20は、端部22の方が中央部21よりも、短手方向(Y軸方向)の幅が大きくなるように形成されている。なお、巻軸20の材質は特に限定されず、樹脂製であっても金属製であってもよい。   Thus, the winding shaft 20 is formed such that the end portion 22 has a width in the short side direction (Y-axis direction) larger than that of the central portion 21. The material of the winding shaft 20 is not particularly limited, and may be made of resin or metal.

次に、電極体400の製造方法について説明する。   Next, a method for manufacturing the electrode body 400 will be described.

図5は、本発明の実施の形態に係る電極体400の製造方法を説明するための図である。   FIG. 5 is a diagram for explaining a method of manufacturing the electrode body 400 according to the embodiment of the present invention.

同図の(a)及び(b)に示すように、巻軸20が芯材410内方の空間に挿入される。そして、同図の(c)及び(d)に示すように、巻軸20が回転することで、芯材410の周りに正極と負極とセパレータとが捲回され、電極体400が形成される。そして、電極体400が形成された後、巻軸20が引き抜かれる。   As shown in FIGS. 5A and 5B, the winding shaft 20 is inserted into the space inside the core material 410. And as shown to (c) and (d) of the figure, when the winding shaft 20 rotates, a positive electrode, a negative electrode, and a separator are wound around the core material 410, and the electrode body 400 is formed. . Then, after the electrode body 400 is formed, the winding shaft 20 is pulled out.

このようにして、形成された電極体400は、容器100内方に収容される。   Thus, the formed electrode body 400 is accommodated inside the container 100.

図6は、本発明の実施の形態に係る電極体400が容器100内方に収容された状態を示す図である。   FIG. 6 is a view showing a state in which the electrode body 400 according to the embodiment of the present invention is housed inside the container 100.

同図に示すように、芯材410は、端部412の方が中央部411よりも剛性が低くなるように形成されているため、端部412が変形して、容器100から受ける応力F1が低減する。これにより、容器100から受ける応力F1を、応力F2に近けることができ、あるいは応力F1を応力F2よりも小さくすることができる。   As shown in the figure, the core material 410 is formed such that the end portion 412 has lower rigidity than the central portion 411. Therefore, the end portion 412 is deformed and the stress F1 received from the container 100 is reduced. To reduce. Thereby, the stress F1 received from the container 100 can be close to the stress F2, or the stress F1 can be made smaller than the stress F2.

以上のように、本発明の実施の形態に係る蓄電素子10によれば、電極体400の最内周に、捲回軸に垂直の断面における長手方向の端部の方が中央部よりも剛性が低い芯材410を備える。つまり、芯材410は、捲回前の状態で、長手方向の端部の方が中央部よりも空間占有率が小さいように形成されている。また、芯材410は板状の部材から成り、当該板状の部材は、長手方向の端部の方が中央部よりも厚みが薄いように形成されている。また、芯材410は、長手方向の端部の方が中央部よりも幅が大きい空間が形成されている。このため、図9の(b)に示した電極体の端部の幅Aが中央部の幅Bの長さに近づくように電極体が変形するため、電極体400を容器100に挿入した場合の挿入係数の均一性を向上させることができ、電極体400が容器100から受ける応力の均一性を向上させることができる。これにより、電極体400の耐久性を向上させることができるため、蓄電素子10の性能を向上させることができる。   As described above, according to the electric storage element 10 according to the embodiment of the present invention, the end portion in the longitudinal direction in the cross section perpendicular to the winding axis is more rigid than the center portion on the innermost periphery of the electrode body 400. Is provided with a low core material 410. That is, the core material 410 is formed so that the end portion in the longitudinal direction has a smaller space occupancy rate than the center portion in a state before winding. Further, the core member 410 is formed of a plate-like member, and the plate-like member is formed so that the end portion in the longitudinal direction is thinner than the center portion. Further, the core material 410 has a space in which the end portion in the longitudinal direction is wider than the center portion. Therefore, when the electrode body 400 is inserted into the container 100 because the electrode body is deformed so that the width A of the end portion of the electrode body shown in FIG. 9B approaches the length of the width B of the center portion. The uniformity of the insertion coefficient can be improved, and the uniformity of the stress that the electrode body 400 receives from the container 100 can be improved. Thereby, since durability of the electrode body 400 can be improved, the performance of the electrical storage element 10 can be improved.

また、同様に、本発明の実施の形態に係る巻軸20によれば、捲回軸に垂直の断面における長手方向の端部の方が中央部よりも、捲回軸に垂直の断面における短手方向の幅が大きいように形成されている。つまり、巻軸20の端部の方が中央部よりも幅が大きいことで、電極体400の最内周において端部の方が中央部よりも幅が大きい空間が形成されることになる。これにより、図9の(b)に示した電極体の端部の幅Aが中央部の幅Bの長さに近づくように変形する電極体を形成することができる。このため、電極体400を容器100に挿入した場合の挿入係数の均一性を向上させることができ、電極体400が容器100から受ける応力の均一性を向上させることができる。   Similarly, according to the winding shaft 20 according to the embodiment of the present invention, the end in the longitudinal direction in the cross section perpendicular to the winding axis is shorter in the cross section perpendicular to the winding axis than the center. It is formed so that the width in the hand direction is large. That is, the end portion of the winding shaft 20 has a width larger than that of the center portion, so that a space having a width greater at the end portion than that of the center portion is formed in the innermost periphery of the electrode body 400. As a result, an electrode body can be formed that is deformed so that the width A of the end portion of the electrode body shown in FIG. 9B approaches the length of the width B of the center portion. For this reason, the uniformity of the insertion coefficient when the electrode body 400 is inserted into the container 100 can be improved, and the uniformity of the stress that the electrode body 400 receives from the container 100 can be improved.

(変形例1)
次に、本実施の形態の変形例1について説明する。図7は、本発明の実施の形態の変形例1に係る芯材410aの構成を示す斜視図である。
(Modification 1)
Next, Modification 1 of the present embodiment will be described. FIG. 7 is a perspective view showing the configuration of the core material 410a according to the first modification of the embodiment of the present invention.

同図に示すように、芯材410aは、長手方向(Z軸方向)の中央部分に中央部411aを備え、長手方向(Z軸方向)の両端部に端部412aを備えている。ここで、本変形例1においては、中央部411aの外周が外方に突出した曲面で形成されているところが上記実施の形態の芯材410と異なる。なお、その他の構成については、上記実施の形態における構成と同様であるため、説明は省略する。   As shown in the figure, the core material 410a includes a central portion 411a at a central portion in the longitudinal direction (Z-axis direction) and end portions 412a at both ends in the longitudinal direction (Z-axis direction). Here, in the first modification, the outer periphery of the central portion 411a is formed with a curved surface protruding outward, which is different from the core material 410 of the above embodiment. Since other configurations are the same as the configurations in the above-described embodiment, the description thereof is omitted.

このように、本変形例1に係る芯材410aは、中央部411aの方が端部412aよりもさらに厚みが厚いように形成されているため、端部412aの方が中央部411aよりもさらに剛性が低くなる。このため、電極体を容器に挿入した場合の挿入係数の均一性をさらに向上させることができ、電極体が容器から受ける応力の均一性をさらに向上させることができる。   As described above, the core member 410a according to the first modification is formed so that the central portion 411a is thicker than the end portion 412a, and thus the end portion 412a is further further than the central portion 411a. Stiffness is reduced. For this reason, the uniformity of the insertion coefficient when the electrode body is inserted into the container can be further improved, and the uniformity of the stress that the electrode body receives from the container can be further improved.

(変形例2)
次に、本実施の形態の変形例2について説明する。図8は、本発明の実施の形態の変形例2に係る芯材410bの構成を示す斜視図である。
(Modification 2)
Next, a second modification of the present embodiment will be described. FIG. 8 is a perspective view showing a configuration of a core material 410b according to Modification 2 of the embodiment of the present invention.

同図に示すように、芯材410bは、長手方向(Z軸方向)の中央部分に中央部411bを備え、長手方向(Z軸方向)の両端部に端部412bを備えている。ここで、本変形例2においては、中央部411aと端部412bとは厚みが同等であるが、端部412aの方が中央部411aよりも剛性が低い材質で成形されている。なお、その他の構成については、上記実施の形態における構成と同様であるため、説明は省略する。   As shown in the figure, the core material 410b includes a central portion 411b at a central portion in the longitudinal direction (Z-axis direction) and end portions 412b at both ends in the longitudinal direction (Z-axis direction). Here, in the second modification, the central portion 411a and the end portion 412b have the same thickness, but the end portion 412a is formed of a material having lower rigidity than the central portion 411a. Since other configurations are the same as the configurations in the above-described embodiment, the description thereof is omitted.

このように、本変形例2に係る芯材410bは、端部412aの方が中央部411aよりも剛性が低い材質で成形されているため、端部412aの方が中央部411aよりもさらに剛性が低くなる。このため、電極体を容器に挿入した場合の挿入係数の均一性を向上させることができ、電極体が容器から受ける応力の均一性を向上させることができる。   Thus, since the core part 410b which concerns on this modification 2 is shape | molded by the material whose end part 412a has lower rigidity than the center part 411a, the end part 412a is still more rigid than the center part 411a. Becomes lower. For this reason, the uniformity of the insertion coefficient when the electrode body is inserted into the container can be improved, and the uniformity of the stress that the electrode body receives from the container can be improved.

以上、本発明の実施の形態及びその変形例に係る蓄電素子及び巻軸について説明したが、本発明は、この実施の形態及びその変形例に限定されるものではない。   The power storage element and the winding shaft according to the embodiment of the present invention and the modifications thereof have been described above, but the present invention is not limited to this embodiment and the modifications thereof.

つまり、今回開示された実施の形態及びその変形例は全ての点で例示であって制限的なものではないと考えられるべきである。本発明の範囲は上記した説明ではなくて特許請求の範囲によって示され、特許請求の範囲と均等の意味及び範囲内での全ての変更が含まれることが意図される。   In other words, it should be considered that the embodiment and its modification disclosed this time are illustrative and not restrictive in all respects. The scope of the present invention is defined by the terms of the claims, rather than the description above, and is intended to include any modifications within the scope and meaning equivalent to the terms of the claims.

また、上記実施の形態及び上記変形例を任意に組み合わせて構築される形態も、本発明の範囲内に含まれる。例えば、上記変形例1における芯材410aに形成されている空間は、上記変形例2における芯材410bに形成されている空間と同じ形状であってもよい。また、上記変形例2における芯材410bの中央部411bは、上記変形例1における芯材410aの中央部411aと同様の形状であってもよい。   Moreover, the form constructed | assembled combining the said embodiment and the said modification arbitrarily is also contained in the scope of the present invention. For example, the space formed in the core material 410a in Modification 1 may have the same shape as the space formed in the core material 410b in Modification 2. Further, the central portion 411b of the core material 410b in Modification 2 may have the same shape as the central portion 411a of the core material 410a in Modification 1.

また、本発明は、このような蓄電素子10として実現することができるだけでなく、蓄電素子10が備える電極体400、または電極体400が備える芯材410として実現することもできる。   In addition, the present invention can be realized not only as such a power storage element 10 but also as an electrode body 400 included in the power storage element 10 or a core material 410 included in the electrode body 400.

本発明は、電極体が容器から受ける応力の均一性を向上させることができる蓄電素子等に適用できる。   INDUSTRIAL APPLICABILITY The present invention can be applied to a power storage element that can improve the uniformity of stress that an electrode body receives from a container.

10 蓄電素子
20 巻軸
21 中央部
22 端部
100 容器
110 ふた板
120 正極集電体
130 負極集電体
200 正極端子
300 負極端子
400 電極体
410、410a、410b 芯材
411、411a、411b 中央部
412、412a、412b 端部
420 電極部
DESCRIPTION OF SYMBOLS 10 Power storage element 20 Winding axis 21 Central part 22 End part 100 Container 110 Cover plate 120 Positive electrode current collector 130 Negative electrode current collector 200 Positive electrode terminal 300 Negative electrode terminal 400 Electrode body 410, 410a, 410b Core material 411, 411a, 411b Central part 412, 412a, 412b End 420 Electrode

Claims (7)

正極と負極とセパレータとが捲回軸周りに捲回されて形成される電極体を備える蓄電素子であって、
前記電極体は、捲回された前記正極と前記負極と前記セパレータとの最内周内方に配置される芯材を備え、
前記芯材は、前記捲回軸に垂直の断面における長手方向の端部の方が中央部よりも剛性が低い
蓄電素子。
A storage element comprising an electrode body formed by winding a positive electrode, a negative electrode, and a separator around a winding axis,
The electrode body includes a core material disposed on the innermost inner periphery of the wound positive electrode, the negative electrode, and the separator,
The power storage element in which the core member has lower rigidity at the end in the longitudinal direction in the cross section perpendicular to the winding axis than at the center.
前記捲回軸に垂直の断面における短手方向において、前記芯材の幅に対して前記芯材が占める長さの割合を空間占有率とし、
前記芯材は、前記正極と前記負極と前記セパレータとが捲回されていない状態で、前記長手方向の端部の方が中央部よりも空間占有率が小さい
請求項1に記載の蓄電素子。
In the short direction in the cross section perpendicular to the winding axis, the ratio of the length of the core material to the width of the core material is the space occupancy rate,
The power storage element according to claim 1, wherein the core material has a smaller space occupancy rate at an end portion in the longitudinal direction than at a central portion in a state where the positive electrode, the negative electrode, and the separator are not wound.
前記芯材は、板状の部材から成り、
前記板状の部材は、前記長手方向の端部の方が中央部よりも前記短手方向の厚みが薄い
請求項2に記載の蓄電素子。
The core material is composed of a plate-shaped member,
The electric storage element according to claim 2, wherein the plate-like member has a thickness in the short-side direction that is thinner at an end portion in the longitudinal direction than at a center portion.
前記芯材は、前記長手方向の端部の方が中央部よりも前記短手方向の幅が大きい空間が形成されている
請求項2または3に記載の蓄電素子。
The electrical storage element according to claim 2, wherein the core material has a space in which the end in the longitudinal direction has a width in the short-side direction larger than that in the center.
蓄電素子に備えられ、正極と負極とセパレータとが捲回軸周りに捲回されて形成される電極体であって、
捲回された前記正極と前記負極と前記セパレータとの最内周内方に配置される芯材を備え、
前記芯材は、前記捲回軸に垂直の断面における長手方向の端部の方が中央部よりも剛性が低い
電極体。
An electrode body that is provided in a storage element and is formed by winding a positive electrode, a negative electrode, and a separator around a winding axis,
A core material disposed on the innermost inner periphery of the wound positive electrode, the negative electrode, and the separator;
The core member has a lower rigidity at an end portion in a longitudinal direction in a cross section perpendicular to the winding axis than a central portion.
正極と負極とセパレータとが捲回軸周りに捲回されて形成される電極体の、捲回された前記正極と前記負極と前記セパレータとの最内周内方に配置される芯材であって、
前記芯材は、前記捲回軸に垂直の断面における長手方向の端部の方が中央部よりも剛性が低い
芯材。
A core material disposed inside the innermost circumference of the wound positive electrode, negative electrode, and separator of an electrode body formed by winding a positive electrode, a negative electrode, and a separator around a winding axis. And
The core material has a lower rigidity at the end in the longitudinal direction in the cross section perpendicular to the winding axis than at the center.
請求項1〜6のいずれか1項に記載の芯材に挿入され、正極と負極とセパレータとを捲回軸周りに捲回して電極体を形成するための巻軸であって、
前記捲回軸に垂直の断面における長手方向の端部の方が中央部よりも、前記捲回軸に垂直の断面における短手方向の幅が大きい
巻軸。
A winding shaft that is inserted into the core material according to any one of claims 1 to 6 and wound around a winding axis of a positive electrode, a negative electrode, and a separator to form an electrode body,
A winding shaft in which the end in the longitudinal direction in the cross section perpendicular to the winding axis has a greater width in the short direction in the cross section perpendicular to the winding axis than the center.
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