JP2013087265A - Soil conditioner - Google Patents

Soil conditioner Download PDF

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JP2013087265A
JP2013087265A JP2011231945A JP2011231945A JP2013087265A JP 2013087265 A JP2013087265 A JP 2013087265A JP 2011231945 A JP2011231945 A JP 2011231945A JP 2011231945 A JP2011231945 A JP 2011231945A JP 2013087265 A JP2013087265 A JP 2013087265A
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soil
mixed
soil conditioner
amino acid
sulfuric acid
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JP5846366B2 (en
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Tetsuo Fujiwara
哲丘 藤原
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TOYO SHOJI KK
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TOYO SHOJI KK
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Priority to CN2012103996458A priority patent/CN103058793A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K17/00Soil-conditioning materials or soil-stabilising materials
    • C09K17/40Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2101/00Agricultural use

Abstract

PROBLEM TO BE SOLVED: To provide a soil conditioner that has a high effect as a soil conditioner, for example, a high effect of increasing the number of viable bacteria in soil to be used while it enables to control the offensive odor emission resulting from the processing of poultry manure and stabilize the quality.SOLUTION: The soil conditioner includes poultry manure mixed with a compound of at least either calcium silicate or calcium carbonate and sulfuric acid, powdered or granulated unpolished rice, a residue of enzymatically decomposed soybean and an amino acid. Additionally, the soil conditioner includes, 0.005 to 10 pts.wt. of the amino acid and 100 pts.wt. of an agent containing the poultry manure, the unpolished rice and the residue of enzymatically decomposed soybean.

Description

本発明は、養鶏場等で大量に発生するため、廃棄処理が社会的問題となっている鶏糞を利用した土壌改良剤に関する。 The present invention relates to a soil conditioner that uses chicken manure, which is a social problem because it occurs in large quantities in poultry farms and the like.

従来、養鶏場等においては、鶏糞が大量に発生するため、その廃棄処理を巡って社会的な問題となっているが、鶏糞には農作物に有用な有機化合物が含有されており、土壌改良剤や肥料として有効活用されている。鶏糞を土壌改良剤や肥料として利用するためには、天日によって自然乾燥させたり、燃料を使用することによって強制的に乾燥させたり、さらには発酵処理を施されたりしている。   Conventionally, poultry manure is generated in large quantities in poultry farms and the like, and this has become a social problem over its disposal. However, chicken manure contains organic compounds that are useful for agricultural crops and is a soil conditioner. It is effectively used as a fertilizer. In order to use chicken manure as a soil conditioner or fertilizer, it is naturally dried by the sun, forcibly dried by using fuel, or further subjected to a fermentation treatment.

そして、鶏糞を土壌改良や肥料として使用するために、鶏糞をそのまま天日によって自然乾燥させたり、燃料を使用することによって強制的に乾燥させたりする方法では、腐敗等による悪臭が発生したり、処理を終えるまでに多くの時間を要したり、処理の費用が高額になるという問題や、さらには発酵処理を施されたりしても、発酵によって有害なガスが発生する可能性があり、その発酵の制御するために長年蓄積された経験や技術が必要であるため安定な品質の土壌改良剤や肥料を製造することが困難であるという問題があったが、種々の解決が図られた。   And in order to use chicken manure as a soil improvement and fertilizer, chicken manure is naturally dried by the sun as it is, or by forced drying by using fuel, bad odor due to spoilage etc. occurs, Even if it takes a lot of time to finish the process, the cost of the process is high, and even if it is subjected to a fermentation process, harmful gases may be generated by the fermentation. There are problems that it is difficult to produce a soil improver and fertilizer of stable quality because experience and technology accumulated over many years are necessary to control the fermentation, but various solutions have been achieved.

例えば、特許文献1には、カルシウム塩、硫酸を添加、混合された鶏糞を主成分とし、それに粉粒化した玄米と大豆酵素の分解後の残渣を混合させた土壌改良剤が開示されている。また、その土壌改良剤に腐葉土を混合させた土壌改良剤も開示されている。   For example, Patent Document 1 discloses a soil conditioner in which calcium salt and sulfuric acid are added and mixed with chicken dung, which is a main component, and granulated brown rice and a residue after decomposition of soybean enzymes are mixed. . Moreover, the soil improvement agent which mixed the humus soil with the soil improvement agent is also disclosed.

特許第4392542号公報Japanese Patent No. 4392542

しかしながら、上述の特許文献1に記載の土壌改良剤では、腐敗等により悪臭の発生や、安定な品質の土壌改良剤を製造することが困難であるという従来の課題は解決できたものの、使用する土壌中の一般生菌数を増加させる効果としては十分とはいえなかった。すなわち、養鶏場等で大量に発生する鶏糞である産業廃棄物を土壌改良剤という経営資源として有効活用できるという観点から、養鶏場等の運営業者にとってはメリットがあるものの、それを利用する農業関係者からすると、特許文献1に記載の土壌改良剤では、土壌改良剤としての効果、例えば、使用する土壌中の一般生菌数を増加させる効果に対する魅力が低く、さらなる改良が求められていた。   However, the soil improver described in Patent Document 1 described above is used although the conventional problem that it is difficult to produce a bad odor due to spoilage or the like and to produce a soil improver having a stable quality is used. The effect of increasing the number of general viable bacteria in the soil was not sufficient. In other words, from the standpoint that industrial waste, which is a large amount of poultry manure generated at poultry farms, can be effectively used as a management resource called a soil conditioner, there is a merit for operators of poultry farms, etc. From the viewpoint of the person skilled in the art, the soil improver described in Patent Document 1 is less attractive for the effect as a soil improver, for example, the effect of increasing the number of viable bacteria in the soil used, and further improvement has been demanded.

また、特許文献1に記載の土壌改良剤では、一般に養分として知られる腐葉土を混合した土壌改良剤についても、一般生菌数の増加について実験されているが、やはり農業関係者からは、さらに効果が高い土壌改良剤が求められていた。   In addition, the soil conditioner described in Patent Document 1 has been experimented on the increase in the number of general viable bacteria for a soil conditioner mixed with humus, which is generally known as a nutrient. There was a need for a high soil conditioner.

そこで、本発明では、鶏糞の加工による悪臭の発生や、品質を安定にすることができつつも、土壌改良剤としての効果、例えば、使用する土壌中の一般生菌数を増加させる効果が高い土壌改良剤を提供することを目的とする。   Therefore, in the present invention, the generation of malodors due to processing of chicken manure and the quality can be stabilized, but the effect as a soil conditioner, for example, the effect of increasing the number of general viable bacteria in the soil to be used is high. An object is to provide a soil conditioner.

すなわち、本発明に係る土壌改良剤は、少なくともケイ酸カルシウム又は炭酸カルシウムのいずれかの化合物、及び、硫酸を混合された鶏糞と、粉粒化した玄米と、大豆酵素分解残渣と、アミノ酸と、を含有することを特徴とする土壌改良剤である。   That is, the soil conditioner according to the present invention includes at least any compound of calcium silicate or calcium carbonate, and chicken dung mixed with sulfuric acid, granulated brown rice, soybean enzymatic decomposition residue, amino acid, It is a soil improvement agent characterized by containing.

そして、前記鶏糞、前記玄米、及び、前記大豆酵素分解残渣を含有する剤100重量部に対して、前記アミノ酸が0.005〜10重量部配合されている上記の土壌改良剤である。   And it is said soil improving agent by which 0.005-10 weight part of said amino acids are mix | blended with respect to 100 weight part of agents containing the said chicken dung, the said brown rice, and the said soybean enzyme degradation residue.

そして、前記アミノ酸が、少なくともグルタミン酸、アルギニン、アスパラギン酸、フェニルアラニン、又は、シスチンのいずれかを含有する上記の土壌改良剤である。   And said amino acid is said soil improving agent containing at least any one of glutamic acid, arginine, aspartic acid, phenylalanine, or cystine.

このように構成すれば鶏糞の加工による悪臭の発生や、品質を安定にすることができつつも、土壌改良剤としての効果、例えば、使用する土壌中の一般生菌数を増加させる効果を高くすることができる。   If configured in this way, the generation of bad odor due to processing of chicken manure and the quality can be stabilized, but the effect as a soil conditioner, for example, the effect of increasing the number of general viable bacteria in the soil to be used is high. can do.

以上、説明したように本発明によれば、鶏糞の加工による悪臭の発生や、品質を安定にすることができつつも、土壌改良剤としての効果、例えば、使用する土壌中の一般生菌数を増加させる効果を高くすることができる。   As described above, according to the present invention, as described above, the generation of bad odor due to processing of chicken manure and the effect as a soil improver while being able to stabilize the quality, for example, the number of viable bacteria in the soil to be used The effect of increasing can be increased.

以下、本発明に係る土壌改良剤に関する実施形態について詳しく説明する。なお、説明中における範囲を示す表記は、上限と下限を含有するものである。   Hereinafter, the embodiment regarding the soil improvement agent which concerns on this invention is described in detail. In addition, the description which shows the range in description contains an upper limit and a minimum.

本発明に係る土壌改良剤は、少なくともケイ酸カルシウム又は炭酸カルシウムのいずれかの化合物、及び、硫酸を混合された鶏糞と、粉粒化した玄米と、大豆酵素分解残渣と、アミノ酸と、を含有することを特徴とするが、例えば、以下のように製造される。   The soil conditioner according to the present invention contains at least a compound of either calcium silicate or calcium carbonate, and chicken dung mixed with sulfuric acid, granulated brown rice, soybean enzyme degradation residue, and amino acids. For example, it is manufactured as follows.

本発明において使用される鶏糞は、養鶏場等で大量に発生したものを何も加工せずに回収して用いることができる。ケイ酸カルシウム、炭酸カルシウムは、鶏糞を粒状化するために使用され、これらのうち少なくともいずれかの化合物を混合されれば良いが、両方とも混合されても良い。この化合物、又は、これらの化合物は、鶏糞100重量部に対して10〜20重量部混合される。   The chicken manure used in the present invention can be recovered and used without processing anything that has been generated in large quantities in a poultry farm or the like. Calcium silicate and calcium carbonate are used to granulate chicken dung, and at least one of these compounds may be mixed, but both may be mixed. This compound or these compounds are mixed in an amount of 10 to 20 parts by weight per 100 parts by weight of chicken manure.

さらに、硫酸は、鶏糞中の塩基性化合物と反応させて中和させるために混合されるものであり、市販されている濃硫酸を使用することができるし、その濃硫酸を水で希釈した希硫酸を使用することもできる。この硫酸は、鶏糞100重量部に対して3〜15重量部混合される。   Furthermore, sulfuric acid is mixed to react with the basic compound in chicken manure to neutralize it. Commercially available concentrated sulfuric acid can be used, and diluted sulfuric acid diluted with water. Sulfuric acid can also be used. This sulfuric acid is mixed in an amount of 3 to 15 parts by weight with respect to 100 parts by weight of chicken manure.

このように、鶏糞に、少なくともケイ酸カルシウム又は炭酸カルシウムのいずれかの化合物と、硫酸とが混合されるが、少なくともケイ酸カルシウム又は炭酸カルシウムのいずれかの化合物と硫酸とは、何れを先に鶏糞に混合しても、同時に混合してもよいが、悪臭を効果的に除去するためには、硫酸を先に添加する方が好ましい。鶏糞に硫酸を添加し充分に混合した後、少なくともケイ酸カルシウム又は炭酸カルシウムのいずれかの化合物を混合すると、鶏糞の粘稠な形態が団子状の塊へと変化する。さらに、団子状の塊となった鶏糞を粉砕機や粉粒機にかけるなどして、粒状化させる。   Thus, at least any compound of calcium silicate or calcium carbonate and sulfuric acid are mixed with chicken manure, but at least either of the compound of calcium silicate or calcium carbonate and sulfuric acid is first of all. Although it may be mixed with chicken manure or simultaneously, it is preferable to add sulfuric acid first in order to effectively remove malodor. When sulfuric acid is added to chicken dung and mixed well, at least one compound of calcium silicate or calcium carbonate is mixed, and the viscous form of chicken dung changes into a dumpling lump. Furthermore, the chicken dung which became dumpling-like lump is granulated by, for example, applying it to a grinder or a granulator.

本発明において使用される粉粒化した玄米は、粉状又は粒状まで玄米を粉砕されたものあればよく、下記の実施例にて使用した玄米を高熱焙煎して粉粒化したものに限定されるものではない。この粉粒化した玄米は、上記の少なくともケイ酸カルシウム又は炭酸カルシウムのいずれかの化合物、及び、硫酸を混合された鶏糞100重量部に対して1〜3重量部混合される。また、大豆酵素分解残渣は、大豆を麹菌で発酵させた後、直ちに酵素分解させてエキス抽出した後の残渣等が混合され、上記の少なくともケイ酸カルシウム又は炭酸カルシウムのいずれかの化合物、及び、硫酸を混合された鶏糞100重量部に対して1〜3重量部混合される。   The pulverized brown rice used in the present invention only needs to be obtained by pulverizing the brown rice into a powdery or granular form, and is limited to those pulverized by high-heat roasting of the brown rice used in the following examples. Is not to be done. This granulated brown rice is mixed in an amount of 1 to 3 parts by weight with respect to 100 parts by weight of chicken manure mixed with at least one of the compounds of calcium silicate or calcium carbonate and sulfuric acid. In addition, the soybean enzymatic degradation residue is fermented with Aspergillus oryzae, immediately after enzymatic digestion and extract extraction, etc. are mixed, and at least one of the above compounds of calcium silicate or calcium carbonate, and 1 to 3 parts by weight is mixed with 100 parts by weight of chicken dung mixed with sulfuric acid.

そして、本発明において使用されるアミノ酸は、分子中にアミノ基とカルボキシル基の両方の官能基を備える有機化合物であり、土壌中の一般生菌の増加に大きく寄与する素材である。このようなアミノ酸として、例えば、アラニン、アルギニン、アスパラギン、アスパラギン酸、システイン、グルタミン、グルタミン酸、グリシン、ヒスチジン、イソロイシン、ロイシン、リシン、メチオニン、フェニルアラニン、プロリン、セリン、トレオニン、トリプトファン、チロシン、バリンなどのアミノ酸、そして、これらのアミノ酸がアミノ基とカルボキシル基が脱水縮合して得られる二量体であるシスチンなどが好ましい。そして、上記のうち、グルタミン酸、アルギニン、アスパラギン酸、フェニルアラニン、シスチンなどが、より好ましい。なお、これらのアミノ酸は、1種類のみ、又は、2種類以上組み合わせて使用することができる。また、アミノ酸は、前記鶏糞、前記玄米、及び、前記大豆酵素分解残渣を含有する剤100重量部に対して0.005〜10重量部配合されることが好ましく、0.01〜5重量部配合されることがさらに好ましい。この範囲の配合量であると、土壌中の一般生菌数を従来に比べ大幅に増加させることができ、さらに、必要以上のアミノ酸を添加しても効果が逆に下がる傾向にあるのでアミノ酸添加によるコストの増加も抑制することができる。これらの液状、又は、固体状のアミノ酸をそのまま混合してもよいが、一度水に溶解させてから、少なくともケイ酸カルシウム又は炭酸カルシウムのいずれかの化合物、及び、硫酸を混合された鶏糞と、粉粒化した玄米と、大豆酵素分解残渣とを含有する剤に含浸させて混合してもよい。   And the amino acid used in this invention is an organic compound provided with the functional group of both an amino group and a carboxyl group in a molecule | numerator, and is a raw material which contributes greatly to the increase in the general living microbe in soil. Examples of such amino acids include alanine, arginine, asparagine, aspartic acid, cysteine, glutamine, glutamic acid, glycine, histidine, isoleucine, leucine, lysine, methionine, phenylalanine, proline, serine, threonine, tryptophan, tyrosine, and valine. Preferred are amino acids, and cystine, which is a dimer obtained by dehydrating condensation of an amino group and a carboxyl group of these amino acids. Of the above, glutamic acid, arginine, aspartic acid, phenylalanine, cystine and the like are more preferable. These amino acids can be used alone or in combination of two or more. The amino acid is preferably added in an amount of 0.005 to 10 parts by weight, and 0.01 to 5 parts by weight based on 100 parts by weight of the agent containing the chicken dung, the brown rice, and the soybean enzyme degradation residue. More preferably. If the amount is within this range, the number of viable bacteria in the soil can be greatly increased compared to the conventional method, and even if more amino acids are added, the effect tends to decrease. The increase in cost due to can also be suppressed. These liquid or solid amino acids may be mixed as they are, but once dissolved in water, at least any compound of calcium silicate or calcium carbonate, and chicken manure mixed with sulfuric acid, You may impregnate and mix the agent containing a granulated brown rice and a soybean enzyme degradation residue.

なお、土壌中の一般生菌数の増加に影響の及ばない範囲内において、必要に応じて本発明に種々の添加剤を加えることができる。   In addition, various additives can be added to this invention as needed within the range which does not affect the increase in the number of general viable bacteria in soil.

以上のようにして各種成分を含有する土壌改良剤が粒粉化されて製造される。また、この粒粉化された土壌改良剤を打錠機などによって、ペレット化してもよい。   As described above, the soil conditioner containing various components is granulated and manufactured. The granulated soil conditioner may be pelletized by a tableting machine or the like.

次に、本発明の土壌改良剤についての好ましい実施例を挙げ、その土壌改良剤を使用した際の一般生菌数の増加について測定した結果を示す。   Next, the preferable Example about the soil improvement agent of this invention is given, and the result measured about the increase in the number of general viable bacteria at the time of using the soil improvement agent is shown.

<実施例1>
鶏糞100gに対して、ケイ酸カルシウム5g、炭酸カルシウム5g、及び、濃硫酸10gを添加し、混合してから、粉粒機にかけて粒状化した。そして、この粒状化した混合鶏糞100gに対して、粉粒化した玄米1g、及び、大豆酵素分解後残渣1gを添加し、混合した。そして、上記のケイ酸カルシウム、炭酸カルシウム、濃硫酸を混合された鶏糞と、粉粒化した玄米と、大豆酵素分解残渣とを包含する剤100gに、グルタミン酸、アルギニン、アスパラギン酸、フェニルアラニン、シスチンを含有する濃度0.01g/mlの混合アミノ酸水溶液を1ml噴霧した。以上の方法によって、土壌改良剤を得た。
<Example 1>
To 100 g of chicken manure, 5 g of calcium silicate, 5 g of calcium carbonate, and 10 g of concentrated sulfuric acid were added and mixed, and then granulated using a granulator. And 1g of granulated brown rice and 1g of soybean enzyme-decomposed residues were added to and mixed with 100g of this granulated mixed chicken manure. Then, glutamic acid, arginine, aspartic acid, phenylalanine, cystine are added to 100 g of an agent containing chicken feces mixed with calcium silicate, calcium carbonate, and concentrated sulfuric acid, granulated brown rice, and soybean enzymatic residue. 1 ml of a mixed amino acid aqueous solution having a concentration of 0.01 g / ml was sprayed. The soil improvement agent was obtained by the above method.

<実施例2>
上記の実施例1のうち、混合アミノ酸水溶液を5ml噴霧した以外は、実施例1と同様に土壌改良剤を製造した。
<Example 2>
A soil improver was produced in the same manner as in Example 1 except that 5 ml of the mixed amino acid aqueous solution was sprayed.

<実施例3>
上記の実施例1のうち、混合アミノ酸水溶液を10ml噴霧した以外は、実施例1と同様に土壌改良剤を製造した。
<Example 3>
A soil improver was produced in the same manner as in Example 1 except that 10 ml of the mixed amino acid aqueous solution was sprayed.

<実施例4>
上記の実施例1のうち、混合アミノ酸水溶液を50ml噴霧した以外は、実施例1と同様に土壌改良剤を製造した。
<Example 4>
A soil improver was produced in the same manner as in Example 1 except that 50 ml of the mixed amino acid aqueous solution was sprayed.

<比較例1>
上記の実施例1のうち、混合アミノ酸水溶液を全く噴霧しなかった以外は、実施例1と同様に製剤を製造した。
<Comparative Example 1>
A preparation was prepared in the same manner as in Example 1 except that the mixed amino acid aqueous solution was not sprayed at all.

これら実施例1〜4、比較例1で製造したものを用いて、それぞれ0.01gずつシャーレに分配して、分配前(初期値)及び24時間37℃で培養した後の一般生菌数について測定した。その測定結果を表1に示す。   About the number of general viable bacteria after distributing at 0.01g each petri dish using what manufactured in these Examples 1-4 and comparative example 1, and cultivating at 37 degreeC before distribution (initial value) and 24 hours. It was measured. The measurement results are shown in Table 1.

Figure 2013087265
Figure 2013087265

上記の測定結果から、本発明の土壌改良剤は、何れの実施例においても、比較例よりも一般生菌数を増加させる効果が高いことがわかり、特に、ケイ酸カルシウム、炭酸カルシウム、濃硫酸を混合された鶏糞と、粉粒化した玄米と、大豆酵素分解残渣とを包含する剤100gに、濃度0.01g/mlの混合アミノ酸水溶液を10ml、50ml噴霧して製造した土壌改良剤では、混合アミノ酸水溶液を噴霧しない場合に比べて10倍以上の効果を示すことがわかり、単に鶏糞の再利用という観点だけではなく、土壌改良剤そのものとして非常に有用であることがわかった。   From the above measurement results, it can be seen that the soil conditioner of the present invention has a higher effect of increasing the number of general viable bacteria than any of the comparative examples, in particular, calcium silicate, calcium carbonate, concentrated sulfuric acid. In a soil conditioner manufactured by spraying 10 ml and 50 ml of a mixed amino acid aqueous solution having a concentration of 0.01 g / ml to 100 g of an agent containing chicken dung mixed with rice, granulated brown rice, and soybean enzyme degradation residue, It was found that the effect of 10 times or more compared with the case where the mixed amino acid aqueous solution was not sprayed, was found to be very useful not only as a reuse of chicken manure but also as a soil conditioner itself.

Claims (3)

少なくともケイ酸カルシウム又は炭酸カルシウムのいずれかの化合物、及び、硫酸を混合された鶏糞と、
粉粒化した玄米と、
大豆酵素分解残渣と、
アミノ酸と、
を含有することを特徴とする土壌改良剤。
Chicken dung mixed with at least a compound of either calcium silicate or calcium carbonate, and sulfuric acid,
Pulverized brown rice,
Soy enzyme degradation residue,
Amino acids,
A soil conditioner comprising:
前記鶏糞、前記玄米、及び、前記大豆酵素分解残渣を含有する剤100重量部に対して、前記アミノ酸が0.005〜10重量部配合されていることを特徴とする請求項1に記載の土壌改良剤。 The soil according to claim 1, wherein 0.005 to 10 parts by weight of the amino acid is blended with respect to 100 parts by weight of the agent containing the chicken dung, the brown rice, and the soybean enzyme degradation residue. Improver. 前記アミノ酸が、少なくともグルタミン酸、アルギニン、アスパラギン酸、フェニルアラニン、又は、シスチンのいずれかを含有することを特徴とする請求項1又は請求項2に記載の土壌改良剤。 The soil improver according to claim 1 or 2, wherein the amino acid contains at least one of glutamic acid, arginine, aspartic acid, phenylalanine, or cystine.
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