JP2012514072A - ディーゼルバイオ原料および重質油の共処理 - Google Patents
ディーゼルバイオ原料および重質油の共処理 Download PDFInfo
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- JP2012514072A JP2012514072A JP2011543498A JP2011543498A JP2012514072A JP 2012514072 A JP2012514072 A JP 2012514072A JP 2011543498 A JP2011543498 A JP 2011543498A JP 2011543498 A JP2011543498 A JP 2011543498A JP 2012514072 A JP2012514072 A JP 2012514072A
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- hydrotreating
- dewaxing
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- hydrocracking
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
- C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
- C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/12—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
- C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1011—Biomass
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/202—Heteroatoms content, i.e. S, N, O, P
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/04—Diesel oil
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/10—Lubricating oil
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
【選択図】図1
Description
Claims (16)
- 潤滑油基材の製造方法であって、
少なくとも100vppmの硫黄を含む原料材を、第一の効果的な水素化処理条件下に水素化処理して、第一の水素化処理流出油を製造する工程;
前記第一の水素化処理流出油を、水素化分解触媒の存在下で、効果的な水素化分解条件下に水素化分解する工程;
全水素化分解流出油を、分離なしに、接触脱ロウ段へカスケードする工程;
全水素化分解流出油を、効果的な接触脱ロウ条件下に脱ロウする工程;および
全脱ロウ/水素化分解流出油を、第二の効果的な水素化処理条件下に水素化処理する工程
を含むことを特徴とする方法。 - 前記水素化処理/脱ロウ/水素化分解流出油を分留して、少なくとも潤滑油基材部分を製造する工程;および
前記潤滑油基材部分を脱ロウする工程
を更に含むことを特徴とする請求項1に記載の方法。 - 前記潤滑油基材部分を脱ロウする工程は、
前記潤滑油基材部分を溶剤脱ロウする工程、および
前記潤滑油基材部分を接触脱ロウする工程
のうち少なくとも1つを含むことを特徴とする請求項2に記載の方法。 - ディーゼル燃料の製造方法であって、
少なくとも100vppmの硫黄を含む原料材を、第一の効果的な水素化処理条件下に水素化処理して、第一の水素化処理流出油を製造する工程;
前記第一の水素化処理流出油を、水素化分解触媒の存在下で、効果的な水素化分解条件下に水素化分解する工程;
全水素化分解流出油を、分離なしに、接触脱ロウ段へカスケードする工程;
全水素化分解流出油を、効果的な接触脱ロウ条件下に脱ロウする工程;および
全脱ロウ/水素化分解流出油を、第二の効果的な水素化処理条件下に水素化処理する工程
を含むことを特徴とする方法。 - 前記水素化処理/脱ロウ/水素化分解流出油を分留して、少なくともディーゼル沸点範囲留分および潤滑油基材留分を製造する工程を更に含むことを特徴とする請求項4に記載の方法。
- 前記第一の水素化処理流出油は、分離なしに、水素化分解工程へカスケードされることを特徴とする請求項1〜5のいずれかに記載の方法。
- 前記原料材は、少なくとも10vppmの窒素を含むことを特徴とする請求項1〜6のいずれかに記載の方法。
- 前記脱ロウ触媒は、SiO2:Al2O3比100以下を有するモレキュラーシーブおよび金属酸化物結合剤を含み、
前記脱ロウ触媒は、ゼオライト表面積/外表面積の比率少なくとも80:100を有することを特徴とする請求項1〜7のいずれかに記載の方法。 - 前記モレキュラーシーブは、一次元10員環細孔を有することを特徴とする請求項8に記載の方法。
- 前記モレキュラーシーブは、EU−1、ZSM−35、ZSM−11、ZSM−57、NU−87、ZSM−22、EU−2、EU−11、ZBM−30、ZSM−48、ZSM−23またはそれらの組み合わせ、好ましくはEU−2、EU−11、ZBM−30、ZSM−48、ZSM−23またはそれらの組み合わせ、より好ましくはZSM−48、ZSM−23またはそれらの組み合わせ、更により好ましくはZSM−48であることを特徴とする請求項8に記載の方法。
- 前記SiO2:Al2O3の比は、80以下、好ましくは75以下、より好ましくは60以下であることを特徴とする請求項8〜10のいずれかに記載の方法。
- 粉末形態の前記金属酸化物結合剤は、表面積80m2/g以下、好ましくは60m2/g以下を有することを特徴とする請求項8〜11のいずれかに記載の方法。
- 前記脱ロウ触媒は、ゼオライト表面積/外表面積の比率少なくとも90:100、好ましくは少なくとも1:1、より好ましくは少なくとも105:100を有することを特徴とする請求項8〜12のいずれかに記載の方法。
- 前記結合剤は、シリカ、アルミナ、チタニア、ジルコニアまたはシリカ−アルミナであることを特徴とする請求項8〜13のいずれかに記載の方法。
- 前記結合剤は、更に、第一の金属酸化物と異なる第二の金属酸化物を含むことを特徴とする請求項8〜14のいずれかに記載の方法。
- 前記第二の金属酸化物は、シリカ、アルミナ、チタニア、ジルコニアまたはシリカ−アルミナであることを特徴とする請求項15に記載の方法。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US20362708P | 2008-12-24 | 2008-12-24 | |
US61/203,627 | 2008-12-24 | ||
US12/653,459 US8632675B2 (en) | 2008-12-24 | 2009-12-15 | Co-processing of diesel biofeed and heavy oil |
US12/653,459 | 2009-12-15 | ||
PCT/US2009/006695 WO2010074756A2 (en) | 2008-12-24 | 2009-12-23 | Co-processing of diesel biofeed and heavy oil |
Publications (1)
Publication Number | Publication Date |
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JP2012514072A true JP2012514072A (ja) | 2012-06-21 |
Family
ID=41698525
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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JP2011543498A Ceased JP2012514072A (ja) | 2008-12-24 | 2009-12-23 | ディーゼルバイオ原料および重質油の共処理 |
Country Status (8)
Country | Link |
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US (1) | US8632675B2 (ja) |
EP (1) | EP2376605A2 (ja) |
JP (1) | JP2012514072A (ja) |
CN (1) | CN102282238A (ja) |
AU (1) | AU2009330666A1 (ja) |
CA (1) | CA2747862A1 (ja) |
SG (1) | SG172271A1 (ja) |
WO (1) | WO2010074756A2 (ja) |
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US8734638B2 (en) * | 2009-06-19 | 2014-05-27 | Exxonmobil Research And Engineering Company | Ebullating bed methods for treatment of biocomponent feedstocks |
US20110184105A1 (en) * | 2009-09-29 | 2011-07-28 | Exxonmobil Research And Engineering Company | Phenylene Oxo-Diester Plasticizers and Methods of Making |
JP5789272B2 (ja) * | 2010-03-09 | 2015-10-07 | エクソンモービル リサーチ アンド エンジニアリング カンパニーExxon Research And Engineering Company | 再生可能ディーゼル燃料の脱ロウ処理 |
US8729330B2 (en) * | 2010-03-09 | 2014-05-20 | Exxonmobil Research And Engineering Company | Hydroprocessing of diesel range biomolecules |
US8906236B2 (en) * | 2010-07-26 | 2014-12-09 | Sapphire Energy, Inc. | Process for the recovery of oleaginous compounds and nutrients from biomass |
BR112013002003A2 (pt) | 2010-07-26 | 2019-09-24 | Sapphire Energy Inc | processo para recuperação de compostos oleaginosos de biomassa |
US9028696B2 (en) | 2010-07-26 | 2015-05-12 | Sapphire Energy, Inc. | Process for the recovery of oleaginous compounds from biomass |
US8704020B2 (en) | 2010-12-13 | 2014-04-22 | Exxonmobil Research And Engineering Company | Catalytic hydrothermal treatment of biomass |
US8704019B2 (en) | 2010-12-13 | 2014-04-22 | Exxonmobil Research And Engineering Company | Catalyst recovery in hydrothermal treatment of biomass |
US8487148B2 (en) | 2010-12-13 | 2013-07-16 | Exxonmobil Research And Engineering Company | Hydrothermal treatment of biomass with heterogeneous catalyst |
US8624070B2 (en) | 2010-12-13 | 2014-01-07 | Exxonmobil Research And Engineering Company | Phosphorus recovery from hydrothermal treatment of biomass |
ES2482915B1 (es) * | 2011-06-23 | 2015-07-03 | Foster Wheeler Usa Corporation | Proceso para la producción de biocombustibles por coprocesamiento de biomasa en una unidad de procesamiento térmico en una refinería. |
US8911514B2 (en) | 2011-12-15 | 2014-12-16 | Uop Llc | Hydrotreating methods and hydrotreating systems |
US9598645B2 (en) | 2012-03-30 | 2017-03-21 | Exxonmobil Research And Engineering Company | Coprocessing of biofeeds with group VI metal catalysts |
US9464238B2 (en) | 2012-03-30 | 2016-10-11 | Exxonmobil Research And Engineering Company | Production of olefinic diesel, lubricants, and propylene |
US9708544B2 (en) | 2012-03-30 | 2017-07-18 | Exxonmobil Research And Engineering Company | Production of olefinic diesel and corresponding oligomers |
US20130338414A1 (en) * | 2012-06-04 | 2013-12-19 | Exxonmobil Research And Engineering Company | Hydrodesulfurization, deoxygenation and dewaxing processes with water stable catalysts for biomass-containing hydrocarbon feedstocks |
US10160923B2 (en) | 2014-11-05 | 2018-12-25 | Uop Llc | Processes for maximizing high quality distillate |
US11873455B2 (en) | 2020-12-30 | 2024-01-16 | Chevron U.S.A. Inc. | Process having improved base oil yield |
CA3240660A1 (en) * | 2021-12-30 | 2023-07-06 | Neste Oyj | Producing hydrocarbons from organic material of biological origin |
CN115232642B (zh) * | 2022-05-09 | 2023-12-12 | 北京航空航天大学 | 一种生物油脂与重油共炼制航油的装置及方法 |
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- 2009-12-15 US US12/653,459 patent/US8632675B2/en active Active
- 2009-12-23 EP EP09796160A patent/EP2376605A2/en not_active Withdrawn
- 2009-12-23 SG SG2011045028A patent/SG172271A1/en unknown
- 2009-12-23 CN CN2009801526365A patent/CN102282238A/zh active Pending
- 2009-12-23 CA CA2747862A patent/CA2747862A1/en not_active Abandoned
- 2009-12-23 AU AU2009330666A patent/AU2009330666A1/en not_active Abandoned
- 2009-12-23 JP JP2011543498A patent/JP2012514072A/ja not_active Ceased
- 2009-12-23 WO PCT/US2009/006695 patent/WO2010074756A2/en active Search and Examination
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Also Published As
Publication number | Publication date |
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SG172271A1 (en) | 2011-07-28 |
WO2010074756A3 (en) | 2011-05-26 |
WO2010074756A2 (en) | 2010-07-01 |
CA2747862A1 (en) | 2010-07-01 |
US20100176026A1 (en) | 2010-07-15 |
CN102282238A (zh) | 2011-12-14 |
EP2376605A2 (en) | 2011-10-19 |
AU2009330666A1 (en) | 2011-07-14 |
US8632675B2 (en) | 2014-01-21 |
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