JP2012508298A5 - - Google Patents

Info

Publication number

JP2012508298A5

JP2012508298A5 JP2011535701A JP2011535701A JP2012508298A5 JP 2012508298 A5 JP2012508298 A5 JP 2012508298A5 JP 2011535701 A JP2011535701 A JP 2011535701A JP 2011535701 A JP2011535701 A JP 2011535701A JP 2012508298 A5 JP2012508298 A5 JP 2012508298A5

Authority

JP

Japan

Prior art keywords

ion

group

refrigerant

liquid

composition

Prior art date

2009-11-06

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Abandoned

Links

• Espacenet
• Global Dossier
• Discuss

• 239000003507 refrigerant Substances 0.000 claims 26
• -1 tetrachloroborate ion Chemical class 0.000 claims 25
• 239000000203 mixture Substances 0.000 claims 22
• 239000007788 liquid Substances 0.000 claims 18
• 150000001450 anions Chemical class 0.000 claims 7
• 229910052794 bromium Inorganic materials 0.000 claims 7
• 229910052801 chlorine Inorganic materials 0.000 claims 7
• 229910052731 fluorine Inorganic materials 0.000 claims 7
• 125000002009 alkene group Chemical group 0.000 claims 6
• 150000001924 cycloalkanes Chemical group 0.000 claims 6
• 125000005842 heteroatom Chemical group 0.000 claims 6
• 229910052757 nitrogen Inorganic materials 0.000 claims 6
• 229910052760 oxygen Inorganic materials 0.000 claims 6
• 150000008040 ionic compounds Chemical class 0.000 claims 5
• 238000000034 method Methods 0.000 claims 5
• 229910052710 silicon Inorganic materials 0.000 claims 5
• QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 4
• 230000002745 absorbent Effects 0.000 claims 4
• 239000002250 absorbent Substances 0.000 claims 4
• 238000010521 absorption reaction Methods 0.000 claims 4
• RWRIWBAIICGTTQ-UHFFFAOYSA-N difluoromethane Chemical compound FCF RWRIWBAIICGTTQ-UHFFFAOYSA-N 0.000 claims 4
• 125000001072 heteroaryl group Chemical group 0.000 claims 4
• 229910052740 iodine Inorganic materials 0.000 claims 4
• 150000002500 ions Chemical class 0.000 claims 4
• 239000006096 absorbing agent Substances 0.000 claims 3
• 150000001768 cations Chemical class 0.000 claims 3
• 125000004122 cyclic group Chemical group 0.000 claims 3
• 150000008282 halocarbons Chemical class 0.000 claims 3
• 229910052717 sulfur Inorganic materials 0.000 claims 3
• LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 claims 2
• UJPMYEOUBPIPHQ-UHFFFAOYSA-N 1,1,1-trifluoroethane Chemical compound CC(F)(F)F UJPMYEOUBPIPHQ-UHFFFAOYSA-N 0.000 claims 2
• WXGNWUVNYMJENI-UHFFFAOYSA-N 1,1,2,2-tetrafluoroethane Chemical compound FC(F)C(F)F WXGNWUVNYMJENI-UHFFFAOYSA-N 0.000 claims 2
• NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 claims 2
• CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 2
• DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims 2
• WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims 2
• PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 2
• ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 2
• 125000003282 alkyl amino group Chemical group 0.000 claims 2
• 125000000217 alkyl group Chemical group 0.000 claims 2
• 229910021529 ammonia Inorganic materials 0.000 claims 2
• 125000003118 aryl group Chemical group 0.000 claims 2
• 238000010438 heat treatment Methods 0.000 claims 2
• WZNJWVWKTVETCG-UHFFFAOYSA-N kojic acid Natural products OC(=O)C(N)CN1C=CC(=O)C(O)=C1 WZNJWVWKTVETCG-UHFFFAOYSA-N 0.000 claims 2
• 229910052744 lithium Inorganic materials 0.000 claims 2
• WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims 2
• GTLACDSXYULKMZ-UHFFFAOYSA-N pentafluoroethane Chemical compound FC(F)C(F)(F)F GTLACDSXYULKMZ-UHFFFAOYSA-N 0.000 claims 2
• 229910052700 potassium Inorganic materials 0.000 claims 2
• 239000011591 potassium Substances 0.000 claims 2
• 125000001424 substituent group Chemical group 0.000 claims 2
• 125000000547 substituted alkyl group Chemical group 0.000 claims 2
• 125000003107 substituted aryl group Chemical group 0.000 claims 2
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
• UIERETOOQGIECD-ARJAWSKDSA-M 2-Methyl-2-butenoic acid Natural products C\C=C(\C)C([O-])=O UIERETOOQGIECD-ARJAWSKDSA-M 0.000 claims 1
• NIPWFPYJCVZBSC-UHFFFAOYSA-M 2-hydroxyethyl(trimethyl)phosphanium;chloride Chemical compound [Cl-].C[P+](C)(C)CCO NIPWFPYJCVZBSC-UHFFFAOYSA-M 0.000 claims 1
• 125000001054 5 membered carbocyclic group Chemical group 0.000 claims 1
• 125000004008 6 membered carbocyclic group Chemical group 0.000 claims 1
• 229910016467 AlCl 4 Inorganic materials 0.000 claims 1
• 241000234282 Allium Species 0.000 claims 1
• 235000002732 Allium cepa var. cepa Nutrition 0.000 claims 1
• DHMQDGOQFOQNFH-UHFFFAOYSA-M Aminoacetate Chemical compound NCC([O-])=O DHMQDGOQFOQNFH-UHFFFAOYSA-M 0.000 claims 1
• UIERETOOQGIECD-UHFFFAOYSA-N Angelic acid Natural products CC=C(C)C(O)=O UIERETOOQGIECD-UHFFFAOYSA-N 0.000 claims 1
• CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Natural products OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims 1
• BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims 1
• KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims 1
• 229910021591 Copper(I) chloride Inorganic materials 0.000 claims 1
• KKUKTXOBAWVSHC-UHFFFAOYSA-N Dimethylphosphate Chemical compound COP(O)(=O)OC KKUKTXOBAWVSHC-UHFFFAOYSA-N 0.000 claims 1
• IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims 1
• BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 claims 1
• 239000004471 Glycine Substances 0.000 claims 1
• DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
• MUBZPKHOEPUJKR-UHFFFAOYSA-L Oxalate Chemical compound [O-]C(=O)C([O-])=O MUBZPKHOEPUJKR-UHFFFAOYSA-L 0.000 claims 1
• 239000002202 Polyethylene glycol Substances 0.000 claims 1
• XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims 1
• LCTONWCANYUPML-UHFFFAOYSA-M Pyruvate Chemical compound CC(=O)C([O-])=O LCTONWCANYUPML-UHFFFAOYSA-M 0.000 claims 1
• YGSDEFSMJLZEOE-UHFFFAOYSA-N Salicylic acid Natural products OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims 1
• KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims 1
• 239000000654 additive Substances 0.000 claims 1
• 150000001335 aliphatic alkanes Chemical group 0.000 claims 1
• 125000003342 alkenyl group Chemical group 0.000 claims 1
• KQNPFQTWMSNSAP-UHFFFAOYSA-N alpha-isobutyric acid Natural products CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 claims 1
• 150000001412 amines Chemical class 0.000 claims 1
• 229940072107 ascorbate Drugs 0.000 claims 1
• 235000010323 ascorbic acid Nutrition 0.000 claims 1
• 239000011668 ascorbic acid Substances 0.000 claims 1
• TUCIXUDAQRPDCG-UHFFFAOYSA-N benzene-1,2-diol Chemical compound OC1=CC=CC=C1O.OC1=CC=CC=C1O TUCIXUDAQRPDCG-UHFFFAOYSA-N 0.000 claims 1
• 125000002619 bicyclic group Chemical group 0.000 claims 1
• 229910052792 caesium Inorganic materials 0.000 claims 1
• TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims 1
• 150000001720 carbohydrates Chemical class 0.000 claims 1
• 229910052799 carbon Inorganic materials 0.000 claims 1
• 239000001569 carbon dioxide Substances 0.000 claims 1
• 229910002092 carbon dioxide Inorganic materials 0.000 claims 1
• 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims 1
• 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 1
• OEYIOHPDSNJKLS-UHFFFAOYSA-N choline Chemical compound C[N+](C)(C)CCO OEYIOHPDSNJKLS-UHFFFAOYSA-N 0.000 claims 1
• 229960001231 choline Drugs 0.000 claims 1
• 229910017052 cobalt Inorganic materials 0.000 claims 1
• 239000010941 cobalt Substances 0.000 claims 1
• GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 1
• OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 claims 1
• 150000003983 crown ethers Chemical class 0.000 claims 1
• 230000006837 decompression Effects 0.000 claims 1
• 230000007423 decrease Effects 0.000 claims 1
• 238000001704 evaporation Methods 0.000 claims 1
• UHCBBWUQDAVSMS-UHFFFAOYSA-N fluoroethane Chemical compound CCF UHCBBWUQDAVSMS-UHFFFAOYSA-N 0.000 claims 1
• UPWPDUACHOATKO-UHFFFAOYSA-K gallium trichloride Chemical compound Cl[Ga](Cl)Cl UPWPDUACHOATKO-UHFFFAOYSA-K 0.000 claims 1
• ZRALSGWEFCBTJO-UHFFFAOYSA-O guanidinium Chemical compound NC(N)=[NH2+] ZRALSGWEFCBTJO-UHFFFAOYSA-O 0.000 claims 1
• 229910052736 halogen Inorganic materials 0.000 claims 1
• 150000002367 halogens Chemical class 0.000 claims 1
• SMWDFEZZVXVKRB-UHFFFAOYSA-O hydron;quinoline Chemical compound [NH+]1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-O 0.000 claims 1
• 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
• 230000033444 hydroxylation Effects 0.000 claims 1
• 238000005805 hydroxylation reaction Methods 0.000 claims 1
• AWJUIBRHMBBTKR-UHFFFAOYSA-O isoquinolin-2-ium Chemical compound C1=[NH+]C=CC2=CC=CC=C21 AWJUIBRHMBBTKR-UHFFFAOYSA-O 0.000 claims 1
• 229960004705 kojic acid Drugs 0.000 claims 1
• 229910052746 lanthanum Inorganic materials 0.000 claims 1
• FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims 1
• 229940058352 levulinate Drugs 0.000 claims 1
• WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 1
• 229910052751 metal Inorganic materials 0.000 claims 1
• 239000002184 metal Substances 0.000 claims 1
• 150000002739 metals Chemical class 0.000 claims 1
• 239000002105 nanoparticle Substances 0.000 claims 1
• 229910052759 nickel Inorganic materials 0.000 claims 1
• FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims 1
• VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Chemical compound [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 claims 1
• 229940085991 phosphate ion Drugs 0.000 claims 1
• 229950010765 pivalate Drugs 0.000 claims 1
• 229920000058 polyacrylate Polymers 0.000 claims 1
• 229920001223 polyethylene glycol Polymers 0.000 claims 1
• 229920001451 polypropylene glycol Polymers 0.000 claims 1
• 150000003254 radicals Chemical class 0.000 claims 1
• 229960004889 salicylic acid Drugs 0.000 claims 1
• 229910052708 sodium Inorganic materials 0.000 claims 1
• 239000011734 sodium Substances 0.000 claims 1
• 239000000126 substance Substances 0.000 claims 1
• 239000001384 succinic acid Substances 0.000 claims 1
• RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 claims 1
• 150000003573 thiols Chemical class 0.000 claims 1
• UAXOELSVPTZZQG-UHFFFAOYSA-N tiglic acid Natural products CC(C)=C(C)C(O)=O UAXOELSVPTZZQG-UHFFFAOYSA-N 0.000 claims 1
• VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims 1
• 239000010457 zeolite Substances 0.000 claims 1