JP2012240985A - Aerosol type skin cleanser - Google Patents
Aerosol type skin cleanser Download PDFInfo
- Publication number
- JP2012240985A JP2012240985A JP2011114760A JP2011114760A JP2012240985A JP 2012240985 A JP2012240985 A JP 2012240985A JP 2011114760 A JP2011114760 A JP 2011114760A JP 2011114760 A JP2011114760 A JP 2011114760A JP 2012240985 A JP2012240985 A JP 2012240985A
- Authority
- JP
- Japan
- Prior art keywords
- aerosol
- skin cleanser
- type
- type skin
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000443 aerosol Substances 0.000 title claims abstract description 19
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 24
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 23
- 229930195729 fatty acid Natural products 0.000 claims abstract description 23
- 239000000194 fatty acid Substances 0.000 claims abstract description 23
- -1 fatty acid ester Chemical class 0.000 claims abstract description 15
- 150000001413 amino acids Chemical class 0.000 claims abstract description 12
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 12
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 12
- 239000003915 liquefied petroleum gas Substances 0.000 claims abstract description 12
- 229920000223 polyglycerol Polymers 0.000 claims abstract description 10
- 239000004094 surface-active agent Substances 0.000 claims abstract description 9
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 8
- 239000003380 propellant Substances 0.000 claims description 16
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000007789 gas Substances 0.000 claims description 5
- 239000001294 propane Substances 0.000 claims description 5
- 239000006260 foam Substances 0.000 abstract description 16
- 230000000694 effects Effects 0.000 abstract description 12
- 238000005406 washing Methods 0.000 abstract description 10
- 239000011148 porous material Substances 0.000 abstract description 8
- 230000002262 irrigation Effects 0.000 abstract 1
- 238000003973 irrigation Methods 0.000 abstract 1
- 230000007794 irritation Effects 0.000 description 13
- 125000002252 acyl group Chemical group 0.000 description 11
- 150000004665 fatty acids Chemical class 0.000 description 11
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- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
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- 239000002453 shampoo Substances 0.000 description 2
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- 239000011550 stock solution Substances 0.000 description 2
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- 125000001419 myristoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 125000002801 octanoyl group Chemical group C(CCCCCCC)(=O)* 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 125000001312 palmitoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- CDAISMWEOUEBRE-UHFFFAOYSA-N scyllo-inosotol Natural products OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 description 1
- 231100000245 skin permeability Toxicity 0.000 description 1
- 230000036555 skin type Effects 0.000 description 1
- 229940096501 sodium cocoamphoacetate Drugs 0.000 description 1
- 229940010747 sodium hyaluronate Drugs 0.000 description 1
- 229940045944 sodium lauroyl glutamate Drugs 0.000 description 1
- IWIUXJGIDSGWDN-UQKRIMTDSA-M sodium;(2s)-2-(dodecanoylamino)pentanedioate;hydron Chemical compound [Na+].CCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC(O)=O IWIUXJGIDSGWDN-UQKRIMTDSA-M 0.000 description 1
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 125000003696 stearoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、エアゾール型皮膚洗浄料に関する。 The present invention relates to an aerosol type skin cleanser.
洗顔料、ボディシャンプー、ハンドソープに代表される皮膚洗浄料には、クリーミィな泡質が求められている。一般的に皮膚洗浄料は固形や液状であり、使用時に水を加え手やスポンジ等で泡立てて使用する必要があった。そのため簡便に泡立てるため、フォーマー容器に充填した皮膚洗浄料やエアゾール型の皮膚洗浄料の開発が進んでいる。例えば炭酸ガスと、ポリグリセリンモノ脂肪酸エステルと、グリセリンとを組み合わせたエアゾール型水性洗顔化粧料が報告されている（特許文献１参照）。 Skin cleansing agents such as facial cleansers, body shampoos and hand soaps are required to have a creamy foam quality. In general, skin cleansing materials are solid or liquid, and it is necessary to add water during use and foam with a hand or a sponge. For this reason, development of skin cleansers and aerosol-type skin cleansers filled in former containers for easy foaming is in progress. For example, an aerosol-type aqueous facial cleanser that combines carbon dioxide, polyglycerin monofatty acid ester, and glycerin has been reported (see Patent Document 1).
エアゾール型皮膚洗浄料においては、噴射剤としてプロパン、ブタン、ペンタン等の低級炭化水素の混合物である液化石油ガスが汎用されている。低分子の炭化水素を用いたエアゾール型皮膚洗浄料は、クリーミィな泡質の実現に適している一方、分子量が小さいため皮膚透過性の懸念があり、使用する人の肌タイプによっては刺激を感じることがあった。また、液化石油ガス以外の噴射剤として炭酸ガスの使用が知られているが、炭酸ガスには血行促進効果があり、多量の炭酸ガスを使用する場合に人によっては赤み、ほてり等の刺激に似た感触を受けることがあった。そのため、アルギニンを配合したり、ｐＨを調整することで噴射剤の刺激感を低減する研究が行われている（特許文献２、３参照）。 In aerosol-type skin cleansers, liquefied petroleum gas, which is a mixture of lower hydrocarbons such as propane, butane and pentane, is widely used as a propellant. Aerosol-type skin cleanser using low molecular weight hydrocarbons is suitable for realizing creamy foam quality, but there is concern about skin permeability due to low molecular weight, and irritation may be felt depending on the skin type of the person using it There was a thing. Also, the use of carbon dioxide as a propellant other than liquefied petroleum gas is known, but carbon dioxide has an effect of promoting blood circulation, and when a large amount of carbon dioxide is used, depending on the person, it may cause irritation such as redness and hot flashes. I felt a similar feeling. Therefore, studies have been conducted to reduce the irritation of the propellant by blending arginine or adjusting pH (see Patent Documents 2 and 3).
しかしながらエアゾール型皮膚洗浄剤において泡質、洗浄効果、感触を損なわずに刺激感を低減しようとする試みはほとんどなされていない。
従って、本発明の課題は、キメ細かくクリーミィな泡質で、毛穴の汚れに対し優れた洗浄効果を有し、洗いあがり後にはさっぱりとした感触であるだけでなく、刺激感の少ないエアゾール型皮膚洗浄料を提供することにある。
However, there have been almost no attempts to reduce irritation without impairing foam quality, cleaning effect and feel in aerosol type skin cleansing agents.
Therefore, the object of the present invention is to provide an aerosol-type skin cleanser that has a fine and creamy foam quality, has an excellent cleaning effect against dirt on pores, has a refreshing feel after washing, and has a less irritating feeling. Is to provide a fee.
本発明者は上記課題を解決するために鋭意研究を行なった結果、特定のアミノ酸系界面活性剤とポリグリセリン脂肪酸エステルと多価アルコールに、噴射剤として液化石油ガスと炭酸ガスを組み合せて用いてエアゾール型皮膚洗浄料とすることにより、キメ細かくクリーミィな泡質で、毛穴の汚れに対し優れた洗浄効果を有し、洗いあがり後にはさっぱりとした感触であり、さらに刺激感も少ないことを見出し、本発明を完成するに至った。 As a result of intensive studies to solve the above problems, the present inventor used a specific amino acid surfactant, polyglycerin fatty acid ester and polyhydric alcohol in combination with liquefied petroleum gas and carbon dioxide as a propellant. By using an aerosol-type skin cleansing agent, it has a fine and creamy foam, has an excellent cleaning effect on pore dirt, has a refreshing feel after washing, and has less irritation, The present invention has been completed.
すなわち、本発明は、（Ａ）Ｎ−アシルグリシン型又はＮ−アシルメチルアラニン型アミノ酸系界面活性剤、（Ｂ）ポリグリセリン脂肪酸エステル、（Ｃ）多価アルコール、（Ｄ）液化石油ガス及び（Ｅ）炭酸ガスを含有するエアゾール型皮膚洗浄料を提供するものである。 That is, the present invention relates to (A) N-acylglycine type or N-acylmethylalanine type amino acid surfactant, (B) polyglycerin fatty acid ester, (C) polyhydric alcohol, (D) liquefied petroleum gas and ( E) An aerosol type skin cleansing material containing carbon dioxide gas is provided.
本発明のエアゾール型皮膚洗浄料は、キメ細かくクリーミィな泡質で、毛穴の汚れに対し優れた洗浄効果を有し、洗いあがり後にはさっぱりとした感触であり、刺激感が少ない。 The aerosol type skin cleanser of the present invention has a fine and creamy foam, has an excellent cleaning effect against pore dirt, has a refreshing feel after washing, and has little irritation.
以下、本発明の構成を詳述する。 Hereinafter, the configuration of the present invention will be described in detail.
本発明において成分（Ａ）として用いられるＮ−アシルグリシン型のアミノ酸系界面活性剤は下記式（１）で、Ｎ−アシルメチルアラニン型のアミノ酸系界面活性剤は下記式（２）で表される。 The N-acylglycine type amino acid surfactant used as component (A) in the present invention is represented by the following formula (1), and the N-acylmethylalanine type amino acid surfactant is represented by the following formula (2). The
（式中Ｒ1は、炭素数６〜２２のアシル基を示し、Ｍは水素原子、アルカリ金属、アルカノールアミン又は塩基性アミノ酸を示す。） (In the formula, R 1 represents an acyl group having 6 to 22 carbon atoms, and M represents a hydrogen atom, an alkali metal, an alkanolamine, or a basic amino acid.)
（式中Ｒ2は、炭素数６〜２２のアシル基を示し、Ｍは水素原子、アルカリ金属、アルカノールアミン又は塩基性アミノ酸を示す。） (Wherein R 2 represents an acyl group having 6 to 22 carbon atoms, and M represents a hydrogen atom, an alkali metal, an alkanolamine, or a basic amino acid.)
式（１）及び式（２）におけるＲ1及びＲ2で示されるアシル基としては、炭素数８〜２０の脂肪族アシル基が好ましく、より好ましくは炭素数１０〜１８の脂肪族アシル基である。これらの脂肪族アシル基としては、飽和でも不飽和でもよく、例えばカプリロイル、カプリノイル、ラウロイル、ミリストイル、パルミトイル、ステアロイル、ヤシ油脂肪酸アシル等が挙げられる。 The acyl group represented by R 1 and R 2 in formula (1) and formula (2) is preferably an aliphatic acyl group having 8 to 20 carbon atoms, more preferably an aliphatic acyl group having 10 to 18 carbon atoms. is there. These aliphatic acyl groups may be saturated or unsaturated, and examples thereof include capryloyl, caprinoyl, lauroyl, myristoyl, palmitoyl, stearoyl, and coconut oil fatty acid acyl.
式（１）及び式（２）におけるＭのうち、アルカリ金属としてはナトリウム、カリウム、リチウムが挙げられるが、洗いあがりのさっぱり感の点からカリウムがより好ましい。アルカノールアミンとしては、モノエタノールアミン、ジエタノールアミン、トリエタノールアミン、ジイソプロパノールアミン、トリイソプロパノールアミン等の炭素数２〜４のアルカノールアミンが挙げられる。塩基性アミノ酸としては、リジン、アルギニン、ヒスチジン等が挙げられる。 Among M in Formula (1) and Formula (2), examples of the alkali metal include sodium, potassium, and lithium, and potassium is more preferable in terms of a refreshing feeling after washing. Examples of the alkanolamine include C2-C4 alkanolamines such as monoethanolamine, diethanolamine, triethanolamine, diisopropanolamine, and triisopropanolamine. Examples of basic amino acids include lysine, arginine, histidine and the like.
本発明の成分（Ａ）としては、具体的にはＮ−ヤシ油脂肪酸アシルグリシンカリウム、Ｎ−ヤシ油脂肪酸アシルグリシンナトリウム、Ｎ−ヤシ油脂肪酸メチルアラニンナトリウム、Ｎ−ラウロイルメチルアラニンナトリウム、Ｎ−ラウロイルメチルアラニントリエタノールアミンが挙げられる。本発明では、洗いあがり後のさっぱり感の面から、Ｎ−アシルグリシン型アミノ酸系界面活性剤が好ましく、特にＮ−ヤシ油脂肪酸アシルグリシンカリウムが好ましい。 As the component (A) of the present invention, specifically, N-coconut oil fatty acid acylglycine potassium, N-coconut oil fatty acid acylglycine sodium, N-coconut oil fatty acid methylalanine sodium, N-lauroylmethylalanine sodium, N- Lauroylmethylalanine triethanolamine is mentioned. In the present invention, an N-acyl glycine type amino acid surfactant is preferable from the viewpoint of a refreshing feeling after washing, and N-coconut oil fatty acid acyl glycine potassium is particularly preferable.
本発明のエアゾール型皮膚洗浄料における、（Ａ）Ｎ−アシルグリシン型又はＮ−アシルメチルアラニン型アミノ酸系界面活性剤の含有量は、エアゾール型皮膚洗浄料の総量を基準として、０．０１〜１０質量％（以下、単に％と略す）が好ましく、さらに好ましくは０．２〜７％であり、特に好ましくは、０．５〜５％である。アミノ酸系界面活性剤の含有量が当該範囲内であれば、泡のクリーミィさ、洗いあがり後のさっぱり感が良好となる。 The content of the (A) N-acylglycine type or N-acylmethylalanine type amino acid surfactant in the aerosol-type skin cleanser of the present invention is 0.01 to 10% by mass (hereinafter simply referred to as%) is preferable, more preferably 0.2 to 7%, and particularly preferably 0.5 to 5%. When the content of the amino acid surfactant is within the above range, the creaminess of the foam and the refreshing feeling after washing are improved.
本発明における（Ｂ）ポリグリセリン脂肪酸エスエルは、グリセリンの縮合体であるポリグリセリンと脂肪酸からなるエステルであり、下記式（３）で表されるものが好ましい。 The (B) polyglycerin fatty acid ester in the present invention is an ester composed of polyglycerin and a fatty acid, which is a glycerin condensate, and is preferably represented by the following formula (3).
（式中、Ｒ3はいずれか一つ以上が炭素数８〜２０の脂肪族アシル基であり、他は水素原子である。ｎは２〜１８の整数である。） (In the formula, any one or more of R 3 is an aliphatic acyl group having 8 to 20 carbon atoms, and the other is a hydrogen atom. N is an integer of 2 to 18)
式（３）中の脂肪族アシル基であるＲ3は、ポリグリセリン脂肪酸エステルを構成する脂肪酸に由来する。この脂肪酸は、直鎖若しくは分岐鎖のいずれであっても、また飽和若しくは不飽和のいずれであってもよいが、特に直鎖飽和脂肪酸が好ましい。また、その炭素数は８〜２０が好ましく、より好ましくは１０〜１８であり、さらに好ましくは１２〜１６である。脂肪酸の具体例としてはラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、イソステアリン酸、オレイン酸、ヤシ油脂肪酸等が挙げられる。より好ましくは、ラウリン酸、ミリスチン酸、パルミチン酸であるが、本発明ではラウリン酸がさらに好ましく用いられる。 R 3 which is an aliphatic acyl group in the formula (3) is derived from the fatty acid constituting the polyglycerol fatty acid ester. The fatty acid may be linear or branched, and may be either saturated or unsaturated, but linear saturated fatty acid is particularly preferable. Moreover, 8-20 are preferable, More preferably, it is 10-18, More preferably, it is 12-16. Specific examples of the fatty acid include lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, oleic acid, coconut oil fatty acid and the like. More preferred are lauric acid, myristic acid and palmitic acid, but lauric acid is more preferably used in the present invention.
式（３）中のｎは、ポリグリセリン脂肪酸エステルを構成するポリグリセリンの平均縮合度である。本発明に（Ｂ）成分におけるポリグリセリンの平均縮合度は２〜１８が好ましく、より好ましくは６〜１４であり、さらに好ましくは８〜１２である。これらの中でも平均縮合度が１０のデカグリセリンが特に好ましく用いられる。 N in Formula (3) is an average degree of condensation of polyglycerol constituting the polyglycerol fatty acid ester. 2-18 are preferable, as for the average condensation degree of the polyglycerol in (B) component in this invention, More preferably, it is 6-14, More preferably, it is 8-12. Of these, decaglycerin having an average degree of condensation of 10 is particularly preferably used.
本発明の（Ｂ）成分であるポリグリセリン脂肪酸エステルは、式（３）中の脂肪族アシル基であるＲ3の数により、モノエステル、ジエステル、トリエステル、テトラエステル等がある。本発明では、アシル基であるＲ3の数が１又は２であるポリグリセリンモノ脂肪酸エステル又はポリグリセリンジ脂肪酸エステルが好ましく、さらにポリグリセリンモノ脂肪酸エステルが好ましく用いられる。本発明に用いられる（Ｂ）ポリグリセリン脂肪酸エステルの具体例としては、ラウリン酸デカグリセリル、ミリスチン酸デカグリセリル、パルミチン酸デカグリセリル、ラウリン酸ドデカグリセリル、ミリスチン酸ドデカグリセリル、パルミチン酸ドデカグリセリル等であり、これらを一種又は二種以上を組み合わせて添加することができる。これらの中でも特にラウリン酸デカグリセリル、ミリスチン酸デカグリセリルを用いることが好適である。 The polyglycerin fatty acid ester which is the component (B) of the present invention includes monoesters, diesters, triesters, tetraesters and the like depending on the number of R 3 which is an aliphatic acyl group in the formula (3). In the present invention, a polyglycerol monofatty acid ester or polyglycerol difatty acid ester in which the number of R 3 that is an acyl group is 1 or 2 is preferable, and a polyglycerol monofatty acid ester is preferably used. Specific examples of the (B) polyglyceryl fatty acid ester used in the present invention include decaglyceryl laurate, decaglyceryl myristate, decaglyceryl palmitate, dodecaglyceryl laurate, dodecaglyceryl myristate, dodecaglyceryl palmitate, etc. These can be added singly or in combination of two or more. Among these, it is particularly preferable to use decaglyceryl laurate and decaglyceryl myristate.
本発明のエアゾール型皮膚洗浄料における、（Ｂ）ポリグリセリン脂肪酸エステルの含有量は、エアゾール型皮膚洗浄料の総量を基準として、０．１〜５％が好ましく、さらに好ましくは０．２〜３％であり、特に好ましくは、０．５〜２％である。ポリグリセリン脂肪酸エステルの含有量が当該範囲内であれば、泡のクリーミィさ、毛穴汚れに対する洗浄効果が良好となる。 The content of the (B) polyglycerol fatty acid ester in the aerosol-type skin cleanser of the present invention is preferably 0.1 to 5%, more preferably 0.2 to 3 based on the total amount of the aerosol-type skin cleanser. %, Particularly preferably 0.5 to 2%. When the content of the polyglycerin fatty acid ester is within the above range, the foaming creaminess and the cleaning effect against pore dirt are good.
本発明における（Ｃ）多価アルコールとしては、２価〜８価の多価アルコール、例えば、エチレングリコール、ジエチレングリコール、ヘキシレングリコール、ポリエチレングリコール、プロピレングリコール、ジプロピレングリコール、ポリプロピレングリコール、イソプレングリコール、グリセリン、ジグリセリン、トリグリセリン、テトラグリセリン、ヘキサグリセリン、デカグリセリン、１，３−ブチレングリコール、トリメチルプロパノール、エリスリトール、ペンタエリスリトール、ジペンタエリスリトール、グルコース、マンノース、ガラクトース、ショ糖、フルクトース、マルトース、マルチトール、キシリトール、イノシトール、ソルビタン、ソルビトールなどが挙げられる。より好ましい例としては、プロピレングリコール、ジプロピレングリコール、グリセリン、１，３−ブチレングリコール、ソルビトールなどが挙げられる。これらは、それぞれ単独で用いても、２種以上を組み合わせて用いてもよい。 The polyhydric alcohol (C) in the present invention is a dihydric to octahydric polyhydric alcohol such as ethylene glycol, diethylene glycol, hexylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, polypropylene glycol, isoprene glycol, glycerin. , Diglycerin, triglycerin, tetraglycerin, hexaglycerin, decaglycerin, 1,3-butylene glycol, trimethylpropanol, erythritol, pentaerythritol, dipentaerythritol, glucose, mannose, galactose, sucrose, fructose, maltose, maltitol , Xylitol, inositol, sorbitan, sorbitol and the like. More preferred examples include propylene glycol, dipropylene glycol, glycerin, 1,3-butylene glycol, sorbitol and the like. These may be used alone or in combination of two or more.
本発明のエアゾール型皮膚洗浄料における、（Ｃ）多価アルコールの含有量は、エアゾール型皮膚洗浄料の総量を基準として、５〜５０％が好ましく、さらに好ましくは５〜４０％であり、特に好ましくは、１０〜３０％である。多価アルコールの含有量が当該範囲内であれば、毛穴汚れに対する洗浄効果、洗いあがり後のさっぱり感が良好となる。 In the aerosol type skin cleanser of the present invention, the content of the (C) polyhydric alcohol is preferably 5 to 50%, more preferably 5 to 40%, based on the total amount of the aerosol type skin cleanser. Preferably, it is 10 to 30%. If the content of the polyhydric alcohol is within the above range, the cleaning effect against pore dirt and the refreshing feeling after washing will be good.
本発明のエアゾール型皮膚洗浄料は、上記成分（Ａ）〜（Ｃ）を含有する皮膚洗浄料の原液を、噴射剤成分と共に容器に充填することにより製造される。本発明では、噴射剤成分として、（Ｄ）液化石油ガスと（Ｅ）炭酸ガスを組合わせて使用する。 The aerosol-type skin cleanser of the present invention is produced by filling a container together with a propellant component with a stock solution of the skin cleanser containing the above components (A) to (C). In the present invention, (D) liquefied petroleum gas and (E) carbon dioxide gas are used in combination as the propellant component.
本発明における（Ｄ）液化石油ガスとしては、プロパン、ｎ−ブタン、ｉ−ブタン、ｎ−ペンタン、ｉ−ペンタンが挙げられ、通常これらを混合して圧力を調整して用いる。 Examples of the liquefied petroleum gas (D) in the present invention include propane, n-butane, i-butane, n-pentane, and i-pentane. Usually, these are mixed and used after adjusting the pressure.
本発明のエアゾール型皮膚洗浄料における、（Ｄ）液化石油ガスの含有量は、エアゾール型皮膚洗浄料の総量を基準として、１〜１０％が好ましく、さらに好ましくは２〜７％であり、特に好ましくは３〜６％である。液化石油ガスの含有量が当該範囲内にあれば、泡のクリーミーさ、刺激感の無さの面で好ましい。 The content of (D) liquefied petroleum gas in the aerosol-type skin cleanser of the present invention is preferably 1 to 10%, more preferably 2 to 7%, based on the total amount of the aerosol-type skin cleanser. Preferably it is 3 to 6%. If content of liquefied petroleum gas exists in the said range, it is preferable at the surface of the creaminess of a bubble and the absence of irritation.
本発明のエアゾール型皮膚洗浄料における、（Ｅ）炭酸ガスの含有量は、エアゾール型皮膚洗浄料の総量を基準として、０．１〜２％が好ましく、さらに好ましくは０．５〜１．２％である。炭酸ガスの含有量が当該範囲内にあれば、泡のクリーミーさ、刺激感の無さの面で好ましい。 The content of (E) carbon dioxide in the aerosol-type skin cleanser of the present invention is preferably 0.1 to 2%, more preferably 0.5 to 1.2, based on the total amount of the aerosol-type skin cleanser. %. If the content of carbon dioxide gas is within this range, it is preferable in terms of foam creaminess and no irritation.
本発明では、吐出圧や吐出される洗浄料の泡質を調整する目的で、噴射剤として上記成分（Ｄ）、（Ｅ）以外に、通常使用されるエーテル系噴射剤（ジメチルエーテル等）や圧縮ガス（窒素ガス、空気等）、その他の噴射剤を適宜併用することができる。本発明のエアゾール型皮膚洗浄料では、２５℃における圧力が０．４〜０．７ＭＰａとなるように噴射剤を配合することが好ましい。 In the present invention, for the purpose of adjusting the discharge pressure and the foam quality of the discharged cleaning material, in addition to the above components (D) and (E), the propellant is usually used as an ether-based propellant (such as dimethyl ether) or compressed. Gas (nitrogen gas, air, etc.) and other propellants can be used in combination as appropriate. In the aerosol type skin cleanser of the present invention, it is preferable to blend a propellant so that the pressure at 25 ° C. is 0.4 to 0.7 MPa.
さらに、本発明では、（Ｄ）液化石油ガスの成分であるプロパンの含有量を、噴射剤の総量を基準として、１０％未満とするのが好ましく、さらに好ましくは１％未満とする。プロパンの含有量をこれらの範囲に抑えることにより、刺激感の無さにおいてより好ましいものとなる。 Furthermore, in the present invention, the content of propane, which is a component of (D) liquefied petroleum gas, is preferably less than 10%, more preferably less than 1%, based on the total amount of propellant. By suppressing the content of propane within these ranges, it becomes more preferable in the absence of irritation.
本発明のエアゾール型皮膚洗浄料は、上記成分（Ａ）〜（Ｃ）を含有する皮膚洗浄料の原液を上記（Ｄ）、（Ｅ）の噴射剤と共にスチール、アルミ等の耐圧性のエアゾール容器に充填することにより製造される。その噴射の形態としては泡状にして吐出するフォームタイプとするのが好ましい。 The aerosol-type skin cleanser of the present invention is a pressure-resistant aerosol container made of a skin cleanser containing the above components (A) to (C) together with the propellant (D) or (E), such as steel or aluminum. It is manufactured by filling. As a form of the injection, it is preferable to use a foam type that is discharged in the form of foam.
本発明のエアゾール型皮膚洗浄料は、洗顔料、クレンジング化粧料、ボディシャンプー、ハンドソープとして好適に利用できる。 The aerosol type skin cleanser of the present invention can be suitably used as a facial cleanser, cleansing cosmetic, body shampoo, and hand soap.
以下に実施例、比較例を挙げて本発明を説明する。本発明は、これらにより限定されるものではない。 Hereinafter, the present invention will be described with reference to examples and comparative examples. The present invention is not limited to these.
実施例、比較例にて行った官能試験の試験方法は下記の通りである。尚、以下の実施例、比較例の組成物の配合量は、全て質量％（単に％と略記）である。 The test methods of the sensory test performed in the examples and comparative examples are as follows. In addition, the compounding quantity of the composition of a following example and a comparative example is all the mass% (simply abbreviated as%).
・官能試験
１０名の被験者によってエアゾール型皮膚洗浄料の試料を頬の部位に塗布した。塗布後３０秒間マッサージを続け、ぬるま湯にて洗い流した。その後被験者本人が、泡のクリーミィさ、洗いあがりのさっぱり感、毛穴汚れの洗浄効果、刺激感の無さについて、下記評価基準に基いて官能評価し、評点の平均点により評価した。
-Sensory test A sample of aerosol type skin cleanser was applied to the cheek site by 10 subjects. Massage was continued for 30 seconds after application, and rinsed off with warm water. Thereafter, the subject himself / herself performed a sensory evaluation based on the following evaluation criteria with respect to the creaminess of the foam, the refreshing feeling of washing up, the cleaning effect of pore dirt, and the absence of irritation, and evaluated by the average score.
（評価基準）
４：非常に良好
３：良好
２：やや悪い
１：悪い
(Evaluation criteria)
4: Very good 3: Good 2: Slightly bad 1: Bad
実施例１〜３、比較例１〜６
表１に示した処方において、噴射剤以外の成分を加熱混合し、冷却後、耐圧容器に充填した。その後、噴射剤を加圧充填することによりエアゾール型皮膚洗浄料を調製した。次いで前記の官能試験を実施し、エアゾール型皮膚洗浄料を評価した。試験結果を表１に併せて示す。
Examples 1-3, Comparative Examples 1-6
In the prescription shown in Table 1, components other than the propellant were heated and mixed, and after cooling, filled in a pressure resistant container. Thereafter, an aerosol type skin cleanser was prepared by pressure filling with a propellant. Subsequently, the above-mentioned sensory test was carried out to evaluate the aerosol type skin cleanser. The test results are also shown in Table 1.
表１より明らかなように本発明の成分（Ａ）〜（Ｅ）を用いた実施例のエアゾール型皮膚洗浄料はいずれも優れた性能を有していた。一方、成分（Ａ）〜（Ｅ）のうちのいずれかを欠いた比較例では、泡のクリーミィさ、さっぱり感、洗浄効果、刺激感の無さのいずれかの面で劣っており、本発明の目的を達成できなかった。 As is clear from Table 1, all of the aerosol type skin cleansing agents of Examples using the components (A) to (E) of the present invention had excellent performance. On the other hand, the comparative example lacking any one of the components (A) to (E) is inferior in any aspect of foam creaminess, refreshing feeling, cleaning effect, and lack of irritation. The purpose of could not be achieved.
実施例４
配合成分 配合量
（原液）
Ｎ−ヤシ油脂肪酸アシルグリシンカリウム ３．０
ミリスチン酸デカグリセリル ０．７
１，３−ブチレングリコール １０．０
グリセリン ５．０
ココアンホ酢酸ナトリウム １．０
ヒドロキシエチルセルロース ０．１
ラウロイルグルタミン酸ナトリウム ０．３
ステアリルアルコール ０．５
ポリオキシエチレン硬化ヒマシ油（６０Ｅ．Ｏ．） ０．３
ポリオキシエチレンセチルエーテル（５Ｅ．Ｏ．） ０．５
ポリオキシプロピレン（１）ヤシ油脂肪酸 ０．３
モノイソプロパノールアミド
エデト酸２ナトリウム ０．０２
チンピエキス ０．１
アルテアエキス ０．０５
キラヤエキス ０．０５
ヒアルロン酸ナトリウム ０．０１
フェノキシエタノール ０．２
グリチルリチン酸ジカリウム ０．１
香料 ０．２
精製水 残 部
（噴射剤）
液化石油ガス（０．１５ＭＰａ、２５℃） ５．０
炭酸ガス １．０
Example 4
Compounding ingredients Compounding amount
(Stock solution)
N-coconut oil fatty acid acylglycine potassium 3.0
Decaglyceryl myristate 0.7
1,3-butylene glycol 10.0
Glycerin 5.0
Sodium cocoamphoacetate 1.0
Hydroxyethyl cellulose 0.1
Sodium lauroyl glutamate 0.3
Stearyl alcohol 0.5
Polyoxyethylene hydrogenated castor oil (60 EO) 0.3
Polyoxyethylene cetyl ether (5EO) 0.5
Polyoxypropylene (1) Palm oil fatty acid 0.3
Monoisopropanolamide edetic acid disodium 0.02
Chimp extract 0.1
Altea extract 0.05
Kiraya extract 0.05
Sodium hyaluronate 0.01
Phenoxyethanol 0.2
Dipotassium glycyrrhizinate 0.1
Fragrance 0.2
Purified water balance (propellant)
Liquefied petroleum gas (0.15 MPa, 25 ° C.) 5.0
Carbon dioxide 1.0
上記組成のエアゾール型皮膚洗浄料を作製し評価したところ、泡のクリーミィさ、さっぱり感、洗浄効果、刺激感の無さのいずれにおいても、優れた性能を有していた。尚、上記エアゾール型化粧料の圧力（２５℃）は０．６ＭＰａであった。 When an aerosol type skin cleanser having the above composition was prepared and evaluated, it had excellent performance in any of creaminess, refreshing feeling, cleansing effect, and no irritation. In addition, the pressure (25 degreeC) of the said aerosol type cosmetics was 0.6 MPa.
尚、上記の実施例４において使用した香料の組成を表２に示す。 Table 2 shows the composition of the fragrance used in Example 4 above.
本発明によれば、キメ細かくクリーミィな泡で、毛穴の汚れに対し優れた洗浄効果を有し、洗いあがり後にはさっぱりとした感触であり、刺激感の少ないエアゾール型皮膚洗浄料を提供できる。 According to the present invention, it is possible to provide an aerosol-type skin cleansing agent that has a fine and creamy foam, has an excellent cleaning effect on pore dirt, has a refreshing feel after washing, and has a little irritation.
Claims (2)
（Ａ）Ｎ−アシルグリシン型又はＮ−アシルメチルアラニン型アミノ酸系界面活性剤
（Ｂ）ポリグリセリン脂肪酸エステル
（Ｃ）多価アルコール
（Ｄ）液化石油ガス
（Ｅ）炭酸ガス An aerosol type skin cleanser containing the following components (A) to (E).
(A) N-acylglycine type or N-acylmethylalanine type amino acid surfactant (B) polyglycerol fatty acid ester (C) polyhydric alcohol (D) liquefied petroleum gas (E) carbon dioxide gas
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| JP2014136702A (en) * | 2013-01-18 | 2014-07-28 | Maruzen Pharmaceut Co Ltd | Foaming liquid composition and production method thereof |
| JP2017095393A (en) * | 2015-11-24 | 2017-06-01 | 株式会社マンダム | Foamy skin cleanser |
| WO2018221420A1 (en) * | 2017-05-30 | 2018-12-06 | 株式会社マンダム | Foamed skin cleanser |
| JP2019199407A (en) * | 2018-05-15 | 2019-11-21 | 東洋エアゾール工業株式会社 | Foam-forming aerosol composition |
| KR20190133782A (en) | 2017-09-25 | 2019-12-03 | 가부시키가이샤 만다무 | Foam Skin Cleanser |
| CN110680759A (en) * | 2019-11-18 | 2020-01-14 | 浙江绿岛科技有限公司 | Aerosol type amino acid face-cleaning gel and preparation method thereof |
| KR20210118736A (en) | 2020-03-23 | 2021-10-01 | 가부시키가이샤 만다무 | Foamed skin cleanser |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2014136702A (en) * | 2013-01-18 | 2014-07-28 | Maruzen Pharmaceut Co Ltd | Foaming liquid composition and production method thereof |
| JP2017095393A (en) * | 2015-11-24 | 2017-06-01 | 株式会社マンダム | Foamy skin cleanser |
| WO2018221420A1 (en) * | 2017-05-30 | 2018-12-06 | 株式会社マンダム | Foamed skin cleanser |
| KR20190100295A (en) | 2017-05-30 | 2019-08-28 | 가부시키가이샤 만다무 | Foam Skin Cleanser |
| CN110214001A (en) * | 2017-05-30 | 2019-09-06 | 株式会社漫丹 | Foam-like skin cleaner |
| JPWO2018221420A1 (en) * | 2017-05-30 | 2019-11-07 | 株式会社マンダム | Foam skin cleanser |
| KR20190133782A (en) | 2017-09-25 | 2019-12-03 | 가부시키가이샤 만다무 | Foam Skin Cleanser |
| JP2019199407A (en) * | 2018-05-15 | 2019-11-21 | 東洋エアゾール工業株式会社 | Foam-forming aerosol composition |
| JP7120803B2 (en) | 2018-05-15 | 2022-08-17 | 東洋エアゾール工業株式会社 | Foam forming aerosol composition |
| CN110680759A (en) * | 2019-11-18 | 2020-01-14 | 浙江绿岛科技有限公司 | Aerosol type amino acid face-cleaning gel and preparation method thereof |
| KR20210118736A (en) | 2020-03-23 | 2021-10-01 | 가부시키가이샤 만다무 | Foamed skin cleanser |
| JP7427486B2 (en) | 2020-03-23 | 2024-02-05 | 株式会社マンダム | foam skin cleanser |
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Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |