JP2012220487A - Water purification apparatus improving radioactive substance removal performance - Google Patents

Water purification apparatus improving radioactive substance removal performance Download PDF

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JP2012220487A
JP2012220487A JP2011103261A JP2011103261A JP2012220487A JP 2012220487 A JP2012220487 A JP 2012220487A JP 2011103261 A JP2011103261 A JP 2011103261A JP 2011103261 A JP2011103261 A JP 2011103261A JP 2012220487 A JP2012220487 A JP 2012220487A
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osmosis membrane
reverse osmosis
radioactive
filter
radioactive substance
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Takayuki Kawabata
孝幸 川端
Koji Yamamoto
山本  幸司
Kazuhisa Kageyama
和久 影山
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Abstract

PROBLEM TO BE SOLVED: To obtain a water purification apparatus capable of improving a removal ratio of radioactive substance in addition to a removal performance using a reverse osmosis membrane since, in a generally spread water purifier using a reverse osmosis membrane, most of various substances contained in a liquid can be removed to a concentration meeting a drinking water quality criterion or lower, but perfect removal is disabled in accordance with various conditions such as a removal target substance, liquid temperature, pressure, osmosis membrane type and the like, in the case of radioactive substance, even if a reverse osmosis membrane is used, the radioactive substance is made residual in approximately 2 to 5% and, in particular, regarding radioactive iodine 131, if it is residual in drinking water even a little, it may be accumulated in the thyroid of infant or child, thereby increasing risk in health such as thyroid cancer.SOLUTION: As preprocessing of a reverse osmosis membrane filter, an active carbon filter is disposed and as post-processing of filtrate of the reverse osmosis membrane filter, a filter is disposed which removes radioactive substances through chemical reaction of silver ion with respect to the radioactive substances and water is purified, thereby improving a removal ratio of radioactive substances.

Description

本発明は放射性物質除去性能を備える浄水装置に関する。  The present invention relates to a water purifier having a radioactive substance removing performance.

既に普及している浄水技術のうち逆浸透膜を使用する浄水装置では、液中に含まれる様々な物質を飲用水質基準に適合する濃度以下まで除去でき、原水に含まれる放射性ヨウ素・放射性セシウム等の放射性物質も除去可能である。  Water purification equipment that uses reverse osmosis membranes among water purification technologies that are already in widespread use can remove various substances contained in the liquid to a concentration that conforms to the drinking water quality standards, including radioactive iodine and radioactive cesium contained in raw water The radioactive material can also be removed.

しかし、除去対象の物質・濃度・液温・圧力・浸透膜の種類など諸条件によって100%の除去を行う事はできず、放射性物質の場合では逆浸透膜を使用しても平均的に2乃至5%程度の残留が生じる事が知られている。  However, 100% removal cannot be performed depending on various conditions such as the substance to be removed, concentration, liquid temperature, pressure, and type of osmotic membrane. It is known that a residue of about 5% occurs.

以上に示したように、精密濾過性能に優れる逆浸透膜を用いてもなお、浄水において数%の残留濃度が生じ、特に放射性ヨウ素131にあっては飲用水中に微量でも残留していると、乳幼児や小児の甲状腺に蓄積されて体内被曝を生じ、癌や白血病の原因となる危険性が高いことから、本発明において放射性ヨウ素131の完全な除去性能を備える浄水装置を得る事を目的とする。As shown above, even when a reverse osmosis membrane having excellent microfiltration performance is used, a residual concentration of several percent is generated in purified water, and in particular, in the case of radioactive iodine 131, even a minute amount remains in drinking water. The purpose of the present invention is to obtain a water purifier having a complete removal performance of radioactive iodine 131 in the present invention, because it accumulates in the thyroid gland of infants and children and causes internal exposure, resulting in high risk of causing cancer and leukemia. To do.

逆浸透膜を使用することで浄化対象である原水に含まれる放射性物質は、概ね95%乃至98%程度を除去する事が出来るので、これに加えて逆浸透膜フィルターの前処理として活性炭フィルターを配置し、逆浸透膜フィルターで濾過された水の後処理として、銀イオンと放射性物質(主に放射性ヨウ素)による化学反応によって放射性物質の除去を行うフィルターを配置して、浄水することで放射性物質の除去率を高めることができる。    By using a reverse osmosis membrane, approximately 95% to 98% of the radioactive substances contained in the raw water to be purified can be removed. In addition, an activated carbon filter is used as a pretreatment for the reverse osmosis membrane filter. As a post-treatment of water that has been placed and filtered through a reverse osmosis membrane filter, a radioactive substance is removed by placing a filter that removes the radioactive substance by a chemical reaction with silver ions and radioactive substances (mainly radioactive iodine) and purifying the water. The removal rate can be increased.

上述したように、本発明による浄水装置では一般的に普及している逆浸透膜による浄水方法と放射性物質(放射性ヨウ素131)を除去するフィルターを組み合わせて用いることで、放射性セシウム137の98%以上を除去する事ができ、特に甲状腺への蓄積性が深刻な健康被害の原因となる放射性ヨウ素131は完全に除去できる。  As described above, 98% or more of radioactive cesium 137 can be obtained by combining a water purification method using a reverse osmosis membrane, which is commonly used in a water purification apparatus according to the present invention, and a filter that removes radioactive substances (radioactive iodine 131). In particular, radioactive iodine 131 that causes serious health damage due to accumulation in the thyroid gland can be completely removed.

本発明による各フィルターの接続構成例図  Connection example diagram of each filter according to the present invention

以下、本発明の実施の形態を図1に基づいて説明する。  Hereinafter, an embodiment of the present invention will be described with reference to FIG.

図1において、原水1は加圧ポンプ2に吸込まれて概ね0.5乃至0.7MPs程度に加圧されて活性炭フィルター3へ流入する。加圧ポンプ2は活性炭フィルター3と逆浸透膜フィルター4の間に挿入してもよい。原水1は活性炭フィルター3内の活性炭層を通過する際に、逆浸透膜フィルター4と放射性物質除去フィルター4を損耗させる有機物や塩素等を吸着除去され、続いて逆浸透膜フィルター4へ流入する。  In FIG. 1, raw water 1 is sucked into a pressurizing pump 2, pressurized to about 0.5 to 0.7 MPs, and flows into the activated carbon filter 3. The pressure pump 2 may be inserted between the activated carbon filter 3 and the reverse osmosis membrane filter 4. When the raw water 1 passes through the activated carbon layer in the activated carbon filter 3, organic substances, chlorine and the like that wear the reverse osmosis membrane filter 4 and the radioactive substance removal filter 4 are adsorbed and removed, and then flows into the reverse osmosis membrane filter 4.

活性炭フィルター3から逆浸透膜フィルター4に流入した前処理済みの水に含まれている物質の95%乃至98%程度は、浸透膜を通過できず排水6となって浄水装置の系外へ排出される。この際の排水割合は排水調整バルブ5によって調整する事が出来る。  About 95% to 98% of the substances contained in the pretreated water flowing into the reverse osmosis membrane filter 4 from the activated carbon filter 3 cannot pass through the osmosis membrane and are discharged out of the water purification system as waste water 6. Is done. The drainage ratio at this time can be adjusted by the drainage adjustment valve 5.

逆浸透膜フィルター4を通過して濾過された水には、まだ2%乃至5%程度の放射性物質の残留がある。そこで続いて放射性物質除去フィルター7に流入させる。放射性物質除去フィルター7の内部には銀が蒸着された吸着材8が充填されている。ここで水中に残留している放射性ヨウ素131はヨウ素イオンと銀イオンがヨウ素銀反応を起こしてヨウ化銀となり吸着材8に固定されることとなる。  The water filtered through the reverse osmosis membrane filter 4 still contains about 2% to 5% of radioactive material remaining. Then, it is made to flow into the radioactive substance removal filter 7 continuously. The radioactive substance removal filter 7 is filled with an adsorbent 8 on which silver is deposited. Here, the radioactive iodine 131 remaining in the water undergoes a silver iodide reaction with iodine ions and silver ions to form silver iodide and is fixed to the adsorbent 8.

以上により、残留していた放射性物質のうち放射性ヨウ素131を完全に除去した浄化済みの浄水9を得ることができる。  By the above, the purified water 9 which has been purified by completely removing the radioactive iodine 131 from the remaining radioactive substance can be obtained.

本発明は、飲用水などの液中に含まれる有害な物質をはじめ、特に健康上の被害が懸念される放射性物質に対して、高い除去率を得る事が出来るので原子力炉事故等により環境放出された放射性物質が、地下浸透して井戸水を汚染したり河川湖沼等の水系を経由して浄水場に混入した場合でも、安心して飲用水を確保する事が出来る。  Since the present invention can obtain a high removal rate for harmful substances contained in liquids such as drinking water, especially radioactive substances that are of concern for health damage, it is released into the environment due to nuclear reactor accidents, etc. Even if the radioactive material is infiltrated underground and contaminates well water or enters water purification plants via river systems such as rivers and lakes, drinking water can be secured with peace of mind.

1・・・原水
2・・・加圧ポンプ
3・・・活性炭フィルター
4・・・逆浸透膜フィルター
5・・・排水調整バルブ
6・・・排水
7・・・放射性物質除去フィルター
8・・・吸着材
9・・・浄水
DESCRIPTION OF SYMBOLS 1 ... Raw water 2 ... Pressure pump 3 ... Activated carbon filter 4 ... Reverse osmosis membrane filter 5 ... Drainage adjustment valve 6 ... Drainage 7 ... Radioactive substance removal filter 8 ... Adsorbent 9 ... purified water

Claims (2)

液中に含まれる放射性物質の除去率を高めるため、活性炭フィルタと逆浸透膜フィルタと銀イオンの放射性物質に対する化学反応によって放射性物質の除去を行うフィルタ、を備えることを特徴とする浄水装置。  A water purifier comprising: an activated carbon filter, a reverse osmosis membrane filter, and a filter that removes a radioactive substance by a chemical reaction of silver ions to the radioactive substance in order to increase a removal rate of the radioactive substance contained in the liquid. 逆浸透膜フィルタの前処理として活性炭フィルタを配置し、逆浸透膜フィルタの濾過液の後処理として銀イオンの放射性物質に対する化学反応によって放射性物質の除去を行うフィルタを配置すること、を特徴とする請求項1に記載の浄水装置。  An activated carbon filter is disposed as a pretreatment of the reverse osmosis membrane filter, and a filter that removes the radioactive substance by a chemical reaction with respect to the radioactive substance of silver ions is disposed as a post-treatment of the filtrate of the reverse osmosis membrane filter. The water purifier according to claim 1.
JP2011103261A 2011-04-13 2011-04-13 Water purification apparatus improving radioactive substance removal performance Withdrawn JP2012220487A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103474122A (en) * 2013-09-04 2013-12-25 清华大学 Method of removing tetrahydrofurfuryl alcohol from waste water in production of high temperature reactor fuel elements
US20150175448A1 (en) * 2013-12-19 2015-06-25 Benq Materials Corporation System for treating wastewater containing boron and iodine

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103474122A (en) * 2013-09-04 2013-12-25 清华大学 Method of removing tetrahydrofurfuryl alcohol from waste water in production of high temperature reactor fuel elements
US20150175448A1 (en) * 2013-12-19 2015-06-25 Benq Materials Corporation System for treating wastewater containing boron and iodine

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