JP2012210671A - Drill made of alloy steel - Google Patents

Drill made of alloy steel Download PDF

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JP2012210671A
JP2012210671A JP2011077131A JP2011077131A JP2012210671A JP 2012210671 A JP2012210671 A JP 2012210671A JP 2011077131 A JP2011077131 A JP 2011077131A JP 2011077131 A JP2011077131 A JP 2011077131A JP 2012210671 A JP2012210671 A JP 2012210671A
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steel
alloy steel
tempering
temperature
hardness
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Hiroshi Watanabe
博史 渡邊
Koichi Matsumura
宏一 松村
Ryo Katashima
亮 片島
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Mitsubishi Materials Corp
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Abstract

PROBLEM TO BE SOLVED: To provide a drill formed of alloy steel and a surface coated drill formed of alloy steel each having excellent wear resistance in use over a long period.SOLUTION: Each of the drill formed of alloy steel and the surface coated drill formed of alloy steel has a tool base composed of alloy steel which contains 2.0-3.0 mass% of C, 3.0-6.0 mass% of Si, 9.0-15.0 mass% of Cr, 10.0-15.0 mass% of Co (preferably, C+Si+Cr+Co: 25.0-35.0 mass%), 9.0-11.0 mass% in the total of one or two of W and Mo, 1.5-2.5 mass% of V, and whose remaining part is composed Fe and inevitable impurities and which has resistance to high temperature temper softening.

Description

この発明は、長期の使用にわたってすぐれた耐摩耗性を発揮するドリルに関し、特に、高速切削加工時に、刃先が焼戻し温度以上の高温に晒された場合でも優れた高温焼戻し軟化抵抗性を備える合金鋼で工具基体を構成することにより、刃先の硬度低下が防止され、高温下で優れた切削性を発揮する合金鋼製ドリルおよび工具基体表面に硬質被覆層を蒸着形成した表面被覆合金鋼製ドリルに関する。   The present invention relates to a drill that exhibits excellent wear resistance over a long period of use, and in particular, an alloy steel having excellent high-temperature tempering softening resistance even when the cutting edge is exposed to a temperature higher than the tempering temperature during high-speed cutting. The present invention relates to a drill made of an alloy steel that prevents a decrease in the hardness of the cutting edge and exhibits excellent machinability at high temperatures and a surface-coated alloy steel drill in which a hard coating layer is deposited on the surface of the tool base. .

切削工具用の材料としては、合金鋼(JIS SKH、SKD等)、超硬合金、サーメット、cBN、ダイヤモンド等が知られているが、切削工具用合金鋼のなかでは、耐摩耗性と靭性に優れることから高速度工具鋼(JIS SKH)が多用されている。   Alloy steels (JIS SKH, SKD, etc.), cemented carbide, cermet, cBN, diamond, etc. are known as materials for cutting tools. However, among the alloy steels for cutting tools, they have high wear resistance and toughness. High speed tool steel (JIS SKH) is frequently used because of its superiority.

高速度工具鋼は、C,Cr,W,Mo,V,Co等の合金元素を多量に添加し、特に高温での硬さや耐摩耗性を高めた工具鋼であるが、大別して、溶製により製造する高速度工具鋼と粉末冶金法により製造する粉末高速度工具鋼(粉末ハイスともいう)の2種類がある。   High-speed tool steel is a tool steel to which a large amount of alloying elements such as C, Cr, W, Mo, V, Co, etc. are added to improve hardness and wear resistance especially at high temperatures. There are two types of high-speed tool steel manufactured by the method and powder high-speed tool steel (also referred to as powder high speed) manufactured by the powder metallurgy method.

溶製法による場合には、通常の製法により製造し得るものの、粗大炭化物の偏析等による材料の均質化が問題となりやすく、一方、粉末冶金法による場合は、製造工程が複雑でコスト高になるという欠点はあるものの、溶製法により製造が困難である材質をも製造可能とするとともに、均一組織を形成することができるという利点がある。   In the case of the melting method, although it can be manufactured by a normal manufacturing method, the homogenization of the material due to segregation of coarse carbides tends to be a problem, while in the case of the powder metallurgy method, the manufacturing process is complicated and expensive. Although there are drawbacks, there is an advantage that even a material that is difficult to manufacture by a melting method can be manufactured and a uniform structure can be formed.

溶製法による高速度工具鋼については、例えば、特許文献1〜5に記載されており、特許文献1によれば、鋼中成分として微量の希土類元素を含有させ、また、共晶炭化物の形態制御を行うことにより、耐衝撃性と切削性能を高めることが知られている。   The high-speed tool steel by the melting method is described in, for example, Patent Documents 1 to 5. According to Patent Document 1, a trace amount of rare earth elements is contained as a component in the steel, and the shape control of the eutectic carbide is performed. It is known to improve impact resistance and cutting performance by performing.

また、特許文献2によれば、鋼中にVC炭化物を形成することにより耐摩耗性を向上させるとともに、VC炭化物の晶出形態を微細かつ均一化することで靭性を高めることが知られている。   Further, according to Patent Document 2, it is known to improve wear resistance by forming VC carbide in steel and to improve toughness by making the crystallization form of VC carbide fine and uniform. .

また、特許文献3によれば、鋼中の合金成分およびその含有量を調整することにより、熱間加工性、靭性、耐衝撃性、疲労強度を向上させることが知られている。   Further, according to Patent Document 3, it is known that hot workability, toughness, impact resistance, and fatigue strength are improved by adjusting alloy components and their contents in steel.

また、特許文献4によれば、鋼中の合金成分、特に、C、Si、Cr、Mo,Wの含有量を調整し、C:1.05〜2.00%、Si:0.3〜2.0%(好ましくは、Si:0.3〜1.0%)、Cr:3.0〜5.0%とした上で、0.4≦2Mo/(W+2Mo)×Si≦1.0の関係を満足させることにより、焼戻し硬さが高く、靭性、耐摩耗性を向上させることが知られている。   Moreover, according to Patent Document 4, the content of alloy components in steel, particularly C, Si, Cr, Mo, W, is adjusted, and C: 1.05 to 2.00%, Si: 0.3 to 2.0% (preferably Si: 0.3-1.0%), Cr: 3.0-5.0%, 0.4 ≦ 2Mo / (W + 2Mo) × Si ≦ 1.0 It is known that tempering hardness is high and toughness and wear resistance are improved by satisfying the above relationship.

また、特許文献5によれば、鋼中に高硬度の微細炭化物を形成することにより耐摩耗性、耐熱性、耐焼付き性の向上を図り、さらに、鋳造組織を微細化することにより工具切刃の耐チッピング性の向上を図ることが知られている。   Further, according to Patent Document 5, the wear resistance, heat resistance, and seizure resistance are improved by forming fine carbides with high hardness in the steel, and further, the tool cutting edge is obtained by refining the cast structure. It is known to improve chipping resistance.

粉末冶金法による粉末高速度工具鋼(粉末ハイス)については、例えば、特許文献6,7に記載されており、特許文献6によれば、1.5%を超え2.6%以下のC、6%を超え13%以下のCrをそれぞれ含有させ、Siを1.0%以下とし、かつ、鋼中の(W+2Mo)量及び(C−Ceq)の値を規制するとともに、Nb/Vの値を規制することにより、靭性、耐食性を有し、かつ、高温焼戻し軟化抵抗性を高めた粉末高速度工具鋼を得ることができるとされている。   About the powder high-speed tool steel (powder high speed) by the powder metallurgy method, for example, it is described in Patent Documents 6 and 7, and according to Patent Document 6, C is more than 1.5% and 2.6% or less. More than 6% and less than 13% Cr are contained, Si is 1.0% or less, and the (W + 2Mo) amount and (C-Ceq) value in the steel are regulated, and the value of Nb / V It is said that a powder high-speed tool steel having toughness and corrosion resistance and enhanced resistance to high-temperature tempering softening can be obtained by regulating the above.

また、特許文献7によれば、鋼中の合金成分相互の含有量を、一定の関係を満足するように調整することによって、耐摩耗性および靭性を向上させ得るとされている。   According to Patent Document 7, it is said that the wear resistance and toughness can be improved by adjusting the contents of the alloy components in the steel so as to satisfy a certain relationship.

特開平1−165748号公報JP-A-1-165748 特開平7−228946号公報JP-A-7-228946 特開平8−100239号公報Japanese Patent Application Laid-Open No. 8-100239 特開2000−144333号公報JP 2000-144333 A 特許第2573951号明細書Japanese Patent No. 2573951 特開平5−171373号公報JP-A-5-171373 特開2001−294986号公報JP 2001-294986 A

近年の切削技術の進展はめざましく、加えて切削加工における省力化、省エネ化、低コスト化さらに効率化等の要求も強く、これに伴い、高速切削加工、高能率切削加工も求められているが、上記従来の合金鋼から作製された合金鋼製ドリルを用いて高速切削を行ったような場合には、切刃が切削加工時の高熱にさらされるため、合金鋼が高温焼戻し軟化を起こして硬度低下を生じ、その結果、摩耗が進行し工具寿命が短くなるという問題があった。   Recent progress in cutting technology is remarkable, and in addition, there are strong demands for labor saving, energy saving, cost reduction and efficiency improvement in cutting, and accordingly, high speed cutting and high efficiency cutting are also required. When high-speed cutting is performed using an alloy steel drill made from the above-mentioned conventional alloy steel, the cutting blade is exposed to high heat during cutting, and the alloy steel is softened at high temperature. There was a problem that the hardness decreased, and as a result, the wear progressed and the tool life was shortened.

そこで、本発明者等は、高熱発生を伴う高速切削を行ったような場合にも、高温焼戻し軟化を生じず、硬度低下の少ない合金鋼製ドリル、表面被覆合金鋼製ドリルを提供すべく、鋭意研究を行った結果、次のような知見を得たのである。   Therefore, the present inventors do not cause high-temperature temper softening even when high-speed cutting with high heat generation is performed, and to provide a drill made of alloy steel and a surface-coated alloy steel with less hardness reduction, As a result of earnest research, the following findings were obtained.

従来の合金鋼、特に、高速度工具鋼においては、通常その合金成分として、C,Si,Mn,Cr,W,Mo,V,Co等が含有されているが、その合金成分のうちのSiについては、主として脱酸剤としての作用を期待して添加されており、硬さを向上させる作用もあるが、Si含有量が多くなりすぎると、高速度工具鋼の靭性を劣化させることになる(例えば、前記特許文献4参照)ので、靭性に悪影響を与えないという観点から通常は多くても2%以下の範囲内で添加されていた。   Conventional alloy steels, particularly high-speed tool steels, usually contain C, Si, Mn, Cr, W, Mo, V, Co, etc. as their alloy components. Of these alloy components, Si Is added mainly in anticipation of the action as a deoxidizer, and also has the effect of improving hardness, but if the Si content is too high, the toughness of the high-speed tool steel will be deteriorated. (For example, refer to Patent Document 4) Therefore, from the viewpoint of not adversely affecting the toughness, it was usually added within a range of at most 2%.

本発明者等は、C成分、Si成分、Cr成分及びCo成分の含有量と作用に着目し、これらの各成分の含有量を種々に変化させた場合の高温焼戻し軟化特性への影響を調査したところ、鋼中のSi成分の含有量を3.0〜6.0%と高くし、しかも、鋼中のC成分、Cr成分およびCo成分を同時に多量添加した場合には、合金鋼の高温焼戻し軟化特性が大きく改善されること、さらに、C成分、Si成分、Cr成分及びCo成分を同時に多量添加するとともに、C+Si+Cr+Coの合計含有量を特定の数値範囲内に規制した場合には、より一段と高温焼戻し軟化特性が改善され、高温に晒された場合でも硬度低下が抑制されることを見出したのである。   The inventors pay attention to the contents and actions of the C component, Si component, Cr component, and Co component, and investigate the influence on the high-temperature temper softening characteristics when the content of each of these components is variously changed. As a result, when the content of the Si component in the steel is increased to 3.0 to 6.0%, and when a large amount of the C component, the Cr component and the Co component in the steel are added at the same time, the high temperature of the alloy steel. When the temper softening characteristics are greatly improved, and when the C component, Si component, Cr component and Co component are simultaneously added in large quantities, and the total content of C + Si + Cr + Co is regulated within a specific numerical range, it is further enhanced. It has been found that the high-temperature temper softening property is improved, and the hardness reduction is suppressed even when exposed to high temperatures.

なお、ここでいう多量のSiとは、通常の合金鋼において、脱酸剤として添加される量をはるかに超える量をいい、例えば、先に挙げた特許文献1〜6の高速度工具鋼におけるSi含有量は、最大で2質量%であり(なお、特許文献4においては、2%を超える過度の添加は、偏析による靭性の低下を招くとしている)、最大3質量%のSiを含有し得るとしている特許文献7においても、Si含有量の好ましい上限値は1%(段落0022参照)とされており、本発明者等は3質量%以上のSiを添加すると同時にC、Cr及びCoの多量添加を行うことによって、従来技術からは予期し得ない程度に合金鋼の高温焼戻し軟化特性が大きく改善されることを見出したのであり、また、この合金鋼によって構成されたドリルは、刃先が焼戻し温度以上の高温に晒された場合でも優れた高温焼戻し軟化抵抗性を備え、刃先の硬度低下が防止されることから、高温下で優れた耐摩耗性、靭性を発揮することを見出したのである。   In addition, in this case, a large amount of Si refers to an amount far exceeding the amount added as a deoxidizer in ordinary alloy steel. For example, in the high-speed tool steels of Patent Documents 1 to 6 listed above. The Si content is 2% by mass at the maximum (in Patent Document 4, excessive addition exceeding 2% is said to cause a decrease in toughness due to segregation), and the content of Si is 3% by maximum. Also in Patent Document 7 to be obtained, the preferable upper limit value of the Si content is 1% (see paragraph 0022), and the present inventors added 3 mass% or more of Si, and at the same time, added C, Cr and Co. It was found that by adding a large amount, the high temperature temper softening property of the alloy steel was greatly improved to an extent that could not be expected from the prior art, and the drill tip made of this alloy steel had a cutting edge. Tempering It has been found that it has excellent high temperature tempering softening resistance even when exposed to high temperatures, and the hardness of the cutting edge is prevented, so it exhibits excellent wear resistance and toughness at high temperatures. .

この発明は、上記の知見に基づいてなされたものであって、
「(1)質量%で、C:2.0〜3.0%、Si:3.0〜6.0%、Cr:9.0〜15.0%、Co:10.0〜15.0%、WおよびMoのうちの1種または2種の合計:9.0〜11.0%、V:1.5〜2.5%、残部はFeおよび不可避不純物からなる高温焼戻し軟化抵抗性を備える合金鋼で構成したことを特徴とする合金鋼製ドリル。
This invention has been made based on the above findings,
“(1) In mass%, C: 2.0 to 3.0%, Si: 3.0 to 6.0%, Cr: 9.0 to 15.0%, Co: 10.0 to 15.0 %, W and Mo, one or two total: 9.0 to 11.0%, V: 1.5 to 2.5%, the balance being high temperature temper softening resistance consisting of Fe and inevitable impurities An alloy steel drill characterized by comprising alloy steel provided.

(2) C,Si,Cr及びCoの合計含有量が、25.0〜35.0%である前記(1)に記載の高温焼戻し軟化抵抗性を備える合金鋼で構成したことを特徴とする合金鋼製ドリル。   (2) The total content of C, Si, Cr, and Co is 25.0 to 35.0%, and is made of an alloy steel having high-temperature temper softening resistance as described in (1) above. Alloy steel drill.

(3) 前記(1)または(2)に記載の高温焼戻し軟化抵抗性を備える合金鋼を基体とし、該基体表面に硬質被覆層を蒸着形成したことを特徴とする表面被覆合金鋼製ドリル。」
に特徴を有するものである。
(3) A surface-coated alloy steel drill characterized in that the alloy steel having high-temperature temper softening resistance described in (1) or (2) is used as a base, and a hard coating layer is formed by vapor deposition on the surface of the base. "
It has the characteristics.

この発明について、以下に詳細に説明する。   The present invention will be described in detail below.

まず、この発明の合金鋼製ドリルを構成する合金鋼の合金成分組成範囲についての数値限定理由は次の通りである。   First, the reasons for limiting the numerical values of the alloy component composition range of the alloy steel constituting the alloy steel drill of the present invention are as follows.

C:2.0〜3.0質量%(以下においては、質量%を単に%で示す)
Cは、焼入れ状態でその一部がマトリックスに固溶してマトリックスを強化し、また、一部は、W,Mo,Cr,Vと結合して炭化物を形成し、合金鋼の硬さと耐摩耗性を向上させる。
C: 2.0-3.0 mass% (in the following, mass% is simply indicated by%)
Part of C is hardened and solidifies in the matrix to strengthen the matrix, and part of it combines with W, Mo, Cr, and V to form carbides, and the hardness and wear resistance of the alloy steel. Improve sexiness.

C含有量が2.0%未満では、硬さと耐摩耗性向上を期待できないばかりか、後述するSiとの相互作用によって、高温焼戻し軟化特性の改善を図ることができない。また、C含有量が3.0%を超えると、硬くなり過ぎて靭性劣化が生じるようになり、また、不均一なミクロ組織の形成により材質の均質性が担保できなくなることから、C含有量は2.0〜3.0%と定めた。   If the C content is less than 2.0%, not only the hardness and wear resistance can be expected to be improved, but also the high temperature temper softening property cannot be improved by the interaction with Si described later. Further, if the C content exceeds 3.0%, it becomes too hard and deterioration of toughness occurs, and the uniformity of the material cannot be ensured due to the formation of a non-uniform microstructure. Was determined to be 2.0 to 3.0%.

Si:3.0〜6.0%
通常の合金鋼の場合と同様に、Siは脱酸剤としての作用を有する。
Si: 3.0-6.0%
As in the case of ordinary alloy steel, Si acts as a deoxidizer.

さらに、この発明においては、合金鋼の高温焼戻し軟化特性の改善を図る上で、上記Cおよび後記するCr,Coとともに重要な合金成分である。   Further, in the present invention, in order to improve the high temperature temper softening property of the alloy steel, it is an important alloy component together with the C and Cr and Co described later.

Si含有量が3.0%未満では軟化抵抗の向上に寄与がみられず、一方、Si含有量が6.0%を超えると靭性が大幅に低下するため、Si含有量は3.0〜6.0%と定めた。   If the Si content is less than 3.0%, no contribution is seen in improving the softening resistance. On the other hand, if the Si content exceeds 6.0%, the toughness is greatly reduced. Set to 6.0%.

Cr:9.0〜15.0%
Crは、鋼の焼入れ性を確保するとともに、熱処理時の耐酸化性を高め、またSiと同時に大量添加すると軟化特性向上に寄与するため9.0%以上のCrの含有を必要とし、一方、Cr含有量が15.0%を超えると、Cr炭化物が偏析し、加工性が劣化するだけでなく靭性が大幅に低下するため、Cr添加量は、9.0〜15.0%と定めた。
Cr: 9.0 to 15.0%
Cr secures the hardenability of the steel, improves the oxidation resistance during heat treatment, and, if added in a large amount simultaneously with Si, contributes to improving the softening properties, and therefore requires a Cr content of 9.0% or more, If the Cr content exceeds 15.0%, Cr carbide segregates, and not only the workability deteriorates but also the toughness significantly decreases. Therefore, the Cr addition amount is determined to be 9.0 to 15.0%. .

Co:10.0〜15.0%
Coは、十分な焼き戻し硬さを得るためには10.0%以上の含有が必要であるが、その含有量が15.0%を超えると、Co単相で析出し、靭性を大幅に低下させることから、Co含有量は10.0〜15.0%と定めた。
Co: 10.0-15.0%
Co needs to be contained in an amount of 10.0% or more in order to obtain a sufficient tempering hardness. However, if its content exceeds 15.0%, it precipitates in a single phase of Co and greatly increases the toughness. In order to reduce, Co content was defined as 10.0 to 15.0%.

本発明者等は、合金鋼の合金成分である上記のC,Si,Cr,Coの含有量と、焼戻し温度、高温硬さの関連について詳細な調査を行った。   The present inventors conducted a detailed investigation on the relationship between the contents of the above-mentioned C, Si, Cr, Co, which are alloy components of alloy steel, the tempering temperature, and the high temperature hardness.

図1に、各種の鋼についての、焼戻し温度(℃)による高温硬さ変化(軟化割合(HRC硬さ))の一例を示す。   In FIG. 1, an example of the high temperature hardness change (softening ratio (HRC hardness)) by tempering temperature (degreeC) about various steel is shown.

図1において、鋼中のC、Si、CrおよびCoの各含有量は、次のとおりである。
本発明鋼1−A:2.1%C,4.0%Si,12.4%Cr、10.2%Co、
かつ、C+Si+Cr+Co=28.7%
本発明鋼2−A:2.5%C,4.0%Si,9.2%Cr、14.1%Co、
かつ、C+Si+Cr+Co=29.8%
比較鋼11−A:2.1%C、4.0%Si、9.1%Cr、4.7%Co、
比較鋼12−A:3.0%C、4.0%Si、9.0%Cr、4.6%Co、
比較鋼13−A:2.5%C、4.0%Si、12.0%Cr、4.3%Co、
比較鋼15−A:1.0%C,0.2%Si,4.0%Cr、7.3%Co、
ここで、上記比較鋼15は、C,Si,Cr,Co含有量のいずれもが、本発明の組成範囲を外れる従来鋼であり、また、比較鋼11は、C含有量およびSi含有量は本発明の範囲内であるが、Cr含有量、Co含有量が本発明の範囲外であって、比較鋼12、13は、C含有量、Si含有量およびCr含有量は本発明の範囲内であるが、Co含有量が本発明の範囲外のものである。
In FIG. 1, the contents of C, Si, Cr and Co in the steel are as follows.
Invention steel 1-A: 2.1% C, 4.0% Si, 12.4% Cr, 10.2% Co,
And C + Si + Cr + Co = 28.7%
Invention steel 2-A: 2.5% C, 4.0% Si, 9.2% Cr, 14.1% Co,
And C + Si + Cr + Co = 29.8%
Comparative steel 11-A: 2.1% C, 4.0% Si, 9.1% Cr, 4.7% Co,
Comparative steel 12-A: 3.0% C, 4.0% Si, 9.0% Cr, 4.6% Co,
Comparative steel 13-A: 2.5% C, 4.0% Si, 12.0% Cr, 4.3% Co,
Comparative steel 15-A: 1.0% C, 0.2% Si, 4.0% Cr, 7.3% Co,
Here, the comparative steel 15 is a conventional steel in which all of the C, Si, Cr, and Co contents are out of the composition range of the present invention, and the comparative steel 11 has the C content and the Si content. Although within the scope of the present invention, the Cr content and the Co content are outside the scope of the present invention, and the comparative steels 12 and 13 have the C content, the Si content and the Cr content within the scope of the present invention. However, the Co content is outside the scope of the present invention.

図1において、600℃の焼戻し温度における硬さ(H600)を基準とし、焼戻し温度T(℃)(但し、T≧600)における硬さをHとした場合の、焼戻し温度による硬さ低下の度合い示す指標である軟化割合(但し、軟化割合(%)=(H−H600)×100/H600)をみると、Si含有量の多い比較鋼11は、比較鋼15に比しすぐれた軟化抵抗性を有するが、SiとともにCrを同時に多量添加した比較鋼12、13は、比較鋼11よりもすぐれた焼き戻し軟化抵抗性を有するが、Si、CrとともにCoを同時に多量添加した本発明鋼1、2は、比較鋼11〜13、15に比して、さらに一段と優れた焼き戻し軟化抵抗性を有することが分かる。 In Figure 1, a reference hardness at tempering temperature of 600 ° C. The (H 600), tempering temperature T (° C.) (where, T ≧ 600) when the hardness at was H T, decreases the hardness due to tempering temperature When the softening ratio (however, the softening ratio (%) = (H T −H 600 ) × 100 / H 600 ), which is an index indicating the degree of the above, the comparative steel 11 having a high Si content is compared with the comparative steel 15. Comparative steels 12 and 13 having excellent softening resistance but simultaneously adding a large amount of Cr with Si have better tempering softening resistance than Comparative Steel 11, but simultaneously adding a large amount of Co together with Si and Cr. It can be seen that the inventive steels 1 and 2 have even more excellent temper softening resistance than the comparative steels 11 to 13 and 15.

図2には、請求項1、請求項2に記載の成分組成を満足する本発明鋼と、本発明範囲外の成分組成を有する比較鋼について、C+Si+Cr+Coの合計含有量による焼戻し温度(℃)−焼戻し硬さ(HRC)の関係を示すが、図2からわかるように、C+Si+Cr+Coの合計含有量が25.0〜35.0質量%の範囲内である本発明鋼1,5,9(請求項2に対応)は、比較鋼11,12,13に比して、高温焼き戻しによる焼戻し硬さの変化が少なく、焼戻し硬さの低下量も少ないものとなる。   FIG. 2 shows the tempering temperature (° C.) − By the total content of C + Si + Cr + Co for the steel of the present invention satisfying the component compositions of claims 1 and 2 and the comparative steel having a component composition outside the scope of the present invention. As shown in FIG. 2, the steels according to the present invention 1, 5 and 9 have a total content of C + Si + Cr + Co in the range of 25.0 to 35.0% by mass. 2)), the change in tempering hardness due to high-temperature tempering is small and the amount of decrease in tempering hardness is small compared to the comparative steels 11, 12, and 13.

このことから、C含有量を2.0〜3.0%とした上で、Si含有量を3.0〜6.0%と高くし、さらに、Cr含有量を9.0〜15.0%、Co含有量を10.0〜15.0%とした本発明の合金鋼(より好ましくは、C+Si+Cr+Coの合計含有量が25.0〜35.0質量%)の高温焼戻し軟化抵抗性は、非常に優れていることが分かる。   From this, the C content is set to 2.0 to 3.0%, the Si content is increased to 3.0 to 6.0%, and the Cr content is set to 9.0 to 15.0. %, The high temperature temper softening resistance of the alloy steel of the present invention in which the Co content is 10.0 to 15.0% (more preferably, the total content of C + Si + Cr + Co is 25.0 to 35.0% by mass) is It turns out that it is very excellent.

本発明で高温焼戻し軟化抵抗性が向上する理由は未だ十分に解明されているとはいえないが、おそらく、600〜700℃の温度範囲では、鋼中に多量に含有されているSiがセメンタイト形成を抑制するとともに、セメンタイトに固溶したCrが連続的に炭化物を形成することでセメンタイトの凝集・粗大化を遅らせ、焼戻し時の母相の軟化が遅れると考えられる。
加えてSi、Crを同時添加することで母相中にSiとCrの金属間化合物が形成され、焼戻し二次硬化ピークが高温側に移動し、焼戻し時の軟化開始点が高温側になると考えられる。
これらの効果により高温焼戻し軟化抵抗が大幅に向上していると推測される。
The reason why the high-temperature tempering softening resistance is improved in the present invention has not yet been fully elucidated. However, in a temperature range of 600 to 700 ° C., Si contained in a large amount in the steel forms cementite. It is considered that Cr dissolved in cementite continuously forms carbides, thereby delaying cementite aggregation and coarsening and delaying softening of the matrix during tempering.
In addition, the simultaneous addition of Si and Cr forms an intermetallic compound of Si and Cr in the matrix, and the tempering secondary hardening peak moves to the high temperature side, and the softening start point during tempering is on the high temperature side. It is done.
It is presumed that the high temperature temper softening resistance is greatly improved by these effects.

WおよびMoのうちの1種または2種の合計:9.0〜11.0%
Wは、MC型やMC型の炭化物を形成すると共に、その一部がマトリックス中に固溶し、耐摩耗性、高温焼戻し軟化抵抗性を向上させるが、Wの含有量が過剰になると、炭化物の粗大化を招き、靭性も低下する。
Total of one or two of W and Mo: 9.0 to 11.0%
W forms MC-type and M 6 C-type carbides, and a part thereof dissolves in the matrix to improve wear resistance and high-temperature temper softening resistance. However, when the W content is excessive, , Leading to coarsening of carbides and toughness.

また、Moは、Wと同様に、MC型やM6C型の炭化物を形成して耐摩耗性、高温焼戻し軟化抵抗性を高めるとともに、靭性を向上させるが、Moの含有量が過剰になると、結晶粒が粗大化し脆弱になるとともに、熱処理時に脱炭を生じやすくなる。 Mo, like W, forms MC-type and M 6 C-type carbides to improve wear resistance and high-temperature temper softening resistance and improve toughness, but when the Mo content becomes excessive The crystal grains become coarse and brittle, and decarburization is likely to occur during heat treatment.

したがって、耐摩耗性、高温焼戻し軟化抵抗性を向上させるためには、WおよびMoのうちの1種または2種の合計は9.0%以上必要であるが、その合計量が11.0%を超えると、炭化物の粗大化、結晶粒の粗大化による靭性の低下等が生じるようになるので、WおよびMoのうちの1種または2種の含有量は、9.0〜11.0%と定めた。   Therefore, in order to improve wear resistance and high temperature temper softening resistance, the total of one or two of W and Mo needs to be 9.0% or more, but the total amount is 11.0%. If it exceeds 1, the carbides become coarse and the toughness is lowered due to the coarsening of crystal grains. Therefore, the content of one or two of W and Mo is 9.0 to 11.0%. It was determined.

V:1.5〜2.5%
Vは、強力な炭化物形成元素で、Cと結合することによってMC型の微細な炭化物を形成し、耐摩耗性の向上に効果がある。また、Vは、結晶粒の微細化作用を有し、結晶粒の粗大化による靭性の低下を防止するとともに、高温焼戻し軟化抵抗性を高める。このような効果を発揮させるためには、1.5%以上含有させる必要があるが、過剰に含有されると研削性を害するのでその上限は2.5%に定めた。
V: 1.5-2.5%
V is a strong carbide-forming element, and when combined with C, forms fine MC-type carbides, and is effective in improving wear resistance. Further, V has a crystal grain refining action, prevents a decrease in toughness due to crystal grain coarsening, and increases high-temperature temper softening resistance. In order to exert such an effect, it is necessary to contain 1.5% or more, but if it is contained excessively, grindability is impaired, so the upper limit was set to 2.5%.

Mn: 1.0%以下
本発明では、Siを多量に含有し、これが脱酸剤として作用することから、Si同様に脱酸剤として作用するMnの添加は必ずしも必要でないが、Mnには焼入れ性向上作用もあるので、1.0%以下の範囲内で添加することができる。
Mn: 1.0% or less In the present invention, since Si contains a large amount and acts as a deoxidizing agent, it is not always necessary to add Mn that acts as a deoxidizing agent like Si, but Mn is quenched. Since there is also a property improving effect, it can be added within a range of 1.0% or less.

上記のとおり、本発明の合金鋼は、質量%で、C:2.0〜3.0%、Si:3.0〜6.0%、Cr:9.0〜15.0%、Co:10.0〜15.0%(好ましくは、C,Si,Cr及びCoの合計含有量は、25.0〜35.0%)、WおよびMoのうちの1種または2種の合計:9.0〜11.0%、V:1.5〜2.5%、残部はFeからなるが、前記のとおり、1.0%以下のMnを含有することが許容されるとともに、不可避不純物として、本発明の合金鋼の高温焼戻し軟化抵抗性に影響を与えない範囲内でのP,S,N,Ni,Nb,Cu,As,Sb等の含有が許容される。   As described above, the alloy steel of the present invention is in mass%, C: 2.0 to 3.0%, Si: 3.0 to 6.0%, Cr: 9.0 to 15.0%, Co: 10.0 to 15.0% (preferably, the total content of C, Si, Cr and Co is 25.0 to 35.0%), the total of one or two of W and Mo: 9 0.0 to 11.0%, V: 1.5 to 2.5%, and the balance is made of Fe. As described above, it is allowed to contain 1.0% or less of Mn, and as an inevitable impurity The alloy steel of the present invention is allowed to contain P, S, N, Ni, Nb, Cu, As, Sb, etc. within a range that does not affect the high temperature temper softening resistance.

また、本発明の合金鋼の高温焼戻し軟化抵抗性を実験により定量化したところ、600〜700℃における軟化割合(%)を、
軟化割合(%)=(H−H600)×100/H600
で表した場合、本発明の合金鋼では、上記軟化割合(%)は0〜10%の範囲内であることを確認した。
Moreover, when the high temperature temper softening resistance of the alloy steel of the present invention was quantified by experiment, the softening ratio (%) at 600 to 700 ° C.
Softening ratio (%) = (H T −H 600 ) × 100 / H 600
In the alloy steel of the present invention, it was confirmed that the softening ratio (%) was in the range of 0 to 10%.

ここで、軟化割合(%)とは、600℃の焼戻し温度における硬さ(H600)を基準とし、焼戻し温度T(℃)(但し、600≦T≦700)における硬さをHとした場合の、焼戻し温度による硬さ低下の度合い示す指標である。 Here, the softening percentage, as a reference hardness at tempering temperature of 600 ° C. The (H 600), tempering temperature T (° C.) (where, 600 ≦ T ≦ 700) The hardness at was H T This is an index indicating the degree of hardness reduction due to tempering temperature.

また、本発明では、合金鋼製ドリルを基体とし、その表面に、AlとTiの複合窒化物層、AlとTiとSiの複合窒化物層、AlとCrの複合窒化物層等の当業者に既によく知られている硬質被覆層を蒸着形成することにより、表面被覆合金鋼製ドリルとして利用することができる。   Further, in the present invention, a person skilled in the art such as a composite nitride layer of Al and Ti, a composite nitride layer of Al, Ti and Si, a composite nitride layer of Al and Cr, etc. on the surface of a drill made of alloy steel as a base. Can be used as a surface-coated alloy steel drill by vapor deposition of a well-known hard coating layer.

上記の硬質被覆層を蒸着形成した表面被覆合金鋼製ドリルは、耐熱性、耐摩耗性が一段と向上し、高温切削条件下でさらに優れた切削性を発揮するものである。   The surface-coated alloy steel drill on which the hard coating layer is formed by vapor deposition is further improved in heat resistance and wear resistance, and exhibits further excellent machinability under high-temperature cutting conditions.

本発明の合金鋼製ドリル、表面被覆合金鋼製ドリルは、特に、合金成分としてのCを2.0〜3.0%とした上で、Si添加量、Cr添加量およびCo添加量を高め、Si含有量を3.0〜6.0%、Cr含有量を9.0〜15.0%、Co含有量を10.0〜15.0%(好ましくは、C,Si,Cr及びCoの合計含有量は、25.0〜35.0%)、としたことにより、600〜700℃の温度範囲で焼戻しを行った場合でもすぐれた高温焼戻し軟化抵抗性を示すことから、高温にさらされる高速切削条件下であっても、刃先の軟化(硬度低下)が生じることがないために、長期の使用に亘って、すぐれた切削性能を発揮することができる。   The alloy steel drill and surface-coated alloy steel drill of the present invention increase the Si addition amount, the Cr addition amount, and the Co addition amount, particularly with C as the alloy component being 2.0 to 3.0%. The Si content is 3.0 to 6.0%, the Cr content is 9.0 to 15.0%, the Co content is 10.0 to 15.0% (preferably C, Si, Cr and Co). Therefore, even when tempering is performed in a temperature range of 600 to 700 ° C., it exhibits excellent high-temperature tempering softening resistance, so that it is exposed to high temperatures. Even under high-speed cutting conditions, since the cutting edge is not softened (decrease in hardness), excellent cutting performance can be exhibited over a long period of use.

焼戻しを行った場合の、焼戻し温度(℃)と軟化割合(%)との関係を示すグラフである。It is a graph which shows the relationship between tempering temperature (degreeC) and a softening ratio (%) at the time of performing tempering. 本発明鋼と比較鋼の焼戻し温度(℃)と焼戻し硬さ(HRC)との関係に及ぼすC,Si、Cr及びCoの合計含有量の影響を示すグラフである。It is a graph which shows the influence of the total content of C, Si, Cr, and Co on the relationship between the tempering temperature (° C.) and the tempering hardness (HRC) of the steel of the present invention and the comparative steel.

本発明を実施例により、以下に説明する。   The invention is illustrated below by means of examples.

窒素ガスアトマイズ法によって製造した所定の成分組成を有する粉末を、カプセルに充填・脱気後、温度1150℃×圧力100MPaにてHIP処理(熱間静水圧プレス処理)し、表1に示す成分組成を有する本発明の粉末合金鋼1〜10(以下、本発明鋼1〜10という)を作製した。   A powder having a predetermined component composition produced by a nitrogen gas atomization method is filled into a capsule and degassed, and then subjected to HIP treatment (hot isostatic pressing) at a temperature of 1150 ° C. and a pressure of 100 MPa to obtain the component composition shown in Table 1. The powder alloy steels 1 to 10 of the present invention (hereinafter referred to as the present invention steels 1 to 10) were produced.

また、同様にして、本発明から外れる成分組成を有する比較例の粉末合金鋼11〜15(以下、比較鋼11〜15という)を作製した。   Similarly, powder alloy steels 11 to 15 of comparative examples (hereinafter referred to as comparative steels 11 to 15) having component compositions that depart from the present invention were produced.

同じく表1に、比較鋼11〜15の成分組成を示す。   Similarly, Table 1 shows component compositions of comparative steels 11 to 15.

Figure 2012210671
上記本発明鋼1〜10について、表2に示す条件で熱処理を行い、本発明鋼1−A〜1−D,本発明鋼2−A〜2−D,本発明鋼3−A、3−B,本発明鋼4−A、4−B,本発明鋼5−A、5−B,本発明鋼6−A、6−B,本発明鋼7−A、7−B,本発明鋼8−A、8−B,本発明鋼9−A、9−B,本発明鋼10−A、10−Bを作製した。
Figure 2012210671
About the said invention steel 1-10, it heat-processes on the conditions shown in Table 2, this invention steel 1-A to 1-D, this invention steel 2-A to 2-D, this invention steel 3-A, 3- B, Invention Steel 4-A, 4-B, Invention Steel 5-A, 5-B, Invention Steel 6-A, 6-B, Invention Steel 7-A, 7-B, Invention Steel 8 -A, 8-B, Invention steels 9-A, 9-B, Invention steels 10-A, 10-B were produced.

同様に、比較鋼11〜15についても、表3に示す条件で熱処理を行い、比較鋼11−A〜11−D,比較鋼12−A〜12−D,比較鋼13−A、13−B,比較鋼14−A、14−B,比較鋼15−A、15−Bを作製した。   Similarly, the comparative steels 11 to 15 were also heat-treated under the conditions shown in Table 3, and the comparative steels 11-A to 11-D, the comparative steels 12-A to 12-D, the comparative steels 13-A and 13-B were used. Comparative steels 14-A and 14-B and comparative steels 15-A and 15-B were produced.

即ち、850〜950℃×60〜90分の条件でオーステナイト化処理を行った後、1130〜1180℃×30分間保持で焼入れし、その後、600〜700℃×1時間保持、戻し回数3回で焼戻しを行った。   That is, after performing austenitizing treatment under conditions of 850 to 950 ° C. × 60 to 90 minutes, quenching is performed by holding at 1130 to 1180 ° C. for 30 minutes, then holding at 600 to 700 ° C. for 1 hour, and the number of times of return is 3 Tempering was performed.

それぞれについて、焼入れ硬さ、600℃における硬さ(H600)、所定の焼戻し温度Tにおける硬さ(H)をロックウェル硬度計で測定(いずれも5点測定の平均値)することにより硬度を求め、その硬度値から
軟化割合(%)(=(H−H600)×100/H600
を算出した。
For each, the hardness is measured by measuring the quenching hardness, the hardness at 600 ° C. (H 600 ), and the hardness at a predetermined tempering temperature T (H T ) with a Rockwell hardness meter (both are average values of five points). And the softening ratio (%) from the hardness value (= (H T −H 600 ) × 100 / H 600 )
Was calculated.

これらの値を、表2、表3に示す。   These values are shown in Tables 2 and 3.

なお、本発明鋼1−A、本発明鋼2−A、比較鋼11−A、比較鋼12−A、比較鋼13−A、比較鋼15−Aについては、焼戻し温度と軟化割合の関係を、図1に示した。   In addition, about this invention steel 1-A, this invention steel 2-A, comparative steel 11-A, comparative steel 12-A, comparative steel 13-A, and comparative steel 15-A, the relationship between tempering temperature and a softening ratio is shown. This is shown in FIG.

Figure 2012210671
Figure 2012210671

Figure 2012210671
表2、表3および図1から明らかなように、600〜700℃という高温焼戻しが行われた場合でも、本発明鋼1〜10は、すぐれた焼戻し硬さ(HRCは50以上)を有するとともに、比較鋼11〜15に比してすぐれた高温焼戻し軟化抵抗性を示し、例えば、焼戻し温度700℃における軟化割合(%)は最大でも−10%(例えば、本発明鋼1−D,3−B,5−B,10−B)であった。
Figure 2012210671
As is apparent from Tables 2 and 3 and FIG. 1, even when high temperature tempering of 600 to 700 ° C. is performed, the steels 1 to 10 of the present invention have excellent tempering hardness (HRC is 50 or more). And high temperature tempering softening resistance compared to comparative steels 11 to 15, for example, the softening ratio (%) at tempering temperature of 700 ° C. is −10% at the maximum (for example, steels of the present invention 1-D, 3- B, 5-B, 10-B).

これに対して、比較鋼11〜15は、本発明鋼1〜10に比して、高温焼戻し軟化抵抗性が劣り、例えば、焼戻し温度700℃における軟化割合(%)
は、−34%(比較鋼14−B),−26%(比較鋼15−B)であって、高温焼戻し軟化抵抗性が十分であるとは言えない。
On the other hand, the comparative steels 11 to 15 are inferior in high-temperature temper softening resistance as compared with the inventive steels 1 to 10, for example, the softening ratio (%) at a tempering temperature of 700 ° C.
Are -34% (Comparative Steel 14-B) and -26% (Comparative Steel 15-B), and cannot be said to have sufficient high-temperature temper softening resistance.

次に、上記で作製した表1に示す成分組成の本発明鋼1〜10を素材として、研削加工にて、溝形成部の直径×長さは、それぞれ6mm×56mmであり、ねじれ角30度の2枚刃形状をもつ本発明合金鋼製ドリル(以下、本発明ドリルという)1〜10をそれぞれ製造した。   Next, the present invention steels 1 to 10 having the composition shown in Table 1 prepared as described above are used as a raw material, and the diameter x length of the groove forming portion is 6 mm x 56 mm and the twist angle is 30 degrees by grinding. The present invention alloy steel drills (hereinafter referred to as the present invention drills) 1 to 10 having a two-blade shape were manufactured, respectively.

同様に、比較例鋼11〜15についても、比較例ドリル11〜15を作製した。   Similarly, the comparative example drills 11-15 were produced also about the comparative example steels 11-15.

ついで、上記本発明ドリル1〜10および比較例ドリル11〜15のそれぞれに対して、(Al0.6,Ti0.4)Nからなる層厚5μmの硬質被覆層をアークイオンプレーティングにより蒸着形成することにより、本発明合金鋼製ドリル(本発明被覆ドリルという)1〜10および比較例合金製ドリル(比較例被覆ドリルという)11〜15を作製した。 Next, a hard coating layer made of (Al 0.6 , Ti 0.4 ) N and having a layer thickness of 5 μm is deposited on each of the above-described drills 1 to 10 and comparative drills 11 to 15 by arc ion plating. By forming, drills 1-10 of the present invention alloy steel (referred to as this invention coated drill) and 11-15 drills made as a comparative example alloy (referred to as comparative example covered drill) were produced.

ついで、上記硬質被覆層を蒸着形成した本発明被覆ドリル1〜10および比較例被覆ドリル11〜15を用いて、次の条件で湿式高速穴あけ切削加工試験を行ない、切削性能を評価した。   Next, using the inventive coated drills 1 to 10 and comparative example coated drills 11 to 15 on which the hard coating layer was formed by vapor deposition, a wet high speed drilling cutting test was performed under the following conditions to evaluate the cutting performance.

被削材−平面:100mm×250mm、厚さ:16mmの寸法のJIS・S50Cの板材、
切削速度: 60 m/min.、
送り: 0.22 mm/rev、
穴深さ: 16 mm、
の条件での炭素鋼の湿式高速穴あけ切削加工試験(通常の切削速度は30m/min.)。
上記の湿式高速穴あけ切削加工試験(水溶性切削油使用)において工具寿命に至るまでの切削長を測定した。
上記の結果を表4に示した。
Work material-plane: 100 mm x 250 mm, thickness: 16 mm JIS / S50C plate material,
Cutting speed: 60 m / min. ,
Feed: 0.22 mm / rev,
Hole depth: 16 mm,
Wet high-speed drilling test of carbon steel under the conditions (normal cutting speed is 30 m / min.).
In the wet high-speed drilling test (using a water-soluble cutting oil), the cutting length up to the tool life was measured.
The results are shown in Table 4.

Figure 2012210671
表4に示す結果から、本発明被覆ドリル1〜10は切削加工時の高温にさらされても、切刃部の高温焼戻し軟化抵抗性が高いことから、軟化(硬度低下)による摩耗進行は抑制され、また、欠損等の異常損傷を生じることもなく、正常な摩耗形態をとり、本発明被覆ドリル1〜10では切削長は120m以上であり、すぐれた切削性能を示した。
Figure 2012210671
From the results shown in Table 4, the coated drills 1 to 10 of the present invention have high resistance to high-temperature tempering and softening at the cutting edge portion even when exposed to high temperatures during cutting, so that the progress of wear due to softening (decrease in hardness) is suppressed. Moreover, it took a normal wear form without causing abnormal damage such as defects, and the coated drills 1 to 10 of the present invention had a cutting length of 120 m or more, and showed excellent cutting performance.

これに対して、比較例被覆ドリル11〜15は、本発明被覆ドリル1〜10に比べ軟化抵抗が低いことから、硬度低下による摩耗進行が促進され、切削長も120m未満であって、短寿命であった。   On the other hand, since the comparative example coated drills 11 to 15 have lower softening resistance than the coated drills 1 to 10 of the present invention, the progress of wear due to the decrease in hardness is promoted, the cutting length is less than 120 m, and the short service life is achieved. Met.

上記のとおり、本発明の合金鋼製ドリル、表面被覆合金鋼製ドリルは、すぐれた高温焼戻し軟化抵抗性を有し、刃先の硬度低下が防止される結果、高熱を発生する切削条件下で、すぐれた切削性能、耐摩耗性を発揮し、また、長寿命であることから、産業上の有益性が非常に大きいといえる。   As described above, the alloy steel drill of the present invention, the surface-coated alloy steel drill has excellent high-temperature tempering softening resistance, and as a result of preventing hardness reduction of the blade edge, under cutting conditions that generate high heat, Since it exhibits excellent cutting performance and wear resistance, and has a long life, it can be said that the industrial benefits are very large.

Claims (3)

質量%で、C:2.0〜3.0%、Si:3.0〜6.0%、Cr:9.0〜15.0%、Co:10.0〜15.0%、WおよびMoのうちの1種または2種の合計:9.0〜11.0%、V:1.5〜2.5%、残部はFeおよび不可避不純物からなる高温焼戻し軟化抵抗性を備える合金鋼で構成したことを特徴とする合金鋼製ドリル。   In mass%, C: 2.0 to 3.0%, Si: 3.0 to 6.0%, Cr: 9.0 to 15.0%, Co: 10.0 to 15.0%, W and Sum of one or two of Mo: 9.0 to 11.0%, V: 1.5 to 2.5%, the balance is an alloy steel having high temperature temper softening resistance composed of Fe and inevitable impurities Alloy steel drill characterized by comprising. C,Si,Cr及びCoの合計含有量が、25.0〜35.0%である請求項1に記載の高温焼戻し軟化抵抗性を備える合金鋼で構成したことを特徴とする合金鋼製ドリル。   The total content of C, Si, Cr and Co is 25.0 to 35.0%. The alloy steel drill comprising the alloy steel having high temperature temper softening resistance according to claim 1. . 請求項1または2に記載の高温焼戻し軟化抵抗性を備える合金鋼を基体とし、該基体表面に硬質被覆層を蒸着形成したことを特徴とする表面被覆合金鋼製ドリル。   A drill made of surface-coated alloy steel, characterized in that the alloy steel having high-temperature temper softening resistance according to claim 1 or 2 is used as a base, and a hard coating layer is formed by vapor deposition on the surface of the base.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104561500A (en) * 2013-10-21 2015-04-29 湖州市千金宝云机械铸件有限公司 Thermal treatment method for mining drill bit

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104561500A (en) * 2013-10-21 2015-04-29 湖州市千金宝云机械铸件有限公司 Thermal treatment method for mining drill bit

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