JP2012162635A - Sterilizing detergent composition for bathroom - Google Patents
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Abstract
Description
本発明は、少なくとも界面活性剤、カチオン系殺菌剤を含むトイレ用除菌洗浄剤において、そのカチオン系殺菌剤がポリヘキサメチレングアニジン・塩酸塩であることを特徴とするトイレ用除菌洗浄剤組成物に関するものであり、特に水洗トイレのタンク上部に設置される透明または半透明の容器に充填される製品に関する。 The present invention relates to a toilet sanitizing detergent comprising at least a surfactant and a cationic fungicide, wherein the cationic fungicide is polyhexamethylene guanidine hydrochloride, wherein the toilet sanitizing detergent composition is characterized in that In particular, the present invention relates to a product filled in a transparent or translucent container installed in the upper part of a tank of a flush toilet.
水洗トイレの貯水タンクに設置されるトイレ用除菌洗浄剤あるいはトイレ用消臭芳香剤は、通常透明又は半透明の容器に入れられ、必要に応じて該容器の排出孔から排出されることにより使用される。そして排出毎に一定量の除菌洗浄剤が排出孔から流出することにより、毎使用時に安定した除菌洗浄効果を得ることができる。また使用される水は、一般的には水道水が主流であり、残留塩素が0.3ppm〜1.5ppmが含まれる。 The toilet sanitizer or toilet deodorant fragrance installed in the water storage tank of the flush toilet is usually placed in a transparent or translucent container and discharged from the discharge hole of the container as necessary. used. And since a fixed amount of sterilization detergent flows out from the discharge hole for every discharge, a stable sterilization and cleaning effect can be obtained at each use. Moreover, the water used is generally tap water, and residual chlorine is contained in an amount of 0.3 ppm to 1.5 ppm.
除菌洗浄剤組成物のカチオン系殺菌剤としてポリヘキサメチレンビグアナイド塩を使用するということは、特許文献1−5に開示されている。しかしながら、ポリヘキサメチレンビグアナイド塩を除菌洗浄剤の殺菌剤として使用する場合、使用する水が水道水の場合、水道水に含まれる残留塩素の影響により除菌効果が低下する。 It is disclosed in Patent Documents 1-5 that polyhexamethylene biguanide salt is used as a cationic disinfectant of a disinfecting detergent composition. However, when polyhexamethylene biguanide salt is used as a disinfectant for a disinfecting detergent, when the water used is tap water, the disinfecting effect is reduced due to the influence of residual chlorine contained in the tap water.
また除菌洗浄剤組成物において、カチオン系殺菌剤としてポリヘキサメチレングアニジン塩を使用することは特許文献6−10に開示されている。しかしながら、これらに使用されているポリヘキサメチレングアニジン塩はリン酸塩であるため、河川等に流出した場合、河川の富栄養化等が懸念される。 Moreover, it is disclosed by patent documents 6-10 that polyhexamethylene guanidine salt is used as a cation type | system | group germicide in disinfection detergent composition. However, since the polyhexamethylene guanidine salt used in these is a phosphate, there is concern about eutrophication of the river when it flows into the river.
本発明の課題は、上記問題点がなく、かつ、除菌効果に優れ、黒ずみの発生を抑制するトイレ用除菌洗浄剤を提供することである。 An object of the present invention is to provide a sterilization detergent for toilets that does not have the above-described problems, has an excellent sterilization effect, and suppresses the occurrence of darkening.
本発明は、
[1] 界面活性剤及びカチオン系殺菌剤を含むトイレ用除菌洗浄剤組成物において、カチオン系殺菌剤が下記化学式Iで表わされるポリヘキサメチレングアニジン・塩酸塩であることを特徴とするトイレ用除菌洗浄剤組成物。
化学式I
(式中nは1〜100の整数である。)、
[2] ポリヘキサメチレングアニジン・塩酸塩の含有量が0.1重量%以上10重量%以下であることを特徴とする[1]記載のトイレ用除菌洗浄剤組成物、
に関する。
本発明によれば、トイレ用除菌洗浄剤におけるカチオン系殺菌剤がポリヘキサメチレングアニジン・塩酸塩であるため、極低濃度使用においても水道水の残留塩素の影響を受けないので安定した除菌効果が提供できる。
The present invention
[1] A toilet sanitizing detergent composition containing a surfactant and a cationic fungicide, wherein the cationic fungicide is polyhexamethyleneguanidine hydrochloride represented by the following chemical formula I: Disinfectant cleaning composition.
Formula I
(Wherein n is an integer of 1 to 100),
[2] The disinfectant cleaning composition for toilets according to [1], wherein the content of polyhexamethylene guanidine hydrochloride is 0.1 wt% or more and 10 wt% or less,
About.
According to the present invention, since the cationic disinfectant in the disinfectant cleaning agent for toilets is polyhexamethyleneguanidine hydrochloride, it is not affected by residual chlorine in tap water even when used at extremely low concentrations, so that stable disinfection is possible. An effect can be provided.
水洗トイレの貯水タンクに設置されるトイレ用除菌洗浄剤は、毎使用時に排出される除菌洗浄剤濃度が極低濃度であり、流出水は残留塩素を含有する水道水が一般的に使用されている。
カチオン系殺菌剤としてポリヘキサメチレンビグアナイド塩をこのような用途に使用する場合、ポリヘキサメチレンビグアナイド塩が水道水の残留塩素と反応する結果、ポリヘキサメチレンビグアナイド塩の一部が失活してしまい除菌効果が低下することが分かった。
本発明は、少なくとも界面活性剤、カチオン系殺菌剤を含むトイレ用除菌洗浄剤において、カチオン系殺菌剤がポリヘキサメチレングアニジン塩酸塩であり、好ましくはその含有量が0.1重量%以上10重量%以下であるトイレ用除菌洗浄剤組成物である。
Disinfecting detergents for toilets installed in the storage tanks of flush toilets are extremely low in the concentration of disinfecting detergents discharged at each use, and tap water containing residual chlorine is generally used as effluent. Has been.
When polyhexamethylene biguanide salt is used for such applications as a cationic bactericidal agent, polyhexamethylene biguanide salt reacts with residual chlorine in tap water, and as a result, part of polyhexamethylene biguanide salt is deactivated. It was found that the sterilization effect decreased.
The present invention relates to a toilet sanitizing detergent containing at least a surfactant and a cationic fungicide, wherein the cationic fungicide is polyhexamethylene guanidine hydrochloride, and the content thereof is preferably 0.1% by weight or more and 10%. It is a disinfectant cleaning composition for toilets that is not more than wt%.
本発明によれば、残留塩素を含有した水道水を使用しても除菌効果の高いトイレ用除菌洗浄剤が得られる。 ADVANTAGE OF THE INVENTION According to this invention, even if it uses the tap water containing a residual chlorine, the disinfection cleaning agent for toilets with a high disinfection effect is obtained.
本発明に係るトイレ用除菌洗浄剤組成物において用いられる界面活性剤としては、「界面活性剤の化学と応用」(妹尾 学著、(社)日本化学会、1995年1月30日)発行、「界面活性剤 −物性・応用・化学生態学−」(北原 文雄、玉井 康勝、早野 重雄、原 一郎 編、(株)講談社、1994年11月1日発行)、「洗浄の基礎知識」(大木 健司、八木 和久著、産業図書(株)、平成11年3月31日発行)に記載されている陰イオン系界面活性剤、陽性界面活性剤、非イオン系界面活性剤、両性界面活性剤が使用できるが、好ましくは陽性界面活性剤、非イオン系界面活性剤、両性界面活性剤から選択されるのが好ましい。これらの界面活性剤の配合割合は、洗浄性、起泡性、安定性等を考慮して任意に配合できる。 As the surfactant used in the disinfectant cleaning composition for toilets according to the present invention, “Chemistry and Application of Surfactants” (Satoshi Senao, The Chemical Society of Japan, January 30, 1995) issued. , "Surfactants-Physical properties, applications, chemical ecology-" (Fumio Kitahara, Yasukatsu Tamai, Shigeo Hayano, Ichiro Hara, edited by Kodansha, November 1, 1994), "Basic knowledge of cleaning" ( Anionic surfactants, positive surfactants, nonionic surfactants, amphoteric surfactants described in Kenji Oki, Kazuhisa Yagi, Sangyo Tosho Co., Ltd., issued on March 31, 1999) However, it is preferable to select from positive surfactants, nonionic surfactants, and amphoteric surfactants. The blending ratio of these surfactants can be arbitrarily blended in consideration of detergency, foamability, stability, and the like.
化学式Iのポリヘキサメチレングアニジン・塩酸は公知の方法、例えばRU−2191606(UA−2000127055)で製造できる。 The polyhexamethyleneguanidine / hydrochloric acid of the formula I can be produced by a known method, for example, RU-2191606 (UA-2000127055).
その他、除菌洗浄剤の成分として必要に応じて公知の水溶性溶剤、アルカリ剤、防錆剤、香料、変色防止剤を任意に配合できる。 In addition, a known water-soluble solvent, alkali agent, rust inhibitor, fragrance, and discoloration inhibitor can be optionally blended as necessary as a component of the sterilizing detergent.
水溶性溶剤としては、例えばエタノール等の炭化水素1〜5の1価アルコール、プロピレングリコール等の炭素数2〜12の2価アルコール、ジエチレングリコールモノエチルエーテル等のポリアルキレングリコールアルキルエーテルが挙げられる。 Examples of the water-soluble solvent include monohydric alcohols having 1 to 5 hydrocarbons such as ethanol, dihydric alcohols having 2 to 12 carbon atoms such as propylene glycol, and polyalkylene glycol alkyl ethers such as diethylene glycol monoethyl ether.
アルカリ剤としては例えば、モノエタノールアミン等のアルカノールアミン等が挙げられる。 Examples of the alkali agent include alkanolamines such as monoethanolamine.
防錆剤としては例えば、亜硝酸塩、安息香酸塩、ベンゾトリアゾール、ベンゾチアゾール等が挙げられる。 Examples of the rust inhibitor include nitrite, benzoate, benzotriazole, benzothiazole and the like.
香料としては、単独の香料成分を用いてもよく、複数の香料成分を特定の比率で使用できる。香料成分としては、「香料の化学」(赤星亮一著、日本化学編 産業化学シリーズ 昭和58年9月16日発行)や「合成香料 化学と商品知識」(印藤 元一著、化学工業日報社、1996年3月6日発行)等に記載されたものが挙げられる。具体的には炭化水素系香料、アルコール系香料、エーテル系香料、アルデヒト系香料、ケトン系香料、エステル系香料、ラクトン系香料、環状ケトン系香料、含窒素系香料が挙げられる。 As a fragrance | flavor, a single fragrance | flavor component may be used and a some fragrance | flavor component can be used in a specific ratio. Perfume ingredients include "Perfume Chemistry" (written by Ryoichi Akahoshi, Nihon Kagaku, Industrial Chemistry Series, published on September 16, 1983) and "Synthetic Perfume Chemistry and Product Knowledge" (Gentomo Indo, Chemical Industry Daily, Issued on March 6, 1996). Specific examples include hydrocarbon-based fragrances, alcohol-based fragrances, ether-based fragrances, aldehyde-based fragrances, ketone-based fragrances, ester-based fragrances, lactone-based fragrances, cyclic ketone-based fragrances, and nitrogen-containing fragrances.
変色防止剤としては、例えば過酸化水素およびその金属塩、ペルオキソ酸およびその金属塩、金属キレート剤からなる群の少なくとも一種の化合物を含むが、複数で併用する方が変色防止の効果が期待できる場合がある。 Examples of the discoloration preventing agent include at least one compound of the group consisting of hydrogen peroxide and its metal salt, peroxo acid and its metal salt, and metal chelating agent. There is a case.
本発明の少なくとも界面活性剤、カチオン系殺菌剤を含むトイレ用除菌洗浄剤において、カチオン系殺菌剤はポリヘキサメチレングアニジン・塩酸塩であり、好ましくはその配合量は0.1重量%から10重量%である。配合量が0.1重量%以下の場合には除菌効果が得られにくいことがあり、また10重量%を越える場合は洗浄性、低コストを維持することが困難になることがある。 In the toilet sanitizing detergent containing at least a surfactant and a cationic fungicide according to the present invention, the cationic fungicide is polyhexamethylene guanidine hydrochloride, and the blending amount is preferably 0.1 to 10% by weight. % By weight. When the blending amount is 0.1% by weight or less, it may be difficult to obtain a sterilizing effect. When the blending amount exceeds 10% by weight, it may be difficult to maintain detergency and low cost.
(実施例)
ラウリルグリコシド(製品名マイドール12、花王株式会社製)60%、ヤシ油脂肪酸アミドプロピルベタイン(製品名アモーゲンCB−H、第一工業製薬株式会社製)35%、RU−2191606(UA−2000127055)に準じて作成したポリヘキサメチレングアニジン・塩酸塩20%水溶液を5%配合し、トイレ用除菌洗浄剤標準液Iを作成した。表1に示した実施例1−5で使用した試験水および除菌性試験方法を下記に記した。
(Example)
Lauryl glycoside (product name Mydol 12, Kao Corporation) 60%, palm oil fatty acid amidopropyl betaine (product name Amogen CB-H, Daiichi Kogyo Seiyaku Co., Ltd.) 35%, RU-2191606 (UA-2000127055) 5% polyhexamethylene guanidine / hydrochloride 20% aqueous solution prepared according to the above was formulated to prepare a sterilization detergent standard solution I for toilets. The test water and sterilization test method used in Example 1-5 shown in Table 1 are described below.
(試験水)
滅菌水に次亜塩素酸ナトリウムを所定量添加し、残留塩素濃度が0.5ppm、1.0ppmになるよう各試験水A(残存塩素濃度:0.5ppm)、試験水B(残存塩素濃度:1.0ppm)を調製した。残留塩素濃度はDPD法(ジエチル−p−フェニレンジアミン法)により測定した。
(Test water)
A predetermined amount of sodium hypochlorite is added to sterilized water, and each test water A (residual chlorine concentration: 0.5 ppm) and test water B (residual chlorine concentration: 0.5 ppm) so that the residual chlorine concentration becomes 0.5 ppm and 1.0 ppm. 1.0 ppm) was prepared. The residual chlorine concentration was measured by the DPD method (diethyl-p-phenylenediamine method).
(除菌性試験)
(1)菌液の調整
大腸菌(Escherichia coli NBRC 3972)、黄色ブドウ球菌(Staphylococcus aureus NBRC 12732)試験菌をSCD寒天平板培地にて温度36〜37℃、24時間培養した。培養後、試験菌を普通ブイヨン液体培地に1白金耳移植し(滅菌ポリエチレンプラスチックボトル)、菌数108CFU/mLレベルになるよう調整し、試験菌液とした。
(Sterilization test)
(1) Preparation of Bacterial Solution Test bacteria of Escherichia coli NBRC 3972 and Staphylococcus aureus NBRC 12732 were cultured on a SCD agar plate medium at a temperature of 36 to 37 ° C. for 24 hours. After culturing, the test bacteria were transplanted into a normal bouillon liquid medium by 1 platinum ear (sterilized polyethylene plastic bottle), adjusted to a bacterial count of 10 8 CFU / mL, and used as a test bacterial solution.
(試験液の調整方法)
50mL容量の滅菌ポリエチレンプラスチックボトルにトイレ用除菌洗浄剤標準液Iが14ppmになるように試験水Aまたは試験水Bで調整し、各試験試料39.6mLを正確に計量した。1.0〜5.0×108CFU/mLレベルに調整した菌液を0.4mL添加した直後にミキサーでよく攪拌した。この時点で初期菌数1.0〜5.0×106CFU/mLレベルとなる。
(Test liquid adjustment method)
A 50 mL sterilized polyethylene plastic bottle was adjusted with test water A or test water B so that the toilet sanitizing detergent standard solution I was 14 ppm, and 39.6 mL of each test sample was accurately weighed. Immediately after 0.4 mL of the bacterial solution adjusted to 1.0 to 5.0 × 10 8 CFU / mL level was added, the mixture was thoroughly stirred with a mixer. At this point, the initial bacterial count is 1.0 to 5.0 × 10 6 CFU / mL.
(除菌試験方法)
菌液接種直後の生菌数(CFU/mL)を希釈法にて測定した。尚、10倍段階希釈液列は作用ボトルより1mLを取り出し、Promedia MT−10(株式会社エルメックス製)を用いて作成した。各希釈はマイクロピペットでのピペッティングにより十分混和した後、次希釈へ1mL移行したものである。また各希釈より0.1mLをSCDLP寒天培地塗沫した。3時間接触後においても同様の操作を行い、菌数をチェックした。平板の培養は36〜37℃、24時間行った。
(Sanitization test method)
The viable cell count (CFU / mL) immediately after inoculation with the bacterial solution was measured by a dilution method. The 10-fold serial dilution row was prepared using Promedia MT-10 (manufactured by Elmex Corporation) by taking out 1 mL from the action bottle. Each dilution is obtained by thoroughly mixing by pipetting with a micropipette and then transferring 1 mL to the next dilution. Further, 0.1 mL of each dilution was smeared on the SCDLP agar medium. The same operation was performed after 3 hours of contact, and the number of bacteria was checked. Plates were cultured at 36-37 ° C. for 24 hours.
(除菌効果の判定)
接種3時間後に初発菌数より102CFU/mLレベル以上菌数が減少していた場合を除菌効果ありと判定した。
(Determination of sterilization effect)
When the number of bacteria was reduced by 10 2 CFU / mL level or more from the initial number of bacteria 3 hours after inoculation, it was determined that there was a sterilization effect.
(比較例)
ラウリルグリコシド(製品名マイドール12、花王株式会社製)60%、ヤシ油脂肪酸アミドプロピルベタイン(製品名アモーゲンCB−H、第一工業製薬株式会社製)35%、ポリヘキサメチレンビグアナイド・塩酸塩20%水溶液(製品名プロキセルIB、アーチ・ケミカルズ社製)を5%配合し、トイレ用除菌洗浄剤標準液IIを作成した以外は実施例と同様に除菌効果の判定を行った。
(Comparative example)
Lauryl glycoside (product name Mydol 12, Kao Corporation) 60%, palm oil fatty acid amidopropyl betaine (product name Amogen CB-H, Daiichi Kogyo Seiyaku Co., Ltd.) 35%, polyhexamethylene biguanide / hydrochloride 20 5% aqueous solution (product name Proxel IB, manufactured by Arch Chemicals Co., Ltd.) was blended, and the sterilization effect was determined in the same manner as in Example, except that a toilet sanitizing detergent standard solution II was prepared.
(試験結果)
試験結果を表1に示した。
(Test results)
The test results are shown in Table 1.
Claims (2)
化学式I
(式中nは1〜100の整数である。) Disinfecting and cleaning composition for toilets comprising a surfactant and a cationic disinfectant, wherein the disinfecting and cleaning composition for toilets is a polyhexamethyleneguanidine hydrochloride represented by the following chemical formula I: Agent composition.
Formula I
(In the formula, n is an integer of 1 to 100.)
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