JP2012097061A - Pest control agent and method for using the same - Google Patents
Pest control agent and method for using the same Download PDFInfo
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Abstract
Description
本発明は、有害生物防御剤に関する技術を提供する。より詳細には、サリチル酸誘導体(サリチル酸2−ヒドロキシエチル、サリチル酸メチル、サリチル酸等)からなる群から選ばれる化合物の1種又は2種以上を有効成分として含有し、その他にテルペン類またはフェニルプロパン類を含めてもよい混合物からなる有害生物防除剤とその利用方法を提供する。The present invention provides techniques relating to pest protection agents. More specifically, it contains one or more compounds selected from the group consisting of salicylic acid derivatives (2-hydroxyethyl salicylate, methyl salicylate, salicylic acid, etc.) as active ingredients, and in addition, terpenes or phenylpropanes. A pest control agent comprising a mixture that may be included and a method of using the same are provided.
ヒルを代表とした有害生物などは、里山の荒廃に取り組む森林管理者を吸血し被害をもたらす。
現在の防除方法には、市販の虫除けスプレー、N,N−ジエチル−m−トルアミド(DEET)、木酢液、塩、石けん、アニオン系環形動物忌避剤がある。Pests such as hills can cause blood damage to forest managers working on the devastation of satoyama.
Current control methods include commercially available insect repellent sprays, N, N-diethyl-m-toluamide (DEET), wood vinegar, salt, soap, anionic ring-shaped animal repellents.
しかし、木酢液や塩よりも高い忌避効果と実用性のあるDEET等は、米国小児科学会では子供用虫除け薬のDEET含有量を極端に下げるように指導している(非特許文献1)。また、手についた場合は石けんと水でよく洗うなど、使用上の注意が多く肌に触れて良いものとは言えない。However, DEET, which has higher repellent effect and practicality than wood vinegar and salt, is instructed by the American Academy of Pediatrics to extremely reduce the DEET content of insect repellents for children (Non-patent Document 1). Also, if you touch your hands, wash them with soap and water, and you may not be able to touch your skin.
そこで、前述の殺虫剤よりも安全性が高く、環境負担が低い有害生物忌避剤の有効成分として木酢液やシトロネラ油が挙げられるが、その忌避効果を確認するには大量の散布を必要とする(非特許文献2)。Therefore, wood vinegar and citronella oil are listed as active ingredients for pest repellents that are safer and less environmentally burdensome than the insecticides mentioned above, but a large amount of spraying is required to confirm their repellent effects. (Non-patent document 2).
本発明は、持続性、安定性に優れ、優れた防除効果を示し、使用形態が限定されず、天然物由来のように安全性(特に人体に対する安全性が高い)があり、且つ環境負担の軽減が期待できる有害生物を対象とした防除剤とその使用方法を提供すること。ここで述べる有害生物とはヤマビルを中心とした環形動物個体群および扁平動物個体群である。The present invention is excellent in sustainability and stability, exhibits an excellent control effect, is not limited in use form, has safety (particularly high safety to the human body) as derived from natural products, and has an environmental burden. To provide a control agent for pests that can be expected to be reduced and a method for using the same. The pest described here is an annelid population and a flat animal population centered on Yamavir.
本発明の有害生物防除剤は、サリチル酸2−ヒドロキシエチルあるいはその類似化合物からなる群から選ばれる化合物の1種又は2種以上を有効成分として含有することを特徴とする。また、L−メントールを代表とするテルペン類あるいはバニリンを代表とするフェニルプロパン類を含めることでより高い効果が得られる。有害生物防除用組成物を、防除を所望する物体(例えば、履物、衣服、住宅外壁等)に噴霧、塗布、散布あるいは有害生物に直接、接触させることにより、上記目的である有害生物防除効果を達成できる。The pest control agent of the present invention is characterized by containing one or more compounds selected from the group consisting of 2-hydroxyethyl salicylate or an analogous compound as an active ingredient. Moreover, a higher effect can be obtained by including terpenes typified by L-menthol or phenylpropanes typified by vanillin. By spraying, applying, spraying or directly contacting the pest control composition (such as footwear, clothes, housing outer walls, etc.) with the pest control composition, it is possible to achieve the above-mentioned pest control effect. Can be achieved.
少なくとも1種類以上のサリチル酸誘導体あるいはその類似化合物を有効成分とした有害生物個体群防除剤を提供する。さらに、テルペン類あるいはフェニルプロパン類からなる天然有機化合物を混合することでより高い有害生物個体群防除効果を得ることが出来る。本発明による防除剤は忌避効果のみならず駆除効果をも有する。また、本発明による防除剤は、薬剤の保持力が高いため、下草の多い山林での作業や雨中等にも効果を発揮する。また、その簡便な利用方法を提供し、小児や身体に障害のある人でも容易に使用可能とすることである。A pest population control agent comprising at least one salicylic acid derivative or a similar compound as an active ingredient is provided. Furthermore, a higher pest population control effect can be obtained by mixing natural organic compounds composed of terpenes or phenylpropanes. The control agent according to the present invention has a repellent effect as well as a repellent effect. In addition, since the control agent according to the present invention has a high drug holding power, it is effective in work in a forest with a lot of undergrowth and in the rain. In addition, it is intended to provide a simple usage method that can be easily used by children and persons with physical disabilities.
本発明における有害生物防除剤は、サリチル酸誘導体(サリチル酸2−ヒドロキシエチル、サリチル酸メチル、サリチル酸等)からなる群から選ばれる化合物の1種又は2種以上を有効成分として含有し、その他にテルペン類またはフェニルプロパン類を含めてもよい混合物からなる液体状または固体状の物質である。The pest control agent in the present invention contains, as an active ingredient, one or more compounds selected from the group consisting of salicylic acid derivatives (2-hydroxyethyl salicylate, methyl salicylate, salicylic acid, etc.), and other terpenes or It is a liquid or solid substance composed of a mixture that may contain phenylpropanes.
本発明において効果が認められたサリチル酸誘導体は、サリチル酸、サリチル酸メチル、サリチル酸エチル、およびサリチル酸2−ヒドロキシエチルである。中でもサリチル酸2−ヒドロキシエチルが最も高い効果が得られた。しかし、上記化合物に限定するものではない。Salicylic acid derivatives that have been found to be effective in the present invention are salicylic acid, methyl salicylate, ethyl salicylate, and 2-hydroxyethyl salicylate. Of these, 2-hydroxyethyl salicylate was most effective. However, it is not limited to the above compounds.
本発明におけるテルペン類の利用例としては、メントール、メンタンが挙げられるが、これらの化合物に限定するものではない。Examples of the use of terpenes in the present invention include menthol and menthane, but are not limited to these compounds.
本発明におけるフェニルプロパン類の利用例としては、バニリンが挙げられるが、これらの化合物に限定するものではない。Examples of the use of phenylpropanes in the present invention include vanillin, but are not limited to these compounds.
テルペン類の由来としては特にハッカ油が有効であったが、これに限定するものではない。Although mint oil was particularly effective as the origin of terpenes, it is not limited to this.
フェニルプロパン類の由来としてはバニラ抽出物が有効であったが、これに限定するものではない。Vanilla extract was effective as a source of phenylpropanes, but is not limited thereto.
本発明における有害生物防除剤は特に加工することなく防除効果を示すが、溶液状にすることでより高い利便性を示すことができる。Although the pest control agent in the present invention exhibits a control effect without any particular processing, it can exhibit higher convenience by being in the form of a solution.
溶液状にするための方法として、有機溶媒への溶解や、界面活性剤による乳化、またはマイクロカプセルへの包埋による水への溶解が有効である。有機溶媒としてはエタノールなど身体に有害でないものが好ましい。As a method for forming a solution, dissolution in an organic solvent, emulsification with a surfactant, or dissolution in water by embedding in a microcapsule is effective. As the organic solvent, ethanol and the like which are not harmful to the body are preferable.
本発明における溶液状の有害生物防除剤は、噴射用圧縮ガスと共に噴射ノズル及びバルブ付きのスプレー用容器に封入することで、簡便に噴霧することが可能である。この有害生物防除剤は防除効果を噴霧によって失うことはない。The solution-like pest control agent in the present invention can be easily sprayed by enclosing it in a spray container with a spray nozzle and a valve together with a compressed gas for spraying. This pest control agent does not lose its control effect by spraying.
本発明における有害生物防除剤は紙、布、不織布、合成樹脂シートなど吸収性物体あるいは、ゼラチンや寒天などゲル状物質への塗布、吹き付け、注入、浸漬、練り込み、添加および石鹸や蝋など固形油脂への混合、練り込みなどにより、その防除成分を徐放することが可能である。
この方法により防除効果を簡便に長期間にわたり持続させることが可能である。The pest control agent in the present invention is applied to absorptive objects such as paper, cloth, non-woven fabric and synthetic resin sheet, or gelled substances such as gelatin and agar, sprayed, poured, dipped, kneaded, added and solids such as soap and wax It is possible to release the control component gradually by mixing with oil or fat, kneading and the like.
By this method, the control effect can be easily maintained for a long time.
本発明における有害生物防除剤は、ヒトをはじめとする動物や植物に対して有害でなく、天然由来成分を主とするため環境負荷も少ない。これらのことから、人体あるいは動物表面または履物、衣服、機械、網戸、ガラス、床、壁など、あらゆる生活区域への適用が可能である。また成分が比較的長期間にわたり安定であり、かつ薬剤の保持力が高いため、下草の多い山林での作業や雨中等にも効果を発揮する。The pest control agent in the present invention is not harmful to animals and plants including human beings, and has a low environmental load because it mainly contains naturally derived components. Therefore, it can be applied to all living areas such as human or animal surfaces or footwear, clothes, machines, screen doors, glass, floors and walls. In addition, since the ingredients are stable for a relatively long period of time and have high drug retention, they are also effective in working in forests with a lot of undergrowth and in the rain.
本発明における有害生物防除剤は、直接有害生物に接触させることでも防除効果を発揮する。
例えばスプレータイプの有害生物防除剤を直接吹きかけ防除効果が得られる。The pest control agent in the present invention exerts a control effect even when it is brought into direct contact with a pest.
For example, a spray type pest control agent can be sprayed directly to obtain a control effect.
実験方法はA6サイズのコピー用紙の中心に直径8.6センチメートルの円を鉛筆で書き、その円の外に試薬を塗る。円の中にヤマビルを置き、その円の中からヤマビルが出られるかどうか忌避率を調べた。試薬を溶解するものは100%エタノールとする。In the experiment method, a circle of 8.6 cm in diameter is written with a pencil in the center of A6 size copy paper, and a reagent is applied outside the circle. I placed a Yamabiru in the circle, and examined the repellent rate to see if it could come out of the circle. The reagent is dissolved in 100% ethanol.
サリチル酸2−ヒドロキシエチルを3、5、10、15、30、40、50、100mg/1mlの濃度で円の外に塗り実験を行った。その結果、忌避率は0、30、80、100、100、100、100および100%であった。An experiment was conducted in which 2-hydroxyethyl salicylate was applied outside the circle at concentrations of 3, 5, 10, 15, 30, 40, 50, and 100 mg / 1 ml. As a result, the repelling rate was 0, 30, 80, 100, 100, 100, 100 and 100%.
テルペン類(L−メントール)を3、5、10、15、30、40、50、100mg/1mlの濃度で円の外に塗り実験を行った。その結果、忌避率は0、0、0、10、20、50、100および100%であった。Terpenes (L-menthol) were applied to the outside of the circle at concentrations of 3, 5, 10, 15, 30, 40, 50, and 100 mg / 1 ml, and experiments were conducted. As a result, the repelling rate was 0, 0, 0, 10, 20, 50, 100 and 100%.
フェニルプロパン類(バニリン)を3、5、7.5、10、15、30、40mg/1mlの濃度で円の外に塗り実験を行った。その結果、ヤマビルの忌避率は0、10、50、80、80、80および100%であった。Phenylpropanes (vanillin) were applied to the outside of the circle at concentrations of 3, 5, 7.5, 10, 15, 30, and 40 mg / 1 ml. As a result, the repellent rate of Yamavir was 0, 10, 50, 80, 80, 80 and 100%.
表1は、サリチル酸2−ヒドロキシエチル、サリチル酸メチル、サリチル酸、アセチルサリチル酸、L−メントール、バニリンおよびカプサイシンの濃度と忌避率の関係を示す表である。Table 1 is a table showing the relationship between the concentration of 2-hydroxyethyl salicylate, methyl salicylate, salicylic acid, acetylsalicylic acid, L-menthol, vanillin and capsaicin and the repellent rate.
サリチル酸2−ヒドロキシエチルを5mg/1mlとバニリンを7.5mg/1mlの濃度で円の外に塗り実験を行った。忌避率は100%であった。また、成分量を増加した場合も100%であった。Experiments were conducted by applying 2-hydroxyethyl salicylate outside the circle at a concentration of 5 mg / 1 ml and vanillin 7.5 mg / 1 ml. The repellent rate was 100%. Moreover, it was 100% when the amount of components was increased.
サリチル酸2−ヒドロキシエチルを5mg/1mlとL−メントール40mg/1mlの濃度で円の外に塗り実験を行った。忌避率は100%であった。また成分量を増加した場合も100%であった。The experiment was carried out by applying 2-hydroxyethyl salicylate outside the circle at a concentration of 5 mg / 1 ml and L-menthol 40 mg / 1 ml. The repellent rate was 100%. Moreover, it was 100% when the amount of ingredients was increased.
表2は、サリチル酸2−ヒドロキシエチル、L−メントール、バニリンおよびカプサイシンの濃度と忌避率の関係を示す表である。Table 2 is a table showing the relationship between the concentration of 2-hydroxyethyl salicylate, L-menthol, vanillin and capsaicin and the repellent rate.
(比較例1)
エタノール100%を円の外に塗り実験を行った。忌避率は0%であった。よってエタノールを試薬の溶解する有機溶媒として使用する。(Comparative Example 1)
An experiment was performed in which 100% ethanol was applied outside the circle. The repellent rate was 0%. Therefore, ethanol is used as the organic solvent in which the reagent is dissolved.
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JPH10259103A (en) * | 1997-03-18 | 1998-09-29 | Dainippon Jochugiku Co Ltd | Gastropod expellent |
JP2006509029A (en) * | 2002-12-06 | 2006-03-16 | オルガノックス エイビー | Pest population control composition and use thereof |
JP2009543870A (en) * | 2006-07-17 | 2009-12-10 | タイラテック, インク. | Compositions and methods for insect control |
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JPH10259103A (en) * | 1997-03-18 | 1998-09-29 | Dainippon Jochugiku Co Ltd | Gastropod expellent |
JP2006509029A (en) * | 2002-12-06 | 2006-03-16 | オルガノックス エイビー | Pest population control composition and use thereof |
JP2009543870A (en) * | 2006-07-17 | 2009-12-10 | タイラテック, インク. | Compositions and methods for insect control |
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