JP2012061616A - Single-sided metal-clad laminated sheet, and method of manufacturing the same - Google Patents

Single-sided metal-clad laminated sheet, and method of manufacturing the same Download PDF

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JP2012061616A
JP2012061616A JP2010205233A JP2010205233A JP2012061616A JP 2012061616 A JP2012061616 A JP 2012061616A JP 2010205233 A JP2010205233 A JP 2010205233A JP 2010205233 A JP2010205233 A JP 2010205233A JP 2012061616 A JP2012061616 A JP 2012061616A
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roller
sided metal
insulating film
conductive film
clad laminate
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Tomoyoshi Saito
朋善 齋藤
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Seiko Epson Corp
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Abstract

PROBLEM TO BE SOLVED: To solve the problem with a conventional method of manufacturing a single-sided metal-clad laminated sheet, wherein a striped strain is generated and thereby a bonding quality is degraded.SOLUTION: The method is provided for manufacturing the single-sided metal-clad laminated sheet formed by bonding an insulating film with a conductive film through a thermoplastic adhesive. In the method, the insulating film with the thermoplastic adhesive is adhered along a heated metallic roller, and also the insulating film and the conductive film are introduced between the metallic roller and an elastic roller, while the conductive film is adhered along the heated elastic roller.

Description

本発明は、片面金属張積層板、片面金属張積層板の製造方法に関する。   The present invention relates to a single-sided metal-clad laminate and a method for producing a single-sided metal-clad laminate.

従来から、1対以上のローラーで、絶縁性フィルムをゴムローラーに沿わせ、次いで導電性フィルムを前記絶縁性フィルムに合わせて熱圧着する片面金属張積層板の製造方法が知られている(例えば、特許文献1参照)。   Conventionally, a manufacturing method of a single-sided metal-clad laminate in which an insulating film is placed along a rubber roller with a pair of rollers and then a conductive film is thermocompression bonded to the insulating film is known (for example, , See Patent Document 1).

特開2001−79946号公報JP 2001-79946 A

しかしながら、上記特許文献1の製造方法では、導電性フィルムの厚みが薄い場合には、加熱された金属性ローラーに接触した時の熱膨張を解放できないことがある。また、表面が平滑な導電性フィルムの場合には、加熱された金属性ローラーの表面に貼り付いてしまい、熱膨張を解放できなくなる。これにより、絶縁性フィルムおよび導電性フィルムにスジ状の歪みが発生し、絶縁性フィルムと導電性フィルムとの接合品質が低下してしまう、という課題があった。   However, in the manufacturing method of Patent Document 1, when the conductive film is thin, thermal expansion may not be released when it comes into contact with the heated metallic roller. Further, in the case of a conductive film having a smooth surface, it sticks to the surface of the heated metallic roller, and thermal expansion cannot be released. As a result, there is a problem that streak-like distortion occurs in the insulating film and the conductive film, and the bonding quality between the insulating film and the conductive film is deteriorated.

本発明は、上述の課題の少なくとも一部を解決するためになされたものであり、以下の形態又は適用例として実現することが可能である。   SUMMARY An advantage of some aspects of the invention is to solve at least a part of the problems described above, and the invention can be implemented as the following forms or application examples.

[適用例1]本適用例にかかる片面金属張積層板の製造方法は、熱可塑性接着剤を介して、絶縁性フィルムと、導電性フィルムとが接着形成された片面金属張積層板の製造方法であって、前記熱可塑性接着剤付きの絶縁性フィルムを加熱された金属性ローラーに沿わせるとともに、前記導電性フィルムを加熱された弾性ローラーに沿わせた状態で、前記絶縁性フィルムと前記導電性フィルムとを前記金属性ローラーと前記弾性ローラーとの間に導入することを特徴とする。   Application Example 1 A method for producing a single-sided metal-clad laminate according to this application example is a method for producing a single-sided metal-clad laminate in which an insulating film and a conductive film are bonded and formed via a thermoplastic adhesive. The insulating film with thermoplastic adhesive is placed along a heated metallic roller, and the conductive film is placed along a heated elastic roller, and the insulating film and the conductive film are placed along the heated elastic roller. A conductive film is introduced between the metallic roller and the elastic roller.

この適用例の製造方法では、熱可塑性接着剤付きの絶縁性フィルムを加熱された金属性ローラーに沿わせ、導電性フィルムを加熱された弾性ローラーに沿わせた状態で、金属性ローラーと弾性ローラー間に導入することで、ローラーに接触したときの絶縁性フィルム及び、導電性フィルムの熱膨張を解放することができ、スジ状の歪みの発生を防止し、接合品質を向上させることができる。特に、導電性フィルムは、応力が緩和されながら弾性ローラーに倣って搬送されるため、金属性ローラーと弾性ローラーとの間に導入されるまでに皺等の発生を解消させることができる。   In the manufacturing method of this application example, the metallic roller and the elastic roller are arranged with the insulating film with the thermoplastic adhesive along the heated metallic roller and the conductive film along the heated elastic roller. By introducing in between, the thermal expansion of the insulating film and the conductive film when contacting the roller can be released, the generation of streak-like distortion can be prevented, and the bonding quality can be improved. In particular, since the conductive film is conveyed following the elastic roller while the stress is relaxed, generation of wrinkles and the like can be eliminated before being introduced between the metallic roller and the elastic roller.

[適用例2]本適用例にかかる片面金属張積層板は、上記の片面金属張積層板の製造方法により製造されたことを特徴とする。   Application Example 2 A single-sided metal-clad laminate according to this application example is manufactured by the above-described method for manufacturing a single-sided metal-clad laminate.

この構成によれば、絶縁性フィルムと導電性フィルムとの接合品質が高い片面金属張積層板を提供することができる。   According to this configuration, a single-sided metal-clad laminate with high bonding quality between the insulating film and the conductive film can be provided.

片面金属張積層板の構成を示す断面図。Sectional drawing which shows the structure of a single-sided metal-clad laminated board. 片面金属張積層板の製造方法を示す模式図。The schematic diagram which shows the manufacturing method of a single-sided metal clad laminated board.

まず、片面金属張積層板の構成について説明する。図1は、片面金属張積層板の構成を示す断面図である。図1に示すように、片面金属張積層板6は、導電性フィルム2と、絶縁性フィルム8とが、熱可塑性接着剤7を介して、互いに接着されたものである。   First, the structure of a single-sided metal-clad laminate will be described. FIG. 1 is a cross-sectional view showing a configuration of a single-sided metal-clad laminate. As shown in FIG. 1, the single-sided metal-clad laminate 6 is obtained by bonding a conductive film 2 and an insulating film 8 to each other via a thermoplastic adhesive 7.

次に、片面金属張積層板の製造方法について説明する。図2は、片面金属張積層板の製造方法を示す模式図である。本実施形態における片面金属張積層板の製造方法は、熱可塑性接着剤を介して、絶縁性フィルムと、導電性フィルムとが接着形成された片面金属張積層板の製造方法であって、熱可塑性接着剤付きの絶縁性フィルムを加熱された金属性ローラーに沿わせるとともに、導電性フィルムを加熱された弾性ローラーに沿わせた状態で、絶縁性フィルムと導電性フィルムとを金属性ローラーと弾性ローラー間に導入するものである。以下、具体的に説明する。   Next, a method for manufacturing a single-sided metal-clad laminate will be described. FIG. 2 is a schematic view showing a method for producing a single-sided metal-clad laminate. The method for producing a single-sided metal-clad laminate in this embodiment is a method for producing a single-sided metal-clad laminate in which an insulating film and a conductive film are bonded and formed via a thermoplastic adhesive, and is thermoplastic. With the insulating film with adhesive along the heated metal roller and the conductive film along the heated elastic roller, the insulating film and the conductive film are connected to the metallic roller and the elastic roller. Introduced in between. This will be specifically described below.

図2に示すように、熱可塑性接着剤付きの絶縁性フィルム1(7,8)を加熱された金属性ローラー3に沿わせ、また、導電性フィルム2を加熱された弾性ローラー4に沿わせて、金属性ローラー3と弾性ローラー4との間に導入して熱圧着し、片面金属張積層板6を製造する。熱可塑性接着剤付きの絶縁性フィルム1は、例えば、ポリイミドフィルムであり、その厚みは、20〜60μmの範囲が好ましく、30〜50μmの範囲がより好ましい。導電性フィルム2は、例えば、銅箔であり、その厚みは、5〜18μmの範囲が好ましく、8〜10μmがより好ましい。   As shown in FIG. 2, the insulating film 1 (7, 8) with the thermoplastic adhesive is placed along the heated metallic roller 3, and the conductive film 2 is placed along the heated elastic roller 4. Then, it is introduced between the metallic roller 3 and the elastic roller 4 and thermocompression bonded to produce a single-sided metal-clad laminate 6. The insulating film 1 with a thermoplastic adhesive is a polyimide film, for example, and the thickness thereof is preferably in the range of 20 to 60 μm, and more preferably in the range of 30 to 50 μm. The conductive film 2 is, for example, a copper foil, and the thickness is preferably in the range of 5 to 18 μm, and more preferably 8 to 10 μm.

金属性ローラー3の表面温度は、250〜400℃の範囲であるのが好ましく、弾性ローラー4の表面温度は、100〜300℃の範囲が好ましい。本実施形態では、熱可塑性接着剤付きの絶縁性フィルム1及び導電性フィルム2は、金属性ローラー3と弾性ローラー4間での熱圧着前に、金属性ローラー3および弾性ローラー4に沿って搬送されることにより、両ローラーに接触したときに生じる熱膨張による寸法変化が解放されている必要がある。以下、かかる工程を熱膨張解放工程と言う。   The surface temperature of the metallic roller 3 is preferably in the range of 250 to 400 ° C, and the surface temperature of the elastic roller 4 is preferably in the range of 100 to 300 ° C. In this embodiment, the insulating film 1 and the conductive film 2 with a thermoplastic adhesive are conveyed along the metallic roller 3 and the elastic roller 4 before thermocompression bonding between the metallic roller 3 and the elastic roller 4. Therefore, it is necessary to release the dimensional change caused by thermal expansion that occurs when both rollers are brought into contact with each other. Hereinafter, this process is referred to as a thermal expansion release process.

熱圧着温度が、250℃よりも低い場合には、熱可塑性接着剤付きの絶縁性フィルム1と導電性フィルム2とが全く接着しないか、または接着したとしても、両者の積層体は剥離しやすいものとなり実用に耐えない。また、熱膨張解放工程が無い場合には、加熱された両ローラーに接触した瞬間に、熱可塑性接着剤付きの絶縁性フィルム1および導電性フィルム2に急激な熱膨張による歪みが生じ、片面金属張積層板6の外観が悪化するとともに、回路を形成した時にショートや断線の原因となり、実用に耐えない。急激な熱膨張による歪みを防ぐために、巻き出し部の張力を増加させる場合には、片面金属張積層板6の長手方向に平行にスジ状の歪みが生じ、張力を減少させる場合には、片面金属張積層板6の幅方向に平行にスジ状の歪みが発生し、接合品質が良好な片面金属張積層板6を製造することができなくなる。   When the thermocompression bonding temperature is lower than 250 ° C., even if the insulating film 1 with the thermoplastic adhesive and the conductive film 2 are not bonded at all or are bonded, the laminate of both is easily peeled off. It becomes a thing and cannot withstand practical use. Further, when there is no thermal expansion releasing step, the insulating film 1 with the thermoplastic adhesive and the conductive film 2 are distorted due to rapid thermal expansion at the moment when they are in contact with both heated rollers. The appearance of the tension laminate 6 deteriorates, and when a circuit is formed, it causes a short circuit or disconnection and cannot be put into practical use. In order to prevent distortion due to rapid thermal expansion, when increasing the tension of the unwinding portion, streak-like distortion occurs parallel to the longitudinal direction of the single-sided metal-clad laminate 6, and when reducing the tension, single-sided A streak-like distortion is generated parallel to the width direction of the metal-clad laminate 6, making it impossible to manufacture the single-sided metal-clad laminate 6 with good bonding quality.

そこで、熱膨張解放工程により、熱膨張による寸法変化が解放された熱可塑性接着剤付きの絶縁性フィルム1および導電性フィルム2は、加熱された金属性ローラー3と加熱された弾性ローラー4間での熱圧着時に歪みが生じることはない。金属性ローラー3および弾性ローラー4の加熱温度は、熱可塑性接着剤付きの絶縁性フィルム1および導電性フィルム2の材質、熱膨張係数、厚みを考慮して設定する必要がある。例えば、ポリイミド系の熱可塑性接着剤付きのポリイミドフィルムを使用する場合は、金属性ローラー3の加熱温度は、250〜350℃程度の温度が好ましい。また、電気分解法により製造された厚さ8〜10μmの銅箔を使用する場合には、弾性ローラー4の加熱温度は、150〜250℃程度の温度が好ましい。   Therefore, the insulating film 1 and the conductive film 2 with the thermoplastic adhesive, in which the dimensional change due to the thermal expansion is released by the thermal expansion releasing process, is performed between the heated metallic roller 3 and the heated elastic roller 4. There is no distortion during thermocompression bonding. The heating temperature of the metallic roller 3 and the elastic roller 4 needs to be set in consideration of the material, thermal expansion coefficient, and thickness of the insulating film 1 and the conductive film 2 with a thermoplastic adhesive. For example, when using a polyimide film with a polyimide-based thermoplastic adhesive, the heating temperature of the metallic roller 3 is preferably about 250 to 350 ° C. Moreover, when using the copper foil of thickness 8-10 micrometers manufactured by the electrolysis method, the heating temperature of the elastic roller 4 has a preferable temperature of about 150-250 degreeC.

本実施形態において使用する金属性ローラー3および弾性ローラー4の直径は、それぞれ15〜45cmの範囲が好ましく、両者の直径は、ほぼ同じであるのが好ましい。熱膨張解放工程において、熱可塑性接着剤層付き絶縁性フィルム1と金属性ローラー3と接触角度θ1および導電性フィルム2と弾性ローラー4との接触角度θ2は、金属性ローラー3と弾性ローラー4との接点を基準にして30〜350°の範囲が好ましく、180〜270°の範囲がより好ましい。また、接触角度θ1とθ2が同じであってもよい。この接触角度θ1およびθ2は、ガイドローラー5の位置で調整することができる。   The diameters of the metallic roller 3 and the elastic roller 4 used in this embodiment are preferably in the range of 15 to 45 cm, and the diameters of both are preferably substantially the same. In the thermal expansion release process, the insulating film 1 with the thermoplastic adhesive layer, the metallic roller 3, the contact angle θ 1, and the contact angle θ 2 between the conductive film 2 and the elastic roller 4 are: Is preferably in the range of 30 to 350 °, more preferably in the range of 180 to 270 °. Further, the contact angles θ1 and θ2 may be the same. The contact angles θ1 and θ2 can be adjusted at the position of the guide roller 5.

熱可塑性接着剤付きの絶縁性フィルム1は、金属性ローラー3に接した時に発生する熱膨張が、金属性ローラー3上を滑り寸法が増大することで熱膨張を開放し、無緊張状態となる。本実施形態においては、金属性ローラー3の直径とその回転速度、熱可塑性接着剤付きの絶縁性フィルム1と金属性ローラー3との接触角度θ1などを調整することにより、金属性ローラー3と弾性ローラー4間での加熱圧着に至るまでに、熱可塑性接着剤付きの絶縁性フィルム1を、無緊張状態にする。同様に導電性フィルム2も金属性ローラー3と弾性ローラー4間での加熱圧着に至るまでに、無緊張状態にする。   The insulating film 1 with a thermoplastic adhesive releases thermal expansion when the thermal expansion that occurs when contacting the metallic roller 3 increases the sliding dimension on the metallic roller 3, and is in a no-tension state. . In the present embodiment, by adjusting the diameter of the metallic roller 3 and its rotational speed, the contact angle θ1 between the insulating film 1 with the thermoplastic adhesive and the metallic roller 3, etc., the metallic roller 3 and the elastic roller 3 are elastic. Before reaching the thermocompression bonding between the rollers 4, the insulating film 1 with the thermoplastic adhesive is brought into a no-tension state. Similarly, the conductive film 2 is brought into a non-tensioned state before the thermocompression bonding between the metallic roller 3 and the elastic roller 4.

金属性ローラー3と弾性ローラー4間で熱可塑性接着剤付きの絶縁性フィルム1および導電性フィルム2に加えられる圧力は、加圧部位で実質的に変形が生じないローラー同士の組み合わせである場合には、線圧換算で5kg/cm以上であることが十分な接着力を発現させる上で好ましい。圧力の上限は特に限定されるものではないが、線圧換算で200kg/cmを超えないことが望ましい。なお、ここでの線圧とは、各ローラーに付与した力(圧着加重)をローラーの有効幅で除した値である。   When the pressure applied to the insulating film 1 and the conductive film 2 with the thermoplastic adhesive between the metallic roller 3 and the elastic roller 4 is a combination of rollers that do not substantially deform at the pressurizing site. Is preferably 5 kg / cm or more in terms of linear pressure in order to develop sufficient adhesive force. The upper limit of the pressure is not particularly limited, but it is desirable not to exceed 200 kg / cm in terms of linear pressure. In addition, the linear pressure here is the value which remove | divided the force (crimping load) provided to each roller by the effective width | variety of a roller.

本実施形態により、外観が良好で接着力および寸法安定性に優れる片面金属張積層板6を得るためには、両ローラー間を通過させて熱圧着するときに、ローラーの回転速度を、その外周の線速度に換算して30m/分以下とすることが好ましい。下限は特に限定されるものではないが、回転速度が低すぎると生産効率の低下を招くため、0.1m/分より低くしないことが望ましい。以上の工程を経ることにより、片面金属張積層板6が形成される。   According to this embodiment, in order to obtain a single-sided metal-clad laminate 6 having a good appearance and excellent adhesion and dimensional stability, the rotation speed of the roller is changed to the outer circumference when thermocompression bonding is performed between both rollers. The linear velocity is preferably 30 m / min or less. The lower limit is not particularly limited. However, if the rotational speed is too low, the production efficiency is lowered. Therefore, it is desirable that the lower limit is not lower than 0.1 m / min. The single-sided metal-clad laminate 6 is formed through the above steps.

従って、上記実施形態によれば以下に示す効果が得られる。   Therefore, according to the above embodiment, the following effects can be obtained.

加熱された弾性ローラーに導電性フィルムを沿わせながら搬送させるので、熱膨張によるスジ状の歪みの発生がなく、外観が良好で、十分な接着強度を有した片面金属張積層板6が提供される。   Since the conductive film is conveyed along the heated elastic roller, the single-sided metal-clad laminate 6 is provided which has no appearance of streak-like distortion due to thermal expansion, good appearance, and sufficient adhesive strength. The

1…熱可塑性接着剤付きの絶縁性フィルム、2…導電性フィルム、3…金属性ローラー、4…弾性ローラー、5…ガイドローラー、6…片面金属張積層板、7…熱可塑性接着剤、8…絶縁性フィルム。   DESCRIPTION OF SYMBOLS 1 ... Insulating film with a thermoplastic adhesive, 2 ... Conductive film, 3 ... Metallic roller, 4 ... Elastic roller, 5 ... Guide roller, 6 ... Single-sided metal-clad laminate, 7 ... Thermoplastic adhesive, 8 ... insulating film.

Claims (2)

熱可塑性接着剤を介して、絶縁性フィルムと、導電性フィルムとが接着形成された片面金属張積層板の製造方法であって、
前記熱可塑性接着剤付きの絶縁性フィルムを加熱された金属性ローラーに沿わせるとともに、前記導電性フィルムを加熱された弾性ローラーに沿わせた状態で、
前記絶縁性フィルムと前記導電性フィルムとを前記金属性ローラーと前記弾性ローラーとの間に導入することを特徴とする片面金属張積層板の製造方法。
A method for producing a single-sided metal-clad laminate in which an insulating film and a conductive film are bonded and formed via a thermoplastic adhesive,
While keeping the insulating film with the thermoplastic adhesive along a heated metal roller, the conductive film along the heated elastic roller,
The method for producing a single-sided metal-clad laminate, wherein the insulating film and the conductive film are introduced between the metallic roller and the elastic roller.
請求項1に記載の片面金属張積層板の製造方法により製造されたことを特徴とする片面金属張積層板。   A single-sided metal-clad laminate produced by the method for producing a single-sided metal-clad laminate according to claim 1.
JP2010205233A 2010-09-14 2010-09-14 Single-sided metal-clad laminated sheet, and method of manufacturing the same Withdrawn JP2012061616A (en)

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JP2014166742A (en) * 2013-02-28 2014-09-11 Iwai Giken Co Ltd Thermal adhesive film sticking method and device
CN114630746A (en) * 2019-11-04 2022-06-14 海拉有限双合股份公司 Method for joining thermoplastic film to metal member

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014166742A (en) * 2013-02-28 2014-09-11 Iwai Giken Co Ltd Thermal adhesive film sticking method and device
CN114630746A (en) * 2019-11-04 2022-06-14 海拉有限双合股份公司 Method for joining thermoplastic film to metal member

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