JP2012035200A - Hollow fiber module - Google Patents

Hollow fiber module Download PDF

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JP2012035200A
JP2012035200A JP2010177847A JP2010177847A JP2012035200A JP 2012035200 A JP2012035200 A JP 2012035200A JP 2010177847 A JP2010177847 A JP 2010177847A JP 2010177847 A JP2010177847 A JP 2010177847A JP 2012035200 A JP2012035200 A JP 2012035200A
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hollow fiber
cylindrical portion
nozzle
inner diameter
nozzle opening
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JP5543875B2 (en
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Shosaku Aramaki
昌作 荒牧
Yayoi Ideta
弥生 出田
Noriko Yanagida
範子 柳田
Keiko Yamamoto
恵子 山本
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Asahi Kasei Medical Co Ltd
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Asahi Kasei Medical Co Ltd
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Priority to CN2011102251956A priority patent/CN102371122A/en
Priority to CN2011202846153U priority patent/CN202224069U/en
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Abstract

PROBLEM TO BE SOLVED: To provide a hollow fiber module capable of stabilizing the supply position of a potting agent at both end parts of a cylindrical part.SOLUTION: A hollow fiber module 1 includes a cylindrical part 10 in which a hollow fiber membrane A is accommodated and a lid part 11 which closes each opening end of both sides of the cylindrical part 10, and both end parts of the hollow fiber membrane A is sealed by a potting agent B at both end parts of the cylindrical part 10. At each lid part 11, the first nozzle 20 is formed, and the second nozzle 21 is formed at an inner side of the potting agent B of both end parts of the cylindrical part 10, and a nozzle opening part 21a of the second nozzle 21 is formed. The inside diameter at an end 10a of the cylindrical part 10 is larger than the inside diameter at an outside end E of the nozzle opening part 21a of the cylindrical part 10. At the endmost part including the end 10a of the cylindrical part 10, a constant large same diameter part 44, whose inside diameter is the same as the end 10a of the cylindrical part 10, is formed.

Description

本発明は、中空糸モジュールに関する。   The present invention relates to a hollow fiber module.

中空糸モジュールは、中空糸膜を用いて液体から所定成分を分離するものであり、血液処理、水処理、ガス分離処理などに多く用いられている。   A hollow fiber module separates a predetermined component from a liquid using a hollow fiber membrane, and is often used for blood treatment, water treatment, gas separation treatment, and the like.

中空糸モジュールは、束状の中空糸膜が収容される筒状部と、筒状部の両側の各開口端を閉鎖する蓋部を有しており、筒状部の両端部において中空糸膜の両端部がポッティング剤により封止されている。両側の各蓋部には、一次側のノズルが形成されており、筒状部の両端部付近には、二次側のノズルが形成されている。   The hollow fiber module has a cylindrical portion in which a bundle of hollow fiber membranes is accommodated, and lid portions that close open ends on both sides of the cylindrical portion, and hollow fiber membranes are formed at both ends of the cylindrical portion. Both ends of the are sealed with a potting agent. A primary-side nozzle is formed on each of the lid portions, and a secondary-side nozzle is formed near both ends of the cylindrical portion.

上記中空糸モジュールの製造プロセスでは、例えば先ず筒状部の内部に多数本の束状の中空糸膜が挿入され、筒状部の各開口端に一旦キャップが嵌め込まれる。次に例えば筒状部が回転され、その状態で、キャップの流入口から筒状部内にポッティング剤が注入される(特許文献1参照。)。これにより、筒状部の端部において中空糸膜の端部同士の間と、中空糸膜の端部と筒状部の内周面との間でポッティング剤が硬化して、中空糸膜の両端部が封止される。その後、中空糸膜の両端部の余分な部分がポッティング剤のある位置で切断され、中空糸膜の両側に開口端が形成される。その後、筒状部の各開口端に一次側のノズル付きの蓋部が取り付けられる。   In the manufacturing process of the hollow fiber module, for example, a large number of bundled hollow fiber membranes are first inserted into the cylindrical portion, and a cap is once fitted into each open end of the cylindrical portion. Next, for example, the cylindrical portion is rotated, and in this state, a potting agent is injected into the cylindrical portion from the inlet of the cap (see Patent Document 1). As a result, the potting agent is cured between the ends of the hollow fiber membranes at the ends of the cylindrical portion and between the ends of the hollow fiber membrane and the inner peripheral surface of the cylindrical portion, Both ends are sealed. Then, the excess part of the both ends of a hollow fiber membrane is cut | disconnected in a position with a potting agent, and an open end is formed in the both sides of a hollow fiber membrane. Thereafter, a lid portion with a primary nozzle is attached to each opening end of the cylindrical portion.

特開2008-279374号公報JP 2008-279374 A

しかしながら、上記中空糸モジュールの製造プロセスのポッティング剤供給工程においては、例えばキャップに管路を通じて接続されたポッティング剤供給装置から、筒状部の両端部内の狭小な領域にポッティング剤を供給する必要がある。このため、ポッティング剤の供給量は少なく、ポッティング剤供給装置によりポッティング剤の供給量を厳密に安定して制御するのが難しい。また、ポッティング剤は粘性流体であり、供給開始時に、その供給スピードにバラツキが生じるため、少量の供給量では、そのバラツキが大きくなり、ポッティング剤の供給量を制御するのが難しくなる。特に、中空糸モジュールの性能を確認するための試用品は、性能試験時に用いられる高価な試験液の使用量を減らすため、通常使用される市販の中空糸モジュール(通常品)よりもサイズが小さいものが用いられるが、その試用品の中空糸モジュールの製造時には、ポッティング剤の供給量が極めて少量になるため、その供給量を厳密に制御することは非常に難しくなる。   However, in the potting agent supply step of the hollow fiber module manufacturing process, for example, it is necessary to supply the potting agent from a potting agent supply device connected to the cap through a conduit to a narrow region in both ends of the cylindrical portion. is there. For this reason, the amount of potting agent supplied is small, and it is difficult to strictly and stably control the amount of potting agent supplied by the potting agent supply device. In addition, since the potting agent is a viscous fluid and the supply speed varies at the start of supply, the variation increases with a small supply amount, and it becomes difficult to control the supply amount of the potting agent. In particular, the sample for confirming the performance of the hollow fiber module is smaller in size than the commercially available hollow fiber module (ordinary product) that is normally used in order to reduce the amount of expensive test solution used during the performance test. However, when the hollow fiber module of the trial product is manufactured, the supply amount of the potting agent is extremely small, and it is very difficult to strictly control the supply amount.

そして、ポッティング剤の供給量が設定よりも多すぎると、ポッティング剤が二次側のノズルのノズル開口部まで達し、二次側のノズルを塞いで、二次側のノズルの通液性が低下する恐れがある。また、ポッティング剤の供給量が設定により少なすぎると、中空糸膜の十分な封止が行われず、例えば中空糸膜の一次側と二次側との間に液体の漏れが生じる恐れがある。さらに、ポッティング剤の供給量がばらついてポッティング剤の内側端の位置が不安定になると、ポッティング剤の内側の中空糸膜の有効長(ポッティング剤のない部分の長さ)がばらつき、中空糸膜の膜面積がばらつくため、中空糸モジュールの性能に大きな影響を与えることになる。   And if the amount of potting agent supplied is too much than the setting, the potting agent reaches the nozzle opening of the secondary nozzle, plugs the secondary nozzle, and the liquid permeability of the secondary nozzle decreases. There is a fear. Further, if the supply amount of the potting agent is too small due to the setting, the hollow fiber membrane is not sufficiently sealed, and for example, there is a possibility that liquid leaks between the primary side and the secondary side of the hollow fiber membrane. Furthermore, if the potting agent supply amount varies and the position of the inner end of the potting agent becomes unstable, the effective length of the hollow fiber membrane inside the potting agent (the length of the portion without the potting agent) varies, and the hollow fiber membrane As a result, the performance of the hollow fiber module is greatly affected.

本発明は、かかる点に鑑みてなされたものであり、筒状部の両端部におけるポッティング剤の供給位置(内側端の位置)をより安定させることが可能な中空糸モジュールを提供することをその目的とする。   The present invention has been made in view of such points, and provides a hollow fiber module capable of further stabilizing the potting agent supply position (inner end position) at both ends of the cylindrical portion. Objective.

上記目的を達成するための本発明は、中空糸膜が収容される筒状部と、前記筒状部の両側の各開口端を閉鎖する蓋部とを有し、前記筒状部の両端部において前記中空糸膜の両端部がポッティング剤により封止されている中空糸モジュールであって、前記各蓋部には、第1のノズルが形成され、前記筒状部の両端部の前記ポッティング剤より内側には、第2のノズルが形成されて当該第2のノズルのノズル開口部が形成され、前記筒状部のノズル開口部の外側端における内径よりも、前記筒状部の端における内径が大きくなっているものである。   The present invention for achieving the above object has a cylindrical portion in which a hollow fiber membrane is accommodated, and lid portions that close open ends on both sides of the cylindrical portion, and both end portions of the cylindrical portion. A hollow fiber module in which both ends of the hollow fiber membrane are sealed with a potting agent, wherein the first nozzle is formed on each lid, and the potting agent at both ends of the cylindrical portion A second nozzle is formed on the inner side to form a nozzle opening of the second nozzle, and the inner diameter at the end of the cylindrical portion is larger than the inner diameter at the outer end of the nozzle opening of the cylindrical portion. Is something that is getting bigger.

本発明によれば、筒状部のノズル開口部の外側端よりも筒状部の端の内径が大きいため、筒状部の端部内の容積が大きくなる。これにより、筒状部の端部に供給されるポッティング剤の供給量を増やすことができ、その供給量のバラツキが小さくなるため、ポッティング剤の供給位置をより安定させることができる。この結果、ポッティング剤によって中空糸膜を確実に封止できる。また、ポッティング剤が第2のノズルに入り込んで硬化することを防止し、第2のノズルの通液性を確保できる。さらに中空糸膜の有効長のばらつきを抑えて中空糸モジュールの性能を安定させることができる。   According to the present invention, since the inner diameter of the end of the cylindrical portion is larger than the outer end of the nozzle opening of the cylindrical portion, the volume in the end portion of the cylindrical portion is increased. Thereby, the supply amount of the potting agent supplied to the end of the cylindrical portion can be increased, and the variation in the supply amount can be reduced, so that the potting agent supply position can be made more stable. As a result, the hollow fiber membrane can be reliably sealed with the potting agent. Further, it is possible to prevent the potting agent from entering and curing the second nozzle, and to ensure the liquid permeability of the second nozzle. Furthermore, the performance of the hollow fiber module can be stabilized by suppressing variations in the effective length of the hollow fiber membrane.

前記筒状部の端を含む最端部には、前記筒状部の端と内径が同じで一定の大同径部が形成されていてもよい。かかる場合、筒状部の端部内の容積がより大きくなり、その分ポッティング剤の供給量を増やすことができる。これにより、ポッティング剤の供給量のバラツキが小さくなり、ポッティング剤の供給位置をより安定させることができる。   An end portion including the end of the cylindrical portion may be formed with a constant large same diameter portion having the same inner diameter as the end of the cylindrical portion. In such a case, the volume in the end of the cylindrical portion becomes larger, and the amount of potting agent supplied can be increased accordingly. Thereby, the variation in the supply amount of the potting agent is reduced, and the supply position of the potting agent can be further stabilized.

前記大同径部の内側には、前記ノズル開口部の外側端側に向かって次第に内径が小さくなるテーパ部が形成されていてもよい。かかる場合、例えばポッティング剤の供給時に混入した気泡が、滞留することなくテーパ部に沿って移動するので、ポッティング剤から排出され易くなる。よって、筒状部の端の内径をノズル開口部の外側端の内径よりも大きくした場合であっても、ポッティング剤内に気泡が残留することが抑制され、ポッティング剤の強度や封止性が確保される。   A tapered portion that gradually decreases in inner diameter toward the outer end side of the nozzle opening may be formed inside the large diameter portion. In such a case, for example, the air bubbles mixed when the potting agent is supplied move along the tapered portion without staying, so that it becomes easy to be discharged from the potting agent. Therefore, even when the inner diameter of the end of the cylindrical portion is larger than the inner diameter of the outer end of the nozzle opening, it is suppressed that bubbles remain in the potting agent, and the strength and sealing performance of the potting agent are reduced. Secured.

前記テーパ部と前記ノズル開口部の外側端との間には、前記ノズル開口部の外側端と内径が同じで一定の小同径部が形成されていてもよい。かかる場合、小同径部にポッティング剤の内側端を位置させることにより、第2のノズルのノズル開口部の外側端からポッティング剤までの筒状部の内径が一定になる。これにより、そのノズル開口部の外側端からポッティング剤までの筒状部内に液体が流入した場合でも当該液体が第2のノズルから排出されやすくなる。また、第2のノズルと筒状部を通じる液体の通液性が向上する。   Between the tapered portion and the outer end of the nozzle opening, a constant small same diameter portion having the same inner diameter as the outer end of the nozzle opening may be formed. In such a case, by positioning the inner end of the potting agent at the small diameter portion, the inner diameter of the cylindrical portion from the outer end of the nozzle opening of the second nozzle to the potting agent becomes constant. Thereby, even when the liquid flows into the cylindrical portion from the outer end of the nozzle opening to the potting agent, the liquid is easily discharged from the second nozzle. Further, the liquid permeability through the second nozzle and the cylindrical portion is improved.

前記筒状部のノズル開口部の外側端と前記大同径部との間には、前記ノズル開口部の外側端と内径が同じで一定の小同径部が形成されていてもよい。かかる場合、小同径部にポッティング剤の内側端を位置させることにより、ノズル開口部の外側端からポッティング剤までの筒状部の内径が一定になる。これにより、そのノズル開口部の外側端からポッティング剤までの筒状部内に液体が流入した場合でも当該液体が第2のノズルから排出されやすくなる。また、第2のノズルと筒状部を通じる液体の通液性が向上する。   Between the outer end of the nozzle opening of the cylindrical portion and the large diameter portion, a small small diameter portion having the same inner diameter as the outer end of the nozzle opening and having a constant diameter may be formed. In such a case, by positioning the inner end of the potting agent at the small diameter portion, the inner diameter of the cylindrical portion from the outer end of the nozzle opening to the potting agent becomes constant. Thereby, even when the liquid flows into the cylindrical portion from the outer end of the nozzle opening to the potting agent, the liquid is easily discharged from the second nozzle. Further, the liquid permeability through the second nozzle and the cylindrical portion is improved.

前記筒状部のノズル開口部の外側端から前記筒状部の端に近づくにつれて内径が次第に大きくなっていてもよい。かかる場合、筒状部の端部の内周面が傾斜するので、ポッティング剤の供給時に混入した気泡が当該傾斜に沿って移動しポッティング剤から排出され易くなる。よって、筒状部の端の内径をノズル開口部の外側端の内径よりも大きくした場合であっても、ポッティング剤内に気泡が残留することが抑制され、ポッティング剤の強度や封止性が確保される。   The inner diameter may gradually increase from the outer end of the nozzle opening of the cylindrical portion toward the end of the cylindrical portion. In such a case, since the inner peripheral surface of the end portion of the cylindrical portion is inclined, the air bubbles mixed at the time of supplying the potting agent move along the inclination and are easily discharged from the potting agent. Therefore, even when the inner diameter of the end of the cylindrical portion is larger than the inner diameter of the outer end of the nozzle opening, it is suppressed that bubbles remain in the potting agent, and the strength and sealing performance of the potting agent are reduced. Secured.

また、中空糸モジュールは、前記筒状部の端から前記筒状部のノズル開口部の外側端側に向けて内径が次第に小さくなるテーパ部が形成され、前記テーパ部と前記ノズル開口部の外側端との間には、前記ノズル開口部の外側端と内径が同じで一定の小同径部が形成されていてもよい。かかる場合、ポッティング剤内に気泡が残留することを抑制しポッティング剤の強度や封止性を確保できる。また、筒状部内に流入した液体が筒状部の端部付近で滞ることなく第2のノズルから排出されやすくなる。また、第2のノズルと筒状部を通じる液体の通液性を向上できる。   Further, the hollow fiber module is formed with a tapered portion whose inner diameter gradually decreases from the end of the tubular portion toward the outer end side of the nozzle opening of the tubular portion, and the outside of the tapered portion and the nozzle opening. A small small-diameter portion having the same inner diameter as the outer end of the nozzle opening and having a constant diameter may be formed between the ends. In such a case, it is possible to prevent bubbles from remaining in the potting agent and to ensure the strength and sealing performance of the potting agent. In addition, the liquid that has flowed into the cylindrical portion is easily discharged from the second nozzle without stagnation near the end of the cylindrical portion. In addition, liquid permeability through the second nozzle and the cylindrical portion can be improved.

上記いずれかに記載の中空糸モジュールは、ポッティング部の長さの最大長さが2.0mm〜15mmである試用品であってもよい。試用品の場合は、ポッティング剤の供給量が極めて少なく当該供給量の制御が難しいため、筒状部の端の内径を大きくしてポッティング剤の供給量を増やすメリットは大きい。   The hollow fiber module according to any one of the above may be a trial product having a maximum potting length of 2.0 mm to 15 mm. In the case of a trial product, since the supply amount of the potting agent is extremely small and it is difficult to control the supply amount, the merit of increasing the supply amount of the potting agent by increasing the inner diameter of the end of the cylindrical portion is great.

本発明によれば、筒状部の両端部におけるポッティング剤の供給位置をより安定させることができる。   According to the present invention, the potting agent supply position at both ends of the cylindrical portion can be further stabilized.

中空糸モジュールの概略を示す説明図である。It is explanatory drawing which shows the outline of a hollow fiber module. 筒状部の端部の内周面の形状を示す縦断面図である。It is a longitudinal cross-sectional view which shows the shape of the internal peripheral surface of the edge part of a cylindrical part. 筒状部の端部に遠心力を用いてポッティング剤を供給している状態を示す説明図である。It is explanatory drawing which shows the state which is supplying the potting agent to the edge part of a cylindrical part using centrifugal force. ノズル開口部の外側端と封止部との間の領域を示す中空糸モジュールの端部の説明図である。It is explanatory drawing of the edge part of the hollow fiber module which shows the area | region between the outer side edge of a nozzle opening part, and a sealing part. 大同径部と小同径部との間にテーパ部を有する筒状部の端部を示す説明図である。It is explanatory drawing which shows the edge part of the cylindrical part which has a taper part between a large same diameter part and a small same diameter part. 大同径部とノズル開口部の外側端との間にテーパ部を形成した筒状部の端部を示す説明図である。It is explanatory drawing which shows the edge part of the cylindrical part which formed the taper part between the large diameter part and the outer end of a nozzle opening part. ノズル開口部の外側端から筒状部の端に向けて次第に内径が大きくなる筒状部の端部を示す説明図である。It is explanatory drawing which shows the edge part of the cylindrical part from which the internal diameter becomes large gradually toward the edge of a cylindrical part from the outer end of a nozzle opening part. テーパ部と小同径部を有する筒状部の端部を示す説明図である。It is explanatory drawing which shows the edge part of the cylindrical part which has a taper part and a small same diameter part.

以下、図面を参照して、本発明の好ましい実施の形態について説明する。図1は、本実施の形態にかかる中空糸モジュール1の構成の概略を示す縦断面の説明図である。なお、本明細書及び図面において、実質的に同一の機能構成を有する構成要素については、同一の符号を付することにより重複説明を省略する。   Hereinafter, preferred embodiments of the present invention will be described with reference to the drawings. Drawing 1 is an explanatory view of the longitudinal section showing the outline of the composition of hollow fiber module 1 concerning this embodiment. In addition, in this specification and drawing, about the component which has the substantially same function structure, duplication description is abbreviate | omitted by attaching | subjecting the same code | symbol.

中空糸モジュール1は、例えば図1に示すように中空糸膜Aが長手方向(軸方向)に収容される筒状部10と、筒状部10の両側の開口端を閉鎖する蓋部11を有している。   For example, as shown in FIG. 1, the hollow fiber module 1 includes a cylindrical portion 10 in which the hollow fiber membrane A is accommodated in the longitudinal direction (axial direction), and a lid portion 11 that closes open ends on both sides of the cylindrical portion 10. Have.

中空糸膜Aは、多数本からなる束状になって筒状部10に収容されている。   The hollow fiber membrane A is accommodated in the cylindrical portion 10 in a bundle shape composed of a large number.

筒状部10の両端部において中空糸膜Aの両端部は、ポッティング剤Bにより封止されている。ポッティング剤Bは、円柱状に硬化しており、中空糸膜A同士の間と、中空糸膜Aと筒状部10の内周面と間に充填され、中空糸膜Aの両端部を封止している。なお、中空糸膜Aの両端は、ポッティング剤Bの外側端面に開口している。   Both ends of the hollow fiber membrane A are sealed with a potting agent B at both ends of the tubular portion 10. The potting agent B is hardened in a cylindrical shape, and is filled between the hollow fiber membranes A and between the hollow fiber membrane A and the inner peripheral surface of the tubular portion 10, and seals both ends of the hollow fiber membrane A. It has stopped. Note that both ends of the hollow fiber membrane A are open to the outer end face of the potting agent B.

各蓋部11の内側には、中空糸膜Aの端が開口する端部空間Gが形成されている。各蓋部11の中央には、第1のノズル20が形成され、中空糸モジュール1の外部と蓋部11内の端部空間Gが連通している。   An end space G in which the end of the hollow fiber membrane A opens is formed inside each lid portion 11. A first nozzle 20 is formed at the center of each lid portion 11, and the end space G in the lid portion 11 communicates with the outside of the hollow fiber module 1.

筒状部10の両端部付近には、それぞれ第2のノズル21が形成されている。第2のノズル21は、ポッティング剤Bよりも内側に形成され、中空糸モジュール1の外部と、筒状部10内の中空糸膜Aの外周空間Cが連通している。   In the vicinity of both end portions of the tubular portion 10, second nozzles 21 are respectively formed. The second nozzle 21 is formed inside the potting agent B, and the outside of the hollow fiber module 1 communicates with the outer peripheral space C of the hollow fiber membrane A in the tubular portion 10.

かかる構成により、例えば蓋部11の一方の第1のノズル20から流入した第1の液体は、端部空間Gを通過して中空糸膜A内に流入し、中空糸膜Aの中空部を通って反対側の端部空間Gに流出し、他方の第1のノズル20から外部に流出する。また、筒状部10の一方の第2のノズル21から流入した第2の液体は、中空糸膜Aの外周空間Cを通過して他方の第2のノズル21から外部に流出する。第1のノズル20から流入した第1の液体は、各中空糸膜Aの管内を通る際に、特定成分が管の側壁の微細な孔を通過し外周空間Cに流出し、第2の液体と共に第2のノズル21から外部に流出される。こうして第1の液体から特定成分が分離される。また、他の例として、第1のノズル20から流入した液体が中空糸膜Aを通って濾過され、そのろ過液が第2のノズル21から排出されてもよく、その逆で第2のノズル21から流入した液体が、中空糸膜Aを通って濾過され第1のノズル20から排出されてもよい。また、第1のノズル20と第2のノズル21は、それぞれ2つずつあるが、中空糸モジュール1の用途に応じて、それぞれ片方のみを用いてもう片方が封鎖されていてもよい。   With this configuration, for example, the first liquid that has flowed from one first nozzle 20 of the lid portion 11 passes through the end space G and flows into the hollow fiber membrane A, and the hollow portion of the hollow fiber membrane A is It flows out to the end space G on the opposite side, and flows out from the other first nozzle 20 to the outside. Further, the second liquid that has flowed in from the second nozzle 21 of the cylindrical portion 10 passes through the outer peripheral space C of the hollow fiber membrane A and flows out of the other second nozzle 21 to the outside. When the first liquid flowing in from the first nozzle 20 passes through the pipes of the hollow fiber membranes A, the specific component passes through the fine holes on the side walls of the pipes and flows out into the outer peripheral space C. At the same time, it flows out from the second nozzle 21 to the outside. In this way, the specific component is separated from the first liquid. As another example, the liquid flowing in from the first nozzle 20 may be filtered through the hollow fiber membrane A, and the filtrate may be discharged from the second nozzle 21, and vice versa. The liquid flowing in from 21 may be filtered through the hollow fiber membrane A and discharged from the first nozzle 20. Moreover, although there are two each of the first nozzle 20 and the second nozzle 21, depending on the application of the hollow fiber module 1, only one of them may be used and the other may be sealed.

ここで、筒状部10の内周面30の形状について説明する。内周面30は、例えば中央に細径部40を有し、中央から両方の外側に向けてテーパ部41、小同径部42、垂直部43及び大同径部44をこの順番で有している。   Here, the shape of the inner peripheral surface 30 of the cylindrical portion 10 will be described. The inner peripheral surface 30 has, for example, a thin-diameter portion 40 at the center, and has a tapered portion 41, a small-diameter portion 42, a vertical portion 43, and a large-diameter portion 44 in this order from the center toward both outsides. Yes.

細径部40は、内周面30の中央に形成され、内径が一定若しくは若干の射出成型用の抜き勾配があり、最も小さく(抜き勾配がある場合は、中央付近が最も小さく)なっている。小同径部42は、内径が一定で細径部40よりも大きくなっている。第2のノズル21は、小同径部42に開口している。テーパ部41は、細径部40と小同径部42の間に存在し斜めに傾斜している。大同径部44は、筒状部10の端10aを含む最端部に位置し、内径が一定で小同径部42よりも大きくなっている。垂直部43は、小同径部42と大同径部44に対し垂直に形成され、小同径部42と大同径部44の間に存在している。なお、小同径部42、大同径部44についても、若干の射出成型用の抜き勾配があってもよい。   The small-diameter portion 40 is formed at the center of the inner peripheral surface 30 and has a constant inner diameter or a slight draft for injection molding, and is the smallest (when there is a draft, the vicinity of the center is the smallest). . The small-diameter portion 42 has a constant inner diameter and is larger than the small-diameter portion 40. The second nozzle 21 is open to the small-diameter portion 42. The taper portion 41 exists between the small diameter portion 40 and the small diameter portion 42 and is inclined obliquely. The large-diameter portion 44 is located at the outermost end portion including the end 10a of the tubular portion 10, has a constant inner diameter and is larger than the small-equal-diameter portion 42. The vertical portion 43 is formed perpendicularly to the small-diameter portion 42 and the large-diameter portion 44, and exists between the small-diameter portion 42 and the large-diameter portion 44. The small-diameter portion 42 and the large-diameter portion 44 may have a slight draft for injection molding.

したがって、この中空糸モジュール1の筒状部10では、図2に示すように第2のノズル21のノズル開口部21aの外側端Eの内径D1よりも、筒状部10の端10aの内径D2が大きくなっている。また、筒状部10の端10aを含む最端部には、径が一定の大同径部44が形成され、大同径部44とノズル開口部21aの外側端Eとの間には、ノズル開口部21aの外側端Eと同じ内径の小同径部42が形成されている。ポッティング剤Bは、小同径部42におけるノズル開口部21aの外側端Eより外側の位置から、大同径部44の外側の端まで形成されている。なお、内径D1の内径D2に対する比率は、10%〜80%が好ましい。また、大同径部44の長さL1は、例えば小同径部42の大同径部44からノズル開口部21aの外側端Eまでの長さL2よりも長く設定されている。   Therefore, in the cylindrical portion 10 of the hollow fiber module 1, as shown in FIG. 2, the inner diameter D2 of the end 10a of the cylindrical portion 10 is larger than the inner diameter D1 of the outer end E of the nozzle opening 21a of the second nozzle 21. Is getting bigger. In addition, a large-diameter portion 44 having a constant diameter is formed at the outermost end portion including the end 10a of the tubular portion 10, and a nozzle opening is provided between the large-diameter portion 44 and the outer end E of the nozzle opening portion 21a. A small same diameter portion 42 having the same inner diameter as the outer end E of the portion 21a is formed. The potting agent B is formed from a position outside the outer end E of the nozzle opening 21 a in the small same diameter portion 42 to an outer end of the large same diameter portion 44. The ratio of the inner diameter D1 to the inner diameter D2 is preferably 10% to 80%. The length L1 of the large diameter portion 44 is set to be longer than, for example, the length L2 from the large diameter portion 44 of the small diameter portion 42 to the outer end E of the nozzle opening 21a.

次に中空糸モジュール1の製造プロセスにおけるポッティング剤Bの形成工程について説明する。中空糸モジュール1の製造時には、図3に示すように筒状部10に中空糸膜Aが収容された状態で、筒状部10の両端部に、蓋部11と異なるキャップ60が嵌め込まれる。キャップ60には、管路61を通じてポッティング剤供給装置62が接続される。筒状部10の長手方向に直角で筒状部10の中心を通る中心線Fを中心に、筒状部10が回転され、その状態で、所定量のポッティング剤Bが、キャップ60の流入口から筒状部10内に供給される。筒状部10内に流入したポッティング剤Bは、遠心力で筒状部10の両端部に集められて硬化する。これにより、第2のノズル21のノズル開口部21aの外側端Eよりも外側にポッティング剤Bが形成される。ポッティング剤Bの内側端面は、小同径部42上に位置する。その後、ポッティング剤Bの筒状部10の端10aより外側に出た部分が切断され、その後キャップ60の代わりに蓋部11が取り付けられて、中空糸モジュール1となる。   Next, the step of forming the potting agent B in the manufacturing process of the hollow fiber module 1 will be described. At the time of manufacturing the hollow fiber module 1, a cap 60 different from the lid portion 11 is fitted into both ends of the tubular portion 10 with the hollow fiber membrane A being accommodated in the tubular portion 10 as shown in FIG. 3. A potting agent supply device 62 is connected to the cap 60 through a conduit 61. The cylindrical portion 10 is rotated about a center line F perpendicular to the longitudinal direction of the cylindrical portion 10 and passing through the center of the cylindrical portion 10, and in this state, a predetermined amount of potting agent B is supplied to the inlet of the cap 60. Is supplied into the cylindrical portion 10. The potting agent B that has flowed into the tubular portion 10 is collected and cured at both ends of the tubular portion 10 by centrifugal force. Thereby, the potting agent B is formed outside the outer end E of the nozzle opening 21 a of the second nozzle 21. The inner end surface of the potting agent B is located on the small-diameter portion 42. Thereafter, the portion of the potting agent B that protrudes from the end 10 a of the cylindrical portion 10 is cut, and then the lid portion 11 is attached instead of the cap 60 to form the hollow fiber module 1.

以上の実施の形態によれば、筒状部10の端10aの内径D2が、第2のノズル21のノズル開口部21aの外側端Eの内径D1よりも大きいため、筒状部10の端部内の容積が大きくなる。これにより、筒状部10の端部に供給されるポッティング剤Bの供給量を増やすことができ、その供給量のバラツキが小さくなるため、ポッティング剤Bの供給位置(内側端の位置)をより安定させることができる。この結果、ポッティング剤Bによって中空糸膜Aを確実に封止できる。また、ポッティング剤Bが第2のノズル21に入り込んで硬化することを防止し、第2のノズル21の通液性を確保できる。さらに中空糸膜Aの有効長のばらつきを抑えて中空糸モジュール1の性能を安定させることができる。   According to the above embodiment, the inner diameter D2 of the end 10a of the cylindrical portion 10 is larger than the inner diameter D1 of the outer end E of the nozzle opening 21a of the second nozzle 21, so The volume of increases. Thereby, the supply amount of the potting agent B supplied to the end portion of the cylindrical portion 10 can be increased, and the variation in the supply amount is reduced, so that the supply position (inner end position) of the potting agent B is further increased. It can be stabilized. As a result, the hollow fiber membrane A can be reliably sealed by the potting agent B. Further, the potting agent B can be prevented from entering and curing the second nozzle 21, and the liquid permeability of the second nozzle 21 can be ensured. Furthermore, the variation of the effective length of the hollow fiber membrane A can be suppressed, and the performance of the hollow fiber module 1 can be stabilized.

筒状部10の端10aを含む最端部には、筒状部10の端と内径が同じで一定の大同径部44が形成されているので、筒状部10の端部内の容積がより大きくなり、その分ポッティング剤Bの供給量を増やすことができる。これにより、ポッティング剤Bの供給量のバラツキを小さくすることができ、ポッティング剤Bの供給位置をより安定させることができる。   The outermost end portion including the end 10a of the tubular portion 10 is formed with a constant large-diameter portion 44 having the same inner diameter as the end of the tubular portion 10 and thus has a larger volume in the end portion of the tubular portion 10. The amount of the potting agent B can be increased accordingly. Thereby, the variation in the supply amount of the potting agent B can be reduced, and the supply position of the potting agent B can be further stabilized.

筒状部10のノズル開口部21aの外側端Eと大同径部44との間には、ノズル開口部21aの外側端Eと内径が同じで一定の小同径部42が形成されている。かかる場合、小同径部42にポッティング剤Bの内側端を位置させることにより、ノズル開口部21aの外側端Eからポッティング剤Bまでの筒状部10の内径が一定になる。これにより、例えば図4に示すようにノズル開口部21aの外側端Eからポッティング剤Bまでの筒状部10内(図4の領域R)に液体が流入した場合でも当該液体が第2のノズル21から排出されやすくなる。また、第2のノズル21と筒状部10の外周空間Cを通る液体の通液性が向上する。   Between the outer end E of the nozzle opening 21a of the cylindrical portion 10 and the large-diameter portion 44, a small small-diameter portion 42 having the same inner diameter as the outer end E of the nozzle opening 21a and having a constant diameter is formed. In this case, by positioning the inner end of the potting agent B in the small-diameter portion 42, the inner diameter of the cylindrical portion 10 from the outer end E of the nozzle opening 21a to the potting agent B becomes constant. Thereby, for example, as shown in FIG. 4, even when the liquid flows into the cylindrical portion 10 (region R in FIG. 4) from the outer end E of the nozzle opening 21a to the potting agent B, the liquid is supplied to the second nozzle. 21 is easily discharged. Further, the liquid permeability of the liquid passing through the second nozzle 21 and the outer peripheral space C of the cylindrical portion 10 is improved.

以上の実施の形態で記載した筒状部10の内周面30において、図5に示すように小同径部42と大同径部44との間にテーパ部70が形成されていてもよい。かかる場合、ポッティング剤Bの供給時に混入した気泡が、滞留することなくテーパ部70に沿って移動するので、ポッティング剤Bから排出され易くなる。よって、筒状部10の端10aの内径をノズル開口部21aの外側端Eの内径よりも大きくした場合であっても、気泡の残留が抑制され、ポッティング剤Bの強度や封止性が確保される。   In the inner peripheral surface 30 of the cylindrical portion 10 described in the above embodiment, a tapered portion 70 may be formed between the small-diameter portion 42 and the large-diameter portion 44 as shown in FIG. In such a case, the air bubbles mixed when the potting agent B is supplied move along the tapered portion 70 without staying, so that the potting agent B is easily discharged. Therefore, even when the inner diameter of the end 10a of the cylindrical portion 10 is larger than the inner diameter of the outer end E of the nozzle opening 21a, the remaining of bubbles is suppressed and the strength and sealing performance of the potting agent B are ensured. Is done.

また、図6に示すように大同径部44とノズル開口部21aの外側端Eとの間をテーパ部70としてもよい。かかる場合も、ポッティング剤Bの供給時に混入した気泡をテーパ部70に沿って適切に排出できる。   Moreover, as shown in FIG. 6, it is good also as the taper part 70 between the large same diameter part 44 and the outer side edge E of the nozzle opening part 21a. Even in such a case, the air bubbles mixed when the potting agent B is supplied can be appropriately discharged along the tapered portion 70.

また、筒状部10の端部の内周面30には、図7に示すように筒状部10のノズル開口部21aの外側端Eから筒状部10の端10aに近づくにつれて内径が次第に大きくなる傾斜面80を形成してもよい。かかる場合も、ポッティング剤Bの供給時に混入した気泡が、傾斜面80に沿って移動し適切に排出される。よって、筒状部10の端10aの内径をノズル開口部21aの外側端Eの内径よりも大きくした場合であっても、気泡の混入が抑制され、ポッティング剤Bの強度や封止性が確保される。   Further, as shown in FIG. 7, the inner diameter gradually increases from the outer end E of the nozzle opening 21 a of the tubular portion 10 toward the end 10 a of the tubular portion 10 on the inner peripheral surface 30 of the end portion of the tubular portion 10. You may form the inclined surface 80 which becomes large. Even in such a case, the bubbles mixed during the feeding of the potting agent B move along the inclined surface 80 and are appropriately discharged. Therefore, even when the inner diameter of the end 10a of the cylindrical portion 10 is larger than the inner diameter of the outer end E of the nozzle opening 21a, the mixing of bubbles is suppressed and the strength and sealing performance of the potting agent B are ensured. Is done.

また、中空糸モジュール1は、図8に示すように筒状部10の端10aから筒状部10のノズル開口部21aの外側端E側に向けて内径が次第に小さくなるテーパ部90が形成され、テーパ部90とノズル開口部21aの外側端Eとの間に、ノズル開口部21aの外側端Eと内径が同じで一定の小同径部42が形成されていてもよい。かかる場合、テーパ部90に沿って気泡が排出されるので、ポッティング剤B内に気泡が残留することを抑制しポッティング剤Bの強度や封止性を確保できる。また、筒状部10内に流入した液体が筒状部10の端部付近で滞ることなく第2のノズル21から排出されやすくなる。また、第2のノズル21と筒状部10を通じる液体の通液性を向上できる。   Moreover, the hollow fiber module 1 is formed with a tapered portion 90 whose inner diameter gradually decreases from the end 10a of the tubular portion 10 toward the outer end E side of the nozzle opening 21a of the tubular portion 10 as shown in FIG. Between the taper portion 90 and the outer end E of the nozzle opening 21a, a constant small same diameter portion 42 having the same inner diameter as the outer end E of the nozzle opening 21a may be formed. In such a case, since the bubbles are discharged along the tapered portion 90, it is possible to suppress the bubbles from remaining in the potting agent B and to ensure the strength and sealing performance of the potting agent B. Further, the liquid that has flowed into the cylindrical portion 10 is easily discharged from the second nozzle 21 without stagnation near the end of the cylindrical portion 10. In addition, the liquid permeability through the second nozzle 21 and the cylindrical portion 10 can be improved.

以上に記載した中空糸モジュール1は、試用品の中空糸モジュールであってもよい。中空糸モジュールは、一般に購入されて通常使用される通常品と、例えば購入前に当該通常品の性能の確認等するための試用品がある。高価な試験液の使用量を減らすため、試用品の中空糸モジュールには、通常品の中空糸モジュールより小さい寸法に形成されているものがある。例えばその試用品の中空糸モジュールは、通常品の中空糸モジュールと相似形状であって、1/3以下程度の縮小サイズで形成される。また、中空糸膜Aの数も、通常品が数千本以上であるのに対し、試用品は、1〜500本程度になる。例えば試用品の中空糸モジュールは、内径D1が1mm〜20mm程度、さらに好ましくは1mm〜10mm程度となる。例えば通常品の中空糸モジュールは、ポッティング部(ポッティング剤Bの部分)の最大長さが15mmより大きいのに対し、試用品の中空糸モジュールは、ポッティング部の最大長さが2.0mm〜15mm程度となる。なお、ポッティング部は、遠心成形であるため、回転軸の上方から見て、内端面に曲率を有しており、中心部が最も短く、外側部が最も長くなっている。   The hollow fiber module 1 described above may be a trial hollow fiber module. The hollow fiber module includes a normal product that is generally purchased and normally used, and a sample for checking the performance of the normal product before purchase, for example. In order to reduce the amount of expensive test solution used, some of the hollow fiber modules of the sample are formed to have a size smaller than that of the normal hollow fiber module. For example, the hollow fiber module of the trial product has a shape similar to that of a normal hollow fiber module, and is formed with a reduced size of about 1/3 or less. Further, the number of hollow fiber membranes A is usually several thousand or more, while the number of trial products is about 1 to 500. For example, the hollow fiber module of the trial product has an inner diameter D1 of about 1 mm to 20 mm, more preferably about 1 mm to 10 mm. For example, a normal hollow fiber module has a maximum potting portion (potting agent B portion) having a maximum length greater than 15 mm, whereas a trial hollow fiber module has a maximum potting portion length of 2.0 mm to 15 mm. It will be about. In addition, since the potting part is centrifugal molding, it has a curvature at the inner end face when viewed from above the rotation shaft, and the center part is the shortest and the outer part is the longest.

小型の試用品の中空糸モジュールを製造する場合、ポッティング剤Bの供給量が極めて少なく制御が難しいため、以上の実施の形態のように筒状部10の端10aの内径を大きくしてポッティング剤Bの供給量を増やすメリットは大きい。この結果、試供用の中空糸モジュールにおいて、筒状部10の端部に適正な量のポッティング剤Bが供給され、ポッティング剤Bの封止性、第2のノズル21の通液性を確保できる。さらに中空糸膜Aの有効長のばらつきを抑えて中空糸モジュール1の性能を安定させることができる。よって、通常品の中空糸モジュールの性能確認を正確に行うことができる。   When manufacturing a hollow fiber module of a small trial product, since the amount of potting agent B supplied is extremely small and difficult to control, the potting agent is increased by increasing the inner diameter of the end 10a of the cylindrical portion 10 as in the above embodiment. The merit of increasing the supply amount of B is great. As a result, in the sample hollow fiber module, an appropriate amount of the potting agent B is supplied to the end of the cylindrical portion 10, and the sealing property of the potting agent B and the liquid permeability of the second nozzle 21 can be ensured. . Furthermore, the variation of the effective length of the hollow fiber membrane A can be suppressed, and the performance of the hollow fiber module 1 can be stabilized. Therefore, the performance of the normal hollow fiber module can be accurately confirmed.

以上、添付図面を参照しながら本発明の好適な実施の形態について説明したが、本発明はかかる例に限定されない。当業者であれば、特許請求の範囲に記載された思想の範疇内において、各種の変更例または修正例に想到し得ることは明らかであり、それらについても当然に本発明の技術的範囲に属するものと了解される。   The preferred embodiments of the present invention have been described above with reference to the accompanying drawings, but the present invention is not limited to such examples. It is obvious for those skilled in the art that various modifications or modifications can be conceived within the scope of the idea described in the claims, and these naturally belong to the technical scope of the present invention. It is understood.

例えば中空糸モジュール1の筒状部10の内周面30の形状は、筒状部10のノズル開口部21aの外側端Eにおける内径D1よりも、筒状部10の端10aにおける内径D2が大きくなっていれば、他の形状であってもよい。また、蓋部11が複数の部材から構成されるなど、筒状部10以外の他の部分も他の形状を有していてもよい。   For example, the shape of the inner peripheral surface 30 of the tubular portion 10 of the hollow fiber module 1 is such that the inner diameter D2 at the end 10a of the tubular portion 10 is larger than the inner diameter D1 at the outer end E of the nozzle opening 21a of the tubular portion 10. Other shapes may be used as long as they are. Moreover, other parts other than the cylindrical part 10 may have other shapes, such as the cover part 11 being comprised from several members.

本発明は、中空糸モジュールの筒状部の両端部におけるポッティング剤の供給位置をより安定させる際に有用である。   The present invention is useful for further stabilizing the potting agent supply position at both ends of the cylindrical portion of the hollow fiber module.

1 中空糸モジュール
10 筒状部
10a 筒状部の端
11 蓋部
20 第1のノズル
21 第2のノズル
21a ノズル開口部
42 小同径部
44 大同径部
A 中空糸膜
B ポッティング剤
E ノズル開口部の外側端
D1 ノズル開口部の外側端の内径
D2 筒状部の端の内径
DESCRIPTION OF SYMBOLS 1 Hollow fiber module 10 Cylindrical part 10a End of cylindrical part 11 Lid part 20 1st nozzle 21 2nd nozzle 21a Nozzle opening part 42 Small equidiameter part 44 Large equidiameter part A Hollow fiber membrane B Potting agent E Nozzle opening Outer end D1 inner diameter D2 of nozzle opening outer end inner diameter of cylindrical end

Claims (8)

中空糸膜が収容される筒状部と、前記筒状部の両側の各開口端を閉鎖する蓋部とを有し、前記筒状部の両端部において前記中空糸膜の両端部がポッティング剤により封止されている中空糸モジュールであって、
前記各蓋部には、第1のノズルが形成され、
前記筒状部の両端部の前記ポッティング剤より内側には、第2のノズルが形成されて当該第2のノズルのノズル開口部が形成され、
前記筒状部のノズル開口部の外側端における内径よりも、前記筒状部の端における内径が大きくなっている、中空糸モジュール。
A cylindrical portion in which the hollow fiber membrane is accommodated, and lid portions that close open ends on both sides of the cylindrical portion, and both ends of the hollow fiber membrane are potting agents at both ends of the cylindrical portion. A hollow fiber module sealed by
Each lid is formed with a first nozzle,
Inside the potting agent at both ends of the cylindrical portion, a second nozzle is formed to form a nozzle opening of the second nozzle,
A hollow fiber module, wherein an inner diameter at an end of the cylindrical portion is larger than an inner diameter at an outer end of a nozzle opening of the cylindrical portion.
前記筒状部の端を含む最端部には、前記筒状部の端と内径が同じで一定の大同径部が形成されている、請求項1に記載の中空糸モジュール。   2. The hollow fiber module according to claim 1, wherein the end portion including the end of the cylindrical portion is formed with a constant large same diameter portion having the same inner diameter as the end of the cylindrical portion. 前記大同径部の内側には、前記ノズル開口部の外側端側に向かって次第に内径が小さくなるテーパ部が形成されている、請求項2に記載の中空糸モジュール。   The hollow fiber module according to claim 2, wherein a tapered portion having an inner diameter gradually decreasing toward an outer end side of the nozzle opening is formed inside the large-diameter portion. 前記テーパ部と前記ノズル開口部の外側端との間には、前記ノズル開口部の外側端と内径が同じで一定の小同径部が形成されている、請求項3に記載の中空糸モジュール。   The hollow fiber module according to claim 3, wherein a small small-diameter portion having the same inner diameter and the same inner diameter as the outer end of the nozzle opening is formed between the tapered portion and the outer end of the nozzle opening. . 前記筒状部のノズル開口部の外側端と前記大同径部との間には、前記ノズル開口部の外側端と内径が同じで一定の小同径部が形成されている、請求項2に記載の中空糸モジュール。   The fixed small same-diameter portion having the same inner diameter as the outer end of the nozzle opening and a constant inner diameter is formed between the outer end of the nozzle opening of the cylindrical portion and the large-diameter portion. The hollow fiber module as described. 前記筒状部のノズル開口部の外側端から前記筒状部の端に近づくにつれて内径が次第に大きくなっている、請求項1に記載の中空糸モジュール。   The hollow fiber module according to claim 1, wherein the inner diameter gradually increases from the outer end of the nozzle opening of the cylindrical portion toward the end of the cylindrical portion. 前記筒状部の端から前記筒状部のノズル開口部の外側端側に向けて内径が次第に小さくなるテーパ部が形成され、
前記テーパ部と前記ノズル開口部の外側端との間には、前記ノズル開口部の外側端と内径が同じで一定の小同径部が形成されている、請求項1に記載の中空糸モジュール。
A tapered portion is formed in which the inner diameter gradually decreases from the end of the tubular portion toward the outer end side of the nozzle opening of the tubular portion,
The hollow fiber module according to claim 1, wherein a small small-diameter portion having the same inner diameter as the outer end of the nozzle opening and a constant inner diameter is formed between the tapered portion and the outer end of the nozzle opening. .
請求項1〜7のいずれかに記載の中空糸モジュールは、ポッティング部の長さの最大長さが2.0mm〜15mmである試用品である。   The hollow fiber module in any one of Claims 1-7 is a trial product whose maximum length of the length of a potting part is 2.0 mm-15 mm.
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