JP2012020538A - Laminate - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a laminate for obtaining a hard coat film that can be satisfactorily used for a touch panel of electric capacitance, is excellent in scratch resistance and has as fewer defects as required recently.SOLUTION: In the laminate having a protection film on at least one side of the hard coat film, hardness of fish eye existing on a surface of the hard coat film, to which the protection film is applied, is kept within a specific numerical value.

Description

  The present invention relates to a laminate. In particular, the present invention relates to a laminate having a hard coat film and a protective film.

  In recent years, a touch panel can be operated while looking at the screen by providing a transparent or translucent input device directly on a display such as an LCD (Liquid Crystal Display), and can be easily operated by anyone. Also, since it is possible to input characters and pictures, it has come to be widely used as a man / machine interface.

  The touch panel includes an optical method, an ultrasonic method, an electromagnetic induction method, a capacitance method, a resistance film method, and the like. Among these, the electrostatic capacity method is used because it has excellent transparency due to the small number of films used, there is no deterioration due to wear because there is no contact between conductive films, and detection at multiple points is possible. In recent years, the touch panel has been frequently used.

  The capacitive touch panel is a surface on the front side of a display after laminating a plurality of PET films having an etched ITO layer on a polyethylene terephthalate (PET) film as a carrier film. Obtained by laminating a hard coat layer or a hard coat film. Then, the obtained capacitive touch panel is mounted on the display such as LCD with the carrier film side on the display such as LCD (in this case, an air layer exists between them) or is adhered to the display such as LCD using an adhesive or the like. Used.

JP 2004-114355 A JP 2004-230562 A JP 2005-186484 A JP 2009-40056 A JP 2007-58162 A JP 2008-96781 A

  In the manufacturing process of the capacitive touch panel as described above, there is a problem that the carrier film is easily damaged during transportation. Thus, it is conceivable to use a hard coat film as the carrier film. Generally, however, the hard coat film has poor smoothness because of the high smoothness of the hard coat layer surface, and it is difficult to wind it into a roll shape. Therefore, further, a protective film having slipperiness is attached and wound.

  Moreover, as a hard coat film used for a capacitive touch panel, there is a demand for further reduction of defects as compared with the conventional technique in order to make use of the feature that the touch panel of this system is highly transparent. However, the present inventor newly discovered a problem that a defect occurs in the hard coat film if the protective film is pasted and stored in a roll shape for a long period of time.

Therefore, the present invention provides a laminate for obtaining a hard coat film that can be suitably used for a capacitive touch panel, has excellent scratch resistance, and has a small number of defects as required in recent years. Objective.
In addition, when a hard coat film is used as a carrier film as described above, a general hard coat layer has low adhesion, and can be bonded to a film such as an ITO film or an LCD serving as a touch panel constituent material using an adhesive. There is a problem that becomes difficult.

Accordingly, it is a desirable object of the present invention to provide a hard coat film having excellent adhesiveness in addition to the above.
These hard coat films are particularly hard coat films used in touch panel displays.

  As a result of intensive studies, the inventors have determined that the hardness of fish eyes existing on the side of the protective film attached to the hard coat film in the laminate having the protective film on at least one side of the hard coat film is a specific numerical value. The inventors have found that the above object can be achieved by setting the range, and have reached the present invention. That is, the present invention employs the following configuration.

1. A laminate having a hard coat film having a hard coat layer on at least one side of a base film, and a protective film having an adhesion layer on one side of the base film on at least one side of the hard coat film, the adhesion layer of the protective film A laminate having a fisheye Vickers hardness of 0.70 or less on the side surface.

Moreover, this invention includes the following structures.
2. 2. The laminate according to 1 above, wherein the contact angle of water on the surface of the hard coat layer in the hard coat film is 78 degrees or greater and 86 degrees or less, and the contact angle of n-dodecane is 22 degrees or less.
3. 3. The laminate according to 1 or 2 above, comprising an easy-adhesion layer comprising a polyester resin and a crosslinking agent as constituent components between the base film and the hard coat layer.
4). 4. The laminate according to any one of 1 to 3 above, wherein the hard coat film has a haze of 1.0% or less.
5. The laminated body of any one of said 1-4 whose thickness of a base film is 12 micrometers or more and 60 micrometers or less.
6). The laminate according to any one of 1 to 5 above, wherein the thickness of the hard coat layer is 1.0 μm or more and 3.0 μm or less.
7). The laminate according to any one of 1 to 6 above, wherein the hard coat film is for a capacitive touch panel.
8). The hard coat film obtained by peeling a protective film from the laminated body of any one of said 1-7.

  ADVANTAGE OF THE INVENTION According to this invention, the laminated body for obtaining the hard coat film which is excellent in abrasion resistance and has few faults to the extent requested | required in recent years can be provided. And since the hard coat film obtained from the laminated body of the present invention has few defects, mainly indentations, it is suitable for touch panels, particularly for capacitive touch panels. Further, since the number of defects is small, it can be suitably used for a touch panel in a high definition display.

Moreover, according to the preferable aspect of this invention, the hard coat film excellent in adhesiveness can be provided further simultaneously.
These hard coat films can be particularly suitably used as a hard coat film used inside a capacitive touch panel, particularly as a base film in the manufacturing process of the capacitive touch panel.

[Laminate]
The laminate of the present invention has a protective film on at least one side of a hard coat film. Hereafter, each structural component which comprises the laminated body of this invention is demonstrated.

[Hard coat film]
The hard coat film in the present invention has a hard coat layer on at least one surface of the base film.

(Haze)
The hard coat film of the present invention preferably has a haze of 2.0% or less, and more preferably 1.0% or less. When the haze is 2.0% or less, the clear feeling when the touch panel is used is sufficient, which is suitable for a smartphone or the like. Moreover, when haze is 1.0% or less, it is excellent in the clear feeling when it is further used as a touch panel, and can be used more suitably for a capacitive touch panel.

(Pencil hardness)
The pencil hardness on the hard coat layer surface of the hard coat film in the present invention is preferably H or more. Thereby, the damage | wound which arises in the manufacturing process of a capacitive touch panel can be suppressed.

(Concave defect)
The hard coat film in the present invention is bonded to a protective film as in the measurement method described later, and is concave on the surface of the base film after being stored in a roll for one month in an environment of a temperature of 23 ° C. and a relative humidity of 50% RH. It is preferable that the defects are 15 pieces / m ² or less. With such an embodiment, there are few defects and it can be suitably used for a touch panel, particularly for a capacitive touch panel. The number of concave defects on the surface of the substrate film is more preferably 10 pieces / m ² or less, and further preferably 5 pieces / m ² or less.

  In order to achieve such a number of concave defects, the Vickers hardness of the fish eye on the surface of the adhesion layer side of the protective film to be bonded may be within the numerical range defined by the present invention. Since the surface of the hard coat layer is generally harder than the surface of the base film, if the concave defects on the surface of the base film can be suppressed, the concave defects and / or the convex defects on the surface of the hard coat layer can be suppressed. Become. That is, if it is an aspect as mentioned above, even if it bonds together so that the adhesion layer of a protective film may become the hard-coat layer side, the concave-shaped defect in the hard-coat layer surface can also be suppressed, for example.

[Hard coat layer]
The hard coat layer in the present invention is mainly composed of a radiation curable resin (hereinafter sometimes referred to as a hard coat main agent) which will be described later. Here, “mainly” means 80% by mass or more, preferably 90% by mass or more, based on the total mass of the hard coat layer.

(Radiation curable resin composition)
The radiation curable resin in the present invention is a monomer, oligomer, or polymer that can be cured by radiation. As the radiation curable resin in the present invention, it is possible to increase the crosslinking density after curing, from the viewpoint that the effect of improving the surface hardness can be increased, and the effect of improving the transparency can be increased. A polyfunctional (meth) acrylate compound such as a polyfunctional (meth) acrylate monomer, a polyfunctional (meth) acrylate oligomer, or a polyfunctional (meth) acrylate polymer is preferable.

  Such a polyfunctional (meth) acrylate compound is a compound containing a (meth) acryloyl group in the molecule, and preferably contains at least two (meth) acryloyl groups in the molecule. As a result, the crosslinking reaction of the radiation curable resin can easily proceed, and the effect of improving the surface hardness can be further increased. Moreover, the polyfunctional (meth) acrylate compound in this invention may contain other polymerizable functional groups other than a (meth) acryloyl group in a molecule | numerator.

  Specific examples of the polyfunctional (meth) acrylate compound containing at least two (meth) acryloyl groups in the molecule include, for example, neopentyl glycol di (meth) acrylate, trimethylolpropane tri (meth) acrylate, pentaerythritol tri ( (Meth) acrylate, trimethylolethane tri (meth) acrylate, pentaerythritol tetra (meth) acrylate, dipentaerythritol tetra (meth) acrylate, alkyl-modified dipentaerythritol tetra (meth) acrylate, dipentaerythritol penta (meth) acrylate, Alkyl modified dipentaerythritol penta (meth) acrylate, dipentaerythritol hexa (meth) acrylate, caprolactone modified dipentaerythritol hexa (Meth) acrylate, ditrimethylolpropane tetra (meth) acrylate), melamine (meth) acrylate, and the like, oligomers of about 1 to 22 mer consisting of at least one of these, and polymers consisting of at least one of these Can be mentioned. Such polyfunctional (meth) acrylate compounds may be used alone or in combination of two or more.

  The radiation curable resin in the present invention is a (poly) alkylene glycol component-containing radiation-cured material in which a (poly) alkylene glycol component is copolymerized on the main chain or side chain of an acrylic polymer comprising the above polyfunctional (meth) acrylate compound. A mold resin is preferable, and the method of using this for the hard coat layer can be exemplified as a particularly preferable method for achieving the contact angle of water and n-dodecane that the present invention preferably defines. As such a (poly) alkylene glycol component, alkylene glycols such as ethylene glycol and propylene glycol can be preferably exemplified, and among these, ethylene glycol is preferable. The (poly) alkylene glycol component may be mono (alkylene glycol) without having a repeating structure, or may be oligo (alkylene glycol) or poly (alkylene glycol) having a repeating structure. . Preferred embodiments include an embodiment having (meth) acryloyl groups as functional groups at both ends of a (poly) alkylene glycol component, and a random copolymerization of a (poly) alkylene glycol component with a polyfunctional (meth) acrylate compound (oligomer or polymer). Or the aspect which carried out block copolymerization is mentioned. A particularly preferred embodiment is an embodiment in which a (poly) alkylene glycol component is block copolymerized in the main chain or side chain of a polyfunctional (meth) acrylate compound (oligomer or polymer).

  The (poly) alkylene glycol component has a number average molecular weight Mn of preferably 46 to 1,000,000, more preferably 60 to 500,000. When the number average molecular weight Mn is in the above numerical range, the contact angle of water and the contact angle of n-dodecane on the surface of the hard coat layer can be easily set within the numerical range preferably defined by the present invention. When the number average molecular weight Mn is too high, the contact angle of water tends to be too high. Also, since the viscosity of the coating becomes too high, coating tends to be difficult. Moreover, since it tends to be difficult to dissolve in a solvent with low polarity, it tends to be difficult to handle as a coating agent.

  The copolymerization amount of the (poly) alkylene glycol component is preferably 1% by mass or more and 5% by mass or less, more preferably 1.5% by mass or more and 4% by mass with respect to the mass of the acrylic polymer composed of the polyfunctional (meth) acrylate compound. It is 2 mass% or less, Most preferably, it is 2 mass% or less and 3 mass% or less. When the copolymerization amount of the (poly) alkylene glycol component is in the above numerical range, the contact angle of water and the contact angle of n-dodecane on the surface of the hard coat layer may be within the numerical range preferably defined by the present invention. It becomes easy. Increasing the copolymerization amount of the (poly) alkylene glycol component tends to reduce the contact angle of water, but does not significantly affect the contact angle of n-dodecane. Therefore, according to the method using the (poly) alkylene glycol component, a combination of a contact angle range of water and a contact angle range of n-dodecane that cannot be obtained only by adding a normal surfactant can be obtained.

  The number average molecular weight Mn of the radiation curable resin as described above is preferably 100 to 1,000,000, more preferably 1000 to 500,000. When the number average molecular weight Mn is too high, since the viscosity is too high, coating tends to be difficult.

(Photopolymerization initiator)
In the present invention, it is preferable to add a photopolymerization initiator to the hard coat layer in order to form a hard coat layer with higher hardness. Examples of the photopolymerization initiator include 1-hydroxycyclohexyl phenyl ketone, 2,2-dimethoxy-2-phenylacetophenone, xanthone, fluorenone, anthraquinone, benzaldehyde, fluorene, anthraquinone, triphenylamine, carbazole, 3-methylacetophenone, 4- Chlorobenzophenone, 2,2-dimethoxy-2-phenylacetophenone, 2-methyl-1-1 [4- (methylthio) phenyl] -2-morpholino-propan-1-one, 2,4,6-trimethylbenzoyldiphenylphosphine Examples thereof include oxides and bis- (2,6-dimethoxybenzoyl) 2,4,4-trimethylpentylphosphine oxide. The addition amount of the photopolymerization initiator is preferably 0.1% by mass or more and 10% by mass or less based on 100% by mass of the radiation curable resin. By making addition amount into the said numerical range, the improvement effect of the surface hardness of a hard-coat layer can be made higher. When there is too much addition amount, the added photoinitiator tends to work as a plasticizer, and there exists a possibility that the intensity | strength of a hard-coat layer may become low.

(Other additives that may be optionally added)
In the hard coat layer in the present invention, inorganic fine particles, organic fine particles, photosensitizers, leveling agents, plasticizers, ultraviolet absorbers, antioxidants, antistatic agents, pigments, dyes and the like can be added. These may be used in a range that does not inhibit the aspect of the contact angle on the surface of the hard coat layer preferably defined by the present invention.

[Method of forming hard coat layer]
The hard coat film of the present invention is obtained by coating a coating liquid for forming a hard coat layer on the surface on the side on which a hard coat layer on the base film to be described later is formed, drying by heating, and curing. be able to.

  The coating liquid for forming the hard coat layer in the present invention was mixed with a solvent by adding a radiation curable resin, a photopolymerization initiator preferably added, and other additives that may optionally be added. It is a solution. When adding each component, it may be added as a solid such as a powder, or a solid in a form of a solution or a dispersion using an appropriate solvent may be added. The solvent used in the coating liquid for forming the hard coat layer is not particularly limited, but for example, ketones such as methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone, methanol, ethanol, propanol, n-butanol, secondary butanol, isopropyl alcohol Hard coats such as alcohols such as butyl acetate and ethyl acetate, aromatic hydrocarbons such as toluene and xylene, glycol ethers such as propylene glycol monomethyl ether and propylene glycol monomethyl ether acetate, etc. The dispersibility of the coating liquid for forming the layer becomes good, and the appearance of the hard coat layer becomes good. Of these, ketones are preferable from the viewpoint of good solubility, and methyl ethyl ketone and methyl isobutyl ketone are particularly preferable. The solid concentration of the coating liquid for forming the hard coat layer is preferably 1 to 70% by mass, more preferably 10 to 50% by mass. By adopting such an embodiment, defects such as smears are reduced. can do.

As a method for applying the coating liquid for forming the hard coat layer, a method known per se can be employed. For example, the lip direct method, comma coater method, slit reverse method, die coater method, gravure roll coater method, blade coater method, spray coater method, air knife coat method, dip coat method, bar coater method and the like can be preferably mentioned. By these application methods, a coating liquid for forming a hard coat layer is applied on the base film to form a hard coat film, and the obtained hard coat film is heated and dried. As conditions for heat drying, it is preferable to heat at 50 to 150 ° C. for 10 to 180 seconds, more preferably at 50 to 122 ° C. for 22 to 150 seconds, and heating at 50 to 80 ° C. for 30 to 122 seconds. Is particularly preferred. After heat drying, the hard coat film is cured by ultraviolet irradiation or electron beam irradiation. For UV irradiation, the irradiation amount is preferably 10~2200mJ / cm ^2, more preferably 50~1500mJ / cm ^2, particularly preferably a 100~1000mJ / cm ^2.

(Contact angle)
In the present invention, the contact angle of water on the hard coat layer surface is preferably 78 degrees or more and 86 degrees or less, and at the same time, the contact angle of n-dodecane is preferably 22 degrees or less. By setting the wettability on the surface of the hard coat layer within the above numerical range, in the capacitive touch panel, the surface of the hard coat layer and the display surface such as LCD or other material film are bonded together with an adhesive. Excellent adhesion, but also excellent scratch resistance. When the contact angle of water is smaller than 78 degrees, it tends to be difficult to obtain a hard coat film having excellent scratch resistance. Moreover, lipophilicity will fall simultaneously, and the adhesive improvement effect with respect to an adhesive etc. may become low depending on the kind of adhesive. On the other hand, when the water contact angle is larger than 86 degrees, the effect of improving the wettability with respect to the polar solvent becomes extremely low, so that the adhesive processing is difficult or the adhesion with the adhesive layer having a hydrophilic group is improved. The effect tends to be low. Moreover, when the contact angle of n-dodecane exceeds 22 degrees, the lipophilicity tends to be low, and the effect of improving the adhesion with an adhesive or the like tends to be remarkably reduced. From such a viewpoint, the contact angle of water is more preferably 80 ° to 85 °, particularly preferably 82 ° to 85 °, and the contact angle of n-dodecane is 22 ° or less. Is preferred. Here, the contact angle of 22 degrees or less means that the droplets are wet and spread in the contact angle measurement, and the angle cannot be measured.

  In order to achieve the contact angle as described above, for example, the aforementioned (poly) alkylene glycol component-containing radiation curable resin may be used. Examples of such radiation curable resins include KZ6404 (manufactured by JSR Corporation), Lucifar G-004 (manufactured by Nippon Paint Industry), Beam Set 1460 (manufactured by Arakawa Chemical Industries), and the like.

  The inventor has found that such adjustment of the contact angle cannot be achieved by simple addition of independent additives such as surfactants that can adjust wettability. That is, when a surfactant is added, the hydrophilic and hydrophobic groups of the surfactant are mixed on the hard coat layer surface after coating and curing, so that the wettability to water and oil (n-dodecane) At the same time, the wettability with respect to becomes worse. On the other hand, in a general acrylic hard coat layer to which no surfactant is added, the contact angle range of n-dodecane is achieved, but the contact angle range of water is not achieved. In any case, it was confirmed that a normal hard coat layer or a layer to which a surfactant was added could not achieve the preferable contact angle range in the present invention, that is, excellent adhesion could not be obtained.

(Thickness of hard coat layer)
The thickness of the hard coat layer in the present invention is preferably 1 to 10 μm. A thicker hard coat layer tends to have a lower water contact angle, while a thinner hard coat layer tends to have a higher water contact angle. From the viewpoint of facilitating the adjustment of the water contact angle to the range preferably defined by the present invention, the thickness of the hard coat layer is more preferably 1 to 8 μm, and particularly preferably 1 to 6 μm.

  Moreover, when using for a capacitive touch panel, the thickness of the hard coat layer is preferably 1.0 μm or more and 3.0 μm or less. When the thickness of the hard coat layer is in the above numerical range, the contact angle of water is easily adjusted as described above, and the hard coat film tends to be difficult to curl during heating. From such a viewpoint, when used for a capacitive touch panel, the thickness of the hard coat layer is more preferably 1.0 μm or more and 2.2 μm or less.

[Base film]
The base film in this invention is not specifically limited, For example, the sheet | seat or film which consists of a polyethylene terephthalate, a polyethylene naphthalate, a polycarbonate, polyethylene, a polystyrene triacetyl cellulose, an acryl etc. can be mentioned. Of these, a film made of polyethylene terephthalate or polyethylene naphthalate is preferable from the viewpoint of good balance between optical properties such as transparency, mechanical properties, heat resistance, and price.

  The thickness of the base film is not particularly limited, but is preferably 12 μm or more and 300 μm or less, more preferably 25 μm or more and 300 μm or less, and even more preferably 50 μm or more, from the viewpoint of rigidity suitable for a touch panel and good handling properties. It is 220 μm or less, particularly preferably 75 μm or more and 195 μm or less.

  Moreover, when using for a capacitive touch panel, the thickness of the base film is more preferably 12 μm or more and 60 μm or less. When the thickness of the base film is in the above numerical range, the light transmittance tends to be high and the haze tends to be low, and the total thickness of the touch panel as a product can be reduced while maintaining sufficient rigidity. From such a viewpoint, when used for a capacitive touch panel, the thickness of the base film is more preferably 20 μm or more and 55 μm or less.

[Easily adhesive layer]
In the present invention, for the purpose of improving the adhesion between the hard coat layer and the base film, an easy-adhesion layer containing a polyester resin and a crosslinking agent as constituent components is provided between the hard coat layer and the base film. It is preferable. Further, the easy adhesion layer makes it easier to set the contact angle of water and the contact angle of n-dodecane within the ranges preferably defined by the present invention.
Such an easy-adhesion layer contains a polyester resin and a crosslinking agent as constituent components. Hereinafter, each component which comprises an easily bonding layer is demonstrated.

(Polyester resin)
The polyester resin used for the easy-adhesion layer is a polyester obtained from a dicarboxylic acid component and a diol component. Dicarboxylic acid components include terephthalic acid, isophthalic acid, phthalic acid, phthalic anhydride, 2,6-naphthalenedicarboxylic acid, 1,4-cyclohexanedicarboxylic acid, adipic acid, sebacic acid, trimellitic acid, pyromellitic acid, dimer Examples of the acid include 5-sodium sulfoisophthalic acid. Examples of the diol component include ethylene glycol, 1,4-butanediol, diethylene glycol, dipropylene glycol, 1,6-hexanediol, 1,4-cyclohexanedimethanol, xylene glycol, dimethylolpropane, and the like, poly (ethylene oxide) ) Glycol and poly (tetramethylene oxide) glycol.

  As such a polyester resin, it is preferable to use a copolyester using two or more kinds of dicarboxylic acid components and / or two or more kinds of diol components, and is more excellent in adhesiveness. The polyester resin may contain an unsaturated polybasic acid component such as maleic acid and itaconic acid, or a hydroxycarboxylic acid component such as p-hydroxybenzoic acid, as long as it is in a slight amount.

  The glass transition temperature (Tg) of such a polyester resin is preferably 40 to 100 ° C. When Tg is within this range, excellent adhesion and scratch resistance can be obtained. Moreover, it becomes easy to make the contact angle of the hard coat layer surface into the aspect which this invention prescribes | regulates preferably. When the glass transition temperature is less than 40 ° C., the blocking resistance tends to be inferior. On the other hand, when it exceeds 100 ° C., the easy-adhesion layer becomes hard and brittle, and the scratch resistance tends to deteriorate. From such a viewpoint, Tg is more preferably 60 to 80 ° C.

The intrinsic viscosity (IV) of the polyester resin is preferably 0.4 or more and less than 0.7. If IV is in this range, the generation of low molecular weight substances from the polyester resin itself can be suppressed to a higher degree, and the cohesive strength of the polyester resin becomes higher, so that better adhesion and scratch resistance can be obtained. . Moreover, it becomes easy to make the contact angle of the hard coat layer surface into a mode that the present invention preferably prescribes. When the intrinsic viscosity is less than 0.4, a low molecular weight product is easily generated from the polyester resin itself, and the transparency of the substrate is easily deteriorated. From such a viewpoint, IV is more preferably 0.5 or more and less than 0.7.
The polyester resin is preferably soluble or dispersible in water, but water-soluble one containing some organic solvent can also be used.

  The polyester resin can be produced, for example, by the following method. A dicarboxylic acid component and a diol component are charged into a transesterification reactor, a catalyst is added, the temperature is controlled at 230 ° C. under a nitrogen atmosphere, and the produced methanol is distilled off to conduct a transesterification reaction. Next, the temperature is gradually raised to 255 ° C., and the polycondensation reaction is carried out under reduced pressure in the system to obtain a polyester resin. When the molecular weight increases during the polycondensation, the melt viscosity increases and stirring in the system becomes difficult. The polyester resin used in the easy-adhesion layer has a high melt viscosity for a low molecular weight compared to homopolyethylene terephthalate, making stirring in the system very difficult, increasing the torque of the motor of the stirring equipment, and the shape of the blade Intrinsic viscosity can be increased by devising the above and by extending the polymerization time.

  The content of the polyester resin is preferably 50 to 95% by mass, more preferably 60 to 90% by mass, based on the total mass of the easy-adhesion layer. It becomes easy to make it into the numerical range which invention prescribes | regulates preferably.

(Crosslinking agent)
As the crosslinking agent used for the easy adhesion layer, an epoxy crosslinking agent, an oxazoline crosslinking agent, a melamine crosslinking agent and an isocyanate crosslinking agent are preferable, and an oxazoline crosslinking agent is particularly preferable. Blocking resistance can be made high because an easily bonding layer contains a crosslinking agent. Moreover, the strength (cohesive force) of the easy-adhesion layer can be increased, and the adhesiveness is excellent. Furthermore, the contact angle on the surface of the hard coat layer is easily set to an embodiment that the present invention preferably defines. In particular, the oxazoline-based crosslinking agent is preferable because it is easy to handle and the pot life of the coating liquid for forming the easy-adhesion layer is long. In addition, these may use 1 type and may use 2 or more types.

  Examples of the epoxy crosslinking agent include polyepoxy compounds, diepoxy compounds, monoepoxy compounds, and glycidylamine compounds. Here, examples of the polyepoxy compound include sorbitol, polyglycidyl ether, polyglycerol polyglycidyl ether, pentaerythritol polyglycidyl ether, diglycerol polyglycidyl ether, triglycidyl tris (2-hydroxyethyl) isocyanate, glycerol polyglycidyl ether. , Trimethylolpropane polyglycidyl ether, diepoxy compound, for example, neopentyl glycol diglycidyl ether, 1,6-hexanediol diglycidyl ether, resorcin diglycidyl ether, ethylene glycol diglycidyl ether, polyethylene glycol diglycidyl ether, propylene Glycol diglycidyl ether, polypropylene glycol diglycidyl ether Ether, polytetramethylene glycol diglycidyl ether, as a monoepoxy compound, e.g., allyl glycidyl ether, 2-ethylhexyl glycidyl ether, phenyl glycidyl ether. Examples of the glycidylamine compound include N, N, N ′, N ′,-tetraglycidyl-m-xylylenediamine, 1,3-bis (N, N-diglycidylamino) cyclohexane and the like.

  The oxazoline-based crosslinking agent is preferably a polymer containing an oxazoline group. Such a polymer can be prepared by polymerization of an addition polymerizable oxazoline group-containing monomer alone or with another monomer. Addition polymerizable oxazoline group-containing monomers include 2-vinyl-2-oxazoline, 2-vinyl-4-methyl-2-oxazoline, 2-vinyl-5-methyl-2-oxazoline, 2-isopropenyl-2-oxazoline, 2-isopropenyl-4-methyl-2-oxazoline, 2-isopropenyl-5-ethyl-2-oxazoline, and the like can be mentioned, and one or a mixture of two or more thereof can be used. Among these, 2-isopropenyl-2-oxazoline is preferred because it is easily available industrially. The other monomer is not limited as long as it is a monomer copolymerizable with an addition-polymerizable oxazoline group-containing monomer, such as alkyl acrylate, alkyl methacrylate (the alkyl group includes a methyl group, an ethyl group, an n-propyl group, an isopropyl group, (meth) acrylic acid esters such as n-butyl group, isobutyl group, t-butyl group, 2-ethylhexyl group, cyclohexyl group); acrylic acid, methacrylic acid, itaconic acid, maleic acid, fumaric acid, crotonic acid, Unsaturated carboxylic acids such as styrenesulfonic acid and its salts (sodium salt, potassium salt, ammonium salt, tertiary amine salt, etc.); Unsaturated nitriles such as acrylonitrile, methacrylonitrile; acrylamide, methacrylamide, N-alkyl Acrylamide, N-alkyl methacrylate N, N-dialkylacrylamide, N, N-dialkylmethacrylate (alkyl groups include methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, t-butyl, 2-ethylhexyl Groups, cyclohexyl groups, etc.); vinyl esters such as vinyl acetate, vinyl propionate, acrylic acid, methacrylic acid with polyalkylene oxide added to the ester moiety; methyl vinyl ether, ethyl vinyl ether, etc. Vinyl ethers; α-olefins such as ethylene and propylene; Halogen-containing α and β-unsaturated monomers such as vinyl chloride, vinylidene chloride and vinyl fluoride; α and β-unsaturations such as styrene and α-methylstyrene An aromatic monomer etc. can be mentioned, These 1 type or 2 types It may be used monomers above.

  The melamine-based crosslinking agent is preferably a compound obtained by reacting methylol melamine derivative obtained by condensing melamine and formaldehyde with methyl alcohol, ethyl alcohol, isopropyl alcohol or the like as a lower alcohol, and a mixture thereof. Examples of the methylol melamine derivative include monomethylol melamine, dimethylol melamine, trimethylol melamine, tetramethylol melamine, pentamethylol melamine, hexamethylol melamine and the like.

  Isocyanate-based crosslinking agents include, for example, tolylene diisocyanate, diphenylmethane-4,4′-diisocyanate, metaxylylene diisocyanate, hexamethylene-1,6-diisocyanate, 1,6-diisocyanate hexane, tolylene diisocyanate and hexanetriol. Products, adducts of tolylene diisocyanate and trimethylolpropane, polyol-modified diphenylmethane-4,4'-diisocyanate, carbodiimide-modified diphenylmethane-4,4'-diisocyanate, isophorone diisocyanate, 1,5-naphthalene diisocyanate, 3,3'- Bitrilene-4,4 ′ diisocyanate, 3,3′dimethyldiphenylmethane-4,4′-diisocyanate, metaphenylene diisocyanate and the like can be mentioned.

  The content of the crosslinking agent is preferably 0.1 to 35% by mass, more preferably 10 to 30% by mass, based on the total mass of the easy-adhesion layer. When the amount is less than 0.1% by mass, the cohesive force of the easy-adhesion layer may not be exhibited, and the adhesiveness may be insufficient. When the amount is more than 35% by mass, the easy-adhesion layer becomes very hard, stress relaxation is reduced and adhesion is not exhibited, and when a film having the easy-adhesion layer is collected and used, foreign matters due to the crosslinked body tend to be generated. It is in.

(Fine particles)
In the present invention, the easy-adhesion layer preferably contains fine particles.
Examples of the fine particles used in the present invention include calcium carbonate, magnesium carbonate, calcium oxide, zinc oxide, magnesium oxide, silicon oxide, sodium silicate, aluminum hydroxide, iron oxide, zirconium oxide, barium sulfate, titanium oxide, and oxide. Use inorganic fine particles such as tin, antimony trioxide, carbon black, molybdenum disulfide; organic fine particles such as acrylic cross-linked polymer, styrene cross-linked polymer, silicone resin, fluororesin, benzoguanamine resin, phenol resin, nylon resin Can do. One of these may be used, or two or more may be used.

  Such fine particles have an average particle diameter of preferably 22 to 220 nm, more preferably 40 to 122 nm. If the average particle diameter is larger than 220 nm, the particles are likely to fall off, and if it is smaller than 22 nm, sufficient lubricity and scratch resistance may not be obtained.

  As for content of microparticles | fine-particles, 0.1-10 mass% is preferable in the total mass of an easily bonding layer. If it is less than 0.1% by mass, sufficient lubricity and scratch resistance cannot be obtained, and if it exceeds 10% by mass, the cohesive force of the coating film is lowered and the adhesiveness is deteriorated. Moreover, it exists in the tendency for it to become the aspect which this invention prescribes | regulates the contact angle in the hard-coat layer surface preferably.

(Aliphatic wax)
In the present invention, the easily adhesive layer preferably contains an aliphatic wax.
Specific examples of the aliphatic wax include plant-based waxes such as carnauba wax, candelilla wax, rice wax, wood wax, jojoba oil, palm wax, rosin modified wax, cucumber wax, sugar cane wax, esparto wax, and bark wax. Animal waxes such as beeswax, lanolin, whale wax, ibota wax and shellac wax; mineral waxes such as montan wax, ozokerite and ceresin wax; petroleum waxes such as paraffin wax, microcrystalline wax and petrolactam; And synthetic hydrocarbon waxes such as polyethylene wax, oxidized polyethylene wax, polypropylene wax, and oxidized polypropylene wax. Among these, carnauba wax, paraffin wax, and polyethylene wax are particularly preferable because they are excellent in adhesion to the hard coat layer and the base film and have good lubricity. These are preferably used as an aqueous dispersion because of their ability to reduce environmental burden and ease of handling.

  The content of the aliphatic wax is preferably 0.5 to 30% by mass and more preferably 1 to 10% by mass in the total mass of the easy-adhesion layer. If the content is less than 0.5% by mass, the smoothness of the film surface may not be obtained, which is not preferable. When it exceeds 30 mass%, the adhesive improvement effect with respect to the base film or the hard coat layer tends to be low.

[Method of forming easy-adhesion layer]
In the present invention, each of the above-described components is used in the form of a coating liquid (an aqueous coating liquid such as an aqueous solution, an aqueous dispersion or an emulsified liquid. Hereinafter, it may be referred to as a coating liquid) for forming an easy adhesion layer. It is preferred that If necessary, the coating liquid may contain other resins than the above-described components, such as an antistatic agent, a colorant, a surfactant, an ultraviolet absorber, and a crosslinking agent.

  The solid content concentration of the coating liquid used in the present invention is usually preferably 22% by mass or less, and particularly preferably 1 to 10% by mass. If this ratio is less than 1% by mass, the coatability to the substrate film may be insufficient, and if it exceeds 22% by mass, the stability of the coating liquid and the appearance of the easy-adhesive layer may be deteriorated. .

  Application of the coating liquid can be carried out at any stage, but so-called in-line coating, which is carried out during the production process of the base film, is preferred, and further, it is preferably applied to the film before orientation crystallization is completed. . Here, the film before the crystal orientation is completed is an unstretched film, a uniaxially stretched film obtained by stretching the unstretched film in either the longitudinal direction or the transverse direction, and further in two directions, the longitudinal direction and the transverse direction. The film is stretched at a magnification (a biaxially stretched film before it is finally re-stretched in the machine direction or the transverse direction to complete orientation crystallization), and the like. Especially, it is preferable to apply | coat a coating liquid to an unstretched film or a uniaxially stretched film, and to perform longitudinal stretch and / or horizontal stretch and heat setting as it is.

  When applying the coating liquid to the base film, either a corona surface treatment, a flame treatment, a plasma treatment, or other physical treatment is applied to the surface of the base film as a pretreatment for improving the coating property, or the coating liquid is interfaced. It is preferred to add an activator. Such a surfactant improves the function of promoting the wetting of the coating liquid on the film and the stability of the coating liquid. For example, polyoxyethylene-fatty acid ester, sorbitan fatty acid ester, glycerin fatty acid ester, fatty acid metal soap And anionic and nonionic surfactants such as alkyl sulfates, alkyl sulfonates, and alkyl sulfosuccinates. The amount of the surfactant added is preferably 0.01 to 2% by mass in the coating solution.

  As a coating method, any known coating method can be applied. For example, a roll coating method, a gravure coating method, a roll brush method, a spray coating method, an air knife coating method, an impregnation method, a curtain coating method and the like can be used alone or in combination. In addition, a coating film may be formed only on one side of a film as needed, and may be formed on both surfaces.

  The thickness of the easy adhesion layer is preferably 0.01 to 0.3 μm, more preferably 0.02 to 0.25 μm. That is, the coating amount of the coating liquid is such that the thickness of the easy adhesion layer is within the above numerical range. Preferably, the amount is such that If the easy-adhesion layer is too thin, the adhesion tends to be inferior. Conversely, if it is too thick, blocking tends to occur or the haze value tends to increase.

[Protective film]
The protective film in the present invention is obtained by providing an adhesion layer on one side of a base film. Examples of the adhesion layer include an adhesive layer or an adsorption layer described later.
The base film of the protective film in the present invention is not particularly limited, but preferred examples include polyester films such as polyethylene terephthalate, polyolefin films such as polyethylene, polypropylene, and cycloolefin, and triacetyl cellulose films. Among these, polyester film, polyethylene film, and polypropylene film are particularly preferable from the viewpoint of balance between performance such as mechanical properties and cost. Furthermore, a polyester film is most preferable from the viewpoint that fish eyes can be further reduced. Moreover, although the thickness of a base film is not specifically limited, 10-150 micrometers is preferable, More preferably, it is 15-75 micrometers, and it is excellent in the point of handleability, protective property, and lubricity.

  The protective film has an adhesion layer on one side for the purpose of being fixed with an appropriate strength when attached to a hard coat film. An example of such an adhesion layer is an adhesive layer. The material used for the pressure-sensitive adhesive layer is not particularly limited, but acrylic and urethane pressure-sensitive adhesives are preferably exemplified from the viewpoints of optical characteristics and appropriate pressure-sensitive adhesiveness that can be removed again. Further, as the adhesion layer, there is an adsorption layer made of a soft resin. The material used for the adsorption layer is not particularly limited, but an ethylene vinyl alcohol copolymer is preferably exemplified. These adhesion layers may be applied by a method of applying a coating liquid for forming the adhesion layer to the base film, or by a method of melt extrusion at the same time as the formation of the base film, a so-called coextrusion method. Also good.

(Fish eye)
In the laminate of the present invention, the Vickers hardness of the fish eye on the surface on the adhesion layer side of the protective film is required to be 0.70 or less.
In the present invention, the fisheye refers to a defect that occurs as an eyeball-shaped defect on the film surface due to a foreign matter caused by a resin that has become gelled by heat or the like. The fish eye may be caused by a gel-like resin in the base film of the protective film, or may be caused by a gel-like resin in the adhesion layer. In the present invention, the fish eye on the surface on the adhesion layer side includes both those present in the adhesion layer itself and those existing in the base film and projecting until the adhesion layer surface is deformed into a convex shape. .

  When the protective film is bonded to the hard coat film, an adhesion layer of the protective film may be bonded to the hard coat layer. In this case, concave defects on the surface of the hard coat layer can be suppressed by setting the fish eye on the surface of the protective film on the adhesion layer side as described above.

  Moreover, in the hard coat film which has a hard-coat layer on one side, the contact | adherence layer of a protective film may be bonded together on the opposite surface (base film surface) to a hard-coat layer. In this case, the occurrence of the concave defects on the surface of the base film and the convex defects on the surface of the hard coat layer can be suppressed by setting the fish eye on the surface on the adhesion layer side of the protective film as described above. Can do. In other words, when hard fish eyes are present on the adhesion layer side of the protective film, the hard coating is caused by the laminating pressure when the protective film is bonded to the hard coat film or the pressure applied by winding the protective film into a roll after bonding. A protective film is pressed against the film, and a concave defect occurs on the surface of the base film due to the convex portion of the fish eye in the protective film. When the deformation reaches the opposite surface, that is, the surface of the hard coat layer, a convex defect may occur on the surface of the hard coat layer. In particular, the surface of the base film is softer than the surface of the hard coat layer, so that it is easy to cause concave defects due to the fish eye of the protective film, and it is important to suppress such defects.

  As described above, in the present invention, the concave defects on the surface of the base film can be suppressed by setting the hardness of the fish eye on the surface on the adhesion layer side of the protective film within the above numerical range. Moreover, the concave or convex defect on the surface of the hard coat layer can be suppressed. From such a viewpoint, the fish eye is preferably soft, and the Vickers hardness is preferably 0.60 or less, and more preferably 0.50 or less.

  The method for reducing the Vickers hardness of fish eye is not particularly limited, but the following methods can be exemplified. For example, when the adhesion layer is formed by a coating method, the Vickers hardness of fish eyes in the adhesion layer can be lowered. Further, by strengthening the coating liquid for forming the adhesion layer and filtering of the molten resin, the hard gel-like resin can be reduced, and the number of fish eyes having high Vickers hardness can be reduced. In addition, there is a method of selecting a resin that is soft to some extent as a material for the adhesion layer and the base layer.

  By using a laminate in which the protective film as described above is bonded to a hard coat film, such a laminate is subjected to pressure such as a state of being wound in a roll at a certain temperature and humidity. Even if stored, the occurrence of concave or convex defects on the surface of the base film or the hard coat layer can be suppressed, and a suitable hard coat film can be obtained. The hard coat film thus obtained has few defects and can be suitably used for optical applications such as for touch panels, and is particularly suitable for use in capacitive touch panels that require high optical properties. it can.

  Hereinafter, the present invention will be described more specifically with reference to examples. In addition, each evaluation in an Example followed the following method.

(1) Water contact angle Slowly drop 0.2 mL of distilled water from a height of 5 mm onto the surface of the hard coat layer with a syringe and leave it for 30 seconds, then contact angle (tangential line between the hard coat layer surface and the droplet) The angle formed by observing with a CCD camera was measured. The same operation was repeated 5 times, and the average value was used.

(2) Contact angle of n-dodecane It measured like the contact angle of water except having used n-dodecane as a liquid for a measurement. In addition, in the area | region whose contact angle is 22 degrees or less, since the numerical value of a contact angle cannot be calculated | required correctly, it was set as the measured value by the result that a contact angle was 22 degrees or less.

(3) Haze The haze of the hard coat film was measured with a haze meter HCM-2B manufactured by Suga Test Instruments Co., Ltd. based on JIS K7150. The measurement light was incident from the hard coat layer side. The measurement was carried out at arbitrary five locations, and the average value thereof was defined as haze (unit:%).

(4) Measuring method of content of ethylene glycol unit The radiation curable resin was divided into each component by preparative GPC, and the structure comprised by performing pyrolysis GC-MS for each component was identified. Thereafter, each component was quantified from the peak integrated value of ¹ H-NMR, and the content of the (poly) alkylene glycol component was identified.
[Preparation GPC conditions]
Column: JAIGEL-2H x 2 600 x 22 mmI. D. (Nippon Analytical Industry)
Mobile phase solvent: chloroform 3.5 ml / min
[Pyrolysis GC-MS conditions]
Pyrolysis temperature: 600 ° C simple pyrolysis and on-line methylation Pyrolysis methylating agent: tetramethylammonium hydroxide (TMAH)
Column: ZB-1, length 30 m × inner diameter 0.32 mm, film thickness 0.5 μm
GC temperature: 40 ° C. (0 min), 15 ° C./min, 322 ° C. (10 min)
[Quantification by ¹ H-NMR]
Calculation formula: Content = molecular weight × (integral ratio / ¹ H number), normalized so that the sum is 100.
As for pentaerythritol triacrylate and dipentaerythritol pentaacrylate, it was assumed that the area ratio of GPC coincided with the weight ratio, and the integral value (1000) of acrylic groups in ¹ H-NMR was assigned to the ratio.

(5) Thickness of hard coat layer The sample film was cut with a sharp razor, and the thickness of the hard coat layer was measured by observing the obtained cross section with an optical microscope. The measurement was carried out at 10 arbitrary locations, and the average value thereof was taken as the thickness (unit: μm) of the hard coat layer.

(6) Pencil hardness It implemented based on JISK5600.
Evaluation was carried out on the surface of the hard coat layer of the hard coat film.

(7) Evaluation method of fish eye hardness Vickers hardness was measured with a microhardness meter (ENTION 1100a manufactured by Elionix Co., Ltd.) based on JIS Z2244 for the fish eye on the surface on the adhesion layer side of the protective film. The indentation depth was 5 μm. The size of the fish eye is several tens of μm or more, which is sufficiently larger than the diameter of the measurement terminal. At the time of inspection, care was taken to push the center of the fish eye as much as possible. Measurements are made on 30 fisheye points randomly extracted from a 1 m ² sample with a major axis of 20 μm or more and a height of 3 μm or more, or when the height is less than 30 points, and the average value is used for the Vickers hardness of fish eyes. It was. The major axis and height were confirmed with an optical microscope and a laser microscope.

(8) Evaluation of concave defects after peeling the protective film from the laminate The obtained laminate was long under conditions where the speed was 10 m / min, the winding tension was 60 N / m, no touch roll was used and no contact pressure was applied. The roll was wound into a 200 m roll, and the roll was stored for 1 month in an environment of a temperature of 23 ° C. and a relative humidity of 50% RH. Then, the sample was extract | collected at the position of 100 m from the surface layer, the protective film was peeled from the obtained laminated body, and the hard coat film was obtained. The obtained hard coat film is placed on a black examination table with the hard coat layer facing down, and a three-wave fluorescent lamp is irradiated from a distance of 50 cm from above (1200 lux or more) with a concave shape in an area of 1 m ^2. The number of defects (thickness 0.5 mm or more and visible with the naked eye) was counted. When the concave defects are 15 pieces / m ² or less, it is assumed that a sufficient level can be expected as a yield when processed into a touch panel substantially.

(9) Glass transition temperature (Tg)
About 10 mg for resin samples and about 20 mg for film samples (base film) are sealed in an aluminum pan for measurement and attached to a differential scanning calorimeter (DSC) (DuPont Instrument 910 DSC). The temperature was raised to 290 ° C. at a rate of 22 ° C./min, held at 290 ° C. for 3 minutes, then taken out, immediately transferred onto ice and rapidly cooled. The pan was mounted on the DSC again, and the temperature was raised from 25 ° C. to 22 ° C./min, and the glass transition temperature Tg (unit: ° C.) was measured.

(10) Adhesion evaluation of hard coat layer [initial adhesion]
A polyester adhesive tape with a width of 25 mm (No. 31B, manufactured by Nitto Denko Corporation) was adhered to the surface of the hard coat layer with a 500 g load roller, peeled 180 ° using a peeling tester, and the peeling force (unit: g / 25 mm) was measured to evaluate the initial adhesion between the pressure-sensitive adhesive and the hard coat layer. In the initial adhesion evaluation, the initial adhesion evaluation passed when the peel force was 1000 g / 25 mm or more. When the peeling force is in the above numerical range, it indicates that the substrate has sufficient initial adhesion for a capacitive touch panel.
[Adhesion over time]
Similar to the evaluation of initial adhesion, a sample was prepared by sticking an adhesive tape to the surface of the hard coat layer, held for 240 hours under the condition of 60 ° C. × 90% humidity, and thereafter the peel force was measured in the same manner. Then, the adhesiveness with time of the adhesive and the hard coat layer was evaluated. In addition, in the time-dependent adhesion evaluation, the case where the peel force was 1000 g / 25 mm or more was regarded as a time-dependent adhesion evaluation pass. When the peeling force is in the above numerical range, it indicates that the adhesive has sufficient temporal adhesion for a capacitive touch panel.

[Example 1]
[Base film and easy adhesion layer]
As the base film, a 38 μm thick polyethylene terephthalate (PET) film having an easy adhesion layer was used.
Here, an easily bonding layer consists of the following structural components.
Polyester resin: The dicarboxylic acid component is composed of 65 mol% of 2,6-naphthalenedicarboxylic acid / 30 mol% of isophthalic acid / 5 mol% of 5-sodium sulfoisophthalic acid, and the glycol component is composed of 90 mol% of ethylene glycol / 10 mol% of diethylene glycol. ing. Tg = 80 ° C., number average molecular weight Mn 13000.
Crosslinking agent: 30 mol% methyl methacrylate / 2 mol of 2-isopropenyl-2-oxazoline / polyethylene oxide (n = 10) methacrylate 10 mol% / acrylamide 30 mol%. Tg = 50 ° C.
Fine particles: Silica filler (average particle size 100 nm) (manufactured by Nissan Chemical Co., Ltd., trade name: Snowtex ZL)
Aliphatic wax: carnauba wax (manufactured by Chukyo Yushi Co., Ltd., trade name: cellosol 524)
Surfactant: Polyoxyethylene (n = 7) lauryl ether (manufactured by Sanyo Kasei Co., Ltd., trade name: NAROACTY N-70)
These components are mixed so that the weight ratio of solids is polyester resin / crosslinking agent / fine particles / aliphatic wax / surfactant = 65/20/5/5/5, and solidified with ion-exchanged water. It diluted so that it might become 5 mass% of partial concentration, and obtained the coating liquid for forming an easily bonding layer.
The obtained coating liquid was coated in-line on both sides after the longitudinal uniaxial stretching and before the transverse stretching step in the base film manufacturing process (ordinary biaxially stretched PET film manufacturing process), resulting in a thickness of 0. The base film which has an easily bonding layer of 15 micrometers on both surfaces was obtained.

[Adjustment of coating liquid to form hard coat layer]
Radiation curable resin in which 2.9% by mass of repeating ethylene glycol units are copolymerized as a (poly) alkylene glycol component to an acrylic polymer mainly composed of pentaerythritol tri (meth) acrylate, based on the mass of the acrylic polymer. (Product name: Beam set 1460, manufactured by Arakawa Chemical Industries, solid content concentration 90% by mass, containing photopolymerization initiator) is diluted with methyl ethyl ketone (MEK) to form a hard coat layer having a solid content concentration of 40% by mass. A coating liquid was obtained. The (poly) alkylene glycol component was confirmed to be (partially) copolymerized by analysis such as ¹ H-NMR, IR, and GC-MS.

[Coating of hard coat layer]
Using a roll coater, a coating for forming the hard coat layer obtained above so that the film thickness after drying and curing is 1.5 μm on the surface of the base film (the surface of the easy adhesion layer). The solution was uniformly applied and dried at 70 ° C. for 2 minutes. Subsequently, using a UV irradiation device (FusionUV Systems Japan Co., Ltd. product name: Fusion H bulb), UV irradiation was performed under the condition of a light amount of 220 mJ / cm ² to obtain a hard coat film.

[Lamination of protective film]
A protective film (manufactured by Sanei Kaken, PAC3-60T) was bonded to the base film surface side of the obtained hard coat film using a pressure roller so that the adhesion layer was on the base film side.
Table 1 shows the evaluation results of the protective film used in Example 1 and the obtained hard coat film.

[Example 2]
A laminate was obtained in the same manner as in Example 1 except that JA16F (manufactured by Sanei Kaken) was used as the protective film. Each evaluation result is shown in Table 1.

[Example 3]
A laminate was obtained in the same manner as in Example 1 except that JA13K (manufactured by Sanei Kaken) was used as the protective film. Each evaluation result is shown in Table 1.

[Comparative Example 1]
A laminate was obtained in the same manner as in Example 1 except that PAC3-60 (manufactured by Sanei Kaken) was used as the protective film. Each evaluation result is shown in Table 1.

[Comparative Example 2]
A laminate was obtained in the same manner as in Example 1 except that FM-4150B (manufactured by Daio Paper Industries Co., Ltd.) was used as the protective film. Each evaluation result is shown in Table 1.

Claims (8)

  A laminate having a hard coat film having a hard coat layer on at least one side of a base film, and a protective film having an adhesion layer on one side of the base film on at least one side of the hard coat film, the adhesion layer of the protective film A laminate having a fisheye Vickers hardness of 0.70 or less on the side surface.   The laminate according to claim 1, wherein the contact angle of water on the surface of the hard coat layer in the hard coat film is 78 degrees or greater and 86 degrees or less, and the contact angle of n-dodecane is 22 degrees or less.   The laminated body of Claim 1 or 2 which has an easily bonding layer which contains a polyester resin and a crosslinking agent as a structural component between a base film and a hard-coat layer.   The haze of a hard coat film is 1.0% or less, The laminated body of any one of Claims 1-3.   The laminate according to any one of claims 1 to 4, wherein the base film has a thickness of 12 µm to 60 µm.   The laminate according to any one of claims 1 to 5, wherein the hard coat layer has a thickness of 1.0 µm to 3.0 µm.   The laminate according to any one of claims 1 to 6, wherein the hard coat film is for a capacitive touch panel.   The hard coat film obtained by peeling a protective film from the laminated body of any one of Claims 1-7.