JP2012009488A - Method of manufacturing ridge type semiconductor optical element - Google Patents

Method of manufacturing ridge type semiconductor optical element Download PDF

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JP2012009488A
JP2012009488A JP2010141554A JP2010141554A JP2012009488A JP 2012009488 A JP2012009488 A JP 2012009488A JP 2010141554 A JP2010141554 A JP 2010141554A JP 2010141554 A JP2010141554 A JP 2010141554A JP 2012009488 A JP2012009488 A JP 2012009488A
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ridge
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JP5454381B2 (en
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Yusuke Higashi
祐介 東
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Mitsubishi Electric Corp
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Abstract

PROBLEM TO BE SOLVED: To provide a method of manufacturing a ridge type semiconductor optical element capable of preventing variation in width of a lower portion of a ridge.SOLUTION: An active layer 12, a p-type InP layer 14, and a p-type InP layer 16 are sequentially formed on an n-type InP substrate 10. Next, a lower portion 20 of a ridge is formed by dry etching of the p-type InP layer 16. Subsequently, the periphery of the lower portion 20 of the ridge is buried in an InGaAsP layer 22 until the height at which the top surface of the lower portion 20 of the ridge is not covered. Subsequently, a p-type InP layer 24 is formed on the lower portion 20 of the ridge and the InGaAsP layer 22. Next, an upper portion 28 of the ridge is formed on the lower portion 20 of the ridge by dry etching of the p-type InP layer 24 such that the width of the top surface of the upper portion 28 of the ridge is wider than the width of the lower portion 20 of the ridge. Next, the InGaAsP layer 22 is selectively removed with respect to the p-type InP layer 14, the lower portion 20 of the ridge, and the upper portion 28 of the ridge.

Description

本発明は、リッジ上部の上面の幅がリッジ下部の幅よりも広いリッジ型半導体光素子の製造方法に関し、特にリッジ下部の幅のばらつきを抑制することができるリッジ型半導体光素子の製造方法に関する。   The present invention relates to a method for manufacturing a ridge-type semiconductor optical device in which the width of the upper surface of the upper portion of the ridge is wider than the width of the lower portion of the ridge. .

リッジ型半導体光素子において、上面の幅が下面の幅よりも広い逆メサリッジ構造が用いられている(例えば、特許文献1参照)。これにより、リッジ上面の面積を広くできるため、電極とのコンタクト抵抗を低減することができる。また、リッジ下部の幅を狭くできるため、容量低減により高速応答を実現できる。   In the ridge-type semiconductor optical device, an inverted mesa ridge structure in which the width of the upper surface is wider than the width of the lower surface is used (see, for example, Patent Document 1). Thereby, the area of the upper surface of the ridge can be increased, and the contact resistance with the electrode can be reduced. In addition, since the width of the lower portion of the ridge can be narrowed, high-speed response can be realized by reducing the capacitance.

特開平2−199891号公報Japanese Patent Laid-Open No. 2-199891

従来のリッジ型半導体光素子の製造方法では、ウェットエッチングにより逆メサリッジ構造を形成していた。このため、エッチング角度やリッジ高さの製造ばらつきによって、リッジ下部の幅がばらつくという問題があった。   In the conventional method for manufacturing a ridge type semiconductor optical device, an inverted mesa ridge structure is formed by wet etching. For this reason, there is a problem that the width of the lower portion of the ridge varies due to manufacturing variations in the etching angle and the ridge height.

本発明は、上述のような課題を解決するためになされたもので、その目的はリッジ下部の幅のばらつきを抑制することができるリッジ型半導体光素子の製造方法を得るものである。   The present invention has been made to solve the above-described problems, and an object of the present invention is to provide a method for manufacturing a ridge-type semiconductor optical device that can suppress variations in the width of the lower portion of the ridge.

本発明に係るリッジ型半導体光素子の製造方法は、半導体基板上に、活性層、第1の半導体層、第2の半導体層を順に形成する工程と、前記第2の半導体層をドライエッチングしてリッジ下部を形成する工程と、前記リッジ下部の周りを埋め込み層により前記リッジ下部の上面を覆わない高さまで埋め込む工程と、前記リッジ下部及び前記埋め込み層上に第3の半導体層を形成する工程と、前記第3の半導体層をパターニングして前記リッジ下部上にリッジ上部を形成する工程と、前記埋め込み層を前記第1の半導体層、前記リッジ下部及び前記リッジ上部に対して選択的に除去する工程とを備え、前記リッジ上部の上面の幅は前記リッジ下部の幅よりも広く、前記埋め込み層の材料は、前記第1の半導体層、前記リッジ下部及び前記リッジ上部の材料とは異なる。   The method for manufacturing a ridge-type semiconductor optical device according to the present invention includes a step of sequentially forming an active layer, a first semiconductor layer, and a second semiconductor layer on a semiconductor substrate, and dry etching the second semiconductor layer. Forming a lower ridge, embedding the periphery of the lower ridge with a buried layer to a height that does not cover the upper surface of the lower ridge, and forming a third semiconductor layer on the lower ridge and the buried layer. Patterning the third semiconductor layer to form an upper ridge on the lower ridge; and selectively removing the buried layer with respect to the first semiconductor layer, the lower ridge, and the upper ridge. And the width of the upper surface of the upper portion of the ridge is wider than the width of the lower portion of the ridge, and the material of the buried layer is the first semiconductor layer, the lower portion of the ridge, and the ridge. Different from the part of the material.

本発明により、リッジ下部の幅のばらつきを抑制することができる。   According to the present invention, variation in the width of the lower portion of the ridge can be suppressed.

本発明の実施の形態1に係るリッジ型半導体光素子の製造方法を説明するための断面図である。It is sectional drawing for demonstrating the manufacturing method of the ridge type semiconductor optical element which concerns on Embodiment 1 of this invention. 本発明の実施の形態1に係るリッジ型半導体光素子の製造方法を説明するための断面図である。It is sectional drawing for demonstrating the manufacturing method of the ridge type semiconductor optical element which concerns on Embodiment 1 of this invention. 本発明の実施の形態1に係るリッジ型半導体光素子の製造方法を説明するための断面図である。It is sectional drawing for demonstrating the manufacturing method of the ridge type semiconductor optical element which concerns on Embodiment 1 of this invention. 本発明の実施の形態1に係るリッジ型半導体光素子の製造方法を説明するための断面図である。It is sectional drawing for demonstrating the manufacturing method of the ridge type semiconductor optical element which concerns on Embodiment 1 of this invention. 本発明の実施の形態1に係るリッジ型半導体光素子の製造方法を説明するための断面図である。It is sectional drawing for demonstrating the manufacturing method of the ridge type semiconductor optical element which concerns on Embodiment 1 of this invention. 本発明の実施の形態1に係るリッジ型半導体光素子の製造方法を説明するための断面図である。It is sectional drawing for demonstrating the manufacturing method of the ridge type semiconductor optical element which concerns on Embodiment 1 of this invention. 本発明の実施の形態1に係るリッジ型半導体光素子の製造方法を説明するための断面図である。It is sectional drawing for demonstrating the manufacturing method of the ridge type semiconductor optical element which concerns on Embodiment 1 of this invention. 本発明の実施の形態2に係るリッジ型半導体光素子の製造方法を説明するための断面図である。It is sectional drawing for demonstrating the manufacturing method of the ridge type semiconductor optical element which concerns on Embodiment 2 of this invention. 本発明の実施の形態2に係るリッジ型半導体光素子の製造方法を説明するための断面図である。It is sectional drawing for demonstrating the manufacturing method of the ridge type semiconductor optical element which concerns on Embodiment 2 of this invention. 本発明の実施の形態2に係るリッジ型半導体光素子の製造方法を説明するための断面図である。It is sectional drawing for demonstrating the manufacturing method of the ridge type semiconductor optical element which concerns on Embodiment 2 of this invention.

実施の形態1.
本発明の実施の形態1に係るリッジ型半導体光素子の製造方法について図面を参照して説明する。この半導体光素子は、リッジの両サイドが半導体で覆われていないリッジ型半導体レーザである。
Embodiment 1 FIG.
A method for manufacturing a ridge-type semiconductor optical device according to the first embodiment of the present invention will be described with reference to the drawings. This semiconductor optical device is a ridge type semiconductor laser in which both sides of the ridge are not covered with a semiconductor.

まず、図1に示すように、n型InP基板10上に、活性層12、p型InP層14、p型InP層16を順に形成する。そして、フォトリソグラフィ等によりp型InP層16上にレジストパターン18を形成する。   First, as shown in FIG. 1, an active layer 12, a p-type InP layer 14, and a p-type InP layer 16 are sequentially formed on an n-type InP substrate 10. Then, a resist pattern 18 is formed on the p-type InP layer 16 by photolithography or the like.

次に、図2に示すように、レジストパターン18をマスクとしてp型InP層16をドライエッチングしてリッジ下部20を形成する。リッジ下部20は、上面の幅と下面の幅が等しい垂直リッジ構造である。   Next, as shown in FIG. 2, the p-type InP layer 16 is dry-etched using the resist pattern 18 as a mask to form a ridge lower portion 20. The ridge lower portion 20 has a vertical ridge structure in which the width of the upper surface is equal to the width of the lower surface.

次に、図3に示すように、リッジ下部20の周りをInGaAsP層22によりリッジ下部20の上面を覆わない高さまで埋め込む。その後、レジストパターン18を除去する。   Next, as shown in FIG. 3, the periphery of the ridge lower portion 20 is buried with an InGaAsP layer 22 to a height that does not cover the upper surface of the ridge lower portion 20. Thereafter, the resist pattern 18 is removed.

次に、図4に示すように、リッジ下部20及びInGaAsP層22上にp型InP層24を形成する。そして、フォトリソグラフィ等によりp型InP層24上にレジストパターン26を形成する。   Next, as shown in FIG. 4, a p-type InP layer 24 is formed on the ridge lower portion 20 and the InGaAsP layer 22. Then, a resist pattern 26 is formed on the p-type InP layer 24 by photolithography or the like.

次に、図5に示すように、レジストパターン26をマスクとしてp型InP層24をドライエッチングしてリッジ下部20上にリッジ上部28を形成する。ここで、リッジ上部28の上面の幅がリッジ下部20の幅よりも広くなるようにする。   Next, as shown in FIG. 5, the p-type InP layer 24 is dry-etched using the resist pattern 26 as a mask to form an upper ridge 28 on the lower ridge 20. Here, the width of the upper surface of the ridge upper portion 28 is made wider than the width of the ridge lower portion 20.

次に、図6に示すように、レジストパターン26を除去する。そして、酒石酸を用いたウェットエッチングにより、InGaAsP層22をp型InP層14、リッジ下部20及びリッジ上部28に対して選択的に除去する。   Next, as shown in FIG. 6, the resist pattern 26 is removed. Then, the InGaAsP layer 22 is selectively removed from the p-type InP layer 14, the ridge lower portion 20, and the ridge upper portion 28 by wet etching using tartaric acid.

次に、図7に示すように、リッジ下部20及びリッジ上部28の側面とp型InP層14の上面を絶縁膜30で覆う。リッジ上部28の上面において絶縁膜30に開口を形成する。リッジ上部28上にp電極32を形成し、n型InP基板10の下面にn電極34を形成する。以上の工程により、実施の形態1に係るリッジ型半導体光素子が製造される。   Next, as shown in FIG. 7, the side surfaces of the ridge lower portion 20 and the ridge upper portion 28 and the upper surface of the p-type InP layer 14 are covered with an insulating film 30. An opening is formed in the insulating film 30 on the upper surface of the ridge upper portion 28. A p-electrode 32 is formed on the ridge upper portion 28, and an n-electrode 34 is formed on the lower surface of the n-type InP substrate 10. The ridge type semiconductor optical device according to the first embodiment is manufactured through the above steps.

本実施の形態により、リッジ上部28の上面の面積を広くできるため、リッジ上部28とp電極32とのコンタクト抵抗を低減することができる。さらに、リッジ下部20の幅を狭くできるため、容量低減により高速応答を実現できる。   According to the present embodiment, since the area of the upper surface of the ridge upper portion 28 can be increased, the contact resistance between the ridge upper portion 28 and the p-electrode 32 can be reduced. Furthermore, since the width of the ridge lower part 20 can be narrowed, a high-speed response can be realized by reducing the capacity.

また、リッジ下部20をドライエッチングで形成することで、エッチング角度やリッジ高さの製造ばらつきに関わらず、リッジ下部20の幅のばらつきを抑制することができる。   Further, by forming the ridge lower portion 20 by dry etching, it is possible to suppress the variation in the width of the ridge lower portion 20 regardless of the manufacturing variation in the etching angle and the ridge height.

実施の形態2.
本発明の実施の形態2に係るリッジ型半導体光素子の製造方法について図面を参照して説明する。実施の形態1と同様の構成要素には同じ符号を付し、説明の繰り返しを省略する場合がある。
Embodiment 2. FIG.
A method for manufacturing a ridge-type semiconductor optical device according to the second embodiment of the present invention will be described with reference to the drawings. Constituent elements similar to those in Embodiment 1 are denoted by the same reference numerals, and repeated description may be omitted.

まず、実施の形態1と同様に図1から図4に示す工程を行う。次に、図8に示すように、レジストパターン26をマスクとしてp型InP層24をHBrによりウェットエッチングしてリッジ下部20上にリッジ上部28を形成する。   First, similarly to the first embodiment, the steps shown in FIGS. 1 to 4 are performed. Next, as shown in FIG. 8, the p-type InP layer 24 is wet-etched with HBr using the resist pattern 26 as a mask to form an upper ridge 28 on the lower ridge 20.

ここで、リッジ上部28の上面の幅がリッジ下部20の幅よりも広くなるようにする。また、リッジ上部28が、上面の幅が下面の幅よりも広い逆メサリッジ構造となるようにする。   Here, the width of the upper surface of the ridge upper portion 28 is made wider than the width of the ridge lower portion 20. Further, the ridge upper portion 28 has a reverse mesa ridge structure in which the upper surface is wider than the lower surface.

次に、図9に示すように、レジストパターン26を除去する。そして、酒石酸を用いたウェットエッチングにより、InGaAsP層22をp型InP層14、リッジ下部20及びリッジ上部28に対して選択的に除去する。   Next, as shown in FIG. 9, the resist pattern 26 is removed. Then, the InGaAsP layer 22 is selectively removed from the p-type InP layer 14, the ridge lower portion 20, and the ridge upper portion 28 by wet etching using tartaric acid.

次に、図10に示すように、リッジ下部20及びリッジ上部28の側面とp型InP層14の上面を絶縁膜30で覆う。リッジ上部28の上面において絶縁膜30に開口を形成する。リッジ上部28上にp電極32を形成し、n型InP基板10の下面にn電極34を形成する。以上の工程により、実施の形態2に係るリッジ型半導体光素子が製造される。   Next, as shown in FIG. 10, the side surfaces of the ridge lower portion 20 and the ridge upper portion 28 and the upper surface of the p-type InP layer 14 are covered with an insulating film 30. An opening is formed in the insulating film 30 on the upper surface of the ridge upper portion 28. A p-electrode 32 is formed on the ridge upper portion 28, and an n-electrode 34 is formed on the lower surface of the n-type InP substrate 10. The ridge type semiconductor optical device according to the second embodiment is manufactured through the above steps.

本実施の形態では、p型InP層24をウェットエッチングして、逆メサリッジ構造のリッジ上部28を形成する。これにより、実施の形態1よりもリッジ下部20及びリッジ上部28の側面に絶縁膜30が付着し易いため、絶縁膜30の剥離を防ぐことができる。その他、実施の形態1と同様の効果も得ることができる。   In this embodiment, the p-type InP layer 24 is wet-etched to form the ridge upper portion 28 having a reverse mesa ridge structure. Thereby, since the insulating film 30 is more likely to adhere to the side surfaces of the ridge lower portion 20 and the ridge upper portion 28 than in the first embodiment, it is possible to prevent the insulating film 30 from being peeled off. In addition, the same effects as those of the first embodiment can be obtained.

10 n型InP基板(半導体基板)
12 活性層
14 p型InP層(第1の半導体層)
16 p型InP層(第2の半導体層)
20 リッジ下部
22 InGaAsP層(埋め込み層)
24 p型InP層(第3の半導体層)
28 リッジ上部
30 絶縁膜
10 n-type InP substrate (semiconductor substrate)
12 Active layer 14 p-type InP layer (first semiconductor layer)
16 p-type InP layer (second semiconductor layer)
20 Lower ridge 22 InGaAsP layer (buried layer)
24 p-type InP layer (third semiconductor layer)
28 Ridge upper portion 30 Insulating film

Claims (4)

半導体基板上に、活性層、第1の半導体層、第2の半導体層を順に形成する工程と、
前記第2の半導体層をドライエッチングしてリッジ下部を形成する工程と、
前記リッジ下部の周りを埋め込み層により前記リッジ下部の上面を覆わない高さまで埋め込む工程と、
前記リッジ下部及び前記埋め込み層上に第3の半導体層を形成する工程と、
前記第3の半導体層をパターニングして前記リッジ下部上にリッジ上部を形成する工程と、
前記埋め込み層を前記第1の半導体層、前記リッジ下部及び前記リッジ上部に対して選択的に除去する工程とを備え、
前記リッジ上部の上面の幅は前記リッジ下部の幅よりも広く、
前記埋め込み層の材料は、前記第1の半導体層、前記リッジ下部及び前記リッジ上部の材料とは異なることを特徴とするリッジ型半導体光素子の製造方法。
Forming an active layer, a first semiconductor layer, and a second semiconductor layer in this order on a semiconductor substrate;
Forming a lower ridge by dry etching the second semiconductor layer;
Embedding the periphery of the lower portion of the ridge to a height that does not cover the upper surface of the lower portion of the ridge with a buried layer;
Forming a third semiconductor layer below the ridge and on the buried layer;
Patterning the third semiconductor layer to form an upper ridge on the lower ridge;
Selectively removing the buried layer with respect to the first semiconductor layer, the ridge lower part and the ridge upper part,
The width of the upper surface of the ridge upper part is wider than the width of the ridge lower part,
The method of manufacturing a ridge-type semiconductor optical device, wherein a material of the buried layer is different from materials of the first semiconductor layer, the lower portion of the ridge, and the upper portion of the ridge.
前記リッジ下部は、上面の幅と下面の幅が等しい垂直リッジ構造であることを特徴とする請求項1に記載のリッジ型半導体光素子の製造方法。   2. The method of manufacturing a ridge type semiconductor optical device according to claim 1, wherein the lower portion of the ridge has a vertical ridge structure in which the width of the upper surface is equal to the width of the lower surface. 前記リッジ下部及び前記リッジ上部の側面を覆う絶縁膜を更に備え、
前記リッジ上部を形成する際に前記第3の半導体層をウェットエッチングし、
前記リッジ上部は、上面の幅が下面の幅よりも広い逆メサリッジ構造であることを特徴とする請求項1又は2に記載のリッジ型半導体光素子の製造方法。
An insulating film covering the ridge lower part and the side surface of the ridge upper part;
Wet etching the third semiconductor layer when forming the ridge top;
3. The method of manufacturing a ridge-type semiconductor optical device according to claim 1, wherein the upper portion of the ridge has an inverted mesa ridge structure in which the width of the upper surface is wider than the width of the lower surface.
前記埋め込み層の材料はInGaAsPであり、
前記第1の半導体層、前記リッジ下部及び前記リッジ上部の材料はInPであり、
前記埋め込み層を除去する際に、酒石酸を用いたウェットエッチングを行うことを特徴とする請求項1〜3の何れか1項に記載のリッジ型半導体光素子の製造方法。
The material of the buried layer is InGaAsP,
The material of the first semiconductor layer, the ridge lower part and the ridge upper part is InP,
The method for manufacturing a ridge-type semiconductor optical device according to claim 1, wherein wet etching using tartaric acid is performed when the buried layer is removed.
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JPWO2020183812A1 (en) * 2019-03-11 2021-11-25 ローム株式会社 Semiconductor light emitting device
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