JP2011516383A5 - - Google Patents
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- Publication number
- JP2011516383A5 JP2011516383A5 JP2011502411A JP2011502411A JP2011516383A5 JP 2011516383 A5 JP2011516383 A5 JP 2011516383A5 JP 2011502411 A JP2011502411 A JP 2011502411A JP 2011502411 A JP2011502411 A JP 2011502411A JP 2011516383 A5 JP2011516383 A5 JP 2011516383A5
- Authority
- JP
- Japan
- Prior art keywords
- mesostructured
- zeolite
- material according
- droplets
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000010457 zeolite Substances 0.000 claims description 116
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 115
- 239000000463 material Substances 0.000 claims description 107
- 229910021536 Zeolite Inorganic materials 0.000 claims description 102
- 238000002360 preparation method Methods 0.000 claims description 72
- 239000002243 precursor Substances 0.000 claims description 43
- 239000002159 nanocrystal Substances 0.000 claims description 40
- 238000000034 method Methods 0.000 claims description 38
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 35
- 239000004094 surface-active agent Substances 0.000 claims description 32
- 239000000725 suspension Substances 0.000 claims description 29
- 239000011159 matrix material Substances 0.000 claims description 27
- 239000012798 spherical particle Substances 0.000 claims description 27
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 24
- 239000007921 spray Substances 0.000 claims description 19
- 239000000377 silicon dioxide Substances 0.000 claims description 17
- 238000005507 spraying Methods 0.000 claims description 17
- 239000000443 aerosol Substances 0.000 claims description 16
- 238000001035 drying Methods 0.000 claims description 16
- FGUUSXIOTUKUDN-IBGZPJMESA-N C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 Chemical compound C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 FGUUSXIOTUKUDN-IBGZPJMESA-N 0.000 claims description 14
- 238000002156 mixing Methods 0.000 claims description 13
- 239000012265 solid product Substances 0.000 claims description 13
- 239000007788 liquid Substances 0.000 claims description 10
- 239000011148 porous material Substances 0.000 claims description 10
- 239000013078 crystal Substances 0.000 claims description 8
- 239000000470 constituent Substances 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- 230000003098 cholesteric effect Effects 0.000 claims description 2
- 230000002194 synthesizing effect Effects 0.000 claims description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 3
- 230000002051 biphasic effect Effects 0.000 claims 1
- 229910052814 silicon oxide Inorganic materials 0.000 claims 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 14
- 239000000203 mixture Substances 0.000 description 12
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- 239000002904 solvent Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- GNFTZDOKVXKIBK-UHFFFAOYSA-N 3-(2-methoxyethoxy)benzohydrazide Chemical compound COCCOC1=CC=CC(C(=O)NN)=C1 GNFTZDOKVXKIBK-UHFFFAOYSA-N 0.000 description 5
- 238000001988 small-angle X-ray diffraction Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000007787 solid Substances 0.000 description 4
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229920001400 block copolymer Polymers 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 239000012013 faujasite Substances 0.000 description 3
- 229910001657 ferrierite group Inorganic materials 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 238000009616 inductively coupled plasma Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052680 mordenite Inorganic materials 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 238000006482 condensation reaction Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- LPSKDVINWQNWFE-UHFFFAOYSA-M tetrapropylazanium;hydroxide Chemical compound [OH-].CCC[N+](CCC)(CCC)CCC LPSKDVINWQNWFE-UHFFFAOYSA-M 0.000 description 2
- 238000004448 titration Methods 0.000 description 2
- 238000004627 transmission electron microscopy Methods 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- -1 aluminum alkoxide Chemical class 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000004993 emission spectroscopy Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000000802 evaporation-induced self-assembly Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 238000002354 inductively-coupled plasma atomic emission spectroscopy Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- 238000001338 self-assembly Methods 0.000 description 1
- 238000001330 spinodal decomposition reaction Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- WOZZOSDBXABUFO-UHFFFAOYSA-N tri(butan-2-yloxy)alumane Chemical compound [Al+3].CCC(C)[O-].CCC(C)[O-].CCC(C)[O-] WOZZOSDBXABUFO-UHFFFAOYSA-N 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000004736 wide-angle X-ray diffraction Methods 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR08/01764 | 2008-03-31 | ||
| FR0801764A FR2929266B1 (fr) | 2008-03-31 | 2008-03-31 | Materiau mesostructure a forte teneur en aluminium et constitue de particules spheriques de taille specifique |
| PCT/FR2009/000210 WO2009122023A2 (fr) | 2008-03-31 | 2009-02-26 | Materiau mesostructure a forte teneur en aluminium et constitue de particules spheriques de taille specifique |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2011516383A JP2011516383A (ja) | 2011-05-26 |
| JP2011516383A5 true JP2011516383A5 (enExample) | 2012-04-12 |
| JP5586578B2 JP5586578B2 (ja) | 2014-09-10 |
Family
ID=40083591
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011502411A Active JP5586578B2 (ja) | 2008-03-31 | 2009-02-26 | アルミニウム含有量が多くかつ特定のサイズの球状粒子からなるメソ構造化材料 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8568882B2 (enExample) |
| EP (1) | EP2274236B1 (enExample) |
| JP (1) | JP5586578B2 (enExample) |
| CN (2) | CN102046532A (enExample) |
| DK (1) | DK2274236T3 (enExample) |
| FR (1) | FR2929266B1 (enExample) |
| WO (1) | WO2009122023A2 (enExample) |
| ZA (1) | ZA201006509B (enExample) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2929264B1 (fr) * | 2008-03-31 | 2010-03-19 | Inst Francais Du Petrole | Materiau inorganique forme de particules spheriques de taille specifique et presentant des nanoparticules metalliques piegees dans une matrice mesostructuree |
| JP2011201724A (ja) * | 2010-03-25 | 2011-10-13 | Neive:Kk | 多孔質アルミナ焼結体及びその製造方法 |
| FR3029835B1 (fr) * | 2014-12-15 | 2019-06-28 | Airbus Group | Revetements anticorrosion charges en particules mesostructurees |
| JP6896095B2 (ja) * | 2017-03-29 | 2021-06-30 | エクソンモービル ケミカル パテンツ インコーポレイテッド | 触媒組成物及び芳香族アルキル化プロセスにおけるそれらの使用 |
| KR102315173B1 (ko) * | 2017-03-29 | 2021-10-20 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 탄화수소 스트림으로부터 불순물을 제거하는 방법 및 방향족 알킬화 공정에서의 이의 용도 |
| US12025544B2 (en) * | 2018-02-07 | 2024-07-02 | Osaka University | Droplet particle, and method and device for producing droplet particle |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5622684A (en) | 1995-06-06 | 1997-04-22 | Board Of Trustees Operating Michigan State University | Porous inorganic oxide materials prepared by non-ionic surfactant templating route |
| ATE275600T1 (de) | 1997-12-09 | 2004-09-15 | Sba Materials Inc | Blockcopolymerverarbeitung für mesostrukturierte anorganische oxidmaterialien |
| AU1684101A (en) | 1999-11-23 | 2001-06-04 | Universite Laval | Mesoporous zeolitic material with microporous crystalline mesopore walls |
| US6387453B1 (en) | 2000-03-02 | 2002-05-14 | Sandia Corporation | Method for making surfactant-templated thin films |
| CN1227157C (zh) * | 2001-09-25 | 2005-11-16 | 三菱化学株式会社 | 硅石 |
| FR2872151B1 (fr) * | 2004-06-24 | 2007-06-29 | Inst Francais Du Petrole | Materiau aluminosilicate mesostructure |
| JP2006069864A (ja) * | 2004-09-03 | 2006-03-16 | National Institute Of Advanced Industrial & Technology | ナノポーラス体及びその製造方法 |
| EP1866250A1 (en) * | 2005-04-05 | 2007-12-19 | University College Cork-National University of Ireland, Cork | Mesoporous particles |
| FR2886637B1 (fr) * | 2005-06-02 | 2007-08-03 | Inst Francais Du Petrole | Materiau mesostructure a forte teneur en aluminium |
-
2008
- 2008-03-31 FR FR0801764A patent/FR2929266B1/fr not_active Expired - Fee Related
-
2009
- 2009-02-26 CN CN2009801201306A patent/CN102046532A/zh active Pending
- 2009-02-26 CN CN201510834034.5A patent/CN105460947A/zh active Pending
- 2009-02-26 WO PCT/FR2009/000210 patent/WO2009122023A2/fr not_active Ceased
- 2009-02-26 US US12/935,334 patent/US8568882B2/en not_active Expired - Fee Related
- 2009-02-26 EP EP09727588A patent/EP2274236B1/fr active Active
- 2009-02-26 JP JP2011502411A patent/JP5586578B2/ja active Active
- 2009-02-26 DK DK09727588.7T patent/DK2274236T3/da active
-
2010
- 2010-09-10 ZA ZA2010/06509A patent/ZA201006509B/en unknown
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