JP2011219903A - Fabric material for producing thermocompression-bonded mark - Google Patents

Fabric material for producing thermocompression-bonded mark Download PDF

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JP2011219903A
JP2011219903A JP2010092958A JP2010092958A JP2011219903A JP 2011219903 A JP2011219903 A JP 2011219903A JP 2010092958 A JP2010092958 A JP 2010092958A JP 2010092958 A JP2010092958 A JP 2010092958A JP 2011219903 A JP2011219903 A JP 2011219903A
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fabric
mark
transfer
adhesive layer
synthetic resin
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Kazuhiko Azumaguchi
一彦 東口
Shigeji Azumaguchi
繁二 東口
Shinichi Nagai
伸一 永井
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Hariron Int Ltd
HARIRON INTERNATIONAL Ltd
Houlaisha Co Ltd
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Hariron Int Ltd
HARIRON INTERNATIONAL Ltd
Houlaisha Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide a fabric material for producing a mark by transferring a design or a pattern printed on a transfer paper with a sublimation dye.SOLUTION: A fabric material for producing a mark comprises a white fabric including a constituent having affinity for a sublimation dye, an ultrathin film formed on the fabric by impregnating the exposed spinning surface on the backside of the fabric with a thermoplastic synthetic resin having a melting point higher than the sublimation temperature of the sublimation dye, and an adhesion layer of peeling material for thermal transfer formed on the ultrathin film.

Description

本発明は、昇華性染料によって所望の色彩、模様、図柄等の印刷を施した転写紙を以て、該転写紙に印刷された所望の色彩、模様、図柄等の転写を可能とした熱圧着型マークを作るためのマーク用生地材料を提供しようとするものである。 The present invention relates to a thermocompression bonding mark that enables transfer of a desired color, pattern, pattern, etc. printed on the transfer paper, using a transfer paper on which a desired color, pattern, pattern, etc. has been printed with a sublimation dye. It is intended to provide a dough material for marks for making.

従来からのありふれた熱圧着型マークの構成は、所望の色彩、模様、図柄等を印刷した織物、編み物、不織布等の布地をマーク地1とし、前記マーク地1の裏面にホットメルト性の熱可塑性合成樹脂から成るいわゆる転写接着層2を形成し、これを剥離紙3で裏打ちして図3に示す構成のマーク用生地4としていた。 The conventional thermocompression-bonding mark has a configuration in which a fabric such as a woven fabric, a knitted fabric, or a nonwoven fabric printed with a desired color, pattern, pattern, or the like is used as a mark fabric 1, and a hot-melt heat is applied to the back surface of the mark fabric 1. A so-called transfer adhesive layer 2 made of a plastic synthetic resin was formed, and this was lined with release paper 3 to form a mark fabric 4 having the configuration shown in FIG.

そして、前記したマーク用生地4から熱圧着型マーク5を作るのには、前記マーク用生地4を所望の形状に裁断して、所望の色彩、模様、図柄から成る熱圧着型マーク5としていた。
従って、従来の熱圧着型マークの構成は、図4に示すとおりマーク地1の裏に転写接着層2を形成し、これを剥離紙3で裏打ちした構成となる。
And in order to make the thermocompression bonding type mark 5 from the above-mentioned mark cloth 4, the mark cloth 4 is cut into a desired shape to form a thermocompression bonding mark 5 having a desired color, pattern and design. .
Therefore, the structure of the conventional thermocompression-bonding type mark is a structure in which the transfer adhesive layer 2 is formed on the back of the mark ground 1 as shown in FIG.

前記熱圧着型マーク5を以てユニホーム等に貼着するには、熱圧着型マーク5のマーク用生地4の構成材である転写接着層2に裏打ちした剥離紙3を取り除き、熱圧着型マーク5の転写接着層2をユニホーム等の生地面(図示しない)に重ね合わせ、加熱プレス機等で約150℃程度の温度条件下で約30秒間、約200g/平方センチメートル程度の圧力をかけて前記マーク5の転写接着層2をユニホーム等の生地とマーク地4の間で溶融して転写接着層2の溶融成分をマーク地1とユニホーム等の生地の両者に滲み込ませ、これが冷却したときは、両者に滲み込んだ前記溶融成分に投錨機能を働かせて両者を貼着すると言うものである。 In order to attach the thermocompression bonding mark 5 to a uniform or the like, the release paper 3 backing the transfer adhesive layer 2 which is a constituent material of the mark fabric 4 of the thermocompression bonding mark 5 is removed, and the thermocompression bonding mark 5 The transfer adhesive layer 2 is overlaid on a fabric surface (not shown) such as a uniform, and a pressure of about 200 g / square centimeter is applied for about 30 seconds under a temperature condition of about 150 ° C. with a heating press or the like. When the transfer adhesive layer 2 is melted between the fabric such as uniform and the mark ground 4 so that the molten component of the transfer adhesive layer 2 penetrates both the mark ground 1 and the fabric such as uniform, It is said that a throwing function is applied to the soaked molten component to paste them together.

ところで、昇華性染料によって色彩、模様、図柄等を印刷した転写紙の開発が進み、現在では、前記した転写紙を使って図5に示す構成の布地から成るマーク用生地を作る技術が普及されるようになった。
この技術とは昇華性染料によって印刷した転写紙を以て転写対象物である布地に、これまでの転写紙による転写手段と同じように、転写対象物である布地面に転写紙の印刷面を重ね合わせて所定の温度、圧力で加熱押圧することにより、転写紙に印刷された昇華性染料の染料成分を昇華させて、昇華性染料により印刷された色彩、模様、図柄等通りの色彩、模様、図柄等を転写対象物である布地に転写する技術である。
By the way, development of transfer paper on which colors, patterns, designs, etc. are printed with sublimation dyes has progressed, and at present, a technique for making a mark fabric made of the fabric shown in FIG. It became so.
With this technology, the transfer paper printed with a sublimation dye is used to superimpose the transfer paper print surface on the fabric ground, which is the transfer target, on the fabric that is the transfer target. By heating and pressing at a predetermined temperature and pressure, the dye component of the sublimation dye printed on the transfer paper is sublimated, and the color, pattern, pattern, etc. as printed with the sublimation dye This is a technology for transferring the image to the fabric that is the transfer object.

前記した転写紙を使って図5に示す構成のマーク用生地を作るため、マーク地6としては、前記した転写紙に色彩、模様、図柄等として印刷された昇華染料の染料成分が昇華して転写するのに親しみのあるポリエステル繊維から成る白地の織物、編物、不織布等の布地を使用する。図5に示す構成のマーク用生地11を作るための手順には、第1の作業として前記したマーク地6裏に、仮接着剤7’が塗布された不織布7の仮接着剤7’を塗布した面を重ね合わせて、加熱プレス機で加熱プレスを行って、前記不織布7を以て裏打ちした複合生地8を作る。第2の作業として、この複合生地8の白地のマーク地6の表面に前記した転写紙の印刷面を押し当て加熱プレス機等で加熱プレスを行い、転写紙に昇華性染料を以て印刷された色彩、模様、図柄等の昇華染料を昇華させて前記白地の布地から成るマーク地6面に昇華した染料から成る色彩、模様、図柄を転写する。
この着色、模様、図柄等の転写を行うときの加熱プレス条件は、加熱温度は約200℃、加圧力は約300g/平方センチメートル、加熱押圧時間は約60秒とされている。
In order to make the mark fabric having the configuration shown in FIG. 5 using the transfer paper described above, as the mark place 6, the dye component of the sublimation dye printed on the transfer paper as a color, pattern, pattern, etc. is sublimated. White fabrics such as woven fabrics, knitted fabrics and nonwoven fabrics made of polyester fibers that are familiar to transfer are used. In the procedure for making the mark fabric 11 having the configuration shown in FIG. 5, the temporary adhesive 7 ′ of the nonwoven fabric 7 coated with the temporary adhesive 7 ′ is applied to the back of the mark base 6 as a first operation. The composite surfaces 8 lined with the non-woven fabric 7 are made by superimposing these surfaces and performing a heat press with a heat press. As a second operation, the printed surface of the transfer paper is pressed against the surface of the white mark ground 6 of the composite fabric 8 and heated with a heating press or the like, and the color printed on the transfer paper with a sublimation dye is used. Sublimation dyes such as patterns, designs, etc. are sublimated to transfer the colors, patterns, designs made of the dyes sublimated onto the 6 mark surfaces made of the white fabric.
The heating press conditions for transferring the coloring, pattern, pattern, etc. are as follows: the heating temperature is about 200 ° C., the applied pressure is about 300 g / square centimeter, and the heating press time is about 60 seconds.

この第2の操作を終えた前記複合生地8の不織布7面に、第3の作業として常法に従って、ユニホーム等の被転写物にマークを転着する機能を果たすホットメルト系の熱可塑性合成樹脂を以て転写接着層9を形成し、その転写接着層9の面に剥離紙10を貼着して図5に示す構成のマーク用生地11とすると言うものである。
ところで、この転写接着層9は、図3に図示する従来のマーク用生地を作る転写接着層2と同じように融点温度を通常約150℃に調節され、加熱加圧時間を通常約30秒とされ、加圧力を約200g/平方センチメートルとされるよう調節されたものである。
上記した手段で作られたマーク用生地11から、熱圧着型マークを作るのには、上記したマーク用生地11から所望の形状に裁断して図6に図示するような熱圧着型マーク12とする。
A hot-melt thermoplastic synthetic resin that performs the function of transferring a mark to a transfer object such as a uniform on the surface of the nonwoven fabric 7 of the composite fabric 8 after the second operation according to a conventional method as a third operation. Thus, the transfer adhesive layer 9 is formed, and the release paper 10 is adhered to the surface of the transfer adhesive layer 9 to obtain the mark fabric 11 having the configuration shown in FIG.
By the way, the transfer adhesive layer 9 is adjusted to a melting point temperature of about 150 ° C. in the same manner as the transfer adhesive layer 2 for producing the conventional mark fabric shown in FIG. The applied pressure is adjusted to about 200 g / square centimeter.
In order to make a thermocompression bonding mark from the mark fabric 11 made by the above-mentioned means, a thermocompression bonding mark 12 as shown in FIG. To do.

従って、従来の手順を変えてまずポリエステル繊維から成る白地の織物、編物、不織布等から選んだ布地をマーク地6とし、このマーク地6に仮接着剤7’を塗布した不織布7で裏打ちした複合生地8とし、次にこの複合生地8の裏面に転写接着層9を形成して、まずマーク用生地材料を作り、後に、このマーク用生地材料の構成材である該複合生地8のマーク地6となる布地に前記転写紙を用いて昇華性染料による色彩、模様、図柄等を転写したマーク用生地11を作ろうとしても従来の手順を変えて作ったマーク用生地材料に、前記転写紙を用いた転写を行って前記転写紙の昇華性染料を転写したマーク用生地材料を作ることはできない。
なぜなら、前記マーク用生地材料の前記マーク地6に転写紙に印刷された昇華性染料を昇華させて、前記マーク用生地材料を構成するマーク地6に着色、模様、図柄を転写させる温度と、マーク用生地材料に形成された転写接着層9の融点温度は異なるだけでなくプレス圧力、プレス時間等の差によって転写紙からの着色、模様、図柄の転写操作中に転写接着層9の溶融が先行し、転写接着層9の溶融樹脂が、複合生地8を構成する不織布7を通してマーク地6の表面に滲み出してしまい、マーク地6面に前記溶融樹脂による被膜ができることで昇華転写不良が生じてしまうからである。
Therefore, a composite selected by changing the conventional procedure and first selecting a fabric selected from white woven fabric, knitted fabric, non-woven fabric, etc. made of polyester fiber as a mark fabric 6 and backing it with a nonwoven fabric 7 coated with a temporary adhesive 7 '. Next, a transfer adhesive layer 9 is formed on the back surface of the composite fabric 8 to make a fabric material for a mark, and then a mark ground 6 of the composite fabric 8 which is a constituent material of the fabric material for the mark. The transfer paper is applied to the mark dough material produced by changing the conventional procedure to make the mark dough 11 in which the transfer paper is used to transfer the color, the pattern, the design, etc. with the sublimation dye. It is not possible to make a mark dough material by transferring the sublimation dye on the transfer paper by performing the transfer used.
Because the sublimation dye printed on the transfer paper is sublimated to the mark base 6 of the mark fabric material, and the color, pattern, and pattern are transferred to the mark base 6 constituting the mark fabric material, and Not only the melting point temperature of the transfer adhesive layer 9 formed on the mark material is different, but also the transfer adhesive layer 9 is melted during the transfer operation of coloring, pattern, or pattern from the transfer paper due to the difference in pressing pressure, pressing time, etc. Prior to this, the molten resin of the transfer adhesive layer 9 oozes out to the surface of the mark base 6 through the nonwoven fabric 7 constituting the composite fabric 8, and a film made of the molten resin is formed on the surface of the mark base 6 to cause sublimation transfer failure. Because it will end up.

また、現在マーク業界に出回っているポリエステル繊維等から成る白地の織物、編物、不織布等を以てマーク地6とし、このマーク地6に仮接着剤7’を塗布した不織布7を裏打ちして複合生地8として、その複合生地8のマーク地6に前記転写紙を以て色彩、模様、図柄を転写した後、その複合生地8の不織布7に転写接着層9を形成して図5に示す構成のマーク用生地11から型取りして作った図6に図示したマーク12とし、これを以て常法による加熱プレス手段で該マークをユニホーム等に接着した場合には、下記の通りの不都合が生じる。
即ち、ユニホームとマークの構成材である複合生地8の不織布7は強固に接着するが、該不織布7とマーク地6とは仮接着剤7’で仮着しているので、ユニホーム等に接着したマーク12は洗濯堅牢度が弱く、洗濯中に剥がれてしまうと言う不都合が生じるマークとなる。また、耐摩擦性も弱いという不都合が生じるマークとなる。
また、複合生地8のマーク地6に前記転写紙を以て色彩、模様、図柄を転写した後に、不織布7を剥離してから転写接着層9を形成しようとすると、前記転写紙を以て色彩、模様、図柄を転写したマーク地6は剥離作業のために歪んでしまうという不都合が生じる。
さらに、上記した不都合を解消するために前記複合生地8を作る手段として前記マーク地6裏に配する不織布7をマーク地6と強固に接着しようとして仮接着剤7’を分厚く塗布した複合生地8を作り、その複合生地8の不織布7に転写接着層9を形成してマーク用生地11を作り、このマーク用生地11からマーク12を型取りし、そのマーク12を以て常法に従った加熱プレスによってユニホーム等に接着しようとすると、仮接着剤7’を作る合成樹脂が、分厚い層となっているので、これが溶融してマーク地6面にも不織布7裏面からも滲み出してしまい、マーク地6面に溶融した合成樹脂による皮膜を形成してしまう。その結果、仮接着剤7’を分厚くした複合生地8を以て作ったマーク用生地並びにこのマーク用生地から作ったマークは商品とはならないという不都合が生ずる。
Also, a white fabric, knitted fabric, non-woven fabric, etc., made of polyester fiber and the like currently available in the mark industry is used as the mark fabric 6, and the nonwoven fabric 7 coated with temporary adhesive 7 'is lined on the mark fabric 6 and the composite fabric 8 is backed. As shown in FIG. 5, after transferring the color, pattern and design to the mark area 6 of the composite fabric 8 by using the transfer paper, a transfer adhesive layer 9 is formed on the nonwoven fabric 7 of the composite fabric 8 and When the mark 12 shown in FIG. 6 is formed by molding from 11, and this is adhered to a uniform or the like by a heating press means by a conventional method, the following inconvenience occurs.
That is, the nonwoven fabric 7 of the composite fabric 8 that is a constituent material of the uniform and the mark adheres firmly, but the nonwoven fabric 7 and the mark fabric 6 are temporarily attached with the temporary adhesive 7 ', so that they adhere to the uniform or the like. The mark 12 has a weakness in washing fastness and becomes a mark that causes inconvenience that it is peeled off during washing. Further, the mark has a disadvantage that the friction resistance is weak.
In addition, after transferring the color, pattern, or pattern to the mark 6 of the composite fabric 8 using the transfer paper, if the transfer adhesive layer 9 is formed after the nonwoven fabric 7 is peeled off, the color, pattern, or pattern is transferred using the transfer paper. There is a disadvantage that the mark place 6 to which the mark is transferred is distorted due to the peeling work.
Further, in order to eliminate the above-mentioned disadvantages, as a means for producing the composite fabric 8, the composite fabric 8 to which the non-woven fabric 7 disposed on the back of the mark fabric 6 is applied to the mark fabric 6 in a thick manner so as to adhere firmly to the mark fabric 6. A transfer adhesive layer 9 is formed on the nonwoven fabric 7 of the composite fabric 8 to form a mark fabric 11. A mark 12 is formed from the mark fabric 11, and a hot press according to a conventional method is used with the mark 12. The synthetic resin that forms the temporary adhesive 7 'becomes a thick layer when it tries to adhere to the uniform or the like, so that it melts and oozes out from both the mark ground 6 and the back of the non-woven fabric 7, and the mark ground A film made of synthetic resin melted on the six surfaces is formed. As a result, there arises an inconvenience that the mark fabric made with the composite fabric 8 in which the temporary adhesive 7 'is thickened and the mark made from the mark fabric are not commodities.

前記した技術の不都合を解消するため、本発明者等は以前に特開2006−322129号公報に開示された発明を開発した。
前記した公開公報に記載された発明の要旨は同公報の[請求項1]に記載されているようにマーク用生地材料を構成するマーク地を、昇華性染料と親和性のある構成成分から成る繊維で作られた白地の布地を用い、
前記した布地であるマーク地の裏面に、前記した布地であるマーク地の構成材である布地の構成成分と親和性のある合成樹脂で、しかも融点高度を昇華性染料の昇華温度より高温度に設定した合成樹脂から成る介在層を形成し、
前記介在層の面に、ホットメルト性の熱可塑性合成樹脂から成る転写接着層を形成し、
この転写接着層の面に剥離紙を貼り合わせた構成としたことを特徴とするマーク用生地材料と言う構成から成るものであり、
また、[請求項2]に記載されているように、
マーク用生地材料を構成するマーク地を、昇華性染料と親和性のある構成成分から成る繊維で作られた白地の布地を用い、
前記した布地であるマーク地の裏面に、前記した布地であるマーク地の構成材である布地の構成成分と親和性のある合成樹脂で、しかも融点高度を昇華性染料の昇華温度より高温度に設定した合成樹脂から成る介在層を形成し、
前記介在層の面に、耐熱性のフィルムを形成し、
前記フィルムの面に、ホットメルト性の熱可塑性合成樹脂から成る転写接着層を形成し、
この転写接着層の面に剥離紙を貼り合わせた構成としたことを特徴とするマーク用生地材料と言う構成から成るものである。
即ち、前記した公開公報に記載された発明は、白地のマーク地裏に介在層を形成し、その裏に転写接着層を形成し、その裏に剥離紙を貼り合わせる工程を経て作るものである。
熱転写マークは、薄手に作ることに越したことはない。
前記した公開公報に記載された発明のマーク用生地材料から作る熱圧着型マークは、前記した工程を経て作ることによって厚手の熱転写型マークとなるという嫌いがないでもない。
前記公開公報に記載された発明に係る熱圧着型マークは、マーク地と転写接着層との間に介在させるものであることから、その介在物が原因して厚手のものとなる。熱圧着型マークが厚手になると、その厚みが原因して、貼着対象物に貼着後貼着対象物からむしり取られる現象、即ち、耐剥離性を十分に発揮できないと言う不都合を生じるようになる。
In order to eliminate the disadvantages of the above-described technique, the present inventors have previously developed an invention disclosed in Japanese Patent Application Laid-Open No. 2006-322129.
The gist of the invention described in the above-mentioned publication is that, as described in [Claim 1] of the same publication, the mark base constituting the mark material is composed of a component having an affinity for the sublimation dye. Using white fabric made of fiber,
A synthetic resin having affinity with the constituent components of the fabric, which is the constituent material of the mark fabric, which is the fabric, and the melting point altitude higher than the sublimation temperature of the sublimation dye on the back surface of the mark fabric, which is the fabric described above. Form an intervening layer made of the set synthetic resin,
A transfer adhesive layer made of a hot-melt thermoplastic synthetic resin is formed on the surface of the intervening layer,
It is composed of a structure called a mark dough material characterized by a structure in which release paper is bonded to the surface of this transfer adhesive layer,
Further, as described in [Claim 2],
The mark fabric that constitutes the fabric material for the mark is a white fabric made of fibers composed of components that are compatible with sublimation dyes,
A synthetic resin having affinity with the constituent components of the fabric, which is the constituent material of the mark fabric, which is the fabric, and the melting point altitude higher than the sublimation temperature of the sublimation dye on the back surface of the mark fabric, which is the fabric described above. Form an intervening layer made of the set synthetic resin,
Forming a heat resistant film on the surface of the intervening layer;
On the surface of the film, a transfer adhesive layer made of a hot-melt thermoplastic synthetic resin is formed,
It is composed of a structure called a mark dough material, characterized in that a release paper is bonded to the surface of the transfer adhesive layer.
That is, the invention described in the above publication is made through a process in which an intervening layer is formed on a white mark background, a transfer adhesive layer is formed on the back, and a release paper is pasted on the back. .
Thermal transfer marks can never be made thin.
The thermocompression-bonding mark made from the mark material of the invention described in the above-mentioned publication is not unpleasant that it becomes a thick heat transfer-type mark by making it through the above-described steps.
Since the thermocompression-bonding mark according to the invention described in the above-mentioned publication is interposed between the mark ground and the transfer adhesive layer, it becomes thick due to the inclusion. When the thermocompression bonding mark becomes thick, the thickness causes the phenomenon that the sticking object is peeled off from the sticking object after sticking, that is, the peeling resistance cannot be sufficiently exhibited. Become.

特開2006−322129号公報JP 2006-322129 A

本発明は、前記した公開公報に記載された発明から成るマーク用生地材料を以て作る熱圧着型マークの生じる不都合を阻止し、前記した公開特許公報に記載されたマーク用生地材料から作られる熱圧着型マークを、より薄手のマークを作ることができるマーク用生地材料を提供しようとし、マーク地について研究を重ねた新たな熱圧着型マークを作るマーク用生地材料を提供しようとするものである。 The present invention prevents the inconvenience caused by the thermocompression bonding type mark made with the mark dough material comprising the invention described in the above-mentioned publication, and the thermocompression bonding made from the mark dough material described in the above-mentioned publication. The purpose of this study is to provide a dough material for a mark that can make a thinner mark, and to provide a dough material for a mark that makes a new thermo-compression-type mark that has been researched about the mark place.

本発明のマーク用生地材料を構成するマーク地とする布地は、昇華性染料と親和性のある構成成分から成る繊維で作られた紡糸から成る布地を用いる。その代表的な例としてポリエステル繊維で作られた紡糸を以て織物、編み物、不織布として作った白地の布地を用いる。
前記した布地を以て本発明のマーク地とするのには、前記した布地を作るために用いる紡糸の構成材である繊維の構成成分であるポリエステル合成樹脂と親和性のある合成樹脂で、しかも融点高度を昇華性染料の昇華温度より高温度に設定した合成樹脂を以て、該布地の裏側面に露出する該紡糸の構成材である繊維の隙間に、且つ、縦糸として使う紡糸の糸芯に達する手前の深さに滲み込ませ、織物、編み物として成る布地の裏側面の織り目、編み目を目潰しする極薄膜を形成して本発明のマーク用生地材料とする。
The cloth used as the mark cloth constituting the mark material of the present invention is a cloth made of a fiber made of a fiber composed of a component having affinity with a sublimable dye. As a typical example, a white fabric made as a woven fabric, a knitted fabric or a non-woven fabric is used.
In order to use the above-mentioned fabric as the mark fabric of the present invention, it is a synthetic resin having an affinity for polyester synthetic resin, which is a constituent component of fiber that is a component of spinning used to make the above-mentioned fabric, and has a high melting point. With a synthetic resin set at a temperature higher than the sublimation temperature of the sublimation dye, before reaching the yarn core of the spinning used as the warp, in the gap between the fibers constituting the spinning material exposed on the back side of the fabric An extremely thin film that penetrates to the depth and crushes the weaves and stitches on the back side of the fabric formed as a woven or knitted fabric is formed as the mark fabric material of the present invention.

前記マーク地を形成する極薄膜の面に、従来のマーク生地を作るのと同様に剥離材の表面にホットメルト性の熱可塑性合成樹脂から成る転写接着層を形成した剥離材の転写接着層を重ね、その状態で加熱加圧操作を行って、前記した熱圧着型マーク地裏と剥離材面に形成した前記した転写接着層とを一体として形成してマークを作るために使うマーク用生地材料とする。 On the surface of the ultrathin film forming the mark ground, a transfer adhesive layer of a release material in which a transfer adhesive layer made of a hot-melt thermoplastic synthetic resin is formed on the surface of the release material in the same manner as making a conventional mark fabric. The dough material for the mark used for making a mark by stacking and performing the heating and pressing operation in this state to integrally form the above-described thermocompression-bonding mark background and the above-mentioned transfer adhesive layer formed on the release material surface And

本発明は、昇華性染料と親和性のある構成成分から成る繊維で作られた白地の布地から成るマーク地に昇華染料を以てする昇華転写温度より高融点の合成樹脂で極薄膜を作り、その極薄膜に剥離剤で裏打ちされたホットメルト系の熱可塑性合成樹脂から成る転写接着層を形成したマーク用生地材料を作るものであるから本発明のマーク用生地材料を入手しさえすれば、加工業者は昇華性染料で所望の色彩、模様、図柄を印刷した転写紙を以て、加工業者が所持する加熱加圧機で、所望の色彩、模様、図柄を転写したマーク地から成るマーク用生地を作り、これから熱圧着型マークを作ることができる。 In the present invention, an extremely thin film is made of a synthetic resin having a melting point higher than a sublimation transfer temperature with a sublimation dye on a mark fabric made of a white fabric made of fibers having a component having an affinity for a sublimation dye, and the extreme Since a mark fabric material is formed by forming a transfer adhesive layer composed of a hot-melt thermoplastic synthetic resin lined with a release agent on a thin film, the processor is only required to obtain the mark fabric material of the present invention. Is a heating and pressurizing machine possessed by a processor with a transfer paper printed with a desired color, pattern, or design with a sublimation dye, and creates a mark fabric consisting of a mark with the desired color, pattern, or design transferred. A thermocompression mark can be made.

上記した構造とすることにより該マーク地の表面は、昇華性染料による転写紙を以てする昇華転写に親しむ性質を発揮し、マーク地の裏に昇華性染料の昇華温度より高温度に設定した合成樹脂から成る極薄膜を形成する層を設けたマーク地とすることになり、マーク地裏に形成する転写接着層は前記した特開2006−322129号公報に記載された発明から成るマーク用生地材料を用いたマーク生地とは異なり、介在層を介在させる必要のないマーク地に形成でき、その結果マーク地用生地は薄手に形成でき、これを以て作ったマークは薄手の熱圧着型マークとすることができ、貼着物に貼着後、貼着物からむしり取られるような厚みとならない。また、昇華性染料を以て作った転写紙を以てする加熱プレス操作時に該転写紙の昇華性染料をマーク地へ転写するとき、下層となる転写接着層の溶融樹脂が加熱によりマーク地の構成材である布側に滲み出すことを防止することができる。
また、マーク地裏の極薄膜と転写接着層との間に耐熱性のフィルムを介在させた場合には、加熱プレスによる昇華性染料の転写に際して、より確実に加熱による影響を受けないようにすることができる。
By using the structure described above, the surface of the mark base exhibits a property familiar to sublimation transfer using transfer paper with a sublimation dye, and the synthetic resin is set on the back of the mark base at a temperature higher than the sublimation temperature of the sublimation dye. And a transfer adhesive layer formed on the back side of the mark is made of the mark dough material according to the invention described in JP-A-2006-322129. Unlike the mark fabric used, it can be formed on a mark ground that does not require an intervening layer. As a result, the mark fabric can be thinly formed, and the mark made with this can be a thin thermocompression-bonded mark. It is not possible to have a thickness that can be peeled off from an adhesive after being attached to the adhesive. In addition, when transferring the sublimation dye of the transfer paper to the mark place during the heat press operation using the transfer paper made with the sublimation dye, the molten resin of the lower transfer adhesive layer is a constituent material of the mark place by heating. It can prevent oozing out to the cloth side.
In addition, when a heat-resistant film is interposed between the ultrathin film on the back of the mark and the transfer adhesive layer, the sublimation dye is more reliably prevented from being affected by heating when transferring with a heating press. be able to.

本発明に係るマーク用生地材料の構成を示す斜視図。The perspective view which shows the structure of the fabric material for marks which concerns on this invention. 本発明に係るマーク用生地材料のA−A線断面拡大図。The AA line section enlarged view of the cloth material for marks concerning the present invention. 本発明に係るマーク用生地材料を所望形状に裁断したときの構成を示す斜視図。The perspective view which shows a structure when the cloth material for marks which concerns on this invention is cut | judged to a desired shape.

本発明のマーク用生地を作るために用いる布地は、昇華性染料と親和性のある構成成分から成る繊維で作られた白地の布地を使う。本発明のマーク用生地を作るためのマーク地は、前記した白地の布地の裏面に、前記した布地の構成成分と親和性があり、しかも融点高度を昇華性染料の昇華温度より高温度に設定した合成樹脂を以て極薄膜を形成したものとする。本発明のマーク用生地は、前記したマーク地の極薄膜の面に、ホットメルト性の熱可塑性合成樹脂から成る転写接着層を表面に形成した剥離材の転写接着層を貼り合わせることによりマーク用生地材料を作る。 The fabric used for making the mark fabric of the present invention is a white fabric made of fibers composed of components having an affinity for sublimation dyes. The mark fabric for making the mark fabric of the present invention has affinity with the above-mentioned fabric constituents on the back side of the white fabric described above, and the melting point altitude is set higher than the sublimation temperature of the sublimable dye. It is assumed that an extremely thin film is formed using the synthetic resin. The mark fabric of the present invention is used for a mark by attaching a transfer adhesive layer of a release material having a transfer adhesive layer made of a hot-melt thermoplastic synthetic resin on the surface of the ultrathin film of the mark base. Make dough materials.

本発明のマーク用生地材料10は図1に示す構成から成るものである。本発明のマーク用生地材料10を構成するマーク地とする布地1としては、昇華性染料に親和性のある構成成分から成る繊維を使った図3に示すように紡糸1Aを以て作られた布地1であって、代表的な例としては、ポリエステル繊維から成る紡糸を以て作られた白地の織物、編み物、不織布から成る布地を用いる。
前記した布地1を用いる理由は、昇華性染料を用いて色彩、模様、図柄の印刷を施した転写紙を以て前記布地に昇華性染料の染料成分を昇華させて該転写紙に印刷された色彩、模様、図柄の転写をする場合、該転写紙から昇華した染料成分による色彩、模様、図柄が他の材料で作った白地の布地、例えばナイロン系の合成樹脂で作った布地では転写した昇華性染料成分による鮮明な色彩、模様、図柄の転写が出来ないからである。
また、前記した白地の布地1は、材料をポリエステル繊維を用いた紡糸で造ると言うだけでなく、その布地1は、少なくとも、前記転写紙を以て、前記転写紙に印刷された昇華性染料を加熱加圧によってその染料成分を昇華して転写紙に印刷された色彩、模様、図柄通りの色彩、模様、図柄を前記布に転写するものであるから、その布地は前記した転写紙による昇華転写の加熱温度に耐える構成成分から成る繊維で作られた紡糸1Aで作られた布地1でなければならない。
The mark dough material 10 of the present invention has the structure shown in FIG. As the fabric 1 as the mark fabric constituting the mark fabric material 10 of the present invention, the fabric 1 made by spinning 1A as shown in FIG. 3 using fibers composed of components having affinity for sublimation dyes. As a typical example, a fabric made of white woven fabric, knitted fabric, and nonwoven fabric made by spinning made of polyester fiber is used.
The reason for using the fabric 1 is the color printed on the transfer paper by sublimating the dye component of the sublimation dye on the fabric with a transfer paper on which printing of a color, a pattern, and a pattern is performed using a sublimation dye, When transferring patterns and designs, sublimation dyes transferred on white fabrics with colors, patterns and designs made of other materials, such as nylon-based synthetic resins, with dye components sublimated from the transfer paper. This is because clear colors, patterns and designs cannot be transferred by the components.
Further, the above-described white fabric 1 is not only made of a material made by spinning using a polyester fiber, but the fabric 1 is also heated at least with the transfer paper and the sublimation dye printed on the transfer paper. Since the dye component is sublimated by pressurization and the color, pattern, pattern-like color, pattern, or pattern printed on the transfer paper is transferred to the cloth, the fabric is subjected to sublimation transfer using the transfer paper described above. It must be a fabric 1 made of spun 1A made of fibers composed of components that can withstand the heating temperature.

前記布地1の裏面に形成する極薄膜は、前記布地1の構成材と親和性のある熱可塑性合成樹脂で極薄膜2として形成する。
この耐熱極薄膜2は、布地1の裏面に露出する前記紡糸1Aの面に前記合成樹脂溶剤をスプレーによるかコーティングするか、前記合成樹脂から成るフィルムをラミネートするかによって極薄膜2として形成する。
即ち、前記した合成樹脂を以て、前記布地1の裏側面に露出した紡糸1Aの面から、前記した紡糸1Aの構成材である繊維の隙間に前記した合成樹脂を滲み込ませる。この操作は、図3に図示するように前記した紡糸1Aに滲み込ませることとする。この滲み込みは紡糸の縦糸の糸芯を通過して滲過するものであってはならない。この合成樹脂の滲み込み操作によって布地1の織り目、編み目の目潰し機能も発揮することになる。その結果は、前記した布地1の裏側面に露出した紡糸の表面形状と極めて近似する表面形状の極薄膜2を形成することになる。
The ultrathin film formed on the back surface of the fabric 1 is formed as the ultrathin film 2 with a thermoplastic synthetic resin having affinity with the constituent material of the fabric 1.
The heat-resistant ultrathin film 2 is formed as an ultrathin film 2 by spraying or coating the synthetic resin solvent on the surface of the spinning 1A exposed on the back surface of the fabric 1 or laminating a film made of the synthetic resin.
That is, with the above-described synthetic resin, the above-described synthetic resin is soaked from the surface of the spinning 1A exposed on the back side surface of the fabric 1 into the gap between the fibers that are the constituent material of the spinning 1A. In this operation, as shown in FIG. 3, the spinning 1A is allowed to penetrate. This soaking should not pass through the core of the warp of the spinning. This wetting operation of the synthetic resin also exhibits the function of crushing the weave and stitches of the fabric 1. As a result, an ultrathin film 2 having a surface shape very close to the surface shape of the spinning exposed on the back side surface of the fabric 1 is formed.

前記した操作を行うために使用する合成樹脂の粘度は当然前記機能を発揮するための極薄膜を作るための粘度に調整しなければならないことは当然である。
前記した極薄膜は、前記した融点温度に設定した合成樹脂を以て作る者であるから昇華染料を使った転写紙を以てする昇華転写時には昇華した染料成分の通過を阻止する機能も発揮することは当然である。
この極薄膜を作るためには、前記した合成樹脂に前記した機能をよりよく果たせるため、前記した合成樹脂に架橋剤、或いは活性炭極微粒子等を混合した昇華性染料の成分の浸透を阻止する極薄膜を形成する成分を混合調整したものを使用することがある。
この操作によって布地1の表側面は昇華性染料を用いた転写紙の転写操作に支障がない表側面とすることができることになる。
Naturally, the viscosity of the synthetic resin used for performing the above-described operation must be adjusted to the viscosity for producing an ultrathin film for exhibiting the above function.
The ultrathin film described above is a person who makes a synthetic resin set at the above-mentioned melting point temperature, and therefore naturally exhibits a function of blocking the passage of the sublimated dye component during sublimation transfer using transfer paper using a sublimation dye. is there.
In order to make this ultrathin film, the above-described synthetic resin can perform the above-described functions better, so that the penetration of components of sublimation dyes in which the above-mentioned synthetic resin is mixed with a crosslinking agent or activated carbon fine particles is prevented. A mixture of components that form a thin film may be used.
By this operation, the front side surface of the fabric 1 can be a front side surface that does not hinder the transfer operation of the transfer paper using the sublimable dye.

本発明のマーク用生地材料10を作るのには、マーク地とする白地の布地1に前記した操作を行って、布地1の裏側面に前記した図1、図3に図解した極薄膜2を形成した布地1をマーク地とすることが特徴である。 In order to make the mark dough material 10 of the present invention, the above-described operation is performed on the white cloth 1 as the mark place, and the ultrathin film 2 illustrated in FIG. 1 and FIG. It is characterized in that the formed fabric 1 is used as a mark place.

本発明のマーク用生地材料10は、前記した操作を行った図1、図3に図解する布地1から成るマーク地裏に形成した極薄膜2裏にホットメルト性の熱可塑性合成樹脂から成る熱転写接着層3に裏打ちした剥離剤4の熱転写接着層3を重ねて、加熱加圧操作を行って、前記マーク地である布地1裏に剥離剤4で裏打ちされた熱転写接着層3を一体物として形成する。
即ち、該操作によりマーク地である布地1の裏の極薄膜2に形成される熱転写接着層4はあたかも布地1の裏側面に露出する紡糸1A面に直接形成された体裁と同じような体裁でしっかりとした一体物として形成される。
The mark dough material 10 of the present invention is a thermal transfer made of a hot-melt thermoplastic synthetic resin on the back of an extremely thin film 2 formed on the back of the mark made of the fabric 1 illustrated in FIGS. The thermal transfer adhesive layer 3 of the release agent 4 lined on the adhesive layer 3 is overlapped, and a heating and pressing operation is performed, and the thermal transfer adhesive layer 3 lined with the release agent 4 on the back of the cloth 1 as the mark is integrated. Form.
That is, the thermal transfer adhesive layer 4 formed on the ultrathin film 2 on the back side of the fabric 1 that is the mark fabric by the operation has the same appearance as that formed directly on the surface of the spinning 1A exposed on the back side surface of the fabric 1. Formed as a solid unit.

本発明に係るマーク用生地材料10は、上記の手順を経て作られるから、その構成は、図1に示すとおりポリエステル繊維による織物、編み物、不織布から成る白地の布地1をマーク地とし、そのマーク地の布地1裏に極薄膜2、その極薄膜2裏に熱転写接着層3、その熱転写接着層裏に剥離紙4を配した構成となる。 Since the mark fabric material 10 according to the present invention is manufactured through the above-described procedure, the structure thereof is a white fabric 1 made of woven fabric, knitted fabric, and nonwoven fabric made of polyester fibers as shown in FIG. The ultrathin film 2 is disposed on the back of the ground fabric 1, the thermal transfer adhesive layer 3 is disposed on the back of the ultrathin film 2, and the release paper 4 is disposed on the back of the thermal transfer adhesive layer.

このマーク用生地材料10を構成する布地1から成るマーク地に所望の色彩、模様、図柄を形成したマーク用生地とするためには、昇華性染料を以て所望の色彩、模様、図柄を印刷した転写紙の印刷面を、マーク用生地材料10のマーク地とする白地の布地1に重ね合わせて、約60秒、約200℃の温度、約300g/平方センチメートルの条件下で加熱加圧を行う。
この操作によって、前記転写紙から印刷に用いた昇華性染料が所望の色彩、模様、図柄として前記白地の布地1であるマーク地に転写し、前記白地の布地1であるマーク地21面に前記昇華性染料による色彩、模様、図柄が形成される。
In order to obtain a mark fabric in which a desired color, pattern, or pattern is formed on the mark fabric formed of the fabric 1 that constitutes the mark fabric material 10, a transfer in which the desired color, pattern, or design is printed with a sublimation dye. The printed surface of the paper is superposed on the white fabric 1 as the mark location of the mark fabric material 10 and heated and pressed under conditions of about 60 seconds, a temperature of about 200 ° C., and about 300 g / square centimeter.
By this operation, the sublimation dye used for printing from the transfer paper is transferred as a desired color, pattern, or pattern to the mark ground that is the white cloth 1, and the surface of the mark cloth 21 that is the white cloth 1 is the surface. Colors, patterns, and patterns are formed by sublimation dyes.

この操作時に、ホットメルト系の熱可塑性合成樹脂によって形成された転写接着層3は、当然前記加熱加圧操作によって、前記極薄膜3と剥離紙4の間で溶融するが、本発明のマーク用生地材料10の構成材である白地の布地1であるマーク地には、前記極薄膜2が設けてあるので、前記白地の布地1であるマーク地には転写接着層2の構成成分である溶融した合成樹脂が滲み出すことはない。また、剥離紙4からも滲み出すことはない。
従って、従来のような不良品となることはない。
During this operation, the transfer adhesive layer 3 formed of a hot-melt thermoplastic synthetic resin naturally melts between the ultrathin film 3 and the release paper 4 by the heating and pressurizing operation. Since the ultrathin film 2 is provided on the mark fabric which is the white fabric 1 which is a constituent material of the fabric material 10, the mark fabric which is the white fabric 1 is melted as a constituent component of the transfer adhesive layer 2. The synthetic resin does not ooze out. Further, no bleeding from the release paper 4 occurs.
Therefore, it does not become a defective product as in the past.

即ち、加工業者は、前記マーク用生地材料10を入手しさえすれば既存の加熱プレス機を以て、昇華性染料により印刷した所望の色彩、模様、図柄を施した転写紙を使って、所望の色彩、模様、図柄を転写したマーク用生地を作ることができる。
このマーク用生地から加工業者がマークを作る手段は、昇華性染料により印刷した転写紙を以て従来法により転写操作を行って転写操作後、転写された図柄通りに所望の形状に裁断して図2に示すマーク20とすることは勿論である。
また、そのマーク20をユニホーム等に接着する手段は従来法によることは勿論である。
That is, the processor only needs to obtain the mark dough material 10 and uses the existing heat press machine to transfer the desired color using the transfer paper printed with the desired color, pattern and pattern printed with the sublimation dye. It is possible to make mark fabrics that transfer patterns and designs.
The means for the processor to make a mark from the fabric for the mark is that the transfer operation is carried out by a conventional method using a transfer paper printed with a sublimation dye, and after the transfer operation, it is cut into a desired shape according to the transferred pattern. Of course, the mark 20 shown in FIG.
Of course, the means for adhering the mark 20 to a uniform or the like is based on the conventional method.

10 マーク用生地材料
1 白地の布地
2 極薄膜
3 熱転写接着層
4 剥離材
10 Mark fabric material 1 White fabric 2 Ultrathin film 3 Thermal transfer adhesive layer 4 Release material

Claims (1)

昇華性染料に親和性のある構成成分から成る繊維を使った紡糸を以て作られた布地であって、代表的な布地としてはポリエステル繊維から成る紡糸を以て作られた白地の布地を用い、該布地裏側面に露出する紡糸面から前記布地の厚さの半分以下の厚さに達する厚さまで融点温度を昇華性染料の昇華温度より高い温度に設定した熱可塑性合成樹脂を滲透させて加熱加圧操作を施して該布地を裏側面に該合成樹脂から成る極薄膜を形成した布地とし、該布地裏側面に形成した該極薄膜面にホットメルト性の熱可塑性合成樹脂を以て熱転写接着層を形成した剥離材の熱転写接着層形成面を重ね合わせて加熱加圧して該布地裏側面に形成した極薄膜面に該剥離材に形成した熱転写接着層を一体として形成したマーク用生地材料。 A fabric made by spinning using fibers composed of components having an affinity for sublimation dyes, and a typical fabric is a white fabric made by spinning of polyester fibers, and the back side of the fabric From the spinning surface exposed on the surface to the thickness reaching the thickness of half or less of the thickness of the fabric, a thermoplastic synthetic resin with a melting point set to a temperature higher than the sublimation temperature of the sublimable dye is permeated to perform a heating and pressing operation. A release material in which the fabric is made into a fabric in which an ultrathin film made of the synthetic resin is formed on the back side surface, and a thermal transfer adhesive layer is formed on the ultrathin film surface formed on the back side surface of the fabric with a hot-melt thermoplastic synthetic resin A fabric material for a mark in which the heat transfer adhesive layer formed on the release material is integrally formed on the ultrathin film surface formed on the back side of the fabric by superimposing the heat transfer adhesive layer forming surfaces of
JP2010092958A 2010-04-14 2010-04-14 Fabric material for producing thermocompression-bonded mark Pending JP2011219903A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016172936A (en) * 2015-03-16 2016-09-29 株式会社宝來社 Cloth material for mark and method for forming mark
US10092053B2 (en) 2014-12-15 2018-10-09 Creedence Holdings Llc Sublimation printed clothing articles

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10092053B2 (en) 2014-12-15 2018-10-09 Creedence Holdings Llc Sublimation printed clothing articles
JP2016172936A (en) * 2015-03-16 2016-09-29 株式会社宝來社 Cloth material for mark and method for forming mark

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