JP2011084800A - High purity aluminum rolled sheet and method for producing the rolled sheet - Google Patents

High purity aluminum rolled sheet and method for producing the rolled sheet Download PDF

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JP2011084800A
JP2011084800A JP2009240504A JP2009240504A JP2011084800A JP 2011084800 A JP2011084800 A JP 2011084800A JP 2009240504 A JP2009240504 A JP 2009240504A JP 2009240504 A JP2009240504 A JP 2009240504A JP 2011084800 A JP2011084800 A JP 2011084800A
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purity aluminum
rolling
rolled sheet
purity
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Hitoshi Yasuda
均 安田
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Sumitomo Chemical Co Ltd
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Sumitomo Chemical Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a high purity aluminum rolled sheet having a smooth surface free from defects such as fine cracks as-rolled without applying chemical polishing and electrolytic polishing. <P>SOLUTION: The high purity aluminum rolled sheet has a purity of ≥99.999 mass%. The surface of the rolled sheet is a mirror face not subjected to polishing treatment, the arithmetic average roughness Ra of the surface is ≤0.05 μm, and the crystal grain size of the surface is ≤50 μm. The high purity aluminum rolled sheet can be obtained by performing rolling in such a manner that rolling ratio in cold rough rolling is ≤90%, and, in cold finish rolling, working ratio is 20-80% and at one pass working ratio of 2-15% while retaining the temperature of the high purity aluminum material to 0-50°C. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

本発明は、例えば、表面にクラック等の欠陥の少なく、表面が鏡面であることを要求される用途に有用な高純度アルミニウム圧延板に関する。   The present invention relates to a high-purity aluminum rolled sheet that is useful for applications that require, for example, a mirror surface with few defects such as cracks on the surface.

例えば、表面を鏡面に加工されたアルミニウム圧延板としては、自動車のモールや反射板などに使われる光輝性アルミニウム合金(特許文献1参照)が用いられている。光輝性を得るためには表面の平滑性が要求されるので、圧延板の表面は化学研磨や電解研磨されて利用されていた。   For example, as an aluminum rolled plate whose surface is mirror-finished, a glittering aluminum alloy (see Patent Document 1) used for automobile moldings, reflectors, and the like is used. Since smoothness of the surface is required to obtain glitter, the surface of the rolled plate has been used after being subjected to chemical polishing or electrolytic polishing.

しかし、化学研磨や電解研磨は化学薬品や電解電力を消費するため環境負荷が高く、圧延板の生産性を低下させるので、圧延板には、このような表面研磨処理を施さない圧延板のままの表面での光輝性が望まれていたが、圧延板の原料に含まれる不純物に起因する化合物が圧延板の表面の平滑性を低下させていたため、光輝性が得られなかった。   However, chemical polishing and electrolytic polishing consume chemicals and electrolysis power, and therefore have a high environmental load and reduce the productivity of the rolled plate. Therefore, the rolled plate remains a rolled plate that is not subjected to such surface polishing treatment. However, since the compound resulting from the impurities contained in the raw material of the rolled sheet had reduced the smoothness of the surface of the rolled sheet, no glitter was obtained.

そこで、本発明者は、表面研磨処理を施さず、かつ表面の平滑な圧延板を得るために、不純物の少ない高純度アルミニウムを原料とした圧延板について検討した。   Therefore, the present inventor has examined a rolled plate made of high-purity aluminum with few impurities in order to obtain a rolled plate having a smooth surface without performing surface polishing treatment.

特開平02−138447号公報Japanese Patent Laid-Open No. 02-138447

しかしながら、従来の高純度アルミニウム圧延板では、化学研磨や電界研磨などの表面研磨を施さなければ、平滑な表面は得られなかった。その原因は、高純度アルミニウム圧延板の表面に微細なクラックが発生したためで、このような微細なクラックは、高純度アルミニウムを原料とする圧延板の表面を化学研磨や電解研磨して利用する場合には、微細なクラックは除去されていた。
しかしながら、圧延板の表面研磨工程を省き、生産性を向上させる為には、表面研磨処理を施さない圧延板のままで欠陥の無い平滑な表面を有するアルミニウム圧延板が要望されていたが、前記微細なクラックの存在により見かけ上は鏡面であっても平滑な表面が得られない、という問題があった。
However, with a conventional high-purity aluminum rolled plate, a smooth surface could not be obtained unless surface polishing such as chemical polishing or electropolishing was performed. The reason is that fine cracks occurred on the surface of the high-purity aluminum rolled plate, and such fine cracks are used when the surface of the rolled plate made of high-purity aluminum is used by chemical polishing or electrolytic polishing. The fine cracks were removed.
However, in order to omit the surface polishing step of the rolled plate and improve productivity, there has been a demand for an aluminum rolled plate having a smooth surface with no defects as a rolled plate not subjected to surface polishing treatment. Due to the presence of fine cracks, there is a problem that a smooth surface cannot be obtained even if the surface is specular.

そこで、本発明は、化学研磨や電解研磨を施さずに圧延のままで微細なクラックなどの欠陥の無い平滑な表面を有する高純度アルミニウム圧延板を提供することを課題とする。   Then, this invention makes it a subject to provide the high purity aluminum rolled sheet which has a smooth surface without defects, such as a fine crack, with a rolling, without performing chemical polishing or electrolytic polishing.

本発明者は、上記課題を解決すべく鋭意検討を行なった。その結果、高純度アルミニウム材を鏡面に圧延する場合、冷間圧延中に圧延方向と直角方向の圧延材の表面に微細なクラックが発生し、このクラックは表面における一部の粗大な結晶粒において発生すること、この粗大な結晶粒の発生は高純度なアルミニウムに特有な現象であり、これを防止することでクラックの無い平滑な圧延面を有する高純度アルミニウム圧延板が得られることを見出し、本発明を完成するに至った。   The present inventor has intensively studied to solve the above problems. As a result, when high-purity aluminum material is rolled to a mirror surface, fine cracks are generated on the surface of the rolled material in the direction perpendicular to the rolling direction during cold rolling. The generation of this coarse crystal grain is a phenomenon peculiar to high-purity aluminum, and it has been found that a high-purity aluminum rolled sheet having a smooth rolled surface without cracks can be obtained by preventing this, The present invention has been completed.

すなわち、本発明は以下の構成を有する。
(1)純度99.999質量%以上である高純度アルミニウム圧延板であって、該圧延板の表面が研磨処理を施されていない鏡面であり、表面の算術平均粗さRaが0.05μm以下であり、表面の結晶粒径が50μm以下であることを特徴とする高純度アルミニウム圧延板。
(2)純度99.999質量%以上である高純度アルミニウムからなる高純度アルミニウム材を冷間粗圧延をした後に、平滑ロールを使用して、冷間仕上圧延をする高純度アルミニウム圧延板の製造方法であって、冷間粗圧延の加工率が90%以下で、かつ冷間仕上圧延の加工率が20〜80%であり、冷間仕上圧延は、前記高純度アルミニウム材の温度を0〜50℃に保ちながら、1パス加工率が2〜15%で行われることを特徴とする前記(1)に記載の高純度アルミニウム圧延板の製造方法。
(3)純度99.999質量%以上である高純度アルミニウムからなる高純度アルミニウム材を冷間粗圧延をした後に、平滑ロールを使用して、冷間仕上圧延をする高純度アルミニウム圧延板の製造方法であって、冷間粗圧延と冷間仕上圧延との間に、表面温度50〜150℃で1〜30分間加熱後、大気中で放冷する中間焼鈍が行われ、前記冷間仕上圧延は、加工率が20〜80%であり、かつ前記高純度アルミニウム材の温度を0〜50℃に保ちながら、1パス加工率が2〜15%で行われることを特徴とする前記(1)に記載の高純度アルミニウム圧延板の製造方法。
(4)前記平滑ロールは表面の最大高さ粗さが、0.05〜3μmである前記(2)または(3)に記載の高純度アルミニウム圧延板の製造方法。
That is, the present invention has the following configuration.
(1) A high-purity aluminum rolled plate having a purity of 99.999% by mass or more, wherein the surface of the rolled plate is a mirror surface that has not been subjected to polishing treatment, and the arithmetic average roughness Ra of the surface is 0.05 μm or less. A high-purity aluminum rolled sheet having a surface crystal grain size of 50 μm or less.
(2) Production of a high-purity aluminum rolled sheet that is cold-rolled using a smooth roll after cold-rolling a high-purity aluminum material made of high-purity aluminum having a purity of 99.999% by mass or more. The cold rough rolling has a processing rate of 90% or less and a cold finishing rolling processing rate of 20 to 80%, and the cold finishing rolling has a temperature of the high-purity aluminum material of 0 to 0%. The method for producing a high-purity aluminum rolled sheet according to (1), wherein the one-pass processing rate is 2 to 15% while maintaining at 50 ° C.
(3) Production of a high-purity aluminum rolled sheet that is cold-rolled using a smooth roll after cold-rolling a high-purity aluminum material made of high-purity aluminum having a purity of 99.999% by mass or more. In the method, between cold rough rolling and cold finish rolling, intermediate annealing is performed by heating at a surface temperature of 50 to 150 ° C. for 1 to 30 minutes and then allowing to cool in the atmosphere. The processing rate is 20 to 80%, and the one-pass processing rate is 2 to 15% while maintaining the temperature of the high-purity aluminum material at 0 to 50 ° C. (1) A method for producing a high-purity aluminum rolled sheet as described in 1.
(4) The said smooth roll is a manufacturing method of the high purity aluminum rolled sheet as described in said (2) or (3) whose maximum height roughness of the surface is 0.05-3 micrometers.

本発明によれば、表面研磨処理を施さない圧延板のままで、高純度アルミニウム圧延板の表面を平滑にすることができる。その結果、低コストで光輝性のある圧延板の生産性を高めることができ、例えば、一般照明、発光ダイオード、フラットディスプレーのバックライトなどの反射板や、パワーデバイス用配線材、平滑陽極酸化被膜用基板などに利用される。また、表面研磨工程が無いので、化学薬品や電解電力を消費しない環境負荷の低い製造工程で光輝性のある圧延板を得ることができる。   ADVANTAGE OF THE INVENTION According to this invention, the surface of a high purity aluminum rolled sheet can be made smooth with the rolled sheet which does not perform a surface polishing process. As a result, it is possible to increase the productivity of low-cost and high-brightness rolled sheets. It is used as a circuit board. In addition, since there is no surface polishing step, it is possible to obtain a rolled sheet having a glittering property in a manufacturing process with low environmental load that does not consume chemicals or electrolytic power.

実施例の試料No.3に係る高純度アルミニウム圧延板の表面を拡大したSEM(走査電子顕微鏡)写真(倍率:500倍、以下同じ)である。Sample No. of Example 3 is an SEM (scanning electron microscope) photograph (magnification: 500 times, hereinafter the same) in which the surface of the high-purity aluminum rolled plate according to 3 is enlarged. 実施例の試料No.4に係る高純度アルミニウム圧延板の表面を拡大したSEM写真である。Sample No. of Example 4 is an SEM photograph in which the surface of a high-purity aluminum rolled sheet according to 4 is enlarged. 実施例の試料No.5に係る高純度アルミニウム圧延板の表面を拡大したSEM写真である。Sample No. of Example 5 is an SEM photograph in which the surface of a high-purity aluminum rolled sheet according to 5 is enlarged. 実施例の試料No.6に係る高純度アルミニウム圧延板の表面を拡大したSEM写真である。Sample No. of Example 6 is an SEM photograph in which the surface of a high-purity aluminum rolled plate according to 6 is enlarged.

(高純度アルミニウム材)
本発明の高純度アルミニウム圧延板は、純度99.999質量%以上である高純度アルミニウムからなる。この高純度アルミニウムの純度の上限は、特に制限されないが、通常、99.99999質量%未満である。このような高純度アルミニウムの純度は、Alの含有量の測定により求めてもよいが、Fe、Ti、V、Cr、Zr、Si、CuおよびMg(以下、これらを纏めて「8元素」と称することもある)について各元素の含有量を求め、それらの合計量を100%から差し引くことにより求めることもできる。つまり、一般に、高純度アルミニウムに不純物として含まれうる元素としては、Si、Cu、Mg、Fe、Ti、V、Cr、Zr、Li、Be、B、Na、K、Ca、Mn、Ni、Co、Zn、Ga、As、Mo、Ag、Cd、In、Sn、Sb、Ba、La、Ce、Pt、Hg、Pb、Bi、ThおよびU(以下、これらを纏めて「35元素」と称することもある)などが挙げられ、さらに、これら35元素以外の不可避不純物を含有することもあるが、これらの中で、上記8元素以外の元素は、通常、含有されていたとしても極めて微量であり、前述のように上記8元素以外の元素の含有量をゼロと仮定して算出した純度であっても殆ど誤差は生じない。
(High-purity aluminum material)
The high-purity aluminum rolled sheet of the present invention is made of high-purity aluminum having a purity of 99.999% by mass or more. The upper limit of the purity of the high-purity aluminum is not particularly limited, but is usually less than 99.99999% by mass. The purity of such high-purity aluminum may be determined by measuring the Al content, but Fe, Ti, V, Cr, Zr, Si, Cu and Mg (hereinafter collectively referred to as “8 elements”) It is also possible to obtain the content of each element by subtracting the total amount from 100%. That is, generally, elements that can be contained as impurities in high-purity aluminum include Si, Cu, Mg, Fe, Ti, V, Cr, Zr, Li, Be, B, Na, K, Ca, Mn, Ni, Co Zn, Ga, As, Mo, Ag, Cd, In, Sn, Sb, Ba, La, Ce, Pt, Hg, Pb, Bi, Th, and U (hereinafter collectively referred to as “35 elements”) In addition, these elements may contain unavoidable impurities other than these 35 elements, but among these, elements other than the above 8 elements are usually very small even if contained. As described above, there is almost no error even if the purity is calculated assuming that the content of elements other than the above eight elements is zero.

前記高純度アルミニウムに含まれうる不純物のうち、Si、CuおよびMgの各元素の含有量はそれぞれ3質量ppm以下であることが好ましく、一方、Fe、Ti、V、CrおよびZrの各元素の含有量はそれぞれ0.1質量ppm以下であることが好ましい。これにより、圧延板表面に現れる不純物を起因とする欠陥を無くすことが出来る。また、前記高純度アルミニウムは、同様の理由から、前記35元素の合計含有量が10質量ppm以下であることが好ましい。   Among impurities that can be contained in the high-purity aluminum, the content of each element of Si, Cu, and Mg is preferably 3 mass ppm or less, respectively, while each of the elements of Fe, Ti, V, Cr, and Zr Each content is preferably 0.1 mass ppm or less. Thereby, defects caused by impurities appearing on the surface of the rolled sheet can be eliminated. The high-purity aluminum preferably has a total content of the 35 elements of 10 mass ppm or less for the same reason.

このような高純度アルミニウムは、比較的純度の低い普通アルミニウム(例えば、純度99.9質量%であるJIS−H2102の特1種程度のグレード)を精製することによって得ることができる。精製方法としては、特に制限されないが、好ましくは、前記高純度アルミニウムは、三層電解法による精製や、偏析法による精製により得られたものであるのがよい。三層電解法と偏析法の両方の精製を施しても良い。また、三層電解法による精製と偏析法による精製は、例えば、交互に繰り返し行ってもよいし、いずれか一方もしくは両方を各々繰り返し行ってもよい。なお、三層電解法による精製および一偏析法による精製の具体的な手法や条件等は、通常この分野で行われている方法や条件等を適宜採用すればよい。   Such high-purity aluminum can be obtained by refining ordinary aluminum having a relatively low purity (for example, a grade of about 1 type of JIS-H2102 having a purity of 99.9% by mass). The purification method is not particularly limited, but preferably, the high-purity aluminum is obtained by purification by a three-layer electrolysis method or purification by a segregation method. You may refine | purify both a three-layer electrolytic method and a segregation method. Further, the purification by the three-layer electrolysis method and the purification by the segregation method may be repeated alternately, for example, or one or both of them may be repeated. As specific methods and conditions for the purification by the three-layer electrolysis method and the one-segregation method, the methods and conditions usually used in this field may be adopted as appropriate.

前記高純度アルミニウムを圧延するに際しては、あらかじめ所望の形状に鋳造し、切削するなどの処理を施すこともできる。鋳造を行うには、例えば、高純度アルミニウムを加熱溶融して溶湯とし、得られた高純度アルミニウム溶湯を鋳型内で冷却固化させるといった通常の方法を採用すればよいが、これに限定されるものではない。鋳造の際の条件等も特に制限されないが、加熱温度は通常700〜800℃であり、加熱溶融は通常、減圧下あるいは不活性ガス(窒素ガス、アルゴンガス等)雰囲気下で、黒鉛製等のルツボ内で行なわれる。減圧下で加熱溶融を行なう場合には、通常1×10-4〜1×10-2Pa、好ましくは、1×10-4〜1×10-3Paとするのがよい。1×10-4Paを下回る減圧下であっても得られる高純度アルミニウム材の性能上は問題ないが、設備等の観点から経済的に不利になる。 When the high-purity aluminum is rolled, it can be cast in a desired shape and cut. For casting, for example, a normal method may be employed in which high-purity aluminum is heated and melted to form a molten metal, and the obtained high-purity aluminum molten metal is cooled and solidified in a mold, but is not limited thereto. is not. The conditions for casting are not particularly limited, but the heating temperature is usually 700 to 800 ° C., and the heating and melting is usually performed under reduced pressure or under an inert gas (nitrogen gas, argon gas, etc.) atmosphere made of graphite or the like. Performed in a crucible. When performing the heating and melting under reduced pressure is usually 1 × 10- 4 ~1 × 10- 2 Pa, preferably in an a 1 × 10- 4 ~1 × 10- 3 Pa. 1 × High purity aluminum material performance of even obtained a reduced pressure below 10- 4 Pa is no problem, is economically disadvantageous in terms of facilities.

(圧延板の製作工程)
本発明に係る高純度アルミニウム圧延板は、前記高純度アルミニウム材に圧延加工を施すことによって得られる。圧延加工は、例えば、鋳塊を一対のロールの間に挟み込むことにより圧力を加えながら、これらロール間に鋳塊を繰り返し通過させる方法などといった通常の方法で、鋳塊から目的の板厚になるまでに、粗圧延と仕上げ圧延を行えばよい。また、粗圧延中に材料が硬化した場合は、後述する中間焼鈍を行えばよい。
(Rolled plate manufacturing process)
The high-purity aluminum rolled sheet according to the present invention can be obtained by rolling the high-purity aluminum material. The rolling process is performed by a normal method such as a method of repeatedly passing the ingot between these rolls while applying pressure by sandwiching the ingot between a pair of rolls. Until then, rough rolling and finish rolling may be performed. Moreover, what is necessary is just to perform the intermediate annealing mentioned later when material hardens | cures during rough rolling.

(粗圧延)
粗圧延は熱間圧延でも冷間圧延でもよく、例えばCr、Mo、W、V、Co等の成分元素を含む通常の合金鋼製ロールを用いて、高純度アルミニウム材を、このロール間に目的の板厚になるまで繰り返し通過させるといった通常の方法で圧延する。冷間粗圧延加工する場合は、90%以下、好ましくは50〜90%の加工率で高純度アルミニウム材を圧延加工する。加工率が50%より低いと生産性が低下する。加工率が90%より高いと高純度アルミニウム材表面が硬化しやすくなる。その他の粗圧延加工を行う際の具体的な手法や条件(処理温度、処理時間など)は、特に制限されるものではなく、本発明の効果を損なわない範囲で適宜設定すればよい。
ここで、加工率は、次式で表される。
加工率(%)=100×(圧延前の板厚―圧延後の板厚)/圧延前の板厚
(Rough rolling)
Rough rolling may be hot rolling or cold rolling. For example, using a normal alloy steel roll containing component elements such as Cr, Mo, W, V, and Co, a high-purity aluminum material is used between the rolls. It rolls by the usual method of making it pass repeatedly until it becomes the plate | board thickness of. In the case of cold rough rolling, a high-purity aluminum material is rolled at a processing rate of 90% or less, preferably 50 to 90%. When the processing rate is lower than 50%, the productivity is lowered. When the processing rate is higher than 90%, the surface of the high purity aluminum material is easily cured. Other specific methods and conditions (processing temperature, processing time, etc.) at the time of performing rough rolling are not particularly limited, and may be appropriately set within a range not impairing the effects of the present invention.
Here, the processing rate is expressed by the following equation.
Processing rate (%) = 100 × (sheet thickness before rolling−sheet thickness after rolling) / sheet thickness before rolling

(中間焼鈍)
圧延パスを繰り返すと、圧延中に高純度アルミニウム材表面が硬化しやすくなる。高純度アルミニウム材表面が粗圧延で硬化した場合には中間焼鈍を行い、仕上げ圧延が継続できる硬さに軟化させるのがよい。その条件は、高純度アルミニウム材表面を温度50〜150℃で1〜30分間加熱して大気中放冷することがよい。高純度アルミニウム材表面の温度は50℃より低いと表面が軟化しにくく、150℃より高いと表面の結晶粒が粗大化してクラックの発生原因になりやすい。加熱時間は、通常1〜30分であるが、1分より短いと高純度アルミニウム材表面が軟化しにくく、30分より長いと表面の結晶粒が粗大化しやすくなる。好ましくは加熱時間は5〜15分であると良い。ただし、中間焼鈍は、上記冷間粗圧延での加工率に依存して行われるものではなく、例えば、冷間粗圧延の加工率が90%以上であっても、上記高純度アルミニウム材表面温度と上記加熱時間が本発明の範囲内であれば、中間焼鈍された高純度アルミニウム材表面にクラックは発生しない。
(Intermediate annealing)
When the rolling pass is repeated, the surface of the high-purity aluminum material is easily hardened during rolling. When the surface of the high-purity aluminum material is hardened by rough rolling, it is preferable to perform intermediate annealing and soften it to a hardness at which finish rolling can be continued. The condition is preferably that the surface of the high-purity aluminum material is heated at a temperature of 50 to 150 ° C. for 1 to 30 minutes and allowed to cool in the atmosphere. When the temperature of the surface of the high-purity aluminum material is lower than 50 ° C., the surface is difficult to soften. The heating time is usually 1 to 30 minutes, but if it is shorter than 1 minute, the surface of the high-purity aluminum material is difficult to soften, and if it is longer than 30 minutes, the crystal grains on the surface tend to become coarse. The heating time is preferably 5 to 15 minutes. However, the intermediate annealing is not performed depending on the processing rate in the cold rough rolling, for example, even if the processing rate of the cold rough rolling is 90% or more, the surface temperature of the high purity aluminum material If the heating time is within the range of the present invention, cracks do not occur on the surface of the high-purity aluminum material subjected to intermediate annealing.

(仕上圧延)
続いて行う仕上げ圧延は、平滑ロールを使用して、20〜80%の加工率で高純度アルミニウム材を圧延加工する。加工率が20%より低いと平滑な表面が得られない。加工率が80%より高くても良いが、圧延を繰り返すパス数が多くなり圧延が効率的でない。好ましくは加工率が30〜70%であると良い。
1パス加工率は2〜15%が良い。1パス加工率が2%より低いと生産性が低く、15%を超える加工率では圧延すると圧延中の結晶粒の粗大化が生じやすくなる。さらに好ましくは1パス加工率が5〜10%であると良い。
ここで、1パス加工率は、次式で表される。
1パス加工率(%)=100×(圧延前の板厚−1パス圧延後の板厚)/圧延前の板厚
(Finish rolling)
Subsequent finish rolling uses a smooth roll to roll a high-purity aluminum material at a processing rate of 20 to 80%. If the processing rate is lower than 20%, a smooth surface cannot be obtained. Although the processing rate may be higher than 80%, the number of passes in which rolling is repeated increases and rolling is not efficient. The processing rate is preferably 30 to 70%.
The 1-pass processing rate is preferably 2 to 15%. When the one-pass processing rate is lower than 2%, the productivity is low, and when the processing rate exceeds 15%, the rolling tends to cause coarsening of crystal grains during rolling. More preferably, the one-pass processing rate is 5 to 10%.
Here, the one-pass processing rate is expressed by the following equation.
1 pass processing rate (%) = 100 × (plate thickness before rolling−sheet thickness after 1 pass rolling) / plate thickness before rolling

仕上圧延に用いる上記平滑ロールはCrメッキした研磨ロールを用いればよい。例えば、高Cr鋼製ロールの表面を研磨後、Crメッキし、さらに仕上げ研磨したものなどで、該ロール表面の粗さは、JIS―B0601:2001に規定されている最大高さ粗さが0.05〜3μmであるものがよく、好ましくは0.1μm程度のものがよい。前記表面のロールの最大高さ粗さが、0.05μmより低いと研磨コストが高く実用的でない。3μmより高いと仕上圧延された高純度アルミニウム圧延材は鏡面にならず光輝性が低下する。   The smooth roll used for finish rolling may be a Cr-plated polishing roll. For example, the surface of a high Cr steel roll is polished, then plated with Cr, and then subjected to finish polishing. The roughness of the roll surface is such that the maximum height roughness specified in JIS-B0601: 2001 is 0. A thickness of 0.05 to 3 μm is preferable, and a thickness of about 0.1 μm is preferable. When the maximum height roughness of the roll on the surface is lower than 0.05 μm, the polishing cost is high and not practical. If it is higher than 3 μm, the high-purity aluminum rolled material that has been finish-rolled does not have a mirror surface, and the glitter is reduced.

仕上圧延中の高純度アルミニウム材の温度は0〜50℃がよい。高純度アルミニウム材の温度は0℃よりも低くても良いが、室温以下では生産性が低下する。50℃より高いと再結晶により圧延中に結晶粒が粗大化して、クラックの発生原因になる。   The temperature of the high-purity aluminum material during finish rolling is preferably 0 to 50 ° C. The temperature of the high-purity aluminum material may be lower than 0 ° C., but the productivity is lowered below room temperature. If the temperature is higher than 50 ° C., the crystal grains become coarse during rolling due to recrystallization, causing cracks.

(高純度アルミニウム圧延板)
前記方法で圧延した高純度アルミニウム圧延板は、純度99.999質量%以上のアルミニウムからなる板厚0.1〜3mmの高純度アルミニウム圧延板であり、該高純度アルミニウム圧延板の表面に観察される結晶の平均結晶粒径が50μm以下と細かい方がよい。前記平均結晶粒径が50μmより大きいと、圧延中に圧延方向と直角方向の圧延材の表面に粗大な結晶粒に起因する微細なクラックが発生するため、平滑な表面が得られない。
(High purity aluminum rolled plate)
The high purity aluminum rolled sheet rolled by the above method is a high purity aluminum rolled sheet having a thickness of 0.1 to 3 mm made of aluminum having a purity of 99.999% by mass or more, and is observed on the surface of the high purity aluminum rolled sheet. It is better that the average crystal grain size of the crystals is as fine as 50 μm or less. If the average crystal grain size is larger than 50 μm, a fine surface due to coarse crystal grains is generated on the surface of the rolled material in the direction perpendicular to the rolling direction during rolling, so that a smooth surface cannot be obtained.

本発明の高純度アルミニウム圧延板の表面粗さは、JIS―B0601:2001に規定されている算術平均粗さRaが0.05μm以下、好ましくは0.02μm以下である方が良い。前記表面の算術平均粗さRaが0.05μmよりも大きいと、高純度アルミニウム圧延板の表面が鏡面にならず光輝性が低くなる。   As for the surface roughness of the high-purity aluminum rolled sheet of the present invention, the arithmetic average roughness Ra specified in JIS-B0601: 2001 is 0.05 μm or less, preferably 0.02 μm or less. When the arithmetic average roughness Ra of the surface is larger than 0.05 μm, the surface of the high-purity aluminum rolled sheet does not become a mirror surface and the glitter is lowered.

本発明の高純度アルミニウム圧延板の硬さは、ビッカーズ硬度で28Hv以上である方が良い。前記ビッカーズ硬度が28Hvよりも低いと、前記圧延板が柔らかくなりすぎて高純度アルミニウム圧延板の表面にクラックが発生する。   The hardness of the high-purity aluminum rolled sheet of the present invention is preferably 28 Hv or more in terms of Vickers hardness. If the Vickers hardness is lower than 28 Hv, the rolled plate becomes too soft and cracks are generated on the surface of the high-purity aluminum rolled plate.

本発明の高純度アルミニウム圧延板の表面は、一般照明、発光ダイオード照明、フラットディスプレーのバックライトなどの反射板などに利用するために鏡面である必要がある。
本発明の高純度アルミニウム圧延板は、従来のように化学研磨や電解研磨などの表面研磨処理を施すことなく、平滑な表面を有する板材を得ることができる。前記表面研磨処理としては、例えば、社団法人日本アルミニウム協会発行「アルミニウムハンドブック(第7版)」180ページに記載のような公知の電解研磨や化学研磨等の方法がある。
The surface of the high-purity aluminum rolled sheet of the present invention needs to be a mirror surface for use in reflectors such as general illumination, light-emitting diode illumination, and flat display backlights.
The high-purity aluminum rolled sheet of the present invention can obtain a plate material having a smooth surface without performing a surface polishing treatment such as chemical polishing or electrolytic polishing as in the prior art. Examples of the surface polishing treatment include known electropolishing and chemical polishing methods described in page 180 of “Aluminum Handbook (7th edition)” issued by the Japan Aluminum Association.

以上のような本発明の高純度アルミニウム圧延板は、一般照明、発光ダイオード照明、フラットディスプレーのバックライトなどの反射材やナノポアーを有する陽極酸化皮膜を形成するに適した平滑基板などに利用できる。表面研磨工程が無いので生産性が向上し、化学薬品や電解電力を消費しない環境負荷の低い材料が得られる。   The high-purity aluminum rolled sheet of the present invention as described above can be used as a smooth substrate suitable for forming a reflective material such as general illumination, light-emitting diode illumination, and flat display backlight, and an anodized film having nanopores. Since there is no surface polishing step, productivity is improved, and a material with low environmental load that does not consume chemicals or electrolytic power can be obtained.

以下、実施例により本発明をより詳細に説明するが、本発明は、かかる実施例により限定されるものではない。   EXAMPLES Hereinafter, although an Example demonstrates this invention in detail, this invention is not limited by this Example.

(性能の評価)
<元素含有量の測定>
以下の実施例および比較例において、アルミニウム(高純度アルミニウム)中の各元素含有量の測定は、以下の方法で行なった。
アルミニウム(高純度アルミニウム)中の各元素含有量は、グロー放電質量分析法(サーモエレクトロン社製「VG9000」を使用)にて測定した。
<鏡面の評価>
鏡面は、目視にてロール模様が無し(○)、有り(×)で評価した。
<粗さの測定>
表面の粗さはJIS―B0601:2001に規定されている算術平均粗さRaを求めた。
<クラックの評価>
圧延板表面を走査型電子顕微鏡にて500倍の二次電子線像を観察し、クラックが無し(○)、有り(×)で評価した。
<ビッカース硬度の測定>
ビッカース硬度計にて荷重5Kgで、ビッカーズ硬さ(Hv)を求めた。
<結晶粒径の測定>
圧延板表面をエメリー紙とバフ研磨後、電解研磨して、5%NaOH水溶液を水温50℃で5分間の腐食処理して、光学顕微鏡で圧延板表面の結晶粒を観察した。また、この圧延板の表面を電子顕微鏡で拡大して撮影された写真に直線(計測長)を引き(倍率50倍では1600μm、倍率200倍では400μmの直線)、この直線内の結晶粒数を計数し、結晶粒径を次式で求めた。
結晶粒子径=計測長/粒数
(Evaluation of performance)
<Measurement of element content>
In the following examples and comparative examples, the content of each element in aluminum (high purity aluminum) was measured by the following method.
The content of each element in aluminum (high purity aluminum) was measured by glow discharge mass spectrometry (using “VG9000” manufactured by Thermo Electron).
<Evaluation of mirror surface>
The mirror surface was visually evaluated as having no roll pattern (O) and having (X).
<Measurement of roughness>
As the surface roughness, arithmetic average roughness Ra defined in JIS-B0601: 2001 was determined.
<Evaluation of crack>
A 500-fold secondary electron beam image was observed on the surface of the rolled plate with a scanning electron microscope, and evaluation was made with no cracks (O) and presence (X).
<Measurement of Vickers hardness>
The Vickers hardness (Hv) was determined with a load of 5 kg with a Vickers hardness tester.
<Measurement of crystal grain size>
The surface of the rolled plate was buffed with emery paper, electropolished, a 5% NaOH aqueous solution was subjected to corrosion treatment at a water temperature of 50 ° C. for 5 minutes, and crystal grains on the surface of the rolled plate were observed with an optical microscope. Also, a straight line (measurement length) is drawn on a photograph taken by enlarging the surface of the rolled plate with an electron microscope (a straight line of 1600 μm at a magnification of 50 times and 400 μm at a magnification of 200 times), and the number of crystal grains in the straight line Counting was performed, and the crystal grain size was determined by the following formula.
Crystal particle size = measured length / number of grains

(高純度アルミニウム圧延板の製造)
<原料:高純度アルミニウム>
三層電解法により精製して得られた純度99.999質量%のアルミニウム(Si=2質量ppm、Cu=2.2質量ppm、Mg=0.4質量ppm、Fe=1質量ppm、これら以外のその他の31元素<1ppm、不純物35元素合計<7質量ppm)を原料の高純度アルミニウムとした。
(Manufacture of high-purity aluminum rolled sheet)
<Raw material: High purity aluminum>
99.999 mass% aluminum obtained by purification by a three-layer electrolytic method (Si = 2 mass ppm, Cu = 2.2 mass ppm, Mg = 0.4 mass ppm, Fe = 1 mass ppm, other than these) The other 31 elements <1 ppm, 35 impurities total <7 mass ppm) were used as the raw material high-purity aluminum.

<高純度アルミニウム材>
黒鉛ルツボの中に原料の高純度アルミニウム(純度99.999質量%)を入れ、これを780℃で真空溶解させた後、150℃の鋳鉄鋳型(内寸法:幅150mm×長さ200mm×高さ22mm)に鋳造し、得られた高純度アルミニウム材の圧延する両面を1mm面削除去し、幅110mm×長さ180mm×厚さ20mmで切断した。以下、試料No.1〜5は、この高純度アルミニウム材を用いた。
<High purity aluminum material>
A high-purity aluminum (purity 99.999 mass%) as a raw material is placed in a graphite crucible, and this is vacuum-melted at 780 ° C., and then cast at 150 ° C. (internal dimensions: width 150 mm × length 200 mm × height) The obtained high-purity aluminum material was removed by removing 1 mm of both surfaces to be rolled and cut at a width of 110 mm × a length of 180 mm × a thickness of 20 mm. Hereinafter, sample No. 1 to 5 used this high-purity aluminum material.

(試料No.1〜No.6)
以下、(A)〜(D)の工程を経て、試料No.1〜6の高純度アルミニウム圧延板を製作した。各試料についての各工程における圧延条件を表1に示す。
(Sample No. 1 to No. 6)
Hereinafter, through the steps (A) to (D), the sample No. 1 to 6 high-purity aluminum rolled sheets were produced. Table 1 shows the rolling conditions in each step for each sample.

(A)熱間圧延
上記高純度アルミニウム材を、一対の合金鋼製の熱間圧延ロール[直径150mm、JIS―B0601:2001に規定される最大高さ粗さは2μm。]の間に挟みこむことにより圧力をかけ、500℃で、1パスあたり板厚を2mmの圧下量で圧延させて、表1に示すように、試料No.1〜3について板厚を20mmから8mmへと熱間圧延させることで、幅110mm×長さ450mm×厚さ8mmの高純度アルミニウム材を得た。その後、該高純度アルミニウム材の温度が室温になるまで放冷させた。尚、試料No.4〜6については、熱間圧延は行わなかった。
(A) Hot Rolling The high-purity aluminum material is a pair of alloy steel hot-rolling rolls (diameter 150 mm, maximum height roughness specified in JIS-B0601: 2001 is 2 μm. ], And rolled at a reduced thickness of 2 mm per pass at 500 ° C., as shown in Table 1, sample No. By hot-rolling the plate thickness from 20 mm to 8 mm for 1-3, a high-purity aluminum material having a width of 110 mm, a length of 450 mm, and a thickness of 8 mm was obtained. Thereafter, the high-purity aluminum material was allowed to cool to room temperature. Sample No. About 4-6, hot rolling was not performed.

(B)冷間粗圧延
上記熱間圧延後、該熱間圧延で用いたものと同じロールで圧力をかけ、室温で1パスの加工率が10〜20%の割合で圧延させた。これを表1に示すように、板厚が1.5〜3.3mmになるまで繰り返し圧延し、高純度アルミニウム材を得た。
詳しくは、鋳造で得られた高純度アルミニウム材、幅110mm×長さ180mm×厚さ20mmを、厚さ3.3mmまで繰り返し圧延し、幅110mm×長さ1090mm×厚さ3.3mmとし、これから長さ400mmを切り取って試料No.1の高純度アルミニウム材とした。
続いて残りの長さ690mmを厚さ3mmまで圧延し、幅110mm×長さ760mm×厚さ3mmとし、これから長さ400mmを切り取って試料No.2の高純度アルミニウム材とした。
続いて残りの長さ360mmを厚さ1.5mmになるまで繰り返し圧延し、幅110mm×長さ720mm×厚さ1.5mmとし、試料No.3の高純度アルミニウム材とした。
また鋳造で得られた高純度アルミニウム材、幅110mm×長さ180mm×厚さ20mmを、厚さ3mmまで繰り返し圧延し、幅110mm×長さ1200mm×厚さ3mmとし、これから長さ400mmを切り取って試料No.4の高純度アルミニウム材とした。
続いて残りの長さ800mmを厚さ1.5mmまで圧延し、幅110mm×長さ1600mm×厚さ1.5mmとし、試料No.5の高純度アルミニウム材とした。
原料の高純度アルミニウムを純度99.7%のアルミニウムに変えて鋳造し、得られたアルミニウム材、幅110mm×長さ180mm×厚さ20mmを、厚さ3mmまで繰り返し圧延し、幅110mm×長さ1200mm×厚さ3mmとし、試料No.6のアルミニウム材とした。
このとき圧延中の試料の温度は、圧延時の発熱により50℃程度になったら20℃の水で浸漬して冷却し、約20℃〜50℃に保った。冷間粗圧延終了後、上記高純度アルミニウム材およびアルミニウム材を20℃の水中に浸漬させ、温度を20〜25℃に冷却した。
(B) Cold rough rolling After the hot rolling, pressure was applied with the same roll as that used in the hot rolling, and rolling was performed at a rate of 10 to 20% at 1 room temperature at room temperature. As shown in Table 1, this was repeatedly rolled until the plate thickness became 1.5 to 3.3 mm to obtain a high-purity aluminum material.
Specifically, the high-purity aluminum material obtained by casting, width 110 mm × length 180 mm × thickness 20 mm, repeatedly rolled to a thickness of 3.3 mm, width 110 mm × length 1090 mm × thickness 3.3 mm, A length of 400 mm was cut off and Sample No. 1 high-purity aluminum material.
Subsequently, the remaining length of 690 mm was rolled to a thickness of 3 mm to obtain a width of 110 mm × a length of 760 mm × a thickness of 3 mm. 2 high-purity aluminum material.
Subsequently, the remaining length of 360 mm was repeatedly rolled to a thickness of 1.5 mm to obtain a width of 110 mm × a length of 720 mm × a thickness of 1.5 mm. 3 high-purity aluminum material.
Also, the high-purity aluminum material obtained by casting, width 110 mm × length 180 mm × thickness 20 mm, was repeatedly rolled to a thickness of 3 mm to obtain a width 110 mm × length 1200 mm × thickness 3 mm, from which a length of 400 mm was cut. Sample No. No. 4 high-purity aluminum material.
Subsequently, the remaining length of 800 mm was rolled to a thickness of 1.5 mm to obtain a width of 110 mm × a length of 1600 mm × a thickness of 1.5 mm. 5 high-purity aluminum material.
High-purity aluminum as a raw material was cast into aluminum with a purity of 99.7%, and the obtained aluminum material, width 110 mm × length 180 mm × thickness 20 mm, was repeatedly rolled to a thickness of 3 mm, width 110 mm × length 1200 mm × thickness 3 mm. 6 aluminum material.
At this time, when the temperature of the sample during rolling reached about 50 ° C. due to heat generated during rolling, the sample was immersed in water at 20 ° C. and cooled, and kept at about 20 ° C. to 50 ° C. After the cold rough rolling, the high-purity aluminum material and the aluminum material were immersed in 20 ° C. water, and the temperature was cooled to 20 to 25 ° C.

(C)中間焼鈍
冷間粗圧延した試料No.4について、幅110mm×長さ200mm×厚さ3mmに切断して、温度100℃で10分間加熱して大気中で放冷させることにより、中間焼鈍を行った。
冷間粗圧延した試料No.5について、幅110mm×長さ200mm×厚さ1.5mmに切断して、温度200℃で10分間加熱して大気中で放冷させることにより、中間焼鈍を行った(表1参照)。
(C) Intermediate annealing Cold rough rolled sample No. No. 4 was cut into a width of 110 mm, a length of 200 mm, and a thickness of 3 mm, heated at a temperature of 100 ° C. for 10 minutes, and allowed to cool in the air, thereby performing intermediate annealing.
Cold rough rolled sample No. 5 was cut into a width of 110 mm, a length of 200 mm, and a thickness of 1.5 mm, heated at a temperature of 200 ° C. for 10 minutes, and allowed to cool in the air, thereby performing intermediate annealing (see Table 1).

(D)冷間仕上圧延
幅110mm×長さ200mmに切断した冷間粗圧延した試料No.1〜3および試料No.6と中間焼鈍した試料No.4および5を、一対のCrメッキ合金製圧延ロール(直径124mm、JIS―B0601:2001に規定される最大高さ粗さは0.1μm。)の間に挟み込むことにより、圧力をかけ、室温で1パスの加工率が5〜12%の割合で圧延させた。これを板厚が1〜3mmになるまで表1に示すパス数で、かつ同表に示す加工率で繰り返し圧延し、幅110mm×長さ220〜600mm×厚さ1〜3mmの高純度アルミニウム圧延板を得た。このとき冷間圧延中の試料温度は、約20〜40℃であった。
(D) Cold finish rolling Cold rough rolled sample No. 1 cut into a width of 110 mm and a length of 200 mm. 1 to 3 and sample no. 6 and intermediate annealed sample No. 4 and 5 are sandwiched between a pair of rolling rolls made of a Cr plating alloy (diameter 124 mm, maximum height roughness specified in JIS-B0601: 2001 is 0.1 μm), pressure is applied at room temperature. Rolling was performed at a rate of 5 to 12% in one pass. This is repeatedly rolled at the number of passes shown in Table 1 and at the processing rate shown in the table until the plate thickness reaches 1 to 3 mm, and is rolled with high purity aluminum having a width of 110 mm, a length of 220 to 600 mm, and a thickness of 1 to 3 mm. I got a plate. At this time, the sample temperature during the cold rolling was about 20 to 40 ° C.

以上のように得られた試料のうち、No.3〜6の高純度アルミニウム圧延板の表面を電子顕微鏡で拡大して撮影した。その顕微鏡写真を図1〜4に示した。   Among the samples obtained as described above, No. The surface of 3 to 6 high-purity aluminum rolled sheets was enlarged and photographed with an electron microscope. The micrographs are shown in FIGS.

また、得られた試料No.1〜6の高純度アルミニウム圧延板に対して、表面状態、表面の結晶粒、圧延板の硬度の評価・測定を行った。その結果を表2に示した。   In addition, the obtained sample No. The surface state, the surface crystal grains, and the hardness of the rolled plate were evaluated and measured for 1 to 6 high-purity aluminum rolled plates. The results are shown in Table 2.

試料No.2および3は、冷間圧延工程の粗圧延、仕上圧延において表1に示すように、圧延加工率、仕上圧延1パス加工率が本発明に係る範囲を満たすため、試料No.2および3で得られた高純度アルミニウム圧延材の表面状態は表2に示すように、未研磨材でありながら、鏡面であり、表面の算術平均粗さRaは0.01μmであり、クラックの発生が無くなっている。
試料No.4は、冷間圧延工程の粗圧延、中間焼鈍、仕上圧延において表1に示すように、圧延加工率、中間焼鈍における高純度アルミニウム材の表面温度、仕上圧延1パス加工率が本発明に係る範囲を満たすため、試料No.4で得られた高純度アルミニウム圧延材の表面状態は表2に示すように、未研磨材でありながら、鏡面であり、表面の算術平均粗さRaは0.01μmであり、クラックの発生が無くなっている。
これに対して、試料No.1は、冷間圧延工程の粗圧延において表1に示すように、圧延加工率が本発明に係る範囲を満たすが、仕上圧延においては表1に示すように、仕上圧延1パス加工率、圧延加工率ともに本発明に係る範囲を満たさないため、試料No.1で得られた高純度アルミニウム圧延材の表面状態は表2に示すように、鏡面ではなく、表面粗さは高いものになっている。
試料No.5は、冷間圧延工程の粗圧延、中間焼鈍において表1に示すように、圧延加工率が本発明に係る範囲を満たず、中間焼鈍における高純度アルミニウム材の表面温度も本発明に係る範囲を満たさないため、試料No.5で得られた高純度アルミニウム圧延材の表面状態は表2に示すように、鏡面であるが、結晶粒径が大きいためにクラックが発生している。
試料No.6は、原料純度が本発明に係る範囲を満たさないため、アルミニウム圧延材の表面状態は表2に示すように、鏡面であるが、クラックが発生している。
Sample No. As shown in Table 1 in rough rolling and finish rolling in the cold rolling process, Samples Nos. 2 and 3 satisfy the ranges according to the present invention in terms of the rolling processing rate and the finishing rolling 1-pass processing rate. As shown in Table 2, the surface state of the high-purity aluminum rolled material obtained in 2 and 3 is a mirror surface while being an unpolished material, and the arithmetic average roughness Ra of the surface is 0.01 μm. The occurrence is gone.
Sample No. 4 shows the rolling processing rate, the surface temperature of the high-purity aluminum material in the intermediate annealing, and the finishing rolling 1-pass processing rate according to the present invention, as shown in Table 1 in the rough rolling, intermediate annealing, and finish rolling in the cold rolling process. In order to satisfy the range, sample no. As shown in Table 2, the surface state of the high-purity aluminum rolled material obtained in No. 4 is a mirror surface while being an unpolished material, the arithmetic average roughness Ra of the surface is 0.01 μm, and cracks are generated. It's gone.
In contrast, sample no. As shown in Table 1, the rolling processing rate satisfies the range according to the present invention as shown in Table 1 in the rough rolling of the cold rolling process. In finish rolling, as shown in Table 1, the finishing rolling 1-pass processing rate, rolling Since the processing rate does not satisfy the range according to the present invention, the sample No. As shown in Table 2, the surface state of the high-purity aluminum rolled material obtained in 1 is not a mirror surface, but has a high surface roughness.
Sample No. As shown in Table 1, in the rough rolling and intermediate annealing of the cold rolling process, 5 is the range in which the rolling processing rate does not satisfy the range according to the present invention, and the surface temperature of the high-purity aluminum material in the intermediate annealing is also according to the present invention. In this case, sample no. As shown in Table 2, the surface state of the high-purity aluminum rolled material obtained in 5 is a mirror surface, but cracks are generated because the crystal grain size is large.
Sample No. In No. 6, since the raw material purity does not satisfy the range according to the present invention, the surface state of the rolled aluminum material is a mirror surface as shown in Table 2, but cracks are generated.

Claims (4)

純度99.999質量%以上である高純度アルミニウム圧延板であって、
該圧延板の表面が研磨処理を施されていない鏡面であり、
表面の算術平均粗さRaが0.05μm以下であり、
表面の結晶粒径が50μm以下であることを特徴とする高純度アルミニウム圧延板。
A high-purity aluminum rolled sheet having a purity of 99.999% by mass or more,
The surface of the rolled plate is a mirror surface that has not been polished,
The arithmetic average roughness Ra of the surface is 0.05 μm or less,
A high-purity aluminum rolled sheet having a surface crystal grain size of 50 μm or less.
純度99.999質量%以上である高純度アルミニウムからなる高純度アルミニウム材を冷間粗圧延をした後に、平滑ロールを使用して、冷間仕上圧延をする高純度アルミニウム圧延板の製造方法であって、
冷間粗圧延の加工率が90%以下で、かつ冷間仕上圧延の加工率が20〜80%であり、
冷間仕上圧延は、前記高純度アルミニウム材の温度を0〜50℃に保ちながら、1パス加工率が2〜15%で行われることを特徴とする請求項1に記載の高純度アルミニウム圧延板の製造方法。
This is a method for producing a high-purity aluminum rolled sheet in which a high-purity aluminum material made of high-purity aluminum having a purity of 99.999% by mass or more is subjected to cold rough rolling and then cold-finished using a smooth roll. And
The processing rate of cold rough rolling is 90% or less, and the processing rate of cold finish rolling is 20 to 80%,
2. The high purity aluminum rolled sheet according to claim 1, wherein the cold finish rolling is performed at a 1-pass processing rate of 2 to 15% while maintaining a temperature of the high purity aluminum material at 0 to 50 ° C. 3. Manufacturing method.
純度99.999質量%以上である高純度アルミニウムからなる高純度アルミニウム材を冷間粗圧延をした後に、平滑ロールを使用して、冷間仕上圧延をする高純度アルミニウム圧延板の製造方法であって、
冷間粗圧延と冷間仕上圧延との間に、表面温度50〜150℃で1〜30分間加熱後、大気中で放冷する中間焼鈍が行われ、
前記冷間仕上圧延は、加工率が20〜80%であり、
かつ前記高純度アルミニウム材の温度を0〜50℃に保ちながら、1パス加工率が2〜15%で行われることを特徴とする請求項1に記載の高純度アルミニウム圧延板の製造方法。
This is a method for producing a high-purity aluminum rolled sheet in which a high-purity aluminum material made of high-purity aluminum having a purity of 99.999% by mass or more is subjected to cold rough rolling and then cold-finished using a smooth roll. And
Between the cold rough rolling and the cold finish rolling, intermediate annealing is performed after heating at a surface temperature of 50 to 150 ° C. for 1 to 30 minutes and then allowing to cool in the atmosphere.
The cold finish rolling has a processing rate of 20 to 80%,
The method for producing a high-purity aluminum rolled sheet according to claim 1, wherein the one-pass processing rate is 2 to 15% while maintaining the temperature of the high-purity aluminum material at 0 to 50 ° C.
前記平滑ロールは表面の最大高さ粗さが0.05〜3μmである請求項2または3に記載の高純度アルミニウム圧延板の製造方法。   The method for producing a high-purity aluminum rolled sheet according to claim 2 or 3, wherein the smooth roll has a maximum surface roughness of 0.05 to 3 µm.
JP2009240504A 2009-10-19 2009-10-19 High purity aluminum rolled sheet and method for producing the rolled sheet Pending JP2011084800A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2020158800A (en) * 2019-03-25 2020-10-01 住友化学株式会社 High-purity aluminum sheet and method for producing the same, and power semiconductor module including high-purity aluminum sheet
CN112425271A (en) * 2018-07-18 2021-02-26 三菱综合材料株式会社 Metal base substrate
WO2022025213A1 (en) * 2020-07-30 2022-02-03 住友化学株式会社 Aluminum member and manufacturing method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112425271A (en) * 2018-07-18 2021-02-26 三菱综合材料株式会社 Metal base substrate
JP2020158800A (en) * 2019-03-25 2020-10-01 住友化学株式会社 High-purity aluminum sheet and method for producing the same, and power semiconductor module including high-purity aluminum sheet
WO2022025213A1 (en) * 2020-07-30 2022-02-03 住友化学株式会社 Aluminum member and manufacturing method thereof

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