JP2011068103A - Low-insect alluring trap sheet and illuminant using the sheet - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a low-insect alluring trap sheet which shows superior insect alluring properties and moldability while possessing a superb designability which emanates a feel peculiar to a material used, as well as a Japanese style illuminant. <P>SOLUTION: This low-insect alluring trap sheet is constituted of at least a base material A, a low-insect alluring functional layer, a base material B and a feel imparting layer formed of a resin composition containing microparticles, laminated in that order. In addition, at least the low-insect alluring functional layer of the sheet contains an ultraviolet absorber and the content of the ultraviolet absorber is 1 to 28 g/m<SP>2</SP>for the whole sheet. Besides, the content of the microparticles in the resin composition is 1 to 30 mass%. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

  The present invention relates to a low insect attracting sheet and a lighting apparatus using the same.

  Since insects such as insects, pests, and moths generally have a habit of traveling toward a light source including wavelengths in the ultraviolet region of 410 nm or less, particularly in the range of 340 to 410 nm, A group of light sources such as white fluorescent lamps that radiate light in the region may cluster, and this tendency is remarkable outdoors. In addition, indoors, especially in living rooms, insects attracted by indoor lighting are very annoying and unhygienic, and dirt accumulated by insects on the lighting cover is unsightly and uncomfortable. Give. In recent years, with increasing awareness of the living space environment, in order to reduce insects attracted by light sources, there has been a demand for luminaires that have a low susceptibility to attract insects.

  As a lighting apparatus having a low insect attracting property, Patent Document 1 discloses a technique relating to a resin lighting cover obtained by molding and stretching a resin plate containing a specific ultraviolet absorber. However, since the cover obtained by this technique is obtained by molding and stretching, it does not have decoration such as a pattern, and it cannot express a complicated shape due to lack of workability due to thickness. There was a problem of poor sex.

  On the other hand, as an illumination cover used for a lighting device having excellent design properties, for example, in Patent Document 2, a transparent synthetic resin thin plate such as an acrylic resin thin plate is bonded to both sides of a Japanese paper sheet such as Japanese paper or Japanese paper rayon paper. A technique related to the decorative synthetic resin sheet is disclosed. However, the decorative synthetic resin sheet is excellent in design that can express a complicated shape because the thickness of the resin sheet used is as thin as about 50 μm, but it absorbs ultraviolet rays due to the limitation of the thickness of the resin sheet. There was a problem that the added amount of the agent was insufficient, and the low repellency could not be sufficiently provided.

  By the way, with the diversification of consumer preferences, a sense of design that makes the material itself feel a unique feel, such as the feel of Japanese paper if it is a Japanese paper cover, and the feel of a wood texture if it is a wood grain cover is required. ing. However, the lighting cover as described above has not been able to sufficiently meet such a demand.

JP 2000-67629 A JP-A-8-103990

  Under such circumstances, the present invention has a low worming sheet having excellent low worming property and moldability while having an excellent design property that makes the material feel a tactile sensation, and a Japanese style using the same. It aims at providing a lighting fixture.

  As a result of intensive studies to achieve the above object, the present inventors have obtained a layer that can contain a predetermined ultraviolet absorber in the sheet and a layer that contains a predetermined amount of fine particles in the outermost layer of the sheet. It has been found that the above-mentioned problems can be solved by providing them. The present invention has been completed based on such findings.

That is, the present invention
(1) A low sensation sheet formed by sequentially laminating a tactile sensation providing layer formed of a resin composition containing at least a base material A, a low repellency functional layer, a base material B, and fine particles, The insect-absorptive functional layer contains an ultraviolet absorber, the content of the ultraviolet absorber as the whole sheet is 1 to 28 g / m ² , and the content of fine particles in the resin composition is 1 to 30% by mass. A low worm sheet, which is
(2) The low worm-inducing sheet according to (1) above, wherein the low worm-insulating functional layer is composed of two layers,
(3) The low sensation sheet according to the above (2), which has an adhesive layer between two layers of the low sensation functional layer,
(4) The low worm sheet according to any one of (1) to (3), further comprising a pattern layer between the base material B and the tactile sensation providing layer,
(5) The low worm sheet according to any one of (1) to (4), wherein the fine particles are at least one selected from silica fine particles, aluminum hydroxide fine particles, acrylic resin filler, urethane resin filler, and urea resin filler,
(6) The low worm sheet according to any one of (1) to (5), wherein the average particle diameter of the fine particles is 0.1 to 30 μm,
(7) A method for producing a low worm sheet having the following steps (A) to (C),
Step (A): Step of forming a low worm-insulating functional layer by applying an ionizing radiation curable resin composition containing an ultraviolet absorber and an ionizing radiation curable resin to the substrate A and / or the substrate B ( B): Step of applying a resin composition containing fine particles to the base material B to form a tactile sensation providing layer (C): the low worm-insulating functional layer is between the base material A and the base material B As described above, the step (8) of laminating the base material A and the base material B via an adhesive further has at least one feature of the following (i) to (iii): (1) to (6) above A Japanese-style lighting fixture cover obtained by sticking or fitting a low worming sheet according to any one of the above to a wooden frame (including a case where a material having a wood-like design is used), and (i) a base material layer A or The base material layer B contains a cut piece of Japanese paper or fabric. (Ii) The pattern layer is a Japanese paper pattern or a fabric pattern. iii) further has a layer made of Japanese paper or fabric (9) Japanese luminaire comprising using Japanese luminaire cover according to the above (8),
Is to provide.

  According to the present invention, there is obtained a low worm sheet having an excellent design that makes the material feel a tactile sensation, and has an excellent low pesticidal property and moldability, and a Japanese-style lighting apparatus using the same. Can do.

It is a schematic diagram which shows the cross section of the low worm insect sheet | seat of this invention. It is a schematic diagram which shows the cross section of the low worm insect sheet | seat of this invention.

[Low insect repellent sheet]
The low worm sheet of the present invention is formed by sequentially laminating at least a base material A, a low worm function layer, a base material B, and a tactile sensation providing layer formed of a resin composition containing fine particles. The functional layer contains an ultraviolet absorber, the content of the ultraviolet absorber as the whole sheet is 1 to 28 g / m ² , and the content of fine particles in the resin composition is 1 to 30% by mass. It is characterized by being.
The structure of the low worm sheet of the present invention will be described with reference to FIGS. FIG. 1 is a schematic diagram showing a cross section of one example of the layer structure of the low worm sheet 1 of the present invention. A low worming sheet 1 shown in FIG. 1 is obtained by sequentially laminating a low worming functional layer 3, a base material B, and a tactile sensation providing layer 7 including fine particles 8 on the surface of a base material A. Moreover, FIG. 2 is the schematic diagram which showed the cross section for one of the preferable layer structure of the low moth-absorbing sheet 1 of this invention as an example. The low sensation sheet 1 shown in FIG. 2 is formed on the surface of the base material A, on the surface of the base material A, the low susceptibility functional layer 31, the adhesive layer 4, the low susceptibility functional layer 32, the base material B, the pattern layer 5, The colored solid layer 6 and the tactile sensation providing layer 7 including the fine particles 8 are sequentially laminated.

"Base material"
Although the base material A and the base material B used by this invention will not be specifically limited if normally used as a base material, Preferably a plastic film, a plastic sheet, etc. can be suitably selected according to a use.

  As a plastic film or a plastic sheet, what consists of various synthetic resins is mentioned. Synthetic resins include low density polyethylene resins (including linear low density polyethylene resins), medium density polyethylene resins, high density polyethylene resins, ethylene-α olefin copolymers, polypropylene resins, polymethylpentene resins, polybutene resins, ethylene. -Polyolefin resins such as propylene copolymer, propylene-butene copolymer, olefinic thermoplastic elastomer or mixtures thereof; polyethylene terephthalate resin, polybutylene terephthalate resin, polyethylene naphthalate-isophthalate copolymer resin, polyester heat Polyester resins such as plastic elastomers; Acrylic resins such as poly (meth) methyl acrylate resin, poly (meth) ethyl acrylate resin, poly (meth) butyl acrylate resin; nylon 6 or Polyamide resins represented by like nylon 66; polystyrene resins; polycarbonate resins; polyarylate resin; cellulose triacetate resins, cellulose resins such as cellophane and the like or a polyimide resin.

  The substrate can be used as a film or a sheet alone or in combination of two or more of the synthetic resins described above. The synthetic resin is preferably a polyolefin resin or a polyester resin, and in particular, compatibility with the low worm-insulating functional layer, which will be described later, that no toxic chlorine-based gas is generated when the manufactured decorative sheet is disposed of by incineration and disposal, and the cost From such viewpoints, a polyolefin resin is more preferable, and a polypropylene resin is particularly preferable. Further, the base material A and the base material B may be the same or different, and may be appropriately selected from the above.

The substrate may be a commercially available plastic film or plastic sheet made of the above-described synthetic resin, or may be used as a film or sheet by a film forming method such as a calendar method, an inflation method, or a T-die extrusion method. Moreover, the ultraviolet absorber mentioned later may be contained in the base material with the above-mentioned synthetic resin. Content of a ultraviolet absorber is about 0.1-10 mass parts with respect to 100 mass parts of synthetic resins.
Although there is no restriction | limiting in particular about the thickness of a base material, when a moldability etc. are considered, it is about 20-200 micrometers normally, Preferably it is 20-150 micrometers, More preferably, it is the range of 50-150 micrometers.

The base material can be subjected to physical or chemical surface treatment such as an oxidation method or an unevenness method on one side or both sides, if desired, in order to improve the adhesion with the layer provided thereon.
Examples of the oxidation method include corona discharge treatment, chromium oxidation treatment, flame treatment, hot air treatment, ozone / ultraviolet treatment method, and examples of the unevenness method include a sand blast method and a solvent treatment method. These surface treatments are appropriately selected depending on the type of substrate, but generally, a corona discharge treatment method is preferably used from the viewpoints of effects and operability.
In addition, the base material may be subjected to a treatment such as forming a primer layer for the purpose of enhancing interlayer adhesion with other adjacent layers.

  In addition, as a base material, a film or sheet obtained by a film forming method such as a T-die extrusion method is used by adding a material such as Japanese paper or fabric, which is appropriately finely cut to a synthetic resin as described above, by cutting or the like. You can also. By using such a film or sheet as a base material, a Japanese-style design can be imparted to the sheet of the present invention.

《Low-insect functional layer 3》
The low worm-inducing function layer 3 is a layer that is provided between the base material A and the base material B and imparts low susceptibility to the sheet of the present invention. There is no particular limitation on the low worm-insulating functional layer 3 as long as it is between the base material A and the base material B. For example, one layer as shown in FIG. Two layers of 32 or a plurality of layers may be used. From the viewpoint of obtaining an excellent low susceptibility by incorporating a large amount of ultraviolet absorber in the sheet of the present invention, the low susceptibility functional layer 3 is preferably a plurality of layers of two or more layers. Moreover, since the low worm-insulating functional layer 3 is between the base material A and the base material B, it becomes possible to prevent the low worm-inducing functional layer from being damaged.

  The low worm-insulating functional layer 3 is not particularly limited as long as it contains at least an ultraviolet absorber. For example, a curable resin composition containing a curable resin such as an ionizing radiation curable resin or a thermosetting resin and an ultraviolet absorber. It can be obtained by curing the product. The curable resin is preferably an ionizing radiation curable resin from the viewpoint of preventing bleed out over time, and the low worm-insulating functional layer 3 is an ionizing radiation curable resin composition containing an ionizing radiation curable resin and an ultraviolet absorber. It is preferable that it is formed by crosslinking and curing.

(Curable resin composition)
The curable resin composition used for forming the low worm-insulating functional layer 3 is preferably an ionizing radiation curable resin composition containing an ionizing radiation curable resin and an ultraviolet absorber, and various other additives as necessary. It is a composition that may be included. Here, the ionizing radiation curable resin is a resin having an energy quantum capable of crosslinking and polymerizing molecules in an electromagnetic wave or a charged particle beam, that is, a resin that is crosslinked and cured by irradiation with ultraviolet rays or electron beams. It is.

<Ultraviolet absorber>
The low absorptive property of the low absorptive sheet of the present invention is manifested by an ultraviolet absorber, and it is essential that the ultraviolet absorber is contained in the low absorptive layer 3, preferably in addition to the substrate 2 described above. , Contained in the adhesive layer 4, the pattern layer 5, the colored solid layer 6, and the tactile sensation imparting layer 7 described later.
The content of the ultraviolet absorber in the low worm sheet of the present invention is 1 to 28 g / m ² , preferably 1 to 20 g / m ² , and more preferably 5 to 15 g / m ² . When the content of the ultraviolet absorber is within the above range, it is possible to sufficiently secure mechanical properties such as adhesion and solvent resistance while obtaining excellent low susceptibility.

The ultraviolet absorbent used in the present invention can be used without limitation as long as it has ultraviolet absorbing performance, but at the same time as obtaining the excellent low susceptibility, when the low worm sheet of the present invention is applied to a lighting device In view of the above, it is desirable to select appropriately from the viewpoint of securing a high total light transmittance in the visible light region and the infrared region.
Among these, an ultraviolet absorber having a maximum absorption wavelength between 250 and 400 nm is preferably used. By setting the maximum absorption wavelength of the ultraviolet absorber within the above range, the total light transmittance of the low repellant sheet is reduced in the ultraviolet region that attracts insects and can be maintained high in the visible light region and the infrared region. The low moth-absorbing sheet of the invention is preferable because it has an excellent low moth-repellency and can be applied to lighting equipment and the like.
Preferred examples of such an ultraviolet absorber include benzophenone-based, benzotriazole-based, benzoate-based, and triazine-based ultraviolet absorbers. Among these, a benzotriazole type is preferable from the viewpoint of ensuring excellent low insect repellency and high total light transmittance in the visible light region and the infrared region.

  Examples of the benzotriazole ultraviolet absorber include 2-ethylhexyl-3- [3-tert-butyl-4-hydroxy-5- (5-chloro-2H-benzotriazol-2-yl) phenyl] propionate (“TINUVIN109” ( Product name): Ciba Specialty Chemicals Co., Ltd.), 2- (2H-benzotriazol-2-yl) -6- (linear and side chain dodecyl) -4-methylphenol ("TINUVIN 171" (trade name): Ciba Specialty Chemicals Co., Ltd.), 2- [5-chloro (2H) -benzotriazol-2-yl] -4-methyl-6- (tert-butyl) phenol (“TINUVIN 326” (trade name): Ciba Specialty Chemicals), 2- (2H-benzotriazol-2-yl) -4,6 Di-tert-pentylphenol (“TINUVIN 328” (trade name): manufactured by Ciba Specialty Chemicals), 2- (2′-hydroxy-5′-methylphenyl) benzotriazole, 2- (2′-hydroxy-3) ', 5'-di-tert-butylphenyl) benzotriazole, 2- (2'-hydroxy-3'-tert-butyl-5'-methylphenyl) benzotriazole, 2- (2'-hydroxy-3', 5'-di-tert-butylphenyl) -5-chlorobenzotriazole, 2- (2'-hydroxy-3 '-(3 ", 4", 5 ", 6" -tetrahydrophthalimidomethyl) -5'-methyl Phenyl) benzotriazole, 2,2-methylenebis (4- (1,1,3,3-tetramethylbutyl) -6- (2H-ben Triazol-2-yl) phenol), and 2- (such as 2'-hydroxy-3'-tert-butyl-5'-methylphenyl) -5-chloro benzotriazole. Among them, 2-ethylhexyl-3- [3-tert-butyl-4-hydroxy-5- (5-chloro-2H-benzotriazol-2-yl) phenyl] propionate (“TINUVIN109” (trade name): Ciba Specialty Chemicals Co., Ltd.), 2- [5-Chloro (2H) -benzotriazol-2-yl] -4-methyl-6- (tert-butyl) phenol (“TINUVIN 326” (trade name): Ciba Specialty Chemicals ( And 2- (2H-benzotriazol-2-yl) -4,6-di-tert-pentylphenol (“TINUVIN 328” (trade name): manufactured by Ciba Specialty Chemicals Co., Ltd.) are preferable. -Ethylhexyl-3- [3-tert-butyl-4-hydroxy-5- (5-chloro -2H- benzotriazol-2-yl) phenyl] propionate ( "TINUVIN109" (trade name): manufactured by Ciba Specialty Chemicals Co.) is particularly preferred. An ultraviolet absorber can be used individually or in mixture of 2 or more types.

  Content of the ultraviolet absorber in curable resin composition is about 1-50 mass% with respect to the sum total of curable resin and an ultraviolet absorber, 5-40 mass% is preferable, and 10-30 mass. % Is more preferable. When the content of the ultraviolet absorber is within the above range, sufficient mechanical properties such as adhesion and solvent resistance can be ensured while exhibiting sufficient low insecticidal properties.

<Ionizing radiation curable resin>
The ionizing radiation curable resin preferably used for the formation of the low worm-insulating functional layer 3 is appropriately selected from polymerizable monomers and polymerizable oligomers or prepolymers conventionally used as ionizing radiation curable resins. However, from the viewpoint of obtaining good curing characteristics, those which are difficult to bleed out, have a coating property even as about 95 to 100% as a solid content standard, and are less likely to cause curing shrinkage upon curing. Representative examples of such ionizing radiation curable resins are described below. “(Meth) acrylate” means “acrylate or methacrylate”.

  As the polymerizable monomer, a (meth) acrylate monomer having a radically polymerizable unsaturated group in the molecule is suitable, and in particular, a polyfunctionality having two or more ethylenically unsaturated bonds in the molecule ( (Meth) acrylate is preferred, and one kind may be used alone, or two or more kinds may be used in combination. As a functional group number, 2-8 are preferable, 2-6 are more preferable, and 3-4 are more preferable.

  In the present invention, together with the polyfunctional (meth) acrylate, for the purpose of adjusting the viscosity, monofunctional (meth) acrylates such as methyl (meth) acrylate are within a range that does not impair the purpose of the present invention. It can be used together as appropriate. A monofunctional (meth) acrylate may be used individually by 1 type, and may be used in combination of 2 or more type.

  Next, as the polymerizable oligomer, an oligomer having a radically polymerizable unsaturated group in the molecule, for example, epoxy (meth) acrylate, urethane (meth) acrylate, polyester (meth) acrylate, polyether (meth) Preferred examples include acrylate oligomers. Among these oligomers, polyfunctional polymerizable oligomers are preferable, and the number of functional groups is preferably 2 to 16, more preferably 2 to 8, and still more preferably 2 to 6.

  Furthermore, other polymerizable oligomers include polybutadiene (meth) acrylate oligomers with high hydrophobicity that have (meth) acrylate groups in the side chain of polybutadiene oligomers, and silicone (meth) acrylate oligomers that have polysiloxane bonds in the main chain. In a molecule such as an aminoplast resin (meth) acrylate oligomer modified with an aminoplast resin having many reactive groups in a small molecule, or a novolak type epoxy resin, bisphenol type epoxy resin, aliphatic vinyl ether, aromatic vinyl ether, etc. There are oligomers having a cationic polymerizable functional group. These polymerizable oligomers may be used individually by 1 type, and may be used in combination of 2 or more type.

  When an ultraviolet curable resin is used as the ionizing radiation curable resin, it is desirable to add about 0.1 to 5 parts by mass of a photopolymerization initiator with respect to 100 parts by mass of the ultraviolet curable resin. The initiator for photopolymerization can be appropriately selected from those conventionally used and is not particularly limited.

  In the present invention, it is preferable to use an electron beam curable resin as the ionizing radiation curable resin. This is because the ionizing radiation curable resin composition in the present invention contains an ultraviolet absorber, and in the case of irradiation with ultraviolet rays, the ultraviolet irradiation amount may be insufficient. Although preparation may be required, in the case of electron beam irradiation, such preparation is unnecessary, and stable curing characteristics can be obtained efficiently.

<Various additives>
Various additives are blended in the curable resin composition used for forming the low worm-insulating functional layer 3 depending on the desired physical properties of the resulting low worm-inducing functional layer. Examples of the additive include a polymerization inhibitor, a crosslinking agent, an antistatic agent, an adhesion improver, an antioxidant, a leveling agent, a thixotropic agent, a coupling agent, a plasticizer, an antifoaming agent, a filler, and a solvent. Is mentioned.

<< Tactile Feeling Layer 7 >>
In order to express the excellent designability which makes the material feel the peculiar tactile sensation of the present invention, the low worm-insulating sheet of the present invention has a tactile sensation imparting layer 7 formed of a resin composition containing fine particles on the outermost surface. The tactile sensation imparting layer 7 is provided on the outer side of the lighting fixture when the low worm-inducing sheet is applied to the lighting fixture. The tactile sensation imparting layer 7 is obtained by curing a resin composition containing fine particles and preferably a thermosetting resin or an ionizing radiation curable resin. The resin used for forming the tactile sensation providing layer 7 is a thermosetting resin from the viewpoint of adhesion to a wooden frame, which is important when the sheet of the present invention is used in a lighting fixture, or productivity and price. An ionizing radiation curable resin is preferable from the viewpoint of obtaining excellent antifouling properties and scratch resistance. These resins may be appropriately selected according to the use of the sheet of the present invention.

(Thermosetting resin)
Examples of the thermosetting resin include thermosetting resins such as polyester resins, epoxy resins, polyurethane resins, aminoalkyd resins, melamine resins, guanamine resins, urea resins, and thermosetting acrylic resins. Among these, a polyurethane resin can be preferably used.

The polyurethane resin is a resin having a polyol (polyhydric alcohol) as a main component and an isocyanate as a crosslinking agent (curing agent).
As the polyol, one having two or more hydroxyl groups in the molecule, for example, polyethylene glycol, polypropylene glycol, acrylic polyol, polyester polyol, polyether polyol, alkyd-modified acrylic polyol, and the like are used. Of these, alkyd-modified acrylic polyols are preferred.
As the isocyanate, a polyvalent isocyanate having two or more isocyanate groups in the molecule is used. For example, aromatic isocyanate such as 2,4-tolylene diisocyanate, xylene diisocyanate, 4,4-diphenylmethane diisocyanate, or aliphatic isocyanate such as hexamethylene diisocyanate, isophorone diisocyanate, hydrogenated tolylene diisocyanate, hydrogenated diphenylmethane diisocyanate, etc. Used.

(Ionizing radiation curable resin)
Preferred examples of the ionizing radiation curable resin used for forming the tactile sensation providing layer 7 include the resins used for the above-described low worm-insulating functional layer 3.
The resin composition for a touch-sensitive layer that forms the touch-sensitive layer 7 can contain a monofunctional or polyfunctional silicone (meth) acrylate for the purpose of improving antifouling properties. Content of silicone (meth) acrylate is 1-5 mass parts with respect to 100 mass parts of curable resin from a viewpoint of maintaining transparency, More preferably, it is 1-2 mass parts.

  The resin composition for a tactile sensation imparting layer preferably contains the above-described ultraviolet absorber for the purpose of obtaining excellent low insecticidal properties and weather resistance. Content of the ultraviolet absorber in this resin composition is about 0.1-10 mass%, and 0.1-5 mass% is preferable. Moreover, the resin composition for tactile sensation imparting layers can contain various additives as required, and preferred examples of the various additives include those used in the above-described low worm-insulating functional layer.

(Fine particle 8)
The resin composition for a tactile sensation-imparting layer contains fine particles for the purpose of imparting a tactile sensation to the low worm sheet of the present invention, and the content of the fine particles in the resin composition is in the range of 1 to 30% by mass. The range of 5 to 25% by mass is more preferable from the viewpoint of obtaining the design property, antifouling property, and coating property of the resin composition that require a certain thing and give a better feel of the material.

  Various fine particles are used, and inorganic fine particles, organic fillers, and the like are used. Preferred examples of the inorganic fine particles include silica, clay, heavy calcium carbonate, light calcium carbonate, precipitated barium sulfate, calcium silicate, synthetic silicate, and fine silicate fine particles. Examples of the organic filler include acrylic resin and urethane. Preferred examples include fillers made of resin, polypropylene resin, nylon, urea resin, and the like, and these can be used alone or in combination. Among these, at least one selected from silica fine particles, aluminum hydroxide fine particles, acrylic resin fillers, urethane resin fillers, and urea resin fillers is particularly preferable from the viewpoint of design properties such as gloss and shine when turned off.

  The average particle diameter of the fine particles is usually about 1 to 35 μm, preferably 1 to 20 μm, and more preferably from the viewpoint of obtaining excellent design properties and excellent antifouling properties that give the material a unique feel. Is 7 to 15 μm. The average particle diameter of the fine particles may vary depending on the thickness of the touch-imparting layer 7, but if it is within the above range, the fine particles are appropriately headed out from the touch-sensitive layer 7. And antifouling property. Here, the average particle diameter of the fine particles is measured by a Coulter counter method or a laser diffraction method.

  1-10 micrometers is preferable and, as for the thickness of the tactile provision layer 7, 1-5 micrometers is more preferable. If the thickness is within the above range, it is possible to obtain an excellent design property that makes the material feel a tactile sensation, and to secure the formability of the low worm-insulating sheet.

<Adhesive layer 4>
The adhesive layer 4 is a layer provided as necessary between the low worm-insulating functional layers 31 and 32 in order to laminate the base material A and the base material B. The adhesive layer 4 is provided in different locations depending on the layer structure and manufacturing process of the low worm-inducing sheet. For example, in the case of FIG. In the case where the number of the low worm-inducing function layer 3 is one, it is provided between the low worm-inducing function layer 3 and the pattern layer 5, or between the low worm-inducing function layer 3 and the substrate A.

  Examples of the adhesive used for the adhesive layer 4 include polyester adhesives; ethylene-vinyl acetate copolymer (EVA) adhesives, vinyl chloride-vinyl acetate copolymer adhesives, vinyl acetate-acrylic copolymers. Vinyl acetate adhesives such as polymer adhesives; two-part curable urethane resins that use blocked isocyanate as a curing agent, aqueous urethane adhesives, aqueous vinyl urethane adhesives, modified urethane adhesives, urethane modified vinyl adhesives Examples thereof include urethane adhesives such as adhesives; adhesives such as styrene-butadiene latex adhesives, aqueous polymer isocyanate adhesives, and acrylic adhesives. Of these, polyester adhesives are preferred.

  Moreover, the adhesive agent can preferably contain the above-described ultraviolet absorber from the viewpoint of improving the low susceptibility. The content of the ultraviolet absorber in the adhesive is preferably about 0.1 to 30% by mass. When the content of the ultraviolet absorber in the adhesive is within the above range, excellent low susceptibility can be obtained while obtaining excellent adhesive force.

<< Picture layer 5 >>
The pattern layer 5 is a layer provided as necessary in order to give design properties to the low moth-absorbing sheet of the present invention. In FIG. 2, the pattern layer 5 is provided between the colored solid layer 6 and the base material B, but may be appropriately selected depending on a desired design feeling or the like. It may be provided between the material B and the low worm-insulating functional layer 32. In order to enhance the Japanese-style design of the present invention, the pattern layer 5 is preferably provided on the outer side of the base material B, as shown in FIG. It is preferable to be outside the pattern layer 5. Here, the outside refers to the side closer to the tactile sensation providing layer 7. For example, when the sheet of the present invention is used for illumination, it is the side closer to the user's side.

The pattern employed in the pattern layer 5 is appropriately selected depending on the application. For example, a Japanese paper pattern, a fabric pattern imitating a cloth or cloth pattern, a wood pattern, a marble pattern (for example, a travertine marble pattern) There are patterns such as parquet and patchwork that combine these, such as a stone pattern that imitates the surface of rocks, tiled patterns, and brickwork patterns. These patterns are formed by multi-color printing with normal yellow, red, blue, and black process colors, and also by multi-color printing performed by preparing individual color plates constituting the pattern. .
When applying the low moth-absorbing sheet of the present invention to a lighting fixture, the pattern applied to the pattern layer 5 is not particularly limited as long as the performance desired as a lighting fixture such as total light transmittance is ensured, but the color is Pale color systems such as white, milky white, and light yellow are preferable, and when used for a Japanese-style lighting fixture cover or the like, a light color system and a Japanese paper pattern or fabric pattern are preferable.

  As the ink composition used for forming the picture layer 5, a binder and a colorant such as a pigment and a dye, an extender pigment, a solvent, a stabilizer, a plasticizer, a catalyst, and a curing agent are appropriately mixed. The binder is not particularly limited. For example, polyurethane resin, vinyl acetate resin, vinyl chloride-vinyl acetate copolymer resin, vinyl chloride-vinyl acetate-acrylic copolymer resin, chlorinated polyethylene resin, chlorinated polypropylene resin, Any one of acrylic resin, polyester resin, polyamide resin, butyral resin, polystyrene resin, nitrocellulose resin, cellulose acetate resin and the like may be used alone or in combination of two or more. Among these, it is preferable to use a polyurethane resin, a vinyl acetate resin, an acrylic resin, a polyester resin, a cellulose resin, a polyamide resin, or the like singly or in combination of two or more.

  Colorants include carbon black (black), iron black, titanium white, antimony white, yellow lead, titanium yellow, petal, cadmium red, ultramarine, cobalt blue and other inorganic pigments, quinacridone red, isoindolinone yellow, phthalocyanine Organic pigments or dyes such as blue, metal pigments made of scaly foil pieces such as aluminum and brass, pearlescent pigments made of scaly foil pieces such as titanium dioxide-coated mica and basic lead carbonate, and the like are used.

  The pattern layer 5 is formed by printing various patterns as described above using an ink composition and a printing machine. In general, it can be formed with ink by a known printing method such as gravure printing, offset printing, silk screen printing, transfer printing from a transfer sheet, and the like.

  Moreover, the ink composition used for formation of the pattern layer 5 may contain the above-mentioned ultraviolet absorber. Content of the ultraviolet absorber in an ink composition is about 0.1-5 mass%.

  The thickness of the pattern layer 5 is preferably about 1 to 20 μm. If the thickness of the pattern layer 5 is within the above range, sufficient design properties can be obtained while ensuring the performance desired as a lighting fixture.

<Colored solid layer 6>
The colored solid layer 6 is a layer provided as necessary in order to give design to the low worm-infestation sheet of the present invention. In the present invention, the pattern layer 5 can be provided alone or the colored solid layer 6 can be provided alone, but these layers are preferably provided in combination from the viewpoint of design.
Further, the colored solid layer 6 is preferably colored and transparent from the viewpoint of ensuring high total light transmittance while enhancing the design properties, and more preferably a light color system such as milky white or light yellow. .
As the ink composition for forming the colored solid layer 6, the same ink composition as that for forming the pattern layer 5 can be used, and it is also the same that an ultraviolet absorber can be contained if necessary.

The sheet | seat of this invention is good also as a thing of the structure which has raw materials, such as Japanese paper and a fabric, in order to improve the design property, especially the purpose of improving the Japanese design property. The sheet of the present invention can be provided with a material such as Japanese paper or cloth alone for improving the Japanese-style design. Further, in order to express various design properties based on Japanese style, the material and the pattern layer 5 or the colored solid layer 7 can be combined.
The location where the material such as Japanese paper or fabric is provided is not particularly limited, but in consideration of the antifouling property, it may be provided inside the outermost surface, that is, at any location on the base material side from the tactile sensation providing layer 7. preferable. Moreover, when providing the said raw material, what is necessary is just to use the adhesive agent etc. which are used for the above-mentioned contact bonding layer 4 as needed.

<Uneven pattern>
In order to impart excellent design properties to the low worm-infestation sheet of the present invention, an uneven pattern by embossing can be applied. The concavo-convex pattern can be formed by heating and pressurizing with the embossing plate when the low worm-insulating sheet in the manufacturing process is at a temperature at which it can be embossed by any means.
From the viewpoint of design properties, it is preferable that the heating and pressurization with the embossed plate is applied from the outermost touch imparting layer 7 side.
A well-known sheet or rotary embossing machine is used to form the concavo-convex pattern. The shape of the concavo-convex pattern is: wood grain conduit groove, stone surface unevenness, fabric surface texture, satin, sand, hairline, There are striated grooves and the like, which can be appropriately selected in consideration of the pattern by the pattern layer.

[Manufacturing method of a low insect repellent sheet]
In the method for producing a low worm sheet according to the present invention, the ionizing radiation curable resin composition containing an ultraviolet absorber and an ionizing radiation curable resin is applied to the step (A): the substrate A and / or the substrate B. A step of forming a low susceptibility functional layer, step (B): a step of applying a resin composition containing fine particles to the substrate B to form a tactile sensation providing layer, and a step (C): the low susceptibility function It includes a step of laminating the base material A and the base material B via an adhesive so that the layer is between the base material A and the base material B.

<< Process (A) >>
In the step (A), the ionizing radiation curable resin composition is applied to the base material A and / or the base material B to form the low susceptibility functional layer 3 (or the low susceptibility functional layer 31 or the low susceptibility functional layer 32). It is a process to do.
In the formation of the low worm-insulating functional layer 3, first, as a preferable curable resin, an ionizing radiation curable resin such as a polymerizable monomer or a polymerizable oligomer, an ultraviolet absorber, and various additives, which are the above-described curable components, The ionizing radiation curable resin composition is prepared by mixing homogeneously at a ratio. The viscosity of the ionizing radiation curable resin composition is not particularly limited as long as it is a viscosity capable of forming an uncured resin layer on the surface of the substrate by a coating method described later.
Then, the prepared ionizing radiation curable resin composition is applied onto the substrate A and / or the substrate B by a known method such as gravure printing, offset printing, silk screen printing, preferably gravure printing, A cured resin layer is formed.

  In the formation of the uncured resin layer, the ionizing radiation curable resin composition may be applied once or a plurality of times depending on the desired thickness of the low worm-insulating functional layer. When the ionizing radiation curable resin composition is applied multiple times, the ionizing radiation curable resin composition may be applied without curing the uncured resin layer, or the uncured resin layer may be cured. Then, a new ionizing radiation curable resin composition may be applied.

The uncured resin layer thus formed is irradiated with ionizing radiation such as electron beams and ultraviolet rays to cure the uncured resin layer, and then the solvent contained in the ionizing radiation curable resin composition is evaporated. In order to make it dry, the low worm-insulating functional layer 3 is obtained.
The thickness of the low absorptive functional layer 3 may be appropriately set according to the amount of the ultraviolet absorber to be contained in the low arousal functional layer, but is usually 10 to 60 μm, preferably 3 to 55 μm, more preferably 5 to 50 μm. More preferably, it is 10-40 micrometers. If the thickness of the low worm-insulating functional layer is within the above range, a sufficient ultraviolet absorber can be retained, and thus excellent low susceptibility can be obtained.

When an electron beam is used as the ionizing radiation when the uncured resin layer is cured, the acceleration voltage can be appropriately selected according to the resin used and the thickness of the layer. However, the acceleration voltage is usually about 70 to 300 kV. It is preferable to cure the cured resin layer.
In addition, in electron beam irradiation, the transmission capability increases as the acceleration voltage increases, so when using a base material that deteriorates due to the electron beam as the base material, the penetration depth of the electron beam and the thickness of the uncured resin layer By selecting an accelerating voltage so as to be substantially equal, it is possible to suppress the irradiation of the extra electron beam to the base material, and to minimize the deterioration of the base material due to the excess electron beam. it can.

The irradiation dose is preferably such that the crosslink density of the ionizing radiation curable resin in the low susceptibility functional layer is saturated, and is usually selected in the range of 5 to 300 kGy (0.5 to 30 Mrad), preferably 10 to 50 kGy (1 to 5 Mrad). Is done.
Further, the electron beam source is not particularly limited. For example, various electron beam accelerators such as a cockroft Walton type, a bandegraft type, a resonant transformer type, an insulated core transformer type, a linear type, a dynamitron type, and a high frequency type. Can be used.
When ultraviolet rays are used as the ionizing radiation, those containing ultraviolet rays having a wavelength of 190 to 380 nm are emitted. There is no restriction | limiting in particular as an ultraviolet-ray source, For example, a high pressure mercury lamp, a low pressure mercury lamp, a metal halide lamp, a carbon arc lamp, etc. are used.

  In addition, drying can be performed for the purpose of evaporating the solvent and the like contained in the ionizing radiation curable resin composition. The drying temperature condition is preferably in the range of room temperature to 55 ° C, more preferably room temperature to 50 ° C, and the drying time is preferably 10 to 120 seconds, more preferably 30 to 90 seconds. In addition, room temperature is about 20 degreeC normally.

<< Process (B) >>
The step (B) is a step of forming a tactile sensation providing layer by coating the base material B with a resin composition containing fine particles. For example, in the case of FIG. 2, the tactile sensation layer is formed by applying a curable resin composition for a tactile sensation layer and then curing after providing a pattern layer and a colored solid layer provided as necessary. Just do it. When the curable resin used in the curable resin composition is an ionizing radiation curable resin, the tactile sensation providing layer is formed by crosslinking and curing in the same manner as the ionizing radiation curable resin used in the above-described low worm-insulating functional layer. be able to. When the curable resin used in the curable resin composition is a thermosetting resin, the tactile sensation imparting layer can be formed by curing with an autoclave or the like.

  The application of the curable resin composition for a touch-imparting layer and the method of cross-linking curing are the same as the formation of the low worm-insulating functional layer. Moreover, the formation of the tactile sensation imparting layer by curing can be performed without any limitation as long as the base material A and the base material B are laminated.

<< Process (C) >>
The step (C) is a step of laminating the base material A and the base material B via an adhesive so that the low worm-insulating functional layer is between the base material A and the base material B.

The adhesive can be formed by coating by a known method such as gravure printing, die coating, bar coating, spray coating, roll coating, reverse roll coating, comma coating, etc. From the above, gravure printing and comma coating are preferably employed. The coating amount of the adhesive is preferably 0.1 to ²⁰ g / m ² (based on solid content), and more preferably 1 to 10 g / m ² (based on solid content).

  For the sticking, a sticking device such as a cold press, hot press, roll press, laminator, wrapping, edge pasting machine, vacuum press or the like can be used. Of these, dry lamination using a laminator is preferably employed.

《Low insect repellent sheet》
The thus obtained low worm sheet of the present invention has an excellent design property that makes it feel a material-specific tactile sensation, and has an excellent low worm property and moldability.
The low worm sheet of the present invention preferably has a total light transmittance at a wavelength of 405 nm of 5% or less, more preferably 3% or less, and a total light transmittance at wavelengths of 555 nm and 945 nm of 30% or more, respectively. It has the characteristic. The low insect attracting sheet of the present invention has excellent low attractant by setting the total light transmittance at a wavelength of 405 nm to 5% or less, and the total light transmittance at a wavelength of 555 nm and 945 nm, respectively. By setting it to 30% or more, sufficient brightness is secured when applied to a lighting fixture, and it is possible to cope with a remote control operation in which wavelengths in the infrared region are mainly used.
In addition, the low worm-inducing sheet of the present invention has a high design property by providing a pattern layer by printing and can respond to diversifying tastes, and can be formed into various shapes by suppressing its thickness to about 350 μm. It becomes possible to do.

(Use)
The low worming sheet of the present invention can be used as a lighting fixture cover by taking advantage of such characteristics, and the lighting fixture cover can be suitably used for a lighting fixture. The lighting fixture includes, for example, a light source and a housing for storing the light source and the lighting fixture cover of the present invention, and irradiates light from the light source through the lighting fixture cover from the inside to the outside of the housing. The thing of the form to do is mentioned.

  Moreover, the low worming sheet of the present invention includes (i) adopting a Japanese paper pattern or a fabric pattern in the pattern layer, and (ii) a cut piece obtained by appropriately cutting a material such as Japanese paper or a cloth into the synthetic resin. Use a film or sheet as a base material, or (iii) Affix to a wooden frame (including a frame made of a material having a wood-like design) having a layer made of a material itself such as Japanese paper or fabric In particular, it can be suitably used as a Japanese-style lighting fixture cover. And this Japanese-style lighting fixture cover is used suitably for the above lighting fixtures, and can be used as a Japanese-style lighting fixture.

  Furthermore, the low worming sheet of the present invention is not limited to indoor use such as the above-mentioned lighting fixtures and Japanese-style lighting fixtures, but is installed outdoors, for example, it has a light source inside, and is internally illuminated by this internal light source. It is also suitably used as a signboard material used for a type signboard. In the case of applying the low insect attracting sheet of the present invention to such an application, the sign sheet material may be formed with the low insect attracting sheet itself, or the sign sheet may be bonded to another sign material and used.

  Other uses of the low moth-absorbing sheet of the present invention include window materials for houses, partition plates for entrances, and the like. Lighting in the house can prevent insects from gathering at the windows and doorways and entering indoors. Furthermore, the low worm-infestation sheet of the present invention can be used by being attached to a window glass of a commercial facility such as a convenience store or a supermarket. The low moth-absorbing sheet of the present invention can be used for various applications by using a release sheet and a release sheet as a tack sheet provided on at least one surface of the low worm-inducing sheet. At this time, as the release layer and release sheet, those usually used for tack sheets can be applied without limitation.

EXAMPLES Next, although an Example demonstrates this invention further in detail, this invention is not limited at all by these examples.
The low worm sheet obtained in each Example and Comparative Example was evaluated by the following method.
(1) Measurement of total light transmittance Using a spectral reflectometer ("PC-3100 (model number)" manufactured by Shimadzu Corporation), the total light transmittance at wavelengths of 405 nm, 555 nm, and 945 nm was measured. Evaluation based on the criteria.
Evaluation of total light transmittance at a wavelength of 405 nm ◎: Total light transmittance of 3% or less ○: Total light transmittance of more than 3% to 5% or less X: Total light transmittance of more than 5% to 10% or less 555 nm and 945 nm, respectively Evaluation of total light transmittance at wavelength ○: Total light transmittance of 30% or more ×: Total light transmittance of less than 30% (2) Gloss measurement Gross meter (“Gloss meter GM-3D”: manufactured by Murakami Color Research Laboratory) In accordance with ASTM D523, the glossiness at an incident angle of 60 degrees was measured and evaluated according to the following criteria.
◎: Less than 4 ○: Less than 10 ×: 10 or more (3) Measurement of surface roughness Using a contact surface roughness meter (“SV3000S4 (model)” manufactured by Mitutoyo Corporation), according to JIS B0601-1994, The centerline average roughness (Ra) and maximum height (Rt) of the surface of the tactile sensation imparting layer of the low tempering sheet were measured.
(4) Evaluation of shine when extinguished The sheets obtained in the examples and comparative examples were placed in the same environment as when the illumination was extinguished, and the condition of the shine was evaluated according to the following criteria.
◎: No shine was generated at all. ○: Little shine was generated, and the sheet did not stand out even when the light was turned off. △: Some shine was generated, but the sheet did not stand out even when turned off. (5) Evaluation of tactile sensation The surface of the sheet obtained in the example and the comparative example was touched and evaluated according to the following criteria.
◎: The material-specific tactile sensation is fully expressed and has a realistic feeling. ○: The material-specific tactile sensation is expressed. △: There is a tactile sensation, but it is slightly artificial. ×: Tactile sensation was not felt at all (6 ) Evaluation of antifouling property Carbon black was deposited on the surface of the sheet obtained in the examples and comparative examples, and this was wiped with a sponge containing a neutral detergent to evaluate the antifouling property. This was done visually.
○ There was no carbon black spray residue. △ Carbon black spray residue remained slightly, but there was no problem in practical use. × Carbon black spray residue was remarkable. (7) Adhesive evaluation Obtained in Examples and Comparative Examples 180 ° peel load (25.4 mm) when peeled after bonding the tactile sensation providing layer and the wooden frame (material: Shiraki) to each other using an adhesive (“Warron Bond” manufactured by Waron Co., Ltd.). , 100 m / min) was measured and evaluated according to the following criteria.
○: Peeling load 8N or more Δ: Peeling load 4N or more and less than 8N ×: Peeling load less than 4N or natural peeling (8) Adhesion A portion of the surface of the low repellency sheet is rubbed 10 times with an eraser and the part is at room temperature , Cellophane tape (cellophane adhesive tape made by Nichiban Co., Ltd., “cello tape (registered trademark)” 25 mm width) is firmly attached, and the cellophane tape is forcibly peeled off in the direction of 90 degrees from the surface of the low worm-inducing sheet. did. The state of the sheet when this was repeated three times was observed.
○ No problem △ There was some peeling, but there was no problem in practical use. × Peeling was remarkable. (9) Solvent resistance The surface of the low repellency sheet was rubbed with methyl ethyl ketone 5 times (500 g load). After rubbing, the following criteria were evaluated by visual observation.
○: No change in appearance △: Some change in appearance was observed, but there was no practical problem ×: Whitening of the appearance was remarkable

Example 1: Production of a low worm sheet Two sheets of a polyolefin resin sheet ("PP film" (trade name) manufactured by Mitsubishi Plastics, Inc.) made of polypropylene resin and having a thickness of 140 µm were prepared as a base material. Gravure printing of ink ("TMK (NT) CC White" (trade name): Showa Ink Industries Co., Ltd.), which contains urethane resin as the main component and white titanium as a color pigment on one base material B Thus, the pattern layer 5 is formed so that the coating amount after drying is 2 g / m ² , and an electron beam curable resin (“KEB-CW” (trade name) mainly composed of an electron beam curable acrylate resin is formed. ): Coated with a curable resin composition (made by Dainichi Seika Co., Ltd.) and fine particles (average particle size: 3-4 μm) (content of fine particles: 20 parts by mass with respect to 100 parts by mass of resin)). Thereafter, an electron beam was irradiated under conditions of 175 keV and 50 kGy (5 Mrad) to crosslink and cure the coating film, thereby forming the tactile sensation imparting layer 7. An ionizing radiation curable resin composition having the following composition is applied to the opposite side of the substrate B where the pattern layer 5 is provided, and an electron beam is irradiated under conditions of 175 keV and 50 kGy (5 Mrad). Then, the coating film was cross-linked and cured to form the low worm-insulating functional layer 32.
On the other hand, an ionizing radiation curable resin composition having the following composition is coated on another substrate A, and the coating is crosslinked and cured by irradiating an electron beam under the conditions of 175 keV and 50 kGy (5 Mrad). Thus, a base material A having the low worm-insulating functional layer 31 on one surface was obtained. In addition, in the coating of the ionizing radiation curable resin composition on the base material A and the base material B, the total coating amount of the ionizing radiation curable resin and the ultraviolet absorber was set to 50 g / m ² .
The low worm-insulating functional layer 32 is coated with 5 to 10 g / m ² by a roll coating method with a two-part curable polyester polyol type adhesive heated to 75 ° C. The insect attracting functional layer 31 was laminated to obtain a low attracting insect sheet of the present invention. Table 1 shows the evaluation results of the obtained low worm sheet.
Ionizing radiation curable resin composition Composition UV absorber ^{* 1} : 10 parts by weight Trifunctional acrylate monomer: 40 parts by weight * 1,2-ethylhexyl-3- [3-tert-butyl-4-hydroxy-5- (5- Chloro-2H-benzotriazol-2-yl) phenyl] propionate (“TINUVIN109” (trade name) manufactured by Ciba Specialty Chemicals)

Examples 2 to 10 and Comparative Examples 1 to 3
In Example 1, except that the content of fine particles, the average particle diameter, or the amount of the curable resin and the ultraviolet absorber in the resin composition for a low worm-insulating functional layer are those described in Table 1. A sheet was prepared in the same manner as in 1. The evaluation results of the obtained sheet are shown in Table 1.

Example 9
Two polyolefin resin sheets (“PP film” (trade name): manufactured by Mitsubishi Plastics, Inc.) having a thickness of 140 μm made of polypropylene resin were prepared as base materials. Gravure printing of ink ("TMK (NT) CC White" (trade name): Showa Ink Industry Co., Ltd.), which contains urethane resin as the main component and white titanium as a color pigment on one base material B Then, the pattern layer 5 is formed so that the coating amount after drying is 2 g / m ^2, and further a thermosetting urethane resin composition (fine particles) containing silica fine particles (average particle size: 4-5 μm). Content: 20 parts by mass with respect to 100 parts by mass of urethane-based resin ”) was applied and allowed to stand for 72 hours in a curing room kept at 40 ° C. to cure, thereby forming tactile imparting layer 7. An ionizing radiation curable resin composition having the following composition is applied to the opposite side of the substrate B where the pattern layer 5 is provided, and an electron beam is irradiated under conditions of 175 keV and 50 kGy (5 Mrad). Then, the coating film was cross-linked and cured to form the low worm-insulating functional layer 32.
On the other hand, an ionizing radiation curable resin composition having the following composition is coated on another substrate A, and the coating is crosslinked and cured by irradiating an electron beam under the conditions of 175 keV and 50 kGy (5 Mrad). Thus, a base material A having the low worm-insulating functional layer 31 on one surface was obtained. In addition, in the coating of the ionizing radiation curable resin composition on the base material A and the base material B, the total coating amount of the ionizing radiation curable resin and the ultraviolet absorber was set to 50 g / m ² .
The low worm-insulating functional layer 32 is coated with 5 to 10 g / m ² by a roll coating method with a two-part curable polyester polyol type adhesive heated to 75 ° C. The insect attracting functional layer 31 was laminated to obtain a low attracting insect sheet of the present invention. Table 2 shows the evaluation results of the obtained low worm sheet.
Curable resin composition Composition UV absorber ^{* 1} : 10 parts by weight Trifunctional acrylate monomer: 40 parts by weight * 1,2-ethylhexyl-3- [3-tert-butyl-4-hydroxy-5- (5-chloro- 2H-benzotriazol-2-yl) phenyl] propionate (“TINUVIN109” (trade name): manufactured by Ciba Specialty Chemicals)

Examples 11 to 15 and Comparative Example 4
In Example 9, a sheet was produced in the same manner as in Example 9 except that the content of fine particles and the average particle diameter were those described in Table 2. The evaluation results of the obtained sheet are shown in Table 2.

＊１，樹脂組成物中の含有量（質量％）

* 1, Content in resin composition (mass%)

＊１，樹脂組成物中の含有量（質量％）

* 1, Content in resin composition (mass%)

  ADVANTAGE OF THE INVENTION According to this invention, the low worming sheet which has the outstanding design property which makes the tactile sensation peculiar to a raw material felt, and has the outstanding low worming property and moldability can be obtained. The low insect-repellent sheet of the present invention is preferably used for lighting equipment, particularly Japanese-style lighting equipment.

1. Low Insect Sheet A. Base material A
B. Base material B
3. Low-attracting functional layer 31. Low-insect functional layer 32. 3. Low worm-insulating functional layer 4. Adhesive layer Pattern layer 6. 6. Colored solid layer Touching layer 8. Fine particles

Claims (9)

A low sensation sheet formed by sequentially laminating at least a base material A, a low susceptibility functional layer, a base material B, and a tactile sensation providing layer formed of a resin composition containing fine particles, and at least the low sensation functional layer of the sheet In which the ultraviolet absorber is contained in an amount of 1 to 28 g / m ² and the content of fine particles in the resin composition is 1 to 30% by mass. Insect sheet.   The low worm-inducing sheet according to claim 1, wherein the low worm-inducing functional layer is composed of two layers.   The low insect attracting sheet according to claim 2 which has an adhesion layer between two layers of the low insect attractant functional layer.   Furthermore, the low worm insect sheet | seat in any one of Claims 1-3 which has a pattern layer between the base material B and a tactile provision layer.   The low worm sheet according to any one of claims 1 to 4, wherein the fine particles are at least one selected from silica fine particles, aluminum hydroxide fine particles, acrylic resin filler, urethane resin filler, and urea resin filler.   The average particle diameter of microparticles | fine-particles is 0.1-30 micrometers, The low worm insect sheet | seat in any one of Claims 1-5. A method for producing a low worm sheet having the following steps (A) to (C):
Step (A): Step of forming a low worm-insulating functional layer by applying an ionizing radiation curable resin composition containing an ultraviolet absorber and an ionizing radiation curable resin to the substrate A and / or the substrate B ( B): Step of applying a resin composition containing fine particles to the base material B to form a tactile sensation providing layer (C): the low worm-insulating functional layer is between the base material A and the base material B Step of laminating base material A and base material B through an adhesive The low worm sheet according to any one of claims 1 to 6 further having at least one of the following characteristics (i) to (iii) is included in a wooden frame (including a case where a material having a wood-like design is used): A Japanese-style lighting fixture cover that is attached or fitted.
(I) The base material layer A or the base material layer B contains a piece of Japanese paper or fabric (ii) The pattern layer is a Japanese paper pattern or a fabric pattern (iii) and further has a layer made of Japanese paper or a fabric.   A Japanese-style lighting fixture using the Japanese-style lighting fixture cover according to claim 8.

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