JP2011020025A - Oil-water separator - Google Patents

Oil-water separator Download PDF

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JP2011020025A
JP2011020025A JP2009165654A JP2009165654A JP2011020025A JP 2011020025 A JP2011020025 A JP 2011020025A JP 2009165654 A JP2009165654 A JP 2009165654A JP 2009165654 A JP2009165654 A JP 2009165654A JP 2011020025 A JP2011020025 A JP 2011020025A
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oil
waste liquid
chamber
floating
water
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Hikari Murata
光 村田
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Panasonic Corp
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<P>PROBLEM TO BE SOLVED: To provide an oil separator capable of reducing the oil concentration of waste liquid and separating and recovering all floating oil even when buoyancy of microbubbles inside treatment target liquid is small, they float in the separator and oil and water are emulsified, in the oil-water separator for surfacing and separating the oil by the oil adsorbing and floating effects of the microbubbles. <P>SOLUTION: In an oil-water separation tank to which the fixed quantity of the oil-mixed waste liquid of an arbitrary flow rate is successively supplied, it is bisected in the direction of flow, a device for generating the microbubbles and a jetting nozzle are provided on the bottom part of the preceding stage, and a partition plate for making the microbubbles float without surfacing to a liquid surface even though they adsorb oil droplets by forced flow by a fixed quantity water supply means and overflow to a post stage is provided. For the post stage, a floating oil recovery chamber is provided to the upstream, a waste liquid discharge chamber is provided to the downstream communicating with the floating oil recovery chamber at the bottom part, and a waste liquid discharge port is provided to a position lower than the oil recovery port of the floating oil recovery chamber. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

本発明は、工場や変電所またはガソリンスタンド等で油が付着した被洗浄物の洗浄水において、集水槽等から放流する際に、水質汚濁防止法の排水基準値を満たす油分に浄化する策として使用する油水分離装置、あるいは工場等で金属の切削や研磨等のクーラントの処理、または設備や工作物等に付着した油を洗浄した際に発生する比較的油分濃度の高い油分混合廃液を排水処理槽へ送水する前処理として油分を分離回収し、排水処理槽の負荷を低減する策として使用する油水分離装置に関する。   The present invention is a measure for purifying oil that meets the wastewater standard value of the Water Pollution Control Law when discharged from a water collection tank or the like in the wash water of the object to which the oil adheres at a factory, substation or gas station. Wastewater treatment of oil-mixed waste liquid with a relatively high oil concentration generated when cleaning oil that adheres to equipment or workpieces, etc. The present invention relates to an oil-water separator used as a measure for separating and collecting oil as a pretreatment for sending water to a tank and reducing the load on a wastewater treatment tank.

例えば機械工場や鋳物工場等に浮遊するミスト状の油を除去する電気集塵装置において、油が付着した装置内を洗浄液で洗浄した際に発生する油分混合洗浄廃液中の油を分離する油水分離装置に関するものである。   For example, in an electrostatic precipitator that removes mist-like oil floating in machine factories, foundries, etc., oil-water separation that separates oil in oil mixed cleaning wastewater generated when the inside of the device to which oil adheres is cleaned with cleaning liquid It relates to the device.

現在、油分混合廃液の処理には、油と水の比重差を利用して油分を浮上分離させる油水分離装置が多数用いられている。この種の装置には微細気泡の油吸着及び浮揚効果を用いて油の浮上を促進する技術が考案されている。つまり、マイクロサイズまたはナノサイズバブル等の微細気泡には、高い表面吸着力により油脂またはスラッジ等を気泡表面に吸着させる特性があることから、槽内処理液中に上記微細気泡を発生させると、微細気泡の表面吸着作用により油脂またはスラッジ等の分離対象物を気泡表面に吸着させて、その吸着分離対象物を微細気泡の持つ浮力により槽内処理液中で浮上分離させることができる。   Currently, many oil-water separators that float and separate oil components using the difference in specific gravity of oil and water are used for the treatment of oil-mixed waste liquids. In this type of apparatus, a technique for promoting the floating of oil using the oil adsorption and floating effect of fine bubbles has been devised. In other words, micro bubbles such as micro-sized or nano-sized bubbles have the property of adsorbing oil or sludge to the surface of the bubbles with a high surface adsorbing power, so when generating the fine bubbles in the treatment liquid in the tank, A separation target such as fat or sludge can be adsorbed on the bubble surface by the surface adsorption action of the fine bubbles, and the adsorption separation target can be floated and separated in the processing liquid in the tank by the buoyancy of the fine bubbles.

これらの技術は下記特許文献1から2に示すものがある。   These techniques are shown in Patent Documents 1 and 2 below.

特許文献1記載の油水分離装置は、微細気泡が油水分離槽下部から順次揃って浮上するように吐出し、油水分離槽上部に設けた排出管を被処理液が流れ落ちる下降速度を微細気泡の上昇速度より遅くなるようにして、被処理液に油が混入しないことをねらった装置である。   The oil / water separation apparatus described in Patent Document 1 discharges fine bubbles so that they rise in order from the lower part of the oil / water separation tank, and increases the lowering speed of the fine bubbles at a rate at which the liquid to be treated flows through the discharge pipe provided at the upper part of the oil / water separation tank It is an apparatus that aims to prevent oil from being mixed into the liquid to be treated so as to be slower than the speed.

しかしこの装置では、微細気泡が順次揃って浮上するように被処理液の液温や循環ポンプの加圧量を都度監視し、空気供給バブルを常時調整する必要があり装置を複雑化している。また、流入する被処理液の油濃度によっては排出する被処理液内にエマルション化した油が混入し分離効率を悪くする課題があり、運転方法を切替える等の処置または制御手段が必要であり、簡素化が十分に図れた装置とは言えない。   However, this apparatus complicates the apparatus because it is necessary to constantly adjust the air supply bubble by monitoring the liquid temperature of the liquid to be processed and the amount of pressurization of the circulation pump so that the fine bubbles rise in order. Further, depending on the oil concentration of the liquid to be treated that flows, there is a problem that the oil that has been emulsified is mixed into the liquid to be discharged and the separation efficiency is deteriorated, and there is a need for measures or control means such as switching the operation method, It cannot be said that the device is sufficiently simplified.

特許文献2記載の分離装置は、微細気泡により油を浮上させ、分離槽内に残った処理液は分離槽下部より連通させた隔離室へ送水し、排出する装置である。   The separation device described in Patent Document 2 is a device that floats oil with fine bubbles, and feeds and discharges the treatment liquid remaining in the separation tank to an isolation chamber communicated from the lower part of the separation tank.

しかしこの装置では、油分混合水の流入量やその油濃度、または微細気泡の発生量やその粒径によっては、分離槽内に浮遊し続ける微細気泡によってエマルション化した油分混合水が排水用隔離室へ送水され、油濃度が著しく高い処理水が排水される恐れがある。   However, in this device, depending on the inflow amount of oil-mixed water, its oil concentration, the amount of fine bubbles generated, and its particle size, the oil-mixed water emulsified by fine bubbles that continue to float in the separation tank is separated from the drain separation chamber. There is a risk that treated water with a very high oil concentration will be discharged.

特許第4126203号公報Japanese Patent No. 4126203 特開2007−38195号公報JP 2007-38195 A

そこで、本発明は微細気泡の油吸着及び浮揚効果により油を浮上分離する油水分離装置において、微細気泡の浮力が小さく浮上せず、処理対象液の油と水をエマルション化する場合であっても、複雑な制御手段を必要とせず簡単な構成で、廃液排水の油濃度を低減することができ、浮上油を残さず分離回収することができる油分離装置を提供することを目的とする。   Therefore, the present invention is an oil-water separator that floats and separates oil by the oil adsorption and levitation effect of fine bubbles, and even when the oil and water of the liquid to be treated are emulsified, the buoyancy of the fine bubbles does not float small. An object of the present invention is to provide an oil separation device that can reduce the oil concentration of waste liquid wastewater and can separate and recover without leaving floating oil with a simple configuration without requiring complicated control means.

上記課題を解決するため、本発明の油水分離装置は、油分と水分を分離する油水分離タンクと、任意流量の廃液を前記油水分離タンクへ順次送水する定量送水手段を備え、前記油水分離タンク内を流れの方向に前段と後段に二分割し、前段の上澄み液が後段に溢れ入るようにした仕切板を備え、前記油水分離タンクの前段は、底部に微細気泡を発生させる装置および前記微細気泡の噴出ノズルを備えた微細気泡による油吸着及び浮揚効果により油と廃液を上下に分離する油水分離室とし、前記油水分離タンクの後段は、さらに流れの方向に二分割し、上流側は浮上した油を回収する浮上油回収室とし、下流側は浮上油を分離し残った廃液が流入する廃液排水室とし、前記廃液排水室の入口は前記浮上油回収室の下部に配置し、さらに前記浮上油回収室内には、装置外へ通ずる油回収口を前記仕切板の上端より低い位置に設け、前記廃液排水室には、装置外へ通ずる廃液排水口を前記油回収口よりも低い位置に設けたことを特徴とするものである。   In order to solve the above-described problems, an oil / water separation apparatus according to the present invention includes an oil / water separation tank that separates oil and water, and a quantitative water supply unit that sequentially supplies waste liquid at an arbitrary flow rate to the oil / water separation tank. In the direction of the flow, and is divided into a front stage and a rear stage so that the supernatant liquid of the front stage overflows into the rear stage, and the front stage of the oil-water separation tank has a device for generating fine bubbles at the bottom and the fine bubbles An oil / water separation chamber that separates oil and waste liquid up and down by oil adsorption and levitation effect with fine air bubbles equipped with a jet nozzle, and the latter stage of the oil / water separation tank is further divided into two in the flow direction, and the upstream side floated A floating oil recovery chamber for recovering oil; a downstream side is a waste liquid drainage chamber into which the remaining waste liquid is separated and the remaining waste liquid flows; an inlet of the waste liquid drainage chamber is disposed at a lower portion of the floating oil recovery chamber; An oil recovery port leading to the outside of the device is provided at a position lower than the upper end of the partition plate in the recovery chamber, and a waste liquid drain port communicating to the outside of the device is provided at a position lower than the oil recovery port in the waste liquid draining chamber. It is characterized by this.

この発明によれば、油水分離室内で油滴を吸着するものの液面まで浮上せず浮遊する微細気泡は、定量送水手段による強制流で仕切板上部まで浮上させられる。仕切板上部まで移動した微細気泡は、浮上油と接触することでより大きな浮力を持つこととなり、油分混合廃液内を再び沈降あるいは浮遊する微細気泡は減少する。また、仕切板上部で大きな浮力を得た微細気泡は僅かな浮上移動により大気と接触することになり、圧力変動により破裂する。すなわち仕切板を溢水する微細気泡は、後段では消滅または十分な浮力を持ち、再び下方へ沈降しなくなる。また、後段では比重差を利用し油の分離回収と廃液排水を一度にかつ同時に行えるので、装置の簡素化と分離効率の向上を図ることができる。   According to the present invention, the fine bubbles that adsorb oil droplets in the oil / water separation chamber but do not float up to the liquid level and float are floated up to the upper part of the partition plate by the forced flow by the quantitative water supply means. The fine bubbles that have moved to the upper part of the partition plate have a greater buoyancy when they come into contact with the floating oil, and the fine bubbles that settle or float again in the oil mixed waste liquid are reduced. In addition, fine bubbles that have obtained a large buoyancy at the upper part of the partition plate come into contact with the atmosphere by a slight levitation movement, and burst due to pressure fluctuations. That is, the fine bubbles overflowing the partition plate disappear or have sufficient buoyancy at the later stage and do not settle downward again. Further, in the latter stage, oil separation and waste liquid drainage can be performed simultaneously and simultaneously using the difference in specific gravity, so that the apparatus can be simplified and the separation efficiency can be improved.

本発明の油水分離装置によれば、油分と水分を分離する油水分離タンクと、任意流量の廃液を前記油水分離タンクへ順次送水する定量送水手段を備え、前記油水分離タンク内を流れの方向に前段と後段に二分割し、前段の上澄み液が後段に溢れ入るようにした仕切板を備え、前記油水分離タンクの前段は、底部に微細気泡を発生させる装置および前記微細気泡の噴出ノズルを備えた微細気泡による油吸着及び浮揚効果により油と廃液を上下に分離する油水分離室とし、前記油水分離タンクの後段は、さらに流れの方向に二分割し、上流側は浮上した油を回収する浮上油回収室とし、下流側は浮上油を分離し残った廃液が流入する廃液排水室とし、前記廃液排水室の入口は前記浮上油回収室の下部に配置し、さらに前記浮上油回収室内には、装置外へ通ずる油回収口を前記仕切板の上端より低い位置に設け、前記廃液排水室には、装置外へ通ずる廃液排水口を前記油回収口よりも低い位置に設けた構造としたことにより、所期の目的を達成することができる。すなわち、油水分離室内で油滴を吸着するものの液面まで浮上せず浮遊する微細気泡は、定量送水手段による強制流で仕切板上部まで浮上させられる。仕切板上部まで移動した微細気泡は、浮上油と接触することでより大きな浮力を持つこととなり、油分混合廃液内を再び沈降あるいは浮遊する微細気泡は減少する。また、仕切板上部で大きな浮力を得た微細気泡は僅かな浮上移動により大気と接触することになり、圧力変動により破裂する。すなわち仕切板を溢水する微細気泡は、後段では消滅または十分な浮力を持ち、再び下方へ沈降しなくなる。また、後段では比重差を利用し油の分離回収と廃液排水を一度にかつ同時に行えるので、装置の簡素化と分離効率の向上が図れる油水分離装置を提供することができる。   According to the oil / water separation device of the present invention, the oil / water separation tank for separating oil and water, and the quantitative water feeding means for sequentially feeding the waste liquid of an arbitrary flow rate to the oil / water separation tank, the flow in the oil / water separation tank is provided. A partition plate that is divided into a front stage and a rear stage so that the supernatant of the front stage overflows into the rear stage is provided, and the front stage of the oil-water separation tank is provided with a device that generates fine bubbles at the bottom and a nozzle for ejecting the fine bubbles. The oil / water separation chamber separates oil and waste liquid up and down due to the oil adsorption and levitation effect due to the fine bubbles, and the latter stage of the oil / water separation tank is further divided into two in the flow direction, and the upstream side is a floating surface that collects the floating oil It is an oil recovery chamber, the downstream side is a waste liquid drain chamber into which the remaining waste liquid is separated and the remaining waste liquid flows in, the inlet of the waste liquid drain chamber is arranged at the lower part of the floating oil recovery chamber, and further in the floating oil recovery chamber The By providing an oil recovery port leading to the outside at a position lower than the upper end of the partition plate, the waste liquid drainage chamber has a structure in which a waste liquid draining port leading to the outside of the apparatus is provided at a position lower than the oil recovery port, The intended purpose can be achieved. That is, although the oil droplets are adsorbed in the oil / water separation chamber, the fine bubbles that do not float up to the liquid level and float are floated up to the upper part of the partition plate by a forced flow by the quantitative water supply means. The fine bubbles that have moved to the upper part of the partition plate have a greater buoyancy when they come into contact with the floating oil, and the fine bubbles that settle or float again in the oil mixed waste liquid are reduced. In addition, fine bubbles that have obtained a large buoyancy at the upper part of the partition plate come into contact with the atmosphere by a slight levitation movement, and burst due to pressure fluctuations. That is, the fine bubbles overflowing the partition plate disappear or have sufficient buoyancy at the later stage and do not settle downward again. Further, since oil separation and recovery and waste liquid drainage can be performed at the same time using the difference in specific gravity at the latter stage, it is possible to provide an oil / water separation apparatus capable of simplifying the apparatus and improving the separation efficiency.

本発明の実施の形態1による油水分離装置の構成を示す概略図Schematic which shows the structure of the oil-water separator by Embodiment 1 of this invention. 同油水分離室に設けた傾斜板を示す概略図Schematic showing an inclined plate provided in the oil-water separation chamber 同油水分離室に混入させた小球を示す概略図Schematic showing small balls mixed in the oil-water separation chamber 同油水分離室と浮上油回収室との間の仕切板部分を示す概略図Schematic showing the partition plate part between the oil-water separation chamber and the floating oil recovery chamber

請求項1記載の発明は、油を含有した油分混合廃液から比重差を利用して油を分離回収する油分離装置であって、油分と水分を分離する油水分離タンクと、任意流量の廃液を前記油水分離タンクへ順次送水する定量送水手段を備え、前記油水分離タンク内を流れの方向に前段と後段に二分割し、前段の上澄み液が後段に溢れ入るようにした仕切板を備え、前記油水分離タンクの前段は、底部に微細気泡を発生させる装置および前記微細気泡の噴出ノズルを備えた微細気泡による油吸着及び浮揚効果により油と廃液を上下に分離する油水分離室とし、前記油水分離タンクの後段は、さらに流れの方向に二分割し、上流側は浮上した油を回収する浮上油回収室とし、下流側は浮上油を分離し残った廃液が流入する廃液排水室とし、前記廃液排水室の入口は前記浮上油回収室の下部に配置し、さらに前記浮上油回収室内には、装置外へ通ずる油回収口を前記仕切板の上端より低い位置に設け、前記廃液排水室には、装置外へ通ずる廃液排水口を前記油回収口よりも低い位置に設けた構造としたものであり、油水分離室内で油滴を吸着するものの液面まで浮上せず浮遊する微細気泡は、定量送水手段による強制流で仕切板上部まで浮上させられる。仕切板上部まで移動した微細気泡は、浮上油と接触することでより大きな浮力を持つこととなり、油分混合廃液内を再び沈降あるいは浮遊する微細気泡は減少する。また、仕切板上部で大きな浮力を得た微細気泡は僅かな浮上移動により大気と接触することになり、圧力変動により破裂する。すなわち仕切板を溢水する微細気泡は、後段では消滅または十分な浮力を持ち、再び下方へ沈降しなくなり、分離性能を高めることができ、低油分濃度で排水できるので排水処理槽への負荷低減を図れる作用を有する。また、後段では比重差を利用し油の分離回収と廃液排水を一度にかつ同時に行えるので、装置のコンパクト化、省メンテナンス化を図れる作用を有する。また回収油中に廃液が混入せず廃棄物量を削減できるので廃棄物処理費を低減できる作用を有する。   The invention according to claim 1 is an oil separation device that separates and recovers oil from oil-mixed waste liquid containing oil by utilizing a difference in specific gravity, an oil-water separation tank that separates oil and water, and waste liquid having an arbitrary flow rate. It comprises a quantitative water supply means for sequentially supplying water to the oil / water separation tank, and includes a partition plate that divides the inside of the oil / water separation tank into a front stage and a rear stage in a flow direction so that the supernatant liquid of the front stage overflows into the rear stage, The front stage of the oil-water separation tank is an oil-water separation chamber that separates oil and waste liquid up and down by the oil adsorption and floating effect by the fine bubbles equipped with a device that generates fine bubbles at the bottom and the fine-bubble jet nozzle, The latter part of the tank is further divided into two in the direction of flow, the upstream side is a floating oil recovery chamber for recovering the floating oil, and the downstream side is a waste liquid drain chamber for separating the floating oil and the remaining waste liquid flows in, and the waste liquid Drainage chamber The inlet is arranged at the lower part of the floating oil recovery chamber, and an oil recovery port is provided in the floating oil recovery chamber at a position lower than the upper end of the partition plate. The waste liquid drain port leading to the oil recovery port is provided at a position lower than the oil recovery port. It is levitated to the upper part of the partition plate by forced flow. The fine bubbles that have moved to the upper part of the partition plate have a greater buoyancy when they come into contact with the floating oil, and the fine bubbles that settle or float again in the oil mixed waste liquid are reduced. In addition, fine bubbles that have obtained a large buoyancy at the upper part of the partition plate come into contact with the atmosphere by a slight levitation movement, and burst due to pressure fluctuations. In other words, the fine bubbles overflowing the partition plate disappear in the later stage or have sufficient buoyancy and do not settle down again, so that the separation performance can be improved and the oil can be drained at a low oil concentration, reducing the load on the wastewater treatment tank. It has an effect that can be achieved. In the latter stage, oil separation and recovery and wastewater drainage can be performed simultaneously and simultaneously by utilizing the difference in specific gravity, so that the apparatus can be made compact and maintenance can be saved. In addition, since the waste liquid is not mixed in the recovered oil and the amount of waste can be reduced, the waste disposal cost can be reduced.

また、請求項2記載の発明は、油水分離室内に傾斜した板を配置したことにより、油滴を吸着するものの浮力が小さく浮上しない微細気泡が、僅かな浮上移動で傾斜した板に接触し吸着される。さらに板表面で他の微細気泡と重なり合うことでより大きな浮力を得て、板の傾斜に沿って浮上することができるので、分離性能を高めることができ、低油分濃度で排水できるので排水処理槽への負荷低減を図れる作用を有する。   Further, according to the second aspect of the present invention, since the inclined plate is disposed in the oil / water separation chamber, fine bubbles that adsorb oil droplets but do not float with a small buoyancy come into contact with the inclined plate with a slight rising movement and adsorb. Is done. Furthermore, it can obtain greater buoyancy by overlapping with other fine bubbles on the surface of the plate, and can float along the inclination of the plate, so that separation performance can be improved and drainage can be drained at a low oil concentration, so a wastewater treatment tank It has the effect | action which can aim at the load reduction to.

また、請求項3記載の発明は、油水分離室内に水よりも比重が小さく疎水性を有する材料の小球を混入させたことにより、油滴を吸着するものの浮力が小さく浮上しない微細気泡が、定量送水手段による強制流で仕切板上部水面まで浮上する前に小球と接触吸着し、球表面で他の微細気泡と重なり合うことでより大きな浮力を得て、浮上することができるので、分離性能を高めることができ、低油分濃度で排水できるので排水処理槽への負荷低減を図れる作用を有する。   Further, the invention according to claim 3 is a mixture of small spheres of material having a specific gravity smaller than water and having hydrophobicity in the oil / water separation chamber, so that fine bubbles that adsorb oil droplets but have low buoyancy and do not float, Separation performance because it is possible to get more buoyancy by associating with small spheres before they ascend to the upper water surface of the partition plate by forced flow by the quantitative water supply means, and by surfacing with other fine bubbles on the sphere surface to obtain greater buoyancy. Since the water can be drained at a low oil concentration, the load on the waste water treatment tank can be reduced.

また、請求項4記載の発明は、仕切板上部表面を凹凸形状にしたことにより、仕切板上部を移動する微細気泡を含む油分混合廃液は乱流になり、浮上油および大気と接触する確率が高まり、仕切板を溢水した微細気泡は油水分離タンク後段では、より消滅または十分な浮力を持ち、再び混合廃液の下方へ沈降しなくなるので、分離性能を高めることができ、低油分濃度で排水できるので排水処理槽への負荷低減を図れる作用を有する。   Further, in the invention according to claim 4, since the upper surface of the partition plate is made uneven, the oil mixed waste liquid containing fine bubbles moving on the upper portion of the partition plate becomes turbulent and has a probability of coming into contact with the floating oil and the atmosphere. The fine bubbles that overflow and overflow the partition plate disappear more or have sufficient buoyancy in the latter part of the oil / water separation tank and do not settle again below the mixed waste liquid, so that the separation performance can be improved and drained at a low oil concentration Therefore, it has the effect | action which can aim at the load reduction to a wastewater treatment tank.

また、請求項5記載の発明は、仕切板上部表面に向けて垂直下方にエアを吹付ける手段を備えたことにより、仕切板上部を移動する微細気泡を含む油分混合廃液は上下方向に攪拌され、浮上油および大気と接触する確率が高まり、仕切板を溢水した微細気泡は油水分離タンク後段では、より消滅または十分な浮力を持ち、再び混合廃液の下方へ沈降しなくなるので、分離性能を高めることができ、低油分濃度で排水できるので排水処理槽への負荷低減を図れる作用を有する。   Further, the invention according to claim 5 is provided with means for blowing air vertically downward toward the upper surface of the partition plate, so that the oil mixed waste liquid containing fine bubbles moving on the upper portion of the partition plate is stirred in the vertical direction. The probability of contact with floating oil and the atmosphere increases, and the fine bubbles overflowing the partition plate disappear more or have sufficient buoyancy at the latter stage of the oil-water separation tank, and do not settle again below the mixed waste liquid, thus improving the separation performance It can be drained with a low oil concentration, and has the effect of reducing the load on the wastewater treatment tank.

また、請求項6記載の発明は、浮上油回収室の水平断面積を廃液排水室の水平断面積よりも小さくしたことにより、浮上油分離室内に流入した浮上油層の厚みが増し、廃液との水位差が大きくなるので分離性能を高めることができ、低油分濃度で排水できるので排水処理槽への負荷低減を図れる作用を有する。   In the invention of claim 6, the horizontal cross-sectional area of the floating oil recovery chamber is made smaller than the horizontal cross-sectional area of the waste liquid drainage chamber, so that the thickness of the floating oil layer flowing into the floating oil separation chamber is increased. Since the water level difference increases, the separation performance can be improved, and drainage can be performed at a low oil concentration, so that the load on the wastewater treatment tank can be reduced.

また、請求項7記載の発明は、浮上油回収室において浮上油を油回収口に運ぶ流路を形成するようにエア吹付け手段を備えたことにより、浮上油回収室の上部に浮上した油を確実かつ迅速に浮上油回収口へ運ぶことで分離効率を高めることができ、低油分濃度で排水できるので排水処理槽への負荷低減を図れる作用を有する。また、液面が常に流動するので浮上油の固化防止となり、省メンテナンス化を図れる作用を有する。   Further, the invention according to claim 7 is the oil that floats above the floating oil recovery chamber by providing air blowing means so as to form a flow path for conveying the floating oil to the oil recovery port in the floating oil recovery chamber. Is reliably and quickly carried to the floating oil recovery port, so that the separation efficiency can be increased and drainage can be performed at a low oil concentration, so that the load on the wastewater treatment tank can be reduced. Further, since the liquid level always flows, the floating oil can be prevented from solidifying, and the operation can be saved.

また、請求項8記載の発明は、浮上油回収室においてエア吹付け手段を浮上油回収室の壁面に向けて設け、浮上油回収室上層に渦を発生させることにより、渦中心に負圧が発生し、浮上油回収室内の油分混合廃液表面では、浮上油が渦の中心に引き込まれるような流れが発生し、分散した浮上油を渦の中心に集めることができ、中心に集めた油を浮上油回収口から機外へ排出できるので、回収する油分量が多くなり分離性能を高めることができ、低油分濃度で排水できるので排水処理槽への負荷低減を図れる作用を有する。   In the invention according to claim 8, air blowing means is provided in the floating oil recovery chamber toward the wall surface of the floating oil recovery chamber, and a vortex is generated in the upper layer of the floating oil recovery chamber, whereby a negative pressure is applied to the vortex center. At the surface of the mixed oil waste liquid in the floating oil recovery chamber, a flow that causes the floating oil to be drawn into the center of the vortex occurs, and the dispersed floating oil can be collected at the center of the vortex. Since the oil can be discharged from the floating oil recovery port to the outside of the machine, the amount of oil to be recovered can be increased, the separation performance can be improved, and drainage can be performed at a low oil concentration, so that the load on the wastewater treatment tank can be reduced.

以下、本発明の実施の形態について図面を参照しながら説明する。   Hereinafter, embodiments of the present invention will be described with reference to the drawings.

(実施の形態1)
図1は本発明の実施の形態1における油水分離装置の構成図を示している。
(Embodiment 1)
FIG. 1 shows a configuration diagram of an oil-water separator in Embodiment 1 of the present invention.

工場や変電所またはガソリンスタンド等で発生した油分混合廃液は、油分混合廃液貯留槽(図示せず)に一旦貯留され、定量送水器具(図示せず)を介して油水分離タンク1に送水される。油水分離タンク1は例えばステンレスまたはポリプロピレン樹脂で形成された容器である。また、油水分離タンク1は廃液の流れの方向に三段に分割されており、前段より油水分離室2、浮上油回収室3、廃液排水室4から構成される。定量送水器具から送水される油分混合廃液(油−水エマルション11)は、油水分離室2の下方に設けた油水分離室入口21から流入する。ここで、油水分離室2の容量は処理対象液体の全量が注水される油分混合廃液貯留槽の容量の1/8程度としている。さらに定量送水器具の流量は、油分混合廃液貯留槽に注水される処理対象液体の全量を2時間から24時間掛けて送水する流量に設定可能としている。なお本装置の配管は油分混合廃液の粘性や目詰まりを考慮し、直径10mm以上としている。また、油水分離室2の底部には微細気泡発生装置5が具備されている。微細気泡発生装置5は、例えば圧縮空気が多孔質であるセラミックスや焼結合金を通過することで気泡を発生する方式であってもよいし、あるいは水流による負圧を利用して空気を油分混合廃液内に巻き込み、水流との相対運動によって空気をせん断し微細気泡を発生する方式であってもよい。なお微細気泡発生装置5のノズルは、油水分離室2の全域に微細気泡9が行き渡るように設けてある。   Oil mixed waste liquid generated at a factory, substation, gasoline station, etc. is temporarily stored in an oil mixed waste liquid storage tank (not shown), and is sent to the oil / water separation tank 1 via a quantitative water supply device (not shown). . The oil / water separation tank 1 is a container formed of, for example, stainless steel or polypropylene resin. The oil / water separation tank 1 is divided into three stages in the direction of the waste liquid flow, and comprises an oil / water separation chamber 2, a floating oil recovery chamber 3, and a waste liquid drain chamber 4 from the previous stage. The oil-mixed waste liquid (oil-water emulsion 11) fed from the fixed-quantity water feeding device flows from an oil-water separation chamber inlet 21 provided below the oil-water separation chamber 2. Here, the capacity | capacitance of the oil-water separation chamber 2 is made into about 1/8 of the capacity | capacitance of the oil content mixing waste liquid storage tank into which the whole quantity of process target liquid is poured. Furthermore, the flow rate of the quantitative water supply device can be set to a flow rate for supplying the entire amount of the liquid to be treated poured into the oil mixed waste liquid storage tank over 2 to 24 hours. The piping of this apparatus has a diameter of 10 mm or more in consideration of the viscosity and clogging of the oil mixed waste liquid. A fine bubble generator 5 is provided at the bottom of the oil / water separation chamber 2. The fine bubble generating device 5 may be a method in which, for example, compressed air passes through a porous ceramic or sintered alloy to generate bubbles, or air is mixed with oil using a negative pressure generated by a water flow. A method of generating fine bubbles by entraining in the waste liquid and shearing the air by relative movement with the water flow may be used. Note that the nozzles of the fine bubble generating device 5 are provided so that the fine bubbles 9 are distributed throughout the oil-water separation chamber 2.

また、油水分離室2、浮上油回収室3の間には、油水分離室2で浮上した油分が浮上油回収室3に溢れ出る敷居となる仕切板6が設けられている。この仕切板6は油水分離室2に溜った上澄み液が浮上油回収室3に溢れ入るように配置している。また、仕切板6はその上部表面積を大きくすることで、仕切板6の上部を溢水する油分混合液体の流速が極力小さくなるような形状をしている。   In addition, a partition plate 6 is provided between the oil / water separation chamber 2 and the floating oil recovery chamber 3 as a sill from which oil floating in the oil / water separation chamber 2 overflows into the floating oil recovery chamber 3. The partition plate 6 is arranged so that the supernatant liquid collected in the oil / water separation chamber 2 overflows into the floating oil recovery chamber 3. Further, the partition plate 6 is shaped so that the flow rate of the oil-mixed liquid overflowing the upper portion of the partition plate 6 is minimized by increasing the upper surface area.

次に浮上油回収室3の下部には廃液排水室入口12を設け、廃液排水室4と連通させている。浮上油10を分離し残った廃液は、廃液排水室4に流入する。ここで、浮上油回収室3の内部には装置外へ通ずる浮上油回収口7を仕切板6より低い位置に設け、廃液排水室4の内部には、同様に装置外へ通ずる廃液排水口8を仕切板6および浮上油回収口7よりも低い位置に設けている。   Next, a waste liquid drain chamber inlet 12 is provided at the bottom of the floating oil recovery chamber 3 so as to communicate with the waste liquid drain chamber 4. The waste liquid remaining after separating the floating oil 10 flows into the waste liquid drainage chamber 4. Here, a floating oil recovery port 7 that leads to the outside of the apparatus is provided at a position lower than the partition plate 6 inside the floating oil recovery chamber 3, and a waste liquid drain port 8 that similarly leads to the outside of the apparatus inside the waste liquid drain chamber 4. Is provided at a position lower than the partition plate 6 and the floating oil recovery port 7.

続いて油水分離室2及び仕切板6で分離した浮上油10及び廃液は、各々の流入量に応じて、浮上油回収室3および廃液排水室4の水位を個別に上昇させ、浮上油回収口7または廃液排水口8の高さを越えた場合に落下し、油を回収または廃液を排水する。   Subsequently, the floating oil 10 and the waste liquid separated by the oil / water separation chamber 2 and the partition plate 6 individually raise the water levels in the floating oil recovery chamber 3 and the waste liquid drainage chamber 4 according to the respective inflow amounts, and the floating oil recovery port 7 or when the height of the waste liquid drain port 8 is exceeded, the oil falls or drains the waste liquid.

ここでは、油水分離室2の後段に浮上油回収室3と廃液排水室4をそれぞれ1室ずつ設けているが、更に廃液排水室4の後段に同様の廃液排水室を複数連続して設け、最も後段の廃液排水室4より廃液を排水すれば、分離性能が高まる。   Here, one floating oil recovery chamber 3 and one waste liquid drain chamber 4 are provided in the subsequent stage of the oil / water separation chamber 2, but a plurality of similar waste liquid drain chambers are continuously provided in the subsequent stage of the waste liquid drain chamber 4, If the waste liquid is drained from the waste liquid drain chamber 4 at the rearmost stage, the separation performance is enhanced.

ここでは、浮上油回収室3と廃液排水室4の水平断面積は同じにしているが、廃液排水室4よりも浮上油回収室3の水平断面積を小さくすれば、浮上油回収室3内部の浮上油10の厚みが増し、廃液との水位差が大きくなり分離性能は高まる。   Here, the horizontal cross-sectional area of the floating oil recovery chamber 3 and the waste liquid drain chamber 4 is the same, but if the horizontal cross-sectional area of the floating oil recovery chamber 3 is smaller than that of the waste liquid drain chamber 4, the inside of the floating oil recovery chamber 3 The thickness of the floating oil 10 increases, and the difference in water level from the waste liquid increases and the separation performance increases.

さらにここでは、浮上油回収口7は浮上油回収室3の水平断面中央に設け、且つ上向きに開口し、浮上油10の液面が開口高さを超えた場合に下向きに溢水するように配置しており、これにより浮上油10の上澄みのみが排出可能になり、回収する油分濃度が高くなる。   Further, here, the floating oil recovery port 7 is provided in the center of the horizontal section of the floating oil recovery chamber 3 and opens upward, and is arranged so as to overflow downward when the liquid level of the floating oil 10 exceeds the opening height. Thus, only the supernatant of the floating oil 10 can be discharged, and the concentration of the oil to be recovered increases.

図2では、油水分離室2に設けた傾斜板13を示している。傾斜板13は例えばポリプロピレン樹脂で形成された薄い板であり、複数枚の板が等間隔に配置され、下流方向が高くなるように一定角度で配置されている。ここで傾斜板13の角度は30度から80度程度としている。油水分離室2で油滴を吸着するものの液面まで浮上せず浮遊する微細気泡9が、僅かな浮上移動で傾斜板13に接触し吸着される。さらに傾斜板13の表面で他の微細気泡9と重なり合うことでより大きな浮力を得て、板の傾斜に沿って液面まで浮上することができるので分離効率が高まる。   In FIG. 2, the inclined plate 13 provided in the oil-water separation chamber 2 is shown. The inclined plate 13 is a thin plate made of, for example, polypropylene resin, and a plurality of plates are arranged at equal intervals and arranged at a constant angle so that the downstream direction becomes higher. Here, the angle of the inclined plate 13 is about 30 to 80 degrees. Although the oil droplets are adsorbed in the oil / water separation chamber 2, the fine bubbles 9 that do not float up to the liquid level and float are brought into contact with the inclined plate 13 and adsorbed by a slight floating movement. Furthermore, it is possible to obtain a greater buoyancy by overlapping with the other fine bubbles 9 on the surface of the inclined plate 13 and to rise to the liquid surface along the inclination of the plate, so that the separation efficiency is increased.

図3では、油水分離室2に混入させた小球14を示している。小球14は、水よりも比重が小さく疎水性を有する材料で、例えばポリプロピレン樹脂で形成されたものである。また、小球14は、直径10から50mm程度の球体であるが、必ずしも球体でなくてもよい。油水分離室2内では、油滴を吸着するものの浮力が小さく浮上しない微細気泡が、定量送水手段による強制流で仕切板上部水面まで浮上する前に小球14と接触吸着し、球表面で他の微細気泡9と重なり合うことでより大きな浮力を得て、浮上することができるので分離効率が高まる。   FIG. 3 shows a small ball 14 mixed in the oil / water separation chamber 2. The small sphere 14 is a material having a specific gravity smaller than that of water and having hydrophobicity, and is formed of, for example, a polypropylene resin. The small sphere 14 is a sphere having a diameter of about 10 to 50 mm, but is not necessarily a sphere. In the oil / water separation chamber 2, fine bubbles that adsorb oil droplets but have low buoyancy and do not rise are brought into contact with and adsorbed on the small sphere 14 before rising to the upper surface of the partition plate by forced flow by the quantitative water supply means. By overlapping with the fine bubbles 9, a greater buoyancy can be obtained and the buoyancy can be achieved, thereby increasing the separation efficiency.

図4では、仕切板上部表面15を凹凸形状にしたものを示している。凹凸形状にしたことにより、仕切板6の上部を移動する微細気泡9を含む油分混合廃液の流れは乱流になって、微細気泡9が浮上油10および大気と接触する確率が高まる。このような仕切板6を溢水した微細気泡9は、浮上油回収室3では消滅するか、または十分な浮力を持ち、再び下方へ沈降せず浮上するので、微細気泡9に吸着した油分を回収でき、分離性能は高まる。   FIG. 4 shows the partition plate upper surface 15 having an uneven shape. Due to the concavo-convex shape, the flow of the oil-mixed waste liquid containing the fine bubbles 9 moving above the partition plate 6 becomes turbulent, and the probability that the fine bubbles 9 come into contact with the floating oil 10 and the atmosphere increases. The fine bubbles 9 overflowing the partition plate 6 disappear in the floating oil collection chamber 3 or have sufficient buoyancy and rise again without sinking downward, so that the oil adsorbed on the fine bubbles 9 is collected. And separation performance is enhanced.

また、仕切板上部表面15に向けて垂直下方にエアを吹付ける手段(エア吹付け手段16)を備えている。ここでエア吹付け流量と流速は、仕切板上部表面15において油分混合廃液が逆流しない程度に調整している。エアを吹付けることにより、仕切板上部表面15を移動する微細気泡9を含む油分混合廃液は上下方向に攪拌され、浮上油10および大気と接触する確率が高まる。このような仕切板6を溢水した微細気泡9は、浮上油回収室3では消滅するか、または十分な浮力を持ち、再び下方へ沈降せず浮上するので、微細気泡9に吸着した油分を回収でき、分離性能は高まる。   In addition, a means (air blowing means 16) for blowing air vertically downward toward the partition plate upper surface 15 is provided. Here, the air blowing flow rate and the flow velocity are adjusted to such an extent that the oil mixed waste liquid does not flow backward on the partition plate upper surface 15. By blowing air, the oil-mixed waste liquid containing the fine bubbles 9 that move on the upper surface 15 of the partition plate is agitated in the vertical direction, and the probability of coming into contact with the floating oil 10 and the atmosphere increases. The fine bubbles 9 overflowing the partition plate 6 disappear in the floating oil collection chamber 3 or have sufficient buoyancy and rise again without sinking downward, so that the oil adsorbed on the fine bubbles 9 is collected. And separation performance is enhanced.

また、浮上油回収室3に浮上油10を浮上油回収口7に運ぶ流路を形成するようにエア吹付け手段16を備えている。エアを吹付けることにより、浮上油回収室3の上層に浮上した油を確実かつ迅速に浮上油回収口7へ運ぶことができ、分離性能は高まる。また、液面が常に流動するので浮上油の固化防止となり得る。   Further, air blowing means 16 is provided in the floating oil recovery chamber 3 so as to form a flow path for carrying the floating oil 10 to the floating oil recovery port 7. By blowing air, the oil that has floated to the upper layer of the floating oil recovery chamber 3 can be reliably and promptly conveyed to the floating oil recovery port 7 and the separation performance is enhanced. In addition, since the liquid level always flows, the floating oil can be prevented from solidifying.

また、浮上油回収室3において浮上油回収室3の壁面に向けてエア吹付け手段16を備えている。エアを吹付けることにより、浮上油回収室3の上層に渦を発生させることにより、渦中心に負圧が発生し、浮上油10が渦の中心に引き込まれるような流れが発生し、分散した浮上油10を渦の中心に集めることができ、中心に集めた油を浮上油回収口7から機外へ排出できるので、回収する油分量が多くなり分離性能は高まる。   The floating oil recovery chamber 3 is provided with air blowing means 16 toward the wall surface of the floating oil recovery chamber 3. By blowing air, a vortex is generated in the upper layer of the floating oil recovery chamber 3, a negative pressure is generated at the center of the vortex, and a flow in which the floating oil 10 is drawn into the center of the vortex is generated and dispersed. The floating oil 10 can be collected at the center of the vortex, and the oil collected at the center can be discharged from the floating oil collection port 7 to the outside of the machine, so that the amount of oil to be collected is increased and the separation performance is improved.

本発明の油水分離装置は、工場や変電所またはガソリンスタンド等で発生する油分混合水の処理において、集水槽等から放流する際に、水質汚濁防止法の排水基準値を満たす油分に浄化する策として使用する油水分離装置、あるいは工場等で金属の切削や研磨等のクーラントの処理、または設備や工作物等に付着した油を洗浄した際に発生する比較的油分濃度の高い油分混合洗浄廃水を排水処理槽へ送水する前処理として油分を分離回収し、排水処理槽の負荷を低減する策として使用する油水分離装置などにおいて利用可能である。   The oil / water separator according to the present invention is a measure for purifying to an oil that meets the wastewater standard value of the Water Pollution Control Law when discharged from a water collection tank or the like in the treatment of oil-mixed water generated at factories, substations, gas stations, etc. Oil / water separation equipment used as a coolant, or processing of coolant such as metal cutting and polishing in factories, etc., or oil mixed washing wastewater with a relatively high oil concentration generated when cleaning oil adhering to equipment or workpieces It can be used in an oil / water separator used as a measure for separating and recovering oil as a pretreatment for sending water to a wastewater treatment tank and reducing the load on the wastewater treatment tank.

1 油水分離タンク
2 油水分離室
3 浮上油回収室
4 廃液排水室
5 微細気泡発生装置
6 仕切板
7 浮上油回収口
8 廃液排水口
9 微細気泡
10 浮上油
11 油−水エマルション
12 廃液排水室入口
13 傾斜板
14 小球
15 仕切板上部表面
16 エア吹付け手段
21 油水分離室入口
DESCRIPTION OF SYMBOLS 1 Oil-water separation tank 2 Oil-water separation chamber 3 Floating oil collection chamber 4 Waste liquid drainage chamber 5 Fine bubble generator 6 Partition plate 7 Floating oil collection port 8 Waste liquid drain port 9 Fine bubble 10 Floating oil 11 Oil-water emulsion 12 Waste liquid drain chamber entrance 13 Inclined plate 14 Small ball 15 Partition plate upper surface 16 Air spraying means 21 Oil water separation chamber inlet

Claims (8)

油を含有した油分混合廃液から比重差を利用して油を分離回収する油分離装置であって、油分と水分を分離する油水分離タンクと、任意流量の廃液を前記油水分離タンクへ順次送水する定量送水手段を備え、前記油水分離タンク内を流れの方向に前段と後段に二分割し、前段の上澄み液が後段に溢れ入るようにした仕切板を備え、前記油水分離タンクの前段は、底部に微細気泡を発生させる装置および前記微細気泡の噴出ノズルを備えた微細気泡による油吸着及び浮揚効果により油と廃液を上下に分離する油水分離室とし、前記油水分離タンクの後段は、さらに流れの方向に二分割し、上流側は浮上した油を回収する浮上油回収室とし、下流側は浮上油を分離し残った廃液が流入する廃液排水室とし、前記廃液排水室の入口は前記浮上油回収室の下部に配置し、さらに前記浮上油回収室内には、装置外へ通ずる油回収口を前記仕切板の上端より低い位置に設け、前記廃液排水室には、装置外へ通ずる廃液排水口を前記油回収口よりも低い位置に設けたことを特徴とする油水分離装置。 An oil separation device that separates and recovers oil from oil-mixed waste liquid containing oil by utilizing a specific gravity difference, and sequentially feeds an oil-water separation tank that separates oil and water, and an arbitrary flow rate of waste liquid to the oil-water separation tank. The oil / water separation tank is divided into a front stage and a rear stage in the direction of flow, and a partition plate is provided so that the supernatant liquid of the front stage overflows into the rear stage, and the front stage of the oil / water separation tank has a bottom portion. And an oil / water separation chamber for separating oil and waste liquid up and down by the effect of oil adsorption and levitation by the fine bubbles equipped with a device for generating fine bubbles, and the latter stage of the oil / water separation tank The upstream side is a floating oil recovery chamber that collects floating oil, the downstream side is a waste liquid drainage chamber that separates the floating oil and the remaining waste liquid flows in, and the inlet of the waste liquid drainage chamber is the floating oil recovery chamber Recovery In addition, an oil recovery port that communicates outside the apparatus is provided at a position lower than the upper end of the partition plate in the floating oil collection chamber, and a waste liquid drain port that communicates outside the apparatus is provided in the waste liquid drain chamber. An oil / water separator characterized by being provided at a position lower than the oil recovery port. 前記油水分離室内に傾斜した板を配置したことを特徴とする請求項1記載の油水分離装置。 The oil / water separator according to claim 1, wherein an inclined plate is disposed in the oil / water separator chamber. 前記油水分離室内に水よりも比重が小さく疎水性の小球を混入させたことを特徴とする請求項1または請求項2記載の油水分離装置。 3. The oil / water separator according to claim 1, wherein hydrophobic spheres having a specific gravity smaller than water are mixed in the oil / water separation chamber. 前記仕切板の上部表面は凹凸形状にしたことを特徴とする請求項1〜3いずれかひとつに記載の油水分離装置。 The oil-water separator according to any one of claims 1 to 3, wherein the upper surface of the partition plate has an uneven shape. 前記仕切板の上部表面に向けて垂直下方にエアを吹付ける手段を備えたことを特徴とする請求項1〜4いずれかひとつに記載の油水分離装置。 The oil-water separator according to any one of claims 1 to 4, further comprising means for blowing air vertically downward toward the upper surface of the partition plate. 前記浮上油回収室の水平断面積は、前記廃液排水室の水平断面積よりも小さくしたことを特徴とする請求項1〜5いずれかひとつに記載の油水分離装置。 The oil / water separator according to any one of claims 1 to 5, wherein a horizontal cross-sectional area of the floating oil recovery chamber is smaller than a horizontal cross-sectional area of the waste liquid drainage chamber. 前記浮上油回収室には、浮上油を前記油回収口に運ぶ流路を形成するようにエアを吹付けるエア吹付け手段を備えたことを特徴とする請求項1〜6いずれかひとつに記載の油水分離装置。 The said floating oil collection | recovery chamber was equipped with the air spraying means which sprays air so that the flow path which conveys floating oil to the said oil collection port may be formed. Oil-water separator. 前記エア吹付け手段を前記浮上油回収室の壁面に向けて設け、浮上油回収室上層に渦を発生させることを特徴とする請求項1〜7いずれかひとつに記載の油水分離装置。 The oil / water separator according to any one of claims 1 to 7, wherein the air blowing means is provided toward a wall surface of the floating oil recovery chamber to generate a vortex in the upper layer of the floating oil recovery chamber.
JP2009165654A 2009-07-14 2009-07-14 Oil-water separator Pending JP2011020025A (en)

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