JP2010285395A - Detergent composition - Google Patents
Detergent composition Download PDFInfo
- Publication number
- JP2010285395A JP2010285395A JP2009141541A JP2009141541A JP2010285395A JP 2010285395 A JP2010285395 A JP 2010285395A JP 2009141541 A JP2009141541 A JP 2009141541A JP 2009141541 A JP2009141541 A JP 2009141541A JP 2010285395 A JP2010285395 A JP 2010285395A
- Authority
- JP
- Japan
- Prior art keywords
- yeast
- hair
- examples
- acid
- amino acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 39
- 239000003599 detergent Substances 0.000 title claims abstract description 15
- 240000004808 Saccharomyces cerevisiae Species 0.000 claims abstract description 49
- 235000014680 Saccharomyces cerevisiae Nutrition 0.000 claims abstract description 47
- 150000001413 amino acids Chemical class 0.000 claims abstract description 31
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 28
- 229940041514 candida albicans extract Drugs 0.000 claims abstract description 25
- 239000012138 yeast extract Substances 0.000 claims abstract description 25
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 24
- 235000019992 sake Nutrition 0.000 claims abstract description 6
- 238000004140 cleaning Methods 0.000 claims description 27
- 238000011282 treatment Methods 0.000 claims description 22
- 235000000346 sugar Nutrition 0.000 claims description 19
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 238000005406 washing Methods 0.000 abstract description 31
- 238000001035 drying Methods 0.000 abstract description 27
- 239000000284 extract Substances 0.000 abstract description 6
- 150000001720 carbohydrates Chemical class 0.000 abstract description 2
- 229940024606 amino acid Drugs 0.000 description 35
- 235000001014 amino acid Nutrition 0.000 description 35
- -1 alkyl glucosides Chemical class 0.000 description 30
- 230000014759 maintenance of location Effects 0.000 description 21
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 17
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 14
- 239000004094 surface-active agent Substances 0.000 description 14
- 235000014113 dietary fatty acids Nutrition 0.000 description 13
- 239000000194 fatty acid Substances 0.000 description 13
- 229930195729 fatty acid Natural products 0.000 description 13
- 238000011156 evaluation Methods 0.000 description 12
- 229920001296 polysiloxane Polymers 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 10
- 239000002253 acid Substances 0.000 description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
- 229930006000 Sucrose Natural products 0.000 description 9
- 150000002148 esters Chemical class 0.000 description 9
- 239000002453 shampoo Substances 0.000 description 9
- 239000005720 sucrose Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 235000019441 ethanol Nutrition 0.000 description 7
- 238000005187 foaming Methods 0.000 description 7
- 235000011187 glycerol Nutrition 0.000 description 7
- 150000003839 salts Chemical group 0.000 description 7
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 125000002252 acyl group Chemical group 0.000 description 6
- 238000004043 dyeing Methods 0.000 description 6
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 5
- 239000004166 Lanolin Substances 0.000 description 5
- 229920001214 Polysorbate 60 Polymers 0.000 description 5
- 150000004665 fatty acids Chemical class 0.000 description 5
- 235000019388 lanolin Nutrition 0.000 description 5
- 229940039717 lanolin Drugs 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 229920001223 polyethylene glycol Polymers 0.000 description 5
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 4
- 239000002202 Polyethylene glycol Substances 0.000 description 4
- 239000012459 cleaning agent Substances 0.000 description 4
- 239000004205 dimethyl polysiloxane Substances 0.000 description 4
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 4
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 4
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000000600 sorbitol Substances 0.000 description 4
- 206010013786 Dry skin Diseases 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- 229960000541 cetyl alcohol Drugs 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000003240 coconut oil Substances 0.000 description 3
- 235000019864 coconut oil Nutrition 0.000 description 3
- 230000002950 deficient Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 230000037336 dry skin Effects 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 229930182478 glucoside Natural products 0.000 description 3
- 229940075507 glyceryl monostearate Drugs 0.000 description 3
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 3
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 3
- 210000004761 scalp Anatomy 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 229920001059 synthetic polymer Polymers 0.000 description 3
- 229940058015 1,3-butylene glycol Drugs 0.000 description 2
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 2
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- JOOXCMJARBKPKM-UHFFFAOYSA-N 4-oxopentanoic acid Chemical compound CC(=O)CCC(O)=O JOOXCMJARBKPKM-UHFFFAOYSA-N 0.000 description 2
- ODHCTXKNWHHXJC-VKHMYHEASA-N 5-oxo-L-proline Chemical compound OC(=O)[C@@H]1CCC(=O)N1 ODHCTXKNWHHXJC-VKHMYHEASA-N 0.000 description 2
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 2
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 2
- SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 2
- FZERHIULMFGESH-UHFFFAOYSA-N N-phenylacetamide Chemical compound CC(=O)NC1=CC=CC=C1 FZERHIULMFGESH-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 241000235070 Saccharomyces Species 0.000 description 2
- 108010077895 Sarcosine Proteins 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- IYFATESGLOUGBX-YVNJGZBMSA-N Sorbitan monopalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O IYFATESGLOUGBX-YVNJGZBMSA-N 0.000 description 2
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 2
- 239000004147 Sorbitan trioleate Substances 0.000 description 2
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 150000008051 alkyl sulfates Chemical class 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 235000006708 antioxidants Nutrition 0.000 description 2
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical compound CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 2
- 235000013871 bee wax Nutrition 0.000 description 2
- 239000012166 beeswax Substances 0.000 description 2
- 229940092738 beeswax Drugs 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 235000019437 butane-1,3-diol Nutrition 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 229920006317 cationic polymer Polymers 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 2
- 239000002738 chelating agent Substances 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- 229940008099 dimethicone Drugs 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000002552 dosage form Substances 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 239000004220 glutamic acid Substances 0.000 description 2
- 235000013922 glutamic acid Nutrition 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 229910017053 inorganic salt Inorganic materials 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 230000007794 irritation Effects 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 2
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 2
- 229960002216 methylparaben Drugs 0.000 description 2
- 230000003020 moisturizing effect Effects 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000003002 pH adjusting agent Substances 0.000 description 2
- CPJSUEIXXCENMM-UHFFFAOYSA-N phenacetin Chemical compound CCOC1=CC=C(NC(C)=O)C=C1 CPJSUEIXXCENMM-UHFFFAOYSA-N 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 229940079889 pyrrolidonecarboxylic acid Drugs 0.000 description 2
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 description 2
- 229940081974 saccharin Drugs 0.000 description 2
- 235000019204 saccharin Nutrition 0.000 description 2
- 239000000901 saccharin and its Na,K and Ca salt Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229940035044 sorbitan monolaurate Drugs 0.000 description 2
- 239000001570 sorbitan monopalmitate Substances 0.000 description 2
- 235000011071 sorbitan monopalmitate Nutrition 0.000 description 2
- 229940031953 sorbitan monopalmitate Drugs 0.000 description 2
- 239000001587 sorbitan monostearate Substances 0.000 description 2
- 235000011076 sorbitan monostearate Nutrition 0.000 description 2
- 229940035048 sorbitan monostearate Drugs 0.000 description 2
- 235000019337 sorbitan trioleate Nutrition 0.000 description 2
- 229960000391 sorbitan trioleate Drugs 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- MTCFGRXMJLQNBG-REOHCLBHSA-N (2S)-2-Amino-3-hydroxypropansäure Chemical compound OC[C@H](N)C(O)=O MTCFGRXMJLQNBG-REOHCLBHSA-N 0.000 description 1
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 1
- CUNWUEBNSZSNRX-RKGWDQTMSA-N (2r,3r,4r,5s)-hexane-1,2,3,4,5,6-hexol;(z)-octadec-9-enoic acid Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O CUNWUEBNSZSNRX-RKGWDQTMSA-N 0.000 description 1
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 1
- FABAOYOFJNAVHB-KVVVOXFISA-N (z)-octadec-9-enoic acid;propane-1,2,3-triol Chemical compound OCC(O)CO.CCCCCCCC\C=C/CCCCCCCC(O)=O FABAOYOFJNAVHB-KVVVOXFISA-N 0.000 description 1
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 1
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 description 1
- OOWQBDFWEXAXPB-IBGZPJMESA-N 1-O-hexadecyl-sn-glycerol Chemical compound CCCCCCCCCCCCCCCCOC[C@@H](O)CO OOWQBDFWEXAXPB-IBGZPJMESA-N 0.000 description 1
- JPPRXACMNPYJNK-UHFFFAOYSA-N 1-docosoxydocosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCCCCCC JPPRXACMNPYJNK-UHFFFAOYSA-N 0.000 description 1
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
- XOAIXMQPJQVGRV-UHFFFAOYSA-N 1-hexadecanoylpyrrolidine-2-carboxylic acid Chemical compound CCCCCCCCCCCCCCCC(=O)N1CCCC1C(O)=O XOAIXMQPJQVGRV-UHFFFAOYSA-N 0.000 description 1
- ANZDLPHEZHHGBH-UHFFFAOYSA-N 1-hexoxydecane Chemical compound CCCCCCCCCCOCCCCCC ANZDLPHEZHHGBH-UHFFFAOYSA-N 0.000 description 1
- HBXWUCXDUUJDRB-UHFFFAOYSA-N 1-octadecoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC HBXWUCXDUUJDRB-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
Description
本発明は、酵母抽出物、糖系非イオン性界面活性剤、及びアミノ酸系アニオン性界面活性剤を含有する、生体に適用される洗浄剤組成物に関し、さらに詳しくは、洗浄及び乾燥後（洗いあがり後）の皮膚又は毛髪に対して優れた水分保持性を与えることのできる洗浄剤組成物に関するものである。 The present invention relates to a detergent composition applied to a living body, which contains a yeast extract, a sugar-based nonionic surfactant, and an amino acid-based anionic surfactant, and more specifically, after washing and drying (washing The present invention relates to a cleaning composition that can give excellent moisture retention to the skin or hair after finishing.
従来、洗浄剤組成物、例えばボディシャンプー及びヘアシャンプーに配合される界面活性剤としてアミノ酸系アニオン性界面活性剤が知られている。このアミノ酸系アニオン性界面活性剤は皮膚への刺激（皮膚一次刺激性）が少なく、皮脂を過剰に除去することのない界面活性剤として、多くの種類の洗浄剤組成物に配合されている。例えば、特許文献１には、特定のアミノ酸系アニオン性界面活性剤と、スルホン酸型又は硫酸塩型アニオン性界面活性剤とを含有する洗浄剤組成物が開示されている。そして、この特許文献１の洗浄剤組成物は、皮膚及び毛髪に対して低刺激で、洗浄力が高く、洗浄後の使用感が向上されたものとなっている。 Conventionally, amino acid-based anionic surfactants are known as surfactants incorporated in detergent compositions such as body shampoos and hair shampoos. This amino acid-based anionic surfactant has little irritation to the skin (primary skin irritation) and is blended in many types of detergent compositions as a surfactant that does not remove excessive sebum. For example, Patent Document 1 discloses a detergent composition containing a specific amino acid anionic surfactant and a sulfonic acid type or sulfate type anionic surfactant. And the cleaning composition of this patent document 1 has low irritation | stimulation with respect to skin and hair, has high cleaning power, and has improved the usability after washing | cleaning.
ところが、特許文献１に記載されるような、アミノ酸系アニオン性界面活性剤を主成分として含有する洗浄剤組成物は、洗浄及び乾燥後の皮膚や毛髪に与える水分保持性（継続的な潤い感）については満足できるものではなかった。洗浄剤組成物を、例えばヘアシャンプーとして構成し、特に累積的にダメージを受けた毛髪、例えば染毛又は脱色処理を複数回繰り返し施された毛髪、熱・紫外線を繰り返し受けた毛髪、及びコーミング又はブラシングを繰り返し受けた毛髪に適用した場合、洗浄及び乾燥後の毛髪に対して十分な水分保持性を与えることができなかった。 However, as described in Patent Document 1, a detergent composition containing an amino acid-based anionic surfactant as a main component has a water retention property (continuous moist feeling) given to skin and hair after washing and drying. ) Was not satisfactory. The cleaning composition is constituted, for example, as a hair shampoo, and in particular, hair that has been cumulatively damaged, such as hair that has been repeatedly subjected to hair dyeing or decoloring treatment, hair that has been repeatedly subjected to heat and ultraviolet rays, and combing or When applied to hair that has undergone repeated brushing, sufficient moisture retention could not be imparted to the hair after washing and drying.
本発明は、本発明者らの鋭意研究の結果、洗浄剤組成物中に（Ａ）酵母抽出物、（Ｂ）糖系非イオン性界面活性剤、及び（Ｃ）アミノ酸系アニオン性界面活性剤を含有させることにより、上記問題が解決されることを見出したことによりなされたものである。この発明の目的は、アミノ酸系アニオン性界面活性剤を含有する洗浄剤組成物において、洗浄及び乾燥後の皮膚又は毛髪に対して優れた水分保持性を与えることのできる洗浄剤組成物を提供することにある。 As a result of intensive studies by the present inventors, the present invention has (A) a yeast extract, (B) a sugar-based nonionic surfactant, and (C) an amino acid-based anionic surfactant in the detergent composition. It has been made by finding that the above-mentioned problems can be solved by containing. An object of the present invention is to provide a cleaning composition containing an amino acid-based anionic surfactant, which can give excellent moisture retention to the skin or hair after cleaning and drying. There is.
上記目的を達成するために、請求項１の洗浄剤組成物は、（Ａ）酵母抽出物、（Ｂ）糖系非イオン性界面活性剤、及び（Ｃ）アミノ酸系アニオン性界面活性剤を含有することを特徴とする。 In order to achieve the above object, the detergent composition of claim 1 comprises (A) a yeast extract, (B) a sugar-based nonionic surfactant, and (C) an amino acid-based anionic surfactant. It is characterized by doing.
請求項２の洗浄剤組成物は、請求項１に記載の発明において、前記（Ａ）酵母抽出物は、ワイン酵母、ビール酵母、パン酵母、及び清酒酵母から選ばれる少なくとも一種の酵母由来の酵母抽出物であることを特徴とする。 The detergent composition according to claim 2 is the invention according to claim 1, wherein the yeast extract (A) is a yeast derived from at least one yeast selected from wine yeast, beer yeast, baker's yeast, and sake yeast. It is an extract.
請求項３の洗浄剤組成物は、請求項１又は請求項２に記載の発明において、毛髪用の処理剤として用いられることを特徴とする。 The cleaning composition according to claim 3 is used as a hair treatment agent in the invention according to claim 1 or claim 2.
本発明の洗浄剤組成物によれば、洗浄及び乾燥後の皮膚又は毛髪に対して優れた水分保持性を与えることができる。 According to the cleaning composition of the present invention, excellent moisture retention can be imparted to the skin or hair after washing and drying.
以下、本発明の洗浄剤組成物を具体化した実施形態について説明する。本実施形態に係る洗浄剤組成物は、（Ａ）酵母抽出物、（Ｂ）糖系非イオン性界面活性剤、及び（Ｃ）アミノ酸系アニオン性界面活性剤を含有する。 Hereinafter, embodiments embodying the cleaning composition of the present invention will be described. The cleaning composition according to this embodiment contains (A) a yeast extract, (B) a sugar-based nonionic surfactant, and (C) an amino acid-based anionic surfactant.
（Ａ）酵母抽出物は、（Ｂ）糖系非イオン性界面活性剤及び（Ｃ）アミノ酸系アニオン性界面活性剤との併用により、洗浄及び乾燥後の皮膚又は毛髪に対して優れた水分保持性を与える。（Ａ）酵母抽出物に用いられる原料酵母は、特に限定されず、飲食品及び化粧品に用いられる公知の酵母が用いられる。例えば、酵母の実用上の分類として、ワイン酵母（ぶどう酒酵母）、ビール酵母、パン酵母、清酒酵母、シェリー酒酵母、ウイスキー酵母、焼酎酵母、及び泡盛酵母が挙げられる。ワイン酵母としては、例えば赤ワイン酵母及び白ワイン酵母が挙げられる。これらの酵母のなかで、洗浄及び乾燥後の皮膚又は毛髪に対する水分保持性の向上効果が優れることから、ワイン酵母、ビール酵母、パン酵母、及び清酒酵母が好ましい。なお、これらの酵母は、例えばサッカロマイセス属、サッカロミコデス属、シゾサッカロマイセス属、クリプトコッカス属、トルロプシス属、及びガンジダ属の酵母から構成される。これらのうちのいずれの酵母を用いてもよいが、洗浄及び乾燥後の皮膚又は毛髪に対する水分保持性の向上効果が優れることからサッカロマイセス属の酵母が好ましい。 (A) Yeast extract has excellent moisture retention for skin or hair after washing and drying by using in combination with (B) sugar-based nonionic surfactant and (C) amino acid-based anionic surfactant Give sex. (A) The raw material yeast used for a yeast extract is not specifically limited, The well-known yeast used for food-drinks and cosmetics is used. For example, practical classifications of yeast include wine yeast (wine yeast), beer yeast, baker's yeast, sake yeast, sherry wine yeast, whiskey yeast, shochu yeast, and Awamori yeast. Examples of wine yeast include red wine yeast and white wine yeast. Among these yeasts, wine yeast, brewer's yeast, baker's yeast, and sake yeast are preferred because they have an excellent effect of improving moisture retention with respect to skin or hair after washing and drying. In addition, these yeasts are comprised from yeast of Saccharomyces genus, Saccharomycodes genus, Schizosaccharomyces genus, Cryptococcus genus, Tolrupsis genus, and Gandida genus, for example. Any of these yeasts may be used, but yeast of the genus Saccharomyces is preferred because of its excellent effect of improving water retention on the skin or hair after washing and drying.
（Ａ）酵母抽出物は、原料酵母から公知の抽出方法によって抽出された抽出物（エキス）である。上記原料酵母としては、例えば、それら原料酵母を乾燥させたもの、乾燥後にすり潰し、粉体状にしたもの、紫外線照射により分解処理したもの、自己消化したもの、並びにタンパク分解処理、例えば酸、アルカリ、及びプロテアーゼにより処理したものを使用することができる。そして、（Ａ）酵母抽出物は、抽出溶媒を用いて上記原料酵母から抽出液を抽出するとともに、その抽出液を濾過後、濃縮及び乾燥させることにより得ることができる。上記抽出溶媒としては、例えば水、メタノール、エタノール、プロピレングリコール、１，３−ブチレングリコール、及びグリセリンが挙げられる。 (A) Yeast extract is an extract (extract) extracted from raw material yeast by a known extraction method. Examples of the raw material yeast include those obtained by drying the raw material yeast, crushed and powdered after drying, those subjected to decomposition treatment by ultraviolet irradiation, those digested by self-digestion, and proteolytic treatments such as acid and alkali. And those treated with protease can be used. The (A) yeast extract can be obtained by extracting an extract from the raw yeast using an extraction solvent and concentrating and drying the extract after filtration. Examples of the extraction solvent include water, methanol, ethanol, propylene glycol, 1,3-butylene glycol, and glycerin.
洗浄剤組成物中における（Ａ）酵母抽出物の含有量（乾物量）は、好ましくは０．０００００１〜１質量％であり、より好ましくは０．０００００５〜０．５質量％であり、さらに好ましくは０．００００１〜０．１質量％である。この含有量が０．０００００１質量％未満であると、洗浄及び乾燥後の皮膚又は毛髪に対して十分な水分保持性を与えることができない場合がある。一方、この含有量が１質量％を超えても、それ以上の効果は得られず不経済である。また、酵母抽出物由来の不快臭が感じられるおそれがある。 The content (dry matter amount) of (A) yeast extract in the cleaning composition is preferably 0.000001 to 1% by mass, more preferably 0.000005 to 0.5% by mass, and still more preferably. Is 0.00001-0.1 mass%. If this content is less than 0.000001% by mass, sufficient moisture retention may not be imparted to the skin or hair after washing and drying. On the other hand, even if the content exceeds 1% by mass, no further effect is obtained, which is uneconomical. In addition, an unpleasant odor derived from the yeast extract may be felt.
（Ｂ）糖系非イオン性界面活性剤は、（Ａ）酵母抽出物及び（Ｃ）アミノ酸系アニオン性界面活性剤との併用により、洗浄及び乾燥後の皮膚又は毛髪に対して優れた水分保持性を与える。（Ｂ）糖系非イオン性界面活性剤は、糖部を親水基として備える非イオン性界面活性剤であり、例えば糖エステル型界面活性剤及びアルキルグルコシドが挙げられる。糖エステル型界面活性剤としては、例えばスクロース脂肪酸エステル及びソルビタン脂肪酸エステルが挙げられる。 (B) The sugar-based nonionic surfactant has excellent moisture retention for the skin or hair after washing and drying by the combined use of (A) yeast extract and (C) amino acid-based anionic surfactant. Give sex. (B) A sugar-based nonionic surfactant is a nonionic surfactant having a saccharide moiety as a hydrophilic group, and examples thereof include sugar ester type surfactants and alkyl glucosides. Examples of the sugar ester type surfactant include sucrose fatty acid ester and sorbitan fatty acid ester.
スクロース脂肪酸エステルとしては、スクロースモノ脂肪酸エステル及びスクロースポリ脂肪酸エステルが挙げられる。スクロースモノ脂肪酸エステルとしては、例えばステアリン酸スクロース、パルミチン酸スクロース、ミリスチン酸スクロース、オレイン酸スクロース、ラウリン酸スクロース、及びヤシ油脂肪酸スクロースが挙げられる。スクロースポリ脂肪酸エステルとしては、例えばポリラウリン酸スクロースが挙げられる。 Examples of sucrose fatty acid esters include sucrose monofatty acid esters and sucrose polyfatty acid esters. Examples of the sucrose mono fatty acid ester include sucrose stearate, sucrose palmitate, sucrose myristate, sucrose oleate, sucrose laurate, and coconut oil fatty acid sucrose. Examples of the sucrose polyfatty acid ester include sucrose polylaurate.
ソルビタン脂肪酸エステルとしては、例えばモノオレイン酸ソルビタン、セスキオレイン酸ソルビタン、トリオレイン酸ソルビタン、モノステアリン酸ソルビタン、モノパルミチン酸ソルビタン、モノラウリン酸ソルビタン、モノオレイン酸ポリオキシエチレン（以下、「ＰＯＥ」と記載する。）ソルビタン、モノステアリン酸ＰＯＥソルビタン（ポリソルベート−６０等）、モノパルミチン酸ＰＯＥソルビタン、モノラウリン酸ＰＯＥソルビタン、トリオレイン酸ＰＯＥソルビタン、テトラオレイン酸ＰＯＥソルビット、ヘキサステアリン酸ＰＯＥソルビット、モノラウリン酸ＰＯＥソルビット、及びＰＯＥソルビットミツロウが挙げられる。 Examples of sorbitan fatty acid esters include sorbitan monooleate, sorbitan sesquioleate, sorbitan trioleate, sorbitan monostearate, sorbitan monopalmitate, sorbitan monolaurate, polyoxyethylene monooleate (hereinafter referred to as “POE”). Sorbitan, POE sorbitan monostearate (polysorbate-60, etc.), POE sorbitan monopalmitate, POE sorbitan monolaurate, POE sorbitan trioleate, POE sorbitol tetraoleate, POE sorbitol hexastearate, POE sorbitol monolaurate And POE sorbite beeswax.
アルキルグルコシドとしては、例えばオクチルグルコシド、ノニルグルコシド、デシルグルコシド、オクチルマルトシド、オクチルチオグルコシド、ラウリルグルコシド及びヤシ油アルキルグルコシドが挙げられる。これら糖系非イオン性界面活性剤のうち、一種のみが単独で含有されてもよいし、二種以上が組み合わされて含有されてもよい。 Examples of the alkyl glucoside include octyl glucoside, nonyl glucoside, decyl glucoside, octyl maltoside, octyl thioglucoside, lauryl glucoside and coconut oil alkyl glucoside. Among these sugar-based nonionic surfactants, only one kind may be contained alone, or two or more kinds may be contained in combination.
洗浄剤組成物中における（Ｂ）糖系非イオン性界面活性剤の含有量は、好ましくは０．０１〜２０質量％であり、より好ましくは０．０５〜１５質量％であり、さらに好ましくは０．１〜１０質量％である。この含有量が０．０１質量％未満であると、洗浄及び乾燥後の皮膚又は毛髪に対して十分な水分保持性を与えることができない場合がある。一方、この含有量が２０質量％を超えると、洗浄及び乾燥後の毛髪がべたつくおそれがある。 The content of the (B) sugar-based nonionic surfactant in the cleaning composition is preferably 0.01 to 20% by mass, more preferably 0.05 to 15% by mass, and still more preferably. It is 0.1-10 mass%. If this content is less than 0.01% by mass, sufficient moisture retention may not be imparted to the skin or hair after washing and drying. On the other hand, if the content exceeds 20% by mass, the hair after washing and drying may become sticky.
（Ｃ）アミノ酸系アニオン性界面活性剤は、（Ａ）酵母抽出物及び（Ｂ）糖系非イオン性界面活性剤との併用により、洗浄及び乾燥後の皮膚や毛髪に対して優れた水分保持性を与える。（Ｃ）アミノ酸系アニオン性界面活性剤としては、例えばＮ−アシルアミノ酸型界面活性剤が挙げられる。Ｎ−アシルアミノ酸型界面活性剤は、飽和または不飽和のアシル基を有するアミノ酸の塩、及び同アミノ酸の類縁体の塩である。当該アミノ酸としては、例えばグルタミン酸、グリシン、アスパラギン酸、アラニン、フェニルアラニン、ロイシン、イソロイシン、メチオニン、プロリン、トリプトファン、バリン、セリン、Ｎ−メチルグリシン（サルコシン）、及びＮ−メチルアラニンが挙げられる。当該アミノ酸の類縁体としては、例えば２−アミノエタンスルホン酸（タウリン）、及びＮ−メチルタウリンが挙げられる。また、当該酸性アミノ酸及びその類縁体は、Ｄ体、Ｌ体、及びＤＬ体のいずれであってもよい。 (C) Amino acid-based anionic surfactant has excellent moisture retention for skin and hair after washing and drying by using in combination with (A) yeast extract and (B) sugar-based nonionic surfactant Give sex. Examples of (C) amino acid anionic surfactants include N-acyl amino acid type surfactants. The N-acyl amino acid type surfactant is a salt of an amino acid having a saturated or unsaturated acyl group and a salt of an analog of the same amino acid. Examples of the amino acid include glutamic acid, glycine, aspartic acid, alanine, phenylalanine, leucine, isoleucine, methionine, proline, tryptophan, valine, serine, N-methylglycine (sarcosine), and N-methylalanine. Examples of the analog of the amino acid include 2-aminoethanesulfonic acid (taurine) and N-methyltaurine. Further, the acidic amino acid and its analogs may be any of D-form, L-form, and DL-form.
アニオン基の対イオンとしては、例えばナトリウム、カリウム、マグネシウム、モノエタノールアミン、及びトリエタノールアミンが挙げられる。Ｎ−アシルアミノ酸型界面活性剤の具体例としては、例えばココイルグルタミン酸トリエタノールアミン、ラウロイルメチル−β−アラニンナトリウム、ラウロイルアスパラギン酸ナトリウム、ラウロイルメチルタウリンナトリウム、ステアロイルグルタミン酸ナトリウム、ミリストイルグルタミン酸ナトリウム、及びパルミトイルプロリンナトリウムが挙げられる。これらアミノ酸系アニオン性界面活性剤のうち、一種のみが単独で含有されてもよいし、二種以上が組み合わされて含有されてもよい。これらのなかで、洗浄及び乾燥後の皮膚又は毛髪に対して、長時間にわたって優れた水分保持性を与える点から、アシル基を有するアミノ酸の塩が好ましい。 Examples of the counter ion of the anionic group include sodium, potassium, magnesium, monoethanolamine, and triethanolamine. Specific examples of the N-acyl amino acid type surfactant include, for example, cocoyl glutamate triethanolamine, sodium lauroylmethyl-β-alanine, sodium lauroyl aspartate, sodium lauroylmethyl taurate, sodium stearoyl glutamate, sodium myristoyl glutamate, and palmitoyl proline. Sodium is mentioned. Among these amino acid anionic surfactants, only one kind may be contained alone, or two or more kinds may be contained in combination. Among these, an amino acid salt having an acyl group is preferable from the viewpoint of imparting excellent moisture retention to the skin or hair after washing and drying.
洗浄剤組成物中における（Ｃ）アミノ酸系アニオン性界面活性剤の含有量は、好ましくは０．０５〜３０質量％であり、より好ましくは０．１〜２５質量％であり、さらに好ましくは０．５〜２０質量％である。この含有量が０．０５質量％未満であると、洗浄及び乾燥後の皮膚又は毛髪に対して十分な水分保持性を与えることができない場合がある。一方、この含有量が３０質量％を超えると、洗浄及び乾燥後の毛髪がべたつくおそれがある。 The content of the (C) amino acid anionic surfactant in the cleaning composition is preferably 0.05 to 30% by mass, more preferably 0.1 to 25% by mass, and still more preferably 0. .5 to 20% by mass. If this content is less than 0.05% by mass, sufficient moisture retention may not be imparted to the skin or hair after washing and drying. On the other hand, if the content exceeds 30% by mass, the hair after washing and drying may become sticky.
洗浄剤組成物は必要に応じて前述した成分以外の成分、例えば可溶化剤、水溶性高分子化合物、油性成分、多価アルコール、上記以外の界面活性剤、糖、防腐剤、キレート剤、安定剤、ｐＨ調整剤、植物抽出物、生薬抽出物、ビタミン、香料、酸化防止剤、紫外線吸収剤、及び無機塩を含有してもよい。 The cleaning composition may contain components other than those described above as necessary, for example, solubilizers, water-soluble polymer compounds, oily components, polyhydric alcohols, surfactants other than those described above, sugars, preservatives, chelating agents, and stable agents. An agent, a pH adjuster, a plant extract, a herbal extract, a vitamin, a fragrance, an antioxidant, an ultraviolet absorber, and an inorganic salt may be contained.
可溶化剤としては、例えば水及び有機溶媒が挙げられる。有機溶媒としては、例えばエタノール、イソプロパノール、ベンジルアルコール、及びベンジルオキシエタノールが挙げられる。水溶性高分子化合物としては、アニオン性高分子化合物、カチオン性高分子化合物、非イオン性高分子化合物、及び両性の天然又は合成高分子化合物が挙げられる。カチオン性高分子化合物としては、例えばポリ塩化ジメチルメチレンピペリジニウム液、ヒドロキシエチルセルロースジメチルジアリルアンモニウムクロリド、ポリクオタニウム−１０、カチオン化グアーガム、及びキトサンヒドロキシプロピルトリモニウムクロリドが挙げられる。非イオン性の合成高分子化合物として、例えばヒドロキシエチルセルロースが挙げられる。両性の合成高分子化合物としては、例えばポリクオタニウム−２２、ポリクオタニウム−３９、及びポリクオタニウム−４７が挙げられる。 Examples of solubilizers include water and organic solvents. Examples of the organic solvent include ethanol, isopropanol, benzyl alcohol, and benzyloxyethanol. Examples of the water-soluble polymer compound include an anionic polymer compound, a cationic polymer compound, a nonionic polymer compound, and an amphoteric natural or synthetic polymer compound. Examples of the cationic polymer compound include polydimethylmethylene piperidinium chloride solution, hydroxyethylcellulose dimethyldiallylammonium chloride, polyquaternium-10, cationized guar gum, and chitosan hydroxypropyltrimonium chloride. Examples of nonionic synthetic polymer compounds include hydroxyethyl cellulose. Examples of the amphoteric synthetic polymer compound include polyquaternium-22, polyquaternium-39, and polyquaternium-47.
油性成分としては、例えば油脂、ロウ、高級アルコール、炭化水素、アルキルグリセリルエーテル、エステル、及びシリコーンが挙げられる。
油脂としては、例えばオリーブ油、ツバキ油、シア脂、アーモンド油、サフラワー油、ヒマワリ油、大豆油、綿実油、ゴマ油、トウモロコシ油、ナタネ油、コメヌカ油、コメ胚芽油、ブドウ種子油、アボカド油、マカダミアナッツ油、ヒマシ油、ヤシ油、及び月見草油が挙げられる。ロウとしては、例えばミツロウ、キャンデリラロウ、カルナウバロウ、ホホバ油、及びラノリンが挙げられる。
Examples of the oil component include fats and oils, waxes, higher alcohols, hydrocarbons, alkyl glyceryl ethers, esters, and silicones.
Examples of oils and fats include olive oil, camellia oil, shea fat, almond oil, safflower oil, sunflower oil, soybean oil, cottonseed oil, sesame oil, corn oil, rapeseed oil, rice bran oil, rice germ oil, grape seed oil, avocado oil, Examples include macadamia nut oil, castor oil, coconut oil, and evening primrose oil. Examples of the wax include beeswax, candelilla wax, carnauba wax, jojoba oil, and lanolin.
高級アルコールとしては、例えばセチルアルコール（セタノール）、２−ヘキシルデカノール、ステアリルアルコール、イソステアリルアルコール、セトステアリルアルコール、オレイルアルコール、アラキルアルコール、ベヘニルアルコール、２−オクチルドデカノール、ラウリルアルコール、ミリスチルアルコール、デシルテトラデカノール、及びラノリンアルコールが挙げられる。 Examples of higher alcohols include cetyl alcohol (cetanol), 2-hexyldecanol, stearyl alcohol, isostearyl alcohol, cetostearyl alcohol, oleyl alcohol, aralkyl alcohol, behenyl alcohol, 2-octyldodecanol, lauryl alcohol, myristyl alcohol, decyltetra Examples include decanol and lanolin alcohol.
炭化水素としては、例えばパラフィン、オレフィンオリゴマー、ポリイソブテン、水添ポリイソブテン、ミネラルオイル、スクワラン、ポリブテン、ポリエチレン、マイクロクリスタリンワックス、及びワセリンが挙げられる。高級脂肪酸としては、例えばラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘニン酸、イソステアリン酸、１２−ヒドロキシステアリン酸、オレイン酸、及びラノリン脂肪酸が挙げられる。アルキルグリセリルエーテルとしては、例えばバチルアルコール、キミルアルコール、セラキルアルコール、及びイソステアリルグリセリルエーテルが挙げられる。 Examples of the hydrocarbon include paraffin, olefin oligomer, polyisobutene, hydrogenated polyisobutene, mineral oil, squalane, polybutene, polyethylene, microcrystalline wax, and petrolatum. Examples of the higher fatty acid include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, isostearic acid, 12-hydroxystearic acid, oleic acid, and lanolin fatty acid. Examples of the alkyl glyceryl ether include batyl alcohol, chimyl alcohol, ceralkyl alcohol, and isostearyl glyceryl ether.
エステルとしては、例えばアジピン酸ジイソプロピル、ミリスチン酸イソプロピル、オクタン酸セチル、イソノナン酸イソノニル、ミリスチン酸オクチルドデシル、パルミチン酸イソプロピル、ステアリン酸ステアリル、ミリスチン酸ミリスチル、ミリスチン酸イソトリデシル、パルミチン酸２−エチルへキシル、リシノール酸オクチルドデシル、１０〜３０の炭素数を有する脂肪酸からなるコレステリル／ラノステリル、乳酸セチル、酢酸ラノリン、ジ−２−エチルヘキサン酸エチレングリコール、ペンタエリスリトール脂肪酸エステル、ジペンタエリスリトール脂肪酸エステル、カプリン酸セチル、トリカプリル酸グリセリル、リンゴ酸ジイソステアリル、コハク酸ジオクチル、コハク酸ジエトキシエチル、及び２−エチルヘキサン酸セチルが挙げられる。これらの油性成分の具体例のうち、一種のみが単独で含有されてもよいし、二種以上が組み合わされて含有されてもよい。 Examples of esters include diisopropyl adipate, isopropyl myristate, cetyl octanoate, isononyl isononanoate, octyldodecyl myristate, isopropyl stearate, stearyl stearate, myristyl myristate, isotridecyl myristate, 2-ethylhexyl palmitate, Octyldodecyl ricinoleate, cholesteryl / lanosteryl consisting of fatty acids having 10 to 30 carbon atoms, cetyl lactate, lanolin acetate, ethylene glycol di-2-ethylhexanoate, pentaerythritol fatty acid ester, dipentaerythritol fatty acid ester, cetyl caprate Glyceryl tricaprylate, diisostearyl malate, dioctyl succinate, diethoxyethyl succinate, and 2-ethylhexanoic acid Le, and the like. Among the specific examples of these oily components, only one kind may be contained alone, or two or more kinds may be contained in combination.
シリコーンとしては、例えばジメチルポリシロキサン（ジメチコン）、メチルフェニルポリシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロヘキサシロキサン、末端水酸基変性ジメチルポリシロキサン、６５０〜１００００の平均重合度を有する高重合シリコーン、ポリエーテル変性シリコーン（例えば、（ＰＥＧ／ＰＰＧ／ブチレン／ジメチコン）コポリマー）、アミノ変性シリコーン、ベタイン変性シリコーン、アルキル変性シリコーン、アルコキシ変性シリコーン、メルカプト変性シリコーン、カルボキシ変性シリコーン、及びフッ素変性シリコーンが挙げられる。これらのシリコーンのうち、一種のみが単独で含有されてもよいし、二種以上が組み合わされて含有されてもよい。 Examples of silicone include dimethylpolysiloxane (dimethicone), methylphenylpolysiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, terminal hydroxyl group-modified dimethylpolysiloxane, highly polymerized silicone having an average degree of polymerization of 650 to 10,000, poly Examples include ether-modified silicones (eg, (PEG / PPG / butylene / dimethicone) copolymers), amino-modified silicones, betaine-modified silicones, alkyl-modified silicones, alkoxy-modified silicones, mercapto-modified silicones, carboxy-modified silicones, and fluorine-modified silicones. Among these silicones, only one kind may be contained alone, or two or more kinds may be contained in combination.
多価アルコールとしては、例えばグリコール、及びグリセリンが挙げられる。グリコールとしては、例えばエチレングリコール、ジエチレングリコール、トリエチレングリコール、ポリエチレングリコール、プロピレングリコール、ジプロピレングリコール、イソプレングリコール、及び１，３−ブチレングリコールが挙げられる。グリセリンとしては、例えばグリセリン、ジグリセリン、及びポリグリセリンが挙げられる。 Examples of the polyhydric alcohol include glycol and glycerin. Examples of the glycol include ethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, isoprene glycol, and 1,3-butylene glycol. Examples of glycerin include glycerin, diglycerin, and polyglycerin.
界面活性剤は、洗浄成分として配合されるほか、乳化剤又は各成分の可溶化剤として各成分を乳化又は可溶化し、組成物の粘度を調整したり粘度安定性を向上させたりする。界面活性剤としては、上記以外のアニオン性界面活性剤、カチオン性界面活性剤、両性界面活性剤、及び上記以外の非イオン性界面活性剤が挙げられる。 The surfactant is blended as a cleaning component, and also emulsifies or solubilizes each component as an emulsifier or a solubilizer for each component, thereby adjusting the viscosity of the composition or improving the viscosity stability. Examples of the surfactant include anionic surfactants other than those described above, cationic surfactants, amphoteric surfactants, and nonionic surfactants other than those described above.
上記以外のアニオン性界面活性剤としては、例えばアルキルエーテル硫酸塩、アルキル硫酸塩、アルケニルエーテル硫酸塩、アルケニル硫酸塩、オレフィンスルホン酸塩、アルカンスルホン酸塩、飽和又は不飽和脂肪酸塩、アルキル又はアルケニルエーテルカルボン酸塩、α-スルホン脂肪酸塩、リン酸モノ又はジエステル型界面活性剤、及びスルホコハク酸エステルが挙げられる。これらの界面活性剤のアニオン基の対イオンとしては、例えばナトリウムイオン、カリウムイオン、及びトリエタノールアミンが挙げられる。アルキル硫酸塩としては、例えばラウリル硫酸ナトリウムが挙げられる。 Examples of other anionic surfactants include alkyl ether sulfate, alkyl sulfate, alkenyl ether sulfate, alkenyl sulfate, olefin sulfonate, alkane sulfonate, saturated or unsaturated fatty acid salt, alkyl or alkenyl. Examples include ether carboxylate, α-sulfone fatty acid salt, phosphoric acid mono- or diester surfactant, and sulfosuccinic acid ester. Examples of the counter ion of the anionic group of these surfactants include sodium ion, potassium ion, and triethanolamine. Examples of the alkyl sulfate include sodium lauryl sulfate.
カチオン性界面活性剤としては、例えば塩化ラウリルトリメチルアンモニウム、塩化セチルトリメチルアンモニウム、塩化ステアリルトリメチルアンモニウム、塩化アルキルトリメチルアンモニウム、塩化ジステアリルジメチルアンモニウム、臭化セチルトリメチルアンモニウム、臭化ステアリルトリメチルアンモニウム、エチル硫酸ラノリン脂肪酸アミノプロピルエチルジメチルアンモニウム、ステアリルトリメチルアンモニウムサッカリン、セチルトリメチルアンモニウムサッカリン、塩化メタクリロイルオキシエチルトリメチルアンモニウム、及びメチル硫酸ベヘニルトリメチルアンモニウムが挙げられる。 Examples of the cationic surfactant include lauryl trimethyl ammonium chloride, cetyl trimethyl ammonium chloride, stearyl trimethyl ammonium chloride, alkyl trimethyl ammonium chloride, distearyl dimethyl ammonium chloride, cetyl trimethyl ammonium bromide, stearyl trimethyl ammonium bromide, ethyl lanolin sulfate. Examples include fatty acid aminopropylethyldimethylammonium, stearyltrimethylammonium saccharin, cetyltrimethylammonium saccharin, methacryloyloxyethyltrimethylammonium chloride, and behenyltrimethylammonium methylsulfate.
両性界面活性剤としては、例えばココベタイン、ラウラミドプロピルベタイン、コカミドプロピルベタイン、ラウロアンホ酢酸ナトリウム、ココアンホ酢酸ナトリウム、及びラウリルベタイン（ラウリルジメチルアミノ酢酸ベタイン）が挙げられる。 Examples of amphoteric surfactants include cocobetaine, lauramidopropyl betaine, cocamidopropyl betaine, sodium lauroamphoacetate, sodium cocoamphoacetate, and laurylbetaine (lauryldimethylaminoacetic acid betaine).
上記以外の非イオン性界面活性剤としては、例えばエーテル型非イオン性界面活性剤、及びエステル型非イオン性界面活性剤が挙げられる。エーテル型非イオン性界面活性剤としては、例えばポリオキシエチレンセチルエーテル（セテス）、ＰＯＥステアリルエーテル（ステアレス）、ＰＯＥベヘニルエーテル、ＰＯＥオレイルエーテル（オレス）、ＰＯＥラウリルエーテル（ラウレス）、ＰＯＥオクチルドデシルエーテル、ＰＯＥヘキシルデシルエーテル、ＰＯＥイソステアリルエーテル、ＰＯＥノニルフェニルエーテル、ＰＯＥオクチルフェニルエーテル、及びＰＯＥセチルステアリルジエーテルが挙げられる。 Examples of nonionic surfactants other than the above include ether type nonionic surfactants and ester type nonionic surfactants. Examples of ether type nonionic surfactants include polyoxyethylene cetyl ether (ceteth), POE stearyl ether (steares), POE behenyl ether, POE oleyl ether (oleth), POE lauryl ether (laureth), and POE octyldodecyl ether. , POE hexyl decyl ether, POE isostearyl ether, POE nonyl phenyl ether, POE octyl phenyl ether, and POE cetyl stearyl diether.
エステル型非イオン性界面活性剤としては、例えばモノステアリン酸ＰＯＥグリセリン、モノミリスチン酸ＰＯＥグリセリン、モノオレイン酸ポリエチレングリコール、モノステアリン酸ポリエチレングリコール、モノラウリン酸ポリエチレングリコール、親油型モノオレイン酸グリセリン、親油型モノステアリン酸グリセリン、自己乳化型モノステアリン酸グリセリン、モノラウリン酸デカグリセリル、モノステアリン酸デカグリセリル、モノオレイン酸デカグリセリル、モノミリスチン酸デカグリセリル、及びラウリン酸ポリグリセリルが挙げられる。これらの界面活性剤の具体例のうち、一種のみが単独で含有されてもよいし、二種以上が組み合わされて含有されてもよい。 Examples of the ester type nonionic surfactant include monostearic acid POE glycerin, monomyristic acid POE glycerin, monooleic acid polyethylene glycol, monostearic acid polyethylene glycol, monolauric acid polyethylene glycol, lipophilic monooleic acid glycerin, parent Examples include oil type glyceryl monostearate, self-emulsifying type glyceryl monostearate, decaglyceryl monolaurate, decaglyceryl monostearate, decaglyceryl monooleate, decaglyceryl monomyristate, and polyglyceryl laurate. Among the specific examples of these surfactants, only one kind may be contained alone, or two or more kinds may be contained in combination.
糖としては、例えばソルビトール、マルトース、及びＮ−アセチルグルコサミンが挙げられる。防腐剤としては、例えばパラベン、メチルパラベン及び安息香酸ナトリウムが挙げられる。キレート剤としては、例えばエチレンジアミン四酢酸（ＥＤＴＡ）及びその塩類、ジエチレントリアミン五酢酸及びその塩類、並びにヒドロキシエタンジホスホン酸（エチドロン酸、ＨＥＤＰ）及びその塩類が挙げられる。 Examples of the sugar include sorbitol, maltose, and N-acetylglucosamine. Examples of preservatives include paraben, methyl paraben, and sodium benzoate. Examples of the chelating agent include ethylenediaminetetraacetic acid (EDTA) and salts thereof, diethylenetriaminepentaacetic acid and salts thereof, and hydroxyethane diphosphonic acid (ethidronic acid, HEDP) and salts thereof.
安定剤としては、例えばフェナセチン、８−ヒドロキシキノリン、アセトアニリド、ピロリン酸ナトリウム、バルビツール酸、尿酸、及びタンニン酸が挙げられる。ｐＨ調整剤としては、例えば乳酸、レブリン酸、グリコール酸、酒石酸、リンゴ酸、ピロリドンカルボン酸（ＰＣＡ）、コハク酸、クエン酸、グルタミン酸、及びアルギニンが挙げられる。酸化防止剤としては、例えばアスコルビン酸、及び亜硫酸塩が挙げられる。無機塩としては、例えば塩化ナトリウム、及び炭酸ナトリウムが挙げられる。 Examples of the stabilizer include phenacetin, 8-hydroxyquinoline, acetanilide, sodium pyrophosphate, barbituric acid, uric acid, and tannic acid. Examples of the pH adjuster include lactic acid, levulinic acid, glycolic acid, tartaric acid, malic acid, pyrrolidone carboxylic acid (PCA), succinic acid, citric acid, glutamic acid, and arginine. Examples of the antioxidant include ascorbic acid and sulfite. Examples of the inorganic salt include sodium chloride and sodium carbonate.
洗浄剤組成物の剤型は特に限定されず、具体例として、例えば固体状、液状、ゲル状、フォーム状、及びクリーム状が挙げられる。剤型が固体状である場合、添加剤として、さらに分散剤、例えばステアリン酸金属塩、タルク、結晶セルロース、低置換度ヒドロキシプロピルセルロース、デキストリン、及びデンプンを配合してもよい。 The dosage form of the cleaning composition is not particularly limited, and specific examples include solid, liquid, gel, foam, and cream. When the dosage form is solid, a dispersant such as metal stearate, talc, crystalline cellulose, low-substituted hydroxypropylcellulose, dextrin, and starch may be further added as an additive.
洗浄剤組成物の用途は、生体に適用されるものであれば特に限定されず、例えば毛髪用の処理剤、身体用の洗浄剤（ボディシャンプー）、洗顔剤、及びハンドソープとして用いることができる。毛髪用の処理剤としては、例えば洗髪剤（ヘアシャンプー）、ヘアトリートメント、ヘアコンディショナー、並びにパーマネントウエーブ処理後、毛髪脱色・脱染処理後、及び染毛処理後の後に適用される各種後処理剤が挙げられる。 The use of the cleaning composition is not particularly limited as long as it is applied to a living body. For example, it can be used as a treatment for hair, a cleaning agent for body (body shampoo), a facial cleanser, and a hand soap. . Examples of hair treatment agents include hair wash agents (hair shampoos), hair treatments, hair conditioners, and various post-treatment agents applied after permanent wave treatment, after hair decoloration / decoloration treatment, and after hair dyeing treatment. Is mentioned.
特に、本発明の洗浄剤組成物は、ハイダメージ毛（ダメージの累積された毛髪、例えば染毛又は脱色処理を複数回繰り返し施された毛髪、熱・紫外線を繰り返し受けた毛髪、及びコーミング又はブラシングを繰り返し受けた毛髪）に対して適用した場合に優れた水分保持性の向上効果を発揮する。そのため、例えばパーマネントウエーブ処理、毛髪脱色・脱染処理、及び毛髪染色処理された毛髪用の後処理剤として好適に用いることができる。また、これら毛髪用の処理剤は、毛髪に適用した後に水や温水で洗い流すようにして使用してもよいし、水や温水で洗い流すことなく乾燥させるように使用してもよい。 In particular, the cleaning composition of the present invention is used for high-damaged hair (hair with accumulated damage, such as hair that has been repeatedly subjected to hair dyeing or decoloring treatment, hair that has been repeatedly subjected to heat and ultraviolet rays, and combing or brushing. When it is applied to hair that has been repeatedly subjected to, an excellent effect of improving moisture retention is exhibited. Therefore, for example, it can be suitably used as a post-treatment agent for hair that has been subjected to permanent wave treatment, hair decoloration / dyeing treatment, and hair dyeing treatment. Further, these hair treatment agents may be used after being applied to the hair and rinsed with water or warm water, or may be used without being washed away with water or warm water.
次に、本実施形態の洗浄剤組成物における作用効果について、以下に記載する。
（１）本実施形態の洗浄剤組成物は、（Ａ）酵母抽出物、（Ｂ）糖系非イオン性界面活性剤、及び（Ｃ）アミノ酸系アニオン性界面活性剤を含有する。したがって、洗浄及び乾燥後の皮膚又は毛髪に対して、優れた水分保持性を与えることができる。特に、洗浄及び乾燥後の皮膚又は毛髪における経時的な水分保持性の低下を抑制することができる。また、本実施形態の洗浄剤組成物は泡立ちに優れる。
Next, the effect in the cleaning composition of this embodiment is described below.
(1) The cleaning composition of this embodiment contains (A) a yeast extract, (B) a sugar-based nonionic surfactant, and (C) an amino acid-based anionic surfactant. Therefore, excellent moisture retention can be imparted to the skin or hair after washing and drying. In particular, it is possible to suppress a decrease in water retention over time in the skin or hair after washing and drying. Moreover, the cleaning composition of this embodiment is excellent in foaming.
（２）本実施形態の洗浄剤組成物は乾燥肌用の洗浄剤、及びハイダメージ毛用の洗浄剤として好適に使用することができる。
（３）好ましくは、（Ａ）酵母抽出物は、ワイン酵母、ビール酵母、パン酵母、及び清酒酵母から選ばれる少なくとも一種の酵母由来の酵母抽出物である。この場合、洗浄及び乾燥後の皮膚又は毛髪に対して優れた水分保持性を与える効果をより確実に得ることができる。
(2) The cleaning composition of this embodiment can be suitably used as a cleaning agent for dry skin and a cleaning agent for high-damaged hair.
(3) Preferably, (A) yeast extract is a yeast extract derived from at least one yeast selected from wine yeast, brewer's yeast, baker's yeast, and sake yeast. In this case, the effect which gives the outstanding water | moisture retention with respect to the skin or hair after washing | cleaning and drying can be acquired more reliably.
（４）好ましくは、（Ｃ）アミノ酸系アニオン性界面活性剤は、アシル基を有するアミノ酸の塩である。この場合、洗浄及び乾燥後の皮膚又は毛髪に対して、長時間にわたって優れた水分保持性を与える効果をより高めることができる。 (4) Preferably, the (C) amino acid anionic surfactant is an amino acid salt having an acyl group. In this case, it is possible to further enhance the effect of giving excellent moisture retention over a long period of time to the washed or dried skin or hair.
次に、実施例及び比較例を挙げて上記実施形態を更に具体的に説明する。
表１に示す各成分を含有する洗髪剤としてのシャンプーを調製した。表１における各成分を示す欄中の数値は当該欄の成分の含有量を示し、その単位は質量％である。なお、酵母エキスは乾燥質量（質量％）を示す。これら各例のシャンプーについて、下記に示す方法に従い「泡立ちの良さの評価」、及び「洗浄及び乾燥後の皮膚又は毛髪に対する水分保持性の評価」を行なった。
Next, the embodiment will be described more specifically with reference to examples and comparative examples.
A shampoo as a hair wash containing each component shown in Table 1 was prepared. The numerical value in the column indicating each component in Table 1 indicates the content of the component in the column, and the unit is mass%. In addition, a yeast extract shows dry mass (mass%). The shampoos of these examples were subjected to “evaluation of good foaming” and “evaluation of water retention on the skin or hair after washing and drying” according to the following methods.
本試験では、ハイダメージ毛であって、かつ乾燥肌であると感じるパネラー２０名を対象として試験を行なった。なお、パネラー２０名の各毛髪のダメージの状態は、酸化染毛剤処理（染毛処理）をほぼ同間隔で定期的に実施していることをもって同程度としている。まず、実施例及び比較例のシャンプーを用いて常法に従い、毛髪の洗浄を行った。その際、シャンプーの泡立ちの良さについて、下記に示す方法に基づいて評価を行なった。洗浄後の濡れた状態の毛髪にテスト用コンディショナー（成分 セタノール：３質量％、セトリモニウムクロリド：２．５質量％、モノステアリン酸グリセリル：０．２質量％、グリセリン：１質量％、メチルパラベン：０．２質量％、香料：０．２質量％、精製水：残量）を塗布し、洗い流し処理及び毛髪の乾燥処理を行なった。そして、乾燥処理がなされた洗いあがりの直後（洗浄及び乾燥の直後）、及びその洗いあがりから常温（２５℃）及び常湿（６５±２０％）の条件下で６時間経過後に、それぞれ頭皮及び毛髪の水分保持性について下記に示す方法に基づいて評価を行なった。 In this test, the test was conducted on 20 panelists who felt high-damaged hair and dry skin. In addition, the state of the damage of each hair of 20 panelists is made into the same level by having regularly performed the oxidation hair dye process (hair dyeing process) at the substantially same space | interval. First, hair was washed according to a conventional method using the shampoos of Examples and Comparative Examples. At that time, the shampoo foaming was evaluated based on the following method. Conditioner for test on wet hair after washing (component cetanol: 3% by mass, cetrimonium chloride: 2.5% by mass, glyceryl monostearate: 0.2% by mass, glycerin: 1% by mass, methyl paraben: 0 2% by mass, fragrance: 0.2% by mass, purified water: remaining amount) were applied, followed by washing off treatment and hair drying treatment. Then, immediately after the drying treatment (immediately after washing and drying), and after 6 hours at room temperature (25 ° C.) and normal humidity (65 ± 20%) after washing, the scalp and The moisture retention of hair was evaluated based on the method shown below.
なお、表中の「成分」欄における（Ａ）、（Ｂ）、（Ｃ）の表記は本願請求項記載の各成分に対応する化合物を示し、ａ、ｂ、ｃの表記は、比較例においてＡ成分、Ｂ成分、Ｃ成分の代替成分として用いた化合物を示す。 In addition, the notation of (A), (B), (C) in the “component” column in the table indicates a compound corresponding to each component described in the claims of the present application, and the notation of a, b, c is in the comparative example. The compound used as an alternative component of A component, B component, and C component is shown.
＜泡立ちの良さの評価＞
２０名のパネラーのうち、泡立ちが良い（起泡性に優れる）と評価したパネラーの数が、１７人以上の場合を「非常に優れる：５」とし、１３〜１６人の場合を「優れる：４」とし、９〜１２人の場合を「良好：３」とし、５〜８人の場合を「やや不良：２」とし、４人以下の場合を「不良：１」として評価した。結果を表１に示す。
<Evaluation of good foaming>
Among the 20 panelists, the number of panelists evaluated as having good foaming (excellent foaming property) was 17 or more, “Excellent: 5”, and 13-16, “Excellent: 4 ”, the case of 9 to 12 persons was evaluated as“ good: 3 ”, the case of 5 to 8 persons was evaluated as“ slightly defective: 2 ”, and the case of 4 persons or less was evaluated as“ defective: 1 ”. The results are shown in Table 1.
＜洗いあがり後の皮膚及び毛髪に対する水分保持性の評価＞
２０名のパネラーのうち、頭皮（毛髪）の潤い感が良いと評価したパネラーの数が、１７人以上の場合を「非常に優れる：５」とし、１３〜１６人の場合を「優れる：４」とし、９〜１２人の場合を「良好：３」とし、５〜８人の場合を「やや不良：２」とし、４人以下の場合を「不良：１」として評価した。結果を表１に示す。
<Evaluation of moisture retention on skin and hair after washing>
Among the 20 panelists, the number of panelists evaluated as having good moisturizing scalp (hair) was 17 or more, “Excellent: 5”, and 13-16, “Excellent: 4” The case of 9 to 12 people was evaluated as “good: 3”, the case of 5 to 8 people was evaluated as “slightly bad: 2”, and the case of 4 people or less was evaluated as “defective: 1”. The results are shown in Table 1.
一方、（Ａ）酵母抽出物を含有しない比較例１、（Ｂ）糖系非イオン性界面活性剤を含有しない比較例３、及び（Ｃ）アミノ酸系アニオン性界面活性剤を含有しない比較例５は、各実施例と比較して、特に洗いあがりから６時間後の水分保持性の評価が低いことが分かった。また、（Ａ）酵母抽出物に代えて、保湿・湿潤剤として使用されるピロリドンカルボン酸ナトリウム（ＰＣＡ−ナトリウム）を含有する比較例２は、洗いあがり直後の水分保持性の評価については高い評価であるものの、洗いあがりから６時間後の水分保持性の評価については低い評価であることが分かった。（Ｂ）糖系非イオン性界面活性剤に代えて、他の非イオン性界面活性剤であるＰＥＧ６０水添ヒマシ油を含有する比較例４、及び（Ｃ）アミノ酸系アニオン性界面活性剤に代えて、他のアニオン性界面活性剤であるラウレス硫酸ナトリウムを含有する比較例６は、各実施例と比較して、水分保持性の評価が低いことが分かった。 On the other hand, (A) Comparative Example 1 containing no yeast extract, (B) Comparative Example 3 containing no sugar-based nonionic surfactant, and (C) Comparative Example 5 containing no amino acid-based anionic surfactant Compared with each Example, it turned out that the evaluation of the water | moisture retention especially 6 hours after washing-up is low. In addition, Comparative Example 2 containing sodium pyrrolidonecarboxylate (PCA-sodium) used as a moisturizing / wetting agent instead of (A) yeast extract is highly evaluated for evaluation of water retention immediately after washing. However, it was found that the evaluation of the moisture retention after 6 hours from the washing was low. (B) In place of the sugar-based nonionic surfactant, Comparative Example 4 containing PEG60 hydrogenated castor oil, which is another nonionic surfactant, and (C) in place of the amino acid-based anionic surfactant Thus, it was found that Comparative Example 6 containing sodium laureth sulfate, which is another anionic surfactant, had a lower evaluation of water retention than each Example.
次に、上記実施形態から把握できる技術的思想について記載する。
（イ）前記（Ｃ）アミノ酸系アニオン性界面活性剤は、アシル基を有するアミノ酸の塩であることを特徴とする前記洗浄剤組成物。
Next, a technical idea that can be grasped from the above embodiment will be described.
(A) The detergent composition, wherein the amino acid anionic surfactant (C) is a salt of an amino acid having an acyl group.
（ロ）乾燥肌用の洗浄剤として用いられることを特徴とする前記洗浄剤組成物。
（ハ）ハイダメージ毛用の毛髪用の処理剤として用いられることを特徴とする前記洗浄剤組成物。
(B) The cleaning composition, which is used as a cleaning agent for dry skin.
(C) The cleaning composition as described above, which is used as a hair treatment agent for high-damaged hair.
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