JP7246362B2 - Cleansing composition for hair or skin - Google Patents
Cleansing composition for hair or skin Download PDFInfo
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- JP7246362B2 JP7246362B2 JP2020503471A JP2020503471A JP7246362B2 JP 7246362 B2 JP7246362 B2 JP 7246362B2 JP 2020503471 A JP2020503471 A JP 2020503471A JP 2020503471 A JP2020503471 A JP 2020503471A JP 7246362 B2 JP7246362 B2 JP 7246362B2
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- Japan
- Prior art keywords
- component
- ether acetate
- fatty acid
- weight
- composition according
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims description 89
- 239000000194 fatty acid Substances 0.000 claims description 55
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 54
- 229930195729 fatty acid Natural products 0.000 claims description 54
- 150000004665 fatty acids Chemical class 0.000 claims description 49
- -1 polyoxyethylene Polymers 0.000 claims description 42
- 239000003599 detergent Substances 0.000 claims description 41
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 38
- 238000004140 cleaning Methods 0.000 claims description 27
- 239000002736 nonionic surfactant Substances 0.000 claims description 26
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 claims description 23
- 125000004432 carbon atom Chemical group C* 0.000 claims description 19
- FPZWZCWUIYYYBU-UHFFFAOYSA-N 2-(2-ethoxyethoxy)ethyl acetate Chemical compound CCOCCOCCOC(C)=O FPZWZCWUIYYYBU-UHFFFAOYSA-N 0.000 claims description 12
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 8
- BJINVQNEBGOMCR-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethyl acetate Chemical compound COCCOCCOC(C)=O BJINVQNEBGOMCR-UHFFFAOYSA-N 0.000 claims description 6
- VXQBJTKSVGFQOL-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethyl acetate Chemical compound CCCCOCCOCCOC(C)=O VXQBJTKSVGFQOL-UHFFFAOYSA-N 0.000 claims description 4
- SGQLKNKVOZVAAY-UHFFFAOYSA-N 2-[2-(2-butoxyethoxy)ethoxy]ethyl acetate Chemical compound CCCCOCCOCCOCCOC(C)=O SGQLKNKVOZVAAY-UHFFFAOYSA-N 0.000 claims description 4
- NVSCAPMJFRYMFK-UHFFFAOYSA-N 2-[2-(2-ethoxyethoxy)ethoxy]ethyl acetate Chemical compound CCOCCOCCOCCOC(C)=O NVSCAPMJFRYMFK-UHFFFAOYSA-N 0.000 claims description 4
- SDHQGBWMLCBNSM-UHFFFAOYSA-N 2-[2-(2-methoxyethoxy)ethoxy]ethyl acetate Chemical compound COCCOCCOCCOC(C)=O SDHQGBWMLCBNSM-UHFFFAOYSA-N 0.000 claims description 4
- 230000001815 facial effect Effects 0.000 claims description 2
- 230000000694 effects Effects 0.000 description 13
- 229920001296 polysiloxane Polymers 0.000 description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
- 125000002252 acyl group Chemical group 0.000 description 9
- 238000005187 foaming Methods 0.000 description 9
- 239000003240 coconut oil Substances 0.000 description 8
- 235000019864 coconut oil Nutrition 0.000 description 8
- 239000002453 shampoo Substances 0.000 description 8
- 239000004094 surface-active agent Substances 0.000 description 8
- 235000011187 glycerol Nutrition 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 239000004166 Lanolin Substances 0.000 description 6
- 206010040880 Skin irritation Diseases 0.000 description 6
- 235000019388 lanolin Nutrition 0.000 description 6
- 229940039717 lanolin Drugs 0.000 description 6
- 230000036556 skin irritation Effects 0.000 description 6
- 231100000475 skin irritation Toxicity 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 229920001214 Polysorbate 60 Polymers 0.000 description 5
- 229920002125 Sokalan® Polymers 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 229920001223 polyethylene glycol Polymers 0.000 description 5
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 4
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 4
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 4
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 4
- 239000002202 Polyethylene glycol Substances 0.000 description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 4
- 239000004205 dimethyl polysiloxane Substances 0.000 description 4
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 4
- 229940070765 laurate Drugs 0.000 description 4
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000006071 cream Substances 0.000 description 3
- 239000000499 gel Substances 0.000 description 3
- 150000002334 glycols Chemical class 0.000 description 3
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 3
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 3
- 125000006353 oxyethylene group Chemical group 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 229920003169 water-soluble polymer Polymers 0.000 description 3
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 2
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 2
- 229940058015 1,3-butylene glycol Drugs 0.000 description 2
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 2
- HBXWUCXDUUJDRB-UHFFFAOYSA-N 1-octadecoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC HBXWUCXDUUJDRB-UHFFFAOYSA-N 0.000 description 2
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 2
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- FZERHIULMFGESH-UHFFFAOYSA-N N-phenylacetamide Chemical compound CC(=O)NC1=CC=CC=C1 FZERHIULMFGESH-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- IYFATESGLOUGBX-YVNJGZBMSA-N Sorbitan monopalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O IYFATESGLOUGBX-YVNJGZBMSA-N 0.000 description 2
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 2
- 239000004147 Sorbitan trioleate Substances 0.000 description 2
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 150000008051 alkyl sulfates Chemical class 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 235000006708 antioxidants Nutrition 0.000 description 2
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical compound CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 235000019437 butane-1,3-diol Nutrition 0.000 description 2
- 229960001631 carbomer Drugs 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 229960000541 cetyl alcohol Drugs 0.000 description 2
- 239000002738 chelating agent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 229940008099 dimethicone Drugs 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000002552 dosage form Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 150000002314 glycerols Chemical class 0.000 description 2
- 229940075507 glyceryl monostearate Drugs 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 2
- 125000001419 myristoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
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- 235000014593 oils and fats Nutrition 0.000 description 2
- 125000001312 palmitoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- CPJSUEIXXCENMM-UHFFFAOYSA-N phenacetin Chemical compound CCOC1=CC=C(NC(C)=O)C=C1 CPJSUEIXXCENMM-UHFFFAOYSA-N 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 description 2
- 229940081974 saccharin Drugs 0.000 description 2
- 235000019204 saccharin Nutrition 0.000 description 2
- 239000000901 saccharin and its Na,K and Ca salt Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
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- 239000001593 sorbitan monooleate Substances 0.000 description 2
- 229940035049 sorbitan monooleate Drugs 0.000 description 2
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- 239000001570 sorbitan monopalmitate Substances 0.000 description 2
- 229940031953 sorbitan monopalmitate Drugs 0.000 description 2
- 235000011076 sorbitan monostearate Nutrition 0.000 description 2
- 239000001587 sorbitan monostearate Substances 0.000 description 2
- 229940035048 sorbitan monostearate Drugs 0.000 description 2
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- 229960000391 sorbitan trioleate Drugs 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 235000000346 sugar Nutrition 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
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- CUNWUEBNSZSNRX-RKGWDQTMSA-N (2r,3r,4r,5s)-hexane-1,2,3,4,5,6-hexol;(z)-octadec-9-enoic acid Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O CUNWUEBNSZSNRX-RKGWDQTMSA-N 0.000 description 1
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
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- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 1
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 description 1
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- ANZDLPHEZHHGBH-UHFFFAOYSA-N 1-hexoxydecane Chemical compound CCCCCCCCCCOCCCCCC ANZDLPHEZHHGBH-UHFFFAOYSA-N 0.000 description 1
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- LQXBZWFNAKZUNM-UHFFFAOYSA-N 16-methyl-1-(16-methylheptadecoxy)heptadecane Chemical compound CC(C)CCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC(C)C LQXBZWFNAKZUNM-UHFFFAOYSA-N 0.000 description 1
- XFOQWQKDSMIPHT-UHFFFAOYSA-N 2,3-dichloro-6-(trifluoromethyl)pyridine Chemical compound FC(F)(F)C1=CC=C(Cl)C(Cl)=N1 XFOQWQKDSMIPHT-UHFFFAOYSA-N 0.000 description 1
- 239000000263 2,3-dihydroxypropyl (Z)-octadec-9-enoate Substances 0.000 description 1
- NLMKTBGFQGKQEV-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-(2-hexadecoxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CCCCCCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO NLMKTBGFQGKQEV-UHFFFAOYSA-N 0.000 description 1
- 125000006176 2-ethylbutyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(C([H])([H])*)C([H])([H])C([H])([H])[H] 0.000 description 1
- SFAAOBGYWOUHLU-UHFFFAOYSA-N 2-ethylhexyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC SFAAOBGYWOUHLU-UHFFFAOYSA-N 0.000 description 1
- XULHFMYCBKQGEE-UHFFFAOYSA-N 2-hexyl-1-Decanol Chemical compound CCCCCCCCC(CO)CCCCCC XULHFMYCBKQGEE-UHFFFAOYSA-N 0.000 description 1
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- MUHFRORXWCGZGE-KTKRTIGZSA-N 2-hydroxyethyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCO MUHFRORXWCGZGE-KTKRTIGZSA-N 0.000 description 1
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- RZRNAYUHWVFMIP-UHFFFAOYSA-N monoelaidin Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-UHFFFAOYSA-N 0.000 description 1
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- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
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- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- PZNOBXVHZYGUEX-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine;hydrochloride Chemical compound Cl.C=CCNCC=C PZNOBXVHZYGUEX-UHFFFAOYSA-N 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
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- 239000010466 nut oil Substances 0.000 description 1
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- ZPIRTVJRHUMMOI-UHFFFAOYSA-N octoxybenzene Chemical compound CCCCCCCCOC1=CC=CC=C1 ZPIRTVJRHUMMOI-UHFFFAOYSA-N 0.000 description 1
- 229940073665 octyldodecyl myristate Drugs 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 229960002969 oleic acid Drugs 0.000 description 1
- 125000002811 oleoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 229960003540 oxyquinoline Drugs 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229960003893 phenacetin Drugs 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 229940048084 pyrophosphate Drugs 0.000 description 1
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 description 1
- DCBSHORRWZKAKO-UHFFFAOYSA-N rac-1-monomyristoylglycerol Chemical compound CCCCCCCCCCCCCC(=O)OCC(O)CO DCBSHORRWZKAKO-UHFFFAOYSA-N 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000008165 rice bran oil Substances 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- NRWMBHYHFFGEEC-UHFFFAOYSA-N selachyl alcohol Natural products CCCCCCCCC=CCCCCCCCCOCC(O)CO NRWMBHYHFFGEEC-UHFFFAOYSA-N 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 229940057910 shea butter Drugs 0.000 description 1
- 230000036620 skin dryness Effects 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229940096501 sodium cocoamphoacetate Drugs 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- HVFAVOFILADWEZ-UHFFFAOYSA-M sodium;2-[2-(dodecanoylamino)ethyl-(2-hydroxyethyl)amino]acetate Chemical compound [Na+].CCCCCCCCCCCC(=O)NCCN(CCO)CC([O-])=O HVFAVOFILADWEZ-UHFFFAOYSA-M 0.000 description 1
- 229960005078 sorbitan sesquioleate Drugs 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 125000003696 stearoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920002258 tannic acid Polymers 0.000 description 1
- 229940033123 tannic acid Drugs 0.000 description 1
- 235000015523 tannic acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000001973 tert-pentyl group Chemical group [H]C([H])([H])C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- DZKXJUASMGQEMA-UHFFFAOYSA-N tetradecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC DZKXJUASMGQEMA-UHFFFAOYSA-N 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- PDSVZUAJOIQXRK-UHFFFAOYSA-N trimethyl(octadecyl)azanium Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)C PDSVZUAJOIQXRK-UHFFFAOYSA-N 0.000 description 1
- SZEMGTQCPRNXEG-UHFFFAOYSA-M trimethyl(octadecyl)azanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C SZEMGTQCPRNXEG-UHFFFAOYSA-M 0.000 description 1
- RRHXZLALVWBDKH-UHFFFAOYSA-M trimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)OCC[N+](C)(C)C RRHXZLALVWBDKH-UHFFFAOYSA-M 0.000 description 1
- VLPFTAMPNXLGLX-UHFFFAOYSA-N trioctanoin Chemical compound CCCCCCCC(=O)OCC(OC(=O)CCCCCCC)COC(=O)CCCCCCC VLPFTAMPNXLGLX-UHFFFAOYSA-N 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 229940116269 uric acid Drugs 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Dermatology (AREA)
- Emergency Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Description
本発明は、毛髪や皮膚の洗浄に用いられる洗浄剤組成物に関する。本願は、２０１８年３月１日に日本に出願した、特願２０１８－０３６８８０の優先権を主張し、その内容をここに援用する。 TECHNICAL FIELD The present invention relates to a detergent composition used for washing hair and skin. This application claims priority of Japanese Patent Application No. 2018-036880 filed in Japan on March 1, 2018, and the content thereof is incorporated herein.
従来、毛髪や皮膚の洗浄に用いられる洗浄剤（クレンジング剤、ヘアシャンプー、ボディソープ等）としては、高い洗浄力、良好な使用感・仕上がり等の特性を有すると共に、良好な泡立ち、皮膚への刺激を低減した洗浄剤組成物が用いられている。 Conventionally, cleaning agents (cleansing agents, hair shampoos, body soaps, etc.) used for cleaning hair and skin have characteristics such as high detergency, good usability and finish, good foaming, and good adhesion to the skin. Cleansing compositions with reduced irritation have been used.
例えば、低刺激性で起泡力及び使用感に優れる毛髪・皮膚用洗浄剤組成物として、ポリオキシエチレン誘導体、ポリグリセリン誘導体等の非イオン系界面活性剤やナノシリカゾルが配合された洗浄剤組成物が知られている（例えば、特許文献１～３等参照）。 For example, as a hair/skin cleansing composition that is hypoallergenic and has excellent foaming power and feeling when used, a cleansing composition containing a nonionic surfactant such as a polyoxyethylene derivative or a polyglycerin derivative or a nanosilica sol is blended. (See, for example, Patent Documents 1 to 3, etc.).
しかしながら、従来の洗浄剤組成物は、洗浄力、使用感、仕上がり感が十分ではなかった。
従って、本発明の目的は、洗浄力、使用感、仕上がり感等に優れ、毛髪や皮膚の洗浄用として好適な洗浄剤組成物を提供することにある。However, conventional detergent compositions are not sufficient in detergency, feeling of use, and finishing feeling.
SUMMARY OF THE INVENTION Accordingly, an object of the present invention is to provide a cleansing composition which is excellent in detergency, feeling of use, feeling of finishing, etc., and which is suitable for cleansing hair and skin.
本発明者等は、上記課題を解決するため鋭意検討した結果、洗浄剤組成物に特定のジ－又はトリ－エチレングリコールエーテルエステル化合物を配合することにより、洗浄力、使用感、仕上がり等に優れ、毛髪や皮膚の洗浄用として好適な洗浄剤組成物が得られることを見出した。本発明はこれらの知見に基づいて完成させたものである。 As a result of intensive studies to solve the above-mentioned problems, the inventors of the present invention have found that by blending a specific di- or tri-ethylene glycol ether ester compound in a detergent composition, excellent detergency, feeling of use, finish, etc. can be obtained. found that a detergent composition suitable for washing hair and skin can be obtained. The present invention has been completed based on these findings.
すなわち、本発明は、下記成分（Ａ）を含有することを特徴とする毛髪又は皮膚用洗浄剤組成物を提供する。
成分（Ａ）：下記式（Ｉ）で表される化合物
Component (A): a compound represented by the following formula (I)
前記毛髪又は皮膚用洗浄剤組成物は、さらに、下記成分（Ｂ）を含有してもよい。
成分（Ｂ）：ノニオン性界面活性剤The hair or skin cleansing composition may further contain the following component (B).
Component (B): nonionic surfactant
前記毛髪又は皮膚用洗浄剤組成物において、前記成分（Ａ）は、ジエチレングリコールモノメチルエーテルアセテート、ジエチレングリコールモノエチルエーテルアセテート、ジエチレングリコールモノブチルエーテルアセテート、トリエチレングリコールモノメチルエーテルアセテート、トリエチレングリコールモノエチルエーテルアセテート、及びトリエチレングリコールモノブチルエーテルアセテートからなる群より選ばれる少なくとも１種であってもよい。 In the hair or skin cleansing composition, the component (A) comprises diethylene glycol monomethyl ether acetate, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether acetate, triethylene glycol monomethyl ether acetate, triethylene glycol monoethyl ether acetate, and At least one selected from the group consisting of triethylene glycol monobutyl ether acetate may be used.
前記毛髪又は皮膚用洗浄剤組成物において、前記成分（Ａ）は、ジエチレングリコールモノエチルエーテルアセテートを含んでいてもよい。 In the hair or skin cleansing composition, the component (A) may contain diethylene glycol monoethyl ether acetate.
前記毛髪又は皮膚用洗浄剤組成物において、前記成分（Ｂ）は、ＨＬＢ値が１０～１８のノニオン性界面活性剤であってもよい。 In the hair or skin cleansing composition, the component (B) may be a nonionic surfactant having an HLB value of 10-18.
前記毛髪又は皮膚用洗浄剤組成物において、前記成分（Ｂ）は、脂肪酸ポリオキシエチレングリセリル、及び脂肪酸ポリグリセリルからなる群より選ばれる少なくとも１種のノニオン性界面活性剤を含んでいてもよい。 In the hair or skin cleansing composition, the component (B) may contain at least one nonionic surfactant selected from the group consisting of fatty acid polyoxyethylene glyceryl and fatty acid polyglyceryl.
前記毛髪又は皮膚用洗浄剤組成物において、前記成分（Ａ）の含有量は、洗浄剤組成物全量（１００重量％）に対して０．５～８重量％であってもよい。 In the hair or skin cleansing composition, the content of component (A) may be 0.5 to 8% by weight with respect to the total amount (100% by weight) of the cleansing composition.
前記毛髪又は皮膚用洗浄剤組成物において、前記成分（Ｂ）の含有量は、洗浄剤組成物全量（１００重量％）に対して０．５～３０重量％であってもよい。 In the hair or skin cleansing composition, the content of the component (B) may be 0.5 to 30% by weight with respect to the total amount (100% by weight) of the cleansing composition.
また、本発明は、前記毛髪又は皮膚用洗浄剤組成物を含む、クレンジング剤を提供する。 The present invention also provides a cleansing agent containing the hair or skin cleansing composition.
本発明の毛髪又は皮膚用洗浄剤組成物は上記式（Ｉ）で表される成分（Ａ）を含有するため、優れた洗浄力、使用感、仕上がり感を発揮することができ、毛髪洗浄用途（例えば、ヘアシャンプー）や皮膚洗浄用途（例えば、クレンジング剤、ボディーシャンプー）に好適に使用することができる。 Since the hair or skin cleansing composition of the present invention contains the component (A) represented by the above formula (I), it can exhibit excellent detergency, feeling of use and finish, and is suitable for use in hair cleansing. (eg, hair shampoo) and skin cleaning applications (eg, cleansing agent, body shampoo).
［毛髪又は皮膚用洗浄剤組成物］
本発明の毛髪又は皮膚用洗浄剤組成物（以下、単に「本発明の洗浄剤組成物」と称する場合がある）は、下記成分（Ａ）を含有することを特徴とする。
成分（Ａ）：下記式（Ｉ）で表される化合物
The hair or skin cleansing composition of the present invention (hereinafter sometimes simply referred to as "the cleansing composition of the present invention") is characterized by containing the following component (A).
Component (A): a compound represented by the following formula (I)
本発明の洗浄剤組成物は、上記成分（Ａ）を含有するため、優れた洗浄力、使用感、仕上がり感を発揮することができる。 Since the detergent composition of the present invention contains the above component (A), it can exhibit excellent detergency, feeling of use, and feeling of finish.
式（Ｉ）中、Ｒ1は炭素数１～６のアルキル基である。炭素数１～６のアルキル基としては、直鎖状、分岐鎖状、又は環状の炭素数１～６のアルキル基を特に限定なく採用することができ、例えば、メチル基、エチル基、ｎ－プロピル基、イソプロピル基、ｎ－ブチル基、イソブチル基、ｓｅｃ－ブチル基、ｔｅｒｔ－ブチル基、ｎ－ペンチル基、イソペンチル基、ネオペンチル基、ｔｅｒｔ－ペンチル基、シクロペンチル基、ｎ－へキシル基、２－エチルブチル基、又はシクロヘキシル基等が挙げられる。本発明の洗浄剤組成物の洗浄力、使用感、仕上がり感の観点から、メチル基、エチル基が好ましく、特にエチル基が好ましい。In formula (I), R 1 is an alkyl group having 1 to 6 carbon atoms. As the alkyl group having 1 to 6 carbon atoms, a linear, branched or cyclic alkyl group having 1 to 6 carbon atoms can be employed without particular limitation. propyl group, isopropyl group, n-butyl group, isobutyl group, sec-butyl group, tert-butyl group, n-pentyl group, isopentyl group, neopentyl group, tert-pentyl group, cyclopentyl group, n-hexyl group, 2 -ethylbutyl group, cyclohexyl group, and the like. From the viewpoint of the detergency of the detergent composition of the present invention, the feeling of use, and the feeling of finishing, a methyl group and an ethyl group are preferable, and an ethyl group is particularly preferable.
式（Ｉ）中、ｍは２又は３（整数）である。本発明の洗浄剤組成物の洗浄力、使用感、仕上がり感の観点から、ｍは２が好ましい。 In formula (I), m is 2 or 3 (integer). m is preferably 2 from the viewpoint of the detergency of the detergent composition of the present invention, the feeling of use, and the feeling of finish.
上記成分（Ａ）としては、特に限定されないが、ジエチレングリコールモノメチルエーテルアセテート、ジエチレングリコールモノエチルエーテルアセテート、ジエチレングリコールモノブチルエーテルアセテート、トリエチレングリコールモノメチルエーテルアセテート、トリエチレングリコールモノエチルエーテルアセテート、トリエチレングリコールモノブチルエーテルアセテート等が挙げられる。発明の洗浄剤組成物の洗浄力、使用感、仕上がり感の観点から、ジエチレングリコールモノメチルエーテルアセテート、ジエチレングリコールモノエチルエーテルアセテート等が好ましく、ジエチレングリコールモノエチルエーテルアセテートが特に好ましい。 The above component (A) is not particularly limited, but diethylene glycol monomethyl ether acetate, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether acetate, triethylene glycol monomethyl ether acetate, triethylene glycol monoethyl ether acetate, triethylene glycol monobutyl ether acetate. etc. Diethylene glycol monomethyl ether acetate, diethylene glycol monoethyl ether acetate, and the like are preferred, and diethylene glycol monoethyl ether acetate is particularly preferred, from the viewpoint of the detergency, feel of use, and finish feel of the detergent composition of the invention.
上記成分（Ａ）は、一種を単独で使用することもできるし、二種以上を組み合わせて使用することもできる。また、成分（Ａ）は、公知乃至慣用の方法により製造することもできるし、例えば、商品名「ＥＤＧＡＣ」（ジエチレングリコールモノエチルエーテルアセテート、（株）ダイセル製）等の市販品を使用することもできる。 The said component (A) can also be used individually by 1 type, and can also be used in combination of 2 or more types. In addition, component (A) can be produced by a known or commonly used method, and for example, a commercially available product such as the trade name "EDGAC" (diethylene glycol monoethyl ether acetate, manufactured by Daicel Co., Ltd.) can also be used. can.
本発明の洗浄剤組成物における成分（Ａ）の含有量（配合量）は、特に限定されないが、本発明の洗浄剤組成物（１００重量％）に対して、０．５～８重量％であることが好ましく、１～６重量％であることがより好ましい。成分（Ａ）の含有量がこの範囲にあることにより、高い洗浄力、良好な使用感、仕上がり感を得ながら、泡立ちを高め、肌の乾燥を抑制する効果、さらには繰り返し使用時の肌の乾燥による皮膚刺激を抑制する効果を高めることができる。一方、成分（Ａ）の含有量がこの範囲を超えると、本発明の洗浄剤組成物の安定性が低下する場合がある。 The content (amount) of component (A) in the cleaning composition of the present invention is not particularly limited, but is 0.5 to 8% by weight with respect to the cleaning composition (100% by weight) of the present invention. preferably 1 to 6% by weight. When the content of component (A) is within this range, it is possible to obtain high detergency, a good feeling of use, and a feeling of finish, while increasing foaming, suppressing dryness of the skin, and further improving the skin's dryness during repeated use. The effect of suppressing skin irritation due to dryness can be enhanced. On the other hand, when the content of component (A) exceeds this range, the stability of the detergent composition of the present invention may be lowered.
本発明の洗浄剤組成物は、さらに、下記成分（Ｂ）を含有することが好ましい。
成分（Ｂ）：ノニオン性界面活性剤The cleaning composition of the present invention preferably further contains the following component (B).
Component (B): nonionic surfactant
本発明の洗浄剤組成物が、上記成分（Ａ）に加えて、成分（Ｂ）を含むことにより、洗浄力、良好な使用感、仕上がり感が向上し、さらに、泡立ちを高め、肌の乾燥を抑制する効果、さらには繰り返し使用時の肌の乾燥による皮膚刺激を抑制する効果を高めることができる。 By including the component (B) in addition to the component (A), the cleansing composition of the present invention has improved detergency, a good feeling of use, and a good feeling of finish, and furthermore, increases foaming and dries the skin. can be enhanced, as well as the effect of suppressing skin irritation due to dryness of the skin during repeated use.
上記ノニオン性界面活性剤のＨＬＢ値としては、特に限定されないが、１０～１８が好ましく、１２～１６がより好ましい。この範囲のＨＬＢ値のノニオン性界面活性剤を使用することにより、洗浄力、良好な使用感、仕上がり感が向上し、さらに、泡立ちを高め、肌の乾燥を抑制する効果、さらには繰り返し使用時の肌の乾燥による皮膚刺激を抑制する効果を高めることができる。
なお、ＨＬＢ（Hydrophile-Lypophile Balance）値は、界面活性剤の水及び油への親和性を示す値であり、グリフィン法により次式から求めることができる。
ＨＬＢ＝２０×[(界面活性剤中に含まれる親水基の分子量)/(界面活性剤の分子量)]The HLB value of the nonionic surfactant is not particularly limited, but is preferably 10-18, more preferably 12-16. By using a nonionic surfactant with an HLB value within this range, the detergency, good feeling of use, and finish feeling are improved, and the effect of increasing foaming and suppressing dryness of the skin, even after repeated use. It is possible to enhance the effect of suppressing skin irritation due to dry skin.
The HLB (Hydrophile-Lypophile Balance) value is a value that indicates the affinity of a surfactant for water and oil, and can be obtained from the following equation by Griffin's method.
HLB = 20 x [(molecular weight of hydrophilic group contained in surfactant)/(molecular weight of surfactant)]
上記ノニオン性界面活性剤としては、特に限定されないが、エーテル型ノニオン性界面活性剤、エステル型ノニオン性界面活性剤、アミド型ノニオン性界面活性剤等が挙げられる。 Examples of the nonionic surfactant include, but are not limited to, ether-type nonionic surfactants, ester-type nonionic surfactants, amide-type nonionic surfactants, and the like.
エーテル型ノニオン性界面活性剤としては、特に限定されないが、例えば、ポリオキシエチレン（以下、ＰＯＥという。）セチルエーテル（セテス）、ＰＯＥステアリルエーテル（ステアレス）、ＰＯＥベヘニルエーテル、ＰＯＥオレイルエーテル（オレス）、ＰＯＥラウリルエーテル（ラウレス）、ＰＯＥオクチルドデシルエーテル、ＰＯＥヘキシルデシルエーテル、ＰＯＥイソステアリルエーテル等のポリオキシエチレンアルキルエーテル；ＰＯＥノニルフェニルエーテル、ＰＯＥオクチルフェニルエーテル等のポリオキシエチレンアルキルフェニルエーテル；ポリグリセリンラウリルエーテル、ポリグリセリンミリスチルエーテル、ポリグリセリンステアリルエーテル等のポリグリセリンアルキルエーテルが挙げられる。 Examples of ether-type nonionic surfactants include, but are not limited to, polyoxyethylene (hereinafter referred to as POE) cetyl ether (ceteth), POE stearyl ether (steareth), POE behenyl ether, and POE oleyl ether (oleth). , POE lauryl ether (laureth), POE octyldodecyl ether, POE hexyldecyl ether, POE isostearyl ether and other polyoxyethylene alkyl ethers; POE nonylphenyl ether, POE octylphenyl ether and other polyoxyethylene alkylphenyl ethers; polyglycerin Examples include polyglycerin alkyl ethers such as lauryl ether, polyglycerin myristyl ether, and polyglycerin stearyl ether.
エステル型ノニオン性界面活性剤としては、特に限定されないが、例えば、モノオレイン酸ＰＯＥソルビタン、モノステアリン酸ＰＯＥソルビタン、モノパルミチン酸ＰＯＥソルビタン、モノラウリン酸ＰＯＥソルビタン、トリオレイン酸ＰＯＥソルビタン等の脂肪酸ポリオキシエチレンソルビタン；モノステアリン酸ＰＯＥグリセリル、モノミリスチン酸ＰＯＥグリセリル、ヤシ油脂肪酸ＰＯＥグリセリル等の脂肪酸ポリオキシエチレングリセリル；テトラオレイン酸ＰＯＥソルビット、ヘキサステアリン酸ＰＯＥソルビット、モノラウリン酸ＰＯＥソルビット、ＰＯＥソルビットミツロウ等の脂肪酸ポリオキシエチレンソルビット；モノオレイン酸ポリエチレングリコール、モノステアリン酸ポリエチレングリコール、モノラウリン酸ポリエチレングリコール等の脂肪酸ポリエチレングリコール；親油型モノオレイン酸グリセリル、親油型モノステアリン酸グリセリル、自己乳化型モノステアリン酸グリセリル等のモノ脂肪酸グリセリル；モノオレイン酸ソルビタン、セスキオレイン酸ソルビタン、トリオレイン酸ソルビタン、モノステアリン酸ソルビタン、モノパルミチン酸ソルビタン、モノラウリン酸ソルビタン等の脂肪酸ソルビタン；ショ糖脂肪酸エステル；モノラウリン酸デカグリセリル、モノステアリン酸デカグリセリル、モノオレイン酸デカグリセリル、モノミリスチン酸デカグリセリル等の脂肪酸ポリグリセリル等が挙げられる。 Examples of ester-type nonionic surfactants include, but are not limited to, POE sorbitan monooleate, POE sorbitan monostearate, POE sorbitan monopalmitate, POE sorbitan monolaurate, and POE sorbitan trioleate. Ethylene sorbitan; fatty acid polyoxyethylene glyceryl such as POE glyceryl monostearate, POE glyceryl monomyristate, and POE glyceryl coconut oil fatty acid; Fatty acid polyoxyethylene sorbitol; fatty acid polyethylene glycol such as polyethylene glycol monooleate, polyethylene glycol monostearate, polyethylene glycol monolaurate; lipophilic glyceryl monooleate, lipophilic glyceryl monostearate, self-emulsifying monostearate mono-fatty acid glyceryl such as glyceryl; fatty acid sorbitan such as sorbitan monooleate, sorbitan sesquioleate, sorbitan trioleate, sorbitan monostearate, sorbitan monopalmitate, sorbitan monolaurate; sucrose fatty acid ester; decaglyceryl monolaurate, Fatty acid polyglyceryls such as decaglyceryl monostearate, decaglyceryl monooleate, decaglyceryl monomyristate and the like.
アミド型ノニオン性界面活性剤としては、特に限定されないが、例えば、ポリオキシエチレンラウリン酸モノエタノールアミド、ポリオキシエチレンヤシ油脂肪酸モノエタノールアミド、ポリオキシプロピレンミリスチン酸モノエタノールアミド等のポリオキシアルキレン脂肪酸アミド（ポリオキシアルキレン脂肪酸アルカノールアミド）等が挙げられる。 The amide-type nonionic surfactant is not particularly limited, but for example, polyoxyalkylene fatty acids such as polyoxyethylene lauric acid monoethanolamide, polyoxyethylene coconut oil fatty acid monoethanolamide, and polyoxypropylene myristate monoethanolamide and amides (polyoxyalkylene fatty acid alkanolamides).
上記ノニオン性界面活性剤としては、特に限定されないが、本発明の洗浄剤組成物の洗浄力、使用感、仕上がり感の観点から、エステル型ノニオン性界面活性剤が好ましく、脂肪酸ポリオキシエチレングリセリル、及び脂肪酸ポリグリセリルからなる群から選ばれる少なくとも１種がより好ましく、脂肪酸ポリオキシエチレングリセリル、及び脂肪酸ポリグリセリルの両方を含むことが特に好ましい。 The nonionic surfactant is not particularly limited, but is preferably an ester-type nonionic surfactant from the viewpoint of the detergency of the cleaning composition of the present invention, feeling of use, and feeling of finish. and fatty acid polyglyceryl is more preferred, and it is particularly preferred to contain both fatty acid polyoxyethylene glyceryl and fatty acid polyglyceryl.
上記脂肪酸ポリオキシエチレングリセリルは、特に限定されないが、下記式（ＩＩ）で表される化合物が挙げられる。
式（ＩＩ）中、Ｒ2は炭素数８～１８のアシル基を示す。炭素数８～１８のアシル基としては、特に限定されないが、デカノイル基、ラウロイル基、ミリストイル基、パルミトイル基、ステアロイル基、オレオイル基、リノレイル基等が挙げられ、ラウロイル基、ミリストイル基、パルミトイル基等の炭素数１２～１６のアシル基が好ましい。In formula (II), R 2 represents an acyl group having 8 to 18 carbon atoms. Examples of acyl groups having 8 to 18 carbon atoms include, but are not limited to, decanoyl, lauroyl, myristoyl, palmitoyl, stearoyl, oleoyl, linoleyl, lauroyl, myristoyl and palmitoyl groups. An acyl group having 12 to 16 carbon atoms such as is preferred.
式（ＩＩ）中、ａ及びｂはオキシエチレン単位の平均量体数を示し、ａとｂの合計（ａ＋ｂ）が１～１０の数であり、好ましくは、３～８の数である。 In formula (II), a and b represent the average number of oxyethylene units, and the sum of a and b (a+b) is a number of 1-10, preferably a number of 3-8.
脂肪酸ポリオキシエチレングリセリルとしては、本発明の洗浄剤組成物の洗浄力、使用感、仕上がり感の観点から、ヤシ油脂肪酸ＰＯＥグリセリルが好ましく、特にヤシ油脂肪酸ＰＥＧ－７グリセリルが好ましい。 As the polyoxyethylene glyceryl fatty acid, POE glyceryl coconut oil is preferred, and PEG-7 glyceryl coconut oil is particularly preferred, from the viewpoint of the detergency, feeling of use, and finish of the detergent composition of the present invention.
上記脂肪酸ポリグリセリルは、特に限定されないが、下記式（ＩＩＩ）で表される化合物が挙げられる。
式（ＩＩＩ）の括弧内のＣ3Ｈ6Ｏ2は、下記式（１）及び（２）で示される何れの構造を有していてもよい。
－ＣＨ2－ＣＨＯＨ－ＣＨ2Ｏ－ （１）
－ＣＨ（ＣＨ2ＯＨ）ＣＨ2Ｏ－ （２）C 3 H 6 O 2 in parentheses in formula (III) may have any structure represented by formulas (1) and (2) below.
-CH 2 -CHOH-CH 2 O- (1)
-CH( CH2OH ) CH2O- (2)
式（ＩＩＩ）中、Ｒ3は炭素数８～１８のアシル基を示す。Ｒ3の炭素数８～１８のアシル基としては、特に限定されないが、上記のＲ2と同様なものが挙げられる。In formula (III), R 3 represents an acyl group having 8 to 18 carbon atoms. The acyl group having 8 to 18 carbon atoms for R 3 is not particularly limited, but includes the same groups as those for R 2 above.
式（ＩＩＩ）中、ｎはグリセリンの重合度を示し、２～１３（好ましくは３～１２、特に好ましくは４～１０）の整数である。 In formula (III), n represents the degree of polymerization of glycerin and is an integer of 2 to 13 (preferably 3 to 12, particularly preferably 4 to 10).
脂肪酸ポリグリセリルとしては、本発明の洗浄剤組成物の洗浄力、使用感、仕上がり感の観点から、ラウリル酸ポリグリセリルが好ましく、特にラウリル酸デカグリセリルが好ましい。 As the fatty acid polyglyceryl, polyglyceryl laurate is preferred, and decaglyceryl laurate is particularly preferred, from the viewpoints of the detergency, feeling of use, and finish of the cleaning composition of the present invention.
上記成分（Ｂ）は、一種を単独で使用することもできるし、二種以上を組み合わせて使用することもできる。また、成分（Ｂ）は、公知乃至慣用の方法により製造することもできるし、市販品を使用することもできる。 The said component (B) can also be used individually by 1 type, and can also be used in combination of 2 or more types. Component (B) can also be produced by a known or commonly used method, or a commercially available product can be used.
本発明の洗浄剤組成物における成分（Ｂ）の含有量（配合量）は、特に限定されないが、本発明の洗浄剤組成物（１００重量％）に対して、０．５～３０重量％であることが好ましく、２～２０重量％であることがより好ましく、２～１５重量％であることがより好ましい。成分（Ｂ）の含有量がこの範囲にあることにより、良好な泡立ち、高い洗浄力、良好な仕上がりを得ながら、肌の乾燥を抑制する効果、さらには繰り返し使用時の手肌の乾燥による皮膚刺激を抑制する効果を高めることができる。 The content (blended amount) of component (B) in the detergent composition of the present invention is not particularly limited, but is 0.5 to 30% by weight with respect to the detergent composition (100% by weight) of the present invention. preferably 2 to 20% by weight, more preferably 2 to 15% by weight. When the content of the component (B) is within this range, it has the effect of suppressing dryness of the skin while obtaining good foaming, high detergency, and a good finish. The effect of suppressing stimulation can be enhanced.
本発明の洗浄剤組成物が成分（Ｂ）として脂肪酸ポリオキシエチレングリセリルを含有する場合、その含有量（配合量）は、特に限定されないが、本発明の洗浄剤組成物（１００重量％）に対して、０．５～２５重量％であることが好ましく、２～１５重量％であることがより好ましく、２～１２重量％であることがさらに好ましい。脂肪酸ポリオキシエチレングリセリルの含有量がこの範囲にあることにより、良好な泡立ち、高い洗浄力、良好な仕上がりを得ながら、肌の乾燥を抑制する効果、さらには繰り返し使用時の手肌の乾燥による皮膚刺激を抑制する効果を高めることができる。 When the detergent composition of the present invention contains fatty acid polyoxyethylene glyceryl as component (B), the content (blended amount) is not particularly limited, but the detergent composition of the present invention (100% by weight) contains On the other hand, it is preferably 0.5 to 25% by weight, more preferably 2 to 15% by weight, even more preferably 2 to 12% by weight. When the content of fatty acid polyoxyethylene glyceryl is within this range, it has the effect of suppressing dryness of the skin while obtaining good foaming, high detergency, and a good finish. The effect of suppressing skin irritation can be enhanced.
本発明の洗浄剤組成物が成分（Ｂ）として脂肪酸ポリグリセリルを含有する場合、その含有量（配合量）は、特に限定されないが、本発明の洗浄剤組成物（１００重量％）に対して、０．５～１５重量％であることが好ましく、２～１０重量％であることがより好ましく、２～５重量％であることがさらに好ましい。脂肪酸ポリグリセリルの含有量がこの範囲にあることにより、良好な泡立ち、高い洗浄力、良好な仕上がりを得ながら、肌の乾燥を抑制する効果、さらには繰り返し使用時の手肌の乾燥による皮膚刺激を抑制する効果を高めることができる。 When the detergent composition of the present invention contains fatty acid polyglyceryl as component (B), the content (blended amount) thereof is not particularly limited, but the detergent composition of the present invention (100% by weight) contains: It is preferably 0.5 to 15% by weight, more preferably 2 to 10% by weight, even more preferably 2 to 5% by weight. The fatty acid polyglyceryl content within this range has the effect of suppressing dryness of the skin while obtaining good foaming, high detergency, and a good finish, and also prevents skin irritation caused by dry hands during repeated use. The suppressing effect can be enhanced.
本発明の洗浄剤組成物が成分（Ｂ）として脂肪酸ポリオキシエチレングリセリル及び脂肪酸ポリグリセリルを含有する場合、その重量比（脂肪酸ポリオキシエチレングリセリル／脂肪酸ポリグリセリル）は、特に限定されないが、５０／５０～９５／５であることが好ましく、６０／４０～９０／１０であることがより好ましく、６５／３５～８５／１５であることがさらに好ましい。脂肪酸ポリオキシエチレングリセリルと脂肪酸ポリグリセリルの重量比がこの範囲にあることにより、良好な泡立ち、高い洗浄力、良好な仕上がりを得ながら、肌の乾燥を抑制する効果、さらには繰り返し使用時の手肌の乾燥による皮膚刺激を抑制する効果を高めることができる。
［その他の成分］
本発明の洗浄剤組成物には、本発明の効果を大きく阻害しない範囲において、前述した成分の他に、例えば、水溶性ポリマー、油性成分、多価アルコール、界面活性剤、ｐＨ調整剤、糖、増粘剤、防腐剤、キレート剤、安定剤、酸化防止剤、植物抽出物、生薬抽出物、ビタミン、香料、紫外線吸収剤、抗菌剤等が配合されていてもよい。When the detergent composition of the present invention contains fatty acid polyoxyethylene glyceryl and fatty acid polyglyceryl as component (B), the weight ratio (fatty acid polyoxyethylene glyceryl/fatty acid polyglyceryl) is not particularly limited, but is from 50/50. It is preferably 95/5, more preferably 60/40 to 90/10, even more preferably 65/35 to 85/15. When the weight ratio of the fatty acid polyoxyethylene glyceryl and the fatty acid polyglyceryl is in this range, it has the effect of suppressing dryness of the skin while obtaining good foaming, high detergency, and a good finish, and even the hand skin after repeated use. The effect of suppressing skin irritation due to dryness can be enhanced.
[Other ingredients]
The detergent composition of the present invention may contain, in addition to the components described above, for example, a water-soluble polymer, an oily component, a polyhydric alcohol, a surfactant, a pH adjuster, and a sugar, as long as the effects of the present invention are not greatly impaired. , thickeners, preservatives, chelating agents, stabilizers, antioxidants, plant extracts, crude drug extracts, vitamins, fragrances, UV absorbers, antibacterial agents, and the like may be added.
水溶性ポリマーとしては、カチオン性ポリマー、アニオン性ポリマー、非イオン性ポリマー、及び両性の天然又は合成ポリマーを配合することができる。このような水溶性ポリマーのより具体的な例としては、キサンタンガム、グアーガム、アルギン酸ナトリウム、トラガントガム、ローカストビーンガム、エチルセルロース、メチルセルロース、ヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、ヒドロキシプロピルメチルセルロース、カルボキシメチルセルロースナトリウム、ヒドロキシエチルセルロースジメチルジアリルアンモニウムクロリド、ヒドロキシエチルセルロースヒドロキシプロピルトリメチルアンモニウムクロリドエーテル、カルボキシビニルポリマー（カルボマー）、ポリアクリル酸とその塩類、（メタ）アクリル酸アルキル共重合体等が挙げられる。 Cationic polymers, anionic polymers, nonionic polymers, and amphoteric natural or synthetic polymers can be blended as water-soluble polymers. More specific examples of such water-soluble polymers include xanthan gum, guar gum, sodium alginate, tragacanth gum, locust bean gum, ethylcellulose, methylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose, sodium carboxymethylcellulose, hydroxyethylcellulose dimethyl. diallyl ammonium chloride, hydroxyethyl cellulose hydroxypropyl trimethyl ammonium chloride ether, carboxyvinyl polymer (carbomer), polyacrylic acid and its salts, alkyl (meth)acrylate copolymer and the like.
油性成分としては、油脂、ロウ、高級アルコール、炭化水素、高級脂肪酸、アルキルグリセリルエーテル、エステル、シリコーン等が挙げられる。 Oily components include oils and fats, waxes, higher alcohols, hydrocarbons, higher fatty acids, alkylglyceryl ethers, esters, silicones and the like.
油脂としては、ラノリン、オリーブ油、ツバキ油、シア脂、アーモンド油、サフラワー油、ヒマワリ油、大豆油、綿実油、ゴマ油、トウモロコシ油、ナタネ油、コメヌカ油、コメ胚芽油、ブドウ種子油、アボカド油、マカダミアナッツ油、ヒマシ油、ヤシ油、月見草油等が挙げられる。 Oils and fats include lanolin, olive oil, camellia oil, shea butter, almond oil, safflower oil, sunflower oil, soybean oil, cottonseed oil, sesame oil, corn oil, rapeseed oil, rice bran oil, rice germ oil, grape seed oil, and avocado oil. , macadamia nut oil, castor oil, coconut oil, evening primrose oil and the like.
ロウとしては、ミツロウ、キャンデリラロウ、カルナウバロウ、ホホバ油、ラノリン等が挙げられる。 Waxes include beeswax, candelilla wax, carnauba wax, jojoba oil, lanolin and the like.
高級アルコールとしては、セチルアルコール（セタノール）、２－ヘキシルデカノール、ステアリルアルコール、イソステアリルアルコール、セトステアリルアルコール、オレイルアルコール、アラキルアルコール、ベヘニルアルコール、２－オクチルドデカノール、ラウリルアルコール、ミリスチルアルコール、デシルテトラデカノール、ラノリンアルコール等が挙げられる。 Higher alcohols include cetyl alcohol (cetanol), 2-hexyldecanol, stearyl alcohol, isostearyl alcohol, cetostearyl alcohol, oleyl alcohol, arachyl alcohol, behenyl alcohol, 2-octyldodecanol, lauryl alcohol, myristyl alcohol, and decyltetradeca. alcohol, lanolin alcohol and the like.
炭化水素としては、パラフィン、オレフィンオリゴマー、ポリイソブテン、水添ポリイソブテン、ミネラルオイル、スクワラン、ポリブテン、ポリエチレン、マイクロクリスタリンワックス、ワセリン等が挙げられる。 Hydrocarbons include paraffin, olefin oligomer, polyisobutene, hydrogenated polyisobutene, mineral oil, squalane, polybutene, polyethylene, microcrystalline wax, vaseline and the like.
高級脂肪酸としては、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘニン酸、イソステアリン酸、１２－ヒドロキシステアリン酸、オレイン酸、ラノリン脂肪酸等が挙げられる。 Higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, isostearic acid, 12-hydroxystearic acid, oleic acid and lanolin fatty acid.
アルキルグリセリルエーテルとしては、バチルアルコール、キミルアルコール、セラキルアルコール、イソステアリルグリセリルエーテル、エチルヘキシルグリセリルエーテル等が挙げられる。 Alkyl glyceryl ethers include batyl alcohol, chimyl alcohol, selachyl alcohol, isostearyl glyceryl ether, ethylhexyl glyceryl ether and the like.
エステルとしては、前記成分（Ａ）以外のエステル、例えばアジピン酸ジイソプロピル、ミリスチン酸イソプロピル、オクタン酸セチル、イソノナン酸イソノニル、ミリスチン酸オクチルドデシル、パルミチン酸イソプロピル、ステアリン酸ステアリル、ミリスチン酸ミリスチル、ミリスチン酸イソトリデシル、パルミチン酸２－エチルへキシル、リシノール酸オクチルドデシル、１０～３０の炭素数を有する脂肪酸コレステリル／ラノステリル、乳酸セチル、酢酸ラノリン、ジ－２－エチルヘキサン酸エチレングリコール、ペンタエリスリトール脂肪酸エステル、ジペンタエリスリトール脂肪酸エステル、カプリン酸セチル、トリカプリル酸グリセリル、リンゴ酸ジイソステアリル、コハク酸ジオクチル、２－エチルヘキサン酸セチル等が挙げられる。 Esters other than component (A) include diisopropyl adipate, isopropyl myristate, cetyl octanoate, isononyl isononanoate, octyldodecyl myristate, isopropyl palmitate, stearyl stearate, myristyl myristate, and isotridecyl myristate. , 2-ethylhexyl palmitate, octyldodecyl ricinoleate, cholesteryl/lanosteryl fatty acid having 10 to 30 carbon atoms, cetyl lactate, lanolin acetate, ethylene glycol di-2-ethylhexanoate, pentaerythritol fatty acid ester, dipenta Erythritol fatty acid ester, cetyl caprate, glyceryl tricaprylate, diisostearyl malate, dioctyl succinate, cetyl 2-ethylhexanoate and the like.
シリコーンとしては、ジメチルポリシロキサン（ジメチコン）、メチルフェニルポリシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロヘキサシロキサン、末端水酸基変性ジメチルポリシロキサン、６５０～１００００の平均重合度を有する高重合シリコーン、ポリエーテル変性シリコーン（例えば、（ＰＥＧ／ＰＰＧ／ブチレン／ジメチコン）コポリマー）、アミノ変性シリコーン、ベタイン変性シリコーン、アルキル変性シリコーン、アルコキシ変性シリコーン、メルカプト変性シリコーン、カルボキシ変性シリコーン、フッ素変性シリコーン等が挙げられる。 Examples of silicones include dimethylpolysiloxane (dimethicone), methylphenylpolysiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, hydroxyl-terminated dimethylpolysiloxane, highly polymerized silicone having an average degree of polymerization of 650 to 10000, and polyether. modified silicone (eg, (PEG/PPG/butylene/dimethicone) copolymer), amino-modified silicone, betaine-modified silicone, alkyl-modified silicone, alkoxy-modified silicone, mercapto-modified silicone, carboxy-modified silicone, fluorine-modified silicone and the like.
多価アルコールとしては、グリコール類、グリセリン類等が挙げられる。グリコール類としては、前記成分（Ｂ）以外のグリコール、例えばエチレングリコール、ジエチレングリコール、トリエチレングリコール、イソプレングリコール、１，３－ブチレングリコール等が挙げられる。グリセリン類としては、グリセリン、ジグリセリン、ポリグリセリン等が挙げられる。 Polyhydric alcohols include glycols, glycerins and the like. Glycols include glycols other than component (B), such as ethylene glycol, diethylene glycol, triethylene glycol, isoprene glycol, and 1,3-butylene glycol. Glycerins include glycerin, diglycerin, polyglycerin and the like.
界面活性剤としては、アニオン性界面活性剤、両性界面活性剤の他、カチオン性界面活性剤を併用することができる。 As the surfactant, in addition to anionic surfactants and amphoteric surfactants, cationic surfactants can be used in combination.
アニオン性界面活性剤としては、アルキルエーテル硫酸塩、アルキル硫酸塩、アルケニルエーテル硫酸塩、アルケニル硫酸塩、オレフィンスルホン酸塩、アルカンスルホン酸塩、飽和又は不飽和脂肪酸塩、アルキル又はアルケニルエーテルカルボン酸塩、α－スルホン脂肪酸塩、Ｎ－アシルアミノ酸型界面活性剤、リン酸モノ又はジエステル型界面活性剤、スルホコハク酸エステル等が挙げられる。これらの界面活性剤のアニオン基の対イオンとしては、ナトリウムイオン、カリウムイオン、トリエタノールアミン等が挙げられる。アルキル硫酸塩としては、ラウリル硫酸ナトリウム等が挙げられる。 Anionic surfactants include alkyl ether sulfates, alkyl sulfates, alkenyl ether sulfates, alkenyl sulfates, olefinsulfonates, alkanesulfonates, saturated or unsaturated fatty acid salts, alkyl or alkenyl ether carboxylates. , α-sulfone fatty acid salts, N-acylamino acid type surfactants, phosphoric acid mono- or diester type surfactants, sulfosuccinic acid esters and the like. Counter ions for the anionic groups of these surfactants include sodium ions, potassium ions, triethanolamine, and the like. Alkyl sulfates include sodium lauryl sulfate and the like.
両性界面活性剤としては、ココベタイン、ラウラミドプロピルベタイン、コカミドプロピルベタイン、ラウロアンホ酢酸ナトリウム、ココアンホ酢酸ナトリウム、ラウリルベタイン（ラウリルジメチルアミノ酢酸ベタイン）等が挙げられる。 Amphoteric surfactants include cocobetaine, lauramidopropylbetaine, cocamidopropylbetaine, sodium lauroamphoacetate, sodium cocoamphoacetate, laurylbetaine (betaine lauryldimethylaminoacetate) and the like.
カチオン性界面活性剤としては、塩化ラウリルトリメチルアンモニウム、塩化セチルトリメチルアンモニウム、塩化ステアリルトリメチルアンモニウム、塩化アルキルトリメチルアンモニウム、塩化ジステアリルジメチルアンモニウム、臭化セチルトリメチルアンモニウム、臭化ステアリルトリメチルアンモニウム、エチル硫酸ラノリン脂肪酸アミノプロピルエチルジメチルアンモニウム、ステアリルトリメチルアンモニウムサッカリン、セチルトリメチルアンモニウムサッカリン、塩化メタクリロイルオキシエチルトリメチルアンモニウム、メチル硫酸ベヘニルトリメチルアンモニウム等が挙げられる。 Cationic surfactants include lauryltrimethylammonium chloride, cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, alkyltrimethylammonium chloride, distearyldimethylammonium chloride, cetyltrimethylammonium bromide, stearyltrimethylammonium bromide, ethyl sulfate lanolin fatty acid. aminopropylethyldimethylammonium, stearyltrimethylammonium saccharin, cetyltrimethylammonium saccharin, methacryloyloxyethyltrimethylammonium chloride, behenyltrimethylammonium methylsulfate and the like.
ｐＨ調整剤としては、クエン酸、酒石酸、乳酸、リンゴ酸、コハク酸、フマル酸、マレイン酸、ピロリン酸、グルコン酸、グルクロン酸、安息香酸、２－アミノ－２－メチル－１，３－プロパンジオール、水酸化カリウム等が挙げられる。 pH adjusters include citric acid, tartaric acid, lactic acid, malic acid, succinic acid, fumaric acid, maleic acid, pyrophosphate, gluconic acid, glucuronic acid, benzoic acid, 2-amino-2-methyl-1,3-propane. diol, potassium hydroxide, and the like.
糖としては、ソルビトール、マルトース等が挙げられる。防腐剤としては、パラベン、フェノキシエタノール、エタノール等が挙げられる。キレート剤としては、エデト酸二ナトリウム等が挙げられる。安定剤としては、フェナセチン、８－ヒドロキシキノリン、アセトアニリド、ピロリン酸ナトリウム、バルビツール酸、尿酸、タンニン酸等が挙げられる。酸化防止剤としては、アスコルビン酸、亜硫酸塩等が挙げられる。 Sugars include sorbitol, maltose, and the like. Examples of antiseptics include paraben, phenoxyethanol, ethanol and the like. Chelating agents include disodium edetate and the like. Stabilizers include phenacetin, 8-hydroxyquinoline, acetanilide, sodium pyrophosphate, barbituric acid, uric acid, tannic acid and the like. Antioxidants include ascorbic acid, sulfites, and the like.
増粘剤としては、塩化ナトリウム、塩化Ｏ－［２－ヒドロキシ－３－（トリメチルアンモニオ）プロピル］ヒドロキシエチルセルロース、グアーヒドロキシプロピルトリモニウムクロリド等が挙げられる。 Thickeners include sodium chloride, O-[2-hydroxy-3-(trimethylammonio)propyl]hydroxyethylcellulose chloride, guar hydroxypropyltrimonium chloride and the like.
本発明の洗浄剤組成物は、例えば、上記成分（Ａ）と、必要に応じて、成分（Ｂ）、その他の成分を混合することにより製造することができる。 The detergent composition of the present invention can be produced, for example, by mixing the above-mentioned component (A), component (B), and other components, if necessary.
本発明の洗浄剤組成物は、例えばｐＨ３～１１が好ましく、特に好ましくはｐＨ４～１０である。 The detergent composition of the present invention preferably has a pH of 3-11, particularly preferably 4-10.
本発明の洗浄剤組成物の剤型は、特に限定されない。具体例として、例えば、固体状、液状、ゲル状、フォーム状、クリーム状等が挙げられる。剤型が固体状である場合、添加剤として、さらに分散剤、例えばステアリン酸金属塩、タルク、結晶セルロース、低置換度ヒドロキシプロピルセルロース、デキストリン、デンプン等を配合してもよい。 The dosage form of the detergent composition of the present invention is not particularly limited. Specific examples include solids, liquids, gels, foams, creams, and the like. When the dosage form is solid, dispersing agents such as metal stearate, talc, crystalline cellulose, low-substituted hydroxypropylcellulose, dextrin, and starch may be added as additives.
本発明の洗浄剤組成物の用途は、生体に適用されるものであれば特に限定されないが、洗浄力、使用感、仕上がり感に優れることから、毛髪用（ヘアシャンプー）、身体（皮膚）用の洗浄剤（クレンジング剤、ボディソープ、洗顔剤、ハンドソープ）等として好適に用いることができる。毛髪用の洗浄剤としては、例えば洗髪剤（ヘアシャンプー）、さらにはパーマネントウエーブ処理後、毛髪脱色・脱染処理後、染毛処理後に適用される各種後処理剤等が挙げられる。 The use of the cleansing composition of the present invention is not particularly limited as long as it is applied to the living body. (cleansing agents, body soaps, facial cleansers, hand soaps) and the like. Hair cleansing agents include, for example, shampoos (hair shampoos), and various post-treatment agents applied after permanent wave treatment, hair bleaching/decoloring treatment, and hair dyeing treatment.
本発明の洗浄剤組成物は、特にクレンジング剤として好ましく用いることができ、例えば洗顔料、洗浄料、クレンジングクリーム、マッサージクリーム、シャンプー等とすることができるが、特にメイクアップ化粧料除去用の洗顔料として好適である。 The cleansing composition of the present invention can be used particularly preferably as a cleansing agent, such as face wash, cleansing agent, cleansing cream, massage cream, shampoo, etc., and is particularly suitable for removing make-up cosmetics. It is suitable as a food.
以下、実施例により本発明をより具体的に説明するが、本発明はこれらの実施例により限定されるものではない。 EXAMPLES The present invention will be described in more detail with reference to examples below, but the present invention is not limited to these examples.
実施例１～３、比較例１
下記表１に示す配合組成（単位：重量部）により洗浄剤組成物を下記手順により調製した。
１） （ａ）～（ｇ）を均一溶解する。
２） １）に（ｈ）を添加し、均一溶解する。
３） ２）に（ｉ）を添加し、混合均一化する。
４） ３）に予め均一混合した（ｊ）～（ｌ）を添加し、混合均一化する。
５） 終了Examples 1 to 3, Comparative Example 1
A detergent composition was prepared according to the following procedure according to the composition (unit: parts by weight) shown in Table 1 below.
1) Uniformly dissolve (a) to (g).
2) Add (h) to 1) and dissolve uniformly.
3) Add (i) to 2) and mix and homogenize.
4) Add (j) to (l) previously uniformly mixed to 3), and mix and homogenize.
5) End
得られた洗浄剤組成物についてクレンジングジェルとして適用し、下記方法で評価した。 The resulting detergent composition was applied as a cleansing gel and evaluated by the following methods.
実施例、比較例の洗浄剤組成物（クレンジングジェル）について、専門パネラー６名にて、メイク汚れの洗浄力、洗い流し後の使用感について評価した。 The cleansing compositions (cleansing gels) of Examples and Comparative Examples were evaluated by 6 expert panelists in terms of cleansing power for makeup stains and feeling after use after rinsing.
［メイク洗浄力の評価］
メイク洗浄力の評価は、専門パネラー６名によって目視にて５段階（１～５）で評価し、平均スコアを算出した。結果を表１に示す。[Evaluation of makeup detergency]
The makeup detergency was evaluated visually by 6 expert panelists on a scale of 5 (1 to 5), and an average score was calculated. Table 1 shows the results.
［洗い流し後の使用感］
洗い流し後の使用感の評価は、専門パネラー６名によって官能評価を行い、５段階（１～５）で評価し、平均スコアを算出した。結果を表１に示す。[Usability after rinsing]
The feeling of use after rinsing was evaluated by sensory evaluation by 6 expert panelists, evaluated on a 5-point scale (1 to 5), and an average score was calculated. Table 1 shows the results.
なお、表１に示した各成分に対応する数値は、いずれも各成分の含有量を示し、その単位は重量％である。 The numerical value corresponding to each component shown in Table 1 indicates the content of each component, and the unit is % by weight.
表１に示す各成分は、以下の通りである。
［成分（Ａ）］
ジエチレングリコールモノエチルエーテルアセテート：商品名「ＥＤＧＡＣ」、（株）ダイセル製
［成分（Ｂ）］
ヤシ油脂肪酸ＰＥＧ－７グリセリル：商品名「ＧＬＹＣＥＲＯＸ ＨＥ」、クローダジャパン（株）製
ラウリン酸ポリグリセリル－１０：商品名「ＰＧＬＥ ＭＬ１０」、（株）ダイセル製
［その他の成分］
ＢＧ：商品名「１，３－ＢＧ（ＵＫ）」、１，３－ブチレングリコール、（株）ダイセル製
グリセリン：商品名「ＰＡＬＭＥＲＡ Ｇ ９０９１」、パームオレオ社製
ＥＤＴＡ－２Ｎａ：エデト酸二ナトリウム
カルボマー：商品名「Ｃａｒｂｏｐｏｌ Ｕｌｔｒｅｚ １０（２％水溶液）」、日本ルーブリゾール（株）製Each component shown in Table 1 is as follows.
[Component (A)]
Diethylene glycol monoethyl ether acetate: trade name "EDGAC", manufactured by Daicel Corporation [Component (B)]
Coconut oil fatty acid PEG-7 glyceryl: trade name “GLYCEROX HE” manufactured by Croda Japan Co., Ltd. Polyglyceryl laurate-10: trade name “PGLE ML10” manufactured by Daicel Corporation [Other components]
BG: trade name “1,3-BG (UK)”, 1,3-butylene glycol, manufactured by Daicel Corporation Glycerin: trade name “PALMERA G 9091” manufactured by Palm Oleo EDTA-2Na: disodium edetate Carbomer: Trade name "Carbopol Ultrez 10 (2% aqueous solution)", manufactured by Lubrizol Japan Co., Ltd.
上記で説明した本発明のバリエーションを以下に付記する。
［１］下記成分（Ａ）を含有することを特徴とする毛髪又は皮膚用洗浄剤組成物。
成分（Ａ）：下記式（Ｉ）で表される化合物
［２］前記成分（Ａ）が、ジエチレングリコールモノメチルエーテルアセテート、ジエチレングリコールモノエチルエーテルアセテート、ジエチレングリコールモノブチルエーテルアセテート、トリエチレングリコールモノメチルエーテルアセテート、トリエチレングリコールモノエチルエーテルアセテート、及びトリエチレングリコールモノブチルエーテルアセテート（好ましくは、ジエチレングリコールモノメチルエーテルアセテート、及びジエチレングリコールモノエチルエーテルアセテート）からなる群より選ばれる少なくとも１種である、上記［１］に記載の洗浄剤組成物。
［３］前記成分（Ａ）が、ジエチレングリコールモノエチルエーテルアセテートを含む、上記［１］又は［２］に記載の洗浄剤組成物。
［４］前記成分（Ａ）の含有量が、洗浄剤組成物全量（１００重量％）に対して０．５～８重量％（好ましくは１～６重量％）である、上記［１］～［３］のいずれか１つに記載の洗浄剤組成物。Variations of the invention described above are appended below.
[1] A hair or skin cleansing composition containing the following component (A).
Component (A): a compound represented by the following formula (I)
[2] The component (A) is diethylene glycol monomethyl ether acetate, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether acetate, triethylene glycol monomethyl ether acetate, triethylene glycol monoethyl ether acetate, and triethylene glycol monobutyl ether acetate (preferably is at least one selected from the group consisting of diethylene glycol monomethyl ether acetate and diethylene glycol monoethyl ether acetate).
[3] The cleaning composition according to [1] or [2] above, wherein the component (A) contains diethylene glycol monoethyl ether acetate.
[4] The content of the component (A) is 0.5 to 8% by weight (preferably 1 to 6% by weight) relative to the total amount (100% by weight) of the cleaning composition [1] to The cleaning composition according to any one of [3].
［５］さらに、下記成分（Ｂ）を含有する、上記［１］～［４］のいずれか１つに記載の洗浄剤組成物。
成分（Ｂ）：ノニオン性界面活性剤
［６］前記成分（Ｂ）が、ＨＬＢ値が１０～１８（好ましくは１２～１６）のノニオン性界面活性剤である、上記［５］に記載の洗浄剤組成物。
［７］前記成分（Ｂ）が、エーテル型ノニオン性界面活性剤、エステル型ノニオン性界面活性剤、及びアミド型ノニオン性界面活性剤からなる群より選ばれる少なくとも１種（好ましくはエステル型ノニオン性界面活性剤）である、上記［５］又は［６］に記載の洗浄剤組成物。
［８］前記成分（Ｂ）が、脂肪酸ポリオキシエチレングリセリル、及び脂肪酸ポリグリセリルからなる群より選ばれる少なくとも１種のノニオン性界面活性剤を含む、上記［５］～［７］のいずれか１つに記載の洗浄剤組成物。
［９］前記脂肪酸ポリオキシエチレングリセリルが、下記式（ＩＩ）で表される化合物である、上記［８］に記載の洗浄剤組成物。
［１０］前記脂肪酸ポリオキシエチレングリセリルが、ヤシ油脂肪酸ＰＯＥグリセリル（好ましくはヤシ油脂肪酸ＰＥＧ－７グリセリル）である、上記［８］又は［９］に記載の洗浄剤組成物。
［１１］前記脂肪酸ポリグリセリルが、下記式（ＩＩＩ）で表される化合物である、上記［８］～［１０］のいずれか１つに記載の洗浄剤組成物。
［１２］前記脂肪酸ポリグリセリルが、ラウリル酸ポリグリセリル（好ましくはラウリル酸デカグリセリル）である、上記［８］～［１１］のいずれか１つに記載の洗浄剤組成物。
［１３］前記成分（Ｂ）の含有量が、洗浄剤組成物全量（１００重量％）に対して０．５～３０重量％（好ましくは２～２０重量％、より好ましくは２～１５重量％）である、上記［５］～［１２］のいずれか１つに記載の洗浄剤組成物。
［１４］前記脂肪酸ポリオキシエチレングリセリルの含有量が、洗浄剤組成物（１００重量％）に対して、０．５～２５重量％（好ましくは２～１５重量％、より好ましくは２～１２重量％）である、上記［８］～［１３］のいずれか１つに記載の洗浄剤組成物。
［１５］前記脂肪酸ポリグリセリルの含有量が、洗浄剤組成物（１００重量％）に対して、０．５～１５重量％（好ましくは２～１０重量％、より好ましくは２～５重量％）である、上記［８］～［１４］のいずれか１つに記載の洗浄剤組成物。
［１６］前記脂肪酸ポリオキシエチレングリセリル及び脂肪酸ポリグリセリルの重量比（脂肪酸ポリオキシエチレングリセリル／脂肪酸ポリグリセリル）が、５０／５０～９５／５（好ましくは６０／４０～９０／１０、より好ましくは６５／３５～８５／１５）である、上記［８］～［１５］のいずれか１つに記載の洗浄剤組成物。[5] The cleaning composition according to any one of [1] to [4] above, further comprising the following component (B).
Component (B): Nonionic surfactant [6] The cleansing product according to [5] above, wherein the component (B) is a nonionic surfactant having an HLB value of 10 to 18 (preferably 12 to 16). agent composition.
[7] The component (B) is at least one selected from the group consisting of ether-type nonionic surfactants, ester-type nonionic surfactants, and amide-type nonionic surfactants (preferably ester-type nonionic surfactant), the cleaning composition according to the above [5] or [6].
[8] Any one of the above [5] to [7], wherein the component (B) contains at least one nonionic surfactant selected from the group consisting of fatty acid polyoxyethylene glyceryl and fatty acid polyglyceryl The cleaning composition according to .
[9] The cleaning composition according to [8] above, wherein the fatty acid polyoxyethylene glyceryl is a compound represented by the following formula (II).
[10] The detergent composition according to [8] or [9] above, wherein the fatty acid polyoxyethylene glyceryl is coconut oil fatty acid POE glyceryl (preferably coconut oil fatty acid PEG-7 glyceryl).
[11] The cleaning composition according to any one of [8] to [10] above, wherein the fatty acid polyglyceryl is a compound represented by the following formula (III).
[12] The cleaning composition according to any one of [8] to [11] above, wherein the fatty acid polyglyceryl is polyglyceryl laurate (preferably decaglyceryl laurate).
[13] The content of component (B) is 0.5 to 30% by weight (preferably 2 to 20% by weight, more preferably 2 to 15% by weight) relative to the total amount (100% by weight) of the detergent composition. ), the cleaning composition according to any one of [5] to [12] above.
[14] The content of the fatty acid polyoxyethylene glyceryl is 0.5 to 25% by weight (preferably 2 to 15% by weight, more preferably 2 to 12% by weight) relative to the detergent composition (100% by weight). %), the cleaning composition according to any one of the above [8] to [13].
[15] The content of the fatty acid polyglyceryl is 0.5 to 15% by weight (preferably 2 to 10% by weight, more preferably 2 to 5% by weight) relative to the detergent composition (100% by weight). The cleaning composition according to any one of [8] to [14] above.
[16] The weight ratio of the fatty acid polyoxyethylene glyceryl and fatty acid polyglyceryl (fatty acid polyoxyethylene glyceryl/fatty acid polyglyceryl) is 50/50 to 95/5 (preferably 60/40 to 90/10, more preferably 65/ 35 to 85/15), the detergent composition according to any one of the above [8] to [15].
［１７］ｐＨ３～１１（好ましくはｐＨ４～１０）である、上記［１］～［１６］のいずれか１つに記載の洗浄剤組成物。
［１８］上記［１］～［１７］のいずれか１つに記載の洗浄剤組成物を含む、クレンジング剤（好ましくはメイクアップ化粧料除去用の洗顔料）。[17] The cleaning composition according to any one of [1] to [16] above, which has a pH of 3 to 11 (preferably a pH of 4 to 10).
[18] A cleansing agent (preferably a face wash for removing make-up cosmetics) containing the cleansing composition according to any one of [1] to [17] above.
本発明の毛髪又は皮膚用洗浄剤組成物は、皮膚洗浄用途（例えば、クレンジング剤、ボディーシャンプー）や毛髪洗浄用途（例えば、ヘアシャンプー）に好適に使用することができる。 The hair or skin cleansing composition of the present invention can be suitably used for skin cleansing (eg, cleansing agent, body shampoo) and hair cleansing (eg, hair shampoo).
Claims (9)
前記成分（Ａ）の含有量が、前記洗浄剤組成物全量（１００重量％）に対して０．５～８重量％である、洗浄剤組成物。
成分（Ａ）：下記式（Ｉ）で表される化合物
A detergent composition, wherein the content of component (A) is 0.5 to 8% by weight with respect to the total amount (100% by weight) of the detergent composition.
Component (A): a compound represented by the following formula (I)
成分（Ｂ）：ノニオン性界面活性剤 The cleaning composition according to Claim 1, further comprising the following component (B).
Component (B): nonionic surfactant
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| JP2018036880 | 2018-03-01 | ||
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| PCT/JP2019/006827 WO2019167837A1 (en) | 2018-03-01 | 2019-02-22 | Detergent composition for hair or skin |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001240851A (en) | 2000-03-01 | 2001-09-04 | Daizo:Kk | Water-in-oil type aerosol product |
| JP2008127278A (en) | 2006-11-16 | 2008-06-05 | Kao Corp | Detergent composition for pet |
| JP2010043050A (en) | 2008-08-18 | 2010-02-25 | Shiseido Co Ltd | Cosmetic suitable for sequential use |
| JP2010070525A (en) | 2008-09-22 | 2010-04-02 | Nippon Fine Chem Co Ltd | Hair cosmetic |
| JP2010120898A (en) | 2008-11-21 | 2010-06-03 | Toyobo Co Ltd | Cosmetic composition |
| JP2010519250A (en) | 2007-03-20 | 2010-06-03 | ザ プロクター アンド ギャンブル カンパニー | Compositions containing amine oxide surfactants or soil penetrants |
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Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001240851A (en) | 2000-03-01 | 2001-09-04 | Daizo:Kk | Water-in-oil type aerosol product |
| JP2008127278A (en) | 2006-11-16 | 2008-06-05 | Kao Corp | Detergent composition for pet |
| JP2010519250A (en) | 2007-03-20 | 2010-06-03 | ザ プロクター アンド ギャンブル カンパニー | Compositions containing amine oxide surfactants or soil penetrants |
| JP2010043050A (en) | 2008-08-18 | 2010-02-25 | Shiseido Co Ltd | Cosmetic suitable for sequential use |
| JP2010070525A (en) | 2008-09-22 | 2010-04-02 | Nippon Fine Chem Co Ltd | Hair cosmetic |
| JP2010120898A (en) | 2008-11-21 | 2010-06-03 | Toyobo Co Ltd | Cosmetic composition |
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| JPWO2019167837A1 (en) | 2021-02-12 |
| TWI803580B (en) | 2023-06-01 |
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