JP2010139547A5 - Image forming method - Google Patents

Image forming method Download PDF

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Publication number
JP2010139547A5
JP2010139547A5 JP2008313215A JP2008313215A JP2010139547A5 JP 2010139547 A5 JP2010139547 A5 JP 2010139547A5 JP 2008313215 A JP2008313215 A JP 2008313215A JP 2008313215 A JP2008313215 A JP 2008313215A JP 2010139547 A5 JP2010139547 A5 JP 2010139547A5
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Prior art keywords
toner
image forming
forming method
fatty acid
metal salt
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JP5517442B2 (en
JP2010139547A (en
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本発明者らは上記課題を解決するべく研究を重ね、トナー担持体及び用いるトナーの摩擦係数を一定のものとすることで課題を解決できることを見出し、発明を完成させた。即ち本発明は、トナー担持体上にトナーの薄層を形成させるための規制部材によりトナー層を形成し、感光体に非接触もしくは接触して現像する前記トナー担持体により前記トナーを現像して感光体上にトナー像を得る画像形成方法であって、
前記トナー担持体の摩擦係数μdが1.35〜2.00であり、
前記トナーが、少なくとも結着樹脂及び着色剤を含有するトナー粒子と、少なくとも無機微粉体を有する一成分現像用トナーであり、
前記トナー担持体上にトナーを形成させた状態における、前記トナーの摩擦係数μtが、0.06〜0.35であることを特徴とする画像形成方法に関する。
The inventors of the present invention have made researches to solve the above problems, and found that the problems can be solved by making the friction coefficient of the toner carrier and the toner to be used constant, thereby completing the invention. The present invention provides a toner layer is formed by the regulating member for forming a thin layer of toner on the toner carrying member, and developing the toner by the toner carrying member for developing a non-contact or contact with the photosensitive member An image forming method for obtaining a toner image on a photoreceptor,
The friction coefficient μd of the toner carrier is 1.35 to 2.00,
The toner has toner particles containing at least a binder resin and a colorant, a toner for one-component development having at least an inorganic fine powder,
The present invention relates to an image forming method, wherein the toner has a friction coefficient μt of 0.06 to 0.35 in a state where a toner layer is formed on the toner carrier.

Claims (9)

トナー担持体上にトナーの薄層を形成させるための規制部材によりトナー層を形成し、感光体に非接触もしくは接触して現像する前記トナー担持体により前記トナーを現像して感光体上にトナー像を得る画像形成方法であって、
前記トナー担持体の摩擦係数μdが1.35〜2.00であり、
前記トナーが、少なくとも結着樹脂及び着色剤を含有するトナー粒子と、少なくとも無機微粉体を有する一成分現像用トナーであり、
前記トナー担持体上にトナーを形成させた状態における、前記トナーの摩擦係数μtが、0.06〜0.35であることを特徴とする画像形成方法。
The toner layer is formed by the regulating member for forming a thin layer of toner on the toner carrying member, the toner on a developing the photosensitive member the toner by the toner carrying member for developing a non-contact or contact with the photosensitive member An image forming method for obtaining an image, comprising:
The friction coefficient μd of the toner carrier is 1.35 to 2.00,
The toner has toner particles containing at least a binder resin and a colorant, a toner for one-component development having at least an inorganic fine powder,
An image forming method, wherein the toner has a friction coefficient μt of 0.06 to 0.35 in a state where a toner layer is formed on the toner carrier.
前記トナーの摩擦係数μtが、0.06〜0.20であることを特徴とする請求項1に記載の画像形成方法。   The image forming method according to claim 1, wherein the toner has a friction coefficient μt of 0.06 to 0.20. 前記トナー粒子が、脂肪酸金属塩を更に含有し、前記脂肪酸金属塩は前記トナー粒子表面に付着しており
前記トナー粒子の個数平均粒径(D1)をDt(μm)、前記脂肪酸金属塩の体積基準のメジアン径(D50)をDf(μm)としたとき、
0.022≦Df/Dt≦0.270
3.00≦Dt≦8.00
0.15≦Df≦1.00
の関係を満たすことを特徴とする請求項1または2に記載の画像形成方法。
The toner particles further contain a fatty acid metal salt , and the fatty acid metal salt adheres to the surface of the toner particles ;
When the number average particle diameter (D1) of the toner particles is Dt (μm) and the volume-based median diameter (D50) of the fatty acid metal salt is Df (μm),
0.022 ≦ Df / Dt ≦ 0.270
3.00 ≦ Dt ≦ 8.00
0.15 ≦ Df ≦ 1.00
The image forming method according to claim 1, wherein the relationship is satisfied.
前記脂肪酸金属塩は、Dfが0.15≦Df≦0.75であり、下記式(1)で定義されるスパン値Bが1.75以下であって、
前記トナーは、トナー中における脂肪酸金属塩の遊離率が1.0%以上30.0%以下であることを特徴とする請求項3に記載の画像形成方法。
スパン値B=(D95s−D5s)/D50s (1)
D5s:脂肪酸金属塩の体積基準における5%積算径
D50s:脂肪酸金属塩の体積基準におけるメジアン径
D95s:脂肪酸金属塩の体積基準における95%積算径
The fatty acid metal salt has a Df of 0.15 ≦ Df ≦ 0.75, a span value B defined by the following formula (1) of 1.75 or less,
4. The image forming method according to claim 3, wherein the toner has a liberation rate of the fatty acid metal salt in the toner of 1.0% or more and 30.0% or less.
Span value B = (D95s−D5s) / D50s (1)
D5s: 5% cumulative diameter based on volume of fatty acid metal salt D50s: Median diameter based on volume of fatty acid metal salt D95s: 95% cumulative diameter based on volume of fatty acid metal salt
前記脂肪酸金属塩がステアリン酸亜鉛またはステアリン酸カルシウムであることを特徴とする請求項3または4に記載の画像形成方法。 Wherein the fatty acid metal salt, an image forming method according to claim 3 or 4, wherein the zinc stearate or calcium stearate. 前記トナーは、トナーに対する微小圧縮試験において、測定するトナーの粒子径をD(μm)、トナーの1粒子に負荷速度9.8×10−5N/secで荷重9.8×10−4Nを負荷したときの最大変位量をX100(μm)、荷重2.0×10−4N負荷時の変位量をX20(μm)としたとき
D1+0.20≧D≧D1−0.20(D1:トナーの個数平均粒径)
0.40≦X100/D≦0.80
0.020≦X20/D≦0.060
を満たすことを特徴とする請求項1〜5のいずれか1項に記載の画像形成方法。
The toner has a particle size of D (μm) to be measured in a minute compression test for the toner, and a load of 9.8 × 10 −4 N / sec at a load speed of 9.8 × 10 −5 N / sec. D1 + 0.20 ≧ D ≧ D1−0.20 where the maximum displacement when X is loaded is X 100 (μm) and the displacement when the load is 2.0 × 10 −4 N is X 20 (μm). D1: Number average particle diameter of toner)
0.40 ≦ X 100 /D≦0.80
0.020 ≦ X 20 /D≦0.060
The image forming method according to any one of claims 1 to 5, characterized in that meet.
前記規制部材が前記トナー担持体に当接しており前記トナー担持体と前記規制部材との当接部における線圧P(nip)[N/m]が10≦P(nip)≦45の条件を満足することを特徴とする請求項1〜6のいずれか1項に記載の画像形成方法。 Wherein and regulating member is brought into contact with the toner carrying member, the condition of the toner linear pressure bearing member and the contact portion between the regulating member P (nip) [N / m ] is 10 ≦ P (nip) ≦ 45 the image forming method according to any one of claims 1 to 6, wherein the benzalkonium be satisfied. 前記規制部材が前記トナー担持体に当接しており前記トナー担持体と前記規制部材との当接部のニップ幅が0.20mm以上1.50mm以下であることを特徴とする請求項1〜7のいずれか1項に記載の画像形成方法。 Wherein and regulating member is brought into contact with the toner carrying member, according to claim 1, the nip width of the abutment portion between the regulating member and the toner carrying member, characterized in der Rukoto than 1.50mm or less 0.20mm the image forming method according to any one of to 7. 前記トナー担持体が芯体の周囲に弾性層および表面層を有し、
前記表面層が樹脂A及びBを含有し、
前記樹脂Aがポリプロピレングリコールまたはポリテトラメチレングリコール骨格からなる熱硬化性ポリエーテルポリウレタン樹脂であり、
前記樹脂Bが、Tgが30℃以上70℃以下、重量平均分子量が30,000以上100,000以下であるアクリル樹脂であるとを特徴とする請求項1〜8のいずれか1項に記載の画像形成方法。
The toner carrier has an elastic layer and a surface layer around the core;
The surface layer contains resins A and B;
The resin A is a thermosetting polyether polyurethane resin comprising a polypropylene glycol or polytetramethylene glycol skeleton,
The resin B is, Tg is 30 ° C. or higher 70 ° C. or less, according to any one of claims 1 to 8, weight average molecular weight is characterized that it is an acrylic resin is 30,000 to 100,000 Image forming method.
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JP2013156430A (en) * 2012-01-30 2013-08-15 Ricoh Co Ltd Toner, and image forming apparatus
JP5915207B2 (en) * 2012-01-31 2016-05-11 株式会社リコー Image forming apparatus and image forming method
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JP6205782B2 (en) * 2013-03-27 2017-10-04 三菱ケミカル株式会社 Image forming apparatus
JP6173137B2 (en) * 2013-09-05 2017-08-02 キヤノン株式会社 toner
JP2017076004A (en) * 2015-10-13 2017-04-20 キヤノン株式会社 Production method of toner
JP6288039B2 (en) * 2015-10-29 2018-03-07 コニカミノルタ株式会社 Toner for electrostatic latent image development
JP2019200330A (en) * 2018-05-17 2019-11-21 花王株式会社 Toner for electrostatic charge image development
JP2020148839A (en) * 2019-03-11 2020-09-17 キヤノン株式会社 Image forming apparatus
WO2023157792A1 (en) * 2022-02-16 2023-08-24 日本ゼオン株式会社 Toner

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