JP2010060731A5 - - Google Patents

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JP2010060731A5
JP2010060731A5 JP2008225089A JP2008225089A JP2010060731A5 JP 2010060731 A5 JP2010060731 A5 JP 2010060731A5 JP 2008225089 A JP2008225089 A JP 2008225089A JP 2008225089 A JP2008225089 A JP 2008225089A JP 2010060731 A5 JP2010060731 A5 JP 2010060731A5
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toner
forming method
image forming
fatty acid
metal salt
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JP2008225089A
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JP2010060731A (en
JP5335334B2 (en
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静電潜像担持体を帯電手段により帯電する帯電工程、該帯電された静電潜像担持体を露光して静電潜像を形成する露光工程、トナー担持体に当接されたトナー層規制部材で該トナー担持体上のトナーを規制するトナー層規制工程、該トナー担持体上のトナーにより該静電潜像を現像する現像工程、及び、現像により形成されたトナー像を中間転写体を介して、又は介さずに転写材へ転写する転写工程を有する画像形成方法において、
該トナー担持体が支持され、非磁性一成分トナー(X)を収容する現像容器に、交換自在な補給トナー容器から非磁性一成分トナー(Y)を補給する補給工程を有し、
該トナー(Y)の凝集度をαとし、該トナー(Y)1.0gと該トナー(Y)を振動篩により開口径53μmのメッシュで6回篩ったトナー4.0gとの混合物の凝集度をβとしたとき、下記(1)及び(2)式を満たし、
30%≦α≦50% (1)式
0.85≦α/β≦1.00 (2)式
かつ、該トナー(X)及び該トナー(Y)は、それぞれトナー粒子と体積基準におけるメジアン径(D50)が0.15μm乃至1.00μmである脂肪酸金属塩とを有することを特徴とする画像形成方法。
A charging step of charging the electrostatic latent image carrier with charging means, an exposure step of exposing the charged electrostatic latent image carrier to form an electrostatic latent image, and regulation of a toner layer in contact with the toner carrier A toner layer regulating step for regulating the toner on the toner carrying member with a member, a developing step for developing the electrostatic latent image with the toner on the toner carrying member, and a toner image formed by development on the intermediate transfer member In an image forming method having a transfer step of transferring to a transfer material via or without,
A replenishment step of replenishing the nonmagnetic monocomponent toner (Y) from the replaceable replenishment toner container to the developer container that supports the toner carrier and contains the nonmagnetic monocomponent toner (X);
Aggregation degree of the toner (Y) is α, and agglomeration of a mixture of 1.0 g of the toner (Y) and 4.0 g of toner obtained by sieving the toner (Y) 6 times with a mesh having an opening diameter of 53 μm using a vibrating sieve When the degree is β, the following formulas (1) and (2) are satisfied,
30% ≦ α ≦ 50% ( 1) formula 0.85 ≦ α / β ≦ 1.00 ( 2) and formula, the toner (X) and the toner (Y) are respectively the toner particles, the median volume-based And a fatty acid metal salt having a diameter (D50) of 0.15 to 1.00 μm.
該脂肪酸金属塩は下記(3)式で定義されるスパン値Bが1.75以下であることを特徴とする請求項1に記載の画像形成方法。
スパン値B=(D95s−D5s)/D50s (3)式
D5s:脂肪酸金属塩の体積基準における5%積算径
D50s:脂肪酸金属塩の体積基準におけるメジアン径(D50)
D95s:脂肪酸金属塩の体積基準における95%積算径
The fatty acid metal salt, an image forming method according to claim 1, span value B defined by the following equation (3) is characterized in that 1.75 or less.
Span value B = (D95s−D5s) / D50s (3) Formula D5s: 5% integrated diameter based on volume of fatty acid metal salt D50s: median diameter based on volume of fatty acid metal salt (D50)
D95s: 95% integrated diameter of fatty acid metal salt based on volume
該トナー層規制部材が、該トナー担持体との当接部にポリアミドまたはポリエステルのエラストマー層を有することを特徴とする請求項1または2に記載の画像形成方法。 The toner layer regulating member, an image forming method according to claim 1 or 2, characterized in that it has an elastomeric layer of polyamide or polyester Le to the contact portion between the toner carrying member. 該エラストマー層のショアーD硬度をγ°、該トナーの微小圧縮試験における、25℃での負荷速度9.8×10-5N/secで2.9×10-4Nの荷重をトナーにかけてから除荷するまでの変位曲線において、除荷して戻る変位と最大変位の比(復元率)をZ(25)としたとき、
25≦γ≦75
0.4≦γ/Z(25)≦2.0
であることを特徴とする請求項3に記載の画像形成方法。
The Shore D hardness of the elastomer layer is γ ( ° ) , and a load of 2.9 × 10 −4 N at a load speed of 9.8 × 10 −5 N / sec at 25 ° C. in the toner micro compression test is applied to the toner. In the displacement curve from unloading to unloading, when the ratio (restoration rate) of the unloading return and the maximum displacement is Z (25),
25 ≦ γ ≦ 75
0.4 ≦ γ / Z (25) ≦ 2.0
The image forming method according to claim 3, wherein:
該脂肪酸金属塩の体積基準におけるメジアン径(D50)が0.15μm乃至0.75μmであることを特徴とする請求項1乃至4のいずれかに記載する画像形成方法。 The image forming method median diameter in the volume-based of the fatty acid metal salt (D50) is, as described in any one of claims 1 to 4, characterized in that a 0.15μm to 0.75 .mu.m. 該脂肪酸金属塩の体積基準におけるメジアン径(D50)が0.30μm乃至0.60μmであり、スパン値Bが1.50以下であることを特徴とする請求項1乃至5のいずれかに記載する画像形成方法。 Median diameter in volume-based of the fatty acid metal salt (D50) is a 0.30μm to 0.60 .mu.m, in any one of claims 1 to 5 wherein the span value B is characterized in that 1.50 or less An image forming method to be described. 該脂肪酸金属塩が脂肪酸亜鉛または脂肪酸カルシウムであることを特徴とする請求項1乃至6のいずれかに記載の画像形成方法。 7. The image forming method according to claim 1 , wherein the fatty acid metal salt is fatty acid zinc or fatty acid calcium. 該トナーはシリカとハイドロタルサイトを有することを特徴とする請求項1乃至7のいずれかに記載の画像形成方法。 The image forming method according to claim 1 , wherein the toner includes silica and hydrotalcite. 該トナー中の該シリカの含有量をA質量部と該ハイドロタルサイトの含有量をB質量部とした時に5.0≦A/B≦30.0であることを特徴とする請求項1乃至8のいずれかに記載の画像形成方法。 The content of the silica in the toner when the content of A parts by weight and the hydrotalcite and B parts by weight, claim 1, characterized in that a 5.0 ≦ A / B ≦ 30.0 The image forming method according to any one of 1 to 8. 該トナーの平均円形度が0.970乃至0.995であることを特徴とする請求項1乃至9のいずれかに記載の画像形成方法。   10. The image forming method according to claim 1, wherein an average circularity of the toner is 0.970 to 0.995. 該トナーは、下記構造式(1)または(2)に示されるエーテル結合を有する化合物が含有されていることを特徴とする請求項1乃至10のいずれか記載の画像形成方法。
Figure 2010060731
〔式中、R 1 乃至R 11 は、炭素数1乃至6までのアルキル基であり、互いに同じであっても、異なっていても良い。〕
The image forming method according to claim 1, wherein the toner contains a compound having an ether bond represented by the following structural formula (1) or (2) .
Figure 2010060731
[Wherein R 1 to R 11 are alkyl groups having 1 to 6 carbon atoms and may be the same or different from each other. ]
該トナーの重量平均粒径(D4)が5μm以上8μm以下であり、かつ該トナーの個数基準の粒度分布における4.00μm以下の粒子の割合が3個数%以上30個数%以下であることを特徴とする請求項1乃至11のいずれかの画像形成方法。 The toner has a weight average particle size (D4) of 5 μm or more and 8 μm or less, and a ratio of particles of 4.00 μm or less in a particle size distribution based on the number of the toner is 3% by number or more and 30% by number or less. Izu Re the image forming method according to claim 1 to 11,.
JP2008225089A 2008-09-02 2008-09-02 Image forming method Active JP5335334B2 (en)

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JP2010060731A5 true JP2010060731A5 (en) 2011-10-20
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7199828B2 (en) 2017-05-15 2023-01-06 キヤノン株式会社 toner

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JP6911346B2 (en) * 2016-12-21 2021-07-28 株式会社リコー Image forming device, image forming method, and toner accommodating unit
JP7250486B2 (en) * 2018-11-14 2023-04-03 キヤノン株式会社 Process cartridge and image forming apparatus
JP7301637B2 (en) 2019-07-02 2023-07-03 キヤノン株式会社 toner

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JP3605983B2 (en) * 1997-02-06 2004-12-22 三菱化学株式会社 Negatively chargeable one-component developer and image forming method using the same
JP2003207923A (en) * 2002-01-15 2003-07-25 Canon Inc Image forming method
JP2004326049A (en) * 2003-04-30 2004-11-18 Kyocera Chemical Corp Nonmagnetic toner for development
JP2006301091A (en) * 2005-04-18 2006-11-02 Canon Inc Image forming method and developing device
JP2006301309A (en) * 2005-04-21 2006-11-02 Canon Inc Color image forming method
JP2008009249A (en) * 2006-06-30 2008-01-17 Canon Inc Nonmagnetic monocomponent developing toner
JP5074755B2 (en) * 2006-12-13 2012-11-14 キヤノン株式会社 toner

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7199828B2 (en) 2017-05-15 2023-01-06 キヤノン株式会社 toner

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