JP2010126456A - Wood preservation composition - Google Patents
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- JP2010126456A JP2010126456A JP2008300332A JP2008300332A JP2010126456A JP 2010126456 A JP2010126456 A JP 2010126456A JP 2008300332 A JP2008300332 A JP 2008300332A JP 2008300332 A JP2008300332 A JP 2008300332A JP 2010126456 A JP2010126456 A JP 2010126456A
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- 239000002023 wood Substances 0.000 title claims abstract description 34
- 239000000203 mixture Substances 0.000 title claims abstract description 17
- 238000004321 preservation Methods 0.000 title claims abstract description 12
- 150000001875 compounds Chemical class 0.000 claims abstract description 15
- -1 sulfamide compound Chemical class 0.000 claims abstract description 8
- 239000004202 carbamide Substances 0.000 claims abstract description 6
- 150000002497 iodine compounds Chemical class 0.000 claims abstract description 6
- NVBFHJWHLNUMCV-UHFFFAOYSA-N sulfamide Chemical compound NS(N)(=O)=O NVBFHJWHLNUMCV-UHFFFAOYSA-N 0.000 claims description 6
- XMTQQYYKAHVGBJ-UHFFFAOYSA-N 3-(3,4-DICHLOROPHENYL)-1,1-DIMETHYLUREA Chemical compound CN(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 XMTQQYYKAHVGBJ-UHFFFAOYSA-N 0.000 claims description 5
- 229940099451 3-iodo-2-propynylbutylcarbamate Drugs 0.000 claims description 3
- WYVVKGNFXHOCQV-UHFFFAOYSA-N 3-iodoprop-2-yn-1-yl butylcarbamate Chemical compound CCCCNC(=O)OCC#CI WYVVKGNFXHOCQV-UHFFFAOYSA-N 0.000 claims description 3
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- 229910052740 iodine Inorganic materials 0.000 claims description 3
- 239000011630 iodine Substances 0.000 claims description 3
- 239000004480 active ingredient Substances 0.000 claims description 2
- 241000233866 Fungi Species 0.000 abstract description 22
- 238000002845 discoloration Methods 0.000 abstract description 7
- 239000003814 drug Substances 0.000 abstract description 7
- 229940079593 drug Drugs 0.000 abstract description 7
- 238000002360 preparation method Methods 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 244000005700 microbiome Species 0.000 abstract description 2
- 229940121375 antifungal agent Drugs 0.000 description 7
- 230000000843 anti-fungal effect Effects 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000002609 medium Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 3
- 235000011613 Pinus brutia Nutrition 0.000 description 3
- 241000018646 Pinus brutia Species 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000001965 potato dextrose agar Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- XKJMBINCVNINCA-UHFFFAOYSA-N Alfalone Chemical compound CON(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 XKJMBINCVNINCA-UHFFFAOYSA-N 0.000 description 2
- OFSLKOLYLQSJPB-UHFFFAOYSA-N Cyclosulfamuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)NC=2C(=CC=CC=2)C(=O)C2CC2)=N1 OFSLKOLYLQSJPB-UHFFFAOYSA-N 0.000 description 2
- 239000005510 Diuron Substances 0.000 description 2
- UWVKRNOCDUPIDM-UHFFFAOYSA-N Ethoxysulfuron Chemical compound CCOC1=CC=CC=C1OS(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 UWVKRNOCDUPIDM-UHFFFAOYSA-N 0.000 description 2
- 240000000731 Fagus sylvatica Species 0.000 description 2
- 235000010099 Fagus sylvatica Nutrition 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 230000000855 fungicidal effect Effects 0.000 description 2
- 239000001963 growth medium Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 239000002798 polar solvent Substances 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- CEPZWWNWJNBTIM-UHFFFAOYSA-N (3-bromo-2,3-diiodoprop-2-enyl) ethyl carbonate Chemical compound CCOC(=O)OCC(I)=C(Br)I CEPZWWNWJNBTIM-UHFFFAOYSA-N 0.000 description 1
- 229940057054 1,3-dimethylurea Drugs 0.000 description 1
- HFOCAQPWSXBFFN-UHFFFAOYSA-N 2-methylsulfonylbenzaldehyde Chemical compound CS(=O)(=O)C1=CC=CC=C1C=O HFOCAQPWSXBFFN-UHFFFAOYSA-N 0.000 description 1
- NXXBCDHYUFWPFQ-UHFFFAOYSA-N 2-tert-butyl-1,3,4-thiadiazole Chemical compound CC(C)(C)C1=NN=CS1 NXXBCDHYUFWPFQ-UHFFFAOYSA-N 0.000 description 1
- 241000228245 Aspergillus niger Species 0.000 description 1
- 241000223678 Aureobasidium pullulans Species 0.000 description 1
- 241000221198 Basidiomycota Species 0.000 description 1
- 241000218645 Cedrus Species 0.000 description 1
- 241001285607 Ceratocystis sp. Species 0.000 description 1
- 241001149955 Cladosporium cladosporioides Species 0.000 description 1
- VYNOULHXXDFBLU-UHFFFAOYSA-N Cumyluron Chemical compound C=1C=CC=CC=1C(C)(C)NC(=O)NCC1=CC=CC=C1Cl VYNOULHXXDFBLU-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 241001105467 Fomitopsis palustris Species 0.000 description 1
- JLLJHQLUZAKJFH-UHFFFAOYSA-N Isouron Chemical compound CN(C)C(=O)NC=1C=C(C(C)(C)C)ON=1 JLLJHQLUZAKJFH-UHFFFAOYSA-N 0.000 description 1
- 239000005573 Linuron Substances 0.000 description 1
- 241000088436 Neurospora sp. Species 0.000 description 1
- 241001136494 Talaromyces funiculosus Species 0.000 description 1
- HBPDKDSFLXWOAE-UHFFFAOYSA-N Tebuthiuron Chemical compound CNC(=O)N(C)C1=NN=C(C(C)(C)C)S1 HBPDKDSFLXWOAE-UHFFFAOYSA-N 0.000 description 1
- 241000222355 Trametes versicolor Species 0.000 description 1
- 241001149558 Trichoderma virens Species 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- MAHPNPYYQAIOJN-UHFFFAOYSA-N azimsulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2N(N=CC=2C2=NN(C)N=N2)C)=N1 MAHPNPYYQAIOJN-UHFFFAOYSA-N 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000012258 culturing Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000009036 growth inhibition Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000008268 mayonnaise Substances 0.000 description 1
- 235000010746 mayonnaise Nutrition 0.000 description 1
- 239000012454 non-polar solvent Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 239000003171 wood protecting agent Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
Description
本発明は、木材に発生するカビ、変色菌、腐朽菌を防ぐために用いられる木材防保存組成物に関するものである。 The present invention relates to a wood-preserving composition used for preventing mold, discoloration, and decaying fungi that occur on wood.
安全性の高い木材防保存剤の開発が盛んに行われるようになり、ヨウ素系化合物やスルファミド系化合物は、木材におけるカビの発生を防止するために添加されることが多い。しかしながらこれらのみの単一成分の使用では、効力を有する微生物の種が限られるのと薬剤の効果が悪くなってきているという理由で十分な効力が得られず、薬剤の使用量が増え、コストも高くなることが多い。このため各種防カビ剤を組み合わせ、防カビスペクトルの安定化や防カビ効力の増強などが試みられているが、通常はいずれか一方の効果の発現に留まるか、相加的な効果しか得られないのが実情である。例えば特開平2−164803号には、ヨウ素系化合物とベンズイミダゾール系化合物を合剤にする方法が提案されている。さらに特開平7−133205号にはヨウ素系化合物とイソチアゾリン系化合物を合剤にする方法が提案されている。しかしながら、木材上に発生する真菌はカビの他、変色菌、腐朽菌も問題であり、これらに対しても効果をもった更なる広い抗菌スペクトルの薬剤が望まれていた。
本発明は、木材に対して飛躍的に防カビ効力が増大し、かつ、変色菌、腐朽菌にも発育抑制があることを目的とする。 The object of the present invention is to dramatically increase the fungicidal effect on wood and to suppress the growth of discolored and decaying fungi.
本発明者は、前記効力不足を補う木材防カビ防変色菌組成物に関し、鋭意研究を重ねた結果、有効成分としてヨウ素系化合物またはスルファミド系化合物から選ばれる少なくとも1種の化合物と尿素系化合物を組み合わせた場合、それぞれ単独で用いた場合と比較して飛躍的に防カビ効力が増大し、かつ、変色菌、腐朽菌にも発育抑制があることを見出した。 As a result of intensive research on the antifungal and antifungal discoloration fungi composition that compensates for the above lack of efficacy, the present inventor has obtained at least one compound selected from iodine compounds or sulfamide compounds and a urea compound as an active ingredient. When combined, it was found that the fungicidal efficacy increased dramatically compared to the case where each was used alone, and that the discoloration and decaying fungi also had growth inhibition.
本発明の組成物を用いることにより、カビ、変色菌、腐朽菌から木材を保護することができる。 By using the composition of the present invention, wood can be protected from mold, discoloration bacteria, and decaying fungi.
尿素系化合物としては、3−(3,4−ジクロロフェニル)−1,1−ジメチル尿素(一般名:ジウロン)、3−(3,4−ジクロロフェニル)−1−メトキシ−1−メチル尿素(一般名:リニュロン)、3−(5−タ−シャリ−ブチル−3−イソオキサゾル)−1、1−ジメチル尿素、(イソウロン)、1−(α,α−ジメチルベンジル)−3−(パラトリル)尿素(一般名:ダイムロン)、1−(2−クロロベンジル)−3−(1−メチル−1−フェニルエチル)尿素(一般名:クミルロン)、1−(5−tert−ブチル−1,3,4−チアジアゾール−2−イル)−1,3−ジメチル尿素(一般名:テブチウロン)、4,6−ジメトキシ−1,3,5−トリアジン−2−イル)−3−[2−(2−メトキシエトキシ)フェニルスルホニル]尿素(一般名:シノスルフロン)、1−(4,6−ジメトキシピリミジン−2−イル)−3−(2−エトキシフェノキシスルホニル)尿素(一般名:エトキシスルフロン)、1−[2−(シクロプロピルカルボニル)アニリノスルホニル]−3−(4,6−ジメトキシピリミジン−2−イル)尿素(一般名:シクロスルファムロン)、1−(4,6−ジメトキシピリミジン−2−イル)−3−[1−メチル−4−(2−メチル−2H−テトラゾール−5−イル)ピラゾール−5−イルスルホニル]尿素(一般名:アジムスルフロン)などが挙げられるが、特に3−(3,4−ジクロロフェニル)−1,1−ジメチル尿素(一般名:ジウロン)が好ましい。 As urea compounds, 3- (3,4-dichlorophenyl) -1,1-dimethylurea (generic name: diuron), 3- (3,4-dichlorophenyl) -1-methoxy-1-methylurea (generic name) : Linuron), 3- (5-tert-butyl-3-isoxazole) -1,1-dimethylurea, (isouron), 1- (α, α-dimethylbenzyl) -3- (paratolyl) urea (general Name: Daimlone), 1- (2-Chlorobenzyl) -3- (1-methyl-1-phenylethyl) urea (generic name: cumylron), 1- (5-tert-butyl-1,3,4-thiadiazole) -2-yl) -1,3-dimethylurea (generic name: tebuthiuron), 4,6-dimethoxy-1,3,5-triazin-2-yl) -3- [2- (2-methoxyethoxy) phenyl Sulfoni L] urea (generic name: sinosulfuron), 1- (4,6-dimethoxypyrimidin-2-yl) -3- (2-ethoxyphenoxysulfonyl) urea (generic name: ethoxysulfuron), 1- [2- ( Cyclopropylcarbonyl) anilinosulfonyl] -3- (4,6-dimethoxypyrimidin-2-yl) urea (generic name: cyclosulfamuron), 1- (4,6-dimethoxypyrimidin-2-yl) -3 -[1-Methyl-4- (2-methyl-2H-tetrazol-5-yl) pyrazol-5-ylsulfonyl] urea (generic name: azimusulfuron) and the like can be mentioned, and in particular, 3- (3,4- Dichlorophenyl) -1,1-dimethylurea (generic name: diuron) is preferred.
ヨウ素系化合物としては、3−ヨード−2−プロピニルブチルカーバメート、p−クロロフェニル−1−3−ヨードプロパギルフォルマール、1−ブロモ−3−エトキシカルボニルオキシ−1,2−ジヨード−1−プロペン、ポリビニルピロリドンヨウ素、ジヨードメチル−p−トリルスルフォンなどが挙げられるが、特に3−ヨード−2−プロピニルブチルカーバメートが好ましい。 Examples of iodine compounds include 3-iodo-2-propynylbutyl carbamate, p-chlorophenyl-1-3-iodopropargyl formal, 1-bromo-3-ethoxycarbonyloxy-1,2-diiodo-1-propene, Polyvinylpyrrolidone iodine, diiodomethyl-p-tolylsulfone and the like can be mentioned, and 3-iodo-2-propynylbutyl carbamate is particularly preferable.
スルファミド系化合物としては、N,N−ジメチル−N`−(フルオロジクロロメチルチオ)−N``−フェニルスルファミド(一般名:ジクロフルアニド)、N−ジクロロフルオロメチルチオ−N`,N`−ジメチル−N−p−トリルスルファミド(一般名:トリフルアニド)などが挙げられるが、特にN,N−ジメチル−N`−(フルオロジクロロメチルチオ)−N``−フェニルスルファミドが好ましい。 Examples of the sulfamide-based compound include N, N-dimethyl-N `-(fluorodichloromethylthio) -N ` `-phenylsulfamide (generic name: dichlorofluoride), N-dichlorofluoromethylthio-N `, N`- Examples thereof include dimethyl-Np-tolylsulfamide (generic name: trifluanide), and N, N-dimethyl-N `-(fluorodichloromethylthio) -N ` `-phenylsulfamide is particularly preferable.
本発明の木材保存組成物は木材に直接塗布するだけでなく、浸漬、加圧注入などの処理方法によっても使用することができる。また、木材用の塗料、撥水剤、ホリマリンキャッチャー剤や木質材料の接着剤などに添加しても良い。 The wood preservation composition of the present invention can be used not only directly on wood but also by a treatment method such as dipping or pressure injection. Further, it may be added to a paint for wood, a water repellent, a horimarin catcher agent, an adhesive for a wood material, or the like.
本発明の木材保存組成物は使用目的に応じて直接適用することもできるが、一般的には油剤、乳剤、ペースト剤、懸濁剤などの剤型として使用する。製剤化する場合に用いる極性溶媒は、単独で用いても良いし、2種以上を組み合わせても良い。また、極性溶媒と非極性溶媒を2種以上組み合わせてもよい。界面活性剤は使用しても使用しなくてもよく、使用する場合は、非イオン界面活性剤、陰イオン界面活性剤、陽イオン界面活性剤、両イオン界面活性剤のいずれを用いてもかまわない。また他の防カビ剤、殺菌剤、殺虫剤、防錆剤、劣化防止剤などを配合して使用することも可能である。 Although the wood preservation composition of the present invention can be directly applied according to the purpose of use, it is generally used as a dosage form such as an oil, emulsion, paste, suspension or the like. The polar solvent used in formulating may be used alone or in combination of two or more. Two or more polar solvents and nonpolar solvents may be combined. Surfactants may or may not be used. When they are used, any of nonionic surfactants, anionic surfactants, cationic surfactants, and amphoteric surfactants may be used. Absent. In addition, other fungicides, bactericides, insecticides, rust inhibitors, deterioration inhibitors and the like can be used in combination.
次に実施例により、さらに詳細に説明するが、本発明はこれらによって限定されるものではない。 EXAMPLES Next, although an Example demonstrates in detail, this invention is not limited by these.
実施例1〜16、比較例1〜8の木材保存組成物を表1に示す。直径1mmのガラスビーズと混合し約15分間粉砕し、金網でろ別することによって防カビ防変色菌分散組成物を得た。分散剤には、ニューカルゲンFS-26(竹本油脂株会社製)、増粘剤にはケルザンS(ケルコ社製)を用いた。 Table 1 shows the wood preservation compositions of Examples 1 to 16 and Comparative Examples 1 to 8. The mixture was mixed with glass beads having a diameter of 1 mm, pulverized for about 15 minutes, and filtered through a wire mesh to obtain a fungus-proof and anti-color-change fungus dispersion composition. Neukalgen FS-26 (manufactured by Takemoto Yushi Co., Ltd.) was used as the dispersant, and Kelzan S (manufactured by Kelco) was used as the thickener.
(試験例1 木材の防カビ試験)
水で規定濃度となるように希釈した実施例及び比較例の木材用防カビ防変色菌組成物の溶液中にベイマツ辺材(2cm×5cm×0.3cm)を30秒浸漬した後風乾する。この試験片をポテトデキストロース寒天培地(以下、PDA培地とする)上に載せ、カビの混合胞子懸濁液1mlをふりかけて温度26℃、湿度95%で28日間培養した。カビ生育の程度の表示は表2の判定基準により行った。結果を表3に示す。
供試菌
Aspergillus niger
Penicillium funiculosum
Aureobasidium pullulans
Gliocladium virens
Cladosporium cladosporioides
Neurospora sp.
(Test Example 1 Wood mold prevention test)
A pine sapwood (2 cm × 5 cm × 0.3 cm) is dipped in the solution of the antifungal discoloration-proofing fungus composition for wood of Examples and Comparative Examples diluted to a specified concentration with water, and then air-dried. This test piece was placed on a potato dextrose agar medium (hereinafter referred to as PDA medium), sprinkled with 1 ml of a mixed spore suspension and cultured at 26 ° C. and 95% humidity for 28 days. The degree of mold growth was displayed according to the criteria shown in Table 2. The results are shown in Table 3.
Test bacteria
Aspergillus niger
Penicillium funiculosum
Aureobasidium pullulans
Gliocladium virens
Cladosporium cladosporioides
Neurospora sp.
(試験例2 木材の防変色菌試験)
シャーレにPDA培地を固化させた上にエチレンオキサイドガス滅菌された無処理のベイマツ(餌木)を置く。これに木材変色菌Ceratocystis sp.の胞子懸濁液2mlを滴下し、26℃、相対湿度90%で2週間前培養した。一方、試験片は水で規定濃度となるように希釈した実施例及び比較例の木材用防カビ防変色菌組成物の溶液中にベイマツ辺材(2cm×5cm×0.3cm)を30秒浸漬した後風乾する。前培養後、菌が生育した餌木の上に薬剤処理された試験体を載せ、26℃、相対湿度90%で28日間培養した変色菌生育の程度の表示は表2の判定基準により行った。結果を表3に示す。
(Test Example 2 Anti-discoloring fungus test on wood)
A PDA medium is solidified in a petri dish and an untreated bay pine (bait tree) sterilized with ethylene oxide gas is placed. In addition to this, the wood-discoloring bacterium Ceratocystis sp. 2 ml of the spore suspension was added dropwise and pre-cultured at 26 ° C. and 90% relative humidity for 2 weeks. On the other hand, the pine sapwood (2 cm × 5 cm × 0.3 cm) was immersed for 30 seconds in the solutions of the antifungal discoloration-proofing fungus composition for wood of Examples and Comparative Examples diluted to a specified concentration with water. And then air dry. After the pre-culture, the test specimen treated with the drug was placed on the prey where the fungus grew and cultured for 28 days at 26 ° C. and 90% relative humidity. . The results are shown in Table 3.
(試験例3 木材の防腐試験)
試験は社団法人日本木材保存協会の表面処理用木材防腐剤の室内防腐試験方法及び性能基準(JWPS−FW−S.1)に従って下記の通り実施した。供試菌オオウズラタケ Fomitopsis palustris 褐色腐朽菌
カワラタケ Trametes versicolor 白色腐朽菌
(Test Example 3 Wood Preservation Test)
The test was conducted as follows according to the indoor preservative test method and performance standard (JWPS-FW-S.1) of the wood preservative for surface treatment of the Japan Wood Preservation Association. Test fungus Oozuratake Fomitopsis palustris brown rot fungus Kawaratake Trametes versicolor white rot fungus
<供試培地の調製>
900mlのマヨネーズ瓶に海砂350gを入れ、下記培養液を100 ml加え殺菌した後、あらかじめ上記担子菌を別々に十分に生育させたブナの小木材片1枚を無菌的に入れ、温度26±2℃、相対湿度70%以上のところで10日〜15日間培養し、菌そうが培養基に十分広がったものを供試培地とした。
<Preparation of test medium>
After putting 350 g of sea sand in a 900 ml mayonnaise bottle and adding 100 ml of the following culture solution to sterilize, aseptically put one small piece of beech wood in which the above basidiomycetes were sufficiently grown separately in advance, temperature 26 ± The culture medium was cultured at 2 ° C. and a relative humidity of 70% or more for 10 to 15 days, and the fungus was sufficiently spread on the culture medium to serve as a test medium.
<供試試料調製>
実施例1、5、11及び比較例1、5、7を規定濃度に希釈した薬液薬液を、木口面をエポキシ樹脂でシールした20mm×40mm、厚さ5mmのスギ及びブナ木材片に110±10g/m2になるように塗布した。20日間以上室温で放置した後、以下の耐候操作を実施した。
<Sample preparation>
110 ± 10 g of a chemical solution obtained by diluting Examples 1, 5, 11 and Comparative Examples 1, 5, 7 to a prescribed concentration on a cedar and beech wood piece having a thickness of 20 mm × 40 mm and a thickness of 5 mm, with the end of which is sealed with epoxy resin / M 2 was applied. After leaving at room temperature for 20 days or more, the following weather resistance operation was performed.
<耐候操作>
薬液を処理した各木材片を9個1組として500ml容量のビーカーにいれ、その中に木材片容積の10倍のイオン交換水(360ml)を注ぎ、木材片が浮かび上がらないように適当なおもりを載せ水面下に沈めた後、水温25±3℃で5時間溶脱させ、続いて19時間40±2℃で乾燥させた。以上の操作を交互に10回繰り返した。耐候操作が終わった後、温度60±2℃で48時間乾燥させ、30分間デシケーター内に放置した試料の質量を測定した。
<Weatherproof operation>
Nine pieces of wood treated with chemicals are placed in a 500 ml capacity beaker as a set, and ion-exchanged water (360 ml) 10 times the volume of the wood pieces is poured into the beaker, and appropriate weights are applied to prevent the wood pieces from floating. After being submerged under the surface of the water, it was leached at a water temperature of 25 ± 3 ° C. for 5 hours and subsequently dried at 40 ± 2 ° C. for 19 hours. The above operation was repeated 10 times alternately. After the weathering operation was completed, the sample was dried at a temperature of 60 ± 2 ° C. for 48 hours, and the mass of the sample left in a desiccator for 30 minutes was measured.
<試験方法>
耐候操作を行った試料を3個ずつ、カワラタケは直接、オオウズラタケは殺菌したプラスチックの網を置きその上に、いずれも繊維方向を垂直に載せ、温度26±2℃、相対湿度70%以上のところに12週間培養した。
培養後、菌糸等の分着物を取り除いた木材片を温度60±2℃で48時間乾燥させ、30分間デシケーター内に放置し試料の質量を測定した。あらかじめ測定しておいた耐候操作直後の重量と比較し次式によって質量減少率を求めた。試験結果を表4に示す。
質量減少率(%)=(耐候操作直後の質量−12週間培養後の質量)/耐候操作直後の質量×100
<Test method>
Three samples were subjected to weathering, Kawaratake was placed directly, and Ozuratake was placed on a sterilized plastic net on which the fiber direction was placed vertically, where the temperature was 26 ± 2 ° C and relative humidity was 70% or more. For 12 weeks.
After the cultivation, the wood pieces from which the attachments such as mycelia were removed were dried at a temperature of 60 ± 2 ° C. for 48 hours and left in a desiccator for 30 minutes to measure the mass of the sample. Compared with the weight immediately after the weathering operation, which was measured in advance, the mass reduction rate was determined by the following formula. The test results are shown in Table 4.
Mass reduction rate (%) = (mass immediately after weathering operation−mass after culturing for 12 weeks) / mass immediately after weathering operation × 100
ヨウ素系化合物またはスルファミド系化合物から選ばれる少なくとも1種の化合物と尿素系化合物を組み合わせた製剤を用いることにより木材のカビ、変色及び腐朽の発育を防止し、木材保存分野に利用できる。 By using a preparation comprising a combination of at least one compound selected from iodine-based compounds or sulfamide-based compounds and a urea-based compound, growth of mold, discoloration and decay of wood can be prevented, and it can be used in the field of wood preservation.
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JP2011121901A (en) * | 2009-12-11 | 2011-06-23 | Sumika Enviro-Science Co Ltd | Wood preservation composition |
EP2926659A1 (en) | 2014-04-04 | 2015-10-07 | LANXESS Deutschland GmbH | Biocidal agent |
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