JPH09510156A - Combination of active insecticide substances - Google Patents

Abstract

  (57) [Summary] Novel active pesticide substances consisting of known active substances on the one hand, triflumuron and, on the other hand, other known active substances are very useful for protecting industrial materials.

Description

Detailed description of the invention Combinations of active pesticide substances The present application consists of novel active agent combinations (triflumuron on the one hand and other known active compounds on the other hand and which are highly suitable for the protection of industrial materials ( ac active combinations). It is known that triflumuron has insecticidal properties. Furthermore, it is known that triflumuron can be used as an active compound against wood-destroying insects [Holz-Zentralblatt. 34 524 (1984)]. However, wood protection must meet requirements beyond mere insecticidal activity. Thus, wood-damaging insects, especially wood-destructive longhorn beetles containing termites [Cerambyci dae, Lyctidae, Bastrychi dae and Anobiide wood and anobiide], and anobiidea (Anoidea). And highly effective against wood-destroying fungi, and has a good long-term action, wherein the activity of the insecticide is not adversely affected by the fungicide, and It was a goal and objective of the present invention to find a wood protectant that is also the reverse. In addition, the wood protection should have good permeation behavior for wood and derived timber products and have a significantly lower vapor pressure compared to conventional pyrethroids. According to the present invention, these aims and objectives are 0.1-99.9% by weight of at least one fungicidal agent and preferably 40% by weight or more of solvent and / or diluent and / or organic chemical bond. Wood and derived timber products consisting of 0.01 to 25% by weight of triflumuron in admixture with agents and / or fixatives, processing aids, colorants, pigments, coloring mixtures and / or mixtures of pigment mixtures Filled with protective composition or thickener. Preferred fungicides as ingredients in the mixture are: Triazoles eg: Amitrole, Azone Crotin, BAS 480F, Vitertanol, Bifenoconazole, Fenbuconazole, Fenchlorazole, Phenetanyl, Fluquinconazole, Flucirazole, Flutriafol, imibenconazole, isazaphos, microbutanyl, ops, paclobutrazol, penconazole, propioconazole, (±) -cis-1- (4-chlorophenyl) -2- (1H-1,2,4- Triazol-1-yl) -cycloheptanol, tetraconazole, triadimefon, triadimenol, triapentenol, triflumizole, uniconazole, hexaconazole; azaconazole: 1-{[2- (2,4 -Dichlorophenyl) -1,3-dio Solan-2-yl] methyl} 1-H-1,2,4-triazole, propiconazole: 1- [2- (2,4-dichlorophenyl) -4-propyl-1,3-dioxolane-2 -Yl] methyl-1-H-1,2,4-triazole, tebuconazole: 1-p-chlorophenyl-4,4-dimethyl-3 (1H-1,2,4-triazol-1-yl-methyl) pentane -3-ol, cyproconazole: 2- (4-chlorophenyl) -3-cyclopropyl-1- (1H-1,2,4-triazol-1-yl) butan-2-ol, 2- (1- Chloro-cyclopropyl) -1- (2-chlorophenyl) -3- (1H-1,2,4-triazol-1-yl) -propan-2-ol, 2- (t-butyl) -1- (2 -Chlorophenyl) -3- (1H-1,2,4-triazol-1-yl) propan-2-ol metconazole: 5-[(4-chlorophenyl) methyl]- 2,2-Dimethyl-1- (1H-1,2,4-triazol-1-yl-methyl) cyclopentanol. Imidazole For example: Imazalil, pefrazoate, prochloraz, triflumizole, 2- (1-t-butyl) -1- (2-chlorophenyl) -3- (1,2,4-triazol-1-yl) -propane-2 -Ol, thiazolcarboxyanilide such as 2 ', 6'-dibromo-2-methyl-4-trifluoromethoxy-4'-trifluoromethyl-1,3-thiazole-5-carboxyanilide. Copper salts For example: copper sulfate, copper carbonate, copper chloride, copper ammonia complex, copper amine complex. Zinc salts, for example: zinc sulfate, zinc carbonate, zinc chloride. Mixed salts, for example: copper / boron mixtures, copper / chromium / boron mixtures, copper / chromium / arsenic mixtures. 2- [2- [6- (2-Cyanophenoxy) pyrimidin-4-yloxy] phenyl] 3-methoxyacrylate (E) -methyl, 2- [2- [6- (2-thioamidophenoxy) pyrimidine- 4-yloxy] phenyl] -3-methoxyacrylic acid (E) -methyl, 2- [2- [6- (2-fluorophenoxy) pyrimidin-4-yloxy] phenyl] -3-methoxyacrylic acid (E ) -Methyl, 2- [2- [6- (2,6-difluorophenoxy) pyrimidin-4-yloxy] -phenyl] -3-methoxyacrylate (E) -methyl, 2- [2- [3 -(Pyrimidin-2-yloxy] phenoxy] -3-methoxyacrylic acid (E) -methyl, 2- [3- [5- (methylpyrimidin-2-yloxy] -phenoxy] phenyl] -3-methoxyacrylic acid ( E) -methyl, 2- [2- [3- (phenyl-sulfonylo Si) -Phenoxy] phenyl] -3-methoxyacrylic acid (E) -methyl, 2- [3- [4- (nitrophenoxy) phenoxy] -phenyl] -3-methoxyacrylic acid (E) -methyl, 2- [ 2-phenoxyphenyl] -3-methoxyacrylic acid (E) -methyl, 2- [2- (3,5-dimethylbenzoyl) pyrrol-1-yl] -3-methoxyacrylic acid (E) -methyl, 2- [2- (3-Methoxyphenoxy) phenyl] -3-methoxyacrylic acid (E) -methyl, 2- [2- (2-phenyl-ethen-1-yl) phenyl] -3-methoxyacryl Acid (E) -methyl, 2- [2- (3,5-dichlorophenoxy) pyridin-3-yl] -3-methoxyacrylic acid (E) -methyl, 2- (2- (3- (1 , 1,2,2-Tetrafluoroethoxy) phenoxy) phenyl) -3-methoxyacrylic acid (E) -methyl, 2- ( -[3- (α-Hydroxybenzyl) phenoxy] phenyl) -3-methoxyacrylic acid (E) -methyl, 2- (2- (4-phenoxypyridin-2-yloxy) phenyl) -3-methoxyacryl Acid (E) -methyl, 2- [2- (3-n-propyloxyphenoxy) -phenyl] -3-methoxyacrylic acid (E) -methyl, 2- [2- (3- (isopropyloxyphen Enoxy) phenyl] -3-methoxyacrylic acid (E) -methyl, 2- [2- [3- [2- (2-fluorophenoxy) phenoxy] phenyl] -3-methoxyacrylic acid (E) -methyl, 2 -[2- (3-Ethoxyphenoxy) phenyl] -3-methoxyacrylic acid (E) -methyl, 2- [2- (4-t-butylpyridin-2-yloxy) phenyl] -3-methoxyacryl Acid (E) -methyl, 2- [2- [3- (3-cyanophenoxy) phenoxy ] Phenyl] -3-methoxyacrylate (E) -methyl, 2- [2- (3-methylpyridin-2-yloxymethyl) phenyl] -3-methoxyacrylate (E) -methyl, 2- [2 -[6- (2-Methylphenoxy) pyrimidin-4-yloxy] phenyl] -3- (meth) acrylic acid (E) -methyl, 2- [2- (5-bromopyridin-2-yloxymethyl] phenyl] -3 -Methoxyacrylic acid (E) -methyl, 2- [2- (3- (3-iodopyridin-2-yloxy] phenoxy] phenyl] -3-methoxyacrylic acid (E) -methyl, 2- [2- [ 6- (2-chloropyridin-3-yloxy] pyrimidin-4-yloxy] phenyl] -3-methoxyacrylate (E) -methyl, 2- [2- (5,6-dimethylpyrazin-2-ylmethyloxy) Iminomethyl) phenyl] -3-methoxyacrylic acid (E), E) -Methyl, 2- {2- [6- [6-methylpyridin-2-yloxy) pyrimidin-4-yloxy] phenyl} -3-methoxyacrylic acid (E) -methyl, 2- {2- (3 -Methoxyphenyl) methyloxyiminomethyl) phenyl} -3-methoxyacrylic acid (E), (E) -methyl, 2- {2- (6- (2-azidophenoxy) pyrimidin-4-yloxy] phenyl]- 3-Methoxyacrylic acid (E) -methyl, 2- {2- [6-phenylpyrimidin-4-yl) methyloxyiminomethyl) phenyl} -3-methoxyacrylic acid (E), (E) -methyl, 2- {2-[(4-chlorophenyl) methyloxyiminomethyl] phenyl} -3-methoxyacrylic acid (E), (E) -methyl, 2- {2- [6- (2-n-propylphenoxy) Si) -1,3,5-triazin-4-yloxy] phenyl} -3-meth (E) -Methyl oxyacrylate, 2- {2-[(3-nitrophenyl) methyloxyiminomethyl) phenyl} -3-methoxyacrylate (E), (E) -methyl. Succinate dehydrogenase inhibitors, for example: Fuenflam, flucarbanil, cilirafluramide, flumecilux, Seedvax, metsulfovax, pyrocarbolide, oxycarboxin, charlan, mebenil (mepronil), benodanil, flutolanil (Moncut). Naphthalene derivatives, for example: turbinafuin, naphthifin, butenafuin, 3-chloro-7- (2-aza-2,7,7-trimethyl-oct-3-en-5-yne). Sulfenamides such as dichlorofluanid, tolylfluanid, fluorpet, fluorfluoropet; captan, captophor, benzimidazole such as carbendazim, benomyl, furatiocarb, fuveridazole, thiofonatomethyl, thiabendazole or salts thereof; thiocyanates such as thiocyanatomethylthiobenzo. Thiazoles, methylenebisthiocyanates; quaternary ammonium compounds such as benzyl dimethyl tetradecyl ammonium chloride, benzyl dimethyl dodecyl ammonium chloride, didecyl dimethyl ammonium chloride, morpholine derivatives such as tridemorph, fuenpropimorph, fualimorph, dimethomorph, dodemorph; aldimorph, fuenpro Pidgin and its aryl sulfonates such as p-tolue Sulfonic acid and p-dodecylphenyl-sulfonic acid, iodine derivatives such as diiodomethyl-p-tolylsulfone, 3-iodo-2-propynyl alcohol, 4-chlorophenyl-3-iodopropargylformal, 3-bromo-2,3-diiodo -2-Propenylethyl carbamate, 2,3,3-triiodoallyl alcohol, 3-bromo-2,3-diiodo-2-propenyl alcohol, 6-iodo-3-oxo-hex-5-yn-olbutylcarbamate , 6-Iodo-3-oxo-hex-5-yn-ol-phenylcarbamate, 3-iodo-2-propynyl n-hexylcarbamate, 3-iodo-2-propynylcyclohexylcarbamate, 3-iodo-2-propynylfuran Enyl carbamate; phenol derivatives such as tribromophenol, tetrachlorophenol, 3-methyl-4- Lolophenyl, dichlorophenyl, o-phenylphenol, m-phenylphenol, p-phenylphenol, 2-benzyl-4-chlorophenol; glutaraldehyde; bromine derivatives such as 2-bromo-2-nitro-1,3- Propanediol; Isothiazolinones such as N-methylisothiazolin-3-one, 5-chloro-N-methyl-isothiazolin-3-one, 4,5-dichloro-N-octyliso-thiazolin-3-one, N-octyl-isothiazolin- Benzisothiazolinone, 4,5-trimethylene-isothiazolinone; Pyridine or pyrimidine such as 1-hydroxy-2-pyridinethione (and its sodium, iron, manganese and zinc salts), tetrachloro-4-methylsulfonylpyridine , Pyrimethanil, mapanipyrim, dipyrithione; Tin tenate, tin octoate, tin 2-ethylhexanoate, tin oleate, tin phosphate, tin benzoate, copper naphthenate, copper octoate, copper 2-ethylhexanoate, copper oleate, copper phosphate, Copper benzoate, zinc naphthelate, zinc octoate, zinc 2-ethylhexanoate, zinc oleate, zinc phosphate and zinc benzoate; oxides such as tributyltin oxide, Cu ₂ O, CuO, ZnO; Dialkyldithiocarbamates such as Na and Zn salts of dialkyldithiocarbamic acid, tetramethylthiuram disulfide; Dithiocarbamate, Kuflaneb, Fuerbam, Mankappa, Mancozeb, Maneb, Metam, Methyram, Tilam, Zineb, Diam; Nitrile For example, 2,4,5,6-tetrachloroisophthalodinitrile, 2,3,5,6-tetrafluoroterephthalodinitrile; benzothiazole such as 2-mercaptobenzothiazole; quinoline such as 8-hydroxyquinoline and its Cu salt Benzamides such as 2,6-dichloro-N- (4-trifluoromethylbenzyl) -benzamide (XRD-563); boron compounds such as boric acid, borate esters, borax; formamide and formamide releasing compounds such as benzi Alcohol mono (poly) hemiformal, oxazolidine, hexahydro-S-triazine, N-methylolchloroacetamide, paraformaldehyde, nitropyrine, oxophosphoric acid, laclophthalam; tris-N- (cyclohexyldiazeniumdioxy) -aluminum, N- ( Cyclo-hexyldiazeniumdioxy) -tributyltin or potassium salt, bis-N- (cyclohexyldiazeniumdioxy) -copper. Other germicidal and fungicidal components in the mixture which are very particularly suitable are: azaconazole, bromuconazole, cyproconazole, diclobutrazol, diniconazole, hexaconazole, methaconazole, penconazole, propicono. Nazole, tebuconazole, methoxyimino [α- (o-tolyloxy-o-tolyl) acetic acid (E) -methyl, 2- {2- [6- (2-cyanophenoxy) -pyrimidin-4-yl-oxy] phenyl} -3-Methoxyacrylic acid (E) -methyl, metofloxam, carboxin, fenpicrinyl, 4 (2,2-difluoro-1,3-benzodioxol-4-yl) -1H-pyrrol-3-carbonitrile, butenafine And / or 3-iodo-2-propynyl-n-butyl carbamate. Furthermore, highly effective mixtures are prepared with the following active compounds: Fungicides: Acipetax, 2-aminobutane, ampropyrifos, anilazine, benalaxyl, bupirimate, quinomethionate, chloroneb, clozolinate, simoxanil, dazomet, Jikuromejin, Jikuroramu, di Etofu ene benthiavalicarb, Jimechirimoru, Jinokabu, dithianon, dodine, Dorazokisoron, Ejifuenfuosu, Echirimoru, etridiazole, Fuenarimoru, Fuenitoropan, acetic Fuenichin, hydroxide Fuenichin, Fuerimuzon, fluazinam, Fururomido, Furusurufuamido, Furutoriafuoru, Fuosechiru, Phthalide, furafuxyl, guazatine, hymexazol, iprobenfuos, iprodione, isoprothiolane, metalaxyl, meta Rufuocalb, Nitrotal Isopropyl, Nuarimol, Offlace, Oxadiyl, Perflurazoate, Penciclone, Fuosdifuene, Pimaricin, Piperaline, Procymidone, Propamocarb, Propineb, Pyrazofos, Pirifenox, Pyroquinone, Kintozene, Tar Oil, Technazene, Chissiaophene -Methyl, tolclophos-methyl, triazoxide, trichlamide, tricyclazole, trifluorine, vinclozolin. If appropriate, the following insecticides are added and mixed in order to achieve a higher activity against wood-destroying insects. Phosphoric acid esters, for example, azinephos-ethyl, azinephos-methyl, α-1 (4-chlorophenyl) -4- (O-ethyl, S-propyl) phosphoryloxy-pyrazole, chlorpyrifos, koumahuos, demeton, demeton-S-methyl, diazinon , Dichlorvos, Dimethoate, Etoate, Etoprofos, Etrimfuos, Huenitrothion, Fuenthione, Heptenophos, Parathion, Parathion-methyl, Phosalon, Huoxime, Pirimifuos-Ethyl, Pirimifuos-Methyl, Prophiofostrifuro, Trifuosufrufostrios, Sulfurofustrifuos, Sulfurofos, Trifufos, Trifufos, Trifufos, Trifufos, Trifufos, Trifufos, Trifuosfu For example, aldicarb, bendiocarb, α-2- (1-methylpropyl) -phenylmethylcarbamate, butocoxime, butoxycarboxyme Carbaryl, carbofuran, carbosulfan, clietocarb, isoprocarb, methomyl, oxamyl, pirimicarb, promecarb, propoxur and thiodicarb; organosilicon compounds, preferably dimethyl (phenyl) silyl-methyl 3-phenoxybenzyl ether such as dimethyl- (4- (Ethoxyphenyl) -silylmethyl 3-phenoxybenzyl ether, or (dimethylphenyl) -silyl-methyl 2-phenoxy-6-pyridylmethyl ether such as dimethyl- (9-ethoxy-phenyl) -silylmethyl 2-phenoxy-6 -Pyridyl methyl ether or [(phenyl) -3- (3-phenoxyoxyphenyl) -propyl] (dimethyl) -silane such as (4-ethoxyphenyl) [3- (4-fluoro-3-phenoxyphene) [Enyl-propyl] -silane, sila Ruofin, pyrethroids such as arethrin, alfamethrin, bioresmethrin, bifrentin, cycloprotin, cyfluthrin, decametrin, cyhalothrin, cypermethrin, deltamethrin, alpha-cyano-3-phenyl-2-methylbenzyl, 2,2-dimethyl-3- (2- Chloro-2-trifluoro-methylvinyl) cyclopropanecarboxylate, phenpropatoline, phenfluthrin, phenvalerate, flucitrinate, flumethrin, fluvalinate, permethrin, resmethrin and tralomethrin; nitroimines and nitromethylenes such as 1- [ (6-Chloro-3-pyridinyl) -methyl] -4,5-dihydro-N-nitro-1H-imidazol-2-amine (imidacloprid), N-[(6-chloro-3-pyridyl) methyl] -N ² -Cyano-N ¹ -Methylacetamide (NI-25), Abamectin, AC303,630, Acephate, Acrinathrin, Alanicalbub, Aldoxicarb, Aldrin, Ammonium difluoride, Amitraz, Azametifus, Bacillus thrungiensis, Phosphine, Phosphine, Huosmet Praletrin, Propahuos, Propetamhuos, Protoate, Pyraclofuus, Pyrethrin, Pyridabene, Pyridafentione, Pyriproxifuene, Quinalfuos, RH-7988, Rotenone, Sodium difluoride, Sodium hexafluorosilicate, Sulfotep, Sulfuryl fluoride, Tar Oil, teflubenzuron, tefluthrin, temehuos, terbuhuos, tetrachlorbinhuos, tetra Thorin, O-2-t-butyl-pyrimidin-5-yl-o-isopropylphosphrothioate, thionecrum, thiophanox, thiomethone, tralomethrin, triflumuron, trimetacarb, bamidthione, Verticillium Lacanii, XMC, xylyl , Benfuracarb, bensultap, bifurenton, bioallethrin, MER bioallethrin (S) -cyclopentenyl isomer, bromofuos, bromofuos-ethyl, buprofezin, kazusafuos, calcium polysulfide, carbophenothione, cartap, quinomethionate, chlordane, chlorfuenbinfuos , Chlorfluazuron, chlormehuos, chloropicrin, chlorpyrifos, cyanofuos, beta-cyfluto Phosphorus, alpha-cypermethrin, cyofenotrin, cyromazine, dazomet, DDT, demeton-S-methylsulfone, diafuenthiuron, dialiphus, dicrotophos, diflubenzuron, dinoceb, dioxabenzofuos, diaxacarb, disulfoton, DNOC, endempentrin. Juan, EPN, esfuenvarelate, ethiofenecarb, ethione, ethuenprox, fenobcarb, phenoxycarb, fuensulfothion, fipronil, flucycloxuron, flufuenprox, flufuenoxuron, huonohuos, phormethanate, flumothion, fuosmethyran, Fratiocarb, heptachlor, hexaflumuron, hydramethylnon, hydrogen cyanide, hydroprene, IPSP, isazo Huos, Isofuenfuos, Isoprothiolane, Isoxathion, Iodofuenfuos, Cadethrin, Lindane, Malathion, Mecarbam, Mephosphorane, Merclous, Chloride, Metam, Metalthidium, Anisopree, Methachuos, Metamidophos, Methidathion, Methiocarb, Metoprene, Methoxychlor, Methochlor, Methochlor, Methochloric acid Mevinhuos, Monocrotohuos, Naredo, Neodipionon-Sertifer NPV, Nicotine, Omethoate, Oxydemeton-methyl, Pentachlorophenol, Petroleum, Phenotrin, Fuentoate, Fluorate; , Flucycloxuron Hexaflumuron, penfluron, teflubenzuron, and other growth inhibitors such as [2-benzoyl-1- (1,1-dimethylethyl)]-benzohydrazide, 2,6-dimethoxy-N- [5-] 4- (penta Fluoroethoxy) -phenyl- [2,3,4-thiadiazol-2-yl] -benzamide, N-cyclopropyl-1,3,5-triazine-2,4-triamine, 2- (4-phenoxyphenoxy)- Ethyl ethyl carbamate, 1- (decycloquine) -4-[(6-methoxy-4-hexynyl) -oxy] benzene, 4-methoxy-benzoic acid (2-propynyl), phenoxycarb, pyriproxyfen, trialanthene, thiapronil, Hexthiazox, clofendezin, 4-chloro-5- (6-chloro-3-pyridylmethoxy) -2- (3,4-dichlorophenyl) -pyridazin-3 (2H) -one Buprofezin, hydroprene, kinoprene, methoprene, cycloalkyl plate, Gusachin, Padang, Parakison, Toribuniru, isomers and triprene. A synergistic effect is observed when triflumuron, at least one fungicide and, if appropriate, another fungicide or another insecticide are mixed with one another in a certain ratio. The weight ratio of the active compounds can be varied within a relatively wide range, whereby the weight ratio of triflumuron to the fungicides or fungicides to the fungicides is preferably 1: 20,000 to 1:10. , In particular 1: 10,000 to 1: 100. Surprisingly, these active agent combinations have a particularly effective insecticidal action against wood-destroying insects, as well as a wide range of fungicidal and fungicidal action against microorganisms involved in the protection of the material. The following wood-destroying insects may be mentioned by way of example and not limitation: the beetles Hylotrupes bajulus, Chlorophorus pilosis, Anovium punctumum, and Pseudomonas punctum. (Xestobium rufovillosum), Putilinus pecticornis, Dendrobium pertinex, Ernobius crubius vulius mollis, Ernobius prunicus, priobium carnivos, priobius carnibulis, priobius carnivulis, priovium carpius -Africanus (Lyctus africanus), Lictus planicollis (Lictus planicollis), Lyctus inline squirrels (Luctus pleucense), Lichtus vulius (Luctus vulius) Xyleborus species, Tryptodendron species, Apate monochus, Bostrichchus capuscinus, Heterovotricus bruneus. Sinoxylon spec., Dinoderus minutus Hymenoptera Sirex juvencus, Urocerus gigas, Urocerus gigas, Urocerus gigas, Urocerus gigas (U rocerus augur) termites Carotermes flavicollis, Cryptotermers brevis, Heterotermes indicola es ricteres et liceres Ricicles, rechrytermes Reticulitermes santonensis, Reticulitermes lucillus gus, Masttermes orus terus meso terus nesto tereso meso tereso terzos terus ternos tereso terzos tereso terzos tereso terzos tereso terzos tereso terzos teruzos tereso terzos teres meso tereso terzos tereso terzos tereso terzos tereso terzos tereso terzos tereso terzos tereso terzos tereso terzos tereso terzos teres terus tereso tereso tereso tereso tereso terus en tereso tereso terus en teres. The following groups of microorganisms may be mentioned by way of example and not limitation: A: Wood discoloring fungi: A1: Ascomycetes: Ceratocystis, for example Ceratocystis minor. minor A2: Deuteromycetes: Aspergillus, for example, Aspergillus niger, Aureobasidium, for example, Aureobasidium purulans ) For example, Dactylium fusarioides, Peniciliu Penicillium, such as Penicillium brevicaule or Penicillium varieum, such as Penicillium vulia sula, Scleroophia scoula, S. (Scopularia phy comyces), Trichoderma, for example Trichoderma viride or Trichoderma lignorum A3: Zygomycet. (Mucor) For example, Mucor spinorus B: Wood-destroying fungus / mold: B1: Ascomycetes: Chaetomium, for example, Chaetomium globomum albaumbaumum (Chaetomium alba-arenulum), Humicola, for example, Humicola grisea, Petriella, for example, Petriella spteiurus Trichuris, for example, Tricrulus. ) B2: Basidiomycetes es): Con iophora, for example Coniophora pu teana, Coriolus, for example Coriolus vera pisoana, Don kiopora, for example. The genus (Glenospora), for example, Glenospora graphii, the genus Gloeophyllum, for example, Gloeophyllum ma abietinum, the genus Gloeophyllum abietinum, the genus Gloeophyllum. Protactum, Gl. Sepiarium or Gl. Trabeum, Lentinus, such as Lentinus cythiformes or L. Ed odes e.g. Lepideus, L .; Grinus or L. Squalorolosus, Paxillus, for example, Paxillus panuoides, Pleurotus, for example, Pleurotus ostrea P., Pleurotus ostreatus, Pleurotus ostreatus, Pleurotus ostreatus, Pleurotus ostreatus, Pleurotus ostreatus, Pleurotus ostreatus, Pleurotus ostreatus (Pleurotus ostreatus) Placenta, P. Veillan tii or P. Vaporaria, Serpula, for example, Serpula himantoi des or Serpula lacrymans, for example, Stereum, for example, Stereum hirsutum, Sterum, hirsutum, Sterum hirsutum. Tyromyces palustris B3: Deuteromycetes: Alternaria, for example Alternaria t enius, Cladosporium cladosporium Cladosporiu Harbarum) In order to prepare the preparation wood protectants, the active compound mixtures as such, in the form of thickeners or, where appropriate, simply by diluting with water, generally customary preparations such as powders, granules, It can be used as a solution, suspension, emulsion or paste. The above-mentioned compositions or thickeners are prepared in a manner known per se, for example by adding the active compound to at least one solvent or diluent, emulsifier, dispersant and / or binder or fixative, water repellent, if appropriate drying agent and It can be prepared by mixing with UV stabilizers and, where appropriate, colorants and pigments and other processing aids. The solvents and / or diluents used are organic chemical solvents or solvent mixtures and / or oil- or oil-type organic chemical solvents or low-volatility solvent mixtures and / or polar organic chemical solvents or solvent mixtures and / or at least one emulsifier and And / or water in combination with a wetting agent. Suitable organic chemical solvents are oil or oil type solvents having an evaporation number of 35 or more and a flash point of 30 ° C. or more, preferably 45 ° C. or more. Suitable mineral oils or their aromatic fractions or mineral oil-containing solvent mixtures, preferably white spirit, petroleum and / or alkylbenzenes, have low volatility and are insoluble in water. Used as a solvent. Materials used advantageously are mineral oil having a boiling range of 170-220 ° C., white spirit having a boiling range of 170-220 ° C., spindle oil having a boiling range of 250-350 ° C., and boiling oil having a boiling range of 160-280 ° C. Petroleum or aromatic oils, pine oil, etc. In a preferred embodiment, liquid aliphatic hydrocarbons having a boiling range of 180 to 210 ° C. or high boiling compounds of aromatic and aliphatic hydrocarbons having a boiling range of 180 to 220 ° C. and / or spindle oil and / or monochloro Naphthalene, preferably α-monochloronaphthalene, is used. Replacing a low volatility organic oily or oil type solvent having an evaporation number of 35 or higher and a flash point of 30 ° C. or higher, preferably 45 ° C. or higher, with a partially high or moderately volatile organic chemical solvent. Provided that the solvent mixture also has an evaporation number of 35 or higher and a flash point of 30 ° C. or higher, preferably 45 ° C. or higher, and the pesticide / fungicidal mixture is soluble or emulsifiable in this solvent mixture. It will be. In a preferred embodiment, some of the organic chemical solvents or solvent mixtures or aliphatic polar organic chemical solvents or solvent mixtures are substituted. Preferably used substances are aliphatic organic chemical solvents containing hydroxyl and / or ester and / or ether groups, such as glycol ethers, esters and the like. Organic chemical binders used within the scope of the present invention are known per se and can be diluted with water and / or combined dry oils which can be dissolved or dispersed or emulsified in the organic chemical solvent used and / or Or synthetic resins, especially acrylate resins, vinyl resins such as polyvinyl acetate, polyester resins, polycondensation or polyaddition resins, polyurethane resins, alkyd or modified alkyd resins, phenolic resins such as indene / coumarone, silicone resins, dried plants and Physical dry binders based on dry oils and / or natural and / or synthetic resins. The synthetic resin used as the binder may be used in the form of emulsion, dispersion or solution. It is also possible to use up to 10% by weight of bitumen or bitumen-like substances as other binders. In addition, colorants, pigments, water repellents, deodorants and inhibitors or corrosion inhibitors which are known per se can be used. The composition or thickener according to the invention preferably consists of at least one alkyd resin or modified alkyd resin and / or dried vegetable oil as organic chemical binder. The substances preferably used according to the invention are alkyl resins having an oil content of 45% by weight or more, preferably 50 to 68% by weight. Some or all of the above binders can be replaced by fixatives (mixtures) or plasticizers (mixtures). These additives are intended to prevent volatilization or crystallization or precipitation of the active compound. They preferably replace 0.01 to 30% (based on 100% binder used) of binder. Plasticizers include phthalates such as dibutyl phthalate, dioctyl phthalate or benzylbutyl phthalate, phosphates such as tributyl phosphate, adipates such as di- (2-ethylhexyl) adipate, stearates such as butyl stearate or It is from the chemical group of amyl stearate, oleic acid esters such as butyl oleate, glycerin ether or high molecular weight glycol ethers, glycerin esters and p-toluenesulfonic acid esters. Chemically, fixatives are based on polyvinyl alkyl ethers such as polyvinyl methyl ether or ketones such as benzophenone and ethylbenzophenone, or amines such as alkanolamines, especially monoethanolamine, or else ammonia. . Also particularly suitable as solvent or diluent is water, if appropriate as a mixture with one or more of the abovementioned organic chemical solvents or diluents, emulsifiers and dispersants. Wood which can be protected by the composition according to the invention or a mixture of these is, for example, structural wood, wooden timber, railroad ties, bridge parts, breakwaters, wooden cars, boxes, pallets, containers, telephones, wood coverings, It will be understood as meaning wooden windows and doors, plywood, particle boards, derived wood products quite commonly used in joinery work or in the construction industry or building construction. Particularly effective protection of wood is achieved by industrial scale impregnation processes such as vacuum, double vacuum or pressure processes. The wood protectant used in the protection of wood and derived timber products is preferably triflumuron in a concentration of 0.001 to 3% by weight and a fungicide or fungicides in a concentration of 0.1 to 10% by weight.・ It consists of fungicides. A suitable composition (preparation composition) is preferably 0.2-3% by weight of fungicides, 0.005-1% by weight, preferably 0.01-0.5% by weight, if appropriate. Further pesticides, in particular triflumuron in combination with cyfluthrin, and at least one organic chemical solvent or solvent mixture as a balance and / or oil or oil type organic chemical solvent or low volatility and / or polar organic chemical solvent or It comprises a solvent mixture of the solvent mixture and / or water and an emulsifier and / or a wetting agent and, if appropriate, 0-5% by weight, preferably 0.1-3% by weight, of fixatives and / or other additives. A particularly suitable (prepared) composition is 2 to 30% by weight, preferably 5 to 22% by weight, calculated as solid, of synthetic resin binder and alkyd resin and / or dry vegetable oil and at least one organic chemical solvent or Solvent mixture and / or one oily or oil type organic chemical solvent or low volatility solvent mixture and / or one polar organic chemical solvent or solvent mixture and / or water and emulsifier and / or wetting agent and, if appropriate, the remainder As a drying agent, a colorant, a pigment, a suspending agent and / or a UV stabilizer. Thickeners for protecting wood and derived timber products are preferably 0.2 to 25% by weight, preferably 3 to 8% by weight of fungicides, 0.05 to 5% by weight, preferably Is 0.5 to 1% by weight of trihumulone, optionally in combination with an insecticide, 5 to 40% by weight, preferably 10 to 30% by weight (calculated as solids) of at least one organic chemical binder and / or fixing. Agents or plasticizers, and the balance organic chemical solvents or solvent mixtures and / or oily or oil type organic chemical solvents or low volatility solvent mixtures and / or polar organic chemical solvents or solvent mixtures and / or penetrants and It consists of water and / or emulsifiers and / or wetting agents. The amount of composition or thickener used depends on the insect, the species and incidence of the microorganism, the number of the microorganism and the medium. When used, the optimum amount can in each case be determined by a series of tests. However, in general, it is sufficient to use from 0.001 to 20% by weight, preferably from 0.05 to 10% by weight, of active compound, based on the material to be protected. The compositions according to the invention may advantageously replace conventional insecticidal compositions in a more effective manner. They exhibit good stability and advantageously have a broad spectrum of action.

────────────────────────────────────────────────── ─── Continuation of front page    (81) Designated countries EP (AT, BE, CH, DE, DK, ES, FR, GB, GR, IE, IT, LU, M C, NL, PT, SE), OA (BF, BJ, CF, CG , CI, CM, GA, GN, ML, MR, NE, SN, TD, TG), AU, BB, BG, BR, BY, CA, CN, CZ, FI, HU, JP, KR, KZ, LK, N O, NZ, PL, RO, RU, SK, UA, US (72) Inventor Boutcheille House, Hans-Ulrich             Federal Republic of Germany Day 47,800 Klehue             Lut Bethelsyutrase 24

Claims (1)

[Claims]   1. Tree consisting of triflumuron and at least one synergistically complementary active compound Material protectant.   2. In addition, it comprises at least one azole fungicide. The wood protective agent according to item 1.   3. Triflumuron and at least one solvent, diluent and / or additive Scents of compositions or thickeners based on or alternatively of And said composition or thickener comprises at least one fungicide, 0.1-99.9 weight. 0.01 to 25% by weight of triflumuron as a mixture with Or diluents and / or organic chemical binders and / or fixatives, processing aids, adhesives Consist of at least 40% by weight of colorant, pigment, color mixture or mixture of pigment mixtures. A protective composition or thickener for wood and derived timber products, characterized in that   4. The solvent and / or diluent is an organic chemical solvent or solvent mixture and / or Oily or oil type organic chemical solvents or low volatility and / or polar organic chemistry Solvent or solvent mixture of solvent mixtures and / or at least one emulsifier and And / or water in combination with a wetting agent. The listed composition or thickener.   5. As an azole   Azaconazole:   1-{[2- (2,4-dichlorophenyl) -1,3-dioxolan-2-yl] methyi 1-H-1,2,4-triazole,   Propiconazole:   1- [2- (2,4-dichlorophenyl) -4-propyl-1,3-dioxo Lan-2-yl] methyl-1-H-1,2,4-triazole,   Tebuconazole:   1-p-chlorophenyl-4,4-dimethyl-3- (1H-1,2,4-triazol-1- Il-methyl) pentan-3-ol,   Cyproconazole:   2- (4-chlorophenyl) -3-cyclopropyl-1- (1H-1,2,4-triazo Le-1-yl) butane-2-ol,   2- (1-chloro-cyclopropyl) -1- (2-chlorophenyl) -3-1H- (1, 2,4-triazol-1-yl) propan-2-ol,   2- (t-butyl) -1- (2-chlorophenyl) -3-1H- (1,2,4-triazo Ru-1-yl) propane-2-ol   And / or hexaconazole or metconazole A tree according to any one of claims 1 to 4, characterized in that Material protectant.   6. At least one 0.1 to 50% by weight, preferably 0.5 to 25% by weight concentrated A azole according to any one of claims 2 to 5, characterized in that A protective composition or thickener for listed wood and derived timber products.   7. Chlorpyrifos, Foxime, Silafluofen as additional insecticides , Cyfluthrin, cypermethrin, deltamethrin, permethrin, imidaclo Characterized by containing pyrido, hexaflumuron and / or lindane The wood protecting agent according to any one of claims 1 to 5.   8. A composition (prepared composition) of 0.2 to 3% by weight of a bactericide and fungicide, 0.005 to 1% by weight, preferably 0.01 to 0.5% by weight of the insecticide as well as the balance As at least one organic chemical solvent or solvent mixture and / or oil Or oil type organic chemical solvents or low volatility and / or polar organic chemical solvents Or solvent mixture of solvent mixture and / or water and emulsifier and / or lubrication Agent and, if appropriate, 0-5% by weight, preferably 0.1-3% by weight of fixative and / or Or any one of claims 1 to 7, which is characterized by comprising other additives. A composition for protecting wood and derived timber products according to claim 1.   9. 0.2 to 25% by weight thickener, preferably 3 to 8% by weight of bactericide , 0.05-5% by weight, preferably 0.5-1% by weight insecticide, 5-40% by weight, Preferably 10 to 30% by weight (calculated as solids) of at least one organic chemical compound. Mixtures and / or fixatives or plasticizers and in addition organic chemistry as the rest Solvent or solvent mixture and / or oil or oil type organic chemical solvent or Solvent mixtures of low volatility and / or polar organic chemical solvents or solvent mixtures and And / or penetrant and / or water and emulsifier and / or wetting agent Wood and derived lumber according to any of claims 1 to 7, characterized Thickener for product protection.   10. Wood or derived composition according to any of claims 1-9 Applied to a timber product, or a wood or derived timber product A method for protecting wood and derived timber products, characterized in that it is treated with.   11. Claims 1-9 for the protection of wood and derived timber products Use of the composition according to any one.