DE4409040A1 - Insecticidal drug combinations - Google Patents

Abstract

New active insecticide substances composed on the one hand of a known active substance, triflumuron, and on the other hand of other known active substances, are very useful for protecting technical materials.

Description

The present application relates to new combinations of active ingredients resulting from the known triflumuron on the one hand and other known active ingredients on the other exist and are very well suited for the protection of technical materials.

It is already known that triflumuron has insecticidal properties.

It is also known that triflumuron as an active ingredient against wood-destroying Can use insects (Holz-Zentralblatt 34, 524 (1984).

Mixtures of hexaconazoles are also already known (cf. EP 415.569, GB 2.119.653, EP 95.242, EP 289.356, EP 287.346).

However, requirements are placed on wood preservatives that go beyond go beyond pure insecticidal effectiveness.

The aim and object of the present invention was therefore to preserve wood to find agents that are harmful to wood-damaging insects, in particular against wood-destroying longhorn beetles (Cerambycidae, Lyctidae, Bostrychidae and Anobiidae) including termites as well as against wood staining and wood-destroying mushrooms is highly effective and has a good long-term effect, the effectiveness of the insecticide is not impaired by the fungicide or vice versa. In addition, the wood preservative should be a have good penetration in the wood and in the wood material and compare with the pyrethroids used up to now a significantly lower vapor to have pressure.  

According to the invention it was found that these goals and tasks are a means or concentrate for preserving wood and wood-based materials, the 0.01 to 25 wt .-% triflumuron in a mixture of 0.1 to 99.9 wt .-% with at least one fungicide and more than 40 wt .-% of a mixture of Lö solvents and / or diluents and / or organic chemical binders or fixative, processing agent, dye, pigment, dye or pig ment mixture contains.

Preferred fungicides as mixing partners are:
Triazoles:
Amitrole, Azocyclotin, BAS 480F, Bitertanol, Difenoconazole, Fenbuconazole, Fenchlorazole, Fenethanil, Fluquinconazole, Flusilazole, Flutriafol, Imibencona zole, Isazofos, Myclobutanil, Opus, Paclobutrazol, Penconazole, -Prolocazazole, (piocononazole) (propyl ) -2- (1H-1,2,4-triazol-1-yl) cycloheptanol, tetraconazole, triadimphone, triadimenol, triapenthenol, triflumizole, uniconazole;
Azaconazole:
1 - {[2- (2,4-dichlorophenyl) -1,3-dioxolan-2-yl] methyl} 1-H-1,2,4-triazole
Propiconazole:
1- [2- (2,4-dichlorophenyl) -4-propyl-1,3-dioxolan-2-yl] methyl-1-H-1,2,4-triazole
Tebuconazole:
1-p-chlorophenyl-4,4-dimethyl -3 (1H-1,2,4-triazol-1-yl-methyl) pentan-3-ol
Cyproconazole:
2- (4-chlorophenyl) -3-cyclopropyl-1- (1H-1,2,4-triazol-1-yl) butan-2-ol-
2- (1-chloro-cyclopropyl) -1- (2-chlorophenyl) -3- (1H-1,2,4-triazol-1-yl-) propan-2-ol
2- (tert-butyl) -1- (2-chlorophen yl) -3- (1H-1,2,4-triazol-1-yl) propan-2-ol
Metconazole:
5 - [(4-chlorophenyl) methyl] -2,2-dimethyl-1- (1H-1,2,4-triazol-1-yl-meth-yl) cyclopentanol
Imidazole:
Imazalil, pefurazoate, prochloraz, triflumizole, 2- (1-tert-butyl) -1- (2-chlorophenyl) -3- (1,2,4-triazol-1-yl) propan-2-ol, thiazolecarboxanilide such as 2 ′, 6′-dibromo-2-methyl-4-trifluoromethoxy-4′-trifluoromethyl-1,3-thiazole-5-carboxane-ilide
Copper salts:
Copper, sulfate, carbonate, chloride, ammonia complexes, amine complexes
Zinc salts:
Zinc sulfate, carbonate, chloride

Mixed salts

Copper / boron mixtures, copper / chrome / boron mixtures, copper / chrome / arsenic mixtures.
Methyl (E) -2- [2- [6- (2-cyanophenoxy) pyrimidin-4-yloxy] phenyl] -3-methoxyacrylates,
Methyl (E) -2- [2- [6 (2-thioamidophenoxy) pyrimidin-4-yloxy] phenyl] -3-methoxyacrylic late,
Methyl (E) -2- [2- [6- (2-fluorophenoxypyrimidine-4-yloxy] phenyl] -3-methoxyacrylate,
Methyl (E) -2- [2- [6- (2,6-difluorophenoxy) pyrimidin-4-yloxy] phenyl] -3-m-ethoxyacrylic late,
Methyl (E) -2- [2- [3- (pyrimidin-2-yloxy) phenoxy] phenyl] -3-methoxyacrylate,
Methyl (E) -2- [2- [3- (5-methylpyrimidin-2-yloxy) phen oxy] phenyl] -3-methoxyacrylate,
Methyl (E) -2- [2- [3- (phenylsulfonyloxy) phenoxy] phenyl] -3-methoxyacrylic late,
Methyl (E) -2- [2- [3- [4-nitrophenoxy] phenoxy] phenyl] 3-methoxyacrylate,
Methyl (E) -2- [2-phenoxyphenyl] -3-methoxyacrylate,
Methyl (E) -2- [2- [3,5-dimethylbenzoyl) pyrrol-1-yl] -3-methoxyacrylates,
Methyl (E) -2- [2- [3-methoxyphenoxy) phenyl] -3-methoxyacrylate,
Methyl (E) -2- [2- [2-phenylethen-1-yl) phenyl] -3-methoxyacrylate,
Methyl (E) -2- (2- [3,5-dichlorophenoxy] pyridin-3-yl) -3-methoxyacrylate, -
Methyl (E) -2- (2- (3- (1,1,2,2-etrafluoroethoxy) phenoxy) phenyl) -3-methoxyacrylates,
Methyl (E) -2- (2- [3- (α-hydroxybenzyl) phenoxy] phenyl) -3-methoxyacrylate,
Methyl (E) -2- (2- (4-phenoxypyridin-1-yloxy) phenyl) -3-methoxyacrylate,
Methyl (E) -2- [2- (3-n-propyloxyphenoxy) phenyl] -3-methoxyacrylate,
Methyl (E) -2- [2- (3-isopropyloxyphenoxy) phenyl] -3-methoxyacrylate,
Methyl (E) -2- [2- [3- (2-fluorophenoxy) phenoxy] phenyl] -3-methoxyacrylate-,
Methyl (E) -2- [2- (3-ethoxyphenoxy) phenyl] -3-methoxyacrylate,
Methyl (E) -2- [2- (4-tert-butylpyridin-2-yloxy) phenyl] -3-methoxyacrylate,
Methyl (E) -2 - [2- [3- (3-cyanophenoxy) phenoxy] phenyl] -3-methoxyacrylate,
Methyl (E) -2- [2- (3-methylpyridin-2-yloxymethyl) phenyl] -3-methoxyacrylate,
Methyl (E) -2- [2- [6 (2-methylphenoxy) pyrimidin-4-yloxy] phenyl] -3-methoxyacrylates,
Methyl (E) -2- [2- (5-bromopyridin2-yloxymethyl) phenyl] -3-methoxyacrylate-e,
Methyl (E) -2- [2- (3- (3-iodopyridin-2-yloxy) phenoxy) phenyl] -3-methoxyacrylates,
Methyl (E) -2- [2- [6- (2-chloropyridin-3-yloxy) pyrimidin-4-yloxy] phenyl] -3-methoxy acrylates,
(E), (E) -methyl-2- [2- (5,6-dimethylpyrazin-2-ylmethyloximinomethyl) phenyl] -3-methoxyacrylate,
(E) -methyl-2- (2- [6- (6-methylpyridin-2-yloxy) pyrimidin-4-yloxy] phenyl -} - 3-meth oxyacrylates,
(E), (E) -methyl-2- {2- (3-methoxyphenyl) methyloximinomethyl] phenyl} -3-methoxy acrylates,
(E) -methyl-2- {2- [6- (2-azidophenoxy) pyrimidin-4-yloxy] phenyl} -3-methoxy acrylates,
(E), (E) -methyl-2- {2- [6-phenylpyrimidin-4-yl) methyloximinomethyl] phenyl} -3-methoxyacrylates,
(E), (E) -methyl-2- {2 - [(4-chlorophenyl) methyloximinomethyl] phenyl} -3-methoxy acrylates,
(E) -methyl-2- {2- [6- (2-n-propylphenoxy) -1,3,5-triazin-4-yloxy] phenyl} -3-methoxy acrylates,
(E), (E) -methyl-2- {2 - [(3-nitrophenyl) methyloximinomethyl] phenyl} -3-methoxyacrylic late.

Succinate dehydrogenase inhibitors such as:
Fenfuram, Furcarbanil, Cyclafluramid, Furmecyclox, Seedvax, Metsulfovax, Pyrocarbolid, Oxycarboxin, Shirlan, Mebenil (Mepronil), Benodanil, Flutolanil (Moncut),
Naphthalene derivatives such as:
Terbinafine, naftifine, butenafine, 3-chloro-7- (2-aza-2,7,7-trimethyl-oct-3-en-5-in)
Sulfenamides such as dichlorfluanide, tolylfluanid, folpet, fluorfolpet; Captan, Captofol,
Benzimidazoles such as Carbendazim, Benomyl, Furathiocarb, Fuberidazole, Thio phonatmethyl, Thiabendazole or their salts;
Thiocyanates such as thiocyanatomethylthiobenzothiazole, methylene bisthiocyanate;
quaternary ammonium compounds such as benzyldimethyltetradecylammonium chloride, benzyldimethldodecyclammonium chloride, didecyldimethylammonium chloride,
Morpholine derivatives such as tridemorph, fenpropimorph, falimorph, dimethomorph, dodemorph; Aldimorph, fenpropidine and their arylsulfonic salts, such as. B. p-toluenesulfonic acid and p-dodecylphenyl sulfonic acid,
Iodine derivatives such as diiodomethyl-p-tolyl sulfone, 3-iodo-2-propynyl alcohol, 4-chlorophenyl-3-iodopropargyl formal, 3-bromo-2,3-diiodo-2-propenylethyl carbamate, 2,3,3-tri iodallyl alcohol, 3-bromo-2,3-diiodo-2-propenyl alcohol, 6-iodo-3-oxo-hex-5-yn-ol butyl carbamate, 6-iodo-3-oxo-hex-5-yn-ol-phenyl carbamate, 3 -Iodo-2-propynyl-n-hexyl carbamate, 3-iodo-2-propynyl cyclohexyl carbamate, 3-iodo-2-propynyl phenyl carbamate;
Phenol derivatives such as tribromophenol, tetrachlorophenol, 3-methyl-4-chlorophenyl, di chlorophen, o-phenylphenol, m-phenylphenol, p-phenylphenol, 2-benzyl-4-chlorophenol;
Glutaraldehyde;
Bromine derivatives such as 2-bromo-2-nitro-1,3-propanediol;
Isothiazolinones such as N-methylisothiazolin-3-one, 5-chloro-N-methyl-isothiazolin-3-one, 4,5-dichloro-N-octylisothiazolin-3-one, N-octyl-isothiazolin-3-one;
Benzisothiazolinones, 4,5-trimethylene-isothiazolinones;
Pyridines or pyrimidines such as 1-hydroxy-2-pyridinthione (and their Na, Fe, Mn, Zn salts), tetrachloro-4-methylsulfonylpyridine, pyrimethanil, mepanipyrim, dipyrithione;
Metal soaps such as tin, copper, zinc naphthenate, octoate, 2-ethylhexanoate, oleate, phosphate, benzoate;
Oxides such as tributyltin oxide, Cu₂O, CuO, ZnO;
Dialkyldithiocarbamates such as Na and Zn salts of dialkyldithiocarbamates, tetramethylthiuram disulfide;
Dithiocarbamate, Cufraneb, Ferbam, Mancopper, Mancozeb, Maneb, Metam, Metiram, Thiram Zineb, Ziram:
Nitriles such as 2,4,5,6-tetrachloroisophthalonitrile, 2,3,5,6-tetrafluoroterephthalodi nitrile;
Benzothiazoles such as 2-mercaptobenzothiazole;
Quinolines such as 8-hydroxyquinoline and their Cu salts;
Benzamides such as 2,6-dichloro-N- (4-trifluoromethylbenzyl) benzamide (XRD-563);
Boron compounds such as boric acid, boric acid ester, borax;
Formaldehyde and formaldehyde releasing compounds such as benzyl alcohol mono- (poly) -hemiformal, oxazolidines, hexa-hydro-S-triazines, N-methylolchloroacetamide, paraformaldehyde, nitropyrin, oxolinic acid, tecloftalam;
Tris-N- (cyclohexyldiazeniumdioxy) aluminum, N- (cyclohexyldiazeniumdioxy) tributyltin or K salts, bis-N- (cyclohexyldiazeniumdioxy) copper.

Other fungicidal mixing partners are very particularly preferably:
Azaconazole, bromuconazole, cyproconazole, dichlobutrazole, diniconazole, hexaconazole, metaconazole, penconazole, propiconazole, tebuconazole, methyl- (E) methoximino [α- (o-tolyloxy) -o-tolyl)] acetate, methyl- (E) -2 {2- [6- (2-cyanophenoxy) pyrimidin-4-yl-oxy] phenyl} -3-methoxyacrylate, methfuroxam, carboxin, fen piclonil, 4 (2,2-difluoro-1,3-benzodioxol-4- yl) -1H-pyrrole-3-carbonitrile, butenafine and / or 3-iodo-2-propynyl-n-butyl carbamate.

Furthermore, highly effective mixtures with the following active ingredients are also produced:
Fungicides
Acypetacs, 2-aminobutane, ampropylfos, anilazine, benalaxyl, bupirimate, quinomethionate, chloroneb, chlozolinate, cymoxanil, dazomet, diclomezine, dichloram, diethofencarb, dimethirimol, dinocab, dithianon, dodonidolololol, dolonolimololol, dolonimololol, dolonimololol, doline, dolinololol, doline, phenolol, dolimidolol, dolonimolol, dolonimolol, dolonimololol, dolonimolol, phenol, dolimidolol, dolonimolol, dolonimolol, dolonol, zolimolol, dolimidololol, dolimidolol, phenol, zolimolol, dolimidolol, dolimidolol, dolimidololol, dolimidolol, dolimidolol, phenol, dolimidol, phenol, dolimidol Fentin acetate, Fentin Hydroxide, Ferimzone, Fluazinam, Fluromide, Flusulfamide, Flutriafol, Fosetyl, Fthalide, Furalaxyl, Guazatine, Hymexazol, Iprobefos, Iprodione, Isoprothiolane, Metalaxyl, Methasulfocarb, Nitrothal-isopropyl, Puromuroluroluroluroluroluroluroluroluroluroluroluroluroluroluroluroluroluroluroluroluroluroluroluroluroluroluromoluroluroluroluromolurolurolurolurololuroluroluroluroluroluroluroluroluroluroluronoluroluroluroluroluronolofuroluroluroluronoluroluronoloxyrolonolurateurofluorocarburofluorocarbonate Phosdiphen, Pimaricin, Piperalin, Procymidone, Propamocarb, Propineb, Pyrazophos, Pyrifenox, Pyroquilon, Quintozene, Tar Oils, Tecnazene, Thicyofen, Thiophanate-methyl, Tolclofos-methyl, Triazoxide, Trichlamide, Tricyclazole, Triforoline.

In order to achieve further increased effects against wood-destroying insects, If necessary, the following insecticides can also be added.

Phosphoric acid esters such as azinphos-ethyl, azinphos-methyl, a-1 (4-chlorophenyl) -4- (O-ethyl, S-propyl) phosphoryloxy-pyrazole, chlorpyrifos, Coumaphos, Demeton, Demeton-S-methyl, diazinon, dichlorvos, Dimethoate, Ethoate. Bthoprophos, Etrimfos, Fenitrothion, Fenthion, Heptenophos, Parathion, Parathion-methyl, Phosalone, Phoxim, Pirimiphos-ethyl, Pirimiphos-methyl, Profenofosm Prothiofos, Sulfprofos, Triazophos and Trichlorphone;
Carbamates such as aldicarb, bendiocarb, a-2- (1-methylpropyl) phenylmethyl carbamate, butocarboxime, butoxycarboxime, carbaryl, carbofuran, carbosulfan, cloethocarb, isoprocarb, methomyl, oxamyl, pirimicarb, promecarb, propoxur and thiodicarb;
Organosilicon compounds, preferably dimethyl (phenyl) silyl-methyl-3-phenoybenzyl ether such as dimethyl- (4-ethoxyphenyl) -silylmethyl-3-phenoxybenzyl ether or
(Dimethylphenyl) silylmethyl-2-phenoxy-6-pyridylmethyl ether such as e.g. B. Dimethyl- (9-ethoxy-phenyl) -silylmethyl-2-phenoxy-6-pyridylmethyl ether or [(phenyl) -3- (3-phenoxyphenyl) propyl] (dimethyl) -silanes such as, for. B. (4-ethoxyphenyl) - [3- (4-fluoro-3-phenoxyphenylpropyl] dimethyl silane, silafluorine;
Pyrethroids such as Allethrin, Alphamethrin, Bioresmethrin, Byfenthrin, Cycloprothrin, Cyfluthrin, Decamethrin, Cyhalothrin, Cypermethrin, Deltamethrin, Alpha-cyano-3-phenyl-2-methylbenzyl-2,2-dimethyl-3- (2-chloro-2-trif -methylvinyl-) cyclopropane carboxylate, fenpropathrin, fenfluthrin, fenvalerate, flucythrinate, flumethrin, fluvalinate, permethrin, resmethrin and tralomethrin;
Nitroimines and nitromethylenes such as 1 - [(6-chloro-3-pyridinyl) methyl] -4,5-dihydro-N-nitro-1H-imidazol-2-amine (imidacloprid), N - [(6-chloro-3 -pyridyl) methyl-] N²-cyano-N¹-methylacetamide (NI-25),
Abamectin, AC 303,630, Acephate, Acrinathrin, Alanycarb, Aldoxycarb, Aldrin, Ammoniumbifluoride, Amitraz, Azamethiphos, Bacillus thuringiensis, Phosmet, Phosphamidon, Phosphine, Prallethrin, Propaphos, Propetamphos, Prothoate, Pyrethridospyphin, Pyridhrinphosyphin, Pyridhrinophyphid, Pyridhridos, Pyridhrinphyphid, Pyridhridos, Pyridhridos, Pyridhridos, Pyridhridos, Pyridhridos , RH-7988, Rotenone, Sodium fluonde, Sodium hexafluorosilicate, Sulfotep, Sulfuryl fluoride, Tar Oils, Teflubenzuron, Tefluthrm, Temephos, Terbufos, Tetrachlorvinphos, Tetramethrin, O-2-tert.-Butyl-pyflmid-o-5-yl isopropyl-phosphorothiate, thio cyclam, thiofanox, thiometone, tralomethrin, triflumuron, trimethacarb, vamidothion, verticillium lacanii, XMC, xylylcarb, benfuracarb, bensultap, bifenthrin, bioallethrin, MERbioomercyclophone, bromine-cyclophrine, bromine-isoprophenyl, bromomethropene, bromomethropene, bromine, bomorphophosphate, Cadusafos, Calcium Polysulfide, Carbophenothion, Cartap, Chinomethionate, Chlordane, Chlorfenvinphos, Chlorfluazuron, Chlormephos, Chloropicrin, Chlorpyrifos, Cyanophos, Beta-Cyfluthrin, Alpha cype rmethrin, cyophenothrin, cyromazine, Dazomet, DDT, Demeton-S-methylsulphone, diafenthiuron, Dialifos, Dicrotophos, Diflubenzuron, Dinoseb, Dioxabenzofos, Diaxacarb, Disulfoton, DNOC, Empenthrin, Etosulffenucone, Ethenosulfofen, EP, Fenoxycarb, Fen sulfothion, Fipronil, Flucycloxuron, Flufenprox, Flufenoxuron, Fonofos, Formetanate, Formothion, Fosmethilan, Furathiocarb, Heptachlor, Hexaflumuron, Hydramethylnon, Hydrogen Cyanide, Hydroprene, IPSP, Isazofos, Isothionane, Isophenophone, Isofenphosine, Isofenphos, Isofenphos, Isofenphos, Isofenphos, Isofenphos, Iso Malathion, Mecarbam, Mephosfolan, Mercurous, chloride, Metam, Metarthician, anisopliae, Methacrifos, Methamidophos, Methidathion, Methiocarb, Methoprene, Methoxychlor, Methyl isothiocyanate, Metholcarb, Mevinphos, Monocrotophos, Naled, Neodethrone-methylfine, Oxodiprionate , Pentachlorophenol, petroleum oils, phenothrin, phenthoates, phorates;
Benzoyl ureas, such as chlorofluazuron, diflubenzuron, flufenoxuron, flucycloxuron, hexaflumuron, penfluron, teflubenzuron, other development inhibitors such as, for example, benzoic acid [2-benzoyl-1- (1,1-dimethylethyl)] hydrazide, 2,6-dimethoxy-N- [5-] 4- (pentafluoroethoxy) phenyl- [2,3,4-thiadiazol-2-yl] benzamide, N-cyclopropyl-1,3,5-triazine-2,4-triamine, 2- ( 4-phenoxyphenoxy) ethyl ethyl carbamate, 1- (decycloxy) -4 - [(6-methoxy-4-hexynyl) -oxy] benzene, (2-propynyl) -4-methoxy-benzoate, fenoxycarb, pyriproxyfen, triarathenes , Thiapronil, hexythiazox, clofentezine, 4-chloro-5- (6-chloro-3-pyridylmethoxy) -2- (3,4-dichlorophenyl) - pyridazin-3 (2H) -one, buprofezin, hydroprene, kinoprene, methoprene, Cycloprate, Gusathin, Padan, Paraxon, Tribunil, isomers and triprene.

If the mixtures of triflumuron, at least one fungicide and given if necessary, other fungicides or insecticides in certain proportions are mixed together, there are synergistic effects.

The weight ratios of the active ingredients can be relatively large Range can be varied.

Surprisingly, these combinations of active ingredients show a particularly high one insecticidal activity against wood-destroying insects, combined with a broad  fungicidal and bactericidal action against those relevant in material protection Microorganisms.

The following wood-destroying insects are mentioned as examples - but without limitation:
Beetle
Hylotrupes bajulus, Chlorophorus pilosis, Ahobium punctatum, Xestobium rufovillosum, Ptilinus pecticornis, Dendrobium pertinex, Ernobius mollis, Priobium carpini, Lyctus brunneus, Lyctus africanus, Lyctus planicollis, Lyctus linearesces, Lyctus pubis linearis, Lyctus pubis linearis, Lyctus pubis aisles Tryptodendron spec. Apate monachus, Bostrychus capucins, Heterobostrychus brunneus, Sinoxylon spec. Dinoderus minutus
Skin wing
Sirex juvencus, Urocerus gigas, Urocerus gigas taignus, Urocerus augur
Termites
Kalotermes flavicollis, Cryptotermers brevis, Heterotermes indicola, Reticulitermes flavipes, Reticulitermes santonensis, Reticulitermes lucilugus, Mastotermes darwiniensis, Zootermopsis nevadensis, Coptotermes formosanus.

The following groups of microorganisms may be mentioned as examples - but without limitation:
A: Wood-staining fungi:
A1: Ascomycetes:
Ceratocystis such as Ceratocystis minor
A2: Deuteromycetes:
Aspergillus like Aspergillus niger
Aureobasidium such as Aureobasidium pullulans
Dactylium such as Dactylium fusarioides
Penicillium such as Penicillium brevicaule or Penicillium variabile
Sclerophoma such as Sclerophoma pithyophila
Scopularia like Scopularia phycomyces
Trichoderma such as Trichoderma viride or Trichoderma lignorum
A3: Zygomycetes:
Mucor like Mucor spinorus
B: Wood-destroying mushrooms:
B1: Ascomycetes:
Chaetomium such as Chaetomium globosum or Chaetomium alba-arenulum
Humicola like Humicola grisea
Petriella like Petriella setifera
Trichurus like Trichurus spiralis
B2: Basidiomycetes:
Coniophora like Coniophora puteana
Coriolus like Coriolus versicolor
Donkioporia like Donkioporia expansa
Glenospora such as Glenospora graphii
Gloeophyllum such as Gloeophyllum abietinum or
Gloeophyllum adoratum or Eq. protactum or
Gloeophyllum sepiarium or Gl. trabeum
Lentinus such as Lentinus or cyathiformes
Lentinus edodes like Lentinus lepideus or
Lentinus grinus or L. squarrolosus
Paxillus such as Paxillus panuoides
Pleurotus like Pleurotus ostreatus
Poria such as Poria monticola or Poria placenta or
Poria vaillantii or Poria vaporaria
Serpula such as Serpula himantoides or Serpula lacrymans
Stereum like Stereum hirsutum
Tyromyces such as Tyromyces palustris
B3: Deuteromycetes:
Alternaria such as Alternaria tenius
Cladosporium like Clasdosporium herbarum.

The amount of agents or concentrates used depends on the type and type come from insects, microorganisms, the number of bacteria and from the medium dependent. The optimal amount can be used in each case Test series can be determined. In general, however, it is sufficient from 0.001 to 20 wt .-%, preferably 0.05 to 10 wt .-%, based on the active ingredient mixture on the material to be protected.

The active ingredient mixture can be used as such, in the form of concentrates or in general usual formulations such as powders, granules, solutions, suspensions, emul sions or pastes.

The formulations mentioned can be prepared in a manner known per se be, e.g. B. by mixing the active ingredients with at least one solution or diluent, emulsifier, dispersing and / or binding or fixing agent tels, water repellants, possibly desiccants and UV stabilizers and opp if necessary dyes and pigments and other processing aids.

An organic chemical solvent serves as the solvent and / or diluent solvent or solvent mixture and / or an oily or oily heavy volatile organic chemical solvent or solvent mixture and / or a polar organic chemical solvent or solvent combination mixed and / or water and at least one emulsifier and / or wetting agent or consists of it.  

The organic chemical solvents used are preferably oily or oily ones Solvents with an evaporation number above 35 and a flash point above half 30 ° C, preferably above 45 ° C, used. As such volatile, water-insoluble, oily and oily solvents become corresponding mine ralöle or their aromatic fractions or mineral oil-containing solvent mixtures cal, preferably white spirit, petroleum and / or alkylbenzene used.

Mineral oils with a boiling range of 170 to 220 ° C are advantageous, test petrol with a boiling range of 170 to 220 ° C, spindle oil with a boil range from 250 to 350 ° C, petroleum or aromatics with a boiling range of 160 up to 280 ° C, turpentine oil and the like.

In a preferred embodiment, liquid aliphatic hydrocarbons substances with a boiling range of 180 to 210 ° C or high-boiling mixtures of aromatic and aliphatic hydrocarbons with a boiling range from 180 to 220 ° C and / or locker oil and / or monochloronaphthalene, preferably two se α-monochloronaphthalene used.

The organic non-volatile oily or oily solvents with a Evaporation rate above 35 and a flash point above 30 ° C, preferably above 45 ° C, can be partially organic or slightly volatile chemical solvents are replaced, provided that the solvent mix also an evaporation number above 35 and a flash point above 30 ° C, preferably above 45 ° C, and that the insecticide fungicide Mixture is soluble or emulsifiable in this solvent mixture.

According to a preferred embodiment, part of the organic chemical Solvent or solvent mixture or an aliphatic polar organization niche chemical solvent or solvent mixture replaced. Preferably come alipha containing hydroxyl and / or ester and / or ether groups organic chemical solvents such as glycol ether, esters or the like for use.

As an organic chemical binder in the present Er finding the known water-dilutable and / or in the used  organic chemical solvents soluble or dispersing or emul gable synthetic resins and / or binding drying oils, especially binders consisting of or containing an acrylic resin, a vinyl resin, e.g. B. polyvinyl acetate, Polyester resin, polycondensation or polyaddition resin, polyurethane resin, alkyd resin or modified alkyd resin, phenolic resin, hydrocarbon resin such as indene Coumarone resin, silicone resin, drying vegetable and / or drying oils and / or physically drying binders based on a natural and / or Resin used.

The synthetic resin used as a binder can be in the form of an emulsion, disper sion or solution. Bitumen or bituminous substances up to 10 wt .-%, are used. In addition, you can dyes, pigments, water-repellants, odor correctors known per se tien and inhibitors or corrosion protection agents and the like. Be used.

According to the invention, preference is given to organic chemical binders least an alkyd resin or modified alkyd resin and / or a drying one vegetable oil contained in the medium or in the concentrate. According to the invention alkyd resins with an oil content of more than 45 wt .-%, preferably 50 to 68% by weight.

The binder mentioned can be wholly or partly by a fixation medium (mixture) or a plasticizer (mixture) can be replaced. These additions should volatilize the active ingredients and crystallize or from prevent cases. They preferably replace 0.01 to 30% of the binder (based on 100% of the binder used).

The plasticizers come from the chemical classes of phthalic acid esters such as Dibutyl, dioctyl or benzyl butyl phthalate, phosphoric acid esters such as tributyl phosphate, adipic acid esters such as di- (2-ethylhexyl) adipate, stearates such as butyl stearate or amyl stearate, oleates such as butyl oleate, glycerol ether or higher molecular weight Gly kolether, glycerol ester and p-toluenesulfonic acid ester.

Fixing agents are chemically based on polyvinyl alkyl ethers such as. B. Polyvinyl methyl ether or ketones such as benzophenone, ethylene benzophenone.  

Water can also be used as a solvent or diluent if mixed with one or more of the above organic chemical solvents or diluents, emulsifiers and dispersants.

Under wood, which by the agent according to the invention or containing it Mixtures that can be protected are to be understood as examples: construction timber, wood beams, railway sleepers, bridge parts, jetties, wooden vehicles, boxes, Pallets, containers, telephone poles, wooden cladding, wooden windows and doors, Plywood, particle board, carpentry or wood products, all in general used in house building or in carpentry.

A particularly effective wood protection is provided by industrial impregnation drive, e.g. B. vacuum, double vacuum or printing process.

The insecticidal agents used to protect wood and wood-based materials or concentrates contain the active ingredient combination in a concentration of 0.01 to 95% by weight, in particular 0.01 to 60% by weight.

Preferred agents (ready-to-use agents) preferably contain 0.2 to 3 wt .-%, in particular 0.5 to 2 wt .-% of triflumuron in a mixture with the Fungicide, optionally 0.005 to 1% by weight, preferably 0.01 to 0.5% by weight another insecticide or fungicide and at least one organic chemical cal solvent or solvent mixture and / or an oily or oily semi-volatile organic chemical solvent or solvent mixture and / or a polar organic chemical solvent or solvent combination mixed and / or water and emulsifier and / or wetting agent and optionally 0 up to 5% by weight, preferably 0.1 to 3% by weight of fixative and / or others Additive as a residual ingredient.

Particularly preferred (ready-to-use) agents contain 2 to 30% by weight preferably 5 to 22% by weight, calculated as a solid, of a synthetic resin binder, preferably an alkyd resin and / or a drying vegetable oil as well at least one organic chemical solvent or solvent mixture and / or an oily or oily low volatile organic chemical solution  medium or solvent mixture and / or a polar organic chemical solvent solvent or solvent mixture and / or water and emulsifier and / or Wetting agents and possibly desiccants, dyes, color pigments, anti settling agents and / or UV stabilizers as a residual component.

Concentrates for preserving wood and wood-based materials preferably contain as 0.2 to 25 wt .-%, preferably 3 to 8 wt .-% of triflumuron in Mi. with the fungicide, 0.05 to 5% by weight, preferably 0.5 to 1% by weight a further insecticide or fungicide, 5 to 40% by weight, preferably 10 to 30% by weight (calculated as a solid) of at least one organic chemical bin detergent and / or fixative or plasticizer and an additional organic chemical solvent or solvent mixture and / or a oily or oily semi-volatile organic chemical solvent or Solvent mixture and / or a polar organic chemical solvent or solvent mixture and / or a penetration aid and / or water and contains an emulsifier and / or wetting agent as a residual component.

The agents according to the invention advantageously enable the previously ver to replace available insecticidal agents with more effective ones. You show a good one Stability and advantageously have a broad spectrum of activity.

Claims (14)

1. Wood preservative containing triflumuron and at least one itself synergistically complementary active ingredient. 2. Wood preservative according to claim 1 additionally containing at least Another azole fungicide. 3. Medium or concentrate for preserving wood and wood-based materials based on or with the use of triflumuron and minde least a solvent, diluent and / or additive, because characterized in that the agent or concentrate 0.01 to 25 wt .-% of triflumuron in a mixture with 0.1 to 99.9% by weight of at least one Azole and more than 40 wt .-% of a mixture of solution and / or Diluent and / or organic chemical binder and / or Fixative, processing agent, dye, pigment, dye or Contains pigment mixture. 4. agent or concentrate according to claim 3, characterized in that the Solvent and / or diluent is an organic chemical solution medium or solvent mixture and / or an oily or oily semi-volatile organic chemical solvent or solvent mixture and / or a polar organic chemical solvent or Solvent mixture and / or water and at least one emulsifier and / or contains or consists of wetting agents. 5. Wood preservative according to one or more of claims 1 to 4, characterized in that it is as azole
Azaconazole:
1 - {[2- (2,4-dichlorophenyl) -1,3-dioxolan-2-yl] methyl} 1-H-1,2,4-triazole
Propiconazole:
1- [2- (2,4-dichlorophenyl) -4-propyl-1,3-dioxolan-2-yl] methyl-1-H-1,2,4-triazole
Tebuconazole:
1-p-chlorophenyl-4,4-dimethyl-3 (1H-1,2,4-triazol-1-yl-methyl) pentan-3-ol
Cyproconazole:
2- (4-chlorophenyl) -3-cyclopropyl-1- (1H-1,2,4-triazol-1-yl) butan-2-ol-
2- (1-chloro-cyclopropyl) -1- (2-chlorophenyl) -3-1H- (1,2,4-triazol-1yl) -propanan-2-ol
2- (tert-butyl) -1- (2-chlorophenyl) -3-1H- (1,2,4-triazol-1-yl) propan-2-ol
and / or hexaconazole or metconazole
contains. 6. Medium or concentrate for preserving wood and wood-based materials according to one or more of claims 2 to 5, characterized in that that the further azoles from 0 to 50 wt .-%, preferably from 0.5 to 25 wt .-%, are included. 7. Wood preservative according to one or more of claims 1 to 5, characterized in that it is an additional insecticide, chlorpyrifos, Phoxim, silafluofen, cyfluthrin, cypermethrin, deltamethrin, permethrin, Contains imidacloprid, hexaflumuron and / or lindane. 8. Means for preserving wood and wood-based materials according to one or several of claims 1 to 7, characterized in that the agent (ready-to-use agents) 0.2 to 3% by weight of the azoles, 0.005 to 1 wt .-%, preferably 0.01 to 0.5 wt .-% of the insecticide and min an organic chemical solvent or solvent mixture and / or an oily or oily semi-volatile organic chemical Solvent or solvent mixture and / or a polar organic chemical solvent or solvent mixture and / or water and Emulsifier and / or wetting agent and optionally 0 to 5% by weight,  preferably 0.1 to 3 wt .-% fixative and / or other additive contains medium as a residual component. 9. Means for preserving wood and wood-based materials according to one or several of claims 1 to 7, characterized in that the agent (ready-to-use agents) 0.2 to 3 wt .-%, preferably 0.5 to 2% by weight of the azoles, 0.005 to 1% by weight, preferably 0.01 to 0.5% by weight of the insecticide, 2 to 30% by weight, preferably 5 to 22% by weight, calculated as a solid, of a synthetic resin binder preferably an alkyd resin and / or a drying vegetable oil and at least one organic chemical solvent or solvent mixture and / or an oily or oily semi-volatile organic chemical solvent or solvent mixture and / or a polar organic chemical solvent or solvent mixture and / or Water and emulsifier and / or wetting agent and optionally desiccants, Dyes, color pigments, anti-settling agents and / or UV stabilizers as Contains residual ingredient. 10. Concentrate for preserving wood and wood-based materials after one or more of claims 1 to 7, characterized in that the Concentrate 0.2 to 25% by weight, preferably 3 to 8% by weight of the azoles, 0.05 to 5% by weight, preferably 0.5 to 1% by weight of the insecticide, 5 to 40% by weight, preferably 10 to 30% by weight (calculated as a solid) at least one organic chemical binder and / or fixation by means of or plasticizer as well as an additional organic chemical solvent solvent or solvent mixture and / or an oily or oily semi-volatile organic chemical solvent or solvent mixture and / or a polar organic chemical solvent or Lö solvent mixture and / or a penetration aid and / or water and contains an emulsifier and / or wetting agent as a residual component. 11. Medium or concentrate for preserving wood and wood-based materials according to one or more of claims 1 to 10, characterized in net that the agent or concentrate free of aromatic oxyalcohols is.   12. Medium or concentrate for preserving wood and wood-based materials according to one or more of claims 1 to 11, characterized in net that part of the organic chemical solvent or solution medium mixture through an aliphatic polar organic chemical solvent solvent or solvent mixture, preferably a hydroxy and / or aliphatic orga containing ester and / or ether groups niche chemical solvent or solvent mixture is replaced. 13. Process for preserving wood and wood-based materials, thereby ge indicates that an agent according to claims 1 to 12 on the Wood or the wood-based materials applied or mixed with the means. 14. Use of the agent according to claims 1 to 12 for preservation of wood and wood-based materials.