JP4730935B2 - Mold antiseptic composition for wood - Google Patents

Description

  The present invention relates to a fungicide and antiseptic composition for wood, which is used for preventing the occurrence of mold or decaying fungi on wood.

  In recent years, organic fungicides with higher safety have been used as wood fungicides instead of compounds such as halogenated phenols. For example, compounds such as 4,5-dichloro-2-n-octylisothiazolin-3-one (hereinafter abbreviated as COIT) are provided and are often added to prevent the occurrence of mold in wood. However, the use of a single component of COIT alone has a problem that sufficient efficacy cannot be obtained due to the limited species of microorganisms having efficacy, the amount of drug used increases, and the cost increases. In addition, methyl 2-benzimidazolecarbamate (hereinafter abbreviated as BCM) is known as a highly safe anti-fungal agent for wood. If the concentration is not significantly increased, sufficient efficacy cannot be obtained, and the antifungal agent is remarkably unsuitable (Patent Document 1).

For this reason, various antifungal agents have been combined to try to stabilize the antifungal spectrum and enhance the antifungal efficacy, but usually only one of the effects is achieved or only an additive effect is obtained. There is no actual situation. For example, a method of combining a benzimidazole compound and an isothiazoline compound has been proposed (Patent Document 2).
However, fungi that grow on wood include molds and decaying fungi. Recently, many damages caused by decaying fungi have been seen.

On the other hand, N-substituted triazole fungicides are used for agricultural applications and wood preservative applications. For example, a microbicide (Patent Document 3) composed of an azole-based bactericidal / fungicidal agent and an iodopropargyl derivative, a preservative containing a triazole compound, a polybasic acid ester compound, an alcohol compound, or a polyoxyalkylene type emulsifier has been proposed. (Patent Document 4).
These are used for wood preservatives, but have a problem that the spectrum is narrow and the generation of mold cannot be suppressed.

JP-A-61-97204 JP-A-3-251508 JP-A-5-132405 JP-A-7-304609

  It is an object of the present invention to provide a fungicidal and antiseptic composition for wood having an excellent control effect against not only molds generated on wood but also decaying fungi.

  As a result of earnest research on the antifungal composition for wood fungi, the present inventor is generated in wood by mixing COIT, BCM and one or more of N-substituted triazole fungicidal compounds as active ingredients. It has been found that it exhibits a high control effect against mold and decaying fungi. In particular, N-substituted triazole fungicides include α- [2- (4-chlorophenyl) ethyl] -α- (1,1-dimethylethyl) -1H-1,2,4-triazole-1-ethanol (hereinafter referred to as Tebuconazole) and 1-[[2- (2,4-dichlorophenyl) -4-n-propyl-1,3-dioxolan-2-yl] methyl] -1H-1,2,4-triazole (hereinafter, Two kinds of propiconazole) or 2- (2,4-dichlorophenyl) -1- (1H-1,2,4-triazol-1-yl) -2-hexanol (hereinafter abbreviated as hexaconazole) ) Was found to be desirable, and the present invention was completed.

  Antifungal and antiseptic effects were observed by applying the composition of the present invention to wood.

Although the antifungal composition for wood of the present invention can be directly applied according to the purpose of use, it is generally used as a dosage form such as an oil agent, an emulsion, a paste agent or a suspension agent.
The solvent used in the preparation is not particularly limited as long as it dissolves the active ingredient used in the composition of the present invention, and polar solvents include ethylene glycol, propylene glycol, diethylene glycol, triethylene glycol, dipropylene glycol. , Glycol solvents such as hexylene glycol and polyethylene glycol, glycol ether solvents such as diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, alcohol solvents such as isopropyl alcohol and ethanol, dimethylacetamide, dimethyl sulfoxide, γ- A solvent such as butyrolactone, methyl ethyl ketone or water can be used. These may be used alone or in combination of two or more.

  Non-polar solvents include plasticizers such as dioctyl phthalate, diisononyl phthalate, diisononyl adipate, diisobutyl adipate, xylol, toluene, isophorone, phenylxylylethane, diethylene glycol monobutyl ether acetate, propylene carbonate, liquid paraffin, kerosene, Solvents such as coconut oil, rapeseed oil, cottonseed oil, castor oil or soybean oil can be used. These may be used alone or in combination of two or more. Two or more polar solvents and nonpolar solvents may be combined. Surfactants may or may not be used. When they are used, any of nonionic surfactants, anionic surfactants, cationic surfactants, and amphoteric surfactants may be used. Absent.

  Examples of nonionic surfactants include polyoxyethylene alkyl phenyl ether, polyoxyethylene styryl phenyl ether, polyoxyethylene alkyl ether, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, and the like. Examples thereof include alkylbenzene sulfate, polyoxyethylene alkyl ether sulfate, polyoxyethylene alkylphenyl ether sulfate, and dialkyl sulfosuccinate. Examples of cationic surfactants include aliphatic amine salts and quaternary ammonium salts thereof. Examples of amphoteric surfactants include, but are not limited to, betaine surfactants and aminocarboxylates. These nonionic surfactants, anionic surfactants, cationic surfactants and amphoteric surfactants may be used alone or in combination of two or more.

The content of the active ingredient in the composition of the present invention is such that the total amount of N-substituted triazole fungicidal compounds is larger than the amount of 4,5-dichloro-2-n-octylisothiazolin-3-one and 4,5 The total amount of 2-dichloro-2-n-octylisothiazolin-3-one and methyl 2-benzimidazole carbamate is preferably larger than the total amount of N-substituted triazole fungicides, and is extremely excellent in the case of the above mixing ratio Antifungal and antiseptic effects can be obtained.
In addition, other fungicides, bactericides, insecticides, rust inhibitors, deterioration inhibitors and the like can be used in combination.

  The compositions of Examples 1 and 2 and Comparative Examples 1 to 12 are shown in Table 1. In Comparative Examples 1, 3, 4, 5, 6, 8, 10, and 11, the compositions shown in Table 1 were obtained by normal stirring at room temperature. In addition, Examples 1, 2, and Comparative Examples 2, 7, 9, and 12 are mixed in the composition shown in Table 1, glass beads having a diameter of 1 mm are mixed, pulverized for about 15 minutes using a pearl mill, and filtered through a wire mesh. To obtain a composition.

*1：ポリオキシエチレンスチリルフェニルエーテル
*2：ジエチレングリコールモノブチルエーテル

* 1: Polyoxyethylene styryl phenyl ether
* 2: Diethylene glycol monobutyl ether

Test Example 1 Antifungal test of wood Spruce pine sapwood (2 cm x 5 cm x 0.3 cm) in the solution of the antifungal composition for wood of Examples and Comparative Examples diluted to a specified concentration with water Was dipped for 30 seconds and then air-dried. This test piece was placed on a potato dextrose agar medium (hereinafter referred to as PDA medium), and 1 ml of a mixed spore suspension was sprinkled and cultured at 26 ° C. and 95% humidity for 28 days. As test bacteria, Aspergillus niger, Penicillium funiculosum, Aureobasidium pullulans, Gliocladium virens, and Cladosporium cladosporioides were used. The results are shown in Table 2. However, the indication of the degree of mold growth was based on the following criteria.

-: No mold growth was observed on the test piece.
+: Mold growth is observed on the side of the test piece.
++: The area of the mold growth part on the test piece is less than 1/3 of the total area.
+++: The area of the mold growth part on the test piece is 1/3 or more of the total area.

Test Example 2 Wood Preservation Test After a PDA medium was solidified in a petri dish, a wood decay fungus Trametes versicolor was collected and pre-cultured at 26 ° C. and 90% relative humidity for 1 week. A test piece was prepared by immersing Scots pine sapwood (2 cm × 5 cm × 0.3 cm) in the solutions of the compositions of Examples and Comparative Examples diluted to a specified concentration with water for 30 seconds and then air-dried. . After pre-culture, the test piece was placed on the medium on which the bacteria had grown and cultured at 26 ° C. and 90% relative humidity for 28 days.
The results are shown in Table 2. However, the indication of the degree of decaying fungus growth was based on the following criteria.

-: No growth of rotting fungus is observed on the test piece.
+: Growth of decaying fungus is observed on the side of the test piece.
++: The area of the growth part of the decaying fungi on the test piece is less than 1/3 of the total area.
+++: The area of the growth part of the decaying fungus on the test piece is 1/3 or more of the total area.

表２の結果から明らかなように、本発明組成物は比較例に比べ、カビ及び腐朽菌に対して著しい効力が認められた。

As is clear from the results in Table 2, the composition of the present invention was significantly more effective against mold and decaying fungi than the comparative example.

The composition of the present invention exhibits a high fungicidal and antiseptic effect against fungi and decaying fungi generated on wood, and can be used as a fungicide and antiseptic for wood in the wood, plywood and laminated wood industries.

Claims (3)

4,5-dichloro-2-n-octylisothiazolin-3-one, methyl 2-benzimidazole carbamate and α- [2- (4-chlorophenyl) ethyl] -α- (as N-substituted triazole fungicide 1,1-dimethylethyl) -1H-1,2,4-triazole-1-ethanol, 1-[[2- (2,4-dichlorophenyl) -4-triazole or 2- (2,4-dichlorophenyl)- Fungi and basidiomycetes characterized by containing one or more fungicides selected from 1- (1H-1,2,4-triazol-1-yl) -2-hexanol as active ingredients A fungicidal antiseptic composition for wood having a synergistic effect on rotting fungi. N- substituted triazole fungicide is alpha-[2-(4-chlorophenyl) ethyl]-.alpha.-(1,1-dimethylethyl)-1H-1,2,4-triazole-1-ethanol and 1 - [[ The antifungal antiseptic composition for wood according to claim 1, which has a synergistic effect on mold and basidiomycete rot fungi, comprising 2- (2,4-dichlorophenyl) -4-triazole. To claim 1, characterized in that N- substituted triazole fungicide consists 2- (2,4-dichlorophenyl) -1- (IH-1,2,4-triazol-1-yl) -2-hexanol The fungicidal antiseptic composition for wood having a synergistic effect on the fungi and basidiomycete- rotting fungi as described.