JP2009519124A - フィッシャー・トロプシュ反応用触媒体 - Google Patents
フィッシャー・トロプシュ反応用触媒体 Download PDFInfo
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- JP2009519124A JP2009519124A JP2008545002A JP2008545002A JP2009519124A JP 2009519124 A JP2009519124 A JP 2009519124A JP 2008545002 A JP2008545002 A JP 2008545002A JP 2008545002 A JP2008545002 A JP 2008545002A JP 2009519124 A JP2009519124 A JP 2009519124A
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- catalyst
- catalyst body
- synthesis gas
- porous
- normally
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- 239000003054 catalyst Substances 0.000 title claims abstract description 140
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 41
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 40
- 239000007788 liquid Substances 0.000 claims abstract description 37
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 26
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 26
- 238000000034 method Methods 0.000 claims abstract description 23
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 14
- 230000008569 process Effects 0.000 claims abstract description 14
- 239000007787 solid Substances 0.000 claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims description 23
- 229910052751 metal Inorganic materials 0.000 claims description 14
- 239000002184 metal Substances 0.000 claims description 14
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 10
- 229910017052 cobalt Inorganic materials 0.000 claims description 10
- 239000010941 cobalt Substances 0.000 claims description 10
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- 239000012018 catalyst precursor Substances 0.000 claims description 7
- 229910052720 vanadium Inorganic materials 0.000 claims description 7
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 6
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 5
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
- 229910052697 platinum Inorganic materials 0.000 claims description 4
- 229910052726 zirconium Inorganic materials 0.000 claims description 4
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 3
- 238000004517 catalytic hydrocracking Methods 0.000 claims description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 3
- 229910052763 palladium Inorganic materials 0.000 claims description 3
- 229910052707 ruthenium Inorganic materials 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 239000011888 foil Substances 0.000 claims description 2
- 238000011065 in-situ storage Methods 0.000 claims description 2
- 229910052702 rhenium Inorganic materials 0.000 claims description 2
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 2
- 229910001220 stainless steel Inorganic materials 0.000 claims description 2
- 239000010935 stainless steel Substances 0.000 claims description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 2
- 230000002194 synthesizing effect Effects 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 abstract description 22
- 239000002002 slurry Substances 0.000 abstract description 22
- 239000002245 particle Substances 0.000 abstract description 14
- 239000007795 chemical reaction product Substances 0.000 abstract description 7
- 239000007789 gas Substances 0.000 description 30
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 10
- 230000032258 transport Effects 0.000 description 9
- 239000010410 layer Substances 0.000 description 8
- 239000012071 phase Substances 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 238000012546 transfer Methods 0.000 description 8
- 238000001816 cooling Methods 0.000 description 7
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- 229910002091 carbon monoxide Inorganic materials 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 5
- 229910052748 manganese Inorganic materials 0.000 description 5
- 239000011572 manganese Substances 0.000 description 5
- 230000000737 periodic effect Effects 0.000 description 5
- 239000000376 reactant Substances 0.000 description 5
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 5
- 239000007791 liquid phase Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 229910000510 noble metal Inorganic materials 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910052776 Thorium Inorganic materials 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- 229910052768 actinide Inorganic materials 0.000 description 1
- 150000001255 actinides Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 238000005219 brazing Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000003426 co-catalyst Substances 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 238000007037 hydroformylation reaction Methods 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000009828 non-uniform distribution Methods 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Classifications
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
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- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/248—Reactors comprising multiple separated flow channels
- B01J19/2485—Monolithic reactors
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/462—Ruthenium
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- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
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- B01J23/75—Cobalt
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- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/847—Vanadium, niobium or tantalum or polonium
- B01J23/8472—Vanadium
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- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/889—Manganese, technetium or rhenium
- B01J23/8892—Manganese
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- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
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- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
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- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
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- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
- B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0425—Catalysts; their physical properties
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/34—Apparatus, reactors
- C10G2/342—Apparatus, reactors with moving solid catalysts
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- B01J2208/00654—Controlling the process by measures relating to the particulate material
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Abstract
【解決手段】フィッシャー・トロプシュ触媒と、寸法が1〜50mmの多孔質体とを含む、内部間隙率が50〜95%の触媒体;及び三相反応器中に合成ガスを導入する工程、及び合成ガスを高温で非定常触媒と接触、転化させて、通常ガス状、通常液体及び任意に通常固体の炭化水素を得る工程であって、該触媒は、寸法が1〜50mmの複数の多孔質体上に配置され、こうして触媒体が形成されると共に、該触媒体は、前記反応器中の現場で5〜60%の外部間隙率と、触媒体内に50〜95%の気孔率とを有する該工程を含む、合成ガスからの前記炭化水素の製造法。
【選択図】なし
Description
本発明の他の目的は、以下の詳細な説明から明らかになろう。
(i)合成ガスを三相反応器に導入する工程、及び
(ii)合成ガスを、寸法が1〜50mmの複数の多孔質体上に配置された非定常触媒と接触させ、合成ガスを高温高圧下に接触転化して、通常ガス状、通常液体及び任意に通常固体の炭化水素を得る工程、
を含む、三相反応器中で合成ガスから通常ガス状、通常液体及び任意に通常固体の炭化水素を製造する方法を提供する。
好ましい実施態様では多孔質体の寸法は1〜30mmである。
多孔質体は、規則的又は不規則的な形状又はそれらの混合形状であってよい。このような形状としては、円筒形、立方形、球形、卵形等の他、造形多角形が挙げられる。一般に“寸法”は、内部の真直ぐな最長長さとみなし得る。
多孔質体は、前述のような形態の組合わせであってよいことは明らかである。例えば多孔質体は、ハネカム形材料で構成され、かつ外側が円形であってよい。他の例は、織マット製の円筒である。
触媒体、即ち、その上に触媒が塗布された多孔質体、の外部間隙率は、反応器中の現場で5〜60%、好ましくは40容量%未満、更に好ましくは約20容量%である。
合成ガスの転化による通常ガス状、通常液体及び通常固体の炭化水素は、それぞれ室温、約1気圧でガス状、液体及び固体である。
触媒又は触媒材料、或いはその前駆体は、多孔質体に、通常、約1〜約300μ、好ましくは約5〜約200μの厚さの層として塗布することが好ましい。
触媒体の触媒分率は、約1容量%以上、好ましくは約4容量%を超え(触媒体の容量に対し)、好ましくは最大25容量%であることが好ましい。
好適な金属酸化物促進剤は、元素の周期表第2〜7族、又はアクチニド及びランタニドから選んでよい。特にマグネシウム、カルシウム、ストロンチウム、バリウム、スカンジウム、イットリウム、ランタン、セリウム、チタン、ジルコニウム、ハフニウム、トリウム、ウラン、バナジウム、クロム及びマンガン、の酸化物は特に好適な促進剤である。
合成ガスは、スラリー反応器中に0.4〜2.5、好ましくは1.0〜2.5の範囲のモル比で導入された水素及び一酸化炭素である。
(i)合成ガスを供給する工程、及び
(ii)合成ガスを触媒材料と接触させ、工程(i)の合成ガスを高温高圧下に接触転化して、通常ガス状、通常液体及び任意に通常固体の炭化水素を得る工程、
を含む、合成ガスから通常ガス状、通常液体及び任意に通常固体の炭化水素を製造する方法に使用する方法も提供する。
フィッシャー・トロプシュ合成は当業者に周知で、水素と一酸化炭素とのガス状混合物を反応条件下、フィッシャー・トロプシュ触媒と接触させる炭化水素の合成を含む。好適なスラリー液は、当業者に公知である。通常、スラリー液の少なくとも一部は、発熱反応の反応生成物である。スラリー液は、ほぼ完全な反応生成物(又は生成物)であることが好ましい。
フィッシャー・トロプシュ合成は、好ましくは125〜350℃、更に好ましくは175〜275℃、最も好ましくは180〜260℃の範囲の温度で行なわれる。圧力は、好ましくは5〜150バール絶対圧、更に好ましくは5〜80バール絶対圧の範囲である。
当業者ならば、特定の反応器の配置構成及び反応計画に対し最も適した条件を選択できることは理解されよう。
Claims (18)
- フィッシャー・トロプシュ触媒又は触媒前駆体と、寸法が1〜50mm、好ましくは1〜30mmの多孔質体とを含む、内部間隙率が50〜95%の触媒体。
- 多孔質体が、ガーゼ、ハネカム、単一体、メッシュ、ウエッビング、スポンジ、フォイル構造物、又は織マットの形態を有する請求項1に記載の触媒体。
- 多孔質体が、耐火性酸化物、金属又はそれらの混合物よりなる群から選ばれた材料から形成される請求項1又は2に記載の触媒体。
- 多孔質体が、チタニア、シリカ、ジルコニア、アルミナ及びそれらの混合物よりなる群から選ばれた耐火性酸化物材料から形成される請求項3に記載の触媒体。
- 多孔質体が、ステンレス鋼から形成される請求項3に記載の触媒体。
- 触媒体内の開放容積が、60%を超え、好ましくは70%を超え、更に好ましくは80%を超える請求項1〜5のいずれか1項に記載の触媒体。
- 触媒又は触媒前駆体が、多孔質体上に、平均厚さが約1〜300μ、好ましくは約5〜約200μの層として配置される請求項1〜6のいずれか1項に記載の触媒体。
- 触媒体の触媒分率が、触媒体の容量に対し約1容量%以上、好ましくは約4容量%以上である請求項1〜7のいずれか1項に記載の触媒体。
- (i)三相反応器中に合成ガスを導入する工程、及び
(ii)合成ガスを非定常触媒と接触させて、該合成ガスを高温で接触転化させ、これにより通常ガス状、通常液体及び任意に通常固体の炭化水素を得る工程であって、該触媒は、寸法が1〜50mm、好ましくは1〜30mmの複数の多孔質体上に配置され、こうして触媒体が形成されると共に、該触媒体は、前記反応器中の現場で5〜60%の外部間隙率と、触媒体内に50〜95%の気孔率とを有する該工程、
を含む、三相反応器中で合成ガスから通常ガス状、通常液体及び任意に通常固体の炭化水素を製造する方法。 - 触媒体が、請求項1〜8のいずれか1項以上に記載の触媒体である請求項9に記載の方法。
- 工程(ii)の触媒が、多孔質体上の層として複数の多孔質体上に配置される請求項9又は10に記載の方法。
- 多孔質体上の触媒層の平均厚さが、約1〜300μ、好ましくは約5〜約200μである請求項11に記載の方法。
- 触媒の活性成分が、コバルト、鉄、ルテニウム及びそれらの混合物よりなる群、好ましくはコバルト、から選ばれる請求項9〜12のいずれか1項に記載の方法。
- 工程(ii)で更に促進剤が使用される請求項9〜13のいずれか1項に記載の方法。
- 促進剤が、ジルコニウム、マンガン、バナジウム、レニウム、白金及びパラジウム及びそれらの混合物、好ましくはマンガン、バナジウム及びそれらの混合物よりなる群から選ばれる請求項14に記載の方法。
- 更に水素化分解及び/又は水素化処理工程を含む請求項9〜15のいずれか1項に記載の炭化水素の合成方法。
- 請求項9〜16のいずれか1項に記載の方法で製造された炭化水素。
- 請求項1〜8のいずれか1項に定義した触媒体を、
(i)合成ガスを供給する工程、及び
(ii)合成ガスを触媒材料と接触させ、工程(i)の合成ガスを高温高圧下に接触転化して、通常ガス状、通常液体及び任意に通常固体の炭化水素を得る工程、
を含む、合成ガスから通常ガス状、通常液体及び任意に通常固体の炭化水素を製造する方法に使用する方法。
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EP05112320 | 2005-12-16 | ||
PCT/EP2006/069695 WO2007068732A1 (en) | 2005-12-16 | 2006-12-14 | Catalyst bodies for use in fischer-tropsch reactions |
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EP (1) | EP1960325A1 (ja) |
JP (1) | JP2009519124A (ja) |
AU (1) | AU2006325210B8 (ja) |
MY (1) | MY148113A (ja) |
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DE102007046297B4 (de) * | 2007-09-27 | 2016-12-22 | Süd-Chemie Ip Gmbh & Co. Kg | Neues Katalysatordesign und Herstellungsmethode für Dampfreformierungskatalysatoren |
AU2010332961B2 (en) * | 2009-12-16 | 2014-02-20 | Shell Internationale Research Maatschappij B.V. | Process for preparing a catalyst substrate from non-woven fibers |
US20120283963A1 (en) | 2011-05-05 | 2012-11-08 | Mitchell David J | Method for predicting a remaining useful life of an engine and components thereof |
GB201112028D0 (en) | 2011-07-13 | 2011-08-31 | Gas2 Ltd | Fixed bed fischer tropsch reactor |
US8889747B2 (en) | 2011-10-11 | 2014-11-18 | Bp Corporation North America Inc. | Fischer Tropsch reactor with integrated organic rankine cycle |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61227535A (ja) * | 1985-03-28 | 1986-10-09 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | 合成ガスからの有機化合物の製造方法 |
JPH03293036A (ja) * | 1990-04-06 | 1991-12-24 | Exxon Res & Eng Co | 表面含浸分散コバルト金属触媒の製造法 |
JP2003507161A (ja) * | 1999-08-17 | 2003-02-25 | バッテル・メモリアル・インスティチュート | フィッシャー・トロプシュ合成の触媒構造及び方法 |
JP2005530849A (ja) * | 2002-06-26 | 2005-10-13 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | 炭化水素の製造方法 |
JP2006505391A (ja) * | 2002-11-04 | 2006-02-16 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | 長い造形粒子、その触媒又は支持体としての使用法 |
JP2006514876A (ja) * | 2002-06-07 | 2006-05-18 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | 炭化水素合成用造形触媒粒子 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE794908A (fr) * | 1972-02-03 | 1973-08-02 | Petro Tex Chem Corp | Purification de composes insatures |
US4888317A (en) * | 1988-07-15 | 1989-12-19 | Corning Incorporated | Catalyst-agglomerate bodies encapsulated in a structure and method for their production |
US5440872A (en) * | 1988-11-18 | 1995-08-15 | Pfefferle; William C. | Catalytic method |
US5877331A (en) * | 1997-11-12 | 1999-03-02 | Huntsman Petrochemical Corporation | Prevention of catalyst attrition and tar formation in manufacture of maleic anhydride |
DE19751962A1 (de) * | 1997-11-24 | 1999-07-29 | Wacker Chemie Gmbh | Trägerkatalysator, Verfahren zu dessen Herstellung sowie Verwendung bei der Oxichlorierung von Ethylen |
AU2043400A (en) * | 1998-12-07 | 2000-06-26 | Syntroleum Corporation | Structured fischer-tropsch catalyst system and method for its application |
US6713519B2 (en) * | 2001-12-21 | 2004-03-30 | Battelle Memorial Institute | Carbon nanotube-containing catalysts, methods of making, and reactions catalyzed over nanotube catalysts |
US20040043900A1 (en) * | 2002-08-12 | 2004-03-04 | Combs Glenn A. | Heterogeneous gaseous chemical reactor catalyst |
-
2006
- 2006-12-14 WO PCT/EP2006/069695 patent/WO2007068732A1/en active Application Filing
- 2006-12-14 AU AU2006325210A patent/AU2006325210B8/en not_active Ceased
- 2006-12-14 RU RU2008129062/04A patent/RU2412926C2/ru not_active IP Right Cessation
- 2006-12-14 MY MYPI20082014A patent/MY148113A/en unknown
- 2006-12-14 US US12/097,267 patent/US20090012189A1/en not_active Abandoned
- 2006-12-14 EP EP06830613A patent/EP1960325A1/en not_active Withdrawn
- 2006-12-14 JP JP2008545002A patent/JP2009519124A/ja active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61227535A (ja) * | 1985-03-28 | 1986-10-09 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | 合成ガスからの有機化合物の製造方法 |
JPH03293036A (ja) * | 1990-04-06 | 1991-12-24 | Exxon Res & Eng Co | 表面含浸分散コバルト金属触媒の製造法 |
JP2003507161A (ja) * | 1999-08-17 | 2003-02-25 | バッテル・メモリアル・インスティチュート | フィッシャー・トロプシュ合成の触媒構造及び方法 |
JP2006514876A (ja) * | 2002-06-07 | 2006-05-18 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | 炭化水素合成用造形触媒粒子 |
JP2005530849A (ja) * | 2002-06-26 | 2005-10-13 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | 炭化水素の製造方法 |
JP2006505391A (ja) * | 2002-11-04 | 2006-02-16 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | 長い造形粒子、その触媒又は支持体としての使用法 |
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US20090012189A1 (en) | 2009-01-08 |
RU2412926C2 (ru) | 2011-02-27 |
AU2006325210A1 (en) | 2007-06-21 |
AU2006325210B8 (en) | 2010-09-23 |
AU2006325210B2 (en) | 2010-08-26 |
WO2007068732A1 (en) | 2007-06-21 |
MY148113A (en) | 2013-02-28 |
EP1960325A1 (en) | 2008-08-27 |
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