JP2009286992A - Emulsion fuel and method for producing it - Google Patents

Emulsion fuel and method for producing it Download PDF

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JP2009286992A
JP2009286992A JP2008162532A JP2008162532A JP2009286992A JP 2009286992 A JP2009286992 A JP 2009286992A JP 2008162532 A JP2008162532 A JP 2008162532A JP 2008162532 A JP2008162532 A JP 2008162532A JP 2009286992 A JP2009286992 A JP 2009286992A
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water
oil
fuel
emulsion
mixing
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Hiroto Muneta
寛人 棟田
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Yamabishi Industry Co Ltd
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Yamabishi Industry Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for producing a highly practical emulsion fuel producing high combustion energy by mixing water and a fuel oil into an emulsion at a ratio of from 7:3 to 3:7 in the stable state. <P>SOLUTION: When viscosity of water is properly regulated with a thickener derived from a plant according to the fuel oil, in both of the water-in-oil type emulsion mixing state and the oil-in-water type emulsion mixing state, uniform stirring and mixing, by which oil-water separation is stably prevented for a long period, of the fuel oil at a high water mixing ratio can be achieved by high speed shearing and the like. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

本発明は、水と燃料油を安定した状態で懸濁混合したエマルジョン燃料及びその生成方法に関するものである。  The present invention relates to an emulsion fuel in which water and fuel oil are suspended and mixed in a stable state, and a method for producing the emulsion fuel.

近年、化石燃料の急激な高騰と枯渇への危惧や燃焼時の排気ガスによる地球温暖化の防止対策として、燃料油に水をエマルジョン混合したエマルジョン燃料が開発製品化されている。  In recent years, emulsion fuels in which water is mixed with fuel oil have been developed and developed as a measure to prevent global warming due to the fear of sudden rise and depletion of fossil fuels and exhaust gas during combustion.

水と油のエマルジョン化には、油中水滴型と水中油滴型に大別されるが、従来の油に20%程度の少量の水を混入したエマルジョン燃料の殆どは油中水滴型であり、高い混合比率で安定して水を油中水滴型または水中油滴型で混入させているエマルジョン燃料は少ない。  Emulsification of water and oil is roughly classified into a water-in-oil type and an oil-in-water type, but most of the emulsion fuel in which a small amount of water of about 20% is mixed with conventional oil is a water-in-oil type. There are few emulsion fuels in which water is stably mixed at a high mixing ratio in a water-in-oil type or an oil-in-water type.

本来、水は比熱が大きく不活性であるため、燃料油に水分が混入すると燃焼エネルギーが奪われ燃焼が不安定になる。しかし安定して均一にエマルジョン化された場合、燃料組成物中の水が、沸点以上に達すると、水蒸気爆発現象を起こし、油のみを燃焼する場合よりも高い燃焼エネルギーを得られることが周知の事実とされている。  Originally, water has a large specific heat and is inactive, so if water is mixed in the fuel oil, combustion energy is lost and combustion becomes unstable. However, it is well known that when the water in the fuel composition reaches a boiling point or higher when it is stably and uniformly emulsified, a steam explosion phenomenon occurs and higher combustion energy can be obtained than when only oil is burned. It is considered a fact.

しかし、上記のような効果を得るためには、できるだけ多くの水分を、安定した状態で一定時間以上、微細な水滴として、油中にエマルジョン混合することが必要不可欠な条件となる。  However, in order to obtain the effects as described above, it is an indispensable condition to mix as much water as possible as fine water droplets in a stable state for a certain time or more in oil.

しかし、現在開発されているエマルジョン燃料の殆どは、水と油を安定して乳化状態にするために特殊な乳化剤や界面活性剤のような添加物を使用したもので、長期の安定性が得られず、添加物使用量も多いため、燃焼エネルギーを十分に得られないことが問題とされてきた。(特許第3776188号・特許第3103923号)。  However, most of the emulsion fuels currently being developed use special emulsifiers and additives such as surfactants to stabilize water and oil in an emulsified state, providing long-term stability. In addition, since a large amount of additive is used, it has been a problem that sufficient combustion energy cannot be obtained. (Patent No. 3776188 and Patent No. 3103923).

また最近では、水を共鳴電磁波や電磁場エネルギー等により水の水素結合を分離させることにより水のクラスターを微細化し、水蒸気爆発を促進することにより水を可燃剤とする方法も開発されているが、水が活性化し界面活性力が大きくなり油中に溶け込みやすくはなるが、一定量の油中含水量を超えると油水分離が早くなる傾向があり、その現象を防止する対策として、多量の塩化ナトリウム等を添加しているため塩化ナトリウム溶解物の沈殿による配液パイプのつまり等が懸念される。(特開2008−45022)。  Recently, a method has been developed in which water is made into a combustible by refining water clusters by separating water hydrogen bonds by resonance electromagnetic waves, electromagnetic field energy, etc., and promoting water vapor explosion. Water is activated and the surface activity is increased, making it easier to dissolve in oil. However, if a certain amount of water content is exceeded, oil-water separation tends to be accelerated, and as a measure to prevent this phenomenon, a large amount of sodium chloride Therefore, there is a concern about clogging of the liquid distribution pipe due to precipitation of the sodium chloride solution. (JP 2008-45022).

そこで、本発明は上記事情に鑑みてなされたものであり、植物由来の増粘剤を微量、水に添加し水、特に活性水の粘性を高めることにより、粘性が低く油水分離し易い燃料油でも安定して懸濁混合し、水自体を可燃剤としたエマルジョン燃料を生成する方法を提供することを目的としている。
特許第3776188号 特許第3103923号 特開2008−45022
Therefore, the present invention has been made in view of the above circumstances, and by adding a trace amount of a plant-derived thickener to water to increase the viscosity of water, particularly active water, the fuel oil has a low viscosity and is easy to separate into oil and water. However, the object is to provide a method of producing an emulsion fuel that is stably suspended and mixed and water itself is a combustible.
Japanese Patent No. 3776188 Japanese Patent No. 3103923 JP2008-45022

このような課題を解決するために本発明者は、植物由来の増粘剤が、水と比重差のある微粒子を、水中に均一で安定して懸濁できることを応用して、水と燃料油を安定したエマルジョン混合ができることを見出し、本発明をなすに至った。
すなわち、上記課題を解決するために本発明のエマルジョン燃料生成方法は、水に1000ppm程度の割合で、植物由来の増粘剤を添加し水の粘度を高めることにより、油滴を水中に安定して懸濁混合させたり、水滴を安定して油中に懸濁混合させる。
In order to solve such problems, the present inventor applied water and fuel oil by applying that a plant-derived thickener can uniformly and stably suspend fine particles having a specific gravity difference from water. Has been found that stable emulsion mixing can be achieved, and the present invention has been made.
That is, in order to solve the above problems, the emulsion fuel production method of the present invention stabilizes oil droplets in water by adding a plant-derived thickener at a rate of about 1000 ppm to water to increase the viscosity of water. Suspended and mixed, or stably suspended and mixed water droplets in oil.

上述の方法で、粘性を高めた水と燃料油を高せん断速度で攪拌混合することにより、水と油の粒子を微細にして、例えば水分の量を燃料油と同量まで増やした状態でも一定時間安定した懸濁状態のエマルジョン燃料を生成できる。  By stirring and mixing water and fuel oil with increased viscosity at a high shear rate by the above method, the water and oil particles are made finer, for example, even when the amount of water is increased to the same amount as fuel oil. A time-stable emulsion fuel can be produced.

一般的なエマルジョン燃料では、エマルジョン混合するための水を、共鳴電磁波や電磁場等で水素結合を分離し、クラスターの小さい活性化された水とすることにより、油中水滴型エマルジョン混合が促進され、水が可燃剤となり、高い燃焼熱が得られている。他方水のクラスターが小さくなり活性化された分、水中油滴型のエマルジョン混合の油水分離が早くなるため、水中油滴型エマルジョン燃料ほど大きな割合で水を混入できいという問題があった。本発明によれば、植物由来の増粘剤で活性水の粘性を調整することにより、活性水を、燃料油とほぼ同量まで増やした状態でも一定時間安定した懸濁状態のエマルジョン燃料を生成できる。  In general emulsion fuel, the water for emulsion mixing is separated into hydrogen bonds by resonance electromagnetic waves, electromagnetic fields, etc., and activated water with small clusters, thereby promoting water-in-oil emulsion mixing. Water becomes a combustible and high combustion heat is obtained. On the other hand, because the water cluster becomes smaller and activated, the oil-water separation of the oil-in-water emulsion mixture becomes faster, so there is a problem that water cannot be mixed in as much as the oil-in-water emulsion fuel. According to the present invention, by adjusting the viscosity of the active water with a plant-derived thickener, a suspension emulsion fuel that is stable for a certain period of time even when the active water is increased to almost the same amount as the fuel oil is generated. it can.

本発明に係るエマルジョン燃料の生成方法によれば、小型装置を用いて、低コストで効率よくエマルジョン燃料を生成することができる。また水を可燃剤として高比率で燃料油と混合することにより、地球温暖化の主要因である二酸化炭素の発生を削減することが可能となる。  According to the method for producing emulsion fuel according to the present invention, emulsion fuel can be produced efficiently at low cost using a small apparatus. Moreover, it becomes possible to reduce generation | occurrence | production of the carbon dioxide which is a main cause of global warming by mixing water with a fuel oil as a combustible agent in a high ratio.

以下、本発明の実施形態について図面を参照しながら詳細に説明する。
図1は、本発明に係るエマルジョン燃料の生成方法のフローチャートを示す。
Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings.
FIG. 1 shows a flowchart of a method for producing an emulsion fuel according to the present invention.

エマルジョン燃料の原材料の水(活性水)は、水(活性水)供給配管11を通して、水(活性水)タンク1に供給される。燃料油は、燃料油供給配管12を通して、燃料タンク2に供給される。植物由来の増粘剤は、高濃度の水溶状態で増粘剤タンク4に貯蔵される。  Water (active water) as a raw material of the emulsion fuel is supplied to a water (active water) tank 1 through a water (active water) supply pipe 11. The fuel oil is supplied to the fuel tank 2 through the fuel oil supply pipe 12. The plant-derived thickener is stored in the thickener tank 4 in a high-concentration water state.

エダクター8で増粘剤を一定量混入させた状態で、粘度調整水移送ポンプ5により移送される水と、燃料移送ポンプ6により移送される燃料油を、2液混合スタティックミキサー9により、攪拌混合し、エマルジョン燃料タンク3に注入する。.  With the eductor 8 mixed with a certain amount of thickener, the water transferred by the viscosity adjusting water transfer pump 5 and the fuel oil transferred by the fuel transfer pump 6 are stirred and mixed by the two-component mixing static mixer 9. And injected into the emulsion fuel tank 3. .

このエマルジョン燃料タンク3に注入されたエマルジョン燃料は、エマルジョン燃料ポンプ移送ポンプ7により、スタティックミキサー10を介して循環され高速せん断により均一で長時間安定したエマルジョン燃料が生成される。  The emulsion fuel injected into the emulsion fuel tank 3 is circulated through the static mixer 10 by the emulsion fuel pump transfer pump 7, and uniform and stable emulsion fuel is generated by high-speed shearing.

このエマルジョン燃料生成方法には、流量調整弁13〜17が配置され、最適な装置運転状態が得られるようになっている。この流量調整弁を遠隔操作することにより自動運転も可能となる。  In this emulsion fuel generation method, flow rate adjusting valves 13 to 17 are arranged so that an optimum apparatus operating state can be obtained. Automatic operation is also possible by remotely operating this flow control valve.

すなわち、本実施形態のエマルジョン燃料生成方法によれば、エマルジョン燃料生成用の水に植物由来の増粘剤を100ppm程添加し粘性を高めることにより、燃料油と安定してエマルジョン混合可能となり、小型装置を用いて、低コストで効率よくエマルジョン燃料を生成することができる。  That is, according to the emulsion fuel generation method of the present embodiment, by adding about 100 ppm of a plant-derived thickener to water for generating emulsion fuel and increasing the viscosity, the emulsion can be stably mixed with the fuel oil, and the size can be reduced. Using the apparatus, it is possible to efficiently produce an emulsion fuel at a low cost.

本発明の実施例として、植物由来の増粘剤約2gを添加した共鳴電磁波にて処理された活性水約20LとA重油約20Lを、ギヤポンプとスタティックミキサーにより5分間、循環攪拌混合し生成されたエマルジョン燃料を24時間静置後、ボイラー及ディーゼルエンジンの燃料として使用したところ両方とも極めて順調に運転されることが確認された。  As an example of the present invention, about 20 L of active water and about 20 L of heavy oil A treated with resonance electromagnetic waves added with about 2 g of plant-derived thickener were circulated and mixed with a gear pump and a static mixer for 5 minutes. When the emulsion fuel was allowed to stand for 24 hours and then used as fuel for boilers and diesel engines, it was confirmed that both were operating extremely smoothly.

産業上の利用の可能性Industrial applicability

本発明によれば、水の粘度を燃料油の粘度に合わせて適当に高めることにより、水を高比率で安定して混入したエマルジョン燃料の生成が可能となり、既存の燃料油の代替燃料とすることができ、化石燃料の燃焼による二酸化炭素の発生を大幅に削減できる。  According to the present invention, by appropriately increasing the viscosity of water in accordance with the viscosity of the fuel oil, it is possible to generate an emulsion fuel in which water is stably mixed at a high ratio, which is an alternative fuel for the existing fuel oil. And the generation of carbon dioxide due to the combustion of fossil fuels can be greatly reduced.

は、本発明に係るエマルジョン燃料の生成方法のフローチャートを示す。These show the flowchart of the production | generation method of the emulsion fuel which concerns on this invention.

符号の説明Explanation of symbols

1 水(活性水)タンク
2 燃料油タンク
3 エマルジョン燃料タンク
4 増粘剤タンク
5 粘度調整水移送ポンプ
6 燃料油移送ポンプ
7 エマルジョン燃料移送ポンプ
8 エダクター
9 2液混合スタティックミキサー
10 スタティックミキサー
11 水(活性水)供給配管
12 燃料油供給配管
13〜17 流量調整弁
DESCRIPTION OF SYMBOLS 1 Water (active water) tank 2 Fuel oil tank 3 Emulsion fuel tank 4 Thickener tank 5 Viscosity adjustment water transfer pump 6 Fuel oil transfer pump 7 Emulsion fuel transfer pump 8 Eductor 9 Two liquid mixing static mixer 10 Static mixer 11 Water ( Active water) supply pipe 12 Fuel oil supply pipe 13-17 Flow rate adjustment valve

Claims (2)

水と燃料油を、植物由来の増粘剤により安定混合させることを特徴とするエマルジョン燃料  Emulsion fuel characterized by stably mixing water and fuel oil with a plant-derived thickener 請求項1のエマルジョン燃料において水を、共鳴電磁波の共振エネルギーや電磁場により励起された活性水とすることを特徴とするエマルジョン燃料。  The emulsion fuel according to claim 1, wherein water is activated water excited by resonance energy of electromagnetic waves or electromagnetic field.
JP2008162532A 2008-05-27 2008-05-27 Emulsion fuel and method for producing it Pending JP2009286992A (en)

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