JP2009222287A - Refrigerator - Google Patents

Refrigerator Download PDF

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Publication number
JP2009222287A
JP2009222287A JP2008066272A JP2008066272A JP2009222287A JP 2009222287 A JP2009222287 A JP 2009222287A JP 2008066272 A JP2008066272 A JP 2008066272A JP 2008066272 A JP2008066272 A JP 2008066272A JP 2009222287 A JP2009222287 A JP 2009222287A
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antioxidant
resin container
refrigerator
pressure
antioxidant component
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JP2008066272A
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JP4607200B2 (en
Inventor
Atsuko Funayama
敦子 船山
Kuninari Araki
邦成 荒木
Toshie Takasaki
寿江 高崎
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Hitachi Appliances Inc
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Hitachi Appliances Inc
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Priority to JP2008066272A priority Critical patent/JP4607200B2/en
Priority to KR1020080077680A priority patent/KR100979609B1/en
Priority to CN2008102109408A priority patent/CN101532765B/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D17/00Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces
    • F25D17/04Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces for circulating air, e.g. by convection
    • F25D17/042Air treating means within refrigerated spaces
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B7/00Preservation or chemical ripening of fruit or vegetables
    • A23B7/14Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10
    • A23B7/144Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10 in the form of gases, e.g. fumigation; Compositions or apparatus therefor
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D23/00General constructional features
    • F25D23/12Arrangements of compartments additional to cooling compartments; Combinations of refrigerators with other equipment, e.g. stove
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D2317/00Details or arrangements for circulating cooling fluids; Details or arrangements for circulating gas, e.g. air, within refrigerated spaces, not provided for in other groups of this subclass
    • F25D2317/04Treating air flowing to refrigeration compartments

Abstract

<P>PROBLEM TO BE SOLVED: To prevent oxidative deterioration of nutrient components in foods stored in an evacuated storage chamber over a long period of time while preventing an increase in the food storage space and reducing the cost. <P>SOLUTION: In this refrigerator, an antioxidant component releasing cassette 80 encapsulating an oxidation inhibitor is disposed in a storage chamber formed inside the refrigerator. This antioxidant component releasing cassette 80 is disposed inside the evacuated storage chamber 24 sealed when storing foods and reduced in pressure to lower than the atmospheric pressure. An oxidation inhibitor in which the antioxidant component is not released under the atmospheric pressure and which is released under pressure lower than the atmospheric pressure is used as the oxidation inhibitor. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

本発明は、冷蔵庫に係り、特に貯蔵室に収納する食品中の栄養成分の酸化劣化を防止する冷蔵庫に好適なものである。   The present invention relates to a refrigerator, and is particularly suitable for a refrigerator that prevents oxidative deterioration of nutritional components in food stored in a storage room.

この種の従来の冷蔵庫として、特開2007−64620号公報(特許文献1)に記載されたものがある。この冷蔵庫は、冷蔵庫内の冷気が循環される空間に開放された貯蔵室に大気圧状態の基で揮発する抗酸化剤を内包した抗酸化放出ユニットを配置し、この抗酸化剤の抗酸化成分を貯蔵室に放出して貯蔵室内の野菜などの食品を覆うことにより、食品中の栄養成分が空気中の酸素と結びついて酸化されて分解し減少することを防止しようとするものである。   As this type of conventional refrigerator, there is one described in Japanese Patent Application Laid-Open No. 2007-64620 (Patent Document 1). In this refrigerator, an antioxidant release unit containing an antioxidant that volatilizes under an atmospheric pressure group is disposed in a storage room opened in a space where cold air in the refrigerator is circulated, and an antioxidant component of this antioxidant Is intended to prevent the nutritional components in the food from being oxidized and decomposed and reduced in combination with oxygen in the air by covering the food such as vegetables in the storage chamber.

また、別の従来の冷蔵庫として、特許第4015687号公報(特許文献2)に記載されたものがある。この冷蔵庫は、食品の収納時に密閉されて0.7気圧の低圧にされる低圧室を備えたものである。このように低圧室の圧力を0.7気圧まで低下させることにより、低圧室内の酸素濃度を低くすることができ、これによって低圧室に収納した食品中の栄養成分が空気中の酸素と結びつくことを抑制して栄養成分の酸化劣化の防止を図ろうとするものである。   Another conventional refrigerator is described in Japanese Patent No. 4015687 (Patent Document 2). This refrigerator is provided with a low-pressure chamber that is hermetically sealed at the time of storage of food and has a low pressure of 0.7 atm. By reducing the pressure in the low-pressure chamber to 0.7 atm in this way, the oxygen concentration in the low-pressure chamber can be lowered, whereby the nutritional components in the food stored in the low-pressure chamber are combined with oxygen in the air. It is intended to prevent oxidative deterioration of nutritional components by suppressing the above.

特開2007−64620号公報JP 2007-64620 A 特許第4015687号公報Japanese Patent No. 4015687

しかし、上述した特許文献1の冷蔵庫では、貯蔵室に収納される食品は大気圧状態の基にあって酸素濃度の高い状態で保存されるので、食品中の栄養成分の酸化劣化を有効に防止するためには抗酸化剤から多量の抗酸化成分を放出させる必要があった。また、この冷蔵庫では、冷蔵庫内の冷気が循環される空間に開放された貯蔵室に抗酸化放出ユニットを設置しているので、循環される冷気全体の酸素が食品中の栄養成分と結びつくことを防止しなければならず、この点からも抗酸化剤から多量の抗酸化成分を放出させる必要があった。これによって、抗酸化放出ユニットの大型化が必要となり、食品収納スペースの減少及びコストアップを招くこととなっていた。   However, in the refrigerator of Patent Document 1 described above, the food stored in the storage room is stored in a state of high atmospheric pressure and based on atmospheric pressure, so that the oxidative deterioration of nutritional components in the food is effectively prevented. In order to do so, it was necessary to release a large amount of antioxidant components from the antioxidant. Also, in this refrigerator, the antioxidant release unit is installed in a storage room that is open to the space where the cold air in the refrigerator is circulated, so that the oxygen in the entire circulated cold air is linked to the nutritional components in the food. In this respect, it was necessary to release a large amount of antioxidant components from the antioxidant. This necessitates an increase in the size of the antioxidant release unit, leading to a reduction in food storage space and an increase in cost.

また、上述した特許文献2の冷蔵庫では、低圧室の圧力を下げることによってのみ栄養成分の酸化劣化を防止しているため、栄養成分の酸化劣化の有効な防止を図るには低圧室の圧力を極めて低い圧力まで低下させる必要があった。そのために減圧装置の大型化及び低圧室を構成する筐体の耐圧強度の増大が必要となり、食品収納スペースの減少及びコストアップを招くこととなっていた。   Further, in the refrigerator of Patent Document 2 described above, the oxidative degradation of the nutrient component is prevented only by lowering the pressure in the low pressure chamber. Therefore, in order to effectively prevent the oxidative degradation of the nutrient component, the pressure in the low pressure chamber is set. It was necessary to reduce the pressure to a very low pressure. Therefore, it is necessary to increase the size of the decompression device and increase the pressure resistance of the casing constituting the low pressure chamber, leading to a decrease in food storage space and an increase in cost.

本発明の目的は、食品収納スペースの増大及びコスト低減を図りつつ、減圧貯蔵室に収納した食品中の栄養成分の酸化劣化を長期間にわたって防止できる冷蔵庫を提供することにある。   The objective of this invention is providing the refrigerator which can prevent the oxidative degradation of the nutrient in the foodstuff accommodated in the decompression storage chamber over a long period, aiming at the increase in food storage space and cost reduction.

前述の目的を達成するための本発明の第1の態様は、冷蔵庫内に形成される貯蔵室に抗酸化剤を内包した抗酸化成分放出カセットを配置した冷蔵庫において、前記抗酸化剤として大気圧状態の基で抗酸化成分が放出されず且つ大気圧より低い圧力状態の基で抗酸化成分が放出される抗酸化剤を用いると共に、食品の収納時に密閉されて大気圧より低い圧力状態に減圧される減圧貯蔵室の内部に前記抗酸化成分放出カセットを配置したことにある。   The first aspect of the present invention for achieving the above-described object is that, in a refrigerator in which an antioxidant component release cassette containing an antioxidant is disposed in a storage chamber formed in the refrigerator, atmospheric pressure is used as the antioxidant. Use an antioxidant that does not release the antioxidant component under the state of the group and releases the antioxidant component under the state of the pressure lower than the atmospheric pressure, and is sealed when the food is stored and depressurized to a pressure lower than the atmospheric pressure. The anti-oxidant component release cassette is disposed inside the reduced-pressure storage chamber.

係る本発明の第1の態様におけるより好ましい具体的構成例は次の通りである。
(1)前記抗酸化剤としてビタミンC、ビタミンE及び酵素処理ルチンの何れかの栄養成分を含む自然食品に含有する酸化防止剤を用いたこと。
(2)前記(1)において、前記抗酸化剤としてアスコルビン酸またはトコフェノールを用いたこと。
(3)前記(2)において、前記減圧貯蔵室は冷蔵室の内部に配され、前記減圧貯蔵室の容積1リットル当たり0.001g以上の抗酸化成分が前記抗酸化成分放出カセットから放出するように前記減圧貯蔵室の減圧圧力及び当該カセットの放出抵抗を設定したこと。
(4)前記(3)において、前記減圧貯蔵室の減圧時の圧力を0.80〜0.95気圧に設定したこと。
(5)前記抗酸化成分放出カセットは、前記抗酸化剤と、この抗酸化剤を収納した樹脂容器と、この樹脂容器の内部の抗酸化成分をその外部に導いて放出する紙とを備えたこと。
(6)前記(5)において、前記樹脂容器は、内側にアルミフィルムを貼着し且つ前記抗酸化剤を収納した樹脂容器本体と内側にアルミフィルムを貼着した樹脂容器蓋とからなり、前記樹脂容器本体の周縁部及び前記樹脂容器蓋の周縁部をその一部に前記紙を介在して重ねて当該両周縁部のアルミフィルムを接合し、その内部空間を当該アルミフィルムで囲んだ空間とすると共に、前記両アルミフィルムに挟持された前記紙の部分のみを通して前記抗酸化成分を放出すること。
(7)前記(6)において、樹脂容器蓋は前記樹脂容器本体側の面に全長にわたって凹部を形成し、前記紙は、前記樹脂容器蓋の凹部内に全長にわたって配置され、その両端部が当該樹脂容器の外部に臨んでいること。
A more preferable specific configuration example in the first aspect of the present invention is as follows.
(1) An antioxidant contained in a natural food containing any nutritional component of vitamin C, vitamin E, and enzyme-treated rutin as the antioxidant.
(2) In said (1), ascorbic acid or tocophenol was used as said antioxidant.
(3) In the above (2), the decompression storage chamber is disposed inside the refrigeration chamber so that 0.001 g or more of the antioxidant component per liter of the volume of the decompression storage chamber is released from the antioxidant component release cassette. And setting the decompression pressure of the decompression storage chamber and the discharge resistance of the cassette.
(4) In said (3), the pressure at the time of pressure reduction of the said pressure reduction storage chamber was set to 0.80-0.95 atmosphere.
(5) The antioxidant component release cassette includes the antioxidant, a resin container containing the antioxidant, and paper for guiding and releasing the antioxidant component inside the resin container to the outside. thing.
(6) In the above (5), the resin container is composed of a resin container main body in which an aluminum film is adhered and an antioxidant is accommodated, and a resin container lid in which an aluminum film is adhered on the inner side, The peripheral edge of the resin container body and the peripheral edge of the resin container lid are overlapped with part of the paper interposed therebetween to join the aluminum films of both peripheral edges, and the space surrounded by the aluminum film And releasing the antioxidant component only through the portion of the paper sandwiched between the two aluminum films.
(7) In the above (6), the resin container lid forms a recess over the entire length on the surface of the resin container main body, and the paper is disposed over the entire length in the recess of the resin container lid, Facing the outside of the resin container.

また、本発明の第2の態様は、抗酸化剤を内包した抗酸化成分放出カセットにおいて、食品の収納時に密閉されて大気圧より低い圧力状態に減圧される減圧貯蔵室の内部に配置されると共に、前記抗酸化剤として大気圧状態の基で抗酸化成分が放出されず且つ大気圧より低い圧力状態の基で抗酸化成分が放出される抗酸化剤を用いたことにある。   Moreover, the 2nd aspect of this invention is arrange | positioned in the inside of the pressure-reduction storage chamber which is sealed at the time of storage of a foodstuff, and is pressure-reduced to a pressure state lower than atmospheric pressure in the antioxidant component release cassette which included the antioxidant. In addition, an antioxidant that does not release an antioxidant component under an atmospheric pressure group and releases an antioxidant component under a pressure state lower than atmospheric pressure is used as the antioxidant.

係る本発明の第2の態様におけるより好ましい具体的構成例は次の通りである。
(1)前記抗酸化剤とこの抗酸化剤を収納した樹脂容器とこの樹脂容器の内部の抗酸化成分をその外部に導いて放出する紙とを備えて構成され、
前記樹脂容器は、内側にアルミフィルムを貼着し且つ前記抗酸化剤を収納した樹脂容器本体と内側にアルミフィルムを貼着した樹脂容器蓋とからなり、前記樹脂容器本体の周縁部及び前記樹脂容器蓋の周縁部をその一部に前記紙を介在して重ねて当該両周縁部のアルミフィルムを接合し、その内部空間を当該アルミフィルムで囲んだ空間とすると共に、前記両アルミフィルムに挟持された前記紙の部分のみを通して前記抗酸化成分を放出すること。
A more preferable specific configuration example in the second aspect of the present invention is as follows.
(1) It is provided with the said antioxidant, the resin container which accommodated this antioxidant, and the paper which introduce | transduces and discharge | releases the antioxidant component inside this resin container to the exterior,
The resin container includes a resin container main body in which an aluminum film is attached and the antioxidant is stored, and a resin container lid in which an aluminum film is attached on the inner side, and a peripheral portion of the resin container main body and the resin The peripheral edge of the container lid is overlapped with a part of the paper with the paper interposed therebetween, and the aluminum films on both peripheral edges are joined together to form a space surrounded by the aluminum film and sandwiched between the aluminum films. Releasing the antioxidant component only through the portion of the paper that has been made.

係る本発明の冷蔵庫によれば、抗酸化成分放出カセットの小型化、減圧装置の小型化及び減圧貯蔵室の筐体の強度低減を可能として食品収納スペースの増大及びコスト低減を図りつつ、減圧貯蔵室に収納した食品中の栄養成分の酸化劣化を長期間にわたって防止できる。   According to the refrigerator of the present invention, the antioxidant component release cassette can be downsized, the decompression device can be downsized, the strength of the housing of the decompression storage chamber can be reduced, and the food storage space can be increased and the cost can be reduced. Oxidative deterioration of nutrients in food stored in the room can be prevented over a long period of time.

以下、本発明の一実施形態の冷蔵庫について図を用いて説明する。   Hereinafter, the refrigerator of one Embodiment of this invention is demonstrated using figures.

まず、図1及び図2を参照しながら冷蔵庫の構成に関して説明する。図1は本実施形態の冷蔵庫の中央縦断面図、図2は図1の冷蔵室の最下段空間部分の断面斜視図である。   First, the configuration of the refrigerator will be described with reference to FIGS. 1 and 2. FIG. 1 is a central longitudinal cross-sectional view of the refrigerator of the present embodiment, and FIG. 2 is a cross-sectional perspective view of the lowermost space portion of the refrigerator compartment of FIG.

冷蔵庫は、冷蔵庫本体1及び扉6〜9を備えて構成されている。冷蔵庫本体1は、鋼板製の外箱11と樹脂製の内箱12との間にウレタン発泡断熱材13及び真空断熱材(図示せず)を有して構成され、上から冷蔵室2、冷凍室3、4、野菜室5の順に複数の貯蔵室を有している。換言すれば、最上段に冷蔵室2が、最下段に野菜室5が、それぞれ区画して配置されており、冷蔵室2と野菜室5との間には、これらの両室と断熱的に仕切られた冷凍室3、4が配設されている。冷蔵室2及び野菜室5は冷蔵温度帯の貯蔵室であり、冷凍室3、4は、0℃以下の冷凍温度帯(例えば、約−20℃〜−18℃の温度帯)の貯蔵室である。これらの貯蔵室2〜5は仕切り壁33,34,35により区画されている。   The refrigerator includes a refrigerator body 1 and doors 6 to 9. The refrigerator body 1 includes a urethane foam heat insulating material 13 and a vacuum heat insulating material (not shown) between a steel plate outer box 11 and a resin inner box 12. A plurality of storage rooms are provided in the order of the rooms 3 and 4 and the vegetable room 5. In other words, the refrigerator compartment 2 is arranged at the uppermost stage, and the vegetable compartment 5 is arranged at the lowermost stage, and between the refrigerator compartment 2 and the vegetable compartment 5, the two rooms are insulated from each other. Partitioned freezer compartments 3 and 4 are provided. The refrigerator compartment 2 and the vegetable compartment 5 are storage compartments in a refrigerated temperature zone, and the freezer compartments 3 and 4 are storage compartments in a freezing temperature zone of 0 ° C. or less (for example, a temperature zone of about −20 ° C. to −18 ° C.). is there. These storage chambers 2 to 5 are partitioned by partition walls 33, 34, and 35.

冷蔵庫本体1の前面には、貯蔵室2〜5の前面開口部を閉塞する扉6〜9が設けられている。冷蔵室扉6は冷蔵室2の前面開口部を閉塞する扉、冷凍室扉7は冷凍室3の前面開口部を閉塞する扉、冷凍室扉8は冷凍室4の前面開口部を閉塞する扉、野菜室扉9は野菜室5の前面開口部を閉塞する扉である。冷蔵室扉6は観音開き式の両開きの扉で構成され、冷凍室扉7、冷凍室扉8、野菜室扉9は、引き出し式の扉によって構成され、引き出し扉とともに貯蔵室内の容器が引き出される。   On the front surface of the refrigerator body 1, doors 6 to 9 that close the front opening portions of the storage chambers 2 to 5 are provided. The refrigerator compartment door 6 closes the front opening of the refrigerator compartment 2, the freezer compartment door 7 closes the front opening of the freezer compartment 3, and the freezer compartment door 8 closes the front opening of the freezer compartment 4. The vegetable compartment door 9 is a door that closes the front opening of the vegetable compartment 5. The refrigerator compartment door 6 is constituted by a double door with double doors, and the freezer compartment door 7, the freezer compartment door 8, and the vegetable compartment door 9 are constituted by drawer type doors, and a container in the storage compartment is pulled out together with the drawer door.

冷蔵庫本体1には、冷凍サイクルが設置されている。この冷凍サイクルは、圧縮機14、凝縮器(図示せず)、キャピラリチューブ(図示せず)及び蒸発器15、そして再び圧縮機14の順に接続して構成されている。圧縮機14及び凝縮器は冷蔵庫本体1の背面下部に設けられた機械室に設置されている。蒸発器15は冷凍室3、4の後方に設けられた冷却器室に設置され、この冷却器室における蒸発器15の上方に送風ファン16が設置されている。   The refrigerator body 1 is provided with a refrigeration cycle. This refrigeration cycle is configured by connecting a compressor 14, a condenser (not shown), a capillary tube (not shown) and an evaporator 15, and again the compressor 14 in this order. The compressor 14 and the condenser are installed in a machine room provided at the lower back of the refrigerator body 1. The evaporator 15 is installed in a cooler room provided behind the freezing rooms 3 and 4, and a blower fan 16 is installed above the evaporator 15 in the cooler room.

蒸発器15によって冷却された冷気は、送風ファン16によって冷蔵室2、冷凍室3、4及び野菜室5の各貯蔵室へと送られる。具体的には、送風ファン16によって送られる冷気は、開閉可能なダンパー装置を介して、その一部が冷蔵室2及び野菜室5の冷蔵温度帯の貯蔵室へと送られ、他の一部が冷凍室3、4の冷凍温度帯の貯蔵室へと送られる。   The cold air cooled by the evaporator 15 is sent to the storage rooms of the refrigerator compartment 2, the freezer compartments 3, 4 and the vegetable compartment 5 by the blower fan 16. Specifically, a part of the cool air sent by the blower fan 16 is sent to a storage room in the refrigerator temperature zone of the refrigerator room 2 and the vegetable room 5 through a damper device that can be opened and closed, and the other part. Are sent to the freezer compartments 3 and 4 in the freezing temperature zone.

送風ファン16によって冷蔵室2、冷凍室3、4及び野菜室5の各貯蔵室へと送られる冷気は、各貯蔵室を冷却した後、冷気戻り通路を通って冷却器室へと戻される。このように、本実施形態の冷蔵庫は冷気の循環構造を有しており、各貯蔵室2〜5を適切な温度に維持する。   The cool air sent to the storage rooms of the refrigerator compartment 2, the freezer compartments 3, 4 and the vegetable compartment 5 by the blower fan 16 is returned to the cooler compartment through the cool air return passage after cooling each storage compartment. Thus, the refrigerator of this embodiment has a cold air circulation structure, and maintains each of the storage chambers 2 to 5 at an appropriate temperature.

冷蔵室2内には、透明な樹脂板で構成される複数段の棚17〜20が取り外し可能に設置されている。最下段の棚20は、内箱12の背面及び両側面に接するように設置され、その下方空間である最下段空間21を上方空間と区画している。また、各冷蔵室扉6の内側には複数段の扉ポケット25〜27が設置され、これらの扉ポケット25〜27は冷蔵室扉6が閉じられた状態で冷蔵室2内に突出するように設けられている。冷蔵室2の背面には、送風ファン16から供給された冷気を通す通路を形成する背面パネル30が設けられている。   A plurality of shelves 17 to 20 made of a transparent resin plate are detachably installed in the refrigerator compartment 2. The lowermost shelf 20 is installed in contact with the back surface and both side surfaces of the inner box 12, and divides the lowermost space 21, which is the lower space, from the upper space. Further, a plurality of door pockets 25 to 27 are installed inside each refrigerator compartment door 6, and these door pockets 25 to 27 protrude into the refrigerator compartment 2 with the refrigerator compartment door 6 closed. Is provided. A back panel 30 that forms a passage through which the cool air supplied from the blower fan 16 passes is provided on the back of the refrigerator compartment 2.

最下段空間21には、左から順に、冷凍室3の製氷皿に製氷水を供給するための製氷水タンク22、デザートなどの食品を収納するための収納ケース23、室内を減圧して食品の鮮度保持及び長期保存するための減圧貯蔵室24が設置されている。減圧貯蔵室24は、冷蔵室2の横幅より狭い横幅を有し、冷蔵室2の側面に隣接して配置されている。   In the lowermost space 21, in order from the left, an ice making water tank 22 for supplying ice making water to the ice tray in the freezing room 3, a storage case 23 for storing food such as dessert, and the inside of the room are decompressed to store food. A reduced-pressure storage chamber 24 is provided for maintaining freshness and for long-term storage. The decompression storage chamber 24 has a width that is narrower than the width of the refrigerator compartment 2, and is disposed adjacent to the side surface of the refrigerator compartment 2.

製氷水タンク22及び収納ケース23は左側の冷蔵室扉6の後方に配置されている。これによって、左側の冷蔵室扉6を開くのみで、製氷水タンク22及び収納ケース23を引き出すことができる。また、減圧貯蔵室24は右側の冷蔵室扉6の後方に配置されている。これによって、右側の冷蔵室扉6を開くのみで、減圧貯蔵室24の食品トレイ60を引き出すことができる。なお、製氷水タンク22及び収納ケース23は左側の冷蔵室扉6の最下段の扉ポケット27の後方に位置することとなり、減圧貯蔵室24は右側の冷蔵室扉6の最下段の扉ポケット27の後方に位置することとなる。ここで、蒸発器15によって冷却されて冷蔵室2へ送られた冷気が減圧貯蔵室24の周囲を通って減圧貯蔵室24の内部を間接冷却するようになっている。   The ice making water tank 22 and the storage case 23 are disposed behind the left refrigerator compartment door 6. Thereby, the ice making water tank 22 and the storage case 23 can be pulled out only by opening the left refrigerator compartment door 6. The decompression storage chamber 24 is disposed behind the right refrigeration chamber door 6. Thereby, the food tray 60 of the decompression storage chamber 24 can be pulled out only by opening the right refrigerator compartment door 6. The ice-making water tank 22 and the storage case 23 are located behind the lowermost door pocket 27 of the left refrigerator compartment door 6, and the decompression storage chamber 24 is the lowermost door pocket 27 of the right refrigerator compartment door 6. It will be located behind. Here, the cold air cooled by the evaporator 15 and sent to the refrigerator compartment 2 passes through the periphery of the decompression storage chamber 24 to indirectly cool the inside of the decompression storage chamber 24.

製氷水タンク22の後方には、製氷水ポンプ28が設置されている。収納ケース23の後方で且つ減圧貯蔵室24の後部側方の空間には、減圧貯蔵室24を減圧するための減圧装置の一例である負圧ポンプ29が配置されている。負圧ポンプ29は、減圧貯蔵室24の側面に設けられたポンプ接続部に導管を介して接されている。   An ice making water pump 28 is installed behind the ice making water tank 22. A negative pressure pump 29, which is an example of a decompression device for decompressing the decompression storage chamber 24, is disposed behind the storage case 23 and in a space behind the decompression storage chamber 24. The negative pressure pump 29 is in contact with a pump connection provided on the side surface of the decompression storage chamber 24 via a conduit.

減圧貯蔵室24は、食品出し入れ用開口部を有する箱状の減圧貯蔵室本体40と、減圧貯蔵室本体40の食品出し入れ用開口部を開閉する減圧貯蔵室ドア50と、食品を収納して減圧貯蔵室ドア50に出し入れする食品トレイ60とを備えて構成されている。減圧貯蔵室本体40で減圧貯蔵室ドア50の食品出し入れ用開口部を閉じることにより、減圧貯蔵室本体40と減圧貯蔵室ドア50とで囲まれた空間が減圧される低圧空間として形成される。食品トレイ60は、減圧貯蔵室ドア50の背面側に取り付けられ、減圧貯蔵室ドア50の移動に伴って前後に移動可能である。   The decompression storage chamber 24 includes a box-shaped decompression storage chamber main body 40 having an opening for food access, a decompression storage door 50 for opening and closing the food access opening of the decompression storage body 40, and a decompression for storing food. A food tray 60 that is taken in and out of the storage room door 50 is provided. By closing the food storage opening / closing opening of the decompression storage chamber door 50 with the decompression storage chamber body 40, the space surrounded by the decompression storage chamber body 40 and the decompression storage chamber door 50 is formed as a low pressure space to be decompressed. The food tray 60 is attached to the back side of the decompression storage chamber door 50 and can move back and forth with the movement of the decompression storage chamber door 50.

減圧貯蔵室24の内部には、抗酸化剤81(図4参照)を内包した抗酸化成分放出カセット80が設置されている。換言すれば、野菜、肉魚などの生鮮食品を保存する減圧貯蔵室24に空気中の酸素による酸化損失を防止できる抗酸化剤81を内包する抗酸化成分放出カセット80が設置されている。この抗酸化成分放出カセット80は、図2に示すように、食品トレイ60の背壁部に着脱可能に係着されている。抗酸化剤81としては、大気圧状態の基で抗酸化成分が放出されず且つ大気圧より低い圧力状態の基で抗酸化成分が放出される抗酸化剤が用いられている。即ち、抗酸化成分放出カセット80に内包された抗酸化剤81は、減圧貯蔵室24内を減圧することにより、抗酸化成分放出カセット80内部の圧力と抗酸化成分放出カセット80の外部の圧力との圧力差により抗酸化成分が放出される。   Inside the reduced pressure storage chamber 24, an antioxidant component release cassette 80 containing an antioxidant 81 (see FIG. 4) is installed. In other words, an anti-oxidant component release cassette 80 containing an anti-oxidant 81 capable of preventing oxidation loss due to oxygen in the air is installed in the decompression storage chamber 24 for storing fresh foods such as vegetables and meat fish. As shown in FIG. 2, the antioxidant component release cassette 80 is detachably attached to the back wall portion of the food tray 60. As the antioxidant 81, an antioxidant is used in which the antioxidant component is not released under the atmospheric pressure group and the antioxidant component is released under the pressure state lower than the atmospheric pressure. That is, the antioxidant 81 contained in the antioxidant component release cassette 80 depressurizes the inside of the decompression storage chamber 24, thereby reducing the pressure inside the antioxidant component release cassette 80 and the pressure outside the antioxidant component release cassette 80. The antioxidant component is released by the pressure difference.

食品トレイ60に食品を載せて減圧貯蔵室ドア50を閉じることにより、減圧貯蔵室24の内部が密閉状態となり、ドアスイッチがオンされて負圧ポンプ29が駆動され、減圧貯蔵室24が大気圧より低い状態に減圧される。これにより貯蔵室13内の酸素濃度が低下して食品中の栄養成分の劣化を防止することができる。しかも、減圧貯蔵室24が密閉されて減圧された状態となってから抗酸化剤81から抗酸化成分の放出が開始されると共に、限られた容積の減圧貯蔵室24の中で抗酸化成分による食品中の栄養成分と酸素との結合防止をすることができる。その結果、抗酸化成分放出カセット80の小型化、負圧ポンプ29の小型化及び減圧貯蔵室24の筐体の強度低減を可能として食品収納スペースの増大及びコスト低減を図りつつ、減圧貯蔵室24に収納した食品中の栄養成分の酸化劣化を長期間にわたって防止できる。   By putting food on the food tray 60 and closing the decompression storage chamber door 50, the inside of the decompression storage chamber 24 is sealed, the door switch is turned on, the negative pressure pump 29 is driven, and the decompression storage chamber 24 is at atmospheric pressure. Depressurized to a lower state. Thereby, the oxygen concentration in the store room 13 can fall and deterioration of the nutrient component in a foodstuff can be prevented. In addition, the release of the antioxidant component from the antioxidant 81 is started after the decompression storage chamber 24 is sealed and decompressed, and the antioxidant component is contained in the decompression storage chamber 24 having a limited volume. It is possible to prevent binding between nutritional components in food and oxygen. As a result, it is possible to reduce the size of the antioxidant component release cassette 80, to reduce the size of the negative pressure pump 29, and to reduce the strength of the housing of the reduced pressure storage chamber 24, thereby increasing the food storage space and reducing the cost. It is possible to prevent oxidative deterioration of nutritional components in the food stored in the container for a long period of time.

そして、減圧貯蔵室ドア50を手前に引くことにより、減圧貯蔵室ドア50の一部に設けられた圧力解除バルブがまず動作して減圧貯蔵室24の減圧状態が解除されて大気圧の状態となり、減圧貯蔵室ドア50を開くことができる。これによって、簡単に減圧貯蔵室ドア50を開け、食品の出し入れが出来る。   Then, by pulling the decompression storage chamber door 50 toward the front, the pressure release valve provided in a part of the decompression storage chamber door 50 is first operated to release the decompression state of the decompression storage chamber 24 to be in the atmospheric pressure state. The decompression storage chamber door 50 can be opened. Thereby, the decompression storage chamber door 50 can be easily opened and food can be taken in and out.

次に、図3から図5を参照しながら、抗酸化成分放出カセット80について具体的に説明する。図3は図2の抗酸化成分放出カセット80の単独斜視図、図4は図3のA−A断面図、図5図3のB−B断面図である。   Next, the antioxidant component release cassette 80 will be described in detail with reference to FIGS. 3 is a single perspective view of the antioxidant component release cassette 80 of FIG. 2, FIG. 4 is an AA cross-sectional view of FIG. 3, and FIG. 5 is a BB cross-sectional view of FIG.

抗酸化成分放出カセット80は、抗酸化成分を放出する抗酸化剤81と、この抗酸化剤81を収納した樹脂容器82と、この樹脂容器82の内部の抗酸化成分をその外部に導いて放出する紙85とを備えて構成されている。紙85は、和紙や腐食布などで形成され、通気性を有している。   The antioxidant component release cassette 80 is an antioxidant 81 that releases an antioxidant component, a resin container 82 that contains the antioxidant 81, and an antioxidant component inside the resin container 82 that is guided outside and released. Paper 85 to be configured. The paper 85 is formed of Japanese paper or corroded cloth and has air permeability.

抗酸化剤81は、食品中の栄養成分が空気中の酸素により酸化される前に酸化することにより、食品中の栄養成分の酸化を防止するものである。従って、抗酸化剤は、非常に酸化されやすい物質からなるものである。このように、抗酸化剤81は、食品に触れるため、人体に対する安全性に配慮して、ビタミンC、ビタミンE及び酵素処理ルチンなど栄養成分を含む自然食品に含有する酸化防止剤、例えばアスコルビン酸やトコフェノールなどが用いられる。   The antioxidant 81 prevents oxidation of nutritional components in food by oxidizing the nutritional components in food before being oxidized by oxygen in the air. Therefore, an antioxidant consists of a substance which is very easy to oxidize. In this way, the antioxidant 81 is in contact with food, and therefore, in consideration of safety to the human body, an antioxidant contained in natural foods containing nutritional components such as vitamin C, vitamin E and enzyme-treated rutin, for example, ascorbic acid And tocophenol are used.

樹脂容器82は、内側にアルミフィルム83aを貼着し且つ抗酸化剤81を収納した樹脂容器本体83と、内側にアルミフィルム84aを貼着した樹脂容器蓋84とからなっている。樹脂容器本体83の周縁部と樹脂容器蓋84の周縁部とを重ねて、当該両周縁部のアルミフィルム83a、84aを紙85が介在された部分を除いて全周にわたって接合し、その内部空間を当該アルミフィルム83a、84aで囲んだ空間としている。従って、この空間内に配置された抗酸化剤81からアルミフィルム83a、84aを通して抗酸化成分が外部に放出されることはない。   The resin container 82 includes a resin container main body 83 having an aluminum film 83a attached inside and containing an antioxidant 81, and a resin container lid 84 having an aluminum film 84a attached inside. The peripheral portion of the resin container body 83 and the peripheral portion of the resin container lid 84 are overlapped, and the aluminum films 83a and 84a of both peripheral portions are joined over the entire periphery except for the portion where the paper 85 is interposed, and the internal space Is a space surrounded by the aluminum films 83a and 84a. Therefore, the antioxidant component is not released to the outside through the aluminum films 83a and 84a from the antioxidant 81 arranged in this space.

樹脂容器蓋84は、表側に突出する突部84bを形成することにより、樹脂容器本体側の面に全長にわたって凹部84cが形成されている。紙85は、樹脂容器蓋84の凹部84c内に全長にわたって配置され、両端部が樹脂容器82の外部に臨んでいる。これによって、樹脂容器82内に配置された抗酸化剤81から放出される抗酸化成分は、両アルミフィルム83a、84aに挟持された紙85の部分のみを通して樹脂容器82の外部空間である減圧貯蔵室24内に放出される。従って、減圧貯蔵室24内への抗酸化成分の放出率は、紙85の挟持部の断面積(換言すれば、紙85の厚みまたは幅)、挟持部における長さを調整することにより容易に調整することができる。   The resin container lid 84 is formed with a recess 84c over the entire length on the surface of the resin container main body by forming a protrusion 84b protruding to the front side. The paper 85 is disposed over the entire length in the recess 84 c of the resin container lid 84, and both end portions face the outside of the resin container 82. As a result, the antioxidant component released from the antioxidant 81 disposed in the resin container 82 is decompressed and stored as an external space of the resin container 82 through only the portion of the paper 85 sandwiched between the aluminum films 83a and 84a. It is discharged into the chamber 24. Therefore, the release rate of the antioxidant component into the decompression storage chamber 24 can be easily adjusted by adjusting the cross-sectional area of the sandwiched portion of the paper 85 (in other words, the thickness or width of the paper 85) and the length of the sandwiched portion. Can be adjusted.

次に、図6を参照しながら、抗酸化剤81の食品中の栄養成分の損失を防止するための有効濃度について説明する。図6はアスコルビン酸の有効濃度試験によるほうれん草のビタミンC含量測定結果を示す図、図7はアスコルビン酸の有効濃度試験によるマグロのK値測定結果を示す図、図8はアスコルビン酸の有効濃度試験で牛肉の色調測定結果を示す図である。   Next, the effective concentration for preventing the loss of nutritional components in the food of the antioxidant 81 will be described with reference to FIG. FIG. 6 shows the results of measuring the vitamin C content of spinach by an effective concentration test of ascorbic acid, FIG. 7 shows the results of measuring the K value of tuna by the effective concentration test of ascorbic acid, and FIG. 8 shows the effective concentration test of ascorbic acid. It is a figure which shows the color tone measurement result of beef.

これらのアスコルビン酸の有効濃度試験では、10L(リットル)の密閉容器に、抗酸化成分としてアスコルビン酸を0.01g放出させた場合と、0.1g放出させた場合と、未放出の場合とにおいて、この密閉容器に保存していた、ほうれん草のビタミンC含量、マグロの鮮度の指標であるK値、牛肉の色調について、購入直後と3日保存後について測定し、比較したものである。また、図中に示す符号91はアスコルビン酸を0.1g放出させた場合、符号92はアスコルビン酸を0.01g放出させた場合、符号93はアスコルビン酸を放出させなかった場合を示す。   In the effective concentration test of these ascorbic acids, 0.01 g of ascorbic acid was released as an antioxidant component into a 10 L (liter) sealed container, 0.1 g was released, and when it was not released. The Vitamin C content of spinach, the K value that is an indicator of the freshness of tuna, and the color of beef stored in this sealed container were measured immediately after purchase and after storage for 3 days, and compared. Moreover, the code | symbol 91 shown in a figure shows the case where 0.1g of ascorbic acid is released, the code | symbol 92 shows the case where 0.01g of ascorbic acid is released, and the code | symbol 93 shows the case where ascorbic acid is not released.

図6において、縦軸はビタミンC含量〔mg/100g〕、横軸は経過時間を示す。有効濃度試験の結果、アスコルビン酸を放出させなかった93よりもアスコルビン酸を放出させた91、92の方のビタミンC含量が多く、保存中の酸化による損失を防止できたことが判る。   In FIG. 6, the vertical axis represents vitamin C content [mg / 100 g], and the horizontal axis represents elapsed time. As a result of the effective concentration test, it can be seen that the vitamin C contents of 91 and 92 which released ascorbic acid were higher than 93 which did not release ascorbic acid, and loss due to oxidation during storage could be prevented.

図7において、縦軸は鮮度の指標であるK値、横軸は経過時間を示す。有効濃度試験の結果、アスコルビン酸を放出させなかった93よりもアスコルビン酸を放出させた91、92の方のK値の値が小さく、鮮度低下を防止できたことが判る。   In FIG. 7, the vertical axis represents the K value that is an index of freshness, and the horizontal axis represents the elapsed time. As a result of the effective concentration test, it can be seen that the values of K values of 91 and 92 in which ascorbic acid was released were smaller than 93 in which ascorbic acid was not released, and a decrease in freshness could be prevented.

図8は、縦軸は明暗、横軸は彩度を示す色調図であり、中心を購入直後としたときの3日保存後の色調測定結果を示す。中心に近いほうが購入直後の色に近く、鮮度を保っていることを示すが、有効濃度試験の結果、アスコルビン酸を放出させなかった93よりもアスコルビン酸を放出させた91、92のほうが中心に近く、鮮度低下を防止できたことが判る。   FIG. 8 is a color tone diagram in which the vertical axis represents light and dark, and the horizontal axis represents saturation, and shows the color tone measurement results after storage for 3 days when the center is immediately after purchase. The closer to the center is closer to the color immediately after purchase, indicating that the freshness is maintained, but as a result of the effective concentration test, 91 and 92 that released ascorbic acid were more central than 93 that did not release ascorbic acid. It turns out that it was possible to prevent a decrease in freshness.

従って、図6、図7、図8よりアスコルビン酸の放出量は容積1リットル当たり0.001g以上放出することが好ましいことが判った。   Therefore, from FIGS. 6, 7 and 8, it was found that the amount of ascorbic acid released is preferably 0.001 g or more per liter of volume.

次に、図9を参照しながら、抗酸化剤81の抗酸化成分の放出量と減圧量との関係について説明する。図9は抗酸化剤81の抗酸化成分の放出量と減圧量との関係の測定結果を示す図である。   Next, the relationship between the release amount of the antioxidant component of the antioxidant 81 and the reduced pressure amount will be described with reference to FIG. FIG. 9 is a diagram showing the measurement result of the relationship between the release amount of the antioxidant component of the antioxidant 81 and the reduced pressure amount.

抗酸化剤81の抗酸化成分の放出量と減圧量との関係を測定する試験方法は、密閉容器に抗酸化剤81を内包したカセット80を入れ、負圧ポンプにより密閉容器内の空気を吸い出して密閉容器内を減圧して一定に保持し、そのときの密閉容器内の抗酸化剤81の濃度を測定した。   The test method for measuring the relationship between the release amount of the antioxidant component of the antioxidant 81 and the reduced pressure amount is to put a cassette 80 containing the antioxidant 81 in a sealed container and suck out the air in the sealed container by a negative pressure pump. Then, the inside of the sealed container was decompressed and kept constant, and the concentration of the antioxidant 81 in the sealed container at that time was measured.

図9において、縦軸に抗酸化剤濃度、横軸に一定減圧になったときを0分としたときの経過時間を示す。図中の符号94は密閉容器内を0.7気圧に保った場合、符号95は密閉容器内を0.95気圧に保った場合、符号96は大気圧の場合を示す。   In FIG. 9, the vertical axis shows the antioxidant concentration, and the horizontal axis shows the elapsed time when 0 minutes is obtained when the pressure is constant. In the figure, reference numeral 94 indicates a case where the inside of the sealed container is maintained at 0.7 atmosphere, reference numeral 95 indicates a case where the inside of the sealed container is maintained at 0.95 atmosphere, and reference numeral 96 indicates a case where the pressure is atmospheric pressure.

図9より明らかなように、密閉容器内が大気圧の96の場合、抗酸化剤に揮発性がないため、密閉容器内の濃度は上昇しなかったのに対し、減圧した94、95は抗酸化剤の濃度が上昇すると共に、更には、0.95気圧に保った95よりも容器内を0.7気圧に保った94のほうが放出量が大きくなったことが判る。従って、減圧することにより揮発性のない抗酸化剤81を密閉容器内に放出させることが出来る。従って、密閉容器の減圧量で抗酸化剤81の抗酸化成分の放出量を制御できる。しかし、密閉容器内の圧力を低くすればするほど、密閉容器の耐圧構造を強化する必要があるため、密閉容器のコストが増大する。従って、減圧量は0.80〜0.95の範囲とすることが好ましい。   As is clear from FIG. 9, when the inside of the sealed container is at atmospheric pressure 96, since the antioxidant is not volatile, the concentration in the sealed container did not increase, whereas the reduced pressures 94 and 95 were As the concentration of the oxidizing agent increases, it can be seen that the amount of release increased more in 94 in which the inside of the container was kept at 0.7 atm than in 95 kept at 0.95 atm. Therefore, by reducing the pressure, the non-volatile antioxidant 81 can be released into the sealed container. Therefore, the release amount of the antioxidant component of the antioxidant 81 can be controlled by the reduced pressure amount of the sealed container. However, the lower the pressure in the sealed container, the more the pressure-resistant structure of the sealed container needs to be strengthened, so the cost of the sealed container increases. Therefore, the amount of reduced pressure is preferably in the range of 0.80 to 0.95.

本発明の一実施形態の冷蔵庫の中央縦断面図である。It is a center longitudinal cross-sectional view of the refrigerator of one Embodiment of this invention. 図1の冷蔵室の最下段空間部分の断面斜視図である。It is a cross-sectional perspective view of the lowest space part of the refrigerator compartment of FIG. 図2の抗酸化成分放出カセットの単独斜視図である。FIG. 3 is a single perspective view of the antioxidant component release cassette of FIG. 2. 図3のA−A断面図である。It is AA sectional drawing of FIG. 図3のB−B断面図である。It is BB sectional drawing of FIG. アスコルビン酸の有効濃度試験によるほうれん草のビタミンC含量測定結果を示す図である。It is a figure which shows the vitamin C content measurement result of the spinach by the effective concentration test of ascorbic acid. アスコルビン酸の有効濃度試験によるマグロのK値測定結果を示す図である。It is a figure which shows the K value measurement result of the tuna by the effective concentration test of ascorbic acid. アスコルビン酸の有効濃度試験で牛肉の色調測定結果を示す図である。It is a figure which shows the color tone measurement result of beef in the effective concentration test of ascorbic acid. 抗酸化剤の抗酸化成分の放出量と減圧量との関係の測定結果を示す図である。It is a figure which shows the measurement result of the relationship between the discharge | release amount of the antioxidant component of an antioxidant, and the pressure reduction amount.

符号の説明Explanation of symbols

1…冷蔵庫本体、2…冷蔵室、3…冷凍室、3、4…冷凍室、5…野菜室、6…冷蔵室扉、7、8…冷凍室扉、9…野菜室扉、11…外箱、12…内箱、13…発泡断熱材、14…圧縮機、15…蒸発器、16…送風ファン、17〜20…棚、21…最下段空間、22…製氷水タンク、23…収納ケース、24…減圧貯蔵室、25〜27…扉ポケット、28…製氷水ポンプ、29…負圧ポンプ、30…背面パネル、34〜36…仕切り壁、40…低圧室本体、50…低圧室ドア、60…食品トレイ、80…抗酸化成分放出カセット、81…抗酸化剤、82…樹脂容器、83…樹脂容器本体、83a…アルミフィルム、84…樹脂容器蓋、84a…アルミフィルム、85…紙、91…有効濃度を検討するためアスコルビン酸を0.1g放出させた場合、92…有効濃度を検討するためアスコルビン酸を0.01g放出させた場合、93…有効濃度を検討するためアスコルビン酸が未放出の場合、94…有効減圧量検討するため容器内を0.7気圧に保った場合、95…有効減圧量検討するため容器内を0.95気圧に保った場合、96…有効減圧量検討するため容器内を大気圧に保った場合。   DESCRIPTION OF SYMBOLS 1 ... Refrigerator main body, 2 ... Cold room, 3 ... Freezer room, 3, 4 ... Freezer room, 5 ... Vegetable room, 6 ... Cold room door, 7, 8 ... Freezer room door, 9 ... Vegetable room door, 11 ... Outside Box, 12 ... Inner box, 13 ... Foam insulation, 14 ... Compressor, 15 ... Evaporator, 16 ... Blower, 17-20 ... Shelf, 21 ... Bottom space, 22 ... Ice making water tank, 23 ... Storage case 24 ... Depressurized storage chamber, 25-27 ... Door pocket, 28 ... Ice making water pump, 29 ... Negative pressure pump, 30 ... Back panel, 34-36 ... Partition wall, 40 ... Low pressure chamber body, 50 ... Low pressure chamber door, 60 ... Food tray, 80 ... Antioxidant release cassette, 81 ... Antioxidant, 82 ... Resin container, 83 ... Resin container body, 83a ... Aluminum film, 84 ... Resin container lid, 84a ... Aluminum film, 85 ... Paper, 91 ... Release 0.1g of ascorbic acid to examine the effective concentration 92: 0.01 g of ascorbic acid was released to examine the effective concentration, 93 ... Ascorbic acid was not released to examine the effective concentration, 94 ... When maintained at 7 atm. 95: When the inside of the container is kept at 0.95 atm to examine the effective decompression amount, 96 ... At the atmospheric pressure at the inside of the container for examining the effective decompression amount.

Claims (10)

冷蔵庫内に形成される貯蔵室に抗酸化剤を内包した抗酸化成分放出カセットを配置した冷蔵庫において、
前記抗酸化剤として大気圧状態の基で抗酸化成分が放出されず且つ大気圧より低い圧力状態の基で抗酸化成分が放出される抗酸化剤を用いると共に、
食品の収納時に密閉されて大気圧より低い圧力状態に減圧される減圧貯蔵室の内部に前記抗酸化成分放出カセットを配置した
ことを特徴とする冷蔵庫。
In a refrigerator in which an antioxidant component release cassette containing an antioxidant is placed in a storage room formed in the refrigerator,
As the antioxidant, an antioxidant that does not release an antioxidant component in a group under atmospheric pressure and releases an antioxidant component in a group under pressure under atmospheric pressure,
A refrigerator characterized in that the antioxidant component release cassette is disposed inside a decompression storage chamber that is sealed when food is stored and is decompressed to a pressure lower than atmospheric pressure.
請求項1において、
前記抗酸化剤としてビタミンC、ビタミンE及び酵素処理ルチンの何れかの栄養成分を含む自然食品に含有する酸化防止剤を用いたことを特徴とする冷蔵庫。
In claim 1,
A refrigerator characterized by using an antioxidant contained in a natural food containing any nutrient component of vitamin C, vitamin E and enzyme-treated rutin as the antioxidant.
請求項2において、
前記抗酸化剤としてアスコルビン酸またはトコフェノールを用いたことを特徴とする冷蔵庫。
In claim 2,
A refrigerator using ascorbic acid or tocophenol as the antioxidant.
請求項3において、
前記減圧貯蔵室は冷蔵室の内部に配され、前記減圧貯蔵室の容積1リットル当たり0.001g以上の抗酸化成分が前記抗酸化成分放出カセットから放出するように前記減圧貯蔵室の減圧圧力及び当該カセットの放出抵抗を設定したことを特徴とする冷蔵庫。
In claim 3,
The decompression storage chamber is disposed in a refrigerator compartment, and the decompression pressure in the decompression storage chamber is such that 0.001 g or more of the antioxidant component per liter of the decompression storage chamber is released from the antioxidant component release cassette. A refrigerator characterized by setting the discharge resistance of the cassette.
請求項4において、
前記減圧貯蔵室の減圧時の圧力を0.80〜0.95気圧に設定したことを特徴とする冷蔵庫。
In claim 4,
The refrigerator at the time of pressure_reduction | reduced_pressure of the said pressure reduction store room was set to 0.80-0.95 atmosphere.
請求項1において、
前記抗酸化成分放出カセットは、前記抗酸化剤と、この抗酸化剤を収納した樹脂容器と、この樹脂容器の内部の抗酸化成分をその外部に導いて放出する紙とを備えたことを特徴とする冷蔵庫。
In claim 1,
The antioxidant component release cassette includes the antioxidant, a resin container containing the antioxidant, and a paper that guides and releases the antioxidant component inside the resin container to the outside. Refrigerator.
請求項6において、
前記樹脂容器は、内側にアルミフィルムを貼着し且つ前記抗酸化剤を収納した樹脂容器本体と内側にアルミフィルムを貼着した樹脂容器蓋とからなり、前記樹脂容器本体の周縁部及び前記樹脂容器蓋の周縁部をその一部に前記紙を介在して重ねて当該両周縁部のアルミフィルムを接合し、その内部空間を当該アルミフィルムで囲んだ空間とすると共に、前記両アルミフィルムに挟持された前記紙の部分のみを通して前記抗酸化成分を放出することを特徴とする冷蔵庫。
In claim 6,
The resin container includes a resin container main body in which an aluminum film is attached and the antioxidant is stored, and a resin container lid in which an aluminum film is attached on the inner side, and a peripheral portion of the resin container main body and the resin The peripheral edge of the container lid is overlapped with a part of the paper with the paper interposed therebetween, and the aluminum films on both peripheral edges are joined together to form a space surrounded by the aluminum film and sandwiched between the aluminum films. A refrigerator characterized in that the antioxidant component is released only through the paper portion.
請求項7において、
樹脂容器蓋は前記樹脂容器本体側の面に全長にわたって凹部を形成し、前記紙は、前記樹脂容器蓋の凹部内に全長にわたって配置され、その両端部が当該樹脂容器の外部に臨んでいる
ことを特徴とする冷蔵庫。
In claim 7,
The resin container lid is formed with a recess over the entire length on the surface of the resin container main body, the paper is disposed over the entire length within the recess of the resin container lid, and both ends thereof face the outside of the resin container. A refrigerator characterized by.
抗酸化剤を内包した抗酸化成分放出カセットにおいて、
食品の収納時に密閉されて大気圧より低い圧力状態に減圧される減圧貯蔵室の内部に配置されると共に、
前記抗酸化剤として大気圧状態の基で抗酸化成分が放出されず且つ大気圧より低い圧力状態の基で抗酸化成分が放出される抗酸化剤を用いたことを特徴とする抗酸化成分放出カセット。
In the antioxidant component release cassette containing the antioxidant,
It is placed inside a vacuum storage chamber that is sealed when food is stored and reduced to a pressure lower than atmospheric pressure.
Antioxidant component release characterized by using an antioxidant that does not release an antioxidant component under an atmospheric pressure group and releases an antioxidant component under a pressure state lower than atmospheric pressure. cassette.
請求項9において、
前記抗酸化剤とこの抗酸化剤を収納した樹脂容器とこの樹脂容器の内部の抗酸化成分をその外部に導いて放出する紙とを備えて構成され、
前記樹脂容器は、内側にアルミフィルムを貼着し且つ前記抗酸化剤を収納した樹脂容器本体と内側にアルミフィルムを貼着した樹脂容器蓋とからなり、前記樹脂容器本体の周縁部及び前記樹脂容器蓋の周縁部をその一部に前記紙を介在して重ねて当該両周縁部のアルミフィルムを接合し、その内部空間を当該アルミフィルムで囲んだ空間とすると共に、前記両アルミフィルムに挟持された前記紙の部分のみを通して前記抗酸化成分を放出することを特徴とする抗酸化成分放出カセット。
In claim 9,
The anti-oxidant and a resin container containing the anti-oxidant, and a paper for guiding and releasing the anti-oxidant component inside the resin container to the outside are configured.
The resin container includes a resin container main body in which an aluminum film is attached and the antioxidant is stored, and a resin container lid in which an aluminum film is attached on the inner side, and a peripheral portion of the resin container main body and the resin The peripheral edge of the container lid is overlapped with a part of the paper with the paper interposed therebetween, and the aluminum films on both peripheral edges are joined together to form a space surrounded by the aluminum film and sandwiched between the aluminum films. Antioxidant component release cassette, wherein the antioxidant component is released only through the paper portion.
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