JP2009183893A - Method of treating used paper diaper - Google Patents
Method of treating used paper diaper Download PDFInfo
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- JP2009183893A JP2009183893A JP2008027820A JP2008027820A JP2009183893A JP 2009183893 A JP2009183893 A JP 2009183893A JP 2008027820 A JP2008027820 A JP 2008027820A JP 2008027820 A JP2008027820 A JP 2008027820A JP 2009183893 A JP2009183893 A JP 2009183893A
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- 238000000034 method Methods 0.000 title claims abstract description 29
- 238000005406 washing Methods 0.000 claims abstract description 86
- 239000000463 material Substances 0.000 claims abstract description 60
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000000470 constituent Substances 0.000 claims abstract description 16
- 229920000642 polymer Polymers 0.000 claims description 46
- 239000002250 absorbent Substances 0.000 claims description 32
- 230000002745 absorbent Effects 0.000 claims description 32
- 239000004033 plastic Substances 0.000 claims description 23
- 229920003023 plastic Polymers 0.000 claims description 23
- 239000004449 solid propellant Substances 0.000 claims description 23
- 238000003672 processing method Methods 0.000 claims description 14
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 12
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 12
- 239000004571 lime Substances 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 3
- 238000010079 rubber tapping Methods 0.000 claims 1
- 238000004064 recycling Methods 0.000 abstract description 10
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 15
- 230000000694 effects Effects 0.000 description 12
- 238000000926 separation method Methods 0.000 description 11
- 230000018044 dehydration Effects 0.000 description 10
- 238000006297 dehydration reaction Methods 0.000 description 10
- 235000012255 calcium oxide Nutrition 0.000 description 8
- 239000000292 calcium oxide Substances 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 7
- 239000000460 chlorine Substances 0.000 description 7
- 229910052801 chlorine Inorganic materials 0.000 description 7
- 238000011084 recovery Methods 0.000 description 6
- 238000001035 drying Methods 0.000 description 5
- -1 polyethylene Polymers 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000000645 desinfectant Substances 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 238000004659 sterilization and disinfection Methods 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000000295 fuel oil Substances 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- FFBHFFJDDLITSX-UHFFFAOYSA-N benzyl N-[2-hydroxy-4-(3-oxomorpholin-4-yl)phenyl]carbamate Chemical compound OC1=C(NC(=O)OCC2=CC=CC=C2)C=CC(=C1)N1CCOCC1=O FFBHFFJDDLITSX-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 150000002013 dioxins Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B17/02—Separating plastics from other materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B17/02—Separating plastics from other materials
- B29B2017/0213—Specific separating techniques
- B29B2017/0286—Cleaning means used for separation
- B29B2017/0289—Washing the materials in liquids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/48—Wearing apparel
- B29L2031/4871—Underwear
- B29L2031/4878—Diapers, napkins
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
Landscapes
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Mechanical Engineering (AREA)
- Processing Of Solid Wastes (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
Abstract
Description
本発明は、使用済み紙オムツの処理方法に関する。 The present invention relates to a method for processing used paper diapers.
紙オムツは、パルプなどからなる吸収材と、吸収材が吸収した水分を保持する高分子吸収材(高分子ポリマー)と、これらを包む防水材(プラスチック)などの素材から構成されている。 Paper diapers are composed of an absorbent material made of pulp and the like, a polymer absorbent material (polymer polymer) that retains moisture absorbed by the absorbent material, and a waterproof material (plastic) that encloses these.
従来、使い捨て紙オムツの処分は衛生的な理由から焼却処分が最善とされていたが、水分を多く含んでいるため焼却する際に多量の熱量を必要とし、無駄にエネルギーを消費してしまう。また、資源の有効利用の観点から使用済み紙オムツの構成素材は回収して再利用することが望ましい。 Conventionally, disposal of disposable paper diapers has been best done by incineration for hygienic reasons. However, since they contain a lot of moisture, a large amount of heat is required for incineration, which wastes energy. Moreover, it is desirable to collect and reuse the constituent material of used paper diapers from the viewpoint of effective use of resources.
構成素材の回収方法には、例えば、紙オムツを構成するパルプ等を薬品を用いて分離し、回収して再利用できるようにする分離回収処理がある。この分離回収処理では、前処理として紙オムツを回転する刃などで破砕し、その後の分離や回収を行っていた。(特許文献1)
ところが、この分離回収処理では、使用済み紙オムツを分離処理装置へ投入する際に、投入量の管理が行われていないので投入量が一定せず、投入量が多い場合は消毒液が不足して使用済み紙オムツ全体を均一に消毒することができず、少なければ消毒液が余ってしまい、無駄なコストが掛かる。
As a method for recovering the constituent material, for example, there is a separation and recovery process in which pulp or the like constituting the paper diaper is separated using a chemical, and recovered and reused. In this separation and recovery process, the paper diaper was crushed with a rotating blade or the like as a pre-process, and the subsequent separation and recovery were performed. (Patent Document 1)
However, in this separation and recovery process, when the used paper diaper is thrown into the separation processing apparatus, the amount of charge is not managed, so the amount of charge is not constant. As a result, the entire used disposable diaper cannot be sterilized uniformly.
また、従来、使用済み紙オムツは複数の処理工程を1基の槽で行う1バッチシステムで処理することが多く、1バッチシステムでは1バッチの使用済み紙オムツで全ての工程が終了するまで次のバッチの使用済み紙オムツの処理を開始することができず、従って、処理能率が悪く、多量の使用済み紙オムツを一度に処理することができない。 Also, conventionally, used paper diapers are often processed in a single batch system in which a plurality of processing steps are performed in one tank, and in a single batch system, one batch of used paper diapers is used until all processes are completed. The batch of used paper diapers cannot be started, so the processing efficiency is poor and a large amount of used paper diapers cannot be processed at one time.
また、水分を吸収した使用済み紙オムツ中の高分子吸収材は、重量が増加する上に、ゲル状になって流動性を失い、処理装置の能力を低下させるので、水分を吸収した高分子吸収材は脱水(分解)する必要があり、一般に、この脱水には食塩が有効であることが知られている。さらに、使用済み紙オムツの消毒にも食塩等の添加剤が使用されている。しかし、食塩を用いると、脱水後(分解後)の各素材は残留塩素が多くなり、種々のリサイクル方法にとって不利であり、再資源化されたパルプやプラスチック、固形燃料化したパルプとプラスチックは残留塩素によって質が低下し、特に、固形燃料はボイラー等の燃料に不適である。 In addition, the polymer absorbent in used paper diapers that has absorbed moisture increases in weight and also loses its fluidity in the form of a gel, reducing the ability of the processing equipment. The absorbent material needs to be dehydrated (decomposed), and it is generally known that salt is effective for this dehydration. Furthermore, additives such as salt are also used for disinfecting used paper diapers. However, when salt is used, each material after dehydration (after decomposition) has a large amount of residual chlorine, which is disadvantageous for various recycling methods. Recycled pulp and plastic, solid fueled pulp and plastic remain. The quality is deteriorated by chlorine. In particular, solid fuel is unsuitable for fuels such as boilers.
また、従来、使用済み紙オムツの構成素材であるパルプと高分子吸収材とプラスチックはそれぞれの比重の差を利用し水中で沈殿させて分別しているが、この沈殿分別法では各素材が水中で沈殿層を形成するまで待つ必要があり、それだけ時間が掛かって分別効率が悪い上に、比重差だけでは各素材を正確に分別することができず、例えば、高分子吸収材が残留しているとプラスチックとパルプに付着し、これらを固形燃料化するのが困難である。
そこで本願発明は、上記課題を解決し、使用済み紙オムツの構成素材を高能率で分離し、効率よく再利用することを可能にする使用済み紙オムツの処理方法を提供することにある。 SUMMARY OF THE INVENTION Accordingly, the present invention is to provide a processing method for used paper diapers that solves the above-mentioned problems and enables the constituent materials of used paper diapers to be efficiently separated and reused efficiently.
請求項1記載の発明は、直列に配置された複数基の水洗槽を有する連続洗濯機を用い、使用済み紙オムツを前段の水洗槽から後段の水洗槽へ順次移動させながら水洗することを特徴とする使用済み紙オムツの処理方法である。 The invention according to claim 1 is characterized by using a continuous washing machine having a plurality of water washing tubs arranged in series and washing the used paper diapers while sequentially moving the used paper diaper from the preceding water washing tub to the subsequent water washing tub. This is a processing method of used paper diapers.
請求項2記載の発明は、洗濯された前記使用済み紙オムツ中の高分子吸収材を、石灰を用いて脱水することを特徴とする請求項1に記載の使用済み紙オムツの処理方法である。
Invention of
請求項3記載の発明は、前記水洗槽に投入される所定量の使用済み紙オムツに対する前記石灰の割合が、3重量%〜10重量%の範囲内であることを特徴とする請求項2に記載の使用済み紙オムツの処理方法である。
The invention according to
請求項4記載の発明は、使用済み紙オムツを前記水洗槽で揺すり洗い、あるいは、叩き洗いして構成素材を分離させることを特徴とする請求項1〜請求項3に記載の使用済み紙オムツの処理方法である。 The invention according to claim 4 is characterized in that the used paper diaper is washed in the water-washing tank or is washed to separate the constituent materials. It is a processing method.
請求項5記載の発明は、前記水洗槽で分離した粒度の異なる前記構成素材を、スクリーンを通して排出することにより分別することを特徴とする請求項4に記載の使用済み紙オムツの処理方法である。 The invention according to claim 5 is the processing method of used paper diapers according to claim 4, wherein the constituent materials having different particle sizes separated in the washing tank are separated by being discharged through a screen. .
請求項6記載の発明は、前記水洗槽による水洗工程は、投入された使用済み紙オムツを予備洗浄する予洗工程と、予備洗浄された使用済み紙オムツを本洗浄する本洗工程と、本洗浄された使用済み紙オムツをすすぎ洗いするすすぎ工程とからなることを特徴とする請求項1〜請求項5に記載の使用済み紙オムツの処理方法である。
In the invention according to
請求項7記載の発明は、前記水洗工程で分別された後、脱水し、乾燥させた前記構成素材中のパルプとプラスチックを固形燃料化する固形燃料化工程を備えていることを特徴とする請求項1〜請求項6に記載の使用済み紙オムツの処理方法である。 The invention according to claim 7 includes a solid fuel conversion step of converting the pulp and plastic in the constituent material which has been dehydrated and dried after being separated in the water washing step into a solid fuel. It is a processing method of the used paper diaper of Claims 1-6.
請求項1記載の発明によれば、前段の水洗槽から後段の水洗槽へ順次移動させながら使用済み紙オムツを水洗する連続洗濯機を用いることにより、全ての工程が終了するまで次の使用済み紙オムツの処理を開始することができない1バッチシステムと異なって、使用済み紙オムツを連続的に投入し、効率よく処理することができる。 According to the invention described in claim 1, by using a continuous washing machine for washing used paper diapers while sequentially moving from the preceding water washing tank to the subsequent water washing tank, the next used is completed until all processes are completed. Unlike a one-batch system in which processing of paper diapers cannot be started, used paper diapers can be continuously charged and processed efficiently.
また、複数の水洗槽で使用済み紙オムツを連続的に水洗する本発明では、使用済み紙オムツの投入量を所定量に管理することに大きな意味があり、投入量を管理すれば、消毒液の無駄を防止しながら、使用済み紙オムツを均一に効果的に消毒することが可能になる。 Further, in the present invention in which used paper diapers are continuously washed in a plurality of washing tanks, it is significant to manage the input amount of used paper diapers to a predetermined amount. This makes it possible to disinfect used paper diapers uniformly and effectively.
また、処理システムの処理能力に応じて使用済み紙オムツの投入量を管理すれば、処理システムの処理効率が向上し、吸収材と高分子吸収材と防水材などの分離をスムーズに行うことができる。 In addition, if the amount of used disposable diapers is managed according to the processing capacity of the processing system, the processing efficiency of the processing system can be improved, and the absorbent material, polymer absorbent material, waterproof material, etc. can be separated smoothly. it can.
請求項2記載の発明によれば、請求項1の構成と同等の効果が得られる。
According to the invention described in
また、水分を吸収した使用済み紙オムツ中の高分子吸収材を石灰で脱水することにより、高分子吸収材が軽量化されると共に、ゲル状から元の状態に戻って流動性を回復するので、処理システムの処理能力低下が避けられる。 Also, by dehydrating the polymer absorbent in the used paper diaper that has absorbed moisture with lime, the polymer absorbent is reduced in weight, and the fluidity is restored from the gel state to the original state. , A reduction in processing capacity of the processing system is avoided.
また、脱水に食塩を用いる方法と異なって、種々のリサイクル方法、再資源化されたパルプ及びプラスチックなどの素材、パルプとプラスチックを固形燃料にした物、例えば、この固形燃料はボイラー等の燃料に適切である。 Different from the method using salt for dehydration, various recycling methods, recycled materials such as pulp and plastic, pulp and plastic as solid fuel, for example, this solid fuel is used as fuel for boilers, etc. Is appropriate.
また、石灰が水と反応するときの反応熱によって水洗槽の温度が適度に上昇し、石灰による高分子吸収材の脱水分解能力と、使用済み紙オムツの水洗効果と、素材の分離効率と、消毒液の効果などがそれぞれ促進される。 In addition, the temperature of the washing tank rises moderately due to the reaction heat when lime reacts with water, the dehydration and decomposition ability of the polymer absorbent with lime, the washing effect of used paper diapers, the separation efficiency of the material, The effect of the disinfectant is promoted.
さらに、各水洗槽の温度を上げるための熱源の負荷が低減され、従って、ランニングコストがそれだけ低減される。 Furthermore, the load of the heat source for raising the temperature of each washing tank is reduced, and thus the running cost is reduced accordingly.
また、石灰は食塩より安価であり、本発明の方法はそれだけ低コストで実施できる。 Also, lime is less expensive than salt, and the method of the present invention can be implemented at a lower cost.
請求項3記載の発明によれば、請求項2の構成と同等の効果が得られる。 According to the third aspect of the invention, the same effect as that of the second aspect of the invention can be obtained.
また、使用済み紙オムツの所定投入量に対する石灰の適正な割合(3重量%〜10重量%)を規定したことによって、石灰が少なすぎると高分子吸収材がゲル状で残留する問題と、石灰が多すぎるとパルプなどの分離された素材に灰分が付着して質を低下させる問題が防止される。 In addition, by defining an appropriate ratio (3 wt% to 10 wt%) of lime with respect to a predetermined input amount of used paper diaper, if the amount of lime is too small, the polymer absorbent material remains in a gel state, and lime If there is too much, the problem which ash will adhere to the isolate | separated raw materials, such as a pulp, and the quality will be prevented is prevented.
請求項4記載の発明によれば、請求項1〜請求項3の構成と同等の効果が得られる。 According to invention of Claim 4, the effect equivalent to the structure of Claims 1-3 is acquired.
また、使用済み紙オムツを連続洗濯機で連続的に揺すり洗い、あるいは、叩き洗いして構成素材を分離させるので、従来例と異なり、前処理として紙オムツを回転刃で破砕する必要がなく、それだけ低コストに実施できる。 Also, because the used diapers are continuously shaken or washed with a continuous washing machine to separate the constituent materials, unlike conventional examples, there is no need to crush the paper diapers with a rotary blade as a pretreatment, This can be done at low cost.
請求項5記載の発明によれば、請求項4の構成と同等の効果が得られる。 According to the fifth aspect of the invention, the same effect as that of the fourth aspect of the invention can be obtained.
また、水洗槽で分離した粒度の異なる構成素材(パルプと高分子吸収材とプラスチックなど)をスクリーンを通して排出し分別するので、これらを水中で沈殿させて分別する従来例と異なって、分別時間が大きく短縮される上に、各素材を正確に分別することができ、例えば、残留した高分子吸収材の付着が防止されてプラスチックとパルプの固形燃料化が容易になる。 Also, because the constituent materials with different particle sizes (pulp, polymer absorbent and plastic, etc.) separated in the washing tank are discharged through the screen and separated, the separation time differs from the conventional example in which they are precipitated and separated in water. In addition to being greatly shortened, each material can be accurately separated. For example, the remaining polymer absorbent is prevented from adhering, and plastic and pulp can be easily converted into a solid fuel.
請求項6記載の発明によれば、請求項1〜請求項5の構成と同等の効果が得られる。
According to invention of
また、使用済み紙オムツを、予洗工程と本洗工程とすすぎ工程とによって連続的に処理するので、処理時間が短縮されて処理能力が増加し、使用済み紙オムツを大量に処理することが可能になる。 In addition, since used paper diapers are continuously processed through the pre-washing process, the main washing process and the rinsing process, the processing time is shortened and the processing capacity is increased, and a large amount of used paper diapers can be processed. become.
また、予洗、本洗、すすぎ洗いの各工程によって、水分を吸収した高分子吸収材をほぼ完全に分離させることができる。 In addition, the polymer absorbent material that has absorbed moisture can be almost completely separated by the steps of prewashing, main washing, and rinsing.
請求項7記載の発明によれば、請求項1〜請求項6の構成と同等の効果が得られる。 According to invention of Claim 7, the effect equivalent to the structure of Claims 1-6 is acquired.
また、上記のように、食塩を使用しない本発明の方法では、使用済み紙オムツから分別されて再資源化された素材に残留する塩素分が極めて少ない。 Further, as described above, in the method of the present invention in which no salt is used, the chlorine content remaining in the material separated and recycled from the used paper diaper is extremely small.
また、プラスチックはカロリーもA重油並みに高く、固形燃料にすれば利用価値が高い上に、水分を吸収した高分子吸収材が上記の水洗工程によって分離されているので、固形燃料化が容易である。 In addition, plastic has a high calorie as high as heavy oil A. If it is made into a solid fuel, its utility value is high. In addition, the polymer absorbent that has absorbed moisture is separated by the washing process described above, so that it can be easily converted into a solid fuel. is there.
本願発明の一実施例を図1を参照しながら説明する。 An embodiment of the present invention will be described with reference to FIG.
図1は使用済み紙オムツの再資源化システム(使用済み紙オムツの処理方法)の工程図である。 FIG. 1 is a process diagram of a used paper diaper recycling system (used paper diaper processing method).
この再資源化システムは、連続洗濯機101と脱水機103と乾燥機105とを備えており、連続洗濯機101は、直列に配置された1基の予洗槽と8基の本洗槽と2基のすすぎ洗い槽を備えている。また、これらの予洗槽と本洗槽とすすぎ洗い槽は2種類の回転数と2種類の揺動角度でそれぞれの洗い工程を行える。
This recycling system includes a
また、紙オムツは、上記のように、排泄物を吸収する吸収材と、その水分を保持する高分子吸収材と、これらを包む防水材及び表面材とから構成されており、吸収材は綿状パルプや吸収紙などから構成され、高分子吸収材は高分子ポリマーであり、防水材はポリエチレンフィルム、ポリエチレンラミネート、ポリウレタンラミネートのような素材の不織布で構成され、表面材はポリオレフィン系、ポリプロピレン系、ポリエチレン系、ポリエステル系のような素材の不織布で構成されている。 In addition, as described above, a paper diaper is composed of an absorbent material that absorbs excrement, a polymer absorbent material that retains its moisture, and a waterproof material and a surface material that wrap them, and the absorbent material is cotton. The polymer absorbent material is a polymer polymer, the waterproof material is composed of a nonwoven fabric such as polyethylene film, polyethylene laminate, polyurethane laminate, and the surface material is polyolefin-based or polypropylene-based. It is made of a nonwoven fabric made of a material such as polyethylene or polyester.
また、再資源化された使用済み紙オムツの素材は、固形燃料にするためには可燃分が多く含まれて発熱量が大きいことが望ましく、水分と用途のない灰分は少ない程よい。また、固形燃料の場合、大きい発熱量を得るために炭素は多い程よく、ダイオキシンを発生させたり、設備を腐食させる塩素は少ない程よく、大気中に放出する硫黄は少ない程よい。 In addition, it is desirable that the recycled used disposable diaper material contains a large amount of combustible matter and has a large calorific value in order to make it into a solid fuel. In the case of a solid fuel, in order to obtain a large calorific value, the more carbon, the better the less chlorine that generates dioxins or corrodes the equipment, and the less the sulfur released into the atmosphere.
(使用済み紙オムツの再資源化工程の説明)
(A)投入管理工程1では、一定量(所定量)の使用済み紙オムツを水溶性容器(バッグ)に収容して投入口から投入する。この投入管理工程1では、例えぱ、水溶性容器を120秒に1回のサイクルで投入し、このサイクルで使用済み紙オムツを連続処理する。
(Description of recycling process of used paper diapers)
(A) In the input management step 1, a certain amount (predetermined amount) of used paper diaper is accommodated in a water-soluble container (bag) and input from an input port. In this charging management process 1, for example, a water-soluble container is charged in a cycle of once every 120 seconds, and used paper diapers are continuously processed in this cycle.
水洗工程は、1基の予洗槽で行われる予洗工程2と、8基の本洗槽で行われる本洗工程3と、2基のすすぎ洗い槽で行われるすすぎ洗い工程4から構成されている。
The water washing process is composed of a
(B)予洗工程2では、投入管理工程1で投入された1容器分の使用済み紙オムツを予備洗いすると共に、1次消毒のために次亜塩酸が投入される。予備洗いによって水溶性容器の口元が溶け、使用済み紙オムツが下洗いされ、1次消毒されると共に、水分を吸収した高分子ポリマーが分離される。
(B) In the
(C)本洗工程3では、予備洗いされた使用済み紙オムツを、8基の本洗槽の間で前段の本洗槽(水洗槽)から後段へ順次移動させながら、80℃以上で、合計10分以上の洗濯と2次消毒とが行われると共に、水分を吸収した高分子ポリマーが分離される。
(C) In the
(D)すすぎ洗い工程4では、予洗工程2と本洗工程3で付着した次亜塩酸の塩素分を使用済み紙オムツから除去すると共に、水分を吸収した高分子ポリマーが分離される。
(D) In the rinsing step 4, the chlorine content of hypochlorous acid adhering in the
(E)また、予洗工程2と本洗工程3とすすぎ洗い工程4では各水洗槽に、処理中の使用済み紙オムツに対して5重量%の生石灰(CaO)が投入され、投入された生石灰は高分子ポリマーを脱水(分解)する。
(E) In addition, in the
また、投入された生石灰が水と反応することによって反応熱が発生する。 In addition, reaction heat is generated by the quick calcined lime reacting with water.
(F)また、予洗工程2と本洗工程3とすすぎ洗い工程4では、各水洗槽で使用済み紙オムツを揺すり洗い、あるいは、叩き洗いして、吸収材と高分子ポリマーと防水材と表面材をそれぞれ構成素材に分離する。
(F) Further, in the
(G)また、予洗工程2と本洗工程3とすすぎ洗い工程4の各水洗槽には、それぞれ所定の網目(0.3mm〜0.5mm)を有するスクリーン(篩)が取り付けられた排出孔が設けられており、各排出孔はスクリーンのそれぞれの網目によって上記のように分離した各構成素材を排出し、分別する。
(G) Moreover, each water-washing tank of the
(H)脱水工程5では、すすぎ洗いされた使用済み紙オムツの水分を脱水機103で除去する。また、脱水された水分からも高分子ポリマーが分離される。
(H) In the dehydration step 5, the
(I)乾燥工程6では、高分子ポリマーが分離され除去された後の、吸収材(綿状パルプと吸収紙)と防水材及び表面材(プラスチック)から乾燥機105によって水分をさらに除去し、乾燥させる。
(I) In the drying
(J)パルプ等回収/再利用工程7では、上記各工程で分離、分別された高分子ポリマーを回収し、再利用可能な状態にする。 (J) In the recovery / reuse step 7 for pulp and the like, the polymer polymer separated and separated in each of the above steps is recovered and made into a reusable state.
なお、上記工程の中で脱水工程5はなくても良く、すすぎ洗い工程4の後に直ぐに乾燥工程6としても良い。
The dehydration step 5 may not be included in the above steps, and the drying
また、パルプ等回収/再利用工程7の後に脱水工程5を設けて、パルプ〔繊維質〕を回収し再生利用しても良く、脱す工程5の後に乾燥工程(点線で示す)6を設けても良い。 Further, a dehydration step 5 may be provided after the pulp recovery / reuse step 7 to recover and recycle the pulp [fibrous], and a drying step (shown by a dotted line) 6 may be provided after the removal step 5. Also good.
(K)固形燃料化工程8では、乾燥工程6で水分が除去され乾燥された綿状パルプと吸収紙とプラスチックを固形燃料にする。なお、これらの素材を固形燃料に圧縮成形する際に圧縮による80℃以上の摩擦熱が発生し、水分除去効果及び消毒効果が得られる。また、回収したプラスチックは油化してもよい。
(K) In the solid
さらに、回収したプラスチックは、固形燃料化、油化以外に再び再生プラスチックとして再利用することができる。 Further, the recovered plastic can be reused as recycled plastic in addition to solid fuel and oil.
なお、この再資源化システムでは、例えば、80kgの使用済み紙オムツを投入すると、この使用済み紙オムツは脱水工程後に投入量の10%である8kgになり、乾燥工程後は投入量の6%である約5kgにまで軽量化される。 In this recycling system, for example, when 80 kg of used paper diaper is input, this used paper diaper becomes 8 kg, which is 10% of the input amount after the dehydration process, and 6% of the input amount after the drying process. The weight is reduced to about 5kg.
また、上記固形燃料の塩素含有率は0.03%以下であり、極めて良好な結果が得られている。 Further, the chlorine content of the solid fuel is 0.03% or less, and a very good result is obtained.
[使用済み紙オムツの再資源化システムの効果]
上記のように構成された再資源化システムは、連続洗濯機を用いることにより、1バッチシステムと異なって、使用済み紙オムツを連続的に効率よく処理できる。
[Effect of recycling system for used paper diapers]
Unlike the one-batch system, the recycling system configured as described above can efficiently and continuously process used paper diapers by using a continuous washing machine.
また、使用済み紙オムツを連続的に水洗する本発明によって、使用済み紙オムツの投入量を所定量に管理することに大きな意味が生じ、投入量を管理することによって、システムの処理効率が向上し、吸収材と高分子吸収材と防水材と表面材などの分離がスムーズに行われると共に、消毒液の無駄を防止しながら、使用済み紙オムツを均一に効果的に消毒することが可能になる。 In addition, the present invention in which used paper diapers are continuously washed with water has a great meaning in managing the amount of used paper diaper input to a predetermined amount, and the processing efficiency of the system is improved by managing the amount of input. In addition, the absorbent material, polymer absorbent material, waterproof material, surface material, etc. can be separated smoothly, and it is possible to disinfect used paper diapers uniformly and effectively, while preventing waste of the disinfectant. Become.
また、生石灰で脱水することによって高分子吸収材(高分子ポリマー)が軽量化され、ゲル状から元の状態に戻って流動性を回復するので、システムの処理能力低下が避けられる。 Further, dehydration with quick lime reduces the weight of the polymer absorbent (polymer) and restores the fluidity from the gel state to the original state, thereby avoiding a reduction in processing capacity of the system.
また、高分子ポリマーの脱水に食塩を用いないので、種々のリサイクル方法、再資源化されたパルプやプラスチックなどの素材、パルプとプラスチックを固形燃料にした物、油化したプラスチックなどが残留塩素の害から解放され、固形燃料はボイラー等の燃料に適切である。 In addition, since salt is not used to dehydrate the polymer, various recycling methods, recycled pulp and plastic materials, pulp and plastic solid fuel, oiled plastic, etc. Freed from harm, solid fuel is suitable for fuels such as boilers.
また、生石灰と水との反応熱によって各水洗槽で、生石灰による高分子ポリマーの脱水能力と、使用済み紙オムツの水洗効率と、各素材の分離効率と、消毒液の効果などが促進され、さらに、各水洗槽の温度を上げるための熱源の負荷が低減され、従って、ランニングコストがそれだけ低減される。 In addition, the reaction heat of quick lime and water promotes the dehydration ability of the polymer polymer by quick lime, the water washing efficiency of used paper diapers, the separation efficiency of each material, the effect of the disinfectant, etc. Furthermore, the load of the heat source for raising the temperature of each washing tank is reduced, and thus the running cost is reduced accordingly.
また、使用済み紙オムツ(所定投入量)に対する生石灰の適正な割合(3重量%〜10%)を規定したことによって、生石灰が少なすぎると高分子吸収材がゲル状で残留する問題と、生石灰が多すぎると分離された素材に灰分が付着して質を低下させる問題が防止される。 In addition, by defining an appropriate ratio (3 wt% to 10%) of quicklime with respect to used paper diapers (predetermined input amount), if the amount of quicklime is too small, the polymer absorbent material remains in a gel state, and quicklime When there is too much, the problem that ash will adhere to the isolate | separated raw material and quality will be prevented is prevented.
また、使用済み紙オムツを連続水洗槽で揺すり洗い、あるいは、叩き洗いして構成素材を分離させるので、従来例と異なり、紙オムツを回転刃などで破砕する必要がなく、それだけ低コストに実施できる。 In addition, the used diapers are washed in a continuous water tank or scoured to separate the constituent materials. Unlike conventional examples, there is no need to crush paper diapers with a rotating blade, which is less expensive. it can.
また、粒度の異なる構成素材(パルプと高分子ポリマーとプラスチックなど)をスクリーンを用いて分別するので、これらを沈殿させて分別する従来例と異なり、分別時間が大きく短縮される上に、各素材を正確に分別することができるから、例えば、残留した高分子吸収材の付着が防止され、プラスチックとパルプの固形燃料化が容易になる。 In addition, since the constituent materials with different particle sizes (pulp, polymer polymer, plastic, etc.) are separated using a screen, the separation time is greatly reduced, unlike the conventional example in which these are precipitated and separated. Can be accurately separated, for example, adhesion of the remaining polymer absorbent is prevented, and plastic and pulp can be easily made into a solid fuel.
また、使用済み紙オムツを、予洗工程と本洗工程とすすぎ洗い工程とで連続的に水洗することによって処理時間が短縮され、処理能力が増加するから、大量の使用済み紙オムツを処理することが可能になる。 In addition, because the processing time is shortened and the processing capacity is increased by continuously washing the used paper diaper in the pre-washing process, the main washing process and the rinsing process, a large amount of used paper diapers must be processed. Is possible.
また、予洗、本洗、すすぎ洗いの各工程によって、水分を吸収した高分子ポリマーをほぼ完全に分離させることができる。 Moreover, the polymer polymer which absorbed the water | moisture content can be isolate | separated almost completely by each process of a prewash, a main wash, and a rinse.
また、食塩を使用しない本発明の方法では、使用済み紙オムツから分別され再資源化された素材に残留する塩素分が極めて少ない。 Further, in the method of the present invention in which no salt is used, the chlorine content remaining on the material separated and recycled from the used paper diaper is extremely small.
また、プラスチックはカロリーもA重油並みに高いので、固形燃料としての利用価値が高く、水分を吸収した高分子ポリマーが上記の水洗工程によって分離されているので、その後の固形燃料化が容易である。 In addition, since the plastic has a high calorie as high as A heavy oil, it is highly useful as a solid fuel, and the polymer polymer that has absorbed moisture is separated by the water washing step, so that subsequent solid fuel conversion is easy. .
[本発明の範囲に含まれる他の態様]
以上、実施形態について説明したが、本願発明はこれに限定されるものではなく、処理方法の要旨に付随する各種の変更が可能である。
[Other Embodiments Included within the Scope of the Present Invention]
Although the embodiment has been described above, the present invention is not limited to this, and various modifications accompanying the gist of the processing method are possible.
101 連続洗濯機 101 Continuous washing machine
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