JP2009102684A - Steel for ball cage of cvj - Google Patents

Steel for ball cage of cvj Download PDF

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JP2009102684A
JP2009102684A JP2007273830A JP2007273830A JP2009102684A JP 2009102684 A JP2009102684 A JP 2009102684A JP 2007273830 A JP2007273830 A JP 2007273830A JP 2007273830 A JP2007273830 A JP 2007273830A JP 2009102684 A JP2009102684 A JP 2009102684A
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steel
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ball cage
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cvj
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JP5071038B2 (en
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Kunio Kondo
邦夫 近藤
Tadayuki Yamamoto
忠之 山本
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Nippon Steel Corp
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Sumitomo Metal Industries Ltd
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Priority to PCT/JP2008/069091 priority patent/WO2009054394A1/en
Priority to MX2010004254A priority patent/MX2010004254A/en
Priority to KR1020107007473A priority patent/KR20100059951A/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16DCOUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D3/00Yielding couplings, i.e. with means permitting movement between the connected parts during the drive
    • F16D3/16Universal joints in which flexibility is produced by means of pivots or sliding or rolling connecting parts
    • F16D3/20Universal joints in which flexibility is produced by means of pivots or sliding or rolling connecting parts one coupling part entering a sleeve of the other coupling part and connected thereto by sliding or rolling members
    • F16D3/22Universal joints in which flexibility is produced by means of pivots or sliding or rolling connecting parts one coupling part entering a sleeve of the other coupling part and connected thereto by sliding or rolling members the rolling members being balls, rollers, or the like, guided in grooves or sockets in both coupling parts
    • F16D3/223Universal joints in which flexibility is produced by means of pivots or sliding or rolling connecting parts one coupling part entering a sleeve of the other coupling part and connected thereto by sliding or rolling members the rolling members being balls, rollers, or the like, guided in grooves or sockets in both coupling parts the rolling members being guided in grooves in both coupling parts
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/40Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for rings; for bearing races
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/22Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/48Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/50Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16DCOUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D3/00Yielding couplings, i.e. with means permitting movement between the connected parts during the drive
    • F16D3/16Universal joints in which flexibility is produced by means of pivots or sliding or rolling connecting parts
    • F16D3/20Universal joints in which flexibility is produced by means of pivots or sliding or rolling connecting parts one coupling part entering a sleeve of the other coupling part and connected thereto by sliding or rolling members
    • F16D3/22Universal joints in which flexibility is produced by means of pivots or sliding or rolling connecting parts one coupling part entering a sleeve of the other coupling part and connected thereto by sliding or rolling members the rolling members being balls, rollers, or the like, guided in grooves or sockets in both coupling parts
    • F16D3/223Universal joints in which flexibility is produced by means of pivots or sliding or rolling connecting parts one coupling part entering a sleeve of the other coupling part and connected thereto by sliding or rolling members the rolling members being balls, rollers, or the like, guided in grooves or sockets in both coupling parts the rolling members being guided in grooves in both coupling parts
    • F16D2003/22303Details of ball cages
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16DCOUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D3/00Yielding couplings, i.e. with means permitting movement between the connected parts during the drive
    • F16D3/16Universal joints in which flexibility is produced by means of pivots or sliding or rolling connecting parts
    • F16D3/20Universal joints in which flexibility is produced by means of pivots or sliding or rolling connecting parts one coupling part entering a sleeve of the other coupling part and connected thereto by sliding or rolling members
    • F16D3/22Universal joints in which flexibility is produced by means of pivots or sliding or rolling connecting parts one coupling part entering a sleeve of the other coupling part and connected thereto by sliding or rolling members the rolling members being balls, rollers, or the like, guided in grooves or sockets in both coupling parts
    • F16D3/223Universal joints in which flexibility is produced by means of pivots or sliding or rolling connecting parts one coupling part entering a sleeve of the other coupling part and connected thereto by sliding or rolling members the rolling members being balls, rollers, or the like, guided in grooves or sockets in both coupling parts the rolling members being guided in grooves in both coupling parts
    • F16D2003/22316Means for fastening or attaching the bellows or gaiters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16DCOUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D2250/00Manufacturing; Assembly

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
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  • General Engineering & Computer Science (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
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  • Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
  • Rolling Contact Bearings (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a steel for a ball cage of a CVJ, which shows the sufficient useful life even when being used for a CVJ that has been miniaturized and lightened, and even though being applied to the ball cage on which a bigger load stress than a conventional one works. <P>SOLUTION: The steel for the ball cage of a CVJ comprises, by mass%, 0.1 to 0.25% C, 0.05 to 0.7% Si, 0.05 to 1.2% Mn, 0.3 to 1.2% Cr, 0.005% or less S, 0.03% or less P, 0.02% or less N, 0.01% or less O (oxygen), 0.005 to 0.1% sol. Al and the balance Fe with impurities. The steel may further contain one or more elements among Mo, Ni, Ti, V and Zr in place of a part of Fe. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本発明は、自動車等の等速ジョイント(CVJ)のボールケージ部品に用いる鋼に関するものである。   The present invention relates to steel used for a ball cage component of a constant velocity joint (CVJ) such as an automobile.

自動車の駆動車軸から被駆動車軸に動力を伝達する等速継手(以下、CVJと略す)は、図1に示すように、駆動軸1に固設されたインナーレース(内輪)3と被駆動軸2に固設されたアウターレース(外輪)4との間に複数個のボール5を介挿し、これらのボールをボールケージ6にて保持した構造のものである。このボールケージ6とインナーレース3は、機構上非常に大きな回転力を伝達しようとするものであるため、高い強度、靱性および疲労強度が必要である。   As shown in FIG. 1, a constant velocity joint (hereinafter abbreviated as CVJ) that transmits power from a driving axle of an automobile to a driven axle includes an inner race (inner ring) 3 fixed to the driving shaft 1 and a driven shaft. In this structure, a plurality of balls 5 are inserted between an outer race (outer ring) 4 fixed to 2 and these balls are held by a ball cage 6. Since the ball cage 6 and the inner race 3 are intended to transmit a very large rotational force in terms of mechanism, high strength, toughness, and fatigue strength are required.

従って、これら部品には浸炭・焼入によって高い表面硬度と転動疲労性が付与される肌焼鋼が適用されており、従来はJISのSCr415、SCM415、SNC415、SNCM415といったCr系、Cr−Mo系、Ni−Cr系、Ni−Cr−Mo系の機械構造用合金鋼が肌焼鋼として用いられていた。   Accordingly, case hardening steel to which high surface hardness and rolling fatigue are imparted by carburizing and quenching is applied to these parts. Conventionally, Cr-based, Cr-Mo such as JIS SCr415, SCM415, SNC415, SNCM415. , Ni—Cr and Ni—Cr—Mo alloy steels for machine structural use have been used as case hardening steels.

しかしながら、昨今、CVJに対する小型軽量化の要求が大きく、従来に比べてボールケージに作用する応力が大きくなっている。従来の肌焼鋼では、静的強度、靱性および疲労強度が十分でないので、例えば、下記の特許文献1〜5に、合金組成を工夫することによって前記の問題点を解決する技術が提案されている。   However, recently, there is a large demand for reduction in size and weight with respect to the CVJ, and the stress acting on the ball cage is larger than in the past. In conventional case-hardened steel, since static strength, toughness and fatigue strength are not sufficient, for example, the following Patent Documents 1 to 5 propose a technique for solving the above-described problems by devising an alloy composition. Yes.

特許文献1にはCr−Mo量を適正化し、さらにNbまたはTiを添加した鋼が、そして、特許文献2にはCr−Mo量を適正化するとともにNbまたはTiを添加し、さらに、BやNiを添加した鋼が、それぞれ開示されている。特許文献3及び4には、Cr−Mo量を適正化するとともにBを添加した鋼が開示されている。また、特許文献5には、Cr鋼にBを添加した鋼が開示されている。   In Patent Document 1, a steel in which Cr—Mo amount is optimized and Nb or Ti is added is added, and in Patent Document 2, Nb or Ti is added while Cr—Mo amount is optimized, and B and Steels with added Ni are each disclosed. Patent Documents 3 and 4 disclose steels in which the amount of Cr—Mo is optimized and B is added. Patent Document 5 discloses steel in which B is added to Cr steel.

特開平1−39351号公報JP-A-1-39351 特開平5−117806号公報JP-A-5-117806 特開平9−53150号公報JP-A-9-53150 特開平9−53169号公報Japanese Patent Laid-Open No. 9-53169 特開2005−105379号公報JP 2005-105379 A

しかしながら、これらの特許文献で提案された肌焼鋼は、いずれもJISに規定された鋼に比べて、合金コストが高く製造性も低下する問題があった。また、寿命が従来に比べて低下するという問題があった。   However, all the case-hardened steels proposed in these patent documents have a problem that the alloy cost is high and manufacturability is lowered as compared with steels defined in JIS. In addition, there is a problem that the lifetime is reduced compared to the conventional one.

本発明の目的は、従来のものよりも小型軽量化されたCVJにおいて、従来よりも大きな負荷応力が作用するボールケージに適用しても、十分な耐用寿命が得られるCVJボールケージ用鋼を提供することにある。   An object of the present invention is to provide a steel for a CVJ ball cage that can provide a sufficient service life even when applied to a ball cage in which a larger load stress is applied to a CVJ that is smaller and lighter than the conventional one. There is to do.

本発明者らは、従来のものよりも小型軽量化されたCVJにおいて、従来よりも大きな負荷応力が作用するボールケージに関して、それが短期間で使用できなくなる事例を詳細に調査して、最も寿命に影響を及ぼす要因を分析し、その寿命を延ばす方策を検討した。その結果、次の(a)〜(h)に示す知見を得た。   The inventors of the present invention investigated in detail a case in which a CVJ that is smaller and lighter than the conventional one, and a ball cage that is subjected to a larger load stress than the conventional one, cannot be used in a short period of time. We analyzed the factors that affect the life span and examined measures to extend its lifespan. As a result, the following findings (a) to (h) were obtained.

(a)高速回転中にCVJのジョイント切れ角を大きくしたときに、ボールケージに負荷される応力が、材料強度を上回り、ボールケージが破断に至る。従って、材料強度を向上させることが重要である。   (a) When the joint cut angle of the CVJ is increased during high-speed rotation, the stress applied to the ball cage exceeds the material strength, and the ball cage breaks. Therefore, it is important to improve the material strength.

(b)強度の高い材料を用いてCVJのボールケージを作成して耐久試験を実施したが、高強度材であっても、実際のCVJで高速回転中にCVJのジョイント切れ角を大きくしたときに、ボールケージの破壊を抑制することはできず、ボールケージが破壊に至るかどうかと、単純な材料強度との対応は相関しなかった。   (b) A CVJ ball cage was made using a high-strength material and a durability test was conducted. Even when a high-strength material was used, when the joint break angle of the CVJ was increased during high-speed rotation with an actual CVJ. In addition, the failure of the ball cage could not be suppressed, and the correspondence between whether the ball cage would break and the simple material strength did not correlate.

(c)表面硬度を高めたり、靱性を高めたりしてボールケージの破壊が抑制されるかどうかを調査したが、いずれも破壊強度の向上には繋がらず、かえって低下する場合も多かった。   (c) Although it was investigated whether the fracture of the ball cage was suppressed by increasing the surface hardness or increasing the toughness, none of them led to an improvement in the fracture strength, and in many cases, it decreased.

(d)実際のCVJで高速回転中にCVJのジョイント切れ角を大きくすることと、ボールケージが破壊することの対応関係の調査結果により、ボールケージ破断は、ボールを固定するための窓のコーナー部分の応力集中部から発生することが判明した。よって、切欠き付き引張試験による強度と良い対応を示すことが分かった。   (d) Based on the investigation results of the correspondence between the CVJ joint break angle increasing during high-speed rotation in an actual CVJ and the ball cage breaking, the ball cage breakage is caused by the corner of the window for fixing the ball. It was found that it occurred from the stress concentration part of the part. Therefore, it was found that the strength by the notched tensile test shows a good correspondence.

(e)従って、ボールケージという特徴的な形状の部材に肌焼き鋼を使用する時の、破断強度を向上させるための材料設計指標は、切欠き引張強度を上げることであるが分かった。すなわち、ボールケージを小型軽量化する場合に、結果として、負荷される応力が大きくなるが、その場合に従来と同等以上の破断強度を確保したいときには切欠き付き引張強度の向上を図ればよいことが分かった。   (e) Therefore, it has been found that the material design index for improving the breaking strength when the case-hardened steel is used for a member having a characteristic shape called a ball cage is to increase the notch tensile strength. In other words, when the ball cage is reduced in size and weight, as a result, the stress to be applied increases, but in that case, it is necessary to improve the tensile strength with notches when it is desired to secure a breaking strength equal to or higher than the conventional one. I understood.

(f)次に、ボールケージ用としての肌焼き鋼の切欠き付き引張強度を向上させる検討を実施した。その結果、後述するとおり、切欠き付き引張強度は特にS含有量に大きく依存することが判明した。これに対して、引張強度はS含有量には依存しなかった。肌焼き鋼はギア等、種々の用途にも用いられているが、切削加工することが多い。しかしながら、切削性を確保する観点から、Sは通常積極的に添加されているが、今回発想を転換して、鋼中のS含有量を低減させたところ、切欠き付き引張強度が著しく向上することを見出したのである。すなわち、切欠引張強度を改善するためには、切削性の多少の低減が見込まれても、S含有量を低減することが唯一の方法であることが明らかになった。   (f) Next, a study was conducted to improve the notched tensile strength of case-hardened steel for ball cages. As a result, as will be described later, it was found that the notched tensile strength particularly depends greatly on the S content. On the other hand, the tensile strength did not depend on the S content. Case-hardened steel is used in various applications such as gears, but is often cut. However, from the viewpoint of ensuring machinability, S is usually actively added. However, when the S content in the steel is reduced by changing the concept this time, the tensile strength with notches is significantly improved. I found out. That is, in order to improve the notch tensile strength, it has become clear that reducing the S content is the only method even if some reduction in machinability is expected.

(g)Sを低減した時の切欠き付き引張強度の向上は、引張試験後の破面観察により、伸長したMnS系介在物の多寡に起因すると考えられる。切欠き付き引張試験では、試験時に切欠き部に応力が集中し、応力集中部直下に伸長したMnSが存在すると、破壊の起点になって、浸炭部が脆性破壊を生じるとともに、浸炭されていない中心部の靱性も伸長したMnSにより低下するので、一旦、早期にき裂が発生すると、き裂進展は止められずに低応力で破断する。通常の引張試験では、伸長したMnSが存在しても、応力集中する切欠きが存在しないので、浸炭部の脆性破壊が発生しにくく、破断応力が高くなると考えられる。従って、S含有量を低減して、MnS系介在物量を低減させた時、通常の引張強度はほとんど上昇しないが、切欠き付き引張強度は大きく改善される。本発明の用途である、ボールケージの使用中の破壊強度はこの切欠付き引張強度に支配されるので、S量を低減することにより、小型化しても破壊しにくい、信頼性の高いCVJを提供できることが可能となる。なお、本効果は、ボールケージという特有の形状の部品に好適な技術であって、通常の引張強度や、疲労強度に支配される他の用途には、このS量低減の効果はほとんど期待できず、かえって被削性を低下させるので、適用できる技術ではない。   (g) The improvement in notched tensile strength when S is reduced is considered to be due to the number of elongated MnS inclusions by observation of the fracture surface after the tensile test. In a notched tensile test, stress concentrates in the notch part during the test, and if MnS stretched directly under the stress concentrated part exists, it becomes the starting point of fracture, and the carburized part causes brittle fracture and is not carburized. Since the toughness of the central portion is also reduced by the elongated MnS, once a crack is generated at an early stage, the crack growth is not stopped and the fracture occurs with low stress. In a normal tensile test, even if elongated MnS is present, there is no notch where stress is concentrated, so that brittle fracture of the carburized portion is unlikely to occur, and the fracture stress is considered to increase. Therefore, when the S content is reduced and the amount of MnS inclusions is reduced, the normal tensile strength hardly increases, but the notched tensile strength is greatly improved. Since the breaking strength during use of the ball cage, which is an application of the present invention, is governed by this tensile strength with notches, reducing the amount of S provides a highly reliable CVJ that is difficult to break down even when downsized. It becomes possible. This effect is a technique suitable for a part with a specific shape called a ball cage, and the effect of reducing the amount of S can be almost expected for other applications controlled by normal tensile strength and fatigue strength. However, it is not a technique that can be applied because it reduces the machinability.

(h)図2〜17は、後述する実施例において用いた種々の化学組成を有する鋼について、Sの含有量をX軸に、そして、機械的性質をY軸にプロットしたものである。なお、機械的性質としては、通常の引張強度(平滑引張強度)と切欠き付き引張強度をその指標として用いた。   (h) FIGS. 2 to 17 are plots of the S content on the X axis and the mechanical properties on the Y axis for steels having various chemical compositions used in the examples described later. As the mechanical properties, normal tensile strength (smooth tensile strength) and notched tensile strength were used as indicators.

図2及び3は、SCr415系をベースにS含有量を変化させた鋼(鋼No.1〜8)の浸炭後の平滑及び切欠き引張強度を整理したグラフである。図2に示すように、S含有量を低減しても平滑引張強度はほとんど変化しない。ところが、図3に示すように、切欠き付き引張り強度はS含有量によって大きく変化し、鋼中のS含有量を低減すると大幅に強度が上昇することが分かる。   2 and 3 are graphs in which the smooth and notched tensile strengths after carburizing of steels (steel Nos. 1 to 8) in which the S content is changed based on the SCr415 system are arranged. As shown in FIG. 2, even if the S content is reduced, the smooth tensile strength hardly changes. However, as shown in FIG. 3, it can be seen that the notched tensile strength varies greatly depending on the S content, and that the strength increases significantly when the S content in the steel is reduced.

次に、図4及び5は、SCM415系をベースにS含有量を変化させた鋼(鋼No.9〜16)について、図6及び7はSCr420系をベースにS含有量を変化させた鋼(鋼No.17〜24)について、図8及び9はSCM420系をベースにS含有量を変化させた鋼(鋼No.25〜32)について、図10及び11はSAE8617系をベースにS含有量を変化させた鋼(鋼No.33〜41)について、図12及び13はSCr415系にTiを添加した鋼をベースにS含有量を変化させた鋼(鋼No.42〜49)について、図14及び15はSCM420系にNbを添加した鋼をベースにS含有量を変化させた鋼(鋼No.50〜57)について、そして、図16及び17はSAE8617系にTi、Nbを添加した鋼をベースにS含有量を変化させた鋼(鋼No.58〜65)について、それぞれ、浸炭後の平滑及び切欠き引張強度を整理したグラフである。図2及び3と同様に、S含有量を低減しても平滑引張強度はほとんど変化しないが、切欠き付き引張り強度は鋼中のS含有量を低減すると大幅に上昇することが分かる。   Next, FIGS. 4 and 5 are steels (steel Nos. 9 to 16) in which the S content is changed based on the SCM415 system, and FIGS. 6 and 7 are steels in which the S content is changed based on the SCr420 system. 8 and 9 are for steel (steel No. 25-32) in which the S content is changed based on the SCM420 system, and FIGS. 10 and 11 are S-containing based on the SAE8617 system. For steels with changed amounts (steel Nos. 33 to 41), FIGS. 12 and 13 show steels with changed S content (steel Nos. 42 to 49) based on steels with Ti added to the SCr415 system. FIGS. 14 and 15 show a steel (steel No. 50 to 57) in which the S content is changed based on a steel in which Nb is added to the SCM420 system, and FIGS. 16 and 17 show that Ti and Nb are added to the SAE8617 system. S content is changed based on steel For the allowed steel (steel Nanba58~65), respectively, it is a graph organizing smooth and notch tensile strength after carburizing. Similar to FIGS. 2 and 3, the smooth tensile strength hardly changes even when the S content is reduced, but it can be seen that the notched tensile strength increases significantly when the S content in the steel is reduced.

本発明は、上記の知見に基づいて完成したものであって、その要旨は下記の(1)〜(4)に係るCVJボールケージ用鋼にある。   The present invention has been completed based on the above findings, and the gist thereof is the steel for CVJ ball cage according to the following (1) to (4).

(1)質量%で、C:0.1〜0.25%、Si:0.05〜0.7%、Mn:0.05〜1.2%、Cr:0.3〜1.2%、S:0.005%以下、P:0.03%以下、N:0.02%以下、O(酸素):0.01%以下およびsol.Al:0.005〜0.1%を含有し、残部はFeと不純物からなることを特徴とするCVJボールケージ用鋼。   (1) By mass%, C: 0.1-0.25%, Si: 0.05-0.7%, Mn: 0.05-1.2%, Cr: 0.3-1.2% , S: 0.005% or less, P: 0.03% or less, N: 0.02% or less, O (oxygen): 0.01% or less and sol.Al: 0.005 to 0.1% And CVJ ball cage steel, the balance being Fe and impurities.

(2)質量%で、Feの一部に代えてさらにMo:0.7%以下を含有することを特徴とする、上記(1)のCVJボールケージ用鋼。   (2) The steel for a CVJ ball cage according to the above (1), further containing Mo: 0.7% or less instead of a part of Fe in mass%.

(3)質量%で、Feの一部に代えてさらにNi:1%以下を含有することを特徴とする、上記(1)又は(2)のCVJボールケージ用鋼。   (3) The steel for a CVJ ball cage according to the above (1) or (2), wherein the steel further contains Ni: 1% or less instead of a part of Fe in mass%.

(4)質量%で、Feの一部に代えてさらに、Ti:0.3%以下、Nb:0.3%以下、V:0.3%以下及びZr:0.3%以下のうちの1種以上を含有することを特徴とする、上記(1)〜(3)のいずれかのCVJボールケージ用鋼。   (4) By mass%, in place of part of Fe, Ti: 0.3% or less, Nb: 0.3% or less, V: 0.3% or less, and Zr: 0.3% or less The steel for a CVJ ball cage according to any one of (1) to (3) above, which contains one or more kinds.

本発明によれば、従来のものよりも小型軽量化されたCVJにおいて、従来よりも大きな負荷応力が作用するボールケージに適用しても、十分な耐用寿命が得られるCVJボールケージ用鋼を提供することにある。   According to the present invention, a steel for a CVJ ball cage that can provide a sufficient service life even when applied to a ball cage that is subjected to a larger load stress than a conventional CVJ that is smaller and lighter than the conventional one. There is to do.

以下に、本発明に係るCVJボールケージ用鋼を構成する化学組成の限定理由について述べる。なお、各元素の含有量の「%」は「質量%」を表す。   The reason for limiting the chemical composition constituting the CVJ ball cage steel according to the present invention will be described below. In addition, “%” of the content of each element represents “mass%”.

C:0.1〜0.25%
Cは、鋼の硬度あるいは強度を決める基本的な元素であるので、要求される強度に応じて、添加する元素である。ボールケージとして最低の強度を確保するためには、0.10%以上含有させる必要がある。一方、Cの含有量が高くなりすぎると、靱性が低下するので、上限を0.25%とした。
C: 0.1-0.25%
Since C is a basic element that determines the hardness or strength of steel, it is an element to be added according to the required strength. In order to ensure the minimum strength as a ball cage, it is necessary to contain 0.10% or more. On the other hand, if the C content is too high, the toughness decreases, so the upper limit was made 0.25%.

Si:0.05〜0.7%
Siは、鋼の脱酸に効果があり、また、焼入れ性を高めて、鋼を強化する元素であり、0.05%以上含有させる必要がある。しかしながら、Siの含有量が0.7%を超えると、浸炭焼入れ時に粒界酸化を助長して、切欠き付き引張強度を低下させるので、0.7%を上限とした。なお、切欠き付き引張強度の面からは、Si含有量は低い方が好ましい。脱酸レベルとの兼ね合いもあるが、好ましいのは0.5%以下、より好ましいのは0.3%以下である。
Si: 0.05-0.7%
Si is effective in deoxidation of steel, and is an element that enhances hardenability and strengthens steel, and needs to be contained by 0.05% or more. However, if the Si content exceeds 0.7%, grain boundary oxidation is promoted during carburizing and quenching, and the notched tensile strength is reduced, so 0.7% was made the upper limit. From the viewpoint of notched tensile strength, the Si content is preferably low. Although there is a balance with the deoxidation level, 0.5% or less is preferable and 0.3% or less is more preferable.

Mn:0.05〜1.2%
MnもSi同様、鋼の脱酸に効果があり、また、焼入れ性を高めて、鋼を強化する元素であり、0.05%以上含有させる必要がある。しかしながら、Mnの含有量が1.2%を超えると、浸炭焼入れ時に粒界酸化を助長して、切欠き付き引張強度を低下させるので、1.2%以下とした。なお、切欠き付き引張強度の面からは、Mn含有量は低い方が好ましい。脱酸レベルとの兼ね合いもあるが、好ましいのは1.0%以下である。
Mn: 0.05-1.2%
Mn, like Si, is effective in deoxidizing steel, and is an element that enhances hardenability and strengthens steel, and it is necessary to contain 0.05% or more. However, if the Mn content exceeds 1.2%, grain boundary oxidation is promoted during carburizing and quenching, and the notched tensile strength is reduced. From the viewpoint of notched tensile strength, the Mn content is preferably low. Although there is a balance with the deoxidation level, 1.0% or less is preferable.

Cr:0.3〜1.2%
CrはCとの親和性が大きく、短時間で浸炭を進行させるのには必要な元素である。また、浸炭焼入れ時の焼入れ性の確保にも重要な元素である。その効果を得るためには、0.3%以上含有させる必要がある。一方、Crの含有量が1.2%を超えると、Cr炭化物が析出して、靱性を低下させる。したがって、Cr含有量は0.3〜1.2%とした。
Cr: 0.3-1.2%
Cr has a large affinity with C, and is an element necessary for advancing carburization in a short time. It is also an important element for ensuring hardenability during carburizing and quenching. In order to acquire the effect, it is necessary to contain 0.3% or more. On the other hand, if the Cr content exceeds 1.2%, Cr carbide precipitates and the toughness is lowered. Therefore, the Cr content is set to 0.3 to 1.2%.

S:0.005%以下
Sの含有量を低く抑えることは、本発明に係る鋼の最も重要な特徴であり、その含有量が0.005%を超えると、必要な切欠き付き引張強度を確保することができない。したがって、Sの含有量は0.005%以下とした。より好ましくは0.003%以下、さらに好ましくは、0.0015%以下であり、低減すればするほど切欠き付き引張強度が向上する。しかしながら、Sの低減にともない切削加工性が低下するという問題がある上にSを低減すると製鋼コストが上昇するので、これらを考慮する場合には、Sの好ましい下限は0.0009%を超える含有量である。
S: 0.005% or less Keeping the S content low is the most important feature of the steel according to the present invention. If the content exceeds 0.005%, the necessary notched tensile strength is reduced. It cannot be secured. Therefore, the content of S is set to 0.005% or less. More preferably, it is 0.003% or less, and further preferably, 0.0015% or less. The lower the value, the higher the notched tensile strength. However, since there is a problem that the machinability is lowered with the reduction of S and the steel making cost increases when S is reduced, the preferable lower limit of S is more than 0.0009% when considering these. Amount.

P:0.03%以下
Pは鋼中に不純物として含有される。Pは粒界の結合力を小さくして、靱性を低下させる元素であり、可及的に少ない方が好ましいが、低位に押さえようとすると、製鋼コストが上昇するので、経済性を考慮して、0.03%以下とした。0.03%以下であれば、ボールケージとして十分な靱性が得られる。
P: 0.03% or less P is contained as an impurity in the steel. P is an element that reduces the bond strength at the grain boundary and lowers the toughness, and is preferably as small as possible. 0.03% or less. If it is 0.03% or less, sufficient toughness as a ball cage can be obtained.

N:0.02%以下
Nは鋼中に不純物として含有される。Nの含有量が0.02%を超えると靱性が低下するため、その含有量は0.02%以下とした。より好ましい上限は0.01%、さらに好ましい上限は0.007%である。
N: 0.02% or less N is contained as an impurity in the steel. If the N content exceeds 0.02%, the toughness decreases, so the content was set to 0.02% or less. A more preferable upper limit is 0.01%, and a further preferable upper limit is 0.007%.

O(酸素):0.01%以下
Oは鋼中に不純物として含有される。Oの含有量が0.01%を超えると靱性が低下するため、その含有量は0.01%以下とした。
sol.Al:0.005〜0.1%
Alは、鋼の脱酸に必要な元素であり、0.005%以上含有させる必要がある。一方、0.1%を超えると、クラスター状の非金属介在物が生成して靱性が低下するので、0.005%〜0.1%とした。
O (oxygen): 0.01% or less O is contained as an impurity in the steel. If the O content exceeds 0.01%, the toughness decreases, so the content was set to 0.01% or less.
sol.Al: 0.005 to 0.1%
Al is an element necessary for deoxidation of steel, and should be contained by 0.005% or more. On the other hand, if it exceeds 0.1%, cluster-like nonmetallic inclusions are generated and the toughness is lowered, so the content was made 0.005% to 0.1%.

本発明のCVJボールケージ用高強度肌焼鋼管は、上記の成分のほか、Mo、Ni、Ti、Nb、V及びZrのうちの1種以上をさらに含有してもよい。なお、この場合も、P、NおよびOを上記のように低く抑える必要があることは同じである。   The high-strength case-hardened steel pipe for CVJ ball cage of the present invention may further contain one or more of Mo, Ni, Ti, Nb, V and Zr in addition to the above components. In this case, it is the same that P, N, and O need to be kept low as described above.

Mo:0.7%以下
Moは、浸炭部の焼入れ性を向上させ、鋼の強度を向上させる作用を有する。したがって、この効果を発現させたい場合には、Moを含有させることができる。しかし、0.7%を超えて含有させても、効果が飽和して、コストが上昇するだけである。したがって、Moを含有させる場合でも、その含有量の上限は0.7%とした。なお、この効果を確実に得るには、その含有量を0.1%以上とするのが好ましい。
Mo: 0.7% or less Mo has an effect of improving the hardenability of the carburized portion and improving the strength of the steel. Therefore, when this effect is desired to be expressed, Mo can be contained. However, even if the content exceeds 0.7%, the effect is saturated and the cost only increases. Therefore, even when Mo is contained, the upper limit of the content is set to 0.7%. In addition, in order to acquire this effect reliably, it is preferable that the content shall be 0.1% or more.

Ni:1%以下
Niは、鋼の強度と靱性を向上させる作用を有する。CrやMoと異なり、多量に添加しても悪影響が少ない元素であるので、特に強度の高い材質を設計するのに有効な成分である。したがって、この効果を発現させたい場合には、Niを含有させることができる。しかし、1%を超えて含有させても、効果が飽和して、コストが上昇するだけである。したがって、Niを含有させる場合でも、その含有量の上限は1%とした。なお、この効果を確実に得るには、その含有量を0.1%以上とするのが好ましい。
Ni: 1% or less Ni has the effect of improving the strength and toughness of steel. Unlike Cr and Mo, it is an element that has little adverse effect even when added in a large amount, and is therefore an effective component for designing a particularly strong material. Therefore, when this effect is desired to be expressed, Ni can be contained. However, if the content exceeds 1%, the effect is saturated and the cost only increases. Therefore, even when Ni is contained, the upper limit of the content is set to 1%. In addition, in order to acquire this effect reliably, it is preferable that the content shall be 0.1% or more.

Ti、Nb、V及びZr:それぞれ、0.3%以下
これらの元素は、浸炭焼入れ時の結晶粒の粗粒化を抑制し、靱性を向上させる作用を有する。したがって、この効果を発現させたい場合には、Ti、Nb、V及びZrのうち、1種以上を含有させることができる。しかし、それぞれ、0.3%を超えて含有させると、かえって靱性が低下するので、Ti、Nb、V及びZrのうち、1種以上を含有させる場合でも、その含有量の上限は、それぞれ0.3%以下とした。なお、この効果を確実に得るには、その含有量を0.003%以上とするのが好ましい。
Ti, Nb, V, and Zr: each 0.3% or less These elements have the effect of suppressing coarsening of crystal grains during carburizing and quenching and improving toughness. Therefore, when this effect is desired to be expressed, one or more of Ti, Nb, V and Zr can be contained. However, if each content exceeds 0.3%, the toughness is rather lowered. Therefore, even when at least one of Ti, Nb, V and Zr is contained, the upper limit of the content is 0. .. 3% or less In addition, in order to acquire this effect reliably, it is preferable that the content shall be 0.003% or more.

なお、本発明に係るCVJボールケージ用鋼は、ボールケージの形状に加工した後、浸炭焼入れと焼戻し処理を経て、CVJの部品として使用される。   The CVJ ball cage steel according to the present invention is used as a CVJ component after being carburized and tempered after being processed into a ball cage shape.

表1及び表2に示す化学組成の鋼材を溶製し、熱間鍛造および熱間圧延を行って25mm厚、120mm幅、550mm長の板材を作製し、920℃で焼ならしを行った後、720℃で焼戻しを実施して軟化させた。次に、表面スケールを除去した後、16mm厚まで冷間加工し、再度720℃で焼戻しを施して軟化させた。   After melting steel materials having chemical compositions shown in Tables 1 and 2 and performing hot forging and hot rolling to produce plate materials of 25 mm thickness, 120 mm width and 550 mm length, and normalizing at 920 ° C. And tempering at 720 ° C. for softening. Next, after removing the surface scale, it was cold worked to a thickness of 16 mm, and tempered again at 720 ° C. to be softened.

Figure 2009102684
Figure 2009102684

Figure 2009102684
Figure 2009102684

上記の素材から、平行部の直径が8mmの平滑引張試験片と、同じく平行部の直径は8mmで、深さ1mmの切欠を有する切欠き付き引張試験片を、圧延方向に垂直な方向であるT方向から、それぞれ採取した。そして、以下の条件で試験片に浸炭処理および熱処理を実施した。   A smooth tensile test piece having a parallel part diameter of 8 mm and a notched tensile test piece having a parallel part diameter of 8 mm and a depth of 1 mm from the above material are perpendicular to the rolling direction. Each sample was collected from the T direction. And the carburizing process and heat processing were implemented to the test piece on the following conditions.

まず、カーボンポテンシャル0.9%、930℃で、130分浸炭し、続いて、カーボンポテンシャル0.8%、870℃で30分浸炭し、その後油焼入れを行った。次いで、160℃で2時間焼き戻して、平滑引張強度と切欠き付き引張強度を測定し、その機械的性質を評価した。平滑引張強度と切欠き付き引張強度の測定結果を表1及び表2に示す。   First, carburization was performed at a carbon potential of 0.9% and 930 ° C. for 130 minutes, followed by carburization at a carbon potential of 0.8% and 870 ° C. for 30 minutes, followed by oil quenching. Subsequently, it tempered at 160 degreeC for 2 hours, measured the smooth tensile strength and the notched tensile strength, and evaluated the mechanical property. Tables 1 and 2 show the measurement results of the smooth tensile strength and the notched tensile strength.

図2〜17は、この表2のデータを用いて、鋼種毎に、Sの含有量をX軸に、そして、機械的性質(平滑引張強度、切欠き付き引張強度)をY軸にプロットしたグラフであることは前述したとおりである。S含有量を低減しても平滑引張強度はほとんど変化しないが、切欠き付き引張り強度は鋼中のS含有量を低減すると大幅に上昇することが分かる。   2 to 17, using the data in Table 2, for each steel type, the S content is plotted on the X axis, and the mechanical properties (smooth tensile strength, notched tensile strength) are plotted on the Y axis. As described above, it is a graph. It can be seen that even if the S content is reduced, the smooth tensile strength hardly changes, but the notched tensile strength increases significantly when the S content in the steel is reduced.

本発明に係るCVJボールケージ用鋼は、小型軽量化されたCVJにおいて、より大きな負荷応力が作用するボールケージに適用すると、十分な耐用寿命が得られる。したがって、自動車の軽量化と燃費の向上に大きく寄与する。   When the CVJ ball cage steel according to the present invention is applied to a ball cage in which a larger load stress acts in a CVJ reduced in size and weight, a sufficient service life can be obtained. Therefore, it greatly contributes to the weight reduction and fuel consumption improvement of automobiles.

等速継手の一例を示す断面図である。It is sectional drawing which shows an example of a constant velocity joint. SCr415系の鋼種でのSの含有量と平滑引張強度の関係を示す。The relationship between the S content and the smooth tensile strength in the SCr415 steel type is shown. SCr415系の鋼種でのSの含有量と切欠き付き引張強度の関係を示す。The relationship between the S content and the notched tensile strength in the SCr415 steel type is shown. SCM415系の鋼種でのSの含有量と平滑引張強度の関係を示す。The relationship between the S content and the smooth tensile strength in the SCM415 type steel is shown. SCM415系の鋼種でのSの含有量と切欠き付き引張強度の関係を示す。The relationship between the S content and the notched tensile strength in SCM415 steel types is shown. SCr420系の鋼種でのSの含有量と平滑引張強度の関係を示す。The relationship between the S content and the smooth tensile strength in the SCr420 steel type is shown. SCr420系の鋼種でのSの含有量と切欠き付き引張強度の関係を示す。The relationship between the S content and the notched tensile strength in the SCr420 steel grade is shown. SCM420系の鋼種でのSの含有量と平滑引張強度の関係を示す。The relationship between the S content and the smooth tensile strength in the SCM420 steel type is shown. SCM420系の鋼種でのSの含有量と切欠き付き引張強度の関係を示す。The relationship between the S content and the notched tensile strength in the SCM420 steel type is shown. SAE8617系の鋼種でのSの含有量と平滑引張強度の関係を示す。The relationship between the S content and the smooth tensile strength in the SAE8617 steel type is shown. SAE8617系の鋼種でのSの含有量と切欠き付き引張強度の関係を示す。The relationship between the S content and the notched tensile strength in the SAE8617 steel grade is shown. SCr415系にTiを添加した鋼種でのSの含有量と平滑引張強度の関係を示す。The relationship between the S content and the smooth tensile strength in the steel type in which Ti is added to the SCr415 system is shown. SCr415系にTiを添加した鋼種でのSの含有量と切欠き付き引張強度の関係を示す。The relationship between the S content and the notched tensile strength in the steel type in which Ti is added to the SCr415 system is shown. SCM420系にNbを添加した鋼種でのSの含有量と平滑引張強度の関係を示す。The relationship between the S content and the smooth tensile strength in the steel type in which Nb is added to the SCM420 system is shown. SCM420系にNbを添加した鋼種でのSの含有量と切欠き付き引張強度の関係を示す。The relationship between the S content and the notched tensile strength in the steel type in which Nb is added to the SCM420 system is shown. SAE8617系にTiとNbを添加した鋼種でのSの含有量と平滑引張強度の関係を示す。The relationship between the S content and the smooth tensile strength in a steel type in which Ti and Nb are added to the SAE8617 system is shown. SAE8617系にTiとNbを添加した鋼種でのSの含有量と切欠き付き引張強度の関係を示す。The relationship between the S content and the notched tensile strength in steel types obtained by adding Ti and Nb to the SAE8617 system is shown.

符号の説明Explanation of symbols

1 駆動軸
2 被駆動軸
3 インナーレース
4 アウターレース
5 ボール
6 ボールケージ
1 Driving shaft 2 Driven shaft 3 Inner race 4 Outer race 5 Ball 6 Ball cage

Claims (4)

質量%で、C:0.1〜0.25%、Si:0.05〜0.7%、Mn:0.05〜1.2%、Cr:0.3〜1.2%、S:0.005%以下、P:0.03%以下、N:0.02%以下、O(酸素):0.01%以下およびsol.Al:0.005〜0.1%を含有し、残部はFeと不純物からなることを特徴とするCVJボールケージ用鋼。   In mass%, C: 0.1-0.25%, Si: 0.05-0.7%, Mn: 0.05-1.2%, Cr: 0.3-1.2%, S: 0.005% or less, P: 0.03% or less, N: 0.02% or less, O (oxygen): 0.01% or less and sol.Al: 0.005-0.1%, the balance Is a steel for a CVJ ball cage characterized by comprising Fe and impurities. 質量%で、Feの一部に代えてさらにMo:0.7%以下を含有することを特徴とする、請求項1に記載のCVJボールケージ用鋼。   The steel for a CVJ ball cage according to claim 1, wherein the steel further contains Mo: 0.7% or less in mass% instead of part of Fe. 質量%で、Feの一部に代えてさらにNi:1%以下を含有することを特徴とする、請求項1又は2に記載のCVJボールケージ用鋼。   The steel for a CVJ ball cage according to claim 1 or 2, further comprising Ni: 1% or less instead of a part of Fe in mass%. 質量%で、Feの一部に代えてさらに、Ti:0.3%以下、Nb:0.3%以下、V:0.3%以下及びZr:0.3%以下のうちの1種以上を含有することを特徴とする、請求項1から3までのいずれかに記載のCVJボールケージ用鋼。   1% or more of Ti: 0.3% or less, Nb: 0.3% or less, V: 0.3% or less and Zr: 0.3% or less The steel for a CVJ ball cage according to any one of claims 1 to 3, characterized by comprising:
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