JP2009083900A - Paper vessel for liquid - Google Patents

Paper vessel for liquid Download PDF

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Publication number
JP2009083900A
JP2009083900A JP2007255615A JP2007255615A JP2009083900A JP 2009083900 A JP2009083900 A JP 2009083900A JP 2007255615 A JP2007255615 A JP 2007255615A JP 2007255615 A JP2007255615 A JP 2007255615A JP 2009083900 A JP2009083900 A JP 2009083900A
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Japan
Prior art keywords
layer
projecting
paper container
wall part
liquid paper
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JP2007255615A
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Japanese (ja)
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Akira Ishikawa
明 石川
Tatsuya Matsuoka
達哉 松岡
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Dai Nippon Printing Co Ltd
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Dai Nippon Printing Co Ltd
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Priority to JP2007255615A priority Critical patent/JP2009083900A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/80Packaging reuse or recycling, e.g. of multilayer packaging

Abstract

<P>PROBLEM TO BE SOLVED: To provide a paper vessel for liquid capable of being volume-reduced by easily peeling (disassembling) a bottom part after use and being easily reused as resources. <P>SOLUTION: The paper vessel P1 for liquid has the bottom part comprising a bottom wall part 24, overhanging parts 10 connected to both side wall parts and stretching out in the sidelong direction of both the side wall parts respectively and each having an approximately triangle shape in a plan view, a mated-gluing wall part 6 made by mate-gluing one mated wall part and another mated wall part between the tip ends of the overhanging parts, and the first protrusive pieces 8 protrusively mounted on both ends of both overhanging parts of another mated wall part in the direction perpendicular to the lengthwise direction of another mated wall part 7, the bottom part being made by folding the mated-gluing wall part so that another mated wall part contacts the bottom wall part, folding both overhanging parts on the bottom wall part side and fixing both the overhanging parts to the mated-gluing wall part wherein the paper vessel for liquid is separably composed of an outer surface portion of paper as a major component and an inner surface side portion of a plastic as a major component. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本発明は、コーヒー、ジュース、清酒、焼酎、ウイスキー、ワイン、シャンプー、リンス、ドレッシング、ケチャップ、マヨネーズ、あるいは、各種洗浄液等の液状物や粘稠物等の内容物を収容する液体用紙容器に関し、さらに詳しくは、使用した後に液体用紙容器を廃棄する場合に、容易に折り畳んで減容化することができることは元より、特に紙を主体とする部分とプラスチックを主体とする部分とに容易に分離することができ、廃棄し易く、また、容易に資源の再利用に繋げることができる液体用紙容器に関するものである。   The present invention relates to a liquid paper container for storing contents such as liquids and viscous substances such as coffee, juice, sake, shochu, whiskey, wine, shampoo, rinse, dressing, ketchup, mayonnaise, or various cleaning liquids, More specifically, when the liquid paper container is discarded after use, it can be easily folded and reduced in volume, and it is easily separated into a part mainly made of paper and a part mainly made of plastic. The present invention relates to a liquid paper container that can be disposed of easily, can be easily discarded, and can easily lead to reuse of resources.

液体用紙容器としては、1)上部に傾斜屋根部を設けたゲーベルトップ型紙容器や、2)六面体形状からなるブリック(Brick)型紙容器、あるいは、ブリック型紙容器を変形した六角柱状や天面および底面が四角形状で胴部が八角形状の柱状紙容器、また、底面は四角形状で天部が横一線シールを行ったままの楔状紙容器などが知られている。   Examples of liquid paper containers include 1) a Gobeltop paper container with an inclined roof on the top, 2) a brick paper container having a hexahedral shape, or a hexagonal column shape, a top surface, and a bottom surface obtained by modifying the brick paper container. A columnar paper container having a quadrangular shape and an octagonal body shape, and a wedge-shaped paper container having a rectangular bottom surface and a top portion with a horizontal line seal are known.

上記した液体用紙容器は、いずれも底部を構成する構成部材が折り畳まれると共に熱圧着により固着されている。特に、底部において表出する構成部材の先端部が紙容器底部に密着した状態で強固に固着されている。したがって、このような形状の容器をリサイクル時に折り畳んで減容化する時には底部に密着状態で強固に固着された構成部材の先端部を手指で引き上げて剥離して解体する必要があるが、この剥離(解体)時に爪等を傷める虞があるという問題や、また、前記問題を生じないためには、挟みやカッターナイフ等の刃物を用いる必要があるが、刃物を用いて解体する作業は結構鬱陶しいという問題があり、手指で簡単に底部を剥離(解体)することができて減容化することができる液体用紙容器が望まれていた。   In each of the liquid paper containers described above, the constituent members constituting the bottom are folded and fixed by thermocompression bonding. In particular, the tips of the constituent members that are exposed at the bottom are firmly fixed in a state where they are in close contact with the bottom of the paper container. Therefore, when the volume of such a container is folded and reduced in volume, it is necessary to pull up the tip of the structural member firmly fixed in close contact with the bottom with a finger and peel it off to disassemble it. (Dismantling) There is a risk of damaging nails, etc., and in order not to cause the above problem, it is necessary to use a knife such as a pinch or a cutter knife, but the work of disassembling with a knife is quite annoying Therefore, there has been a demand for a liquid paper container that can easily be peeled (disassembled) with a finger and can be reduced in volume.

この要望に応える一つの技術として、液体用紙容器の底面が該液体用紙容器の対向する一組の側面と接するそれぞれの辺を前記液体用紙容器内面側に持ち上げることにより底面を凹面とし、これにより底面シールフラップを底部に固着することなく底部に沿った状態で保持する技術がある(たとえば、特許文献1参照)。   As one technique for meeting this demand, the bottom surface of the liquid paper container is made concave by lifting the respective sides of the liquid paper container that are in contact with a pair of opposing side surfaces to the inner surface side of the liquid paper container, thereby making the bottom surface concave. There is a technique for holding the seal flap in a state along the bottom without being fixed to the bottom (see, for example, Patent Document 1).

また、他の技術としては、液体用紙容器の底面横線シールに2箇所の切り込みを設け、この2箇所の切り込みに底面シールフラップを底面に接触するように折り曲げると共に前記切り込みに前記底面シールフラップを挟み込むことにより底面シールフラップを底部に固着することなく底部に沿った状態で保持する技術がある(たとえば、特許文献2参照)。   As another technique, the bottom horizontal line seal of the liquid paper container is provided with two cuts, the bottom seal flap is bent so as to contact the bottom of the two cuts, and the bottom seal flap is sandwiched between the cuts. Thus, there is a technique for holding the bottom seal flap in a state along the bottom without being fixed to the bottom (see, for example, Patent Document 2).

しかしながら、上記二つの技術は、凹面を形成することにより紙の反発力を利用して底面シールフラップを底部に沿った状態で保持する、あるいは、切り込みに底面シールフラップを挟み込むことにより底面シールフラップを底部に固着することなく底部に沿った状態で保持する、という技術であり、底面シールフラップを底部に固着する従来の紙容器からすると、流通過程等において外力が液体用紙容器に加わった場合等において、保持状態が解除されて販売時に底部の底面シールフラップが開き、製品の外観の悪さのみならず、製品が改竄されたイメージを購入者に与える虞がある。   However, in the above two techniques, the bottom surface seal flap is held along the bottom by using the repulsive force of the paper by forming a concave surface, or the bottom surface seal flap is held by sandwiching the bottom surface seal flap in the notch. It is a technology that keeps the bottom seal flap in a state that does not stick to the bottom, and in the case where an external force is applied to the liquid paper container in the distribution process etc. When the holding state is released, the bottom seal flap at the bottom is opened at the time of sale, which may give the purchaser not only a poor appearance of the product but also an image of the product being altered.

また、液体用紙容器に対する別の要望としては、減容化することができることは元より、特に紙を主体とする部分とプラスチックを主体とする部分とに容易に分離することができて容易に資源の再利用に繋げることができる液体用紙容器が望まれていた。   Another requirement for liquid paper containers is that they can be reduced in volume and can be easily separated into parts mainly made of paper and parts made mainly of plastic. There has been a demand for a liquid paper container that can be reused.

この技術としては、紙を主体とする部分とプラスチックを主体とする部分との間に剥離層を設けて、この剥離層にて紙を主体とする部分とプラスチックを主体とする部分とを容易に分離可能としたものである(たとえば、特許文献3参照)。さらに、特許文献3は、天部と底部が熱接着により密封される構造となっているが、天部と底部において外面同士が熱接着される領域に部分的に接着強度調整層を設けて、天部と底部を容易に解体することができるように構成されており、天部の解体は未だしも、一般的にパーフェクトボトムと言われている底部の解体は上記した接着強度調整層を設けてなお相当な力を必要とするものであり、引用文献1、2と同様に底部の解体の容易な液体用紙容器が望まれていた。   In this technology, a release layer is provided between a paper-based part and a plastic-based part, and the paper-based part and plastic-based part can be easily separated by this release layer. Separable (see, for example, Patent Document 3). Furthermore, Patent Document 3 has a structure in which the top and the bottom are sealed by thermal bonding, but the adhesive strength adjustment layer is partially provided in a region where the outer surfaces are thermally bonded to each other at the top and the bottom. It is configured so that the top and bottom can be easily disassembled, and the disassembly of the top is still provided with the adhesive strength adjustment layer described above, which is generally called the perfect bottom. A considerable amount of force is still required, and a liquid paper container that can be easily disassembled at the bottom has been desired as in the case of the cited documents 1 and 2.

本発明者は、ブリック型紙容器のフラットボトムに着目し、底部において密着状態で強固に固着された構成部材の先端部近傍に構成部材を手指で引き上げて剥離するための掴み代を設けることにより、特に液体用紙容器の底部を容易に解体することができて減容化することができ、廃棄しやすくすることができると共に、特許文献3の技術を適用することにより、紙を主体とする部分とプラスチックを主体とする部分とを容易に分離することができ、資源を再利用しやすくすることができることを見出して本発明に至ったものである。
特開2002−154527号公報 特開2002−225845号公報 特開2000−085756号公報
The present inventor pays attention to the flat bottom of the brick-type paper container, and by providing a grip allowance for pulling up and peeling the constituent member with a finger near the tip of the constituent member firmly fixed in the bottom portion, In particular, the bottom portion of the liquid paper container can be easily disassembled and can be reduced in volume, can be easily disposed of, and by applying the technique of Patent Document 3, The present invention has been achieved by finding that a portion mainly composed of plastic can be easily separated and resources can be easily reused.
JP 2002-154527 A JP 2002-225845 A JP 2000-085756 A

そこで本発明は、使用後に容易に底部を手指で剥離(解体)することができて減容化でき、廃棄しやすくすることができると共に、資源を再利用しやすくすることができる液体用紙容器を提供することである。   Therefore, the present invention provides a liquid paper container that can be easily peeled (disassembled) after use with a finger, can be reduced in volume, can be easily discarded, and can be easily reused. Is to provide.

本発明者は、上記課題を達成するために、請求項1記載の本発明は、四角形状からなる底部を備え、前記底部は底壁部と、対向する位置にある両側壁部のそれぞれに連設されて前記両側壁部のそれぞれの側方に張り出した平面視略三角形状の張出部と、該張出部の両先端部間に亘って前記両張出部と前記底壁部とからなる一方の合掌壁部と他方の合掌壁部とを合掌貼りして底部を密封する合掌貼り壁部と、前記他方の合掌壁部の前記両張出部の両端部に前記他方の合掌壁部の長手方向に直交する方向に突出形成される第1突片とで構成され、前記合掌貼り壁部をその内端縁で前記両張出部と前記底壁部に前記他方の合掌壁部が当接するように折り重ねると共に前記両張出部を前記両張出部を前記底壁部側に折り重ね、前記両張出部を前記合掌貼り壁部で固着してなる前記底部を有する液体用紙容器であって、該液体用紙容器は外面から順に熱可塑性樹脂層と紙層と接着樹脂層と剥離層とガスバリアー層と熱可塑性樹脂層とが積層された積層体からなり、前記剥離層にて前記剥離層より外面側部分と内面側部分とが分離可能に構成されてなることを特徴とするものである。   In order to achieve the above object, the inventor of the present invention includes a bottom portion having a quadrangular shape, and the bottom portion is connected to each of the bottom wall portion and both side wall portions at opposite positions. A projecting portion having a substantially triangular shape in plan view and projecting to the sides of the both side wall portions, and both the projecting portions and the bottom wall portion between both end portions of the projecting portions. And the other joint wall part at both ends of the both projecting parts of the other joint wall part. The first projecting piece is formed to project in a direction perpendicular to the longitudinal direction of the first wall, and the other palm wall portion is formed on the both projecting portions and the bottom wall portion at the inner edge thereof. Folding the two overhangs so that they come into contact with each other, the two overhangs are folded over to the bottom wall side, and the two overhangs are joined to the palm. A liquid paper container having the bottom portion fixed by a wall part, the liquid paper container being in order from the outer surface a thermoplastic resin layer, a paper layer, an adhesive resin layer, a release layer, a gas barrier layer, and a thermoplastic resin layer Is formed such that an outer surface side portion and an inner surface side portion of the release layer are separable from each other in the release layer.

また、請求項2記載の本発明は、四角形状からなる底部を備え、前記底部は底壁部と、対向する位置にある両側壁部のそれぞれに連設されて前記両側壁部のそれぞれの側方に張り出した平面視略三角形状の張出部と、該張出部の両先端部間に亘って前記両張出部と前記底壁部とからなる一方の合掌壁部と他方の合掌壁部とを合掌貼りして底部を密封する合掌貼り壁部と、前記他方の合掌壁部の前記両張出部に両端部に前記他方の合掌壁部の長手方向に直交する方向に突出形成される第1突出部と前記一方の合掌壁部の前記張出部の両端部であって、前記第1突出部と対向する位置に前記第1突出部よりも突出長さが短い第2突出部とからなる第2突片とで構成され、前記合掌貼り壁部をその内端縁で前記両張出部と前記底壁部に前記他方の合掌壁部が当接するように折り重ねると共に前記両張出部を前記底壁部側に折り重ね、前記両張出部を前記合掌貼り壁部で固着してなる前記底部を有する液体用紙容器であって、該液体用紙容器は外面から順に熱可塑性樹脂層と紙層と接着樹脂層と剥離層とガスバリアー層と熱可塑性樹脂層とが積層された積層体からなり、前記剥離層にて前記剥離層より外面側部分と内面側部分とが分離可能に構成されてなることを特徴とするものである。   Further, the present invention according to claim 2 includes a bottom portion having a quadrangular shape, and the bottom portion is connected to each of the bottom wall portion and the opposite side wall portions at opposite positions, and the respective sides of the both side wall portions. One extending wall portion and the other extending wall formed of a protruding portion having a substantially triangular shape in plan view and extending between the distal ends of the protruding portion and the protruding wall portion and the bottom wall portion. A joint-pasting wall part that seals the bottom part with the joint part, and both projecting parts of the other joint-wall part projecting in the direction perpendicular to the longitudinal direction of the other joint-wall part. A first projecting portion and a second projecting portion having a projecting length shorter than the first projecting portion at positions opposite to the first projecting portion at both ends of the projecting portion of the one palm wall portion A second projecting piece comprising: the joint-pasting wall portion at the inner edge of the two projecting portions and the bottom wall portion at the other joint. A liquid paper container having the bottom portion formed by folding the wall portions so that they abut, folding the both overhang portions to the bottom wall portion side, and fixing the both overhang portions with the jointed wall portions. The liquid paper container is composed of a laminate in which a thermoplastic resin layer, a paper layer, an adhesive resin layer, a release layer, a gas barrier layer, and a thermoplastic resin layer are laminated in order from the outer surface. The outer surface side portion and the inner surface side portion are configured to be separable from the layer.

また、請求項3記載の本発明は、請求項1、2のいずれかに記載の液体用紙容器において、前記剥離層が、アクリル系樹脂、塩化ビニル−酢酸ビニル共重合体樹脂、ブチラール系樹脂、環化ゴム系樹脂、ウレタン系樹脂、セルロース系樹脂、エチレン−酢酸ビニル共重合体樹脂、エチレン−酢酸ビニル共重合体変性ウレタン系樹脂、ポリアミド系樹脂、シェラックの単体もしくは混合物にて形成される1層もしくは異なる2層からなることを特徴とするものである。   The present invention according to claim 3 is the liquid paper container according to any one of claims 1 and 2, wherein the release layer comprises an acrylic resin, a vinyl chloride-vinyl acetate copolymer resin, a butyral resin, 1 formed from cyclized rubber resin, urethane resin, cellulose resin, ethylene-vinyl acetate copolymer resin, ethylene-vinyl acetate copolymer modified urethane resin, polyamide resin, shellac alone or in mixture It consists of two layers or two different layers.

また、請求項4記載の本発明は、請求項1〜3のいずれかに記載の液体用紙容器において、前記剥離層が、全面コートもしくは任意のパターンで全面積の95〜5%を有する層で形成されていることを特徴とするものである。   Moreover, the present invention according to claim 4 is the liquid paper container according to any one of claims 1 to 3, wherein the release layer is a full surface coat or a layer having 95 to 5% of the total area in an arbitrary pattern. It is characterized by being formed.

また、請求項5記載の本発明は、請求項1、2のいずれかに記載の液体用紙容器において、前記ガスバリアー層が、アルミニウム箔と2軸延伸プラスチックフィルムの積層体、金属ないし金属酸化物を蒸着した2軸延伸プラスチックフィルムであることを特徴とするものである。   According to a fifth aspect of the present invention, in the liquid paper container according to the first or second aspect, the gas barrier layer is a laminate of an aluminum foil and a biaxially stretched plastic film, a metal or a metal oxide. It is the biaxially stretched plastic film which vapor-deposited this.

また、請求項6記載の本発明は、請求項1〜5のいずれかに記載の液体用紙容器において、該液体用紙容器はその天部がゲーベルトップ型であって、天部および底部の外面同士が熱接着される領域に部分的に接着強度調整層が形成されていることを特徴とするものである。   According to a sixth aspect of the present invention, there is provided the liquid paper container according to any one of the first to fifth aspects, wherein the top of the liquid paper container is a govel top type and the outer surfaces of the top and the bottom are adjacent to each other. The adhesive strength adjusting layer is partially formed in the region where the material is thermally bonded.

本発明は、第1突片を突出形成したことにより、手指で前記第1突片を容易に掴むことができ、この第1突片を引き上げることにより張出部を剥離することができるために、液体用紙容器を折り畳んで容易に減容化することができ、廃棄しやすくすることができるという優れた効果を奏するものである。また、突出長さの異なる第1突出部と第2突出部とからなる第2突片を突出形成したことにより、第1突出部と底壁部との間に第2突出部が介在し、第2突出部の存在により前記第1突出部が前記底壁部から一層浮いた状態となるために、第1突出部を一層手指で掴みやすいものとすることができるという優れた効果を奏するものである。   In the present invention, since the first projecting piece is formed to protrude, the first projecting piece can be easily grasped with fingers, and the overhanging portion can be peeled off by pulling up the first projecting piece. The liquid paper container can be easily folded to reduce the volume and can be easily discarded. Further, by forming the second projecting piece composed of the first projecting part and the second projecting part having different projecting lengths, the second projecting part is interposed between the first projecting part and the bottom wall part, Since the first projecting portion is further lifted from the bottom wall portion due to the presence of the second projecting portion, the first projecting portion can be easily grasped with fingers. It is.

また、本発明の液体用紙容器は、外面から順に熱可塑性樹脂層と紙層と接着樹脂層と剥離層とガスバリアー層と熱可塑性樹脂層とが積層された積層体からなり、前記剥離層にて前記剥離層より外面側部分と内面側部分とが分離可能に構成されているので、使用後に液体用紙容器を解体し、紙容器の端部から紙を主体とする部分とプラスチックを主体とする部分に剥離して分離することができるので、使用後の液体用紙容器の資源を再利用しやすくすることができるという優れた効果を奏するものである。   Further, the liquid paper container of the present invention comprises a laminate in which a thermoplastic resin layer, a paper layer, an adhesive resin layer, a release layer, a gas barrier layer, and a thermoplastic resin layer are laminated in order from the outer surface. Since the outer surface side portion and the inner surface side portion are separable from the release layer, the liquid paper container is disassembled after use, and the paper main part and the plastic main part from the end of the paper container. Since it can be separated and separated into parts, the resource of the used liquid paper container can be easily reused.

上記の本発明について、図面等を用いて以下に詳述する。
図1は本発明にかかる液体用紙容器に用いる積層体の一実施例を図解的に示す層構成図、図2は本発明にかかる液体用紙容器に用いる積層体の他の実施例を図解的に示す層構成図、図3は本発明にかかる液体用紙容器の第1実施形態を示す斜視図、図4は図3の液体用紙容器のブランク板を示す平面図、図5は図3の液体用紙容器の底部構造を説明する図、図6は図3の液体用紙容器の底部を図解的に示す平面図、図7は図3の液体用紙容器の解体後の減容化した状態を図解的に示す平面図、図8は本発明にかかる液体用紙容器の第2実施形態を示す図4に対応する図、図9は図8の液体用紙容器の図5に対応する図、図10は熱可塑性樹脂層と紙層と接着樹脂層とからなる外面側部分を液体用紙容器の端部から剥離し始める状態を示す図、図11は熱可塑性樹脂層と紙層と接着樹脂層とからなる外面側部分を液体用紙容器の全長に亘って剥離した状態を示す図であり、図中の1,2,3,4は側壁板、5は糊代片、1a,2a,3a,4aは傾斜屋根形成板、1b,2b,3b,4bは底部形成板、6は一方の合掌壁部、7は他方の合掌壁部、8は第1突片、9は第2突片、9’は第1突出部、9”は第2突出部、10,30は張出部、1s,3sは張出部の先端部、24は底壁部、67は合掌貼り壁部、P1,P2は液体用紙容器、P1’,P2’はブランク板、L,L’は積層体、L1,L6はポリエチレン層、L2は紙層、L3は接着樹脂層、L4,L4a,L4bは剥離層、L5はガスバリアー層、α,βは接着強度調整層をそれぞれ示す。
The above-described present invention will be described in detail below with reference to the drawings.
FIG. 1 is a layer configuration diagram schematically showing one embodiment of a laminate used in a liquid paper container according to the present invention, and FIG. 2 schematically shows another embodiment of a laminate used in a liquid paper container according to the present invention. FIG. 3 is a perspective view showing a first embodiment of a liquid paper container according to the present invention, FIG. 4 is a plan view showing a blank plate of the liquid paper container of FIG. 3, and FIG. 5 is a liquid paper of FIG. FIG. 6 is a plan view schematically illustrating the bottom of the liquid paper container of FIG. 3, and FIG. 7 is a diagram illustrating the volume-reduced state after disassembly of the liquid paper container of FIG. FIG. 8 is a view corresponding to FIG. 4 showing a second embodiment of the liquid paper container according to the present invention, FIG. 9 is a view corresponding to FIG. 5 of the liquid paper container of FIG. 8, and FIG. The figure which shows the state which begins to peel the outer surface side part which consists of a resin layer, a paper layer, and an adhesive resin layer from the edge part of a liquid paper container, 11 is a view showing a state where an outer surface side portion composed of a thermoplastic resin layer, a paper layer, and an adhesive resin layer is peeled over the entire length of the liquid paper container, and 1, 2, 3, and 4 in the figure are side wall plates. 5 is a glue piece, 1a, 2a, 3a and 4a are inclined roof forming plates, 1b, 2b, 3b and 4b are bottom forming plates, 6 is one palm wall portion, 7 is the other palm wall portion, and 8 is 1st protrusion, 9 is 2nd protrusion, 9 'is 1st protrusion part, 9 "is 2nd protrusion part, 10 and 30 are overhang | projection parts, 1s and 3s are the front-end | tip parts of overhang | projection part, 24 is bottom Wall part, 67 is a jointed wall part, P1 and P2 are liquid paper containers, P1 'and P2' are blank plates, L and L 'are laminates, L1 and L6 are polyethylene layers, L2 is a paper layer, and L3 is an adhesive A resin layer, L4, L4a, and L4b are release layers, L5 is a gas barrier layer, and α and β are adhesive strength adjusting layers.

図1は本発明にかかる液体用紙容器に用いる積層体の一実施例を示す層構成図であって、積層体Lは後述する液体用紙容器P1、P2とした際に、外面から順にポリエチレン層L1と紙層L2と接着樹脂層L3と剥離層L4とガスバリアー層L5とポリエチレン層L6(ポリエチレン層L1/紙層L2/接着樹脂層L3/剥離層L4/ガスバリアー層L5/ポリエチレン層L6)とから構成され、印刷絵柄はポリエチレン層L1の外面に設けられる。前記剥離層L4は全面もしくは任意のパターンで全面積の95〜5%を有する層で形成される。   FIG. 1 is a layer configuration diagram showing an embodiment of a laminated body used in a liquid paper container according to the present invention. When the laminated body L is liquid paper containers P1 and P2 to be described later, a polyethylene layer L1 in order from the outer surface. Paper layer L2, adhesive resin layer L3, release layer L4, gas barrier layer L5 and polyethylene layer L6 (polyethylene layer L1 / paper layer L2 / adhesive resin layer L3 / release layer L4 / gas barrier layer L5 / polyethylene layer L6) The printed pattern is provided on the outer surface of the polyethylene layer L1. The release layer L4 is formed of the entire surface or a layer having an arbitrary pattern and having 95 to 5% of the entire area.

図2は本発明にかかる液体用紙容器に用いる積層体の他の実施例を示す層構成図であって、積層体L’は後述する液体用紙容器P1、P2とした際に、外面から順にポリエチレン層L1と紙層L2と接着樹脂層L3と剥離層L4bと剥離層L4aとガスバリアー層L5とポリエチレン層L6(ポリエチレン層L1/紙層L2/接着樹脂層L3/剥離層L4b/剥離層L4a/ガスバリアー層L5/ポリエチレン層L6)とから構成され、印刷絵柄はポリエチレン層L1の外面に設けられる。前記剥離層L4bと前記剥離層L4aは全面もしくは任意のパターンで全面積の95〜5%を有する層で形成される。   FIG. 2 is a layer configuration diagram showing another embodiment of the laminated body used in the liquid paper container according to the present invention. When the laminated body L ′ is used as liquid paper containers P1 and P2 to be described later, polyethylene is sequentially formed from the outer surface. Layer L1, paper layer L2, adhesive resin layer L3, release layer L4b, release layer L4a, gas barrier layer L5, and polyethylene layer L6 (polyethylene layer L1 / paper layer L2 / adhesive resin layer L3 / release layer L4b / release layer L4a / Gas barrier layer L5 / polyethylene layer L6), and the printed pattern is provided on the outer surface of polyethylene layer L1. The release layer L4b and the release layer L4a are formed of the entire surface or a layer having an arbitrary pattern and having 95 to 5% of the entire area.

前記積層体L、L’はいずれも、前記積層体L、L’の端面を「ほぐす」ないし「折り曲げる」等することにより、前記積層体Lの場合は前記接着樹脂層L3と前記剥離層L4との界面で容易に剥離し、ポリエチレン層L1/紙層L2/接着樹脂層L3からなる外面側部分と、剥離層L4/ガスバリアー層L5/ポリエチレン層L6からなる内面側部分とに容易に分離することができる。前記剥離層L4は前記ガスバリアー層L5に付着した状態で剥離される。また、前記積層体L’の場合は前記剥離層L4bと前記剥離層L4aとの界面、ないしは前記接着樹脂層L3と前記剥離層L4bとの界面で容易に剥離し、ポリエチレン層L1/紙層L2/接着樹脂層L3/剥離層L4bからなる外面側部分と、剥離層L4a/ガスバリアー層L5/ポリエチレン層L6からなる内面側部分、ないしはポリエチレン層L1/紙層L2/接着樹脂層L3からなる外面側部分と、剥離層L4b/剥離層L4a/ガスバリアー層L5/ポリエチレン層L6からなる内面側部分とに容易に分離することができる。   In the case of the laminate L, the laminates L and L ′ are both “unraveled” or “folded” at the end faces of the laminates L and L ′, and the adhesive resin layer L3 and the release layer L4. And easily separated into an outer surface side portion composed of polyethylene layer L1 / paper layer L2 / adhesive resin layer L3 and an inner surface side portion composed of release layer L4 / gas barrier layer L5 / polyethylene layer L6. can do. The release layer L4 is peeled off while adhering to the gas barrier layer L5. Further, in the case of the laminate L ′, it is easily peeled off at the interface between the release layer L4b and the release layer L4a, or at the interface between the adhesive resin layer L3 and the release layer L4b, and the polyethylene layer L1 / paper layer L2. / Outer surface side portion composed of adhesive resin layer L3 / peeling layer L4b and inner surface side portion composed of peeling layer L4a / gas barrier layer L5 / polyethylene layer L6, or outer surface composed of polyethylene layer L1 / paper layer L2 / adhesive resin layer L3 It can be easily separated into a side portion and an inner surface side portion composed of release layer L4b / release layer L4a / gas barrier layer L5 / polyethylene layer L6.

そして、前記積層体Lのように前記剥離層L4が1層からなる場合の前記剥離層L4を形成する樹脂としては、ガスバリアー層L5を構成するアルミニウム箔等の金属箔面またはアルミニウム等の金属や酸化珪素、酸化アルミニウム等の金属酸化物を蒸着してなる2軸延伸プラスチックフィルムの蒸着面との接着性がよく、接着樹脂層L3面との接着性が蒸着面との接着性に比べて劣る樹脂が適当であり、たとえば、アクリル系樹脂、ブチラール系樹脂、ウレタン系樹脂、ポリアミド系樹脂、シェラック等を挙げることができる。前記剥離層L4は上記した樹脂の単体ないし混合物からなる樹脂をインキ化し、このインキをガスバリアー層L5を構成する金属箔面または金属酸化物の蒸着面にグラビア印刷等の周知の印刷法で形成される。   And as the resin which forms the said peeling layer L4 in case the said peeling layer L4 consists of one layer like the said laminated body L, metal foil surfaces, such as aluminum foil which comprises the gas barrier layer L5, or metals, such as aluminum Adhesiveness to the vapor-deposited surface of a biaxially stretched plastic film formed by vapor-depositing metal oxides such as silicon oxide, silicon oxide, and aluminum oxide is better than that of the vapor-deposited surface. Inferior resins are suitable, and examples thereof include acrylic resins, butyral resins, urethane resins, polyamide resins, and shellac. The release layer L4 is formed from a resin or a mixture of the above-described resins, and this ink is formed on the metal foil surface or metal oxide deposition surface constituting the gas barrier layer L5 by a known printing method such as gravure printing. Is done.

また、前記積層体L’のように前記剥離層L4bと前記剥離層L4aの2層から剥離層が構成される場合の樹脂としては、前記剥離層L4aにはガスバリアー層L5を構成するアルミニウム箔等の金属箔面またはアルミニウム等の金属や酸化珪素、酸化アルミニウム等の金属酸化物を蒸着した2軸延伸プラスチックフィルムの蒸着面との接着性がよいアクリル系樹脂、ポリアミド系樹脂、シェラックを挙げることができ、前記剥離層L4a面に形成される前記剥離層L4bには、接着樹脂層L3と接着性がよく、かつ、前記剥離層L4aとの界面で剥離できるセルロース系樹脂、アクリル系樹脂、塩化ビニル−酢酸ビニル共重合体樹脂、エチレン−酢酸ビニル共重合体樹脂、エチレン−酢酸ビニル共重合体変性ウレタン系樹脂等を挙げることができる。前記剥離層L4bと前記剥離層L4aはガスバリアー層L5を構成するアルミニウム箔等の金属箔面またはアルミニウム等の金属や酸化珪素、酸化アルミニウム等の金属酸化物を蒸着した2軸延伸プラスチックフィルムの蒸着面にグラビア印刷等の周知の印刷法で形成される。また、前記剥離層L4,L4a,L4bには所望の剥離強度を得るためにマイクロクリスタリンワックス、シリコーン等を添加することができる。   In addition, as the resin in the case where the release layer is configured by two layers of the release layer L4b and the release layer L4a as in the laminate L ′, the release layer L4a includes an aluminum foil that constitutes the gas barrier layer L5. Acrylic resin, polyamide resin, shellac having good adhesion to a metal foil surface such as aluminum or a vapor-deposited surface of a biaxially stretched plastic film deposited with a metal such as aluminum or a metal oxide such as silicon oxide or aluminum oxide The release layer L4b formed on the surface of the release layer L4a has good adhesion to the adhesive resin layer L3 and can be peeled off at the interface with the release layer L4a. List vinyl-vinyl acetate copolymer resins, ethylene-vinyl acetate copolymer resins, ethylene-vinyl acetate copolymer-modified urethane resins, etc. It can be. The release layer L4b and the release layer L4a are vapor-deposited biaxially stretched plastic films on which a metal foil surface such as an aluminum foil constituting the gas barrier layer L5 or a metal oxide such as aluminum or a metal oxide such as silicon oxide or aluminum oxide is deposited. The surface is formed by a known printing method such as gravure printing. In addition, microcrystalline wax, silicone, or the like can be added to the release layers L4, L4a, and L4b in order to obtain a desired peel strength.

前記ポリエチレン層L1としては低密度ポリエチレンを挙げることができ、前記ポリエチレン層L6には低密度ポリエチレン、中密度ポリエチレン、線状低密度ポリエチレン、シングルサイト触媒を用いて重合したエチレン−αオレフィン共重合体等を挙げることができる。前記紙層L2としては250〜450g/m2の坪量の板紙を挙げることができる。前記接着樹脂層L3としては、低密度ポリエチレン、アイオノマー、エチレン−アクリル酸共重合体(EAA)、エチレン−メタクリル酸共重合体(EMAA)、エチレン−アクリル酸メチル共重合体(EMA)、エチレン−アクリル酸エチル共重合体(EEA)、エチレン−メタクリル酸メチル共重合体(EMMA)等を挙げることができる。前記ガスバリアー層L5としては、厚さが6〜9μmのアルミニウム箔と2軸延伸ポリエチレンテレフタレートフィルムまたは2軸延伸ナイロンフィルムとの積層体、アルミニウムあるいは酸化珪素や酸化アルミニウムを蒸着した2軸延伸ポリエチレンテレフタレートフィルムまたは2軸延伸ナイロンフィルムを挙げることができる。 Examples of the polyethylene layer L1 include low density polyethylene, and the polyethylene layer L6 includes low density polyethylene, medium density polyethylene, linear low density polyethylene, and an ethylene-α olefin copolymer polymerized using a single site catalyst. Etc. Examples of the paper layer L2 include paperboard having a basis weight of 250 to 450 g / m 2 . As the adhesive resin layer L3, low density polyethylene, ionomer, ethylene-acrylic acid copolymer (EAA), ethylene-methacrylic acid copolymer (EMAA), ethylene-methyl acrylate copolymer (EMA), ethylene- Examples thereof include ethyl acrylate copolymer (EEA) and ethylene-methyl methacrylate copolymer (EMMA). As the gas barrier layer L5, a laminate of an aluminum foil having a thickness of 6 to 9 μm and a biaxially stretched polyethylene terephthalate film or a biaxially stretched nylon film, biaxially stretched polyethylene terephthalate in which aluminum, silicon oxide, or aluminum oxide is vapor-deposited. A film or a biaxially stretched nylon film can be mentioned.

次に、本発明について、液体用紙容器として天部が傾斜屋根部を有するゲーベルトップ型液体用紙容器を例に挙げて説明する。図3は本発明にかかる液体用紙容器の第1実施形態を示す斜視図、図4は図3の液体用紙容器のブランク板を示す平面図であって、液体用紙容器P1は糊代片5と側壁板1と側壁板2と側壁板3と側壁板4とが折罫を介してそれぞれ連接すると共に、側面板1の上下端には傾斜屋根部形成板1aと底部形成板1bが、側面板2の上下端には傾斜屋根部形成板2aと底部形成板2bが、側面板3の上下端には傾斜屋根部形成板3aと底部形成板3bが、側面板4の上下端には傾斜屋根部形成板4aと底部形成板4bがそれぞれ折罫を介して連接し、傾斜屋根部形成板1a,3aおよび底部形成板1b,3bの所定位置に折罫が形成されると共に、底部形成板1b,3bの所定位置に第1突片8、8が形成されているブランク板P1’を、前記糊代片5を前記側面板4の裏面に接着して筒状体となし、その後に底部が従来からある、いわゆるブリック(Brick)型紙容器と同様にフラットボトムに形成され、次に天部から内容物が充填された後に、天部が傾斜屋根に成形されて所定箇所が熱接着されて密封され、内部に内容物が収容された天部に傾斜屋根部を備えた液体用紙容器である。そして、前記底部形成板1b,2b,3b,4bの表面同士が熱接着される領域(網点で示した領域)および前記傾斜屋根部形成板1a,3aの表面同士が熱接着される領域(網点で示した領域)にはそれぞれ部分的な接着強度調整層αおよび接着強度調整層βが形成されている。また、印刷絵柄層(図示せず)は前記ブランク板P1’の表面の熱接着される領域(符号α、βで示した領域)を除いた領域に形成される。なお、後述する一方の合掌壁部〔(//)印で示した箇所〕を符号6、他方の合掌壁部〔(\)印で示した箇所〕を符号7で図2において示すと共に前記第1突片8、8は一方の合掌壁部6と他方の合掌壁部7の境界の前記他方の合掌壁部7側に形成されている。   Next, the present invention will be described by taking, as an example, a gobel top type liquid paper container having a top portion having an inclined roof as a liquid paper container. FIG. 3 is a perspective view showing the first embodiment of the liquid paper container according to the present invention, FIG. 4 is a plan view showing a blank plate of the liquid paper container of FIG. Side wall plate 1, side wall plate 2, side wall plate 3 and side wall plate 4 are connected to each other via a crease, and inclined roof portion forming plate 1 a and bottom portion forming plate 1 b are provided on the upper and lower ends of side plate 1. 2 is an inclined roof portion forming plate 2a and a bottom portion forming plate 2b, an upper and lower end of the side plate 3 is an inclined roof portion forming plate 3a and a bottom portion forming plate 3b, and an upper and lower end of the side plate 4 is an inclined roof. The portion forming plate 4a and the bottom forming plate 4b are connected to each other through a crease, and a crease is formed at a predetermined position of the inclined roof portion forming plates 1a, 3a and the bottom forming plates 1b, 3b, and the bottom forming plate 1b. , 3b, the blank plate P1 ′ having the first protrusions 8 and 8 formed at the predetermined positions is attached to the paste. The piece 5 is bonded to the back surface of the side plate 4 to form a cylindrical body, and then the bottom is formed into a flat bottom in the same manner as a so-called Brick type paper container, and then the contents from the top Is a liquid paper container in which a top portion is molded into a sloped roof, a predetermined portion is thermally bonded and sealed, and the top portion in which contents are stored is provided with a sloped roof portion. And the area | region (area | region shown with the halftone dot) where the surfaces of the said bottom part formation board 1b, 2b, 3b, 4b are heat-bonded, and the area | region where the surfaces of the said inclined roof part formation board 1a, 3a are heat-bonded ( A partial adhesive strength adjusting layer α and an adhesive strength adjusting layer β are formed in the areas indicated by halftone dots. Further, a printed pattern layer (not shown) is formed in a region excluding the region (region indicated by symbols α and β) to be thermally bonded on the surface of the blank plate P1 ′. Note that one of the palm wall portions (location indicated by (//) mark), which will be described later, is denoted by reference numeral 6, and the other palm wall portion (location marked by (\)) is denoted by reference numeral 7 in FIG. The one projecting piece 8, 8 is formed on the other joint wall 7 side of the boundary between one joint wall 6 and the other joint wall 7.

前記接着強度調整層α,βは、エチレン−酢酸ビニル共重合体、塩素化エチレン−酢酸ビニル共重合体、塩素化ポリエチレン、塩素化ポリプロピレン、環状ゴム、ポリアミド系樹脂、ウレタン系樹脂、アクリル系樹脂、セルロース系樹脂、アルキッド樹脂の単体またはこれらの混合物からなる樹脂インキを用いて印刷することにより形成することができる。前記接着強度調整層α,βを形成する面積としては、前記底部形成板1b,2b,3b,4bおよび前記傾斜屋根部形成板1a,3aの表面同士が熱接着される領域の20%以上の面積とするのが適当である。前記接着強度調整層α,βの形成面積は、網点面積率で20%以上であってもよいし、単純に面積として20%以上であってもよく、この場合は、適宜のパターンで形成すればよいものである。なお、前記接着強度調整層α,βは、必ず設けなければならないものではなく、設けた方が好ましく、また、いずれか一方であってもよいものである。   The adhesive strength adjusting layers α and β are ethylene-vinyl acetate copolymer, chlorinated ethylene-vinyl acetate copolymer, chlorinated polyethylene, chlorinated polypropylene, cyclic rubber, polyamide resin, urethane resin, acrylic resin. It can be formed by printing using a resin ink composed of a simple substance of cellulose-based resin or alkyd resin or a mixture thereof. The area for forming the adhesive strength adjusting layers α, β is 20% or more of the region where the surfaces of the bottom forming plates 1b, 2b, 3b, 4b and the inclined roof forming plates 1a, 3a are thermally bonded to each other. The area is appropriate. The formation area of the adhesive strength adjusting layers α and β may be a dot area ratio of 20% or more, or may simply be 20% or more as an area. In this case, it is formed in an appropriate pattern. What should I do? The adhesive strength adjusting layers α and β are not necessarily provided, but are preferably provided, and either one may be provided.

図5は図3の液体用紙容器の底部構造を説明する図であって、液体用紙容器P1の底部は四角形状からなり、前記底部は底部形成板2b、4bで形成される底壁部24と、対向する位置にある両側壁部1、3のそれぞれに連設されて前記両側壁部1、3のそれぞれの側方に張り出した底部形成板1b、3bで形成される平面視略三角形状の張出部10、30と、該張出部10、30の両先端部1s、3s間に亘って前記両張出部10、30と前記底壁部24とからなる一方の合掌壁部6と他方の合掌壁部7とを合掌貼りして底部を密封する合掌貼り壁部67と、前記他方の合掌壁部7の前記両張出部10、30の両端部に前記他方の合掌壁部の長手方向に直交する方向に突出形成される第1突片8、8とで構成され、前記合掌貼り壁部67をその内端縁で前記両張出部10、30と前記底壁部24に前記他方の合掌壁部7が当接するように折り重ねると共に前記両張出部10、30を前記底壁部24側に折り重ね、前記両張出部10、30を前記合掌貼り壁部67で固着されて図6に示すような底部が形成される。なお、図5においては、前記接着強度調整層αの領域を示す網点は省略した。   FIG. 5 is a diagram for explaining the bottom structure of the liquid paper container shown in FIG. 3. The bottom of the liquid paper container P1 has a quadrangular shape, and the bottom part includes a bottom wall part 24 formed by bottom part forming plates 2b and 4b. In a plan view substantially triangular shape formed by bottom portion forming plates 1b and 3b that are connected to the opposite side wall portions 1 and 3 at opposite positions and project to the sides of the opposite side wall portions 1 and 3, respectively. The overhanging portions 10 and 30 and one joint wall portion 6 composed of the overhanging portions 10 and 30 and the bottom wall portion 24 between both end portions 1 s and 3 s of the overhanging portions 10 and 30. A joint-pasting wall 67 that seals the bottom by sealing the other joint-wall 7 with the other-hand joint wall 7, and the other joint-wall part of the other joint-wall 7 is provided at both ends of the both projecting portions 10, 30 of the other joint-wall 7. It is composed of first projecting pieces 8 and 8 which are formed to project in a direction perpendicular to the longitudinal direction, The two overhanging portions 10, 30 and the bottom wall portion 24 are folded so that the other palm wall portion 7 is in contact with the both overhanging portions 10, 30 and the bottom wall portion 24 side. The both overhanging portions 10 and 30 are fixed by the joint-pasting wall portion 67 to form a bottom portion as shown in FIG. In FIG. 5, halftone dots indicating the region of the adhesive strength adjusting layer α are omitted.

次に、上記のような底部構造を有する液体用紙容器P1の解体方法について説明する。前記第1突片8、8は、他方の合掌壁部7に連設して突出形成されており、一方の合掌壁部6の厚さだけ浮いた状態となるために、手指で前記第1突片8、8を容易に掴むことができ、この第1突片8、8を手指で掴んで引き上げることにより簡単に底壁部24から剥離することができて図5に示す状態とすることができ、図示はしないが続いて傾斜屋根部を剥離して折り畳むことにより図7に示すような状態とすることができ、嵩張る液体用紙容器P1を廃棄時には嵩張らない状態に減容化することができ、廃棄し易いものとすることができる。なお、解体の順序は、傾斜屋根部を先に解体してもよいものである。なお、前記底部形成板1b,2b,3b,4bの表面同士が熱接着される領域(図4の網点αで示した領域)および前記傾斜屋根部形成板1a,3aの表面同士が熱接着される領域(図4の網点βで示した領域)に前記接着強度調整層を形成しておくことにより、一層容易に前記底部と前記傾斜屋根部を図7に示すように解体することができる。   Next, a method for disassembling the liquid paper container P1 having the bottom structure as described above will be described. The first projecting pieces 8 and 8 are formed so as to protrude from the other palm wall portion 7 and float by the thickness of the one palm wall portion 6, so The projecting pieces 8 and 8 can be easily grasped, and the first projecting pieces 8 and 8 can be easily peeled from the bottom wall portion 24 by grasping and lifting the first projecting pieces 8 and 8 with the fingers, so that the state shown in FIG. Although not shown, the sloped roof portion is subsequently peeled off and folded so that the state shown in FIG. 7 can be obtained, and the bulky liquid paper container P1 can be reduced to a non-bulk state when discarded. Can be easily disposed of. Note that the order of dismantling is such that the inclined roof portion may be disassembled first. It should be noted that the areas where the surfaces of the bottom forming plates 1b, 2b, 3b, 4b are thermally bonded together (the areas indicated by the halftone dots α in FIG. 4) and the surfaces of the inclined roof forming plates 1a, 3a are thermally bonded together. By forming the adhesive strength adjusting layer in a region to be formed (region indicated by a halftone dot β in FIG. 4), the bottom portion and the inclined roof portion can be disassembled more easily as shown in FIG. it can.

図8は本発明にかかる液体用紙容器の第2実施形態を示す図4に対応する図、図9は図8の液体用紙容器の図5に対応する図であって、液体用紙容器P2は第1実施形態の液体用紙容器P1に設けた第1突片8、8に代えて、略L字形状の第2突片9、9を突出長さの長い第1突出部9’が他方の合掌壁部7に位置するように、突出長さの短い第2突出部9”が一方の合掌壁部6に位置するように設けたものであって、これ以外は第1実施形態の液体用紙容器P1と同じである。第1実施形態と同様に底部を形成することにより、第2突片9、9の突出長さの長い第1突出部9’が底部において表出し、突出長さの短い第2突出部9”が突出長さの長い第1突出部9’と底壁部24との間に介在することになり、前記第2突片9、9の前記第1突出部9’を一層手指で掴みやすいものとすることができ、第1実施形態の液体用紙容器に比べてより解体しやすい液体用紙容器P2とすることができる。なお、第2突片9、9を第1突出部9’と第2突出部9”とを折罫を介して設けたものを示したが、第1突出部9’と第2突出部9”とは折罫を設けることなく、それぞれ独立してそれぞれの合掌壁部6、7から突出形成した態様としてもよいものであるが、液体用紙容器とする加工工程の容易さを考慮するなら、第2実施形態のように第1突出部9’と第2突出部9”とは折罫を介した構成とするのが望ましいものである。また、第1突片8、8および第2突片9、9の形状は実施例において示した形状に限るものではなく、手指で掴むことが可能な形状であればよいものである。なお、図8の第2実施形態においては、前記接着強度調整層α,βを設けないものを示した。   FIG. 8 is a view corresponding to FIG. 4 showing a second embodiment of the liquid paper container according to the present invention, FIG. 9 is a view corresponding to FIG. 5 of the liquid paper container of FIG. Instead of the first projecting pieces 8 and 8 provided on the liquid paper container P1 of the embodiment, the first projecting part 9 'having a long projecting length is used as the second projecting piece 9 and 9 having a substantially L shape, and the other projecting palm. The second projecting portion 9 ″ having a short projecting length is provided so as to be located on the one palm wall portion 6 so as to be located on the wall portion 7, and other than this, the liquid paper container of the first embodiment The same as P1 By forming the bottom as in the first embodiment, the first protrusion 9 ′ having the long protrusion length of the second protrusions 9 and 9 is exposed at the bottom, and the protrusion length is short. The second protrusion 9 ″ is interposed between the first protrusion 9 ′ having a long protrusion length and the bottom wall 24, and the second protrusions 9 and 9 The protruding portion 9 'can be assumed that more easily grasp with a finger, it can be a liquid packaging cartons P2 more easily disassembled than the liquid paper container of the first embodiment. In addition, although the 2nd protrusions 9 and 9 provided what provided 1st protrusion part 9 'and 2nd protrusion part 9' 'via the crease, 1st protrusion part 9' and 2nd protrusion part 9 were shown. "" Is not necessarily provided with a crease, but may be formed independently from the respective palm wall portions 6 and 7, but in consideration of the ease of the process of making a liquid paper container, As in the second embodiment, it is desirable that the first projecting portion 9 ′ and the second projecting portion 9 ″ are configured via a crease. Further, the first projecting pieces 8, 8 and the second projecting portion are used. The shape of the pieces 9 and 9 is not limited to the shape shown in the embodiment, but may be any shape as long as it can be grasped with fingers, in the second embodiment in FIG. An example in which the adjustment layers α and β are not provided is shown.

また、図7に示す減容化した液体用紙容器の状態で、たとえば、前記底部形成板4bおよび前記側壁板4および前記傾斜屋根部形成板4aが前記糊代片5と接着された側端部、すなわち、液体用紙容器を構成する前記積層体L,L’の端部が露出している部分の角端部を折り曲げる、ないし、ほぐす等により積層体Lの前記剥離層L4にて剥離させることができるので、図10に示すように、前記底部形成板4bおよび前記傾斜屋根部形成板4aの角端部から、ポリエチレン層L1と紙層L2と接着樹脂層L3とからなる外面側部分を剥離させることができ、図11に示すように、前記底部形成板4bおよび前記側壁板4および前記傾斜屋根部形成板4aの側端部の全長に亘って剥離させ、この剥離をさらに継続することにより、紙層主体の外面側部分とガスバリアー層L5とポリエチレン層L6とからなるプラスチック主体の内面側部分とを完全に分離することができ、それぞれ別々に処置できるので廃棄ないしは再利用が容易なものとなる。   Further, in the state of the volume-reduced liquid paper container shown in FIG. 7, for example, the side end portion where the bottom portion forming plate 4b, the side wall plate 4, and the inclined roof portion forming plate 4a are bonded to the glue margin piece 5 That is, the corners of the portions where the end portions of the laminates L and L ′ constituting the liquid paper container are exposed are bent, or peeled off by the release layer L4 of the laminate L by loosening or the like. As shown in FIG. 10, the outer surface side portion composed of the polyethylene layer L1, the paper layer L2, and the adhesive resin layer L3 is peeled off from the corner ends of the bottom portion forming plate 4b and the inclined roof portion forming plate 4a. As shown in FIG. 11, by peeling over the entire length of the side end portions of the bottom portion forming plate 4b, the side wall plate 4 and the inclined roof portion forming plate 4a, the peeling is further continued. , Mainly paper layer Can completely separate the inner surface portion of the plastic main body consisting of a surface-side portion and the gas barrier layer L5 and the polyethylene layer L6 Prefecture, disposal or recycling is made easy because it treated separately.

また、今までの説明においては、天部が傾斜屋根部を有するゲーベルトップ型液体用紙容器として説明してきたが、本発明の液体用紙容器はこれに限ることはなく、背景技術の項で説明した六面体形状からなるブリック(Brick)型紙容器、あるいは、ブリック型紙容器を変形した六角柱状や天面および底面が四角形状で胴部が八角形状の柱状紙容器、また、底面は四角形状で天部が横一線シールを行ったままの楔状紙容器などであってもよいものである。   Further, in the description so far, the top has been described as a gobeltop type liquid paper container having an inclined roof portion, but the liquid paper container of the present invention is not limited to this, and has been described in the background section. A brick-shaped paper container having a hexahedral shape, a hexagonal column shape obtained by deforming a brick-shaped paper container, a columnar paper container having a quadrilateral shape on the top and bottom, and an octagonal body on the top, and a rectangular shape on the bottom and having a top It may be a wedge-shaped paper container or the like that has been subjected to horizontal line sealing.

次に、本発明について、以下に実施例を挙げてさらに詳しく説明する。   Next, the present invention will be described in more detail with reference to the following examples.

7μm厚さのアルミニウム箔と12μm厚さの2軸延伸ポリエチレンテレフタレートフィルムと60μm厚さのポリエチレンフィルムとをウレタン系接着剤を使用して積層し、次いで、前記アルミニウム箔面に下記組成の樹脂インキA、Bを用いて版深が30μmのグラビア版にて、樹脂インキA、樹脂インキBの順でベタ印刷を行い剥離層を形成した中間積層体1を作製した。
〔樹脂インキAの組成(重量部)〕
・シェラック[日本シェラック工業製:ラックグレーズ20E(商品名)] 20
・溶剤[エタノール] 80
〔樹脂インキBの組成(重量部)〕
・ニトロセルロース[ダイセル化学工業製:SS1/4(商品名)] 25
・溶剤[酢酸エチル:トルエン=2:3] 75
A 7 μm thick aluminum foil, a 12 μm thick biaxially stretched polyethylene terephthalate film and a 60 μm thick polyethylene film were laminated using a urethane-based adhesive, and then the resin ink A having the following composition was formed on the aluminum foil surface. , B was used to print an intermediate laminate 1 in which a release layer was formed by solid printing in the order of resin ink A and resin ink B on a gravure plate having a plate depth of 30 μm.
[Composition of resin ink A (parts by weight)]
Shellac [Nippon Shellac Industry: Rack Glaze 20E (trade name)] 20
・ Solvent [Ethanol] 80
[Composition of resin ink B (parts by weight)]
Nitrocellulose [Daicel Chemical Industries: SS1 / 4 (trade name)] 25
Solvent [ethyl acetate: toluene = 2: 3] 75

他方、400g/m2の厚紙(板紙)の一方の面に30μm厚さのポリエチレンを押出コート法により積層すると共に、前記厚紙の他方の面に上記で作製した中間積層体を該中間積層体の前記剥離層面が前記他方の面側に位置するようにしてポリエチレンを25μm厚さで押出ラミネーションして積層することにより、ポリエチレン(30μm)/厚紙(400g/m2)/ポリエチレン25μm/剥離層B(樹脂インキB)/剥離層A(樹脂インキA)/アルミニウム箔(7μm)/ウレタン系接着剤/2軸延伸ポリエチレンテレフタレート(12μm)/ウレタン系接着剤/ポリエチレン60μmからなり積層体を作製した。得られた積層体の剥離層は積層体と一体化してゲーベルトップ型液体用紙容器とした際の接着力を有するものであった。また、積層体の端部を折り曲げると剥離層Aと剥離層Bとの界面で剥離させて積層体を外面側部分と内面側部分とに容易に分離することができた。上記積層体の30μm厚さのポリエチレン面に印刷絵柄層を形成すると共に所定の領域に接着強度調整層を印刷により形成した後、図4に示すブランク板に打抜き、そのブランク板を筒貼りした後、図3、図5、図6に示すように天部(傾斜屋根部)および底部を成形すると共に所定箇所を熱接着してゲーベルトップ型液体用紙容器を作製した。上記で得られたゲーベルトップ型液体用紙容器の天部(傾斜屋根部)および底部における外面同士の熱接着部は容易に剥離することができて、図7に示すように、容易に折り畳んで減容化することができ、折り畳んだ液体用紙容器を図10および図11で説明した要領で剥離することにより、液体用紙容器を構成する積層体をポリエチレン(30μm)/厚紙(400g/m2)/ポリエチレン25μmからなる紙層主体の外面側部分とアルミニウム箔(7μm)/ウレタン系接着剤/2軸延伸ポリエチレンテレフタレート(12μm)/ウレタン系接着剤/ポリエチレン60μmからなるプラスチック主体の内面側部分とに容易に分離することができた。本実施例では剥離層Aはプラスチック主体の内面側部分と一体化しており、剥離層Bは厚紙主体の外面側部分と一体化しており、剥離層Aと剥離層Bの界面で剥離するタイプである。 On the other hand, polyethylene having a thickness of 30 μm is laminated on one surface of 400 g / m 2 cardboard (paperboard) by extrusion coating, and the intermediate laminate produced above is laminated on the other surface of the cardboard. Polyethylene (30 μm) / cardboard (400 g / m 2 ) / polyethylene 25 μm / peeling layer B (polyethylene (30 μm) / polyethylene 25 μm thick) is laminated with the release layer surface positioned on the other surface side. A laminate was made of resin ink B) / release layer A (resin ink A) / aluminum foil (7 μm) / urethane adhesive / biaxially stretched polyethylene terephthalate (12 μm) / urethane adhesive / polyethylene 60 μm. The release layer of the obtained laminate had an adhesive force when it was integrated with the laminate to form a gobble top type liquid paper container. Moreover, when the edge part of the laminated body was bent, it was made to peel in the interface of the peeling layer A and the peeling layer B, and the laminated body was easily isolate | separated into the outer surface side part and the inner surface side part. After forming a printed pattern layer on the 30 μm-thick polyethylene surface of the laminate and forming an adhesive strength adjusting layer in a predetermined region by printing, after punching into the blank plate shown in FIG. 4 and cylinder-pasting the blank plate 3, 5, and 6, the top part (inclined roof part) and the bottom part were molded, and a predetermined portion was thermally bonded to prepare a gobeltop type liquid paper container. The top part (inclined roof part) and the heat bonding part of the outer surfaces of the bottom part of the gobeltop type liquid paper container obtained as described above can be easily peeled off and easily folded and reduced as shown in FIG. The laminated body constituting the liquid paper container is made of polyethylene (30 μm) / cardboard (400 g / m 2 ) / by peeling the folded liquid paper container in the manner described with reference to FIGS. Easy on the outer side of the paper layer mainly composed of 25 μm of polyethylene and the inner side of the plastic mainly composed of aluminum foil (7 μm) / urethane adhesive / biaxially stretched polyethylene terephthalate (12 μm) / urethane adhesive / polyethylene 60 μm Could be separated. In this embodiment, the release layer A is integrated with the inner surface portion mainly composed of plastic, and the release layer B is integrated with the outer surface portion mainly composed of cardboard, and is peeled off at the interface between the release layer A and the release layer B. is there.

樹脂インキBの組成を下記の組成に変更した以外は実施例1と同様にして積層体および液体用紙容器を作製したが、実施例1と同様に本発明の意図する液体用紙容器の減容化および液体用紙容器を外面側部分と内面側部分とに容易に分離することができた。
〔樹脂インキBの組成(重量部)〕
・エチレン−酢酸ビニル共重合体
[三井デユポンポリケミカル製:エバフレックス220(商品名)] 10
・溶剤[トルエン] 90
A laminate and a liquid paper container were produced in the same manner as in Example 1 except that the composition of the resin ink B was changed to the following composition. However, as in Example 1, the volume reduction of the liquid paper container intended by the present invention was made. In addition, the liquid paper container could be easily separated into the outer surface side portion and the inner surface side portion.
[Composition of resin ink B (parts by weight)]
・ Ethylene-vinyl acetate copolymer
[Mitsui Deyupon Polychemicals: Everflex 220 (trade name)] 10
・ Solvent [Toluene] 90

樹脂インキAおよび樹脂インキBの組成を下記の組成に変更した以外は実施例1と同様にして積層体および液体用紙容器を作製したが、実施例1と同様に本発明の意図する液体用紙容器の減容化および液体用紙容器を外面側部分と内面側部分とに容易に分離することができた。
〔樹脂インキAの組成(重量部)〕
・ポリアミド[ヘンケル白水製:バーサミド940(商品名)] 30
・溶剤[イソプロピルアルコール:トルエン=1:1] 70
〔樹脂インキBの組成(重量部)〕
・エチレン−酢酸ビニル共重合体
[三井デユポンポリケミカル製:エバフレックス220(商品名)] 10
・溶剤[トルエン] 90
A laminate and a liquid paper container were prepared in the same manner as in Example 1 except that the composition of the resin ink A and the resin ink B was changed to the following composition. As in Example 1, the liquid paper container intended by the present invention was used. And the liquid paper container could be easily separated into an outer surface portion and an inner surface portion.
[Composition of resin ink A (parts by weight)]
Polyamide [Henkel Hakusui: Versamide 940 (trade name)] 30
Solvent [isopropyl alcohol: toluene = 1: 1] 70
[Composition of resin ink B (parts by weight)]
・ Ethylene-vinyl acetate copolymer
[Mitsui Deyupon Polychemicals: Everflex 220 (trade name)] 10
・ Solvent [Toluene] 90

本発明にかかる液体用紙容器に用いる積層体の一実施例を図解的に示す層構成図である。It is a layer block diagram which shows one Example of the laminated body used for the liquid paper container concerning this invention schematically. 本発明にかかる液体用紙容器に用いる積層体の他の実施例を図解的に示す層構成図である。It is a layer block diagram which shows other examples of the laminated body used for the liquid paper container concerning this invention schematically. 本発明にかかる液体用紙容器の第1実施形態を示す斜視図である。It is a perspective view which shows 1st Embodiment of the liquid paper container concerning this invention. 図3の液体用紙容器のブランク板を示す平面図である。It is a top view which shows the blank board of the liquid paper container of FIG. 図3の液体用紙容器の底部構造を説明する図である。It is a figure explaining the bottom part structure of the liquid paper container of FIG. 図3の液体用紙容器の底部を図解的に示す平面図である。FIG. 4 is a plan view schematically showing the bottom of the liquid paper container of FIG. 3. 図3の液体用紙容器の解体後の減容化した状態を図解的に示す平面図である。FIG. 4 is a plan view schematically showing a volume-reduced state of the liquid paper container of FIG. 3 after disassembly. 本発明にかかる液体用紙容器の第2実施形態を示す図4に対応する図である。It is a figure corresponding to FIG. 4 which shows 2nd Embodiment of the liquid paper container concerning this invention. 図8の液体用紙容器の図5に対応する図である。It is a figure corresponding to FIG. 5 of the liquid paper container of FIG. 熱可塑性樹脂層と紙層と接着樹脂層とからなる外面側部分を液体用紙容器の端部から剥離し始める状態を示す図である。It is a figure which shows the state which begins to peel from the edge part of a liquid paper container the outer surface side part which consists of a thermoplastic resin layer, a paper layer, and an adhesive resin layer. 熱可塑性樹脂層と紙層と接着樹脂層とからなる外面側部分を液体用紙容器の全長に亘って剥離した状態を示す図である。It is a figure which shows the state which peeled the outer surface side part which consists of a thermoplastic resin layer, a paper layer, and an adhesive resin layer over the full length of a liquid paper container.

符号の説明Explanation of symbols

1,2,3,4 側壁板
5 糊代片
1a,2a,3a,4a 傾斜屋根形成板
1b,2b,3b,4b 底部形成板
6 一方の合掌壁部
7 他方の合掌壁部
8 第1突片
9 第2突片
9’ 第1突出部
9” 第2突出部
10,30 張出部
1s,3s 張出部の先端部
24 底壁部
67 合掌貼り壁部
P1,P2 液体用紙容器
P1’,P2’ ブランク板
L,L’ 積層体
L1,L6 ポリエチレン層
L2 紙層
L3 接着樹脂層
L4,L4a,L4b 剥離層
L5 ガスバリアー層
α,β 接着強度調整層
1, 2, 3, 4 Side wall plate 5 Adhesive strip 1a, 2a, 3a, 4a Inclined roof forming plate 1b, 2b, 3b, 4b Bottom forming plate 6 One joint wall portion 7 The other joint wall portion 8 First protrusion Piece 9 Second protruding piece 9 'First protruding portion 9 "Second protruding portion 10, 30 Overhang portion 1s, 3s End portion of overhang portion 24 Bottom wall portion 67 Jointed wall portion P1, P2 Liquid paper container P1' , P2 ′ Blank plate L, L ′ Laminate L1, L6 Polyethylene layer L2 Paper layer L3 Adhesive resin layer L4, L4a, L4b Release layer L5 Gas barrier layer α, β Adhesive strength adjustment layer

Claims (6)

四角形状からなる底部を備え、前記底部は底壁部と、対向する位置にある両側壁部のそれぞれに連設されて前記両側壁部のそれぞれの側方に張り出した平面視略三角形状の張出部と、該張出部の両先端部間に亘って前記両張出部と前記底壁部とからなる一方の合掌壁部と他方の合掌壁部とを合掌貼りして底部を密封する合掌貼り壁部と、前記他方の合掌壁部の前記両張出部の両端部に前記他方の合掌壁部の長手方向に直交する方向に突出形成される第1突片とで構成され、前記合掌貼り壁部をその内端縁で前記両張出部と前記底壁部に前記他方の合掌壁部が当接するように折り重ねると共に前記両張出部を前記底壁部側に折り重ね、前記両張出部を前記合掌貼り壁部で固着してなる前記底部を有する液体用紙容器であって、該液体用紙容器は外面から順に熱可塑性樹脂層と紙層と接着樹脂層と剥離層とガスバリアー層と熱可塑性樹脂層とが積層された積層体からなり、前記剥離層にて前記剥離層より外面側部分と内面側部分とが分離可能に構成されてなることを特徴とする液体用紙容器。 A bottom portion having a quadrangular shape, the bottom portion being connected to each of the bottom wall portion and the opposite side wall portions at opposite positions, and projecting to the sides of the opposite side wall portions in a substantially triangular shape in plan view. The bottom part is sealed by gluing and sticking one joint wall part composed of the projecting part and the two projecting parts and the bottom wall part between the two projecting parts and the bottom wall part. It is composed of a joint-pasting wall portion, and a first projecting piece that is formed to project in a direction perpendicular to the longitudinal direction of the other joint-wall portion at the both ends of the both overhang portions of the other joint-wall portion, Folding the joint-pasting wall part at the inner edge thereof so that the other joint-wall part comes into contact with the two projecting parts and the bottom wall part, and folding the both projecting parts on the bottom wall part side, A liquid paper container having the bottom portion formed by fixing the both overhang portions with the joint-pasting wall portion, It consists of a laminate in which a thermoplastic resin layer, a paper layer, an adhesive resin layer, a release layer, a gas barrier layer, and a thermoplastic resin layer are laminated in order from the surface, and an outer surface side portion and an inner surface from the release layer in the release layer A liquid paper container characterized in that the side portion is separable. 四角形状からなる底部を備え、前記底部は底壁部と、対向する位置にある両側壁部のそれぞれに連設されて前記両側壁部のそれぞれの側方に張り出した平面視略三角形状の張出部と、該張出部の両先端部間に亘って前記両張出部と前記底壁部とからなる一方の合掌壁部と他方の合掌壁部とを合掌貼りして底部を密封する合掌貼り壁部と、前記他方の合掌壁部の前記両張出部に両端部に前記他方の合掌壁部の長手方向に直交する方向に突出形成される第1突出部と前記一方の合掌壁部の前記張出部の両端部であって、前記第1突出部と対向する位置に前記第1突出部よりも突出長さが短い第2突出部とからなる第2突片とで構成され、前記合掌貼り壁部をその内端縁で前記両張出部と前記底壁部に前記他方の合掌壁部が当接するように折り重ねると共に前記両張出部を前記底壁部側に折り重ね、前記両張出部を前記合掌貼り壁部で固着してなる前記底部を有する液体用紙容器であって、該液体用紙容器は外面から順に熱可塑性樹脂層と紙層と接着樹脂層と剥離層とガスバリアー層と熱可塑性樹脂層とが積層された積層体からなり、前記剥離層にて前記剥離層より外面側部分と内面側部分とが分離可能に構成されてなることを特徴とする液体用紙容器。 A bottom portion having a quadrangular shape, the bottom portion being connected to each of the bottom wall portion and the opposite side wall portions at opposite positions, and projecting to the sides of the opposite side wall portions in a substantially triangular shape in plan view. The bottom part is sealed by gluing and sticking one joint wall part composed of the projecting part and the two projecting parts and the bottom wall part between the two projecting parts and the bottom wall part. A first projecting portion formed on both ends of the joint-pasting wall portion and the two projecting portions of the other joint-wall wall portion and projecting in a direction perpendicular to the longitudinal direction of the other joint-wall portion and the one joint-wall And a second projecting piece formed of a second projecting portion that is at both ends of the projecting portion of the portion and that is opposed to the first projecting portion and has a projecting length shorter than the first projecting portion. Folding the jointed wall part so that the other jointed wall part comes into contact with the two overhanging parts and the bottom wall part at the inner edge thereof And a liquid paper container having the bottom portion formed by folding the both overhang portions on the bottom wall portion side, and fixing the both overhang portions with the joint-pasting wall portion. It consists of a laminate in which a thermoplastic resin layer, a paper layer, an adhesive resin layer, a release layer, a gas barrier layer, and a thermoplastic resin layer are laminated in order, and an outer surface side portion and an inner surface side portion from the release layer in the release layer And a liquid paper container characterized by being configured to be separable. 前記剥離層が、アクリル系樹脂、塩化ビニル−酢酸ビニル共重合体樹脂、ブチラール系樹脂、環化ゴム系樹脂、ウレタン系樹脂、セルロース系樹脂、エチレン−酢酸ビニル共重合体樹脂、エチレン−酢酸ビニル共重合体変性ウレタン系樹脂、ポリアミド系樹脂、シェラックの単体もしくは混合物にて形成される1層もしくは異なる2層からなることを特徴とする請求項1、2のいずれかに記載の液体用紙容器。 The release layer is an acrylic resin, vinyl chloride-vinyl acetate copolymer resin, butyral resin, cyclized rubber resin, urethane resin, cellulose resin, ethylene-vinyl acetate copolymer resin, ethylene-vinyl acetate. The liquid paper container according to any one of claims 1 and 2, wherein the liquid paper container is composed of one layer or two different layers formed of a copolymer-modified urethane resin, a polyamide resin, or shellac alone or in a mixture. 前記剥離層が、全面コートもしくは任意のパターンで全面積の95〜5%を有する層で形成されていることを特徴とする請求項1〜3のいずれかに記載の液体用紙容器。 The liquid paper container according to any one of claims 1 to 3, wherein the release layer is formed of a whole surface coat or a layer having 95 to 5% of the total area in an arbitrary pattern. 前記ガスバリアー層が、アルミニウム箔と2軸延伸プラスチックフィルムの積層体、金属ないし金属酸化物を蒸着した2軸延伸プラスチックフィルムであることを特徴とする請求項1、2のいずれかに記載の液体用紙容器。 The liquid according to claim 1, wherein the gas barrier layer is a laminate of an aluminum foil and a biaxially stretched plastic film, or a biaxially stretched plastic film on which a metal or a metal oxide is deposited. Paper container. 請求項1〜5のいずれかに記載の液体用紙容器において、該液体用紙容器はその天部がゲーベルトップ型であって、天部および底部の外面同士が熱接着される領域に部分的に接着強度調整層が形成されていることを特徴とする液体用紙容器。 The liquid paper container according to any one of claims 1 to 5, wherein the top of the liquid paper container is a govel top type and is partially bonded to a region where the outer surfaces of the top and bottom are thermally bonded to each other. A liquid paper container in which a strength adjusting layer is formed.
JP2007255615A 2007-09-28 2007-09-28 Paper vessel for liquid Withdrawn JP2009083900A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012166796A (en) * 2011-02-10 2012-09-06 Dainippon Printing Co Ltd Paper container for liquid
WO2012124764A1 (en) 2011-03-17 2012-09-20 国立大学法人三重大学 Antibody production method
CN108688230A (en) * 2018-03-28 2018-10-23 江苏南江智能装备股份有限公司 A kind of portable molding machine of gas paper folding matter and portable forming method
KR102033888B1 (en) * 2019-07-16 2019-10-17 주식회사 케이팩 Functional grain packaging box

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012166796A (en) * 2011-02-10 2012-09-06 Dainippon Printing Co Ltd Paper container for liquid
WO2012124764A1 (en) 2011-03-17 2012-09-20 国立大学法人三重大学 Antibody production method
CN108688230A (en) * 2018-03-28 2018-10-23 江苏南江智能装备股份有限公司 A kind of portable molding machine of gas paper folding matter and portable forming method
KR102033888B1 (en) * 2019-07-16 2019-10-17 주식회사 케이팩 Functional grain packaging box

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