JP2009046660A - Water-based glorious ink composition - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a water-based glorious ink composition in which a pearl pigment consisting of metal oxide-covered particles is contained as a glorious pigment and the aging stability of which is made excellent by preventing agglomeration of metal oxide-covered particles though a water-soluble resin emulsion is incorporated to improve ink fixability. <P>SOLUTION: The water-based glorious ink composition comprises: the glorious pigment containing the pearl pigment essentially; the water-soluble resin emulsion; and a cellulose derivative. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

  The present invention relates to a water-based ink composition that exhibits glitter by a so-called pearl pigment, and particularly to a water-based glitter ink composition that is useful in writing instrument inks, printing inks, and paint-related fields.

Conventionally, an aqueous ink composition using an aluminum pigment composed of aluminum particles has been provided in order to obtain a metallic glossy handwriting such as gold or silver. However, since aluminum is a metal, if it is used as it is as a component of a water-based ink composition, it reacts with water to generate hydrogen gas. Therefore, when the water-based ink composition is used for a writing instrument, it is stable over time. There was a problem of becoming poor. Accordingly, an aluminum pigment has been developed in which the surface of the aluminum particles is subjected to water resistance treatment with phosphoric ester, stearic acid, oleic acid or the like. Such a water-resistant aluminum pigment is often used after being made into a paste and dispersed in a water-based ink composition (for example, Patent Document 1).
Japanese Unexamined Patent Publication No. 63-72771

  However, the aluminum pigment, despite the water-resistant treatment, is still difficult to say from the viewpoint of complete suppression of hydrogen gas generation in the water-based ink composition, for example, in the dispersion step, The overlapping aluminum particles are peeled off or the aluminum particles themselves are crushed, so that the aluminum surface not subjected to the water-resistant treatment and water are in contact with each other and hydrogen gas is generated.

Therefore, as a pigment for metallic luster that does not generate hydrogen gas by reacting with water, flaky mineral inorganic particles such as mica (mica), flaky metal, etc. as a core material, A pearl pigment composed of particles obtained by thinly coating the surface of the core material with a metal oxide such as titanium dioxide or iron oxide has been developed. However, since a water-based ink composition using a pearl pigment has a weak ink fixing property on paper as compared with an aluminum pigment, it is necessary to add a fixing agent such as an aqueous resin emulsion (for example, Patent Document 2).
Japanese Patent Laid-Open No. 5-117569

  However, unlike the surface of the aluminum particles of the aluminum pigment that is hydrophobic, the pearl pigment has a hydrophilic surface of the constituent particles of the pearl pigment. For this reason, at the time of production of the aqueous resin emulsion, an excess emulsifier that did not contribute to making the resin into an emulsion state, or once constituted a micellar emulsion, but the emulsifier that was subsequently released from the emulsion core, In some cases, the hydrophilic group is on the inside and the hydrophobic group is on the outside, and adsorbed on the particles constituting the pearl pigment. Then, the pearl pigment to which the emulsifier is adsorbed is in the water-based ink, and the hydrophobic ones gather together, resulting in aggregation and sedimentation of the pearl pigment, so that the writing instrument using the water-based ink composition is stable over time. Sexually worsens.

  In view of the above-mentioned present situation, in the present invention, the aqueous glittering ink composition containing a pearl pigment has an aqueous glittering ink composition excellent in stability over time despite containing an aqueous resin emulsion for ink fixability. The issue is to provide goods.

  In order to solve the above-mentioned problems, the water-based glittering ink composition of the present invention is characterized by including a glittering pigment essentially containing a pearl pigment, an aqueous resin emulsion, and a cellulose derivative.

  In the present invention, since the cellulose derivative not only improves the instability of the aqueous resin emulsion itself, but also binds to the hydrophilic group present on the surface of the metal oxide-coated particles, metal oxidation via an emulsifier released from the aqueous resin emulsion is performed. As a result, it is possible to prevent agglomeration of product-coated particles, so that even a writing instrument made of an aqueous glittering ink composition using a pearl pigment that functions as a glittering pigment is excellent in ink fixability on paper and stable over time. Excellent.

  In addition, in the ink composition, the aqueous composition of the present invention is usually used as a water-soluble organic solvent that is blended in order to exert a wet effect and prevent drying at the pen nib (improve cap-off properties). In the glitter ink composition, the SP value of the ink composition as a whole can be reduced by selecting glycols having a solubility parameter value (SP value) of 32 MPa1 / 2 or less. As a result, since the emulsifier is less likely to be released from the aqueous resin emulsion, it is possible to more effectively prevent aggregation of the metal oxide-coated particles in synergy with the function of the cellulose derivative.

(Bright pigment)
The glitter pigment used in the present invention contains a pearl pigment as an essential component. As described above, what is generally known as a pearl pigment is composed of an aggregate of metal oxide-coated particles obtained by coating the surface of a flaky core material with a metal oxide. Generally used core materials are mica (mica), metal pieces, and the like, but glass flakes, for example, can also be used.

  Although it does not restrict | limit especially as a metal oxide which coat | covers the said core material particle, Iron oxide, titanium dioxide, etc. can be illustrated as a metal oxide generally used. The core material can also be surface-coated with two or more kinds of metal oxides. Although it does not specifically limit as an average particle diameter of the luster pigment which can be used, Preferably it is about 3-150 micrometers.

Specific examples of the series of pearl pigments available as pearl pigments include Merck's Iriodin, Xirallic, Color Stream, Bi-flair, BASF's Paliocrom, Variocrom, Wacker's Helicone, and the like. Any of them may be a so-called weather resistant grade subjected to surface treatment. In particular, in the present invention, trade names “Iriodin 323”, “Iriodin 302”, “Iriodin 500”, “Iriodin 120”, and “Iriodin 123” from Merck can be preferably used.

  Moreover, on the condition that the said pearl pigment is contained essential, other glitter pigments, such as an aluminum pigment, can also be mix | blended with a glitter pigment. Since the pearl pigment has high transparency, the writing instrument using the water-based glittering ink composition in which only the pearl pigment is a glittering pigment has a problem that the coloring property is inferior in writing on black paper. On the other hand, a writing instrument using an aqueous glittering ink composition in which an aluminum pigment is added to a glittering pigment in addition to the pearl pigment is excellent in color developability in writing on black paper. However, since the addition of the aluminum pigment tends to cause a problem of hydrogen generation in the aqueous glittering ink composition as described above, it is preferable to suppress the addition amount as much as possible. Specifically, when an aluminum pigment is contained in the water-based glittering ink composition of the present invention, it is preferably 20% by weight or less based on the weight of the pearl pigment. In addition, in order to further mix | blend an aluminum pigment in the glittering ink composition of this invention, the aluminum paste by which hydrophobic treatment was carried out previously can also be used similarly to the technique known conventionally.

  The preferable content of the luster pigment including the pearl pigment and the aluminum pigment is 1.0 to 30.0% by weight based on the total amount of the ink composition, and more preferably based on the total amount of the ink composition. 1.0 to 20.0% by weight. If the glitter pigment is less than 1.0% by weight, sufficient glitter cannot be exhibited.

(Aqueous resin emulsion)
The aqueous resin emulsion used in the present invention improves the fixability of the pearl pigment in the aqueous glittering ink composition. In the water-based ink composition, as a component for improving the fixability of the pigment, there are other water-soluble synthetic resins. However, when the water-based resin emulsion is used, a thickener and a colorant are blended. , The properties such as thickener solubility, colorant dispersibility and ink viscoelasticity are hardly adversely affected. Therefore, a water-based ink composition using an aqueous resin emulsion for improving the fixing property can improve the fixing property of the glitter pigment without affecting the viscosity of the ink, the writing ability, and the color of the handwriting.

  As the aqueous resin emulsion, for example, an acrylic aqueous resin emulsion, a styrene-acrylic aqueous resin emulsion, or a vinyl acetate aqueous resin emulsion can be used. As the acrylic aqueous resin emulsion, an acrylic acid alkyl ester copolymer aqueous resin emulsion is suitable. As the styrene-acrylic aqueous resin emulsion, a styrene-acrylic ester copolymer aqueous resin emulsion is suitable. For the vinyl acetate aqueous resin emulsion, a vinyl acetate resin aqueous resin emulsion and a vinyl acetate-acrylate copolymer aqueous resin emulsion are preferably used. The synthetic resin emulsion can be used by mixing one or more of these synthetic resins.

  Specifically, as an acrylic synthetic resin emulsion, for example, a trade name “Nicazole FX336” (manufactured by Nippon Carbide Industries, Ltd., minimum film-forming temperature <0 ° C., pH 7.5, 200 mPa · s), a trade name “Nicazole” A-02HN "(manufactured by Nippon Carbide Industries Co., Ltd., minimum film-forming temperature <0 ° C, pH 7.0, 500 mPa · s), trade name" Nicazole FH-011A "(manufactured by Nippon Carbide Industries Co., Ltd., minimum film-forming temperature < As a vinyl acetate synthetic resin emulsion, for example, the product name “Movinyl 231” (manufactured by Clariant Polymer Co., Ltd., minimum film-forming temperature <0 ° C., pH 4.0, And a viscosity of 500 to 1500 mPa · s). In addition, this viscosity measurement is a numerical value measured with a B-type viscometer at 25 ° C.

  Among them, the acrylic acid alkyl ester copolymer aqueous resin emulsion, trade name “Nicazole A-02HN” (manufactured by Nippon Carbide Industries Co., Ltd.) can be used without interfering with the glittering feeling of the glittering pigment. It is suitable as an aqueous resin emulsion to be blended in the composition ink.

  The preferred content of the aqueous resin emulsion is 0.1 to 30% by weight in solid content with respect to the total amount of the ink composition, and 5 to 500% by weight in solid content with respect to the pearl pigment, more preferably The solid content is 1.0 to 20% by weight based on the total amount of the ink composition, and the solid content is 20 to 200% by weight based on the pearl pigment. When the content of the synthetic resin emulsion is less than 0.1 wt% in terms of solid content with respect to the total amount of the ink composition, the fixability of the pearl pigment to the substrate is lowered. On the other hand, in order to ensure the fixability to the substrate, it is not necessary to blend more than 30% by weight in solid content with respect to the total amount of the ink composition or more than 500% by weight in solid content with respect to the pearl pigment. In addition, it becomes easier to form a film with the pen tip, and the writing ability is lowered.

(Cellulose derivative)
In the aqueous glittering ink composition, the cellulose derivative used in the present invention protects the surface of the metal oxide-coated particles that are hydrophilic, and the metal oxide-coated particles pass through the emulsifier released from the aqueous resin emulsion. This is to suppress aggregation. That is, in an aqueous glittering ink composition containing a pearl pigment blended with a cellulose derivative, the metal oxide-coated particles constituting the pearl pigment are presumed to exist in a state where the cellulose derivative is adsorbed on the surface thereof. .

  Specific examples of the cellulose derivative include methyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, hydroxypropyl ethyl cellulose, carboxymethyl cellulose or a salt thereof (such as sodium salt and ammonium salt). Preferred cellulose derivatives include carboxymethyl cellulose or a salt thereof, hydroxyethyl cellulose, more preferably carboxymethyl cellulose or a salt thereof (such as sodium salt or ammonium salt).

  Among them, a preferable cellulose derivative is a water-soluble cellulose derivative, and examples of a particularly preferable water-soluble cellulose derivative include anionic cellulose sodium carboxymethyl cellulose (CMC). Examples of available series include serogens from Daiichi Kogyo Seiyaku Co., Ltd. Among them, trade names “Serogen 5A” and “Serogen PR” (Daiichi Kogyo Seiyaku Co., Ltd.) can be preferably used.

  The number average molecular weight of the cellulose derivative is not particularly limited, but can be selected from the range of, for example, 8,000 to 400,000, preferably 10,000 to 100,000. Examples of the salt include sodium salt, ammonium salt, potassium salt and the like, but sodium salt is common. Moreover, a cellulose derivative can be used individually or in combination of 2 or more types.

  The preferred content of the cellulose derivative is 0.001 to 10.0% by weight with respect to the total amount of the ink composition, and 0.5 to 3.0% by weight with respect to the pearl pigment. If the amount is less than 0.001% by weight based on the total amount of the ink composition or less than 0.5% by weight based on the pearl pigment, it is difficult to obtain the above-mentioned stability effect over time. On the other hand, if the amount exceeds 10.0% by weight based on the total amount of the ink composition, or if the amount exceeds 3.0% by weight based on the pearl pigment, the pearl pigment has sufficient effect as a pearl pigment. It becomes difficult to demonstrate.

(Water-soluble organic solvent)
A water-soluble organic solvent can be further added to the water-based glittering ink composition of the present invention in order to impart a wetting effect and prevent drying at the nib (improvement of cap-off properties). Specific water-soluble organic solvents used in the aqueous glittering ink composition of the present invention include, for example, ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, polyethylene glycol and the like. Glycols, polyhydric alcohols such as glycerin, glycol ethers such as ethylene glycol monomethyl ether, diethylene glycol monomethyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monopropyl ether it can. These organic solvents can be used alone or in combination of two or more.

Of these, glycols having a solubility parameter value (SP value) of 32 MPa1 / 2 or less are preferably used. Among water-soluble organic solvents, the release of an emulsifier from the emulsion core of the aqueous resin emulsion can be suppressed by blending glycols having an SP value of 32 MPa1 / 2 or less.

  The solubility parameter (SP value) is an index indicating the polarity of the substance, and is an index of the affinity between the solvent and the resin. In general, it is known that the closer the SP value of both, the better the solubility of the resin in the solvent, and the smaller the SP value, the greater the lipophilicity. That is, by lowering the SP value of the entire system, the emulsifier contained in the aqueous resin emulsion is less likely to be released from the emulsion core even when highly hydrophilic metal oxide-coated particles are present in the vicinity thereof.

  Table 1 shows the SP values of various glycols. From this table, it can be seen that in the present invention, glycerin and ethylene glycol do not satisfy the above conditions, while propylene glycol, diethylene glycol, triethylene glycol, and polyethylene glycol are compounds that satisfy the above conditions. The water-soluble organic solvent satisfying these conditions can be used alone or in combination of two or more.

  The water-soluble organic solvent is preferably contained in an amount of 40% by weight or less based on the total amount of the ink composition. In the water-based glittering ink composition of the present invention, a water-soluble organic solvent is not an essential component, and therefore there is no preferred lower limit. When the water-soluble organic solvent exceeds 40% by weight based on the total amount of the ink composition, the handwriting is difficult to dry, and characters written on paper and the like are likely to show through due to the penetration of the ink composition.

(Thickener)
When the aqueous glittering ink composition of the present invention is used particularly as an ink for gel ink ballpoint pens, a thickener can be further added. As the thickener, it is preferable to use a compound that gives the ink pseudoplastic flow characteristics (thixotropic properties). Specifically, microbial polysaccharides such as ramsan gum and derivatives thereof, water-soluble plant polysaccharides and derivatives thereof such as traganci gum, water-soluble animal polysaccharides such as gelatin, and thickening resins such as N-vinylacetamide resin Can be mentioned.

  Among these, when the water-based glittering ink composition of the present invention is used as an ink for gel ink, microbial polysaccharides and derivatives thereof, specifically, ramzan gum, welan gum, xanthan gum (kelzane), leozan and the like are preferable. Used. Moreover, the said thickener can be used 1 type or in mixture of 2 or more types.

  These thickeners are preferably contained in an amount of 0.1 to 0.5% by weight based on the total amount of the ink composition. When the thickener exceeds 0.5% by weight in the total amount of the ink composition, the viscosity of the ink is excessively increased and the outflow property is lowered. As a thickener, the optimum blending amount when using microbial polysaccharides such as rhamsan gum, welan gum, xanthan gum (Kelzan), leozan, and dieutan gum and their derivatives is 0.2 to 0.4% by weight. .

(Surfactant)
In the aqueous glittering ink composition of the present invention, the cellulose derivative is combined with the hydrophilic group present on the surface of the metal oxide-coated particles to protect the aqueous resin emulsion from binding with an emulsifier from the aqueous resin emulsion. It is characterized by preventing aggregation of the metal oxide-coated particles through the metal particles.

  However, in addition to the emulsifier that adsorbs to the aqueous resin emulsion, when a surfactant is further added, the added surfactant also causes the aggregating effect, so that the protection by the cellulose derivative exhibited in the present invention cannot catch up. End up. Therefore, it is preferable that an additional surfactant is not added as much as possible in the water-based glittering ink composition of the present invention.

  However, when the glitter pigment used in the present invention is composed of a mixture of a pearl pigment and an aluminum pigment, it is necessary to add a surfactant to disperse the aluminum pigment. However, the amount of surfactant added in this case should also be minimized as much as possible. In the water-based glitter ink composition of the present invention, when the glitter pigment is a mixture of a pearl pigment and an aluminum pigment, the allowable amount of surfactant added is 1.0% by weight or less in the total amount of the ink composition. is there.

(Coloring agent)
The glitter pigment does not give a clear color to the ink, but does not react with the glitter pigment, and does not react with the glitter pigment. A colorant can be further added as long as it does not affect the glittering effect. Specific colorants include water-soluble dyes such as acid dyes, direct dyes, basic dyes, inorganic pigments such as carbon black, copper phthalocyanine pigments, selenium pigments, azo pigments, quinacridone pigments, anthra In addition to organic pigments such as quinone pigments, dioxane pigments, indigo pigments, thioindigo pigments, perinone pigments, perylene pigments, indolenone pigments, azomethine pigments, fluorescent pigments, colored resin emulsions, and the like. Moreover, these can also be used as a pigment dispersion. In the present invention, the pigments can be used alone or in combination of two or more.

  In addition, it is used by mixing with concealing pigments such as various inorganic or organic white pigments such as concealing titanium oxide, alkylene bismelamine derivatives, plastic pigments (synthetic resin particle pigments) of various shapes such as spherical and flat shapes. You can also However, when dispersing in the ink composition, the addition of a compound that requires the use of a surfactant needs to be suppressed as much as the case of adding an aluminum pigment.

  If a colorant other than the glitter pigment is added too much, the glitter feeling of the glitter pigment will be reduced, so that it is 30% by weight or less based on the entire glitter pigment including the pearl pigment and the aluminum pigment. It is preferable to use in a range.

(Other additives)
In the present invention, rust preventives such as benzotriazole and tolyltriazole dicyclohexylammonium nitrate, benzoisothiazoline-based, pentachlorophenol-based, cresol and other antiseptic / antifungal agents can be added as necessary. .

  In the ink composition, specifically, trade names “Proxel XL-2”, “Coatside H” and the like are generally used as a rust inhibitor and antiseptic / antifungal agent.

(Ink preparation method)
The ink can be prepared by a conventionally known dispersion method, defoaming method, filtration, or the like, and the following method is preferred as the charging method. That is, water, a bright pigment, a water-soluble organic solvent (optional component), and a colorant (optional component) are stirred and dispersed at room temperature with a dissolver, and then a thickener (optional component) is added and further stirred. . Thereafter, a cellulose derivative, an aqueous resin emulsion, and an antifungal agent (optional component) are added while stirring, and the pH is adjusted as necessary. An ink composition is obtained.

EXAMPLES Hereinafter, although this invention is demonstrated in detail based on an Example and a comparative example, this invention is not limited to these Examples.
In the composition and blending amount (% by weight) shown in Table 2, water, a bright pigment, and a water-soluble organic solvent were stirred and dispersed at room temperature with a dissolver or the like by the above production method, and then a thickener was added. Stir. Thereafter, a cellulose derivative, an aqueous resin emulsion, and an antifungal agent were added with stirring, and this was filtered by pressure filtration or the like and then defoamed to obtain a glittering aqueous ink composition of Example (Example 1). ~ 7). For comparison, glittering water-based ink compositions not containing a cellulose derivative were also obtained with the compositions and amounts (% by weight) shown in Table 3 (Comparative Examples 1 to 3).

In Tables 2 and 3, the specific composition and trade name of each raw material are as follows.
Pearl pigment (1) Pearl pigment "Iriodin 323" (Merck)
Pearl pigment (2) Pearl pigment "Iriodin 302" (Merck)
Pearl pigment (3) Pearl pigment "Iriodin 500" (Merck)
Pearl pigment (4) Pearl pigment "Iriodin 120" (Merck)
Pearl pigment (5) Pearl pigment "Iriodin 123" (Merck)
Aluminum pigment (1) “Alpaste WXM0620” (manufactured by Toyo Aluminum Co., Ltd.)
Water-soluble organic solvent PEG # 200 Polyethylene glycol, average molecular weight 200
Water-soluble organic solvent PEG # 300 Polyethylene glycol, average molecular weight 300
Colorant GBN color red (pigment 10%) (manufactured by Dainichi Seika Co., Ltd.)
Cellulose derivative (1) CMC “Serogen 5A” (Daiichi Kogyo Seiyaku Co., Ltd.)
Cellulose derivative (2) CMC “Serogen PR” (Daiichi Kogyo Seiyaku Co., Ltd.)
Aqueous resin emulsion (1) Acrylic acid alkyl ester copolymer aqueous resin emulsion “Nicazole A-02HN” (Nippon Carbide Industries, Ltd.)
Antiseptic and antifungal agent (1) "Proxel XL-2" (manufactured by Arch Chemicals)
Antiseptic and antifungal agent (2) “Coatside H” (manufactured by Takeda Pharmaceutical Co., Ltd.)

The pearl pigment “Iriodin” series is an aggregate of particles in which transparent and flaky mica is used as a core and the surface thereof is coated with titanium dioxide and / or iron oxide.
The “Serogen” series is carboxymethylcellulose sodium having a different degree of polymerization and substitution degree of carboxymethyl group.
“Nicazole A-02HN” is an aqueous emulsion of an acrylic alkyl ester / alkylol acrylamide / itaconic acid copolymer.

(Evaluation)
Prepare each of the obtained glittering water-based ink compositions of Examples 1 to 7 and Comparative Examples 1 to 3 in a plastic bottle and one filled in an ink storage part of a pen, and store at 50 ° C. for 1 month. did. The appearance of each of the filled glittering water-based ink compositions after storage was visually observed and evaluated for ◯ ×.
○: No change ×: Ink appears to discolor due to aggregation These evaluations are also shown in Tables 2 and 3 above.

  Since the water-based glittering ink composition of the present invention is an aqueous glittering ink composition that can exhibit the characteristics peculiar to pearl pigments and is excellent in stability over time, it is industrially used in writing instrument inks, printing inks, and paint-related fields. Although it can be used, it has a high industrial utility value as an ink for water-based writing instruments.

Claims (8)

An aqueous glittering ink composition comprising a glittering pigment, an aqueous resin emulsion and a cellulose derivative,
As the glitter pigment, including a pearl pigment composed of metal oxide-coated particles,
Water-based glitter ink composition.   The water-based glittering ink composition according to claim 1, wherein the cellulose derivative is sodium carboxymethyl cellulose.   The water-based glittering ink composition according to claim 1 or 2, wherein the surfactant is incorporated in the water-based glittering ink composition in an amount of 1% by weight or less based on the total amount of the ink composition. The water-based glittering ink composition further contains a water-soluble organic solvent,
The water-based glittering ink composition according to any one of claims 1 to 3, wherein the water-soluble organic solvent is a glycol having a solubility parameter value (SP value) of 32 MPa1 / 2 or less. The water-based glittering ink composition according to claim 4, wherein the water-soluble organic solvent is one or more compounds selected from the group consisting of propylene glycol, diethylene glycol, triethylene glycol, and polyethylene glycol.   The aqueous glittering ink composition according to any one of claims 1 to 5, wherein the aqueous resin emulsion is an acrylic acid alkyl ester copolymer aqueous resin emulsion. An aqueous glittering ink composition comprising a glitter pigment, a colorant, an aqueous resin emulsion, a cellulose derivative, a thickener, a water-soluble organic solvent, a surfactant, an antifungal agent, and water,
The glitter pigment is a pearl pigment composed of metal oxide-coated particles, or a mixture of the pearl pigment and an aluminum pigment,
The aqueous resin emulsion is an acrylic acid alkyl ester copolymer aqueous resin emulsion,
The cellulose derivative is sodium carboxymethylcellulose;
The water-soluble organic solvent has a solubility parameter value (SP value) of 32 MPa1 / 2 or less,
The thickener is one or more compounds selected from the group consisting of rhamsan gum, welan gum, xanthan gum, leozan and diyutan gum;
A water-based glittering ink composition in which the surfactant content is 1.0% by weight or less based on the total amount of the ink composition. The glitter pigment is contained in an amount of 1.0 to 20.0% by weight in the total amount of ink,
The aqueous resin emulsion is contained in a solid content of 20 to 200% by weight with respect to the glitter pigment,
The cellulose derivative is contained in an amount of 0.5 to 3.0% by weight based on the glitter pigment,
The water-based glittering ink composition according to claim 7, wherein the thickener is contained in an amount of 0.1 to 0.5% in the total amount of the ink.