JP2009039021A - Cooking oil-and-fat composition - Google Patents

Cooking oil-and-fat composition Download PDF

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JP2009039021A
JP2009039021A JP2007206447A JP2007206447A JP2009039021A JP 2009039021 A JP2009039021 A JP 2009039021A JP 2007206447 A JP2007206447 A JP 2007206447A JP 2007206447 A JP2007206447 A JP 2007206447A JP 2009039021 A JP2009039021 A JP 2009039021A
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oil
fat composition
cooking
lecithin
cooking oil
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JP4663696B2 (en
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Rika Tanaka
利佳 田中
Kenichi Watanabe
健市 渡辺
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J Oil Mills Inc
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a cooking oil-and-fat composition having satisfactory mold-release characteristic and workability under the condition of industrially continuous high-temperature cooking, and making final cooked food have favorable appearance. <P>SOLUTION: The cooking oil-and-fat composition is obtained by adding a polyglycerol fatty acid ester, a polyglycerin condensed ricinoleate, particle silicon dioxide, and lecithin to edible oil and fat. The cooking oil-and-fat composition preferably contains 0.05-5 wt.% of the particle silicon dioxide having a particle diameter of ≤0.04 μm. The lecithin is preferred to be highly refined one, and the polyglycerol fatty acid ester is preferred to be a diglycerol monooleate fatty acid ester substantially. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本発明は、調理用油脂組成物に関し、さらに詳しくは、離型性、作業性および食品の外観向上の機能を併せ持つ離型油として好適な組成物に関する。   TECHNICAL FIELD The present invention relates to a cooking oil / fat composition, and more particularly to a composition suitable as a release oil having functions of releasing properties, workability, and food appearance.

従来、食品加工業界において、加熱調理の際、焼成後の食品素材と調理器具、焼型、天板などとの付着を防止する目的で、離型油が使用されている。特に、食品工業では、コンベアや鉄板上の調理食品を次工程に移管する際、調理食品が自重により剥離することを可能にする離型油は、省力化や無人化を図り、製造コストを下げ、さらに衛生に寄与する。   2. Description of the Related Art Conventionally, in the food processing industry, mold release oil has been used for the purpose of preventing adhesion between a baked food material and a cooking utensil, a baking mold, a top plate and the like during cooking. In particular, in the food industry, when transferring cooked food on a conveyor or iron plate to the next process, a release oil that allows the cooked food to be peeled off by its own weight saves labor and reduces manpower. Furthermore, it contributes to hygiene.

食品の離型性の得るために、調理用油脂組成物にレシチンを配合することが経済性と効果から見て一般的である。レシチンは主に大豆から抽出されるリン脂質製品である。しかし、レシチンを使用した調理用油脂組成物は、レシチンに由来する独特の臭気がある。また、加熱による褐変が起こりやすく、調理品の風味や外観を損なうという重大な欠点もある。   In order to obtain the mold release property of food, it is common to add lecithin to a cooking oil / fat composition from the viewpoint of economy and effect. Lecithin is a phospholipid product extracted mainly from soybeans. However, the cooking oil and fat composition using lecithin has a unique odor derived from lecithin. In addition, browning due to heating is likely to occur, and there is a serious drawback that the flavor and appearance of the cooked product are impaired.

離型油にレシチンを配合しないと、焼成時に食品が調理器具などに付着してしまい、充分満足のゆく離型性が得られない現状において、レシチンによる離型性を保ちつつ臭気や褐変を改善し、あるいはレシチンを含む調理用油脂組成物の離型性を上げてレシチンの添加量を少なくすることで臭気や褐変を抑える方法が提案されている。例えば、レシチン中のフォスファチジルコリンを分画して得られる分画レシチンを配合する(特許文献1)、レシチンをリゾ化処理することにより得られるリゾレシチンを配合する(特許文献2)、酵素分解処理した酵素レシチンを配合する(特許文献3)などの方法がある。しかし、レシチンの変性だけでは、臭気や加熱褐変の防止には充分でない。   If no lecithin is added to the mold release oil, the food will adhere to cooking utensils during baking, and in the current situation where satisfactory release cannot be obtained, the odor and browning will be improved while maintaining the release characteristics of lecithin. Alternatively, there has been proposed a method for suppressing odor and browning by increasing the releasability of a cooking oil / fat composition containing lecithin and reducing the amount of lecithin added. For example, fractionated lecithin obtained by fractionating phosphatidylcholine in lecithin is blended (Patent Document 1), lysolecithin obtained by lysing lecithin is blended (Patent Document 2), enzymatic degradation There exists a method of mix | blending the processed enzyme lecithin (patent document 3). However, modification of lecithin alone is not sufficient to prevent odor and heat browning.

別法として、澱粉(特許文献4)、シリコーン製剤、各種乳化剤、ワックス(特許文献5)などを配合することも、離型性の向上に有効である。本発明者らも、レシチンおよび微粒二酸化ケイ素を食用油脂に含有させることで高い離型性を持たせることを開示している(特許文献6)。しかし、澱粉を配合した離型油を長期間連続使用すると、炭化したカスが調理器具などに付着して、食品加工に不具合となり、洗浄作業にも手間取る。また、澱粉は、卵焼き、焼きそば、炒飯などの調理で外観や食感を損なうことがある。   As another method, blending starch (Patent Document 4), silicone preparation, various emulsifiers, wax (Patent Document 5), and the like is also effective in improving mold release properties. The present inventors have also disclosed that lecithin and fine silicon dioxide are included in edible fats and oils so as to give high release properties (Patent Document 6). However, if the release oil blended with starch is used continuously for a long period of time, the carbonized residue adheres to cooking utensils and the like, resulting in a problem in food processing and time-consuming washing work. In addition, starch may impair the appearance and texture in cooking such as fried eggs, fried noodles, and fried rice.

一方、ジグリセリン酸モノ脂肪酸エステルの離型効果も知られている(特許文献7〜9)。これらは、レシチンの代替や、ポリグリセリン脂肪酸エステルとの併用として、炊飯用途に限定されている。したがって、レシチン、二酸化ケイ素などと併用し、加熱調理条件下の離型性に優れる離型油は、全く知られていない。
特開2003-238984号公報 特開平8-333378号公報 特公平6-754695号公報 特開平5-030905号公報 特許2569332号公報 特開平10-248488号公報 特開平9-191839号公報 特開平8-131071号公報 特開平4-271748号公報
On the other hand, the mold release effect of diglyceric acid mono fatty acid ester is also known (patent documents 7 to 9). These are limited to rice cooking as an alternative to lecithin or in combination with polyglycerin fatty acid esters. Therefore, a release oil that is used in combination with lecithin, silicon dioxide and the like and has excellent release properties under cooking conditions is not known at all.
Japanese Patent Laid-Open No. 2003-238984 JP-A-8-333378 Japanese Examined Patent Publication No. 6-754695 JP-A-5-030905 Japanese Patent No. 2569332 Japanese Patent Laid-Open No. 10-248488 Japanese Patent Laid-Open No. 9-191839 Japanese Patent Laid-Open No. 8-131071 Japanese Unexamined Patent Publication No. 4-217748

従来の離型油は、一定の剥離性の改善がなされているが、現在でもさらなる剥離性の向上が求められている。   Conventional release oils have been improved in certain peelability, but there is still a need for further improvement in peelability.

離型油を含む調理用油脂組成物に求められる機能は、扱う食材の種類の増加、タレ、調味液などの多用によって一段と高くなっている。例えば、食品加工業の最近の傾向として、調理感をさらに向上させるために、食品素材を直火で炙る、炭火で焼くなどの加工が施されるようになった。食品素材と接する調理器具、焼型、天板の表面温度は、250℃を超える場合もある。   The functions required of cooking oils and fat compositions containing mold release oil are further enhanced by increasing the types of foods to be handled, sauces, seasonings and the like. For example, as a recent trend in the food processing industry, in order to further improve the cooking sensation, processing such as burning the food material on an open fire or baking it on a charcoal fire has been applied. The surface temperature of cooking utensils, baking molds, and top plates in contact with food materials may exceed 250 ° C.

ところで、食品素材から加熱時に溶出するエキス分は、調理器具、焼型、天板などの上で水分が蒸発し、いわゆる「こげ」と呼ばれる状態になる。ある種の食品素材については、調理後の食品が程よく「こげ」ていることが、風味や調理感を向上させ、商品価値を高める。このような商品カテゴリーの場合、調理用油脂組成物に基づく加熱着色(褐変)は、欠点とは位置づけられず、むしろ好ましい現象として受け入れられる。ただし、この「こげ」は、調理器具、焼型、天板などに残っては意味がなく、食品素材に好ましい外観を呈して付着していることが重要となる。   By the way, the extract that elutes from the food material when heated evaporates on cooking utensils, baking molds, top plates, etc., and is in a so-called “burn” state. For certain food ingredients, moderately “cooked” food after cooking improves flavor and cooking and increases the value of the product. In the case of such a product category, heat coloring (browning) based on the cooking oil / fat composition is not positioned as a defect, but rather is accepted as a preferable phenomenon. However, this “burne” is meaningless if left on cooking utensils, baking molds, top plates, etc., and it is important that it adheres to the food material with a favorable appearance.

本発明者らは、食品素材自体の離型性と、調理食品の「こげ」付着という外観の好ましさは、調理用油脂組成物が持つ別の機能であることを見出した。そこで、本発明者らは、最終調理食品の外観の好ましさを、調理用油脂組成物に求められる離型性以外の第二の機能として取り上げた。   The present inventors have found that the releasability of the food material itself and the preference of the appearance of “burnt” adhesion of the cooked food are other functions of the cooking fat composition. Therefore, the present inventors have taken up the preference of the appearance of the final cooked food as a second function other than the releasability required for cooking oil and fat compositions.

食品素材を高温で連続加熱する工業的生産条件下では、調理食品と接する部分よりも空加熱される部分で調理用油脂組成物の褐変、熱重合が激しく起こる。これらの洗浄の不完全さが、後の離型性能の低下に大きく影響する。そこで、本発明者らは、この現象に注目し、洗浄のし易さ(カスや汚れの拭き取り易さ)を、調理用油脂組成物に求められる第三の機能として取り上げた。   Under industrial production conditions in which the food material is continuously heated at a high temperature, browning and thermal polymerization of the cooking oil / fat composition occur more vigorously in the portion heated by air than in the portion in contact with the cooked food. These imperfections in washing greatly affect the subsequent degradation of the mold release performance. Therefore, the present inventors paid attention to this phenomenon and took up ease of cleaning (ease of wiping off residue and dirt) as a third function required for cooking oils and fat compositions.

本発明の目的は、連続的に高温加熱調理される食品工業用途に充分な離型性と作業性を与えるとともに、最終調理食品に良好な外観(こげ)を付与する調理用油脂組成物を提供することである。   The object of the present invention is to provide a cooking oil / fat composition that provides sufficient releasability and workability for food industry applications that are continuously cooked at high temperatures, and that imparts a good appearance (burnt) to the final cooked food. It is to be.

本発明者らは、上記機能を併せ持つ調理用油脂組成物を鋭意検討した結果、食用油脂にポリグリセリン酸脂肪酸エステルおよびポリグリセリン縮合リシノレイン酸エステルを配合し、さらに微粒二酸化ケイ素およびレシチンを添加することによって、調理用油脂組成物が高温の加熱調理においても調理食品に優れた離型性を保持させながら、最終調理食品の外観をも向上させ、しかも鉄板などの洗浄のし易さを飛躍的に向上させることを見出して、本発明を完成させた。   As a result of intensive studies on cooking oil and fat compositions having the above-mentioned functions, the present inventors blended edible fats and oils with polyglyceric acid fatty acid ester and polyglycerin condensed ricinoleic acid ester, and further added fine silicon dioxide and lecithin. As a result, the cooking oil / fat composition retains excellent mold releasability even when cooking at high temperatures, while improving the appearance of the final cooked food, and dramatically improving the ease of cleaning iron plates and the like. The present invention has been completed by finding improvements.

すなわち、本発明は、食用油脂、ポリグリセリン脂肪酸エステル、ポリグリセリン縮合リシノレイン酸エステル、微粒二酸化ケイ素、およびレシチンを含む調理用油脂組成物を提供する。本発明の調理用油脂組成物は、離型油、鉄板焼油、天板油として使用される。   That is, the present invention provides a cooking oil / fat composition comprising an edible oil / fat, a polyglycerin fatty acid ester, a polyglycerin condensed ricinoleic acid ester, fine silicon dioxide, and lecithin. The cooking oil / fat composition of the present invention is used as a mold release oil, iron plate baking oil, or top plate oil.

上記微粒二酸化ケイ素の含有量は、0.05〜10重量%であることが好ましい。さらに、粒子径が0.04μm以下の上記微粒二酸化ケイ素を、0.05〜5重量%含むことが好ましい。   The content of the fine silicon dioxide is preferably 0.05 to 10% by weight. Furthermore, it is preferable to contain 0.05 to 5% by weight of the fine silicon dioxide having a particle size of 0.04 μm or less.

また、上記レシチンは、精製レシチンであることが好ましい。   The lecithin is preferably purified lecithin.

また、上記ポリグリセリン脂肪酸エステルは、実質的にジグリセリンモノオレイン酸脂肪酸エステルからなることが好ましい。   Moreover, it is preferable that the said polyglycerol fatty acid ester consists of a diglycerol monooleic-acid fatty acid ester substantially.

本発明は、また、本発明の調理用油脂組成物を使用してなる食品を提供する。   The present invention also provides a food product using the cooking oil / fat composition of the present invention.

本発明の調理用油脂組成物は、炒め工程や焼き工程といった加熱調理の際に高い離型性を保持する。本発明の調理用油脂組成物は、最終調理食品に好ましいこげ感や調理感を付与して、該食品の外観や風味を改善する。さらに、本発明の調理用油脂組成物は、調理器具、焼型、天板などに付着したカスの拭き取りが容易にし、作業性を向上する。したがって、本発明の調理用油脂組成物は、コンベアなどを用いた連続生産工程での使用に好適である。   The cooking oil / fat composition of the present invention retains high releasability during heat cooking such as a fried process and a baking process. The cooking oil / fat composition of the present invention imparts a preferable burning feeling and cooking feeling to the final cooked food, thereby improving the appearance and flavor of the food. Furthermore, the cooking oil / fat composition of the present invention facilitates wiping off residue adhering to cooking utensils, baking molds, top plates, etc., and improves workability. Therefore, the cooking oil / fat composition of the present invention is suitable for use in a continuous production process using a conveyor or the like.

以下に、本発明の実施の形態を説明する。本発明の調理用油脂組成物に配合される食用油脂は、食用に適するものであれば特に限定されない。例えば、植物性油脂として、ダイズ油、ダイズ胚芽油、ナタネ油、トウモロコシ油、ゴマ油、ゴマサラダ油、シソ油、アマニ油、ラッカセイ油、ベニバナ油、高オレイン酸ベニバナ油、ヒマワリ油、高オレイン酸ヒマワリ油、綿実油、ブドウ種子油、マカデミアナッツ油、ヘーゼルナッツ油、カボチャ種子油、クルミ油、ツバキ油、茶実油、エゴマ油、ボラージ油、オリーブ油、米糠油、コムギ胚芽油、パーム油、パームオレイン油、パーム核油、ヤシ油、カカオ脂、藻類油などが挙げられる。動物性油脂としては、牛脂、ラード、鶏油、乳脂、魚油、アザラシ油などが挙げられる。   Hereinafter, embodiments of the present invention will be described. The edible oil / fat blended in the cooking oil / fat composition of the present invention is not particularly limited as long as it is suitable for edible use. For example, as vegetable oils, soybean oil, soybean germ oil, rapeseed oil, corn oil, sesame oil, sesame salad oil, perilla oil, linseed oil, peanut oil, safflower oil, high oleic safflower oil, sunflower oil, high oleic sunflower oil Oil, cottonseed oil, grape seed oil, macadamia nut oil, hazelnut oil, pumpkin seed oil, walnut oil, camellia oil, tea seed oil, sesame oil, borage oil, olive oil, rice bran oil, wheat germ oil, palm oil, palm olein oil, Palm kernel oil, coconut oil, cacao butter, algal oil and the like can be mentioned. Animal fats and oils include beef tallow, lard, chicken oil, milk fat, fish oil, seal oil and the like.

上記油脂を2種類以上混合した調合油、油脂を水素添加して得られる硬化油、油脂を固形部と液状部とに分別して得られる分別油、油脂をエステル交換して得られるエステル交換油、ならびにこれらの処理を複数組み合わせた食用油や調合油も使用可能である。   Formulated oil obtained by mixing two or more of the above fats and oils, a hardened oil obtained by hydrogenating fats and oils, a fractionated oil obtained by separating fats and oils into a solid part and a liquid part, a transesterified oil obtained by transesterifying fats and oils, In addition, edible oils and formulated oils obtained by combining a plurality of these treatments can also be used.

本発明の調理用油脂組成物には、ポリグリセリン脂肪酸エステルが必須である。ポリグリセリン脂肪酸エステルを添加しないと、充分な離型性が得られない。さらに、ポリグリセリン脂肪酸エステル(特にジグリセリン脂肪酸エステル)と、後述のレシチンとを併用することによって、これまでに評価されてきた一般的な離型機能だけでなく、調理目的でつけた「こげ」を調理食品に好ましい外観を伴って付着させることができる。   Polyglycerin fatty acid ester is essential for the cooking oil / fat composition of the present invention. If the polyglycerin fatty acid ester is not added, sufficient releasability cannot be obtained. Furthermore, by using polyglycerin fatty acid ester (especially diglycerin fatty acid ester) and lecithin, which will be described later, in addition to the general mold release function that has been evaluated so far, it has been added for cooking purposes. Can be attached to the cooked food with a favorable appearance.

上記の現象の生じる機構は定かでないが、レシチンよりも親水性の高いポリグリセリン脂肪酸エステル、特にジグリセリン脂肪酸エステルを配合することが、食品のエキス分およびレシチンを含む調理用油脂組成物が加熱されてできる「こげ」と食品素材とのなじみを高めているためと推察される。なお、上記の内容は、本発明の範囲を拘束するものではない。   The mechanism by which the above phenomenon occurs is not clear, but blending a polyglycerin fatty acid ester having a higher hydrophilicity than lecithin, especially diglycerin fatty acid ester, heats the cooking oil and fat composition containing the extract of food and lecithin. This is thought to be due to the increased familiarity between “Koke” and food ingredients. In addition, said content does not restrain the scope of the present invention.

本発明に使用するポリグリセリン脂肪酸エステルは、構成脂肪酸の種類と数やグリセリン重合度に特に制限されない。ポリグリセリン脂肪酸エステルは、単独でもよく、あるいは2種類以上を併用することができる。   The polyglycerol fatty acid ester used in the present invention is not particularly limited by the type and number of constituent fatty acids and the degree of glycerol polymerization. Polyglycerol fatty acid ester may be individual, or can use 2 or more types together.

ポリグリセリン脂肪酸エステルグリセリンの重合度は、具体的には2〜10であり、好ましくは2〜6であり、さらに好ましくは2(すなわち、ジグリセリン脂肪酸エステル)である。   The degree of polymerization of the polyglycerol fatty acid ester glycerol is specifically 2 to 10, preferably 2 to 6, and more preferably 2 (that is, diglycerol fatty acid ester).

特に好ましくは、ジグリセリンモノ脂肪酸エステルである。ジグリセリンモノ脂肪酸エステルは、ジグリセリン残基に一個の脂肪酸がエステル結合したものであり、一般に、食品添加物の乳化剤として使用されている。ジグリセリンモノ脂肪酸エステルは、一般に、ジグリセリンと脂肪酸のエステル化反応、あるいは、ジグリセリンとトリグリセライドとのエステル交換反応の後、分子蒸留によって、目的に合うモノエステル純度まで高めることにより製造される。モノエステル純度は、通常、30〜100%でよく、50%以上が好ましく、70%以上のものがより好ましい。   Particularly preferred is diglycerin monofatty acid ester. Diglycerin monofatty acid ester is a diglycerin residue in which one fatty acid is ester-bonded, and is generally used as an emulsifier for food additives. A diglycerin monofatty acid ester is generally produced by increasing the purity of a monoester suitable for the purpose by molecular distillation after an esterification reaction between diglycerin and a fatty acid or an ester exchange reaction between diglycerin and triglyceride. The monoester purity may be usually 30 to 100%, preferably 50% or more, and more preferably 70% or more.

ポリグリセリンモノ脂肪酸エステルの構成脂肪酸は、具体的には、炭素数8〜24であり、炭素数8〜22であることが好ましく、炭素数16〜22であることがさらに好ましい。具体的には、オレイン酸、リノール酸、リノレン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘン酸、エルカ酸などが挙げられる。構成脂肪酸は、飽和脂肪酸および不飽和脂肪酸のいずれでもよいが、不飽和脂肪酸が好ましく、オレイン酸がさらに好ましい。   Specifically, the constituent fatty acid of the polyglycerin monofatty acid ester has 8 to 24 carbon atoms, preferably 8 to 22 carbon atoms, and more preferably 16 to 22 carbon atoms. Specific examples include oleic acid, linoleic acid, linolenic acid, myristic acid, palmitic acid, stearic acid, behenic acid, erucic acid, and the like. The constituent fatty acid may be either a saturated fatty acid or an unsaturated fatty acid, but is preferably an unsaturated fatty acid, more preferably oleic acid.

したがって、本発明の調理用油脂組成物に最も好ましいポリグリセリン脂肪酸エステルは、実質的にジグリセリンモノオレイン酸エステルからなる。   Therefore, the most preferred polyglycerin fatty acid ester for the cooking oil / fat composition of the present invention consists essentially of diglycerin monooleate.

本発明の調理用油脂組成物において、ポリグリセリンモノ脂肪酸エステルの添加量に特に制限はない。通常、0.05〜15重量%であり、好ましくは0.1〜5重量%であり、特に好ましくは0.1〜3重量%である。   In the cooking oil / fat composition of the present invention, the amount of the polyglycerin monofatty acid ester added is not particularly limited. Usually, it is 0.05 to 15% by weight, preferably 0.1 to 5% by weight, and particularly preferably 0.1 to 3% by weight.

本発明の調理用油脂組成物に配合されるポリグリセリン縮合リシノレイン酸エステルは、食品添加物である乳化剤の一種である。親油性が強く、一般的には強力なO/W乳化剤として使用されている。本発明では、ポリグリセリン縮合リシノレイン酸エステルは、レシチンの沈殿、分離を防止するために使用される。すなわち、本発明の調理用油脂組成物にポリグリセリン縮合リシノレイン酸エステルを添加しないと、レシチンが分離するなどの調理用油脂組成物として不適切な性状が現れる。   The polyglycerin condensed ricinoleic acid ester blended in the cooking oil / fat composition of the present invention is a kind of emulsifier which is a food additive. It is strongly lipophilic and is generally used as a powerful O / W emulsifier. In the present invention, the polyglycerin condensed ricinoleic acid ester is used to prevent precipitation and separation of lecithin. That is, if a polyglycerin-condensed ricinoleic acid ester is not added to the cooking oil / fat composition of the present invention, inappropriate properties appear as a cooking oil / fat composition such as lecithin separating.

ポリグリセリン縮合リシノレイン酸エステルは、結合脂肪酸数、グリセリンの重合度および添加量に特に制限されることなく用いることができる。ポリグリセリン縮合リシノレイン酸エステルは、リシノレイン酸同士をエステル化して得られる縮合リシノレイン酸とポリグリセリンとをエステル化することにより得られる。   The polyglycerin condensed ricinoleic acid ester can be used without any particular restrictions on the number of bound fatty acids, the degree of polymerization of glycerin and the amount added. Polyglycerin condensed ricinoleic acid ester is obtained by esterifying condensed ricinoleic acid obtained by esterifying ricinoleic acid with polyglycerin.

本発明の調理用油脂組成物においてポリグリセリン縮合リシノレイン酸エステルの添加量は、通常、0.01〜10重量%でよく、0.1〜5重量%であることが好ましく、0.5〜3重量%であることがより好ましい。   In the cooking oil / fat composition of the present invention, the polyglycerin condensed ricinoleic acid ester may be added usually in an amount of 0.01 to 10% by weight, preferably 0.1 to 5% by weight, and preferably 0.5 to 3% by weight. More preferred.

本発明の調理用油脂組成物は、微粒二酸化ケイ素の添加を必須とする。微粒二酸化ケイ素を添加しないと、必要な離型性が得られない。さらに、微粒二酸化ケイ素と後述のレシチンとを併用することにより、離型性を格段に向上させることができる。これにより、最近の食品工業生産連続ラインで必要とされる、自重で剥離する離型効果の向上、ひいては調理食品の歩留の向上が可能になる。   The cooking oil / fat composition of the present invention requires the addition of fine silicon dioxide. If fine silicon dioxide is not added, necessary releasability cannot be obtained. Furthermore, the release properties can be remarkably improved by using the fine silicon dioxide and lecithin described later in combination. As a result, it is possible to improve the mold release effect that peels off by its own weight, which is required in recent food industry production continuous lines, and thus the yield of cooked foods.

本発明の調理用油脂組成物に配合される微粒二酸化ケイ素とは、食品添加物公定書解説書(廣川書店、第7版、1999)に記載されるように、平均粒子径15μm以下の滑らかな触感を持つ白色の微細な粉末を意味する。   The fine silicon dioxide compounded in the cooking oil / fat composition of the present invention is a smooth substance having an average particle diameter of 15 μm or less, as described in the Food Additive Official Manual (Yodogawa Shoten, 7th Edition, 1999). It means a white fine powder with a touch.

前記微粒二酸化ケイ素として、例えば(1)気相法、(2)湿式法、(3)シリカゲルの微粉末化によって製造されたものが挙げられる。   Examples of the fine silicon dioxide include those produced by (1) vapor phase method, (2) wet method, and (3) silica gel fine powder.

(1)の微粒二酸化ケイ素は、四塩化ケイ素の酸水素焔中での高温加水分解により、以下のような反応:
により得られる。
The finely divided silicon dioxide of (1) undergoes the following reaction by high-temperature hydrolysis of silicon tetrachloride in an oxyhydrogen flame:
Is obtained.

微粒二酸化ケイ素は、その平均粒子径と粒度分布が油脂への粒子の分散性および離型性に大きな影響を及ぼす。つまり、粒子径が小さく、かつ粒度分布が均一であるほど、油脂への分散性が高まる。その結果、必要期間沈降のない均一な状態を保つことができる。   In the fine silicon dioxide, the average particle size and particle size distribution have a great influence on the dispersibility and releasability of the particles in fats and oils. That is, the smaller the particle size and the more uniform the particle size distribution, the higher the dispersibility in fats and oils. As a result, it is possible to maintain a uniform state without settling for a necessary period.

(1)の気相法による微粒二酸化ケイ素は、他の製法による二酸化ケイ素とは異なり、1000℃以上の高温で生成されるため、製造直後は無水である。さらに、他の製法による二酸化ケイ素と比較して粒子径が小さく、非常に均一な粒度分布を持つという特徴を有する。したがって、気相法による二酸化ケイ素は、本発明の調理用油脂組成物に添加する成分として好適である。気相法による微粒二酸化ケイ素の平均粒子径は、好ましくは0.04μm以下であり、さらに好ましくは0.02μm以下である。   Unlike the silicon dioxide produced by the other production methods, the fine silicon dioxide produced by the vapor phase method (1) is produced at a high temperature of 1000 ° C. or higher, and thus is anhydrous immediately after production. Furthermore, it has a feature that the particle size is small compared to silicon dioxide produced by other manufacturing methods and has a very uniform particle size distribution. Therefore, silicon dioxide produced by the gas phase method is suitable as a component to be added to the cooking oil / fat composition of the present invention. The average particle size of the fine silicon dioxide by the vapor phase method is preferably 0.04 μm or less, more preferably 0.02 μm or less.

(1)の気相法による微粒二酸化ケイ素は、日本アエロジル(株)製アエロジル、(株)トクヤマ製レオロシールなどの市販のものを使用することができる。   As the finely divided silicon dioxide obtained by the gas phase method (1), commercially available products such as Aerosil manufactured by Nippon Aerosil Co., Ltd. and Reolosil manufactured by Tokuyama Co., Ltd. can be used.

(2)の湿式法で製造された二酸化ケイ素や、(3)のシリカゲルを微粉末化したものとしては、平均粒子径が15μm以下であり、好ましくは10μm以下、特に好ましくは5μm以下である。食品添加物用に製造された市販の微粒二酸化ケイ素(例えば富士シリシア化学(株)製サイロページ720)を使用可能である。   The silicon dioxide produced by the wet method (2) and the silica gel of (3) finely powdered has an average particle size of 15 μm or less, preferably 10 μm or less, particularly preferably 5 μm or less. Commercially available finely divided silicon dioxide (for example, silo page 720 manufactured by Fuji Silysia Chemical Ltd.) manufactured for food additives can be used.

湿式法の微粒二酸化ケイ素は、気相法のものと比較して、一般に粒子径が大きく、粒度分布も広い。このため、湿式法の微粒二酸化ケイ素を単独で調理用油脂組成物に添加した場合、沈降のない均一な状態を保てる期間が多少短くなる、二酸化ケイ素が分離する、調理用油脂組成物の粘度がばらつくなどの現象が起きることがある。よって、本発明の調理用油脂組成物に(2)および/または(3)の微粒二酸化ケイ素を添加する場合は、(1)の微粒二酸化ケイ素を、二酸化ケイ素全量の30%以上配合することが好ましく、特に好ましくは50%以上である。   Compared with the vapor phase method, finely divided silicon dioxide of the wet method generally has a large particle size and a wide particle size distribution. For this reason, when finely divided silicon dioxide of the wet method is added alone to the cooking oil / fat composition, the period for maintaining a uniform state without sedimentation is somewhat shortened, the silicon dioxide is separated, and the viscosity of the cooking oil / fat composition is Phenomena such as dispersion may occur. Therefore, when adding the fine silicon dioxide of (2) and / or (3) to the cooking oil / fat composition of the present invention, the fine silicon dioxide of (1) may be blended at 30% or more of the total amount of silicon dioxide. Preferably, it is 50% or more particularly preferably.

本発明の調理用油脂組成物において、微粒二酸化ケイ素の添加量は、通常、0.05〜12重量%でよく、好ましくは0.05〜10重量%、さらに好ましくは0.1〜10重量%である。粒子径が0.04μm以下の微粒二酸化ケイ素を一部または全量用いる場合、0.05〜5重量%で使用することが好ましい。微粒二酸化ケイ素が多すぎると、分離したり、調理用油脂組成物の粘度が高くなる場合がある。   In the cooking oil / fat composition of the present invention, the amount of fine silicon dioxide added may be usually 0.05 to 12% by weight, preferably 0.05 to 10% by weight, and more preferably 0.1 to 10% by weight. When a part or all of the fine silicon dioxide having a particle size of 0.04 μm or less is used, it is preferably used at 0.05 to 5% by weight. When there is too much fine silicon dioxide, it may isolate | separate or the viscosity of the oil-fat composition for cooking may become high.

本発明の調理用油脂組成物は、レシチンの添加が必須である。レシチンを添加しない場合は、必要な離型性が得られない。レシチンは、リン脂質を主成分とする乳化剤である。本発明の調理用油脂組成物に添加されるレシチンとしては、大豆油を製造する際に副産物として得られる、油分を30〜40重量%の割合で含有する大豆レシチンが好適である。その他、菜種レシチン、コーンレシチン、サフラワーレシチンなどの植物レシチンや、卵黄レシチンなどの動物レシチンを用いてもよい。本明細書において、これらの天然由来の未精製レシチンを、クルードレシチンと呼ぶ。クルードレシチンは市販のものを使用することができる。   In the cooking oil / fat composition of the present invention, addition of lecithin is essential. If lecithin is not added, the required releasability cannot be obtained. Lecithin is an emulsifier mainly composed of phospholipids. As the lecithin to be added to the cooking oil / fat composition of the present invention, soybean lecithin containing 30 to 40% by weight of oil obtained as a by-product when producing soybean oil is suitable. In addition, plant lecithin such as rapeseed lecithin, corn lecithin, safflower lecithin, and animal lecithin such as egg yolk lecithin may be used. In the present specification, these naturally-derived unpurified lecithins are referred to as crude lecithins. A commercially available crude lecithin can be used.

本発明の調理用油脂組成物に使用するレシチンには、上記クルードレシチンから、中性脂質、脂肪酸、炭水化物、タンパク質、無機塩、ステロール、色素などの不純物を公知の手法を用いて除いて得られる高純度(例えば90%以上)に精製された精製レシチンを用いることが好ましい。精製レシチンには市販のものを使用することができる。   The lecithin used in the cooking oil / fat composition of the present invention is obtained by removing impurities such as neutral lipids, fatty acids, carbohydrates, proteins, inorganic salts, sterols, and pigments from the crude lecithin using known techniques. It is preferable to use purified lecithin purified to a high purity (for example, 90% or more). A commercially available product can be used as the purified lecithin.

精製レシチンを用いることによる調理用油脂組成物の性能向上の機構は定かではないが、クルードレシチンに含まれるタンパク質や糖脂質のような離型機能を伴わない不純物が、工業的に連続生産する高温加熱下で褐変や炭化を起こし、これが、後の洗浄工程が妨害するためと推察される。   Although the mechanism for improving the performance of cooking oil and fat compositions by using purified lecithin is not clear, impurities that do not have a mold release function, such as proteins and glycolipids contained in crude lecithin, are industrially continuously produced at high temperatures. It is assumed that browning and carbonization occur under heating, which hinders the subsequent washing process.

上記の製造ライン上で充分な離型性を得るためには、従来、レシチンが多量に必要であったが、一方で、レシチンの持つ風味によって、食品へ悪影響を及ぼしていた。本発明の調理用油脂組成物では、微粒二酸化ケイ素との併用で製造ライン上の離型性が格段に向上するため、レシチンの添加量を減らすことができる。その結果、風味の影響を最小限に抑えた必要最低限の量で使用することが可能となる。本発明の調理用油脂組成物のレシチン添加量は、通常、0.01〜10重量%でよく、特に0.1〜5重量%でよい。   Conventionally, a large amount of lecithin has been required to obtain sufficient release properties on the above production line, but on the other hand, the flavor of lecithin had an adverse effect on food. In the cooking oil / fat composition of the present invention, when used in combination with fine silicon dioxide, the releasability on the production line is remarkably improved, so the amount of lecithin added can be reduced. As a result, it becomes possible to use it in the minimum necessary amount while minimizing the influence of flavor. The amount of lecithin added to the cooking oil / fat composition of the present invention may be usually 0.01 to 10% by weight, particularly 0.1 to 5% by weight.

本発明の調理用油脂組成物には、必要に応じてフレーバー;調味料;乳化剤;糖類(単糖、二糖、オリゴ糖)、多糖類などの糖質;アミノ酸、ペプチド、タンパク質;ならびに当業分野で公知のその他の助剤を、本発明の効果を損なわない範囲で添加することができる。本発明の調理用油脂組成物の形状は、液状、ペースト状、固形状のいずれでもよい。形状は、食用油脂をはじめとする必須成分、およびその他の成分を適宜選択することにより容易に調整可能である。   The cooking oil / fat composition of the present invention includes a flavor, a seasoning, an emulsifier, a saccharide such as a saccharide (monosaccharide, disaccharide, oligosaccharide) or a polysaccharide; an amino acid, a peptide, a protein; Other auxiliary agents known in the field can be added within a range not impairing the effects of the present invention. The cooking oil / fat composition of the present invention may be liquid, pasty, or solid. The shape can be easily adjusted by appropriately selecting essential components including edible fats and oils and other components.

本発明の調理用油脂組成物の製造法としては、食用油脂にポリグリセリン脂肪酸エステル、ポリグリセリン縮合リシノレイン酸エステル、微粒二酸化ケイ素およびレシチンを配合し、40〜100℃に加温して、溶解、攪拌後、室温まで放冷すればよい。   As a method for producing the cooking fat composition of the present invention, polyglycerin fatty acid ester, polyglycerin condensed ricinoleic acid ester, fine silicon dioxide and lecithin are blended in edible fat and oil, heated to 40 to 100 ° C., dissolved, What is necessary is just to cool to room temperature after stirring.

本発明は、また、上記調理用油脂組成物を使用してなる食品を提供する。その食品素材は、卵焼き、焼きそば、焼肉、チャーハン、野菜炒めなどの炒め物類;各種ケーキ類、パン類、ピザ、クレープ、お好み焼きなどの加工食品および生地;肉類;魚介類;卵類;これらをカット、ミンチなどの加工を施したもの;上記食品に類似させた動植物タンパク含有食品などが挙げられる。また、これらの食品素材を加熱調理前に、塩や醤油、砂糖などを含むタレにつけこんだもの、加熱し適度な「こげ」を付与することで好ましい風味や調理感をつけることが可能なものも、本発明における食品素材の範囲内である。これらの食品素材に、本発明の調理用油脂組成物を刷毛やスプレーで塗布する。   This invention also provides the foodstuff which uses the said oil-fat composition for cooking. The food materials are fried foods such as fried eggs, fried noodles, grilled meat, fried rice, and stir-fried vegetables; processed foods and doughs such as cakes, breads, pizzas, crepes, okonomiyaki; meats; seafood; eggs; Foods processed with cuts, mince, etc .; animal and vegetable protein-containing foods similar to the above foods. In addition, these food ingredients are cooked in a sauce containing salt, soy sauce, sugar, etc. before cooking, and can be given a good flavor and cooking feeling by heating to give an appropriate “burnt” Is also within the scope of the food material in the present invention. The cooking oil / fat composition of the present invention is applied to these food materials by brush or spray.

さらに、本発明の調理用油脂組成物は、食品素材に塗布、散布する使い方だけでなく、鉄板や型上に生地を載せ、該生地を焼成して製造する食品の製造に際し、鉄板などに塗布してもよい。特に、コンベアを用いる連続式焼成機での食品製造では、良好な離型性が得られる。焼成後の食品は、剥離性が良好なものとなる。このような食品(焼成品)は、例えば卵焼き、焼きそば、焼肉、チャーハン、野菜炒め、各種炒め物類、ケーキ類、パン類、ピザ、クレープ、お好み焼きなどが挙げられる。   Furthermore, the cooking oil / fat composition of the present invention is applied not only to food materials, but also applied to iron plates, etc. in the production of foods produced by placing the dough on an iron plate or mold and baking the dough. May be. In particular, good mold releasability can be obtained in food production using a continuous baking machine using a conveyor. The food after baking has a good peelability. Examples of such foods (baked products) include fried eggs, fried noodles, grilled meat, fried rice, fried vegetables, various fried foods, cakes, breads, pizzas, crepes, okonomiyaki, and the like.

本発明の調理用油脂組成物は、おにぎり、寿司のように、食品原料を型に充填し、成型後、型抜きして製造する食品にも使用される。本発明の調理用油脂組成物を型に塗布することによって、成型後の食品の剥離性が良好になる。   The cooking oil / fat composition of the present invention is also used for foods such as rice balls and sushi, in which food raw materials are filled in a mold, and then molded and die-cut. By applying the cooking oil / fat composition of the present invention to a mold, the peelability of the molded food is improved.

以下に、実施例を示して本発明をより詳細に説明するが、本発明は、実施例に制限されるものではない。   EXAMPLES Hereinafter, the present invention will be described in more detail with reference to examples. However, the present invention is not limited to the examples.

〔実施例1〜21、比較例1〜5〕
(調理用油脂組成物の調製)
本発明に従う調理用油脂組成物(実施例1〜21)を表1〜3に示す組成で調合した。また、比較例1〜5として、表4に示す組成の調理用油脂組成物を調合した。ここで、微粒二酸化ケイ素として、気相法で製造されたものは平均粒子径0.01μmのアエロジル200(日本アエロジル(株)製)、湿式法で製造されたものは平均粒子径4μmのサイロページ720(富士シリシア化学(株)製)を使用した。クルードレシチンには、商品名:SLPペーストNP(辻製油(株)製)を、高純度に精製した精製レシチンには、商品名:SLPホワイト(辻製油(株)製)を使用した。また、ポリグリセリン縮合リシノレイン酸エステルには、商品名:SYグリスターCR-ED(阪本薬品工業(株)製)を使用した。
[Examples 1 to 21, Comparative Examples 1 to 5]
(Preparation of cooking oil composition)
The oil composition for cooking according to the present invention (Examples 1 to 21) was prepared with the compositions shown in Tables 1 to 3. Moreover, the oil-fat composition for cooking of the composition shown in Table 4 was prepared as Comparative Examples 1-5. Here, as the fine silicon dioxide, those produced by the vapor phase method are Aerosil 200 (manufactured by Nippon Aerosil Co., Ltd.) having an average particle size of 0.01 μm, and those produced by the wet method are silo page 720 having an average particle size of 4 μm. (Fuji Silysia Chemical Co., Ltd.) was used. The product name: SLP Paste NP (manufactured by Sakai Oil Co., Ltd.) was used for the crude lecithin, and the product name: SLP White (manufactured by Sakai Oil Co., Ltd.) was used for the purified lecithin purified to high purity. Also, as the polyglycerin-condensed ricinoleic acid ester, trade name: SY Glyster CR-ED (manufactured by Sakamoto Pharmaceutical Co., Ltd.) was used.

配合された調理用油脂組成物を、60℃にて溶解、撹拌し、放冷後、サンプル瓶に充填して、25℃にて一晩保管した。   The blended cooking oil / fat composition was dissolved and stirred at 60 ° C., allowed to cool, filled into a sample bottle, and stored overnight at 25 ° C.

次に、各調理用油脂組成物の保管後の状態を、均一性、および調理器具へ塗布する際の作業性の2項目について評価した。結果を、表1〜4に示す。   Next, the condition after storage of each cooking oil / fat composition was evaluated for two items: uniformity and workability when applied to cooking utensils. The results are shown in Tables 1-4.

(焼成試験、風味試験)
以下の方法に従って、各調理用油脂組成物の焼成試験および風味試験を行った。焼成試験は、すべてn=15にて実施した。
1) 電熱プレートに鉄板(25cm×25cm)を載せ、230℃に加熱する。
2) 調理用油脂組成物1.5gを鉄板上に落とし、30秒間加熱する。
3) 鉄板上の油をろ紙で薄くのばす。この時、鉄板の表面温度は、250〜260℃に達する。
4) 豚肉(薄切り、赤みの多いタイプ)を鉄板に置き、片面のみ1分間加熱する。
5) 鉄板をペンチで持ち上げ、逆さまにする。その時、肉が自重で剥がれ落ちる割合(枚数)を測定する。剥がれ落ちない場合は、箸などで剥離する。
6) 豚肉の自重剥離率、豚肉の炒め前後の重量に基づく焼成歩留、鉄板についたカスの量、焼き上げ時に肉を取り上げたときの感覚(剥離強度)、製品の外観、カスの残量、カスの拭き取りやすさにて離型性を評価する。また、焼成後の製品は風味試験によって製品の風味を評価する。
(Baking test, flavor test)
According to the following method, the baking test and flavor test of each cooking oil-fat composition were performed. All firing tests were conducted at n = 15.
1) Place an iron plate (25cm x 25cm) on the electric heating plate and heat to 230 ° C.
2) Drop 1.5g of cooking oil / fat composition on iron plate and heat for 30 seconds.
3) Thin the oil on the iron plate with filter paper. At this time, the surface temperature of the iron plate reaches 250 to 260 ° C.
4) Place pork (thin slices, reddish type) on an iron plate and heat only one side for 1 minute.
5) Lift the iron plate with pliers and turn it upside down. At that time, the ratio (number of sheets) at which the meat is peeled off by its own weight is measured. If it does not peel off, peel it off with chopsticks.
6) Pork's own weight exfoliation rate, baking yield based on the weight before and after fried pork, amount of scum on iron plate, sensation when meat was picked up when baked (peel strength), product appearance, residue of residue, The releasability is evaluated by the ease of wiping off the residue. Moreover, the product after baking evaluates the flavor of a product by a flavor test.

自重剥離率(n=15)は、何枚自重剥離したかを百分率(%)で示した。
The self-weight peeling rate (n = 15) indicates how many pieces of self-weight have been peeled off as a percentage (%).

焼成歩留は、下記式で測定した値の平均値で示した。
The firing yield was expressed as an average value of values measured by the following formula.

その他の評価項目では、下記の評価基準に従って、1〜5点の評点をつけた。
剥離強度は、鉄板を逆さまにした際、自重で落下しない豚肉を箸で鉄板から引き剥がした際にかかる力を5段階で評価した。
5点: 端や一部分のみが鉄板に付着し、簡単に剥離することができる
4点: 部分的に鉄板に付着し、軽い力で剥離することができる
3点: 部分的に鉄板に付着し、やや強い力で剥離することができる
2点: ほぼ全体が鉄板に付着し、強い力を入れないと剥離することができない
1点: 全体が鉄板に付着し、強い力を入れないと剥離することができない
For other evaluation items, 1-5 points were assigned according to the following evaluation criteria.
The peel strength was evaluated on a five-point scale when the iron plate was turned upside down and the pork that did not fall under its own weight was peeled off from the iron plate with chopsticks.
5 points: Only the edge or part adheres to the iron plate and can be easily peeled off
4 points: Partially adheres to the iron plate and can be peeled off with light force
3 points: Partially adheres to the iron plate and can be peeled off with a slightly strong force
2 points: Almost all adhere to the iron plate and cannot be peeled off unless a strong force is applied.
1 point: The whole adheres to the iron plate and cannot be peeled off unless a strong force is applied.

製品の外観は、焼きあがった豚肉の焼成面の外観を5段階で評価した。
5点: 表面が美しく、食欲をそそる好ましいこげ感が残っている
4点: 表面が一部ささくれ立っているが好ましいこげ感は残っている
3点: 表面が一部ささくれ立ち、好ましいこげは残っていない
2点: 表面全体がささくれ立ち、一部分がちぎれるなどしている
1点: 表面全体がささくれ立ち、製品の形をとどめていない
As for the appearance of the product, the appearance of the baked pork surface was evaluated in five levels.
5 points: The surface is beautiful and the appetizing sensation is still good
4 points: The surface is partly raised but still has a favorable burn feeling
3 points: The surface is partly raised and no good burn remains
2 points: The whole surface stands up and some parts are broken.
1 point: The whole surface flutters and does not keep the shape of the product

カス残量は、焼成試験後の鉄板に残ったカスの残量と状態を5段階で評価した。
5点: 肉片のこびりつきは見られず、跡形がわずかに残っている
4点: 一部肉片のこびりつきがみられ、跡形はわずかに残っている
3点: 一部肉片のこびりつきがみられ、製品の型が比較的残っている
2点: 肉片が多くこびりつき、製品の型がはっきりと残っている
1点: 肉片が多くこびりつき、製品の一部が鉄板に残っている
As for the remaining amount of residue, the remaining amount and state of residue remaining on the iron plate after the firing test were evaluated in five stages.
5 points: There is no sticking of meat pieces, and a trace remains
4 points: Some pieces of meat are stuck, and traces remain slightly
3 points: Some pieces of meat are stuck, and the product mold remains relatively
2 points: Lots of meat sticks and the product mold remains clearly
1 point: Many pieces of meat stick, and part of the product remains on the iron plate

カスの拭き取りは、カスの付着した鉄板を熱湯に20秒ほど浸した後、キムワイプなどでふき取った際の拭き取りやすさを5段階で評価した。
5点: 熱湯に浸した時点でカスや汚れがとれている
4点: 熱湯に浸した後、軽い力でカスや汚れがふき取れる
3点: 熱湯に浸した後、比較的強い力でカスや汚れがふき取れる
2点: 熱湯に浸した後、力を入れても一部のカスがとれない
1点: 熱湯に浸した後、力を入れても多くのカスがとれない
The wiping of the residue was evaluated on a five-point scale by wiping the iron plate with residue attached in hot water for about 20 seconds and then wiping with a Kim wipe.
5 points: Waste and dirt are removed when immersed in hot water
4 points: After dipping in hot water, you can wipe off dirt and dirt with a light force
3 points: After dipping in hot water, scraps and dirt can be wiped off with a relatively strong force
2 points: After dipping in hot water, some debris cannot be removed even if force is applied
1 point: After dipping in hot water, even if force is applied, many wastes cannot be removed

風味試験は、以下の基準で5段階評価した。
5点: 非常に風味がよくおいしい
4点: 風味がよくある程度のおいしさがある
3点: 風味特によいとは言えず、特においしくもまずくもない
2点: 食品本来の風味と異なる風味がややあり、風味がややよくない
1点: 食品本来の風味と異なる風味がはっきりとあり、非常に風味がよくない
The flavor test was evaluated in five stages according to the following criteria.
5 points: very tasty and delicious
4 points: Flavor is good and there is some taste
3 points: Flavor is not particularly good, not particularly delicious or bad
2 points: There is a slightly different flavor from the original flavor of food, and the flavor is not good.
1 point: There is a distinct flavor different from the original flavor of food, and the flavor is not very good

以上の評価結果を、表5〜8に示す。
The above evaluation results are shown in Tables 5-8.

本発明に従う調理用油脂組成物は、
・実施例3において、やや粘度が高い
・実施例4において、若干の乳化剤の析出、若干の粘度の不均一
・実施例8および11において、若干の乳化剤の析出
・実施例17において、若干の二酸化ケイ素の分離、粘度の増大による若干の作業性の難
・実施例18において、若干の二酸化ケイ素の分離、粘度の不均一による若干の作業性の難
・実施例19において若干のレシチンの分離
という性状が見られた。しかし、これらは、調理用油脂組成物として使用するのに致命的な欠陥というほどのことはなく、通常の使用に耐えられるものであった。また、使用者の判断によって、調理用油脂組成物として使用できるものであった。これらの実施例におけるその他の評価項目では、調理用油脂組成物として不適当な結果はなく、優れた特性を示した。
The cooking oil / fat composition according to the present invention comprises:
In Example 3, the viscosity is slightly higher. In Example 4, some emulsifier precipitates and some inhomogeneity in viscosity. In Examples 8 and 11, some emulsifiers precipitate. In Example 17, some dioxide. Separation of silicon, difficulty in workability due to viscosity increase ・ In Example 18, some separation of silicon dioxide, slight difficulty in workability due to non-uniform viscosity ・ Property of separation of lecithin in Example 19 It was observed. However, these were not so fatal as to be used as cooking oil and fat compositions, and could withstand normal use. Moreover, according to a user's judgment, it could be used as a cooking oil and fat composition. In the other evaluation items in these examples, there was no unsuitable result as a cooking oil and fat composition, and excellent characteristics were shown.

その他の実施例では、保存性、加熱調理の離型性、製品の焼成歩留、剥離強度、製品の外観、カス残量、カスの拭き取り、風味試験のいずれも、調理用油脂組成物として優れた特性を有した。   In other examples, storability, releasability of cooking, baking yield of products, peel strength, appearance of products, remaining amount of residue, wiping residue, and flavor test are all excellent as cooking oils and fat compositions. Had the characteristics.

比較例1〜5では、一部の項目では調理用油脂組成物として求められる性能を持ってはいるが、保存性、加熱調理の離型性、製品の焼成歩留、剥離強度、製品外観、カス残量、カスの拭き取り、風味試験のいずれかに調理用油脂組成物として評点が2以下になるなど、致命的に好ましくない結果が生じた。そのため、調理用油脂組成物としての使用が困難であると判断された。   In Comparative Examples 1 to 5, in some items, the performance required as a cooking oil / fat composition is possessed, but the preservability, mold release of cooking, baking yield of products, peel strength, product appearance, Fatally unfavorable results such as a score of 2 or less as a cooking oil / fat composition in any of the remaining amount of residue, wiping off residue, and flavor test occurred. Therefore, it was judged that the use as a cooking oil and fat composition was difficult.

Claims (6)

食用油脂、ポリグリセリン脂肪酸エステル、ポリグリセリン縮合リシノレイン酸エステル、微粒二酸化ケイ素、およびレシチンを含む調理用油脂組成物。   A cooking oil / fat composition comprising an edible oil / fat, a polyglycerin fatty acid ester, a polyglycerin condensed ricinoleic acid ester, fine silicon dioxide, and lecithin. 前記微粒二酸化ケイ素の含有量が、0.05〜10重量%であることを特徴とする請求項1に記載の調理用油脂組成物。   The cooking oil / fat composition according to claim 1, wherein the content of the fine silicon dioxide is 0.05 to 10% by weight. 粒子径が0.04μm以下の前記微粒二酸化ケイ素を、0.05〜5重量%含むことを特徴とする請求項1または2に記載の調理用油脂組成物。   The cooking oil / fat composition according to claim 1 or 2, comprising 0.05 to 5% by weight of the fine silicon dioxide having a particle size of 0.04 µm or less. 前記レシチンが、精製レシチンであることを特徴とする請求項1〜3のいずれか一項に記載の調理用油脂組成物。   The cooking oil composition according to any one of claims 1 to 3, wherein the lecithin is purified lecithin. 前記ポリグリセリン脂肪酸エステルが、実質的にジグリセリンモノオレイン酸エステルからなることを特徴とする請求項1〜4のいずれか一項に記載の調理用油脂組成物。   5. The cooking oil / fat composition according to any one of claims 1 to 4, wherein the polyglycerin fatty acid ester is substantially composed of diglycerin monooleate. 請求項1〜5のいずれか一項に記載の調理用油脂組成物を使用してなる食品。   The foodstuff which uses the oil-fat composition for cooking as described in any one of Claims 1-5.
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