JP2009035706A - ポリ乳酸系樹脂の製造方法 - Google Patents
ポリ乳酸系樹脂の製造方法 Download PDFInfo
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- JP2009035706A JP2009035706A JP2007299880A JP2007299880A JP2009035706A JP 2009035706 A JP2009035706 A JP 2009035706A JP 2007299880 A JP2007299880 A JP 2007299880A JP 2007299880 A JP2007299880 A JP 2007299880A JP 2009035706 A JP2009035706 A JP 2009035706A
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- Prior art keywords
- acid
- compound
- polylactic acid
- tin
- resin
- Prior art date
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- 229920005989 resin Polymers 0.000 title claims abstract description 75
- 239000011347 resin Substances 0.000 title claims abstract description 75
- 229920000747 poly(lactic acid) Polymers 0.000 title claims abstract description 67
- 239000004626 polylactic acid Substances 0.000 title claims abstract description 67
- 238000004519 manufacturing process Methods 0.000 title claims description 28
- -1 rare earth compound Chemical class 0.000 claims abstract description 63
- 238000000034 method Methods 0.000 claims abstract description 47
- 239000003054 catalyst Substances 0.000 claims abstract description 40
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 32
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000007790 solid phase Substances 0.000 claims abstract description 27
- 238000006068 polycondensation reaction Methods 0.000 claims abstract description 25
- 239000002904 solvent Substances 0.000 claims abstract description 21
- 239000004310 lactic acid Substances 0.000 claims abstract description 14
- 235000014655 lactic acid Nutrition 0.000 claims abstract description 14
- 150000003606 tin compounds Chemical class 0.000 claims abstract description 14
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 8
- 150000003609 titanium compounds Chemical class 0.000 claims abstract description 8
- 150000001869 cobalt compounds Chemical class 0.000 claims abstract description 7
- 150000002506 iron compounds Chemical class 0.000 claims abstract description 7
- 150000002611 lead compounds Chemical class 0.000 claims abstract description 7
- 150000002642 lithium compounds Chemical class 0.000 claims abstract description 7
- 150000003752 zinc compounds Chemical class 0.000 claims abstract description 7
- 239000010409 thin film Substances 0.000 claims description 26
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims description 18
- 239000002994 raw material Substances 0.000 claims description 10
- IUTCEZPPWBHGIX-UHFFFAOYSA-N tin(2+) Chemical compound [Sn+2] IUTCEZPPWBHGIX-UHFFFAOYSA-N 0.000 claims description 9
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 claims description 8
- PNOXNTGLSKTMQO-UHFFFAOYSA-L diacetyloxytin Chemical compound CC(=O)O[Sn]OC(C)=O PNOXNTGLSKTMQO-UHFFFAOYSA-L 0.000 claims description 8
- CCIVGXIOQKPBKL-UHFFFAOYSA-M ethanesulfonate Chemical compound CCS([O-])(=O)=O CCIVGXIOQKPBKL-UHFFFAOYSA-M 0.000 claims description 8
- 239000011342 resin composition Substances 0.000 claims description 5
- 229940098779 methanesulfonic acid Drugs 0.000 claims description 4
- 238000002844 melting Methods 0.000 abstract description 26
- 230000008018 melting Effects 0.000 abstract description 26
- 239000000463 material Substances 0.000 abstract description 8
- 230000002349 favourable effect Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 description 34
- JVTAAEKCZFNVCJ-REOHCLBHSA-N L-lactic acid Chemical compound C[C@H](O)C(O)=O JVTAAEKCZFNVCJ-REOHCLBHSA-N 0.000 description 29
- GRTOGORTSDXSFK-XJTZBENFSA-N ajmalicine Chemical compound C1=CC=C2C(CCN3C[C@@H]4[C@H](C)OC=C([C@H]4C[C@H]33)C(=O)OC)=C3NC2=C1 GRTOGORTSDXSFK-XJTZBENFSA-N 0.000 description 26
- 229910052757 nitrogen Inorganic materials 0.000 description 21
- 239000000126 substance Substances 0.000 description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 14
- 238000003756 stirring Methods 0.000 description 12
- 239000002253 acid Substances 0.000 description 11
- 239000008188 pellet Substances 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 238000002425 crystallisation Methods 0.000 description 10
- 230000008025 crystallization Effects 0.000 description 10
- 239000000843 powder Substances 0.000 description 10
- 239000007864 aqueous solution Substances 0.000 description 9
- 238000005227 gel permeation chromatography Methods 0.000 description 9
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 9
- 238000010992 reflux Methods 0.000 description 9
- JVTAAEKCZFNVCJ-UWTATZPHSA-N D-lactic acid Chemical compound C[C@@H](O)C(O)=O JVTAAEKCZFNVCJ-UWTATZPHSA-N 0.000 description 8
- 238000004898 kneading Methods 0.000 description 7
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 229940022769 d- lactic acid Drugs 0.000 description 6
- 239000000835 fiber Substances 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 6
- 229910019142 PO4 Inorganic materials 0.000 description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 5
- JJTUDXZGHPGLLC-UHFFFAOYSA-N lactide Chemical compound CC1OC(=O)C(C)OC1=O JJTUDXZGHPGLLC-UHFFFAOYSA-N 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 5
- 239000010452 phosphate Substances 0.000 description 5
- 230000035484 reaction time Effects 0.000 description 5
- 150000003460 sulfonic acids Chemical class 0.000 description 5
- MZZYGYNZAOVRTG-UHFFFAOYSA-N 2-hydroxy-n-(1h-1,2,4-triazol-5-yl)benzamide Chemical compound OC1=CC=CC=C1C(=O)NC1=NC=NN1 MZZYGYNZAOVRTG-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- 239000003377 acid catalyst Substances 0.000 description 4
- 229910052797 bismuth Inorganic materials 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- FRXGWNKDEMTFPL-UHFFFAOYSA-N dioctadecyl hydrogen phosphate Chemical compound CCCCCCCCCCCCCCCCCCOP(O)(=O)OCCCCCCCCCCCCCCCCCC FRXGWNKDEMTFPL-UHFFFAOYSA-N 0.000 description 4
- 239000011261 inert gas Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 150000003018 phosphorus compounds Chemical class 0.000 description 4
- 239000012321 sodium triacetoxyborohydride Substances 0.000 description 4
- 150000005846 sugar alcohols Polymers 0.000 description 4
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 4
- BYEAHWXPCBROCE-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropan-2-ol Chemical compound FC(F)(F)C(O)C(F)(F)F BYEAHWXPCBROCE-UHFFFAOYSA-N 0.000 description 3
- XZOYHFBNQHPJRQ-UHFFFAOYSA-N 7-methyloctanoic acid Chemical compound CC(C)CCCCCC(O)=O XZOYHFBNQHPJRQ-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- 229930182843 D-Lactic acid Natural products 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 239000012298 atmosphere Substances 0.000 description 3
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000004927 clay Substances 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 238000011437 continuous method Methods 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000010408 film Substances 0.000 description 3
- 150000002596 lactones Chemical class 0.000 description 3
- 229910052744 lithium Inorganic materials 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 229940091250 magnesium supplement Drugs 0.000 description 3
- UHGIMQLJWRAPLT-UHFFFAOYSA-N octadecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCCCCCCCOP(O)(O)=O UHGIMQLJWRAPLT-UHFFFAOYSA-N 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 229920001432 poly(L-lactide) Polymers 0.000 description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 3
- 239000004926 polymethyl methacrylate Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 150000003568 thioethers Chemical class 0.000 description 3
- 235000010215 titanium dioxide Nutrition 0.000 description 3
- 229960000984 tocofersolan Drugs 0.000 description 3
- YJGJRYWNNHUESM-UHFFFAOYSA-J triacetyloxystannyl acetate Chemical compound [Sn+4].CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O YJGJRYWNNHUESM-UHFFFAOYSA-J 0.000 description 3
- 229940088594 vitamin Drugs 0.000 description 3
- 235000013343 vitamin Nutrition 0.000 description 3
- 239000011782 vitamin Substances 0.000 description 3
- 229930003231 vitamin Natural products 0.000 description 3
- SSADPHQCUURWSW-UHFFFAOYSA-N 3,9-bis(2,6-ditert-butyl-4-methylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound CC(C)(C)C1=CC(C)=CC(C(C)(C)C)=C1OP1OCC2(COP(OC=3C(=CC(C)=CC=3C(C)(C)C)C(C)(C)C)OC2)CO1 SSADPHQCUURWSW-UHFFFAOYSA-N 0.000 description 2
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- ZVVFVKJZNVSANF-UHFFFAOYSA-N 6-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]hexyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCCCCCCOC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 ZVVFVKJZNVSANF-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
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- ZAKOWWREFLAJOT-CEFNRUSXSA-N D-alpha-tocopherylacetate Chemical compound CC(=O)OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-CEFNRUSXSA-N 0.000 description 2
- 239000011627 DL-alpha-tocopherol Substances 0.000 description 2
- 235000001815 DL-alpha-tocopherol Nutrition 0.000 description 2
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- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- FRCLQKLLFQYUJJ-UHFFFAOYSA-N P(O)(O)O.P(O)(O)O.C(C)(C)(C)C1=C(C(=CC(=C1)C)C(C)(C)C)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1C(C)(C)C)C)C(C)(C)C Chemical compound P(O)(O)O.P(O)(O)O.C(C)(C)(C)C1=C(C(=CC(=C1)C)C(C)(C)C)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1C(C)(C)C)C)C(C)(C)C FRCLQKLLFQYUJJ-UHFFFAOYSA-N 0.000 description 2
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 2
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- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
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- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 2
- DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 description 2
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- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
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- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- GUNJVIDCYZYFGV-UHFFFAOYSA-K antimony trifluoride Chemical compound F[Sb](F)F GUNJVIDCYZYFGV-UHFFFAOYSA-K 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 150000007942 carboxylates Chemical class 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
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- 238000009835 boiling Methods 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
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- NZPIUJUFIFZSPW-UHFFFAOYSA-H lanthanum carbonate Chemical compound [La+3].[La+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O NZPIUJUFIFZSPW-UHFFFAOYSA-H 0.000 description 1
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- WQKGAJDYBZOFSR-UHFFFAOYSA-N potassium;propan-2-olate Chemical compound [K+].CC(C)[O-] WQKGAJDYBZOFSR-UHFFFAOYSA-N 0.000 description 1
- HKJYVRJHDIPMQB-UHFFFAOYSA-N propan-1-olate;titanium(4+) Chemical compound CCCO[Ti](OCCC)(OCCC)OCCC HKJYVRJHDIPMQB-UHFFFAOYSA-N 0.000 description 1
- HJCRVWSKQNDSPZ-UHFFFAOYSA-N propan-2-olate;samarium(3+) Chemical compound [Sm+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] HJCRVWSKQNDSPZ-UHFFFAOYSA-N 0.000 description 1
- PYLIDHFYDYRZSC-UHFFFAOYSA-N propan-2-olate;yttrium(3+) Chemical compound [Y+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] PYLIDHFYDYRZSC-UHFFFAOYSA-N 0.000 description 1
- ZGSOBQAJAUGRBK-UHFFFAOYSA-N propan-2-olate;zirconium(4+) Chemical compound [Zr+4].CC(C)[O-].CC(C)[O-].CC(C)[O-].CC(C)[O-] ZGSOBQAJAUGRBK-UHFFFAOYSA-N 0.000 description 1
- AABBHSMFGKYLKE-SNAWJCMRSA-N propan-2-yl (e)-but-2-enoate Chemical compound C\C=C\C(=O)OC(C)C AABBHSMFGKYLKE-SNAWJCMRSA-N 0.000 description 1
- TYQYYJYAFIATKG-UHFFFAOYSA-N propan-2-yloxytin Chemical compound CC(C)O[Sn] TYQYYJYAFIATKG-UHFFFAOYSA-N 0.000 description 1
- KCXFHTAICRTXLI-UHFFFAOYSA-N propane-1-sulfonic acid Chemical compound CCCS(O)(=O)=O KCXFHTAICRTXLI-UHFFFAOYSA-N 0.000 description 1
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- 125000001501 propionyl group Chemical group O=C([*])C([H])([H])C([H])([H])[H] 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
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- JPDBEEUPLFWHAJ-UHFFFAOYSA-K samarium(3+);triacetate Chemical compound [Sm+3].CC([O-])=O.CC([O-])=O.CC([O-])=O JPDBEEUPLFWHAJ-UHFFFAOYSA-K 0.000 description 1
- LVSITDBROURTQX-UHFFFAOYSA-H samarium(3+);trisulfate Chemical compound [Sm+3].[Sm+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O LVSITDBROURTQX-UHFFFAOYSA-H 0.000 description 1
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- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
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- GROMGGTZECPEKN-UHFFFAOYSA-N sodium metatitanate Chemical compound [Na+].[Na+].[O-][Ti](=O)O[Ti](=O)O[Ti]([O-])=O GROMGGTZECPEKN-UHFFFAOYSA-N 0.000 description 1
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- VEALVRVVWBQVSL-UHFFFAOYSA-N strontium titanate Chemical compound [Sr+2].[O-][Ti]([O-])=O VEALVRVVWBQVSL-UHFFFAOYSA-N 0.000 description 1
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Abstract
【解決手段】乳酸を主原料として、直接重縮合により、ポリ乳酸系樹脂を製造する方法であって、薄膜蒸発機を用いて、重縮合を行った後、固相重合することを特徴とするポリ乳酸系樹脂の製造方法であって、好ましくは、無溶媒下で行うこと、触媒として、錫化合物、チタン化合物、鉛化合物、亜鉛化合物、コバルト化合物、鉄化合物、リチウム化合物、希土類化合物、スルホン酸化合物から選択されるいずれか1種以上を用いることを特徴とするポリ乳酸系樹脂の製造方法。
【選択図】 なし
Description
(1)乳酸を主原料として、直接重縮合により、ポリ乳酸系樹脂を製造する方法であって、薄膜蒸発機を用いて、重縮合を行った後、固相重合することを特徴とするポリ乳酸系樹脂の製造方法、
(2)無溶媒下で行うことを特徴とする(1)に記載のポリ乳酸系樹脂の製造方法、
(3)触媒を用いることを特徴とする(1)〜(2)のいずれかに記載のポリ乳酸系樹脂の製造方法、
(4)前記触媒として、錫化合物、チタン化合物、鉛化合物、亜鉛化合物、コバルト化合物、鉄化合物、リチウム化合物、希土類化合物、スルホン酸化合物から選択されるいずれか1種以上を用いることを特徴とする(1)〜(3)のいずれかに記載のポリ乳酸系樹脂の製造方法、
(5)前記触媒として、錫化合物から選択される1種以上およびスルホン酸化合物から選択される1種以上を用いることを特徴とする(1)〜(3)のいずれかに記載のポリ乳酸系樹脂の製造方法、
(6)錫化合物が、酢酸錫(II)および/またはオクチル酸錫(II)であり、スルホン酸化合物が、メタンスルホン酸および/またはエタンスルホン酸であることを特徴とする(5)に記載のポリ乳酸系樹脂の製造方法、
(7)(1)〜(5)のいずれかに記載の製造方法により得られるポリ乳酸系樹脂を含む樹脂組成物、
(8)(7)に記載の樹脂組成物からなる成形品、
である。
トリアゾール系化合物の具体例としては、ベンゾトリアゾール、3−(N−サリシロイル)アミノ−1,2,4−トリアゾールなどが挙げられる。
ヒドラジン誘導体系化合物の具体例としては、デカメチレンジカルボキシリックアシッド−ビス(N’−サリシロイルヒドラジド)、イソフタル酸ビス(2−フェノキシプロピオニルヒドラジド)、N−ホルミル−N’−サリシロイルヒドラジン、2,2−オキザミドビス−[エチル−3−(3,5−ジ−t−ブチル−4−ハイドロオキシフェニル)プロピオネート]、オギザリル−ビス−ベンジリデン−ヒドラジド、ニッケル−ビス(1−フェニル−3−メチル−4−デカノイル−5−ピラゾレート)、2−エトキシ−2’−エチルオキサニリド、5−t−ブチル−2−エトキシ−2’−エチルオキサニリド、N,N−ジエチル−N’,N’−ジフェニルオキサミド、N,N’−ジエチル−N,N’−ジフェニルオキサミド、オキサリックアシッド−ビス(ベンジリデンヒドラジド)、チオジプロピオニックアシッド−ビス(ベンジリデンヒドラジド)、ビス(サリシロイルヒドラジン)、N−サリシリデン−N’−サリシロイルヒドラゾン、N,N’−ビス[3−(3,5−ジ−t−ブチル−4−ヒドロキシフェニル)プロピオニル]ヒドラジン、N,N’−ビス[2−〔3−(3,5−ジ−t−ブチル−4−ヒドロキシフェニル)プロピオニルオキシ〕エチル]オキサミドなどが挙げられる。
ゲルパーミエーションクロマトグラフィー(GPC)により測定した標準ポリメチルメタクリレート換算の重量平均分子量の値である。GPCの測定は、検出器にWATERS社示差屈折計WATERS410を用い、ポンプにMODEL510高速液体クロマトグラフィーを用い、カラムにShodex GPC HFIP−806MとShodex GPC HFIP−LGを直列に接続したものを用いて行った。測定条件は、流速0.5mL/minとし、溶媒にヘキサフルオロイソプロパノールを用い、試料濃度1mg/mLの溶液を0.1mL注入した。
示差走査型熱量計(DSC)により測定した値であり、 パーキンエルマー製DSC7を用い、測定条件は、試料10mg、窒素雰囲気下中、昇温速度20℃/分で行った。
熱重量測定装置(TGA)により測定した値であり、パーキンエルマー製TGA7を用い、測定条件として、試料2mg、窒素雰囲気下中、220℃で30分保持したときの重量保持率から判断した。重量保持率が大きいものほど熱安定性に優れると言える。
目視判断より、下記基準を用いて判断した。
5:無着色
4:3と5の中間
3:やや黄着色
2:1と3の中間
1:着色大
[参考例1]
撹拌装置および還流装置のついた反応容器中に、90%L−乳酸水溶液100部を入れ、温度を160℃にした後、徐々に減圧して800Paとし、水を除去しながら4時間反応させ、Mw4000の低分子量体I(A−1)を得た。そこへ、触媒として酢酸錫(II)0.5部を添加し、170℃、600Paで4時間反応させ、Mw18000の低分子量体II(B−1)を得た。
撹拌装置および還流装置のついた反応容器中に、90%L−乳酸水溶液100部を入れ、温度を160℃にした後、徐々に減圧して800Paとし、水を除去しながら4時間反応させ、Mw4000の低分子量体I(A−2)を得た。そこへ、触媒として酢酸サマリウム4水和物0.5部を添加し、170℃、600Paで4時間反応させ、Mw17000の低分子量体II(B−2)を得た。
撹拌装置および還流装置のついた反応容器中に、90%L−乳酸水溶液100部を入れ、温度を160℃にした後、徐々に減圧して800Paとし、水を除去しながら4時間反応させ、Mw4000の低分子量体I(A−3)を得た。そこへ、触媒として酢酸コバルト(II)0.5部を添加し、170℃、600Paで4時間反応させ、Mw12000の低分子量体II(B−3)を得た。
撹拌装置および還流装置のついた反応容器中に、90%L−乳酸水溶液100部を入れ、温度を140℃にした後、徐々に減圧して800Paとし、水を除去しながら2時間反応させ、次いで、温度を160℃に昇温した後、2時間反応させ、Mw4500の低分子量体I(A−4)を得た。そこへ、触媒として酢酸錫(II)0.2部およびエタンスルホン酸0.8部を添加し、170℃、600Paで4時間反応させ、Mw15000の低分子量体II(B−4)を得た。
撹拌装置および還流装置のついた反応容器中に、90%L−乳酸水溶液100部を入れ、温度を140℃にした後、徐々に減圧して800Paとし、水を除去しながら2時間反応させ、次いで、温度を160℃に昇温した後、2時間反応させ、Mw4500の低分子量体I(A−5)を得た。そこへ、触媒としてオクチル酸錫(II)0.2部およびエタンスルホン酸0.8部を添加し、170℃、600Paで4時間反応させ、Mw17000の低分子量体II(B−5)を得た。
撹拌装置および還流装置のついた反応容器中に、90%L−乳酸水溶液100部を入れ、温度を140℃にした後、徐々に減圧して800Paとし、水を除去しながら2時間反応させ、次いで、温度を160℃に昇温した後、2時間反応させ、Mw4500の低分子量体I(A−6)を得た。そこへ、触媒としてオクチル酸錫(II)0.2部およびメタンスルホン酸0.8部を添加し、170℃、600Paで4時間反応させ、Mw16000の低分子量体II(B−6)を得た。
参考例1で得た低分子量体II(B−1)を内径155mmφ×高さ430mmの円筒と該円筒内壁と2mmのクリアランスを保って回転する傾斜多撹拌翼からなる縦型撹拌式薄膜蒸発機(樹脂温度:170〜180℃、減圧度:50〜600Pa、撹拌翼回転数:800〜1000rpm)に導入し、溶融状態かつ減圧下で処理することにより重合を行った後、30mmφ、L/D=42の二軸押出機に供給し、ペレット状プレポリマー(C−1)を得た。このペレットを、熱風乾燥機を用い、120℃で2時間結晶化処理を行った後、真空乾燥機を用いて、145℃、50Paの条件下で、30時間固相重合し、ポリ乳酸系樹脂(D−1)を得た。結果を表1に示す。
参考例2で得た低分子量体II(B−2)を用いる以外は、実施例1と同様にして行った。結果を表1に示す。
参考例3で得た低分子量体II(B−3)を用いる以外は、実施例1と同様にして行った。結果を表1に示す。
参考例4で得た低分子量体II(B−4)を用いる以外は、実施例1と同様にして行った。結果を表1に示す。
参考例5で得た低分子量体II(B−5)を用いる以外は、実施例1と同様にして行った。結果を表1に示す。
参考例6で得た低分子量体II(B−6)を用いる以外は、実施例1と同様にして行った。結果を表1に示す。
塔型反応器を用い、常圧、窒素気流下で、155℃で30時間固相重合する以外は、実施例4と同様に行った。結果を表1に示す。
固相重合後に得られるポリ乳酸系樹脂100部に対し、触媒失活剤(AX−71)0.5部を、30mmφ、L/D=42の二軸押出機を用いて、溶融混練し、ペレット状のポリ乳酸系樹脂(E−8)とする以外は、実施例7と同様に行った。結果を表1に示す。
撹拌装置および還流装置のついた反応容器中に、90%L−乳酸水溶液100部を入れ、温度を140℃にした後、徐々に減圧して800Paとし、水を除去しながら2時間反応させ、次いで、温度を160℃に昇温した後、2時間反応させ、Mw4500の低分子量体I(A−9)を得た。そこへ、触媒としてオクチル酸錫(II)0.2部およびエタンスルホン酸0.8部を添加し、均一に混合した液状物を、実施例1で用いた縦型撹拌式薄膜蒸発機を直列に2台接続した装置に供給し、1台目については、樹脂温度:160〜170℃、減圧度:50〜600Pa、撹拌翼回転数:800〜1000rpmで反応させ、2台目については、樹脂温度:170〜180℃、減圧度:50〜600Pa、撹拌翼回転数:800〜1000rpmで反応させ、溶融状態かつ減圧下で処理することにより重合を行った後、30mmφ、L/D=42の二軸押出機に供給し、ペレット状プレポリマー(C−9)を得た。このペレットを、熱風乾燥機を用い、120℃で2時間結晶化処理を行った後、塔型反応器を用い、常圧、窒素気流下で、155℃で30時間固相重合し、ポリ乳酸系樹脂(D−9)を得た。さらに、30mmφ、L/D=42の二軸押出機を用いて、ポリ乳酸系樹脂(D−9)100部に対し、触媒失活剤(AX−71)0.5部を、溶融混練し、ペレット状のポリ乳酸系樹脂(E−9)を得た。結果を表1に示す。
撹拌装置および還流装置のついた反応容器中に、90%L−乳酸水溶液100部を入れ、温度を160℃にした後、徐々に減圧して800Paとし、水を除去しながら4時間反応させ、Mw4000の低分子量体I(CA−1)を得た。そこへ、触媒として酢酸錫(II)0.5部を添加し、170℃、600Paで10時間反応させ後、30mmφ、L/D=42の二軸押出機に供給し、Mw40000のペレット状低分子量体II(CB−1)を得た。この低分子量体II(CB−1)を熱風乾燥機を用い、120℃で2時間結晶化処理を行った後、真空乾燥機を用いて、145℃、50Paの条件下で、30時間固相重合し、ポリ乳酸系樹脂(CD−1)を得た。結果を表1に示す。
撹拌装置および還流装置のついた反応容器中に、90%L−乳酸水溶液100部を入れ、温度を160℃にした後、徐々に減圧して800Paとし、水を除去しながら4時間反応させ、Mw4000の低分子量体I(CA−2)を得た。そこへ、触媒として酢酸錫(II)0.5部を添加し、170℃、600Paで4時間反応させ、Mw18000の低分子量体II(CB−2)を得た。この低分子量体II(CB−2)を内径155mmφ×高さ430mmの円筒と該円筒内壁と2mmのクリアランスを保って回転する傾斜多撹拌翼からなる縦型撹拌式薄膜蒸発機を3台接続した装置に導入し、樹脂温度:170〜180℃、減圧度:50〜600Pa、撹拌翼回転数:800〜1000rpmで反応させ、溶融状態かつ減圧下で処理することにより重合を行い、ポリ乳酸系樹脂(CC−2)を得た。結果を表1に示す。
Claims (8)
- 乳酸を主原料として、直接重縮合により、ポリ乳酸系樹脂を製造する方法であって、薄膜蒸発機を用いて、重縮合を行った後、固相重合することを特徴とするポリ乳酸系樹脂の製造方法。
- 無溶媒下で行うことを特徴とする請求項1に記載のポリ乳酸系樹脂の製造方法。
- 触媒を用いることを特徴とする請求項1〜2のいずれかに記載のポリ乳酸系樹脂の製造方法。
- 前記触媒として、錫化合物、チタン化合物、鉛化合物、亜鉛化合物、コバルト化合物、鉄化合物、リチウム化合物、希土類化合物、スルホン酸化合物から選択されるいずれか1種以上を用いることを特徴とする請求項1〜3のいずれかに記載のポリ乳酸系樹脂の製造方法。
- 前記触媒として、錫化合物から選択される1種以上およびスルホン酸化合物から選択される1種以上を用いることを特徴とする請求項1〜3のいずれかに記載のポリ乳酸系樹脂の製造方法。
- 錫化合物が、酢酸錫(II)および/またはオクチル酸錫(II)であり、スルホン酸化合物が、メタンスルホン酸および/またはエタンスルホン酸であることを特徴とする請求項5記載のポリ乳酸系樹脂の製造方法。
- 請求項1〜6のいずれかに記載の製造方法により得られるポリ乳酸系樹脂を含む樹脂組成物。
- 請求項7に記載の樹脂組成物からなる成形品。
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016516870A (ja) * | 2013-04-26 | 2016-06-09 | ザイレコ,インコーポレイテッド | ポリマーへのヒドロキシ−カルボン酸の加工処理 |
CN106146817A (zh) * | 2015-04-21 | 2016-11-23 | 上海浦景化工新材料有限公司 | 羟基烷酸锌聚酯催化剂,其制备方法以及该催化剂的应用 |
US10501761B2 (en) | 2013-04-26 | 2019-12-10 | Xyleco, Inc. | Processing biomass to obtain hydroxylcarboxylic acids |
CN117922124A (zh) * | 2024-03-12 | 2024-04-26 | 嘉兴富瑞邦新材料科技有限公司 | 一种纳米纤维复合空气净化滤材及其制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06306149A (ja) * | 1993-04-22 | 1994-11-01 | Mitsui Toatsu Chem Inc | ポリヒドロキシカルボン酸の製造方法 |
JP2001089558A (ja) * | 1999-07-19 | 2001-04-03 | Mitsui Chemicals Inc | 生分解性を有する脂肪族系ポリエステルの製造方法 |
JP2004051729A (ja) * | 2002-07-18 | 2004-02-19 | Asahi Kasei Chemicals Corp | グリコール酸共重合体賦形化物の製造方法 |
JP2007070413A (ja) * | 2005-09-05 | 2007-03-22 | Teijin Ltd | ポリ乳酸組成物およびその製造方法 |
WO2007037673A1 (en) * | 2005-09-28 | 2007-04-05 | Tate & Lyle Public Limited Company | Novel process for the preparation of polylactic acid |
-
2007
- 2007-11-19 JP JP2007299880A patent/JP5292775B2/ja active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06306149A (ja) * | 1993-04-22 | 1994-11-01 | Mitsui Toatsu Chem Inc | ポリヒドロキシカルボン酸の製造方法 |
JP2001089558A (ja) * | 1999-07-19 | 2001-04-03 | Mitsui Chemicals Inc | 生分解性を有する脂肪族系ポリエステルの製造方法 |
JP2004051729A (ja) * | 2002-07-18 | 2004-02-19 | Asahi Kasei Chemicals Corp | グリコール酸共重合体賦形化物の製造方法 |
JP2007070413A (ja) * | 2005-09-05 | 2007-03-22 | Teijin Ltd | ポリ乳酸組成物およびその製造方法 |
WO2007037673A1 (en) * | 2005-09-28 | 2007-04-05 | Tate & Lyle Public Limited Company | Novel process for the preparation of polylactic acid |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016516870A (ja) * | 2013-04-26 | 2016-06-09 | ザイレコ,インコーポレイテッド | ポリマーへのヒドロキシ−カルボン酸の加工処理 |
US10174160B2 (en) | 2013-04-26 | 2019-01-08 | Xyleco, Inc. | Processing hydroxy-carboxylic acids to polymers |
CN110272535A (zh) * | 2013-04-26 | 2019-09-24 | 希乐克公司 | 将羟基羧酸加工成聚合物 |
US10501761B2 (en) | 2013-04-26 | 2019-12-10 | Xyleco, Inc. | Processing biomass to obtain hydroxylcarboxylic acids |
CN106146817A (zh) * | 2015-04-21 | 2016-11-23 | 上海浦景化工新材料有限公司 | 羟基烷酸锌聚酯催化剂,其制备方法以及该催化剂的应用 |
CN117922124A (zh) * | 2024-03-12 | 2024-04-26 | 嘉兴富瑞邦新材料科技有限公司 | 一种纳米纤维复合空气净化滤材及其制备方法 |
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